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JP2014056672A - Power storage device and manufacturing method of power storage device - Google Patents

Power storage device and manufacturing method of power storage device Download PDF

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Publication number
JP2014056672A
JP2014056672A JP2012199734A JP2012199734A JP2014056672A JP 2014056672 A JP2014056672 A JP 2014056672A JP 2012199734 A JP2012199734 A JP 2012199734A JP 2012199734 A JP2012199734 A JP 2012199734A JP 2014056672 A JP2014056672 A JP 2014056672A
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positive electrode
contact portion
electrode
contact
power storage
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Toshio Odagiri
俊雄 小田切
Takahisa Sugimoto
貴久 杉本
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Toyota Industries Corp
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Toyota Industries Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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Abstract

PROBLEM TO BE SOLVED: To provide a power storage device in which, at a position away from a contact part for contacting a resistance-welding electrode, a metal exposed part group in which metal exposed parts of an electrode are overlapped in a layered manner, and an electrode terminal can be welded, and a manufacturing method of the power storage device.SOLUTION: A positive electrode collector tab group 24a in which positive electrode collector tabs 24 exposing positive electrode metal foils 21 are overlapped in a layered manner includes a contact part 33 to which a welding electrode 32 is contacted, and a press-contact part 35 in which the positive electrode collector tabs 24 constituting the positive electrode collector tab group 24a are press-contacted with each other. The press-contact part 35 is provided at such a position that at least a portion in the press-contact part 35 is not overlapped with the contact part 33, and welded with a positive electrode conductive member 30 in at least a portion that is not overlapped with the contact part 33, in the press-contact part 35.

Description

本発明は、蓄電装置、及び蓄電装置の製造方法に関する。   The present invention relates to a power storage device and a method for manufacturing the power storage device.

従来から、EV(Electric Vehicle)やPHV(Plug-in Hybrid Vehicle)などの車両に搭載される蓄電装置としては、リチウムイオン二次電池やニッケル水素二次電池などがよく知られている。これらの二次電池の中には、金属箔の表面に活物質層を形成した電極を、間にセパレータを介在させた状態で積層又は巻回するなどして電極組立体を形成するとともに、該電極組立体を電極端子が固定されたケースに収容したものがある。   Conventionally, lithium-ion secondary batteries, nickel-hydrogen secondary batteries, and the like are well known as power storage devices mounted on vehicles such as EVs (Electric Vehicles) and PHVs (Plug-in Hybrid Vehicles). In these secondary batteries, an electrode assembly is formed by laminating or winding an electrode in which an active material layer is formed on the surface of a metal foil with a separator interposed therebetween, and the like. Some electrode assemblies are housed in cases in which electrode terminals are fixed.

そして、特許文献1では、例えば電極組立体において電極の縁部から突出する金属箔の露出部が層状に重なった金属露出部群と、電極端子とを抵抗溶接で溶接するにあたり、抵抗溶接用の電極と接触する部分において、金属露出部群を貫通する小孔などを予め設けて導電性を高め、金属露出部群と電極端子との抵抗溶接を容易にしている。   In Patent Document 1, for example, when welding an exposed portion of a metal foil projecting from an edge portion of an electrode in an electrode assembly in a layered manner and an electrode terminal by resistance welding, resistance welding is performed. A small hole or the like penetrating the metal exposed portion group is provided in advance at the portion in contact with the electrode to enhance conductivity, and resistance welding between the metal exposed portion group and the electrode terminal is facilitated.

特開2006−326622号公報JP 2006-326622 A

ところで、近時の二次電池では、二次電池としてのエネルギ密度を向上させる観点からケース内における作業スペースが少なくなっており、特許文献1のように、金属露出部群と電極端子とを抵抗溶接しようとする部分に、抵抗溶接用の電極を接触させることが困難な場合がある。   By the way, in the recent secondary battery, the working space in the case is reduced from the viewpoint of improving the energy density as the secondary battery, and the metal exposed portion group and the electrode terminal are resisted as in Patent Document 1. It may be difficult to bring the resistance welding electrode into contact with the portion to be welded.

この発明は、上記従来技術に存在する問題点に着目してなされたものであり、その目的は、抵抗溶接用の電極を接触させる接触部から離間した位置において、電極の金属露出部が層状に重なる金属露出部群と電極端子とを溶接できる蓄電装置、及び蓄電装置の製造方法を提供することにある。   The present invention has been made paying attention to the problems existing in the above prior art, and its purpose is that the exposed metal portion of the electrode is layered at a position separated from the contact portion where the electrode for resistance welding is brought into contact. An object of the present invention is to provide a power storage device capable of welding overlapping metal exposed portion groups and electrode terminals, and a method for manufacturing the power storage device.

上記課題を解決するために、請求項1に記載の発明は、金属箔の表面に活物質層を形成した電極と、前記電極間を絶縁するセパレータとを有し前記電極が前記セパレータを間に介在させた状態で層状に重なる電極組立体と、前記電極組立体を収容するとともに電極端子が固定されるケースと、を備えた蓄電装置であって、前記電極組立体は、前記電極のうち金属箔が露出する金属露出部が層状に重なる金属露出部群を有し、前記金属露出部群には、抵抗溶接用の電極が接触される接触部と、前記金属露出部群を構成する金属露出部同士が互いに圧接された圧接部とが設けられており、前記圧接部は、該圧接部における少なくとも一部が前記接触部とは重ならない位置に設けられるとともに、該圧接部のうち少なくとも前記接触部とは重ならない部分において前記電極端子と溶接されていることを要旨とする。   In order to solve the above-mentioned problem, the invention described in claim 1 includes an electrode in which an active material layer is formed on a surface of a metal foil, and a separator that insulates between the electrodes, and the electrode is interposed between the separators. A power storage device comprising: an electrode assembly that is layered in an interposed state; and a case that accommodates the electrode assembly and has an electrode terminal fixed thereto, wherein the electrode assembly is a metal among the electrodes. The metal exposed portion group in which the metal exposed portion where the foil is exposed overlaps in layers, and the metal exposed portion group includes a contact portion to which an electrode for resistance welding is contacted, and a metal exposed portion constituting the metal exposed portion group A pressure-contact portion in which the portions are pressed against each other, and the pressure-contact portion is provided at a position where at least a part of the pressure-contact portion does not overlap the contact portion, and at least the contact portion of the pressure-contact portion It ’s the same as the club It is summarized as being welded to the electrode terminal in the portion.

これによれば、金属露出部同士が圧接された圧接部では、該圧接部以外の部分と比較して電気抵抗が低いことから、接触部に接触された抵抗溶接用の電極から供給される電流は、少なくとも一部が接触部とは重ならない位置に設けられる圧接部を優先的に流れ、その結果として圧接部において抵抗溶接が行われる。したがって、抵抗溶接用の電極を接触させる接触部から離間した位置において、金属露出部群と電極端子とを抵抗溶接し、電気的に接続できる。   According to this, since the electric resistance is lower in the press-contact portion where the metal exposed portions are press-contacted with each other than the portion other than the press-contact portion, the current supplied from the resistance welding electrode in contact with the contact portion Flows preferentially through the pressure contact portion provided at a position where at least a portion does not overlap the contact portion, and as a result, resistance welding is performed at the pressure contact portion. Therefore, the metal exposed portion group and the electrode terminal can be resistance-welded and electrically connected at a position away from the contact portion with which the electrode for resistance welding is brought into contact.

請求項2に記載の発明は、請求項1に記載の蓄電装置において、前記圧接部は、孔の内周面に沿って設けられる。これによれば、例えばパンチングなどによって金属露出部群を孔状に押し切ることにより、孔の内周面に沿って簡便に圧接部を設けることができる。   According to a second aspect of the present invention, in the power storage device according to the first aspect, the press contact portion is provided along an inner peripheral surface of the hole. According to this, a press-contact part can be simply provided along the inner peripheral surface of a hole by pushing a metal exposure part group into a hole shape by punching etc., for example.

請求項3に記載の発明は、請求項1に記載の蓄電装置において、前記圧接部は、前記金属露出部群の縁部から前記接触部に向かって延びる切込み部に沿って設けられる。これによれば、縁部からの切込み距離を調節することで、抵抗溶接を行うときの電気抵抗、即ち溶接の強さを調節できる。   According to a third aspect of the present invention, in the power storage device according to the first aspect, the press contact portion is provided along a cut portion extending from an edge portion of the metal exposed portion group toward the contact portion. According to this, the electrical resistance when resistance welding is performed, that is, the strength of welding, can be adjusted by adjusting the cutting distance from the edge.

請求項4に記載の発明は、請求項1〜3のいずれか1項に記載の蓄電装置において、前記圧接部は、該圧接部の全体が前記接触部と重ならない位置に設けられている。これによれば、接触部から離間した位置であっても抵抗溶接により金属露出部群と電極端子とを溶接できる。   According to a fourth aspect of the present invention, in the power storage device according to any one of the first to third aspects, the press-contact portion is provided at a position where the entire press-contact portion does not overlap the contact portion. According to this, even if it is a position away from the contact part, the metal exposed part group and the electrode terminal can be welded by resistance welding.

請求項5に記載の発明は、請求項1〜4のいずれか1項に記載の蓄電装置において、前記蓄電装置は二次電池である。これによれば、二次電池において、抵抗溶接用の電極を接触させる接触部から離間した位置において、電極の金属露出部が層状に重なる金属露出部群と電極端子とを溶接できる。   According to a fifth aspect of the present invention, in the power storage device according to any one of the first to fourth aspects, the power storage device is a secondary battery. According to this, in the secondary battery, the metal exposed portion group in which the metal exposed portion of the electrode overlaps in layers can be welded at a position away from the contact portion where the resistance welding electrode is brought into contact.

請求項6に記載の発明は、金属箔の表面に活物質層を形成した電極と、前記電極間を絶縁するセパレータとを有し前記電極が前記セパレータを間に介在させた状態で層状に重なる電極組立体と、前記電極組立体を収容するとともに電極端子が固定されるケースと、を備え、前記電極組立体は、前記電極のうち金属箔が露出する金属露出部が層状に重なる金属露出部群を有する蓄電装置の製造方法であって、前記金属露出部群を構成する金属露出部同士を接触させる接触工程と、前記金属露出部同士が接触された箇所における少なくとも一部が重ならない位置である接触部に抵抗溶接用の電極を接触させた状態で通電し、前記金属露出部同士が接触された箇所のうち少なくとも前記接触部とは重ならない部分において前記電極端子と溶接する溶接工程と、を含むことを要旨とする。   The invention according to claim 6 has an electrode in which an active material layer is formed on the surface of a metal foil, and a separator that insulates between the electrodes, and the electrode overlaps in layers with the separator interposed therebetween. An electrode assembly, and a case in which the electrode assembly is accommodated and an electrode terminal is fixed. The electrode assembly includes a metal exposed portion in which a metal exposed portion of the electrode where the metal foil is exposed overlaps in a layered manner A method of manufacturing a power storage device having a group, wherein a contact step of contacting metal exposed portions constituting the metal exposed portion group and a position where at least a part of the metal exposed portions are in contact with each other are not overlapped. A current is applied in a state where an electrode for resistance welding is in contact with a certain contact portion, and at least a portion where the exposed metal portions are in contact with each other does not overlap with the contact portion. And summarized in that comprises a step.

これによれば、金属露出部同士が接触された箇所では、該接触された箇所以外の部分と比較して電気抵抗が低いことから、接触部に接触された抵抗溶接用の電極から供給される電流は、少なくとも一部が接触部と重ならない金属露出部同士が接触された箇所を優先的に流れ、その結果として金属露出部同士が接触された箇所において抵抗溶接が行われる。したがって、抵抗溶接用の電極を接触させる接触部から離間した位置において、金属露出部群と電極端子とを抵抗溶接し、電気的に接続できる。   According to this, since the electrical resistance is lower in the portion where the metal exposed portions are in contact with each other than in the portion other than the contacted portion, it is supplied from the resistance welding electrode in contact with the contact portion. The current flows preferentially at a location where the exposed metal portions where at least a portion does not overlap the contact portion are in contact with each other, and as a result, resistance welding is performed at the location where the exposed metal portions are in contact with each other. Therefore, the metal exposed portion group and the electrode terminal can be resistance-welded and electrically connected at a position away from the contact portion with which the electrode for resistance welding is brought into contact.

本発明によれば、抵抗溶接用の電極を接触させる接触部から離間した位置において、電極の金属露出部が層状に重なる金属露出部群と電極端子とを溶接できる。   ADVANTAGE OF THE INVENTION According to this invention, the metal exposure part group and electrode terminal which the metal exposure part of an electrode overlaps in layers can be welded in the position spaced apart from the contact part which contacts the electrode for resistance welding.

リチウムイオン二次電池を模式的に示す断面図。Sectional drawing which shows a lithium ion secondary battery typically. 電極組立体を模式的に示す斜視図。The perspective view which shows an electrode assembly typically. 図1に示す1−1線断面図。FIG. 1 is a sectional view taken along line 1-1 shown in FIG. (a)は、別の実施形態における正極集電タブ群を拡大して模式的に示す正面図、(b)は、(a)に示す2−2線断面図。(A) is the front view which expands and shows typically the positive electrode current collection tab group in another embodiment, (b) is 2-2 sectional view taken on the line shown to (a). (a)は、別の実施形態における正極集電タブ群を拡大して模式的に示す正面図、(b)は、(a)に示す3−3線断面図。(A) is the front view which expands and shows typically the positive electrode current collection tab group in another embodiment, (b) is 3-3 sectional drawing shown to (a).

以下、本発明を具体化した一実施形態を図1〜図4にしたがって説明する。
図1に示すように、車両に搭載される蓄電装置としてのリチウムイオン二次電池(以下「二次電池」と示す)10は、ケース11に電極組立体12が収容されている。ケース11は、電極組立体12を収容する有底矩形箱状の本体部材11aと、該本体部材11aの開口部を閉塞する矩形板状の蓋部材11bとから構成されている。本体部材11a、及び蓋部材11bは、例えばステンレスやアルミニウムなどの金属製である。
Hereinafter, an embodiment embodying the present invention will be described with reference to FIGS.
As shown in FIG. 1, in a lithium ion secondary battery (hereinafter referred to as “secondary battery”) 10 as a power storage device mounted on a vehicle, an electrode assembly 12 is accommodated in a case 11. The case 11 includes a bottomed rectangular box-shaped main body member 11a that houses the electrode assembly 12, and a rectangular plate-shaped lid member 11b that closes an opening of the main body member 11a. The main body member 11a and the lid member 11b are made of a metal such as stainless steel or aluminum.

ケース11内には、電解質として非水電解液13が充填されている。また、ケース11を形成する壁の1つとなる蓋部材11bには、正極端子15及び負極端子16が固定され、外部に向かって突出されている。また、電極組立体12は、絶縁性樹脂から形成された絶縁シート14に覆われた状態でケース11に収容されている。   The case 11 is filled with a nonaqueous electrolytic solution 13 as an electrolyte. A positive electrode terminal 15 and a negative electrode terminal 16 are fixed to the lid member 11b which is one of the walls forming the case 11, and protrudes outward. The electrode assembly 12 is accommodated in the case 11 in a state of being covered with an insulating sheet 14 formed of an insulating resin.

図2に示すように、電極組立体12は、電極(正極)としての正極シート18と、正極シート18とは極性が異なる電極(負極)としての負極シート19と、正極シート18と負極シート19との間を絶縁する矩形シート状のセパレータ20とを有する。そして、電極組立体12は、複数の正極シート18、及び複数の負極シート19を、間にセパレータ20を介在させた状態で交互に層状に重なるように積層された積層型の電極組立体である。以下の説明で「積層方向」という場合には、電極組立体12における正極シート18及び負極シート19の積層方向を意味する。   As shown in FIG. 2, the electrode assembly 12 includes a positive electrode sheet 18 as an electrode (positive electrode), a negative electrode sheet 19 as an electrode (negative electrode) having a polarity different from that of the positive electrode sheet 18, and a positive electrode sheet 18 and a negative electrode sheet 19. And a rectangular sheet-like separator 20 that insulates between the two. The electrode assembly 12 is a stacked electrode assembly in which a plurality of positive electrode sheets 18 and a plurality of negative electrode sheets 19 are stacked so as to be alternately layered with a separator 20 interposed therebetween. . In the following description, the “stacking direction” means the stacking direction of the positive electrode sheet 18 and the negative electrode sheet 19 in the electrode assembly 12.

正極シート18は、正極金属箔21と、その両面に正極活物質を含む活物質合剤を塗布し、乾燥させて形成された正極活物質層22とを有する。本実施形態の正極金属箔21は、アルミニウム、又はアルミニウム合金から形成された金属箔である。正極活物質層22が形成されていない部分の正極金属箔21は、正極金属箔21が露出する金属露出部としての非塗工部23を構成する。また、正極シート18の縁部18aには、正極集電タブ24が突出している。正極集電タブ24は、非塗工部23を構成する正極金属箔21の一部である。   The positive electrode sheet 18 includes a positive electrode metal foil 21 and a positive electrode active material layer 22 formed by applying and drying an active material mixture containing a positive electrode active material on both surfaces thereof. The positive electrode metal foil 21 of this embodiment is a metal foil formed from aluminum or an aluminum alloy. A portion of the positive electrode metal foil 21 where the positive electrode active material layer 22 is not formed constitutes a non-coated portion 23 as a metal exposed portion where the positive electrode metal foil 21 is exposed. Further, a positive electrode current collecting tab 24 protrudes from the edge portion 18 a of the positive electrode sheet 18. The positive electrode current collecting tab 24 is a part of the positive electrode metal foil 21 constituting the non-coated portion 23.

また、負極シート19は、負極金属箔25と、その両面に負極活物質を含む活物質合剤を塗布し、乾燥させて形成された負極活物質層26とを有する。本実施形態の負極金属箔25は、銅から形成された金属箔である。また、負極活物質層26が形成されていない部分の負極金属箔25は、負極金属箔25が露出する非塗工部27を構成する。また、負極シート19の縁部19aには、負極集電タブ28が突出している。負極集電タブ28は、非塗工部27を構成する負極金属箔25の一部である。   Moreover, the negative electrode sheet 19 has the negative electrode metal foil 25, and the negative electrode active material layer 26 formed by apply | coating the active material mixture containing a negative electrode active material to both surfaces, and making it dry. The negative electrode metal foil 25 of the present embodiment is a metal foil formed from copper. The portion of the negative electrode metal foil 25 where the negative electrode active material layer 26 is not formed constitutes an uncoated portion 27 where the negative electrode metal foil 25 is exposed. A negative electrode current collecting tab 28 protrudes from the edge 19 a of the negative electrode sheet 19. The negative electrode current collecting tab 28 is a part of the negative electrode metal foil 25 constituting the non-coated portion 27.

そして、図1に示すように、電極組立体12の縁部12aには、複数の正極集電タブ24が層状に重なる金属露出部群としての正極集電タブ群24aが突設される。正極集電タブ群24aは、正極集電タブ群24aの突出方向に沿って延びる矩形平板状の正極導電部材30の一端と抵抗溶接により接合され、電気的に接続されている。正極導電部材30は、アルミニウム、又はアルミニウム合金から形成されている。   As shown in FIG. 1, a positive electrode current collecting tab group 24 a as a metal exposed portion group in which a plurality of positive electrode current collecting tabs 24 are layered is projected from the edge 12 a of the electrode assembly 12. The positive electrode current collecting tab group 24a is joined and electrically connected to one end of a rectangular plate-like positive electrode conductive member 30 extending along the protruding direction of the positive electrode current collecting tab group 24a by resistance welding. The positive electrode conductive member 30 is made of aluminum or an aluminum alloy.

ここで、抵抗溶接は、図3に示すように、正極集電タブ群24aと正極導電部材30とを、積層方向から抵抗溶接用の一対の電極(以下「溶接用電極」と示す)32で挟持した状態のまま、加圧しながら溶接用電極32の間で通電することにより該通電部分を発熱させ、各正極集電タブ24と正極導電部材30とを溶融させて接合する溶接方法である。なお、図3では、説明の便宜のために6枚の正極集電タブ24を示しているが、実際にはさらに多数の正極集電タブ24が層状に重なっている。   Here, in resistance welding, as shown in FIG. 3, the positive electrode current collecting tab group 24 a and the positive electrode conductive member 30 are paired with a pair of electrodes for resistance welding (hereinafter referred to as “welding electrodes”) 32 from the stacking direction. In this welding method, the energized portion is heated by energizing between the welding electrodes 32 while being pressed while being held, and the positive electrode current collecting tab 24 and the positive electrode conductive member 30 are melted and joined. In FIG. 3, six positive current collecting tabs 24 are shown for convenience of explanation, but in reality, a larger number of positive current collecting tabs 24 are layered.

そして、図1に示すように、正極導電部材30の他端は、正極端子15と電気的に接続されるとともに、正極導電部材30は、ケース11(蓋部材11b)に固定されている。本実施形態では、正極端子15と正極導電部材30により電極端子が構成されている。   As shown in FIG. 1, the other end of the positive electrode conductive member 30 is electrically connected to the positive electrode terminal 15, and the positive electrode conductive member 30 is fixed to the case 11 (lid member 11b). In the present embodiment, the positive electrode terminal 15 and the positive electrode conductive member 30 constitute an electrode terminal.

また、電極組立体12の縁部12aには、正極集電タブ群24aとは異なる部分に、複数の負極集電タブ28が層状に重なった負極集電タブ群28aが突設されている。負極集電タブ群28aは、負極集電タブ群28aの突出方向に沿って延びる矩形平板状の負極導電部材31の一端と抵抗溶接により接合され、電気的に接続されている。負極導電部材31の他端は、負極端子16と電気的に接続されるとともに、ケース11(蓋部材11b)に固定されている。   In addition, a negative electrode current collecting tab group 28a in which a plurality of negative electrode current collecting tabs 28 are stacked in a layered manner at a portion different from the positive electrode current collecting tab group 24a is protruded from the edge 12a of the electrode assembly 12. The negative electrode current collecting tab group 28a is joined and electrically connected to one end of a rectangular plate-like negative electrode conductive member 31 extending along the protruding direction of the negative electrode current collecting tab group 28a by resistance welding. The other end of the negative electrode conductive member 31 is electrically connected to the negative electrode terminal 16 and is fixed to the case 11 (lid member 11b).

次に、正極集電タブ群24aと正極導電部材30との溶接(接合)構造について、図1及び図3にしたがってさらに詳しく説明する。
図1及び図3に示すように、積層方向から見た場合に、正極導電部材30の一端側と、正極集電タブ群24aとは重なっているとともに、正極集電タブ群24aと正極導電部材30とが重なる部分には、抵抗溶接を行うときに溶接用電極32が接触された痕跡となる接触部33が設けられている。本実施形態では、丸棒状の溶接用電極32が用いられることから、接触部33は積層方向から見て円形の凹部となる。なお、接触部33では、正極集電タブ群24aと正極導電部材30とが溶接されていない。
Next, the welding (joining) structure between the positive electrode current collecting tab group 24a and the positive electrode conductive member 30 will be described in more detail with reference to FIGS.
As shown in FIGS. 1 and 3, when viewed from the stacking direction, one end side of the positive electrode conductive member 30 and the positive electrode current collecting tab group 24 a overlap each other, and the positive electrode current collecting tab group 24 a and the positive electrode conductive member are overlapped. A contact portion 33 is provided at a portion overlapping with 30 to be a trace of contact with the welding electrode 32 when resistance welding is performed. In this embodiment, since the round bar-shaped welding electrode 32 is used, the contact portion 33 is a circular recess as viewed from the stacking direction. In the contact portion 33, the positive electrode current collecting tab group 24a and the positive electrode conductive member 30 are not welded.

また、積層方向から見て、正極集電タブ群24aと正極導電部材30とが重なる部分において、接触部33よりも蓋部材11b(正極端子15)側には、正極集電タブ群24aと正極導電部材30とを重ね合わせた状態で、正極集電タブ群24a側から、先端が鋭利な円筒状の冶具Zにより押圧して形成した孔としての孔部34が設けられている。   Further, when viewed from the stacking direction, in the portion where the positive electrode current collecting tab group 24a and the positive electrode conductive member 30 are overlapped, the positive electrode current collecting tab group 24a and the positive electrode are closer to the lid member 11b (positive electrode terminal 15) side than the contact portion 33. A hole 34 is formed as a hole formed by pressing with a cylindrical jig Z having a sharp tip from the positive electrode current collecting tab group 24a side in a state where the conductive member 30 is overlaid.

この孔部34の内周面、及び該内周面に沿って近接する部分は、各正極集電タブ24が冶具Zにより押圧され、円柱状に押し切られることにより、各正極集電タブ24、及び正極導電部材30が相互に積層方向に圧接(接触)された圧接部35となる(図中に墨色に着色して示す)。このように、圧接部35は、その全体が接触部33と重ならない位置に設けられる。   The inner peripheral surface of the hole 34 and a portion adjacent to the inner peripheral surface are each pressed by the jig Z and pressed into a columnar shape by the positive electrode current collecting tabs 24. And the positive electrode conductive member 30 becomes a pressure contact portion 35 that is pressure-contacted (contacted) with each other in the stacking direction (colored in black in the drawing). As described above, the pressure contact portion 35 is provided at a position where the entire portion does not overlap the contact portion 33.

そして、圧接部35のうち、孔部34の内周面に沿った部分には、各正極集電タブ24、及び正極導電部材30が相互に溶接され一体化した溶接部36が設けられている。溶接部36は、孔部34の内周面の全体にわたって、積層方向における正極集電タブ群24aの両端に位置する一方の面と、正極導電部材30と対向する他方の面まで延びている。   A portion of the press-contact portion 35 along the inner peripheral surface of the hole 34 is provided with a welded portion 36 in which the positive electrode current collecting tabs 24 and the positive electrode conductive member 30 are welded and integrated with each other. . The weld 36 extends over the entire inner peripheral surface of the hole 34 to one surface located at both ends of the positive electrode current collecting tab group 24 a in the stacking direction and the other surface facing the positive electrode conductive member 30.

このため、正極集電タブ群24aと正極導電部材30とは、圧接部35のうち孔部34の内周面に沿って設けられた溶接部36によって相互に接合され、電気的に接続されている。このように、圧接部35は、接触部33と重ならない部分において正極導電部材30と溶接されている。   Therefore, the positive electrode current collecting tab group 24a and the positive electrode conductive member 30 are joined and electrically connected to each other by the welded portion 36 provided along the inner peripheral surface of the hole portion 34 in the press contact portion 35. Yes. As described above, the pressure contact portion 35 is welded to the positive electrode conductive member 30 at a portion that does not overlap the contact portion 33.

なお、図1に示すように、積層方向から見て、負極導電部材31の一端側と、負極集電タブ群28aとは重なっているとともに、負極集電タブ群28aと負極導電部材31とが重なる部分には、抵抗溶接を行うときに溶接用電極32が接触された痕跡となる接触部33が設けられている。なお、負極集電タブ群28aにおける接触部33では、各負極集電タブ群28a及び負極導電部材31が積層方向に溶接され、電気的に接続されている。   As shown in FIG. 1, when viewed from the stacking direction, one end side of the negative electrode conductive member 31 and the negative electrode current collecting tab group 28a are overlapped, and the negative electrode current collecting tab group 28a and the negative electrode conductive member 31 are The overlapping portion is provided with a contact portion 33 that becomes a trace of contact with the welding electrode 32 when resistance welding is performed. In addition, in the contact part 33 in the negative electrode current collection tab group 28a, each negative electrode current collection tab group 28a and the negative electrode electrically-conductive member 31 are welded in the lamination direction, and are electrically connected.

次に、上記のように構成した二次電池10の作用について説明する。
一般に、正極集電タブ群24aを構成する各正極集電タブ24の表面には、酸化皮膜(不動態膜)が形成されていることや、個々の正極集電タブ24が僅かに撓んでいることに起因して、積層方向における正極集電タブ群24aの電気抵抗が比較的高くなる。これに対して、各正極集電タブ24や正極導電部材30が互いに圧接(接触)された圧接部35では、該圧接部35以外の部分と比較して積層方向における電気抵抗が低減される。
Next, the operation of the secondary battery 10 configured as described above will be described.
In general, an oxide film (passive film) is formed on the surface of each positive electrode current collecting tab 24 constituting the positive electrode current collecting tab group 24a, and individual positive electrode current collecting tabs 24 are slightly bent. As a result, the electrical resistance of the positive electrode current collecting tab group 24a in the stacking direction becomes relatively high. On the other hand, the electrical resistance in the stacking direction is reduced in the press contact portions 35 where the positive electrode current collecting tabs 24 and the positive electrode conductive members 30 are press contacted (contacted) with each other as compared with portions other than the press contact portions 35.

このため、接触部33に接触される溶接用電極32から供給される電流は、接触部33から離間していたとしても、圧接部35を優先的に流れるようになる。その結果、圧接部35では、抵抗溶接が行われ溶接部36が設けられる。   For this reason, even if the current supplied from the welding electrode 32 that is in contact with the contact portion 33 is separated from the contact portion 33, the current flows preferentially through the pressure contact portion 35. As a result, resistance welding is performed at the press contact portion 35 to provide a weld portion 36.

なお、本実施形態では、円筒状の冶具Zで押し切って孔部34を設けていることから、圧接部35のうち孔部34に近接する部分であるほど、正極集電タブ24や正極導電部材30同士が強く圧接され、電気抵抗が低くなっている。特に孔部34の内周面では、正極金属箔21同士が酸化皮膜を介することなく新生面同士で接合(接触)されることで、さらに電気抵抗が低減される。このため、本実施系形態では、孔部34の内周面に沿って溶接部36が設けられる。   In the present embodiment, since the hole 34 is provided by being pushed out by the cylindrical jig Z, the closer to the hole 34 in the press contact part 35, the more the positive electrode current collecting tab 24 and the positive electrode conductive member are. 30 are strongly pressed and electric resistance is low. In particular, on the inner peripheral surface of the hole 34, the positive electrode metal foils 21 are joined (contacted) with each other without intervening the oxide film, whereby the electrical resistance is further reduced. For this reason, in the present embodiment, the welded portion 36 is provided along the inner peripheral surface of the hole portion 34.

また、本実施形態では、接触部33と圧接部35との離間距離を調節することで、溶接用電極32の間における電気抵抗を調節できる。即ち、溶接用電極32間の電気抵抗は、接触部33と圧接部35とを近接して設けることで低くできる一方で、接触部33と圧接部35とを離間して設けることで高くできる。したがって、接触部33と圧接部35との離間距離を調節することで、溶接部36の大きさ(溶接強さ)を簡便に調節できる。   In the present embodiment, the electrical resistance between the welding electrodes 32 can be adjusted by adjusting the distance between the contact portion 33 and the pressure contact portion 35. In other words, the electrical resistance between the welding electrodes 32 can be lowered by providing the contact portion 33 and the press contact portion 35 close to each other, and can be increased by providing the contact portion 33 and the press contact portion 35 apart from each other. Therefore, the size (welding strength) of the welded portion 36 can be easily adjusted by adjusting the separation distance between the contact portion 33 and the pressure contact portion 35.

そして、圧接部35は、該圧接部35の全体が接触部33と重ならない位置に設けられている。したがって、接触部33から完全に離間した位置であっても抵抗溶接により正極集電タブ群24aと正極導電部材30とを溶接できる。   The press contact portion 35 is provided at a position where the entire press contact portion 35 does not overlap the contact portion 33. Therefore, the positive electrode current collecting tab group 24a and the positive electrode conductive member 30 can be welded by resistance welding even at a position completely separated from the contact portion 33.

次に、二次電池10の製造方法について、正極集電タブ群24aと正極導電部材30との溶接方法を中心に説明する。
まず、正極シート18と負極シート19とを間にセパレータ20を介在させた状態で交互に積層し、縁部12aから正極集電タブ群24a及び負極集電タブ群28aが突出する電極組立体12を形成する。
Next, a method for manufacturing the secondary battery 10 will be described focusing on a method for welding the positive electrode current collecting tab group 24 a and the positive electrode conductive member 30.
First, the positive electrode sheet 18 and the negative electrode sheet 19 are alternately laminated with the separator 20 interposed therebetween, and the electrode assembly 12 in which the positive electrode current collecting tab group 24a and the negative electrode current collecting tab group 28a protrude from the edge 12a. Form.

次に、図3に示すように、正極集電タブ群24aと正極導電部材30とを積層方向に重ね合わせる。そして、溶接用電極32を接触させる接触部33から蓋部材11b側へ離間した位置において、正極集電タブ群24a側から冶具Zの先端を押し付けることで、孔部34を形成しつつ、正極集電タブ24及び正極導電部材30同士を圧接して圧接部35を設ける(圧接工程)。このとき、圧接部35のうち特に孔部34の内周面に沿った部分では、各正極集電タブ24の表面を覆う酸化皮膜が冶具Zによって押し切られることで破れ、新生面同士が接合された状態となる。即ち圧接工程は、各正極集電タブ24同士を、酸化皮膜を介することなく新生面同士で接触させる接触工程として把握できる。   Next, as shown in FIG. 3, the positive electrode current collecting tab group 24 a and the positive electrode conductive member 30 are overlapped in the stacking direction. Then, at the position separated from the contact portion 33 that contacts the welding electrode 32 toward the lid member 11b, the tip of the jig Z is pressed from the positive electrode current collecting tab group 24a side, thereby forming the hole 34 and the positive electrode collector. The electric tab 24 and the positive electrode conductive member 30 are pressed against each other to provide a pressure contact portion 35 (pressure contact process). At this time, the oxide film covering the surface of each positive electrode current collecting tab 24 was broken by the jig Z at the portion along the inner peripheral surface of the hole 34 in the press contact portion 35, and the new surfaces were joined to each other. It becomes a state. That is, the pressure contact process can be grasped as a contact process in which the positive electrode current collecting tabs 24 are brought into contact with each other on the new surfaces without interposing an oxide film.

そして、接触部33において、積層方向から正極集電タブ群24a及び正極導電部材30に溶接用電極32を接触させるとともに、溶接用電極32の間で通電して正極集電タブ群24aと正極導電部材30とを溶接する(溶接工程)。このとき、溶接用電極32から供給される電流は、溶接用電極32の間において正極集電タブ群24aを積層方向へ直線的に流れず、より電気抵抗が低い圧接部35へ迂回して流れる。   Then, in the contact portion 33, the positive electrode current collecting tab group 24 a and the positive electrode conductive member 30 are brought into contact with the positive electrode current collecting tab group 24 a and the positive electrode conductive member 30 from the stacking direction. The member 30 is welded (welding process). At this time, the current supplied from the welding electrode 32 does not flow linearly in the stacking direction in the positive electrode current collecting tab group 24a between the welding electrodes 32, but flows around the pressure contact portion 35 having a lower electrical resistance. .

このため、本実施形態では、圧接部35が発熱して溶融することにより孔部34の内周面に沿って溶接部36が設けられ、正極集電タブ群24aと正極導電部材30とが電気的に接続される。したがって、蓋部材11bから離間した位置において、溶接用電極32を正極集電タブ群24a及び正極導電部材30に接触させることで、溶接用電極32を接触させる作業を行い易くできるともに、蓋部材11b側に近接させた位置で正極集電タブ群24aと正極導電部材30とを溶接できる。   For this reason, in this embodiment, the welding part 36 is provided along the inner peripheral surface of the hole 34 by the pressure contact part 35 generating heat and melting, and the positive electrode current collecting tab group 24a and the positive electrode conductive member 30 are electrically connected. Connected. Therefore, by bringing the welding electrode 32 into contact with the positive electrode current collecting tab group 24a and the positive electrode conductive member 30 at a position apart from the lid member 11b, the operation of bringing the welding electrode 32 into contact can be facilitated, and the lid member 11b. The positive electrode current collecting tab group 24a and the positive electrode conductive member 30 can be welded at a position close to the side.

なお、負極集電タブ群28aと負極導電部材31とは、負極集電タブ群28aに圧接部35(孔部34)が設けられていないことから、接触される溶接用電極32間を積層方向に沿って直線的に結ぶように延びる溶接部が形成され、相互に溶接される。   The negative electrode current collecting tab group 28a and the negative electrode conductive member 31 are not provided with the press contact portion 35 (hole portion 34) in the negative electrode current collecting tab group 28a. Welds extending so as to be linearly connected to each other are formed and welded to each other.

したがって、本実施形態によれば、以下のような効果を得ることができる。
(1)正極集電タブ群24aには、接触部33と重ならない位置に圧接部35が設けられているとともに、圧接部は、該圧接部35のうち接触部33とは重ならない部分において正極導電部材30と溶接されている。各正極集電タブ24が圧接された圧接部35では、該圧接部35以外の部分と比較して電気抵抗が低いことから、接触部33に接触された溶接用電極32から供給される電流は圧接部35を優先的に流れ、その結果として圧接部35において抵抗溶接が行われる。したがって、接触部33から離間した位置において、正極集電タブ群24aと正極導電部材30(正極端子15)とを抵抗溶接し、電気的に接続できる。
Therefore, according to the present embodiment, the following effects can be obtained.
(1) The positive electrode current collecting tab group 24 a is provided with a press contact portion 35 at a position not overlapping the contact portion 33, and the press contact portion is a positive electrode in a portion of the press contact portion 35 that does not overlap the contact portion 33. The conductive member 30 is welded. In the press contact portion 35 where each positive electrode current collecting tab 24 is press-contacted, since the electric resistance is lower than the portion other than the press contact portion 35, the current supplied from the welding electrode 32 in contact with the contact portion 33 is As a result, resistance welding is performed in the pressure contact portion 35. Therefore, the positive electrode current collecting tab group 24a and the positive electrode conductive member 30 (positive electrode terminal 15) can be resistance-welded and electrically connected at a position away from the contact portion 33.

(2)このため、接触部33と溶接部36(圧接部35)とを異なる部分に設定できることから、作業性が低下することを抑制しつつ、正極集電タブ群24aと正極導電部材30とを所望の部分において抵抗溶接できる。   (2) For this reason, since the contact part 33 and the welding part 36 (press-contact part 35) can be set in a different part, while suppressing workability fall, the positive electrode current collection tab group 24a, the positive electrode electrically-conductive member 30, and Can be resistance welded at a desired portion.

(3)接触部33と圧接部35との離間距離を調節することで、溶接部36の大きさ、即ち溶接強さを簡便に調節できる。
(4)圧接部35は、圧接部35の全体が接触部33と重ならない位置に設けられている。このため、接触部33から離間した位置であっても抵抗溶接により正極集電タブ群24aと正極導電部材30とを溶接できる。
(3) By adjusting the separation distance between the contact portion 33 and the pressure contact portion 35, the size of the welded portion 36, that is, the welding strength can be easily adjusted.
(4) The press contact portion 35 is provided at a position where the entire press contact portion 35 does not overlap the contact portion 33. For this reason, even if it is the position away from the contact part 33, the positive electrode current collection tab group 24a and the positive electrode electrically-conductive member 30 can be welded by resistance welding.

(5)二次電池10において、溶接用電極32を接触させる接触部33から離間した位置において正極集電タブ群24aと正極導電部材30(正極端子15)とを溶接できる。
(6)各正極集電タブ24同士を接触させるとともに、正極集電タブ24同士が接触する箇所(圧接部35)と離間した部分である接触部33に溶接用電極32を接触させた状態で通電し、正極集電タブ群24aと正極導電部材30とを溶接している。正極集電タブ24同士が接触する箇所では、該接触する箇所以外の部分と比較して電気抵抗が低いことから、溶接用電極32から供給される電流は、正極集電タブ24同士が接触する箇所を優先的に流れ、その結果として正極集電タブ24同士が接触する箇所において抵抗溶接が行われる。したがって、接触部33から離間した位置において、正極集電タブ群24aと正極導電部材30とを抵抗溶接し、電気的に接続できる。
(5) In the secondary battery 10, the positive electrode current collecting tab group 24 a and the positive electrode conductive member 30 (positive electrode terminal 15) can be welded at a position away from the contact portion 33 with which the welding electrode 32 is brought into contact.
(6) In a state where the positive electrode current collecting tabs 24 are brought into contact with each other, and the welding electrode 32 is brought into contact with a contact portion 33 which is a portion separated from a place where the positive electrode current collecting tabs 24 are in contact with each other (pressure contact portion 35). Energization is performed, and the positive electrode current collecting tab group 24a and the positive electrode conductive member 30 are welded. The electrical current supplied from the welding electrode 32 is in contact with the positive current collecting tabs 24 because the electrical resistance is lower at the locations where the positive current collecting tabs 24 are in contact with each other. As a result, resistance welding is performed at a location where the positive electrode current collecting tabs 24 are in contact with each other. Therefore, the positive electrode current collecting tab group 24a and the positive electrode conductive member 30 can be resistance-welded and electrically connected at a position away from the contact portion 33.

(7)そして、接触部33を蓋部材11bから離間した位置に設定したとしても、蓋部材11bに近接させた位置に設けた圧接部35で抵抗溶接できる。即ち、溶接工程において、抵抗溶接の作業性が低下することを抑制しつつ、所望の部分で正極集電タブ群24aと正極導電部材30とを溶接できる。   (7) Even if the contact portion 33 is set at a position separated from the lid member 11b, resistance welding can be performed by the press contact portion 35 provided at a position close to the lid member 11b. That is, in the welding process, the positive electrode current collecting tab group 24a and the positive electrode conductive member 30 can be welded at a desired portion while suppressing a decrease in resistance welding workability.

実施形態は前記に限定されるものではなく、例えば、次のように具体化してもよい。
○ 孔部34をパンチング加工により形成してもよい。この場合、孔部34は、正極集電タブ群24aと正極導電部材30とを貫通して設けられることから、孔部34の内周面に沿って、各正極集電タブ24と正極導電部材30とが確実に圧接(接触)され、電気抵抗を低減して容易に溶接できる。
The embodiment is not limited to the above, and may be embodied as follows, for example.
○ The hole 34 may be formed by punching. In this case, since the hole 34 is provided through the positive electrode current collecting tab group 24 a and the positive electrode conductive member 30, the positive electrode current collecting tab 24 and the positive electrode conductive member are arranged along the inner peripheral surface of the hole 34. 30 is reliably pressure-contacted (contacted), electric resistance is reduced, and it can weld easily.

○ 図4に示すように、圧接部35は、正極集電タブ群24aの縁部から接触部33に向かって延びる切込み部40に沿って設けられていてもよい。この場合には、正極集電タブ群24aと正極導電部材30とを重ね合わせた状態で、正極集電タブ群24a側からカッタで押し切って切込み部40を形成することで、該切込み部40の切断面に沿って、各正極集電タブ24、及び正極導電部材30を積層方向に圧接(接触)させた圧接部35を設けることができる。このように構成しても、圧接部35のうち、切込み部40の切断面に沿った部分に、各正極集電タブ24、及び正極導電部材30が相互に溶接された溶接部36を設けることができる。これによれば、正極集電タブ群24aに対して簡便に圧接部35を設けることができるとともに、縁部からの切込み距離を調節することで、抵抗溶接を行うときの電気抵抗、即ち溶接の強さを調節できる。   As shown in FIG. 4, the press contact portion 35 may be provided along a cut portion 40 extending from the edge portion of the positive electrode current collecting tab group 24 a toward the contact portion 33. In this case, in a state where the positive electrode current collecting tab group 24a and the positive electrode conductive member 30 are overlapped, the cut portion 40 is formed by pressing the positive current collector tab group 24a with a cutter from the side of the positive current collector tab group 24a. Along each cut surface, it is possible to provide a pressure contact portion 35 in which each positive electrode current collecting tab 24 and the positive electrode conductive member 30 are pressed (contacted) in the stacking direction. Even if comprised in this way, the welding part 36 to which each positive electrode current collection tab 24 and the positive electrode electrically-conductive member 30 were mutually welded is provided in the part along the cut surface of the notch part 40 among the press-contact parts 35. Can do. According to this, while being able to provide the press-contact part 35 simply with respect to the positive electrode current collection tab group 24a, adjusting the notch distance from an edge part, the electrical resistance at the time of performing resistance welding, ie, welding You can adjust the strength.

○ 図4に示すように、圧接部35は一部が接触部33と重なっていてもよい。即ち、圧接部35は、該圧接部35のうち少なくとも接触部33とは重ならない部分において正極端子15と溶接されておればよい。   As shown in FIG. 4, the pressure contact portion 35 may partially overlap the contact portion 33. That is, the press contact portion 35 may be welded to the positive electrode terminal 15 at least in a portion of the press contact portion 35 that does not overlap the contact portion 33.

○ 図5に示すように、例えば先鋭な冶具を押し当てることで、孔部34や切込み部40を設けることなく各正極集電タブ24及び正極導電部材30を積層方向に圧接(接触)させ、圧接部35を設けてもよい。   ○ As shown in FIG. 5, for example, by pressing a sharp jig, the positive electrode current collecting tabs 24 and the positive electrode conductive members 30 are pressed (contacted) in the stacking direction without providing the holes 34 and the notches 40, A pressure contact portion 35 may be provided.

○ 圧接部35は、正極集電タブ群24aの縁部に沿って設けられていてもよい。この場合、正極集電タブ群24aの縁部をカッタなどで押し切ることにより、該切断面に沿って圧接部35を設けることができる。   (Circle) the press-contact part 35 may be provided along the edge of the positive electrode current collection tab group 24a. In this case, the press contact portion 35 can be provided along the cut surface by pressing the edge of the positive electrode current collecting tab group 24a with a cutter or the like.

○ 圧接部35は、針状の冶具で正極集電タブ群24aを貫通させて形成してもよい。
○ 圧接部35では、少なくとも正極集電タブ24同士が圧接(接触)されておればよく、正極集電タブ群24aと正極導電部材30とが圧接されていなくてもよい。
The press contact portion 35 may be formed by penetrating the positive electrode current collecting tab group 24a with a needle-like jig.
In the press contact portion 35, it is sufficient that at least the positive electrode current collecting tabs 24 are pressed (contacted) with each other, and the positive electrode current collecting tab group 24a and the positive electrode conductive member 30 do not have to be pressed.

○ 圧接部35の全体において各正極集電タブ24及び正極導電部材30が溶接されていてもよい。
○ 負極集電タブ群28aに圧接部35を設け、該圧接部35と少なくとも一部が重ならない接触部33に溶接用電極32を接触させて抵抗溶接をしてもよい。
(Circle) each positive electrode current collection tab 24 and the positive electrode electrically-conductive member 30 may be welded in the whole press-contact part 35. FIG.
A pressure welding portion 35 may be provided on the negative electrode current collecting tab group 28a, and resistance welding may be performed by bringing the welding electrode 32 into contact with the contact portion 33 that does not at least partially overlap the pressure welding portion 35.

○ 溶接用電極32は角柱状など異なる形状に変更してもよい。
○ 正極シート18及び負極シート19は帯状の電極であってもよい。この場合、電極組立体12は、正極シート18、及び負極シート19を、間に帯状のセパレータ20を介在させた状態で捲回した捲回型の電極組立体としてもよい。
The welding electrode 32 may be changed to a different shape such as a prismatic shape.
The belt-like electrode may be sufficient as the positive electrode sheet 18 and the negative electrode sheet 19. In this case, the electrode assembly 12 may be a wound electrode assembly in which the positive electrode sheet 18 and the negative electrode sheet 19 are wound with a band-shaped separator 20 interposed therebetween.

○ 正極シート18、及び負極シート19は、片面に活物質合剤を塗布して形成されていてもよい。
○ ニッケル水素二次電池などの二次電池や、リチウムイオンキャパシタなどの蓄電装置に具体化してもよい。
The positive electrode sheet 18 and the negative electrode sheet 19 may be formed by applying an active material mixture on one side.
O You may actualize in secondary batteries, such as a nickel-hydrogen secondary battery, and electrical storage apparatuses, such as a lithium ion capacitor.

○ 車両以外に用いられる蓄電装置に具体化してもよい。   O You may actualize in the electrical storage apparatus used other than a vehicle.

10…リチウムイオン二次電池(二次電池、蓄電装置)、11…ケース、12…電極組立体、15…正極端子(電極端子)、18…正極シート(電極)、20…セパレータ、21…正極金属箔(金属箔)、22…正極活物質層(活物質層)、23…非塗工部(金属露出部)、24…正極集電タブ(金属露出部)、24a…正極集電タブ群(金属露出部群)、30…正極導電部材(電極端子)、32…溶接用電極(抵抗溶接用の電極)、33…接触部、35…圧接部、40…切込み部。   DESCRIPTION OF SYMBOLS 10 ... Lithium ion secondary battery (secondary battery, electrical storage apparatus), 11 ... Case, 12 ... Electrode assembly, 15 ... Positive electrode terminal (electrode terminal), 18 ... Positive electrode sheet (electrode), 20 ... Separator, 21 ... Positive electrode Metal foil (metal foil), 22 ... positive electrode active material layer (active material layer), 23 ... non-coated part (metal exposed part), 24 ... positive electrode current collecting tab (metal exposed part), 24a ... positive electrode current collecting tab group (Metal exposed part group), 30 ... positive electrode conductive member (electrode terminal), 32 ... welding electrode (electrode for resistance welding), 33 ... contact part, 35 ... pressure contact part, 40 ... notch part.

Claims (6)

金属箔の表面に活物質層を形成した電極と、前記電極間を絶縁するセパレータとを有し前記電極が前記セパレータを間に介在させた状態で層状に重なる電極組立体と、前記電極組立体を収容するとともに電極端子が固定されるケースと、を備えた蓄電装置であって、
前記電極組立体は、前記電極のうち金属箔が露出する金属露出部が層状に重なる金属露出部群を有し、
前記金属露出部群には、抵抗溶接用の電極が接触される接触部と、前記金属露出部群を構成する金属露出部同士が互いに圧接された圧接部とが設けられており、
前記圧接部は、該圧接部における少なくとも一部が前記接触部とは重ならない位置に設けられるとともに、該圧接部のうち少なくとも前記接触部とは重ならない部分において前記電極端子と溶接されていることを特徴とする蓄電装置。
An electrode assembly comprising an electrode having an active material layer formed on the surface of a metal foil, and a separator for insulating between the electrodes, wherein the electrode overlaps in layers with the separator interposed therebetween, and the electrode assembly And a case where the electrode terminal is fixed, and a power storage device comprising:
The electrode assembly has a metal exposed portion group in which the metal exposed portions where the metal foil of the electrode is exposed overlap in layers,
The metal exposed portion group is provided with a contact portion to which an electrode for resistance welding is contacted and a pressure contact portion in which the metal exposed portions constituting the metal exposed portion group are pressed against each other,
The pressure contact portion is provided at a position where at least a part of the pressure contact portion does not overlap the contact portion, and is welded to the electrode terminal at a portion of the pressure contact portion that does not overlap at least the contact portion. A power storage device characterized by the above.
前記圧接部は、孔の内周面に沿って設けられる請求項1に記載の蓄電装置。   The power storage device according to claim 1, wherein the press contact portion is provided along an inner peripheral surface of the hole. 前記圧接部は、前記金属露出部群の縁部から前記接触部に向かって延びる切込み部に沿って設けられる請求項1に記載の蓄電装置。   The power storage device according to claim 1, wherein the press-contact portion is provided along a cut portion extending from an edge portion of the metal exposed portion group toward the contact portion. 前記圧接部は、該圧接部の全体が前記接触部と重ならない位置に設けられている請求項1〜3のいずれか1項に記載の蓄電装置。   The power storage device according to claim 1, wherein the press contact portion is provided at a position where the entire press contact portion does not overlap the contact portion. 前記蓄電装置は二次電池である請求項1〜4のいずれか1項に記載の蓄電装置。   The power storage device according to claim 1, wherein the power storage device is a secondary battery. 金属箔の表面に活物質層を形成した電極と、前記電極間を絶縁するセパレータとを有し前記電極が前記セパレータを間に介在させた状態で層状に重なる電極組立体と、前記電極組立体を収容するとともに電極端子が固定されるケースと、を備え、前記電極組立体は、前記電極のうち金属箔が露出する金属露出部が層状に重なる金属露出部群を有する蓄電装置の製造方法であって、
前記金属露出部群を構成する金属露出部同士を接触させる接触工程と、
前記金属露出部同士が接触された箇所における少なくとも一部が重ならない位置である接触部に抵抗溶接用の電極を接触させた状態で通電し、前記金属露出部同士が接触された箇所のうち少なくとも前記接触部とは重ならない部分において前記電極端子と溶接する溶接工程と、を含むことを特徴とする蓄電装置の製造方法。
An electrode assembly comprising an electrode having an active material layer formed on the surface of a metal foil, and a separator for insulating between the electrodes, wherein the electrode overlaps in layers with the separator interposed therebetween, and the electrode assembly And a case where the electrode terminal is fixed, and the electrode assembly is a method of manufacturing a power storage device having a metal exposed portion group in which metal exposed portions where the metal foil of the electrode is exposed overlap in layers. There,
A contact step of contacting the metal exposed portions constituting the metal exposed portion group;
Energization is performed in a state where an electrode for resistance welding is in contact with a contact portion that is a position where at least a part of the portion where the metal exposed portions are in contact with each other, and at least of the portions where the metal exposed portions are in contact with each other And a welding step of welding to the electrode terminal at a portion that does not overlap with the contact portion.
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014203659A (en) * 2013-04-04 2014-10-27 トヨタ自動車株式会社 Method for manufacturing secondary battery
JP2016026827A (en) * 2015-11-09 2016-02-18 京楽産業.株式会社 Game machine
JP2024030406A (en) * 2022-08-24 2024-03-07 プライムプラネットエナジー&ソリューションズ株式会社 Battery cell and its manufacturing method

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014203659A (en) * 2013-04-04 2014-10-27 トヨタ自動車株式会社 Method for manufacturing secondary battery
JP2016026827A (en) * 2015-11-09 2016-02-18 京楽産業.株式会社 Game machine
JP2024030406A (en) * 2022-08-24 2024-03-07 プライムプラネットエナジー&ソリューションズ株式会社 Battery cell and its manufacturing method
JP7546629B2 (en) 2022-08-24 2024-09-06 プライムプラネットエナジー&ソリューションズ株式会社 Battery cell and manufacturing method thereof

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