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JP2013215394A - Dental abutment, and dental resin material - Google Patents

Dental abutment, and dental resin material Download PDF

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JP2013215394A
JP2013215394A JP2012088431A JP2012088431A JP2013215394A JP 2013215394 A JP2013215394 A JP 2013215394A JP 2012088431 A JP2012088431 A JP 2012088431A JP 2012088431 A JP2012088431 A JP 2012088431A JP 2013215394 A JP2013215394 A JP 2013215394A
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dental
abutment
polypropylene
resin material
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Hiroshi Ando
浩史 安藤
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YUNIKKUSU JAPAN KK
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Abstract

PROBLEM TO BE SOLVED: To provide a dental abutment which has less fear for allergy, is easy to be inserted in the root canal while having a proper hardness (elasticity), and by which the breakage or the like of a tooth is hard to occur even during use for a long period of time.SOLUTION: A dental abutment 1 includes: an inserting-fixing section 2 which is inserted in the root canal of a remaining natural tooth and fixed; and a supporting section 3 which is continuously formed from the inserting-fixing section in a manner to protrude to the outside of the root canal from the opening of the root canal, and supports an artificial tooth section. The inserting-fixing section 2 and the supporting section 3 are constituted of an integrally molded article of a resin containing 50 wt.% or more of a polyolefin resin as the major component, and especially of the integrally molded article of a resin of which the major component is a polypropylene containing 50 wt.% or more of a polypropylene.

Description

本発明は歯科用支台および歯科用樹脂材料に関する。   The present invention relates to a dental abutment and a dental resin material.

歯科治療の1つの形態として、例えば、歯の歯冠部が取り除かれた後に、歯根から歯髄をとって根管を空洞にして、支台(コア、core)を築造して、支台築造体あるいは支台歯を形成する治療がある。支台歯、あるいは支台築造体が一体化された歯に対しては、別に人工的に形成した歯冠部(歯冠補綴物)を被せて装着(例えば嵌合、接合、接着など)する。   As one form of dental treatment, for example, after the crown portion of a tooth is removed, the pulp is taken from the root, the root canal is hollowed, and the abutment (core) is built, and the abutment structure is formed. Or there is a treatment that forms an abutment tooth. Abutment tooth or tooth with integrated abutment structure is attached with a artificially formed crown part (crown prosthesis) attached (for example, fitting, joining, bonding, etc.) .

例えば下記特許文献1では、嵌合接着力が弱くなった場合でも、陶材焼付前装冠が支台歯からはずれ難い冠補綴物が提案されている。   For example, Patent Document 1 below proposes a crown prosthesis in which the porcelain pre-baking crown is difficult to be detached from the abutment tooth even when the fitting adhesive force is weak.

特開平6−225890号公報JP-A-6-225890

従来、支台築造体(支台)を構成する材質としては、例えば金属が用いられていた。しかし金属の場合、例えば、金属成分が溶け出して金属アレルギーを引き起こす可能性があった。また金属は弾性を欠いているために、根管の内部形状と必ずしも一致しない支台を根管に挿入しようとしても奥までしっかりと入らず、固定強度が不足し、無理に押し込むと折損することもある。さらに金属の支台の場合、長期に渡る使用で、歯牙(例えば支台以外の部分)が破損(破折)するおそれなどがある。したがって、金属以外で、適切な弾性、例えば天然歯に近い硬さを有する材質で支台を形成することが望ましいと考えられる。   Conventionally, for example, metal has been used as a material constituting the abutment structure (abutment). However, in the case of a metal, for example, the metal component may melt and cause metal allergy. Also, because metal lacks elasticity, even if you try to insert an abutment that does not necessarily match the internal shape of the root canal into the root canal, it does not fit firmly into the back, the fixing strength is insufficient, and it will break if you force it. There is also. Furthermore, in the case of a metal abutment, there is a possibility that a tooth (for example, a portion other than the abutment) may be broken (broken) by long-term use. Therefore, it is considered desirable to form the abutment with a material having an appropriate elasticity other than metal, for example, a hardness close to that of natural teeth.

そこで本発明が解決しようとする課題は、アレルギーの可能性が少なく、天然歯に近い硬さを有して、長期的な使用のもとでも歯牙の破損などを引き起こさない歯科用支台および歯科用樹脂材料を提供することにある。   Therefore, the problem to be solved by the present invention is that a dental abutment and a dentistry that are less likely to be allergic, have a hardness close to that of natural teeth, and do not cause tooth damage under long-term use. It is to provide a resin material.

上記課題を解決するために、本発明に係る歯科用支台は、残存する天然歯の根管に挿入されて固定される挿入固定部と、前記根管の開口からその根管の外側へ突出するように前記挿入固定部から連続して形成されて人工歯部を支持する支持部と、を備え、それら挿入固定部と支持部とがポリオレフィン樹脂を主成分(50重量%以上含有する)とする樹脂の一体成形品で構成されることを特徴とする。これにより、ポリオレフィン樹脂を主成分とする樹脂の特性によって、アレルギーの可能性が小さく、また適度な弾性を有するため根管の奥まで挿入しやすくなって固定強度が増し、またその挿入時や長期の使用時にも破折が生じにくい歯科用支台が実現される。   In order to solve the above-described problems, a dental abutment according to the present invention includes an insertion fixing portion that is inserted into and fixed to a root canal of a remaining natural tooth, and projects from the root canal opening to the outside of the root canal. And a support part that is formed continuously from the insertion fixing part and supports the artificial tooth part, and the insertion fixing part and the support part contain a polyolefin resin as a main component (containing 50% by weight or more). It is characterized by comprising an integrally molded product of resin. This reduces the possibility of allergies due to the characteristics of the resin that is mainly composed of polyolefin resin, and because it has moderate elasticity, it is easy to insert deep into the root canal, increasing the fixing strength. A dental abutment that is less likely to break even when used is realized.

またポリプロピレンが50重量%以上を占めるポリプロピレンを主成分とする樹脂の一体成形品からなるとしてもよい。これにより、ポリプロピレンの特性によって、アレルギーの可能性が小さく、適度な硬さを有し、破折が生じにくい歯科用支台が実現される。   Moreover, it is good also as an integrally molded product of the resin which has a polypropylene as a main component in which a polypropylene accounts for 50 weight% or more. Accordingly, a dental abutment having a low possibility of allergy, moderate hardness, and being less likely to break due to the characteristics of polypropylene is realized.

また前記挿入固定部と支持部とは、ポリプロピレンを65〜90重量%、ポリエチレン又はエチレンαオレフィンコポリマーを7〜25重量%、ステアリン酸マグネシウムを0.01〜2重量%、酸化チタンと酸化鉄の一方又は双方を0.001〜1重量%、顔料を0.0001〜1重量%含む共重合ポリプロピレン樹脂材料を主成分とする一体成形品からなるとしてもよい。これにより、適切な配合比率によるポリプロピレンの特性等によって、アレルギーの可能性が小さく、適度な硬さを有し、破折が生じにくい歯科用支台が実現される。   The insertion fixing part and the support part are made of 65 to 90% by weight of polypropylene, 7 to 25% by weight of polyethylene or ethylene α-olefin copolymer, 0.01 to 2% by weight of magnesium stearate, titanium oxide and iron oxide. One or both of them may be formed as an integrally molded product mainly composed of a copolymerized polypropylene resin material containing 0.001 to 1% by weight and 0.0001 to 1% by weight of a pigment. Accordingly, a dental abutment having a low possibility of allergy, moderate hardness, and being less likely to break is realized by the characteristics of polypropylene with an appropriate blending ratio and the like.

また前記挿入固定部と支持部とは、ポリプロピレンを75〜85重量%、ポリエチレン又はエチレンαオレフィンコポリマーを15〜20重量%、ステアリン酸マグネシウムを0.03〜0.5重量%、酸化チタンと酸化鉄の一方又は双方を0.003〜0.1重量%、顔料を0.001〜0.1重量%含む共重合ポリプロピレン樹脂材料を主成分とする一体成形品からなるとしてもよい。これにより、適切な配合比率によるポリプロピレンの特性等によって、アレルギーの可能性が小さく、適度な硬さを有し、破折が生じにくい歯科用支台が実現される。   The insertion fixing part and the support part are composed of 75 to 85% by weight of polypropylene, 15 to 20% by weight of polyethylene or ethylene α-olefin copolymer, 0.03 to 0.5% by weight of magnesium stearate, and oxidized with titanium oxide. One or both of iron may be formed of an integrally molded product mainly composed of a copolymerized polypropylene resin material containing 0.003 to 0.1% by weight and pigment of 0.001 to 0.1% by weight. Accordingly, a dental abutment having a low possibility of allergy, moderate hardness, and being less likely to break is realized by the characteristics of polypropylene with an appropriate blending ratio and the like.

また本発明の樹脂材料は、口腔内において使用される歯科用支台を製造するために使用される樹脂材料であって、ポリプロピレンを65〜90重量%、ポリエチレン又はエチレンαオレフィンコポリマーを7〜25重量%、ステアリン酸マグネシウムを0.01〜2重量%、酸化チタンと酸化鉄の一方又は双方を0.001〜1重量%、顔料を0.0001〜1重量%含む共重合ポリプロピレン樹脂材料を主成分とするものであることを特徴とする。これにより、適切な配合比率によるポリプロピレンの特性等によって、アレルギーの可能性が小さく、適度な硬さを有し、破折が生じにくい歯科用支台が実現される。   The resin material of the present invention is a resin material used for producing a dental abutment used in the oral cavity, and 65 to 90% by weight of polypropylene and 7 to 25 of polyethylene or ethylene α-olefin copolymer. Mainly a copolymer polypropylene resin material containing 0.01% to 2% by weight of magnesium stearate, 0.001 to 1% by weight of one or both of titanium oxide and iron oxide, and 0.0001 to 1% by weight of pigment. It is characterized by being a component. Accordingly, a dental abutment having a low possibility of allergy, moderate hardness, and being less likely to break is realized by the characteristics of polypropylene with an appropriate blending ratio and the like.

また本発明の樹脂材料は、口腔内において使用される歯科用支台を製造するために使用される樹脂材料であって、ポリプロピレンを75〜85重量%、ポリエチレン又はエチレンαオレフィンコポリマーを15〜20重量%、ステアリン酸マグネシウムを0.03〜0.5重量%、酸化チタンと酸化鉄の一方又は双方を0.003〜0.1重量%、顔料を0.001〜0.1重量%含む共重合ポリプロピレン樹脂材料を主成分とするものであることを特徴とする。これにより、適切な配合比率によるポリプロピレンの特性等によって、アレルギーの可能性が小さく、適度な硬さを有し、破折が生じにくい歯科用支台が実現される。なお上記で硬さとは微小な弾性を有することを意味するとしてもよい。   The resin material of the present invention is a resin material used for producing a dental abutment used in the oral cavity, and is 75 to 85% by weight of polypropylene and 15 to 20 of polyethylene or ethylene α-olefin copolymer. Copolymer containing 0.03 to 0.5% by weight of magnesium stearate, 0.003 to 0.1% by weight of one or both of titanium oxide and iron oxide, and 0.001 to 0.1% by weight of pigment. It is characterized by comprising a polymerized polypropylene resin material as a main component. Accordingly, a dental abutment having a low possibility of allergy, moderate hardness, and being less likely to break is realized by the characteristics of polypropylene with an appropriate blending ratio and the like. In the above, the hardness may mean having a minute elasticity.

本発明の歯科用支台の1実施形態を示す図。The figure which shows one Embodiment of the dental abutment of this invention. 歯科用支台を装着した例を示す図。The figure which shows the example which mounted | wore with the dental abutment. 本発明の歯科用支台の別の実施形態を示す図。The figure which shows another embodiment of the dental abutment of this invention. 図3の歯科用支台を装着した例を示す図。The figure which shows the example which mounted | wore the dental abutment of FIG.

以下、本発明の実施例を図面を参照しつつ説明する。図1は、本発明の歯科用支台の一実施例を示す図である。図2は、その歯科用支台を歯に装着した状態の例を示す図である。なお以下では特に断らない限り、歯の根元方向を下、歯の先端方向を上と表現する。   Embodiments of the present invention will be described below with reference to the drawings. FIG. 1 is a diagram showing an embodiment of a dental abutment according to the present invention. FIG. 2 is a diagram showing an example of a state in which the dental abutment is mounted on a tooth. In the following, unless otherwise specified, the root direction of the tooth is expressed as “down” and the tip direction of the tooth is expressed as “up”.

歯科用支台1(支台)は、歯冠部分が大きく欠損した歯における根管に装着されて、人工的に形成された歯冠部を固定、支持する。図2では残存する天然歯における歯根4の根管40が2本の断面の例が示されている。この例は、天然歯において歯肉部6よりも図示上方の歯冠部が全て欠損した例である。図1に示された歯科用支台1は、図2の根管40の形状に適合する例とする。   The dental abutment 1 (abutment) is attached to a root canal in a tooth having a largely missing crown portion, and fixes and supports an artificially formed crown portion. FIG. 2 shows an example in which the root canal 40 of the root 4 of the remaining natural tooth has two cross sections. This example is an example in which the crown part above the gingiva part 6 in the natural tooth is completely lost. The dental abutment 1 shown in FIG. 1 is an example adapted to the shape of the root canal 40 of FIG.

具体的に歯科用支台1は挿入固定部2と支持部3とを備える。図2に示すように、挿入固定部2は残存する天然歯の歯根4の根管40に挿入されて固定される。そして支持部3は、根管40の開口からその根管40の外側へ突出するように挿入固定部2から連続して形成されて、別に人工的に形成された歯冠部5(人工歯部)を支持する。   Specifically, the dental abutment 1 includes an insertion fixing portion 2 and a support portion 3. As shown in FIG. 2, the insertion fixing portion 2 is inserted into the root canal 40 of the root 4 of the remaining natural tooth and fixed. And the support part 3 is continuously formed from the insertion fixing | fixed part 2 so that it may protrude outside the root canal 40 from the opening of the root canal 40, and the artificial crown part 5 (artificial tooth part) separately formed. ).

歯冠部5には、支持部3が隙間なく嵌合するように凹部50が形成されている。挿入固定部2と根管40との間、歯冠部5と支持部3の間、歯冠部5と歯根4との間などは、例えば歯科用接着剤8によって接着してもよい。なお歯冠部5と支持部3の間、歯冠部5と歯根4との間は接着せずに、歯冠部5を別の手段(例えば隣接する天然歯に連結するブリッジ部など)によって支持部3に固定してもよい。また根管40の先端には支台1の装着に先立って、封止部7(例えば根管充填材)で根管40の図示下方の端(根尖)を封止すればよい。   A concave portion 50 is formed in the tooth crown portion 5 so that the support portion 3 is fitted with no gap. You may adhere between the insertion fixing | fixed part 2 and the root canal 40, between the crown part 5 and the support part 3, between the crown part 5 and the root 4 with the dental adhesive agent 8, for example. The crown portion 5 and the support portion 3 are not bonded to each other, and the crown portion 5 and the root 4 are not bonded to each other, and the crown portion 5 is connected by another means (for example, a bridge portion connected to an adjacent natural tooth). You may fix to the support part 3. FIG. Moreover, what is necessary is just to seal the lower end (root apex) of the root canal 40 with the sealing part 7 (for example, root canal filling material) prior to mounting the abutment 1 at the tip of the root canal 40.

図1および図2に示された歯科用支台1は一例に過ぎず、患者の歯根4の残存状態や、根管40の形状によって本発明の支台は多様な形態をとる。図3および図4には、根管40が1本の場合が示されている。この場合も図1、図2と同様に、挿入固定部2は残存する天然歯の歯根4の根管40に挿入されて固定され、支持部3は、根管40の開口からその根管40の外側へ突出するように挿入固定部2から連続して形成されて、別に人工的に形成された歯冠部5(人工歯部)を支持する。本発明の支台1は、あらゆる根管40の本数や形状、天然歯の残存形状などに対して、何ら限定無く適用される。   The dental abutment 1 shown in FIGS. 1 and 2 is merely an example, and the abutment of the present invention takes various forms depending on the remaining state of the patient's root 4 and the shape of the root canal 40. 3 and 4 show a case where there is one root canal 40. In this case as well, as in FIGS. 1 and 2, the insertion fixing portion 2 is inserted and fixed in the root canal 40 of the remaining root 4 of the natural tooth, and the support portion 3 is opened from the root canal 40 through the root canal 40. It is formed continuously from the insertion fixing portion 2 so as to protrude to the outside, and supports the artificially formed crown portion 5 (artificial tooth portion). The abutment 1 of the present invention can be applied to any number and shape of root canals 40 and the remaining shape of natural teeth without any limitation.

後述するように本発明の支台1は、挿入固定部と支持部とがポリオレフィン樹脂を主体とする樹脂の一体成形品で構成されることを特徴とする。なお主成分とは、50重量%以上の含有率を有する成分を指す。本発明では、挿入固定部と支持部とをポリプロピレンが50重量%以上を占めるポリプロピレンを主体とする樹脂の一体成形品とすればさらに好適である。   As will be described later, the abutment 1 of the present invention is characterized in that the insertion fixing portion and the support portion are formed of an integrally molded product of resin mainly composed of polyolefin resin. In addition, a main component refers to the component which has a content rate of 50 weight% or more. In the present invention, it is more preferable that the insertion fixing portion and the support portion are integrally formed of a resin mainly composed of polypropylene in which polypropylene accounts for 50% by weight or more.

本発明の支台1、1’の製造方法は、従来からある歯科用支台(支台築造体、支台歯)の製造方法を何ら限定無く使用できる。製造方法の一例は以下のとおりである。まず歯冠部分が欠損した患者の天然歯において、歯根4の根管40から歯髄を摘出する。そして空洞となった根管40に対して、清掃や消毒の後に根管充填材7を充填する。これにより根尖が封止される。根管充填材7の材質や充填方法は従来どおりとすればよい。   The manufacturing method of the abutment 1, 1 'of the present invention can use any conventional manufacturing method of a dental abutment (abutment structure, abutment tooth) without any limitation. An example of the manufacturing method is as follows. First, in the natural tooth of a patient with a missing crown part, the pulp is removed from the root canal 40 of the root 4. Then, the root canal filling material 7 is filled into the hollow root canal 40 after cleaning and disinfection. This seals the root apex. The material and filling method of the root canal filling material 7 may be the same as conventional ones.

そして根管40内の根管充填材7のうちで、根管40の上方の部分は不要ならば切除する。次に、必要ならば、根管40において根管充填材7のない部分の形状を、挿入固定部2を挿入するのに適した形状に整える。その場合、例えば根管40を広げたり、あるいは形状が円筒形状に近づくように、根管40の壁部を歯科用器具で切削すればよい。   Of the root canal filling material 7 in the root canal 40, the portion above the root canal 40 is removed if unnecessary. Next, if necessary, the shape of the portion without the root canal filling material 7 in the root canal 40 is adjusted to a shape suitable for inserting the insertion fixing portion 2. In that case, for example, the root canal 40 may be widened or the wall of the root canal 40 may be cut with a dental instrument so that the shape approaches a cylindrical shape.

そしていわゆる間接法を用いて支台を作成する。すなわち、例えば、根管40の形状を整えた後に、印象材(例えば歯科用セメント)によって根管40(を含む残存天然歯)の印象を採取し、印象から石膏模型を作成する。そして、その模型上で歯科用ワックスで、支台1、1’の型を形成する。   Then, an abutment is created using a so-called indirect method. That is, for example, after adjusting the shape of the root canal 40, an impression of the root canal 40 (including the remaining natural teeth) is collected with an impression material (for example, dental cement), and a plaster model is created from the impression. Then, the mold of the abutment 1, 1 ′ is formed with dental wax on the model.

次に、その型を石膏に埋没して石膏が硬化してから、熱湯などでワックスを流して(流蝋)ワックス部分を空洞にする。その空洞に、上述の材料を射出して重合硬化させると支台1,1’が成形される。この支台1,1’を患者の根管40に装着して、別に作成した歯冠部5を支持部3に装着すればよい。   Next, after the mold is buried in gypsum and the gypsum is cured, wax is poured with hot water (flowing wax) to make the wax portion hollow. When the above-mentioned material is injected into the cavity and polymerized and cured, the abutments 1 and 1 'are formed. The abutments 1 and 1 ′ may be attached to the patient's root canal 40, and a separately prepared crown 5 may be attached to the support 3.

本発明の支台1、1’を構成する成分の一例としては、上記の成分よりもさらに詳細に、例えば、重量比でポリプロピレン80%を主成分とし、これにエチレンαオレフィンコポリマー18%を共重合させて精製したポリプロピレンとすることができる。このポリプロピレンについては、重量比でポリプロピレンホモポリマー[CH2−CH(CH3)]mを80%、エチレンαオレフィンコポリマーとしてエチレンプロピレンコポリマー[CH2−CH(CH3)]m−[CH2−CH2]nを18%の割合で使用し、さらに添加剤として、ステアリン酸マグネシウム0.1%、酸化チタン0.03%、顔料(例えば法定色素であるアルミニウムレーキやベンガラ等、有機及び無機顔料等の中から1つの顔料を選択し、又は複数の顔料を選択・調合して使用する)0.03%となるように調整する。なお、酸化チタンに代えて酸化鉄を同量配合し、あるいは酸化チタンと酸化鉄を合計で0.03%となるように配合してもよい。また、エチレンαオレフィンコポリマーとして、エチレンプロピレンコポリマー以外に、例えばエチレンブテン1コポリマーを用いてもよいし、更には、エチレンαオレフィンコポリマーの代わりに、ポリエチレンを例えば18%含有してもよい。   As an example of the components constituting the abutments 1 and 1 'of the present invention, more specifically than the above components, for example, 80% polypropylene by weight is the main component, and 18% ethylene α-olefin copolymer is co-polymerized. Polymerized and purified polypropylene can be obtained. For this polypropylene, polypropylene homopolymer [CH2-CH (CH3)] m is 80% by weight, and ethylene propylene copolymer [CH2-CH (CH3)] m- [CH2-CH2] n is 18 as an ethylene α-olefin copolymer. In addition, as additives, magnesium stearate 0.1%, titanium oxide 0.03%, pigments (for example, legal dyes such as aluminum lake and bengara, organic and inorganic pigments, etc.) Select a pigment, or select and prepare a plurality of pigments) and adjust to 0.03%. Note that the same amount of iron oxide may be blended instead of titanium oxide, or the total amount of titanium oxide and iron oxide may be 0.03%. In addition to the ethylene propylene copolymer, for example, an ethylene butene 1 copolymer may be used as the ethylene α-olefin copolymer, and further, 18% polyethylene may be contained instead of the ethylene α-olefin copolymer.

なお、上記以外の物質が2重量%以下の範囲で不可避的不純物として、又は所定の添加目的の添加剤として、あるいは不可避的不純物と所定の添加剤の合計として入るが、これは本発明の本質的要件及び効果とは関係なく、それらに影響しないものであるから無視してよい。   Substances other than the above are included as inevitable impurities within a range of 2% by weight or less, as additives for a predetermined addition purpose, or as a sum of inevitable impurities and a predetermined additive. This is the essence of the present invention. Regardless of technical requirements and effects, they do not affect them and can be ignored.

そして、上記のプロピレンホモポリマー、エチレンプロピレンコポリマー、ステアリン酸マグネシウム、酸化チタン(酸化鉄)及び顔料を混合して共重合させ、精製することにより歯科用支台の樹脂材料を得た。   The propylene homopolymer, ethylene propylene copolymer, magnesium stearate, titanium oxide (iron oxide), and pigment were mixed and copolymerized, and purified to obtain a resin material for a dental abutment.

この歯科用樹脂材料により、例えば図1から図4に示した歯科用支台1、1’を成形する際には、上記方法を使用して容易に加工が可能である。   For example, when the dental abutment 1, 1 ′ shown in FIGS. 1 to 4 is molded with this dental resin material, it can be easily processed using the above method.

具体的に、歯科用支台を製造する場合、本発明の歯科用樹脂材料は一般にはペレット状原料とされ、これを汎用樹脂成形機のバレルに入れ、ファーネス温度を180℃〜230℃に設定して原料を軟化・溶解させ、例えば石膏の型のなかへ射出成形を行う。本発明においては、添加剤としてステアリン酸マグネシウムが配合されているために、樹脂流動性が高く、成形体に対して細部に至るまで精密に再現することが可能である。   Specifically, when producing a dental abutment, the dental resin material of the present invention is generally a pellet raw material, which is placed in the barrel of a general-purpose resin molding machine, and the furnace temperature is set to 180 ° C. to 230 ° C. Then, the raw material is softened and dissolved, and injection molding is performed, for example, in a plaster mold. In the present invention, since magnesium stearate is blended as an additive, the resin fluidity is high, and it is possible to accurately reproduce the details of the molded product.

このようにして得られた歯科用成形体は、次に列挙するように従来品に比べて極めて有利な特長・特性を備えている。   The dental molded body thus obtained has extremely advantageous features and characteristics as compared with the conventional products as listed below.

1.人体での樹脂アレルギー反応が少ない。
2.内分泌撹乱作用物質であるビスフェノールAの溶出がないため、人体に使用しても安全性が高い。
3.全ての添加剤に対して、この樹脂成分は口腔内での溶出がないため安全性が高く、また、添加剤、顔料についても安全面で心配はない(本発明の歯科用成形樹脂材料の融点は例えば180℃程度であるため)。
4.従来の金属を用いて作られる支台の場合、その支台の上から被覆する人工歯牙が樹脂及びセラミック製の歯牙の場合、金属色の支台が透過し不自然であった。本発明の場合、上部を被覆する人工歯牙が前述のものであったとしても、歯牙色を再現した支台である為審美的に損なうことがなく、また上部歯牙色と同様色に染料を加えた樹脂の提供が可能である。本発明品を口腔内に装着する際に使用する歯科用セメントにおいて像影反応が得られる為、本素材自体の像影性は無くとも十分である。
5.ステアリン酸マグネシウムを添加剤として配合することにより、樹脂染色時において顔料が全てにまんべんなく混ざり、染色性が非常に高まる。
6.ステアリン酸マグネシウムを配合することにより、樹脂自体の表面の滑沢度が増し、滑りが良くなるため、義歯床体の脱着に有効的である。
7.酸化チタン(酸化鉄)を添加剤として配合することにより、天然歯に近い自然観のある色合いを再現できる。
8.本発明の歯科用成形体によれば、従来から使用されている歯科用成形樹脂材料(ポリカーボネート、ポリエチレンテレフタレート(PET)、アクリル等)に比べ、機械的強度、曲げ強度、耐熱性に優れているため、破折も生じにくく、かつ非常にコンパクトで口腔内での違和感のない歯科用支台が可能であり、吸水性も従来からの樹脂材料に比べ非常に低いため、吸水による雑菌の繁殖や樹脂物性劣化が極めて少ない。
9.さらに上述の組成の歯科用成形樹脂材料は、比重において他の樹脂よりも軽いため、使用時に口腔内組織への負担が少ない。
10.本発明の歯科成形樹脂材料は、従来の樹脂材料に比べ、空気中の水分を吸収しにくいため、常温での保管状態においても問題がなく、射出成形時においても水分を除去するために熱乾燥させる必要もなく、作業効率性においても優れている。
11.なお、本発明の歯科用成形樹脂材料はペレット状のものが一般的であるが、これに限定されるものではなく、シート状、ブロック状等のものであっても良い。
1. There are few resin allergic reactions in the human body.
2. Since there is no elution of bisphenol A, which is an endocrine disrupting substance, it is highly safe to use for the human body.
3. For all additives, this resin component is highly safe because it does not dissolve in the oral cavity, and there is no concern about the additives and pigments in terms of safety (the melting point of the dental molding resin material of the present invention). Is, for example, about 180 ° C.).
4). In the case of an abutment made using a conventional metal, when the artificial tooth covered from the top of the abutment is a resin and ceramic tooth, the metallic abutment is permeated and unnatural. In the case of the present invention, even if the artificial tooth covering the upper part is the above-described one, it is an abutment that reproduces the tooth color, so it is not aesthetically impaired, and a dye is added to the same color as the upper tooth color. Resin can be provided. Since an image reaction is obtained in the dental cement used when the product of the present invention is installed in the oral cavity, the image itself of the material itself is sufficient even if it is not.
5. By blending magnesium stearate as an additive, all the pigments are evenly mixed at the time of resin dyeing, and the dyeability is greatly enhanced.
6). By blending magnesium stearate, the smoothness of the surface of the resin itself is increased and the slipping is improved, which is effective for desorption of the denture base.
7). By blending titanium oxide (iron oxide) as an additive, it is possible to reproduce a natural hue close to natural teeth.
8). According to the dental molded body of the present invention, mechanical strength, bending strength, and heat resistance are superior to conventional dental molding resin materials (polycarbonate, polyethylene terephthalate (PET), acrylic, etc.). Therefore, it is difficult to break, and it is possible to create a dental abutment that is very compact and has no sense of discomfort in the oral cavity, and its water absorption is very low compared to conventional resin materials. There is very little deterioration of resin properties.
9. Furthermore, since the dental molding resin material having the above-described composition is lighter than other resins in specific gravity, the burden on the oral cavity tissue during use is small.
10. Since the dental molding resin material of the present invention is less likely to absorb moisture in the air than conventional resin materials, there is no problem even in storage conditions at room temperature, and heat drying to remove moisture even during injection molding. It is not necessary to make it work, and it is excellent in work efficiency.
11. The dental molding resin material of the present invention is generally in the form of pellets, but is not limited thereto, and may be in the form of a sheet, a block, or the like.

以上のような本発明に係る歯科用成形樹脂材料により成形された歯科用成形体について評価試験を行った。その結果が表1に示されている。   An evaluation test was performed on a dental molded body molded from the dental molding resin material according to the present invention as described above. The results are shown in Table 1.

Figure 2013215394
Figure 2013215394

表1に示すとおり、例えば繰返し折曲げ試験においては、吸水前後を測定した結果、本発明品ではともに他の歯科用樹脂材料よりも優れた結果が得られた。例えば吸水前の繰返し折曲げ試験で、ポリカーボネートは5回で折れ、ポリエチレンテレフタレート(PET)+ポリエチレンの複合樹脂では14回で裂け目、38回で折れ、ポリアミドは47回で裂け目、129回で折れたが、本発明品では曲げている所が白くなるだけで、200回の折曲げでも裂け目や折損は生じなかった。   As shown in Table 1, for example, in the repeated bending test, the results before and after water absorption were measured. As a result, in the products of the present invention, results superior to other dental resin materials were obtained. For example, in a repeated bending test before water absorption, the polycarbonate was folded 5 times, the polyethylene terephthalate (PET) + polyethylene composite resin was cracked 14 times and 38 times, and the polyamide was broken 47 times and 129 times. However, in the product of the present invention, the bent portion only became white, and no tears or breakage occurred even after bending 200 times.

また,吸水後の繰返し折曲げ試験では、ポリカーボネートは6回で折れ、PET+ポリエチレンは12回で裂け目、51回で折れ、ポリアミドは53回で裂け目、118回で折れたが、本発明品では曲げている所が白くなるだけで、200回で裂け目なしであった。また本発明の樹脂材料(成形体)においては曲げ強度が61.2MPa、伸度12mm以上、吸水率0.13重量%、溶解率0.1重量%であり、非常に良好な数値が得られた。その他、作業性、着色等の実験結果も、添付するように良好な結果が得られた。   Further, in the repeated bending test after water absorption, polycarbonate was folded at 6 times, PET + polyethylene was broken at 12 times, broken at 51 times, and polyamide was broken at 53 times, broken at 118 times. The only part that turned white was 200, and there was no tear. In the resin material (molded article) of the present invention, the bending strength is 61.2 MPa, the elongation is 12 mm or more, the water absorption is 0.13% by weight, and the dissolution rate is 0.1% by weight. It was. In addition, good results were obtained as shown in the attached experimental results for workability and coloring.

着色の試験に関して補足すれば、表1の下から2段目の「着色ΔEカレー」とは、カレー粉を溶解した湯中に37℃で1週間、試料としての樹脂片を浸漬し、その後試料の樹脂片を取り出して、専用の試験機でカレー粉溶液によってどれだけ着色されたかを検査し、その検査結果を数値化したものであり、数値が小さいほど着色の程度が低い、換言すれば変色が少ないことを意味する。また、「着色ΔEフクシン」とは、カレー粉の代わりに着色料のフクシンを用いて同様の検査を行ったものであり、検査数値が小さいほど変色が少ないことを意味する。これらの結果から明らかなように、本発明品では「着色ΔEカレー」の検査値が1.29、「着色ΔEフクシン」の検査値が5.19であって、ポリアミドやPET+ポリエチレン等の検査値に比べて充分小さく、変色しにくいことがわかる。   Supplementing with respect to the coloring test, the “colored ΔE curry” in the second row from the bottom of Table 1 means that a resin piece as a sample is immersed in hot water in which curry powder is dissolved at 37 ° C. for 1 week, and then the sample. The resin piece was taken out and inspected how much it was colored by the curry powder solution with a dedicated testing machine, and the inspection result was quantified. The smaller the value, the lower the degree of coloring, in other words, discoloration Means less. In addition, “colored ΔE fuchsin” is obtained by performing the same inspection using fuchsin as a colorant instead of curry powder, and means that the smaller the inspection value, the less the color change. As is apparent from these results, the test value of “colored ΔE curry” in the present invention is 1.29, the test value of “colored ΔE fuchsin” is 5.19, and test values of polyamide, PET + polyethylene, etc. It can be seen that it is sufficiently small compared to, and difficult to discolor.

さらに、本発明の成形体に対して耐熱試験も行った。具体的には、本発明の樹脂材料を、射出成形により20mm×20mm×3mmのサイズの板材に製作し調整し、沸騰水(約100℃)中に1時間浸漬し、成形体の外観を確認した。その結果、面荒れや白濁等は見られなかった。したがって本発明材料を使用し製造された歯科用支台においても同様の効果が得られる。   Furthermore, a heat resistance test was also performed on the molded body of the present invention. Specifically, the resin material of the present invention is manufactured and adjusted to a 20 mm × 20 mm × 3 mm size plate material by injection molding, and immersed in boiling water (about 100 ° C.) for 1 hour, and the appearance of the molded body is confirmed. did. As a result, surface roughness and cloudiness were not observed. Accordingly, the same effect can be obtained in a dental abutment manufactured using the material of the present invention.

本発明の歯科用成形体、及び歯科用樹脂材料の組成を上記のようにして歯科用支台を形成した場合の効果について述べる(以下で%は特に断らない場合は重量比を指す)。ポリプロピレンが65%未満であると、剥離破折が生じやすくなり、90%を超えると、樹脂体の膨張による口腔への不適合の問題が生ずる。したがってポリプロピレンは例えば65〜90%とすればよい。   The effects of forming the dental abutment as described above in the composition of the dental molded body and the dental resin material of the present invention will be described (hereinafter% refers to the weight ratio unless otherwise specified). If the polypropylene content is less than 65%, peeling breakage tends to occur, and if it exceeds 90%, a problem of incompatibility with the oral cavity due to expansion of the resin body occurs. Therefore, polypropylene may be, for example, 65 to 90%.

また、ポリエチレン又はエチレンαオレフィンコポリマーが7%未満であると、ポリプロピレンの場合と同様に剥離破折が生じやすくなり、逆に25%を超えると、ポリプロピレンの場合と同様に樹脂体の膨張による口腔への不適合の問題があるので、ポリエチレン又はエチレンαオレフィンコポリマーは例えば7〜25%の範囲であることが望ましい。   Further, if the polyethylene or ethylene α-olefin copolymer is less than 7%, peeling breakage is likely to occur as in the case of polypropylene, and conversely if it exceeds 25%, the oral cavity due to the expansion of the resin body as in the case of polypropylene. It is desirable that the polyethylene or ethylene alpha olefin copolymer is in the range of, for example, 7-25% because of incompatibility problems.

また、ステアリン酸マグネシウムは、顔料、酸化チタン(又は酸化鉄)及び樹脂の相互の撹拌性・混合性を向上させるが、0.01%未満であると、その効果(染色における撹拌性・混合性の向上効果)が期待できず、逆に2%を超えると、撹拌や混合自体が困難になるため、例えば0.01〜2%の範囲での添加が望ましい。ここで染色とは、例えば、歯科用支台に用いる際に、天然歯の色に近い色彩に染色することを指す。顔料及び酸化チタン(又は酸化鉄)は色付け(発色)のために添加される。例えば天然歯に近い色を生じさせるには、適切な顔料と酸化チタン(白系)との混合比が調整される。さらに酸化チタンと酸化鉄の双方を所定の顔料に添加して所望の色に樹脂を染色することもできる。   Magnesium stearate improves the mutual stirrability and mixing of the pigment, titanium oxide (or iron oxide) and resin, but if it is less than 0.01%, the effect (stirring and mixing in dyeing) In contrast, when the content exceeds 2%, stirring and mixing itself become difficult. For example, addition in the range of 0.01 to 2% is desirable. Here, the term “dyeing” refers to, for example, dyeing in a color close to the color of natural teeth when used for a dental abutment. A pigment and titanium oxide (or iron oxide) are added for coloring (coloring). For example, in order to produce a color close to natural teeth, the mixing ratio of an appropriate pigment and titanium oxide (white) is adjusted. Further, both titanium oxide and iron oxide can be added to a predetermined pigment to dye the resin in a desired color.

酸化チタン(又は酸化鉄)の含有量は顔料との関係で主に染色をどのようにするかによって定まり、上記ステアリン酸マグネシウムは、それら顔料及び酸化チタン(酸化鉄)と樹脂材料とを均一に混ぜる撹拌性、ひいてはまんべんなく均一に発色させる均一染色性に寄与するということができる。   The content of titanium oxide (or iron oxide) is determined mainly by the dyeing method in relation to the pigment, and the magnesium stearate uniformly distributes the pigment, titanium oxide (iron oxide) and the resin material. It can be said that it contributes to the agitation ability to mix, and in turn, to the uniform dyeing property that uniformly colors evenly.

酸化チタンと酸化鉄の一方又は双方が、重量比で0.001%未満であると、顔料に対する色調整の役割が果たせず、他方、1%を超えると逆に色調整の機能を逸脱し、また樹脂材料の強度等の物性を阻害するため、0.001〜1%の範囲に設定される。   If one or both of titanium oxide and iron oxide is less than 0.001% by weight, the color adjustment function for the pigment cannot be achieved. On the other hand, if it exceeds 1%, the function of color adjustment deviates. Moreover, in order to inhibit physical properties, such as the intensity | strength of a resin material, it sets to 0.001 to 1% of range.

顔料の組成については、重量比で0.0001%未満であると、染色効果が得られず、他方、1%を超えると却って目的とする染色性を損なうし、樹脂材料の物性上も好ましくないので、顔料の配合率は0.0001〜1%の範囲とする。   As for the composition of the pigment, if it is less than 0.0001% by weight, the dyeing effect cannot be obtained. On the other hand, if it exceeds 1%, the intended dyeability is impaired, and the physical properties of the resin material are not preferable. Therefore, the pigment content is in the range of 0.0001 to 1%.

さらに望ましい組成の歯科用支台において、重量比率でポリプロピレン75〜85%、ポリエチレン又はエチレンαオレフィンコポリマー15〜20%の範囲とすることにより、樹脂の剥離破折がさらに発生しにくくかつ樹脂の膨張も抑えられて、例えば根管内への歯科用成形体の寸法適合性・装着適合性が向上する。なお支台における共重合ポリプロピレン樹脂材料の配合比率は70、80、あるいは90重量%以上としてもよい。   Further, in a dental abutment having a desirable composition, by making the weight ratio within the range of 75 to 85% polypropylene and 15 to 20% polyethylene or ethylene α-olefin copolymer, the resin peeling breakage hardly occurs and the resin expands. For example, the dimensional compatibility and mounting compatibility of the dental molded body in the root canal are improved. The blending ratio of the copolymer polypropylene resin material in the abutment may be 70, 80, or 90% by weight or more.

また、ステアリン酸マグネシウム0.03〜0.5%、酸化チタンと酸化鉄の一方又は双方を0.003〜0.1%、顔料0.001〜0.1%とすれば、まずステアリン酸マグネシウムの上記範囲の配合により、顔料・酸化チタン(酸化鉄)と樹脂とのいっそう良好な撹拌性、まんべんなく均一な染色性が得られ、さらに酸化チタンと酸化鉄の一方又は双方の配合量、並びに顔料の配合量を上記のとおり設定することにより、歯科用成形体又は歯科用樹脂材料に、上記ステアリン酸マグネシウムとの効果とも相まって、さらに良好な発色・染色効果を付与することができる。   Further, if magnesium stearate is 0.03 to 0.5%, one or both of titanium oxide and iron oxide is 0.003 to 0.1%, and pigment is 0.001 to 0.1%, first magnesium stearate In the above range, the pigment / titanium oxide (iron oxide) and the resin can be more satisfactorily stirred and uniformly dyed, and the blending amount of one or both of titanium oxide and iron oxide, as well as the pigment By setting the blending amount of the above as described above, it is possible to give a better coloring and dyeing effect to the dental molded body or dental resin material together with the effect of the magnesium stearate.

いずれにしても、上記の範囲の歯科用成形体とすることによって、例えば歯科用支台として適切な曲げ強度を有し、樹脂体の射出成形後の冷却時の膨張率を抑え、残存天然歯や人工歯冠に対して精密に適合させることができ、人体に対して適度な硬さを持つ特性が得られた。   In any case, by forming a dental molded body in the above range, for example, it has an appropriate bending strength as a dental abutment, suppresses the expansion coefficient at the time of cooling after injection molding of the resin body, and the remaining natural teeth It can be precisely adapted to the dental crown and the artificial crown, and has a characteristic with moderate hardness to the human body.

本発明の組成を有しない、言い換えれば上記組成の配合範囲から外れると、歯科用成形体や歯科用樹脂材料の物性の観点から言えば、本発明が有する特有の曲げ強度が得られず、折曲げにより白く折り目がつきやすく、(支台自身の、あるいは支台以外の歯牙の)破折を来たし、人体に不向きな非常に割れやすい特性となり、また射出成形後においても膨張率が高まり、残存天然歯や人工歯冠に精密に適合できない状況を来たす結果となる。   If the composition does not have the composition of the present invention, in other words, deviates from the blending range of the above composition, the specific bending strength of the present invention cannot be obtained from the viewpoint of the physical properties of the dental molded body and the dental resin material. Bending is easy to crease white, resulting in breakage (of the abutment itself or teeth other than the abutment), making it extremely fragile and unsuitable for the human body. This results in a situation where it cannot be precisely adapted to natural teeth or artificial crowns.

また、添加剤としてのステアリン酸マグネシウム及び酸化チタン(酸化鉄)の添加の効果について付言すれば、これらを添加することにより、例えば歯科用支台にふさわしい顔料染色が可能となり、なおかつ射出成形時の樹脂の流動性が増し、細部成形再現度が向上する。その上、本発明に係る歯科用成形体を使用し、口腔内で人工歯冠の着脱を試みた場合には、上述の添加剤によって摩擦による抵抗を軽減させ、すべりが良好となる結果も得られた。したがって、患者が使用する場合において、従来品に比べて、装着や取外しが容易になる。また、本発明の歯科用成形体によれば、吸水性がきわめて低いため雑菌の繁殖が抑えられ、強度が高いから耐久性があり、比重が小さい(軽い)ため装着感がなく、結果的に患者が衛生的、なおかつ快適に、長期に渡り歯科用支台を使用することが可能となった。   Moreover, if it adds about the effect of the addition of magnesium stearate and titanium oxide (iron oxide) as additives, pigment addition suitable for, for example, a dental abutment can be achieved by adding these, and at the time of injection molding The fluidity of the resin increases and the detail molding reproducibility improves. In addition, when the dental molded body according to the present invention is used and an attempt is made to attach and detach an artificial crown in the oral cavity, the above-mentioned additive reduces the resistance due to friction and results in good sliding. It was. Therefore, when used by a patient, it is easier to attach and remove compared to conventional products. In addition, according to the dental molded body of the present invention, since the water absorption is extremely low, the propagation of various bacteria is suppressed, the strength is high and the durability is high, and the specific gravity is small (light), so there is no feeling of wearing, and as a result The patient can use the dental abutment for a long time in a hygienic and comfortable manner.

本発明の歯科用樹脂材料を用いて歯科用成形体を製造する際には、この樹脂材料を溶融し、一般には射出成形によって所定の歯科用成形体を成形することになる。これによって、前述のように人体に対して樹脂アレルギーが少なく、またビスフェノールA等の溶出のない安全性に優れた、歯科用支台を得ることができる。   When a dental molded body is manufactured using the dental resin material of the present invention, the resin material is melted and a predetermined dental molded body is generally formed by injection molding. As a result, it is possible to obtain a dental abutment that has less resin allergy to the human body as described above and that is excellent in safety without elution of bisphenol A or the like.

1 支台(歯科用支台)
2 挿入固定部
3 支持部
1 abutment (dental abutment)
2 Insertion fixing part 3 Support part

Claims (6)

残存する天然歯の根管に挿入されて固定される挿入固定部と、前記根管の開口からその根管の外側へ突出するように前記挿入固定部から連続して形成されて人工歯部を支持する支持部と、を備え、それら挿入固定部と支持部とがポリオレフィン樹脂を50重量%以上の主成分とする樹脂の一体成形品で構成されることを特徴とする歯科用支台。   An insertion fixing portion that is inserted into and fixed to the root canal of the remaining natural tooth, and an artificial tooth portion that is continuously formed from the insertion fixing portion so as to protrude from the opening of the root canal to the outside of the root canal. A dental abutment comprising: a supporting part that supports the insertion fixing part and the supporting part, wherein the insertion fixing part and the supporting part are made of an integrally molded product of a resin having a polyolefin resin as a main component of 50% by weight or more. ポリプロピレンが50重量%以上を占めるポリプロピレンを主成分とする樹脂の一体成形品からなる請求項1に記載の歯科用支台。   The dental abutment according to claim 1, wherein the dental abutment is made of an integrally molded product of a polypropylene-based resin in which polypropylene accounts for 50% by weight or more. 前記挿入固定部と支持部とは、ポリプロピレンを65〜90重量%、ポリエチレン又はエチレンαオレフィンコポリマーを7〜25重量%、ステアリン酸マグネシウムを0.01〜2重量%、酸化チタンと酸化鉄の一方又は双方を0.001〜1重量%、顔料を0.0001〜1重量%含む共重合ポリプロピレン樹脂材料を主成分とする一体成形品からなる請求項2に記載の歯科用支台。   The insertion fixing part and the support part are 65 to 90% by weight of polypropylene, 7 to 25% by weight of polyethylene or ethylene α-olefin copolymer, 0.01 to 2% by weight of magnesium stearate, and one of titanium oxide and iron oxide. 3. The dental abutment according to claim 2, wherein the dental abutment is composed of an integrally molded product mainly composed of a copolymerized polypropylene resin material containing 0.001 to 1% by weight of both and 0.0001 to 1% by weight of pigment. 前記挿入固定部と支持部とは、ポリプロピレンを75〜85重量%、ポリエチレン又はエチレンαオレフィンコポリマーを15〜20重量%、ステアリン酸マグネシウムを0.03〜0.5重量%、酸化チタンと酸化鉄の一方又は双方を0.003〜0.1重量%、顔料を0.001〜0.1重量%含む共重合ポリプロピレン樹脂材料を主成分とする一体成形品からなる請求項2に記載の歯科用支台。   The insertion fixing part and the support part are 75 to 85% by weight of polypropylene, 15 to 20% by weight of polyethylene or ethylene α-olefin copolymer, 0.03 to 0.5% by weight of magnesium stearate, titanium oxide and iron oxide. The dental product according to claim 2, comprising an integrally molded article mainly comprising a copolymerized polypropylene resin material containing 0.003 to 0.1% by weight of one or both of these and 0.001 to 0.1% by weight of a pigment. Abutment. 口腔内において使用される歯科用支台を製造するために使用される樹脂材料であって、ポリプロピレンを65〜90重量%、ポリエチレン又はエチレンαオレフィンコポリマーを7〜25重量%、ステアリン酸マグネシウムを0.01〜2重量%、酸化チタンと酸化鉄の一方又は双方を0.001〜1重量%、顔料を0.0001〜1重量%含む共重合ポリプロピレン樹脂材料を主成分とするものであることを特徴とする歯科用樹脂材料。   A resin material used for manufacturing a dental abutment used in the oral cavity, which is 65 to 90% by weight of polypropylene, 7 to 25% by weight of polyethylene or ethylene α-olefin copolymer, and 0 of magnesium stearate. .01 to 2% by weight, comprising as a main component a copolymer polypropylene resin material containing 0.001 to 1% by weight of one or both of titanium oxide and iron oxide and 0.0001 to 1% by weight of pigment. Characteristic dental resin material. 口腔内において使用される歯科用支台を製造するために使用される樹脂材料であって、ポリプロピレンを75〜85重量%、ポリエチレン又はエチレンαオレフィンコポリマーを15〜20重量%、ステアリン酸マグネシウムを0.03〜0.5重量%、酸化チタンと酸化鉄の一方又は双方を0.003〜0.1重量%、顔料を0.001〜0.1重量%含む共重合ポリプロピレン樹脂材料を主成分とするものであることを特徴とする歯科用樹脂材料。   A resin material used for manufacturing a dental abutment used in the oral cavity, which is 75 to 85% by weight of polypropylene, 15 to 20% by weight of polyethylene or ethylene α-olefin copolymer, and 0 of magnesium stearate. The main component is a copolymerized polypropylene resin material containing 0.003 to 0.5% by weight, 0.003 to 0.1% by weight of one or both of titanium oxide and iron oxide, and 0.001 to 0.1% by weight of pigment. A dental resin material characterized by that.
JP2012088431A 2012-04-09 2012-04-09 Dental abutment, and dental resin material Pending JP2013215394A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2022504619A (en) * 2018-10-12 2022-01-13 デンツプライ シロナ インコーポレイテッド Methods and systems for making custom dental implants and custom dental implants

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2022504619A (en) * 2018-10-12 2022-01-13 デンツプライ シロナ インコーポレイテッド Methods and systems for making custom dental implants and custom dental implants
JP7560453B2 (en) 2018-10-12 2024-10-02 デンツプライ シロナ インコーポレイテッド CUSTOM DENTAL IMPLANTS AND METHODS AND SYSTEMS FOR MAKING CUSTOM DENTAL IMPLANTS - Patent application

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