JP2013034452A - Bottled fruit juice drink - Google Patents
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- JP2013034452A JP2013034452A JP2011175040A JP2011175040A JP2013034452A JP 2013034452 A JP2013034452 A JP 2013034452A JP 2011175040 A JP2011175040 A JP 2011175040A JP 2011175040 A JP2011175040 A JP 2011175040A JP 2013034452 A JP2013034452 A JP 2013034452A
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- 235000015203 fruit juice Nutrition 0.000 title claims abstract description 107
- 235000010376 calcium ascorbate Nutrition 0.000 claims abstract description 28
- 229940047036 calcium ascorbate Drugs 0.000 claims abstract description 28
- 239000011692 calcium ascorbate Substances 0.000 claims abstract description 28
- BLORRZQTHNGFTI-ZZMNMWMASA-L calcium-L-ascorbate Chemical compound [Ca+2].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] BLORRZQTHNGFTI-ZZMNMWMASA-L 0.000 claims abstract description 28
- 238000004519 manufacturing process Methods 0.000 claims abstract description 18
- 235000013361 beverage Nutrition 0.000 claims description 48
- 238000000034 method Methods 0.000 claims description 15
- 239000000796 flavoring agent Substances 0.000 abstract description 37
- 235000019634 flavors Nutrition 0.000 abstract description 37
- 238000002845 discoloration Methods 0.000 abstract 1
- 238000009472 formulation Methods 0.000 description 96
- 239000000203 mixture Substances 0.000 description 96
- 238000003860 storage Methods 0.000 description 50
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 47
- 238000011156 evaluation Methods 0.000 description 27
- 238000002156 mixing Methods 0.000 description 25
- 235000010323 ascorbic acid Nutrition 0.000 description 22
- 239000011668 ascorbic acid Substances 0.000 description 22
- 229960005070 ascorbic acid Drugs 0.000 description 19
- 230000001953 sensory effect Effects 0.000 description 12
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 11
- 239000011575 calcium Substances 0.000 description 11
- 229960005069 calcium Drugs 0.000 description 11
- 229910052791 calcium Inorganic materials 0.000 description 11
- 230000007423 decrease Effects 0.000 description 11
- 235000013399 edible fruits Nutrition 0.000 description 10
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 9
- PPASLZSBLFJQEF-RKJRWTFHSA-M sodium ascorbate Substances [Na+].OC[C@@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RKJRWTFHSA-M 0.000 description 9
- 235000010378 sodium ascorbate Nutrition 0.000 description 9
- 229960005055 sodium ascorbate Drugs 0.000 description 9
- PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical compound [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 description 9
- 230000002255 enzymatic effect Effects 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 239000002994 raw material Substances 0.000 description 7
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 238000004321 preservation Methods 0.000 description 6
- 235000014214 soft drink Nutrition 0.000 description 6
- 235000015197 apple juice Nutrition 0.000 description 5
- 230000003247 decreasing effect Effects 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000012790 confirmation Methods 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 230000002401 inhibitory effect Effects 0.000 description 4
- 230000001629 suppression Effects 0.000 description 4
- CIWBSHSKHKDKBQ-DUZGATOHSA-N D-araboascorbic acid Natural products OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- 229940072107 ascorbate Drugs 0.000 description 3
- 235000014171 carbonated beverage Nutrition 0.000 description 3
- 235000010350 erythorbic acid Nutrition 0.000 description 3
- 239000004318 erythorbic acid Substances 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 235000015201 grapefruit juice Nutrition 0.000 description 3
- 238000007689 inspection Methods 0.000 description 3
- 229940026239 isoascorbic acid Drugs 0.000 description 3
- BEJNERDRQOWKJM-UHFFFAOYSA-N kojic acid Chemical compound OCC1=CC(=O)C(O)=CO1 BEJNERDRQOWKJM-UHFFFAOYSA-N 0.000 description 3
- 229960004705 kojic acid Drugs 0.000 description 3
- WZNJWVWKTVETCG-UHFFFAOYSA-N kojic acid Natural products OC(=O)C(N)CN1C=CC(=O)C(O)=C1 WZNJWVWKTVETCG-UHFFFAOYSA-N 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 235000006708 antioxidants Nutrition 0.000 description 2
- 239000004227 calcium gluconate Substances 0.000 description 2
- 229960004494 calcium gluconate Drugs 0.000 description 2
- 235000013927 calcium gluconate Nutrition 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- NEEHYRZPVYRGPP-UHFFFAOYSA-L calcium;2,3,4,5,6-pentahydroxyhexanoate Chemical compound [Ca+2].OCC(O)C(O)C(O)C(O)C([O-])=O.OCC(O)C(O)C(O)C(O)C([O-])=O NEEHYRZPVYRGPP-UHFFFAOYSA-L 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 235000015165 citric acid Nutrition 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 235000014058 juice drink Nutrition 0.000 description 2
- 239000001630 malic acid Substances 0.000 description 2
- 235000011090 malic acid Nutrition 0.000 description 2
- 235000000346 sugar Nutrition 0.000 description 2
- WBZFUFAFFUEMEI-UHFFFAOYSA-M Acesulfame k Chemical compound [K+].CC1=CC(=O)[N-]S(=O)(=O)O1 WBZFUFAFFUEMEI-UHFFFAOYSA-M 0.000 description 1
- 244000144730 Amygdalus persica Species 0.000 description 1
- 244000099147 Ananas comosus Species 0.000 description 1
- 235000007119 Ananas comosus Nutrition 0.000 description 1
- 108010011485 Aspartame Proteins 0.000 description 1
- 235000004936 Bromus mango Nutrition 0.000 description 1
- OPSXJNAGCGVGOG-DKWTVANSSA-L Calcium L-aspartate Chemical compound [Ca+2].[O-]C(=O)[C@@H](N)CC([O-])=O OPSXJNAGCGVGOG-DKWTVANSSA-L 0.000 description 1
- 102000030523 Catechol oxidase Human genes 0.000 description 1
- 108010031396 Catechol oxidase Proteins 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 240000000560 Citrus x paradisi Species 0.000 description 1
- SBJKKFFYIZUCET-JLAZNSOCSA-N Dehydro-L-ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(=O)C1=O SBJKKFFYIZUCET-JLAZNSOCSA-N 0.000 description 1
- SBJKKFFYIZUCET-UHFFFAOYSA-N Dehydroascorbic acid Natural products OCC(O)C1OC(=O)C(=O)C1=O SBJKKFFYIZUCET-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 241000220225 Malus Species 0.000 description 1
- 235000011430 Malus pumila Nutrition 0.000 description 1
- 235000015103 Malus silvestris Nutrition 0.000 description 1
- 240000007228 Mangifera indica Species 0.000 description 1
- 235000014826 Mangifera indica Nutrition 0.000 description 1
- 240000008790 Musa x paradisiaca Species 0.000 description 1
- 235000018290 Musa x paradisiaca Nutrition 0.000 description 1
- 239000004384 Neotame Substances 0.000 description 1
- 235000006040 Prunus persica var persica Nutrition 0.000 description 1
- 235000009184 Spondias indica Nutrition 0.000 description 1
- 244000228451 Stevia rebaudiana Species 0.000 description 1
- 239000004376 Sucralose Substances 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 240000006909 Tilia x europaea Species 0.000 description 1
- 235000010358 acesulfame potassium Nutrition 0.000 description 1
- 229960004998 acesulfame potassium Drugs 0.000 description 1
- 239000000619 acesulfame-K Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229940024606 amino acid Drugs 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 235000010208 anthocyanin Nutrition 0.000 description 1
- 239000004410 anthocyanin Substances 0.000 description 1
- 229930002877 anthocyanin Natural products 0.000 description 1
- 150000004636 anthocyanins Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 229940076638 ascorbic acid and calcium Drugs 0.000 description 1
- 239000000605 aspartame Substances 0.000 description 1
- 235000010357 aspartame Nutrition 0.000 description 1
- IAOZJIPTCAWIRG-QWRGUYRKSA-N aspartame Chemical compound OC(=O)C[C@H](N)C(=O)N[C@H](C(=O)OC)CC1=CC=CC=C1 IAOZJIPTCAWIRG-QWRGUYRKSA-N 0.000 description 1
- 229960003438 aspartame Drugs 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 235000001465 calcium Nutrition 0.000 description 1
- 229940034055 calcium aspartate Drugs 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229960003563 calcium carbonate Drugs 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 229940095643 calcium hydroxide Drugs 0.000 description 1
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 description 1
- 239000001527 calcium lactate Substances 0.000 description 1
- 229960002401 calcium lactate Drugs 0.000 description 1
- 235000011086 calcium lactate Nutrition 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 229940087373 calcium oxide Drugs 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 235000021466 carotenoid Nutrition 0.000 description 1
- 150000001747 carotenoids Chemical class 0.000 description 1
- 235000021447 cloudy apple juice Nutrition 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 235000020960 dehydroascorbic acid Nutrition 0.000 description 1
- 239000011615 dehydroascorbic acid Substances 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000003631 expected effect Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000003599 food sweetener Nutrition 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- 235000019412 neotame Nutrition 0.000 description 1
- HLIAVLHNDJUHFG-HOTGVXAUSA-N neotame Chemical compound CC(C)(C)CCN[C@@H](CC(O)=O)C(=O)N[C@H](C(=O)OC)CC1=CC=CC=C1 HLIAVLHNDJUHFG-HOTGVXAUSA-N 0.000 description 1
- 108010070257 neotame Proteins 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- HELXLJCILKEWJH-NCGAPWICSA-N rebaudioside A Chemical compound O([C@H]1[C@H](O)[C@@H](CO)O[C@H]([C@@H]1O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)O[C@]12C(=C)C[C@@]3(C1)CC[C@@H]1[C@@](C)(CCC[C@]1([C@@H]3CC2)C)C(=O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O HELXLJCILKEWJH-NCGAPWICSA-N 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 235000019600 saltiness Nutrition 0.000 description 1
- 235000019643 salty taste Nutrition 0.000 description 1
- 239000004320 sodium erythorbate Substances 0.000 description 1
- 235000010352 sodium erythorbate Nutrition 0.000 description 1
- RBWSWDPRDBEWCR-RKJRWTFHSA-N sodium;(2r)-2-[(2r)-3,4-dihydroxy-5-oxo-2h-furan-2-yl]-2-hydroxyethanolate Chemical compound [Na+].[O-]C[C@@H](O)[C@H]1OC(=O)C(O)=C1O RBWSWDPRDBEWCR-RKJRWTFHSA-N 0.000 description 1
- 235000019408 sucralose Nutrition 0.000 description 1
- BAQAVOSOZGMPRM-QBMZZYIRSA-N sucralose Chemical compound O[C@@H]1[C@@H](O)[C@@H](Cl)[C@@H](CO)O[C@@H]1O[C@@]1(CCl)[C@@H](O)[C@H](O)[C@@H](CCl)O1 BAQAVOSOZGMPRM-QBMZZYIRSA-N 0.000 description 1
- -1 sugar Chemical class 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 239000003765 sweetening agent Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
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- Non-Alcoholic Beverages (AREA)
Abstract
Description
本発明は、褐変が抑制され、果汁飲料本来の香味が維持された容器詰め果汁飲料、及びその製造方法、特に、アスコルビン酸カルシウムを用いることで、褐変が抑制され、果汁飲料本来の香味が維持された容器詰め果汁飲料、及びその製造方法を提供することに関する。 The present invention suppresses browning and maintains the original flavor of the fruit juice beverage, and the method for producing the same, and in particular, by using calcium ascorbate, the browning is suppressed and the original flavor of the fruit juice beverage is maintained. The present invention relates to a containerized fruit juice drink and a method for producing the same.
一般的に果汁飲料は、製造時(殺菌時)や流通時において褐変が進行することで商品価値が低下してしまうといった問題がある。その中でも流通時の経時的な褐変は問題であり、また、混濁果汁、特に混濁りんご果汁や混濁ホワイトグレープフルーツ果汁など乳白色系の混濁果汁を使用した場合は、褐変が目立ちやすく、商品価値が著しく低下してしまう。 In general, fruit juice beverages have a problem that the commercial value is lowered by browning during production (sterilization) and distribution. Of these, browning over time during distribution is a problem, and when using milky white cloudy juices such as cloudy juices, especially cloudy apple juices and cloudy white grapefruit juices, browning is noticeable and the commercial value is significantly reduced. Resulting in.
食品の褐変には、酵素的褐変と非酵素的褐変があるといわれている。酵素的褐変の例としては、ポリフェノールオキシダーゼの作用による褐変が、非酵素的褐変の例としては、メイラード反応による褐変が挙げられる。容器詰め果汁飲料は、一般的に、加熱殺菌により予め酵素を失活させた原料果汁を用いて製造されることから、酵素的褐変が起こる可能性は低い。したがって、容器詰め果汁飲料の褐変については、多くの場合、後者の非酵素的褐変が問題となる。 It is said that browning of food includes enzymatic browning and non-enzymatic browning. Examples of enzymatic browning include browning due to the action of polyphenol oxidase, and examples of non-enzymatic browning include browning due to Maillard reaction. Container-packed fruit juice beverages are generally produced using raw fruit juice in which the enzyme has been previously deactivated by heat sterilization, so that the possibility of enzymatic browning is low. Accordingly, in many cases, the latter non-enzymatic browning becomes a problem with respect to browning of the container-packed fruit juice beverage.
酵素的褐変の抑制方法としては、混濁りんご果汁の搾汁時(製造時)にアスコルビン酸などの酸化防止剤を添加する方法が一般的に知られているが、非酵素的褐変の抑制方法としても、アスコルビン酸やアスコルビン酸ナトリウムといった酸化防止剤を添加する方法が知られている(「最新ソフトドリンクス」(社)全国清涼飲料工業会/(財)日本炭酸飲料検査協会 監修 P196-198)。しかしながら、アスコルビン酸やアスコルビン酸ナトリウムの添加量が少ない場合、期待する効果が得られず、また、効果を上げるために、添加量を増やすとその量に比例して酸味や塩味が生じてしまい、香味への悪影響が避けられないといった問題がある。 As a method for suppressing enzymatic browning, a method of adding an antioxidant such as ascorbic acid during squeezing of turbid apple juice is generally known. However, as a method for suppressing non-enzymatic browning In addition, methods of adding antioxidants such as ascorbic acid and sodium ascorbate are known ("Previous Soft Drinks" Co., Ltd., National Soft Drink Industry Association / Supervision of Japan Carbonated Beverage Inspection Association P196-198) . However, when the amount of ascorbic acid or sodium ascorbate added is small, the expected effect cannot be obtained, and in order to increase the effect, increasing the amount added causes acidity and salty taste in proportion to the amount, There is a problem that adverse effects on the flavor are inevitable.
一方で、使用条件によっては、添加したアスコルビン酸やアスコルビン酸ナトリウムが酸化されることで逆に褐変が進行することが指摘されている(「最新果汁・果実飲料事典」(社)日本果汁協会 監修 P61-63)。これは、果汁飲料中でアスコルビン酸が酸化されてデヒドロアスコルビン酸となり、更に、これが果汁飲料中のアミノ酸と反応して褐変物質に変化することによるものと考えられている。 On the other hand, depending on the use conditions, it has been pointed out that the browning proceeds on the contrary when the added ascorbic acid and sodium ascorbate are oxidized (supervised by the Japan Fruit Juice Association) P61-63). This is considered to be due to the ascorbic acid being oxidized in the fruit juice beverage to dehydroascorbic acid, which further reacts with the amino acid in the fruit juice beverage to turn into a browning substance.
アスコルビン酸の上記反応による褐変を抑制するために、アスコルビン酸やアスコルビン酸ナトリウムのようなアスコルビン酸類を含む果汁飲料にアスコルビン酸類以外の特定の物質を添加する方法が提案されている。例えば、特開平5−103647号公報では、アスコルビン酸やアスコルビン酸ナトリウムのようなアスコルビン酸類と、こうじ酸を添加し、果汁飲料の経時的な褐変を抑制する方法が開示されている。しかしながら、果汁飲料にとって通常馴染みのないこうじ酸のような添加物を使用することは、近年、高まりつつある消費者の自然志向に反するものであり、消費者の印象として好ましいものとはいえないという問題がある。 In order to suppress browning due to the above reaction of ascorbic acid, a method of adding a specific substance other than ascorbic acid to a fruit juice beverage containing ascorbic acid such as ascorbic acid or sodium ascorbate has been proposed. For example, JP-A-5-103647 discloses a method for suppressing browning of a fruit juice beverage over time by adding ascorbic acid such as ascorbic acid or sodium ascorbate and kojic acid. However, the use of additives such as kojic acid, which are usually unfamiliar to fruit juice beverages, is contrary to the increasing natural orientation of consumers in recent years and cannot be said to be a favorable consumer impression. There's a problem.
ところで、近年、健康志向の高まりから、果汁飲料においてもカルシウムを強化した果汁飲料が提供されている。例えば、特表2004−530424号公報には、水酸化カルシウム、炭酸カルシウム、酸化カルシウム、グルコン酸カルシウム、アスコルビン酸カルシウム、アスパラギン酸カルシウムのようなカルシウムを含有する塩基を、約1〜20重量/重量%、好ましくは約5〜15重量/重量%添加したカルシウム強化果汁飲料の沈殿を防止するために、クエン酸、フマル酸、リンゴ酸等の酸を添加して、pHを3.5〜5.3に調整する方法が開示されている。 By the way, in recent years, fruit juice beverages in which calcium is fortified are also provided in fruit juice beverages due to the increase in health consciousness. For example, JP-T-2004-530424 discloses a base containing calcium such as calcium hydroxide, calcium carbonate, calcium oxide, calcium gluconate, calcium ascorbate, calcium aspartate, about 1 to 20 weight / weight. %, Preferably about 5-15 wt / wt%, to prevent precipitation of calcium-enriched fruit juice beverages, an acid such as citric acid, fumaric acid, malic acid or the like is added to adjust the pH to 3.5-5. 3 is disclosed.
カルシウム強化果汁飲料においては、更に、アスコルビン酸や、アスコルビン酸ナトリウムのようなアスコルビン酸塩を添加、含有するものも提供されているが、添加したカルシウムが褐変の進行を促進することが指摘されている。そこで、該カルシウム強化果汁飲料においては、特定の物質を添加する或いは特定の物質の添加によりpHを調整することで褐変を抑制する方法が提案されている。 In calcium-fortified fruit juice drinks, ascorbic acid and ascorbate such as sodium ascorbate are also added and contained, but it has been pointed out that added calcium promotes the progress of browning. Yes. Therefore, in the calcium-fortified fruit juice drink, a method of suppressing browning by adding a specific substance or adjusting pH by adding a specific substance has been proposed.
例えば、特開平7−327648号公報には、カルシウム及びアスコルビン酸含有果汁飲料において、エリソルビン酸の添加が褐変を遅らせることを見出し、カルシウム、アスコルビン酸及びエリソルビン酸を特定濃度となるよう添加することにより、褐変を抑制したカルシウム及びアスコルビン酸含有果汁飲料が開示されている。また、特開平6−133743号公報には、乳酸カルシウムやグルコン酸カルシウムのようなカルシウム塩を添加したカルシウム強化りんご果汁飲料の褐変を防止するために、アスコルビン酸ナトリウム又はエリソルビン酸ナトリウム等を添加して、該カルシウム強化りんご果汁飲料のpHを4.0〜4.3に調整する方法が開示されている。しかしながら、これらの方法については、添加物による香味への悪影響が懸念される他、前述のこうじ酸同様、果汁飲料にとって通常馴染みのないエリソルビン酸の使用が、消費者の印象として好ましいものとはいえないという問題がある。 For example, in JP-A-7-327648, in fruit juice beverages containing calcium and ascorbic acid, it is found that the addition of erythorbic acid delays browning, and by adding calcium, ascorbic acid and erythorbic acid to a specific concentration In addition, calcium and ascorbic acid-containing fruit juice drinks that suppress browning are disclosed. In addition, in JP-A-6-133743, sodium ascorbate or sodium erythorbate is added in order to prevent browning of a calcium-fortified apple juice drink to which a calcium salt such as calcium lactate or calcium gluconate is added. A method of adjusting the pH of the calcium-fortified apple juice drink to 4.0 to 4.3 is disclosed. However, for these methods, there is a concern about the adverse effects on the flavor caused by the additives, and like the above-mentioned kojic acid, the use of erythorbic acid, which is usually unfamiliar to fruit juice drinks, may be preferable as a consumer impression. There is no problem.
以上のとおり、果汁飲料の褐変の抑制方法としては、これまでに各種の方法が開示されているが、褐変を抑制しつつ、果汁飲料にとって重要な要素である果汁飲料本来の香味を維持し、更には消費者の自然志向にも応えるという観点からは、検討の余地があるものであった。 As described above, various methods have been disclosed so far as the method for suppressing the browning of the fruit juice beverage, while maintaining the original flavor of the fruit juice beverage, which is an important element for the fruit juice beverage, while suppressing the browning, Furthermore, there was room for examination from the viewpoint of responding to the natural orientation of consumers.
本発明の課題は、褐変が抑制され、果汁飲料本来の香味が維持された容器詰め果汁飲料、及びその製造方法を提供することにある。 The subject of this invention is providing the container-packed fruit juice drink by which browning was suppressed and the original flavor of fruit juice drink was maintained, and its manufacturing method.
本発明者は、上記課題を解決すべく、鋭意検討する中で、容器詰め果汁飲料の製造において、アスコルビン酸カルシウムを果汁飲料全量に対して特定の割合となるように配合させることにより、容器詰め飲料の褐変を抑制することができ、また、香味への影響を極力抑えて、果汁飲料本来の香味を維持することが可能であることを見出し、本発明を完成するに至った。 In order to solve the above-mentioned problems, the present inventor has intensively studied, and in the production of a container-packed fruit juice beverage, by mixing calcium ascorbate at a specific ratio with respect to the total amount of the fruit juice drink, It has been found that the browning of the beverage can be suppressed, and the original flavor of the fruit juice beverage can be maintained while suppressing the influence on the flavor as much as possible, and the present invention has been completed.
すなわち本発明は、アスコルビン酸カルシウムを、果汁飲料全量に対して0.05〜1重量%配合させることにより、褐変が抑制され、果汁飲料本来の香味が維持された容器詰め果汁飲料からなる。本発明の容器詰め果汁飲料は、特に容器詰め果汁飲料の流通時における経時的な褐変を効果的に抑制することができる。 That is, the present invention comprises a container-packed fruit juice in which browning is suppressed and the original flavor of the fruit juice drink is maintained by incorporating calcium ascorbate in an amount of 0.05 to 1% by weight based on the total amount of the fruit juice drink. The container-packed fruit juice beverage of the present invention can effectively suppress browning over time particularly when the container-packed fruit drink is distributed.
本発明を検討するにあたり、(1)従来、果汁飲料の褐変を抑制するためには、アスコルビン酸や、アスコルビン酸ナトリウムのようなアスコルビン酸塩を添加する方法が知られていたが、褐変を効果的に抑制するためには、酸味や塩味等、香味への悪影響が避けられないこと(2)果汁飲料へのアスコルビン酸や、アスコルビン酸ナトリウムのようなアスコルビン酸塩の添加は、使用条件によっては、アスコルビン酸自身の酸化によって褐変物質が生成され、逆に褐変を進行させること(3)果汁飲料にカルシウムを添加したカルシウム強化果汁飲料においては、カルシウムが褐変の進行を促進してしまうこと(4)一般的にカルシウム塩は独特の香味を有するため、飲料においては、カルシウム強化などの目的以外には使用されることが少ないこと、等を踏まえると、果汁飲料へのアスコルビン酸やカルシウムの添加は、褐変の進行や香味へ悪影響を及ぼす可能性が考えられたが、検討を重ねる中で、果汁飲料にアスコルビン酸カルシウムとして、果汁飲料全量に対して特定の割合となるように配合させることにより、果汁飲料の褐変を効果的に抑制することができること、及び、アスコルビン酸カルシウムの該配合濃度では、果汁飲料の香味への影響を極力抑えて、果汁飲料本来の香味を維持することが可能であることを見出し、本発明をなすに至った。 In examining the present invention, (1) In order to suppress browning of fruit juice beverages, a method of adding ascorbic acid or ascorbate such as sodium ascorbate has been known. (2) Addition of ascorbic acid or ascorbate such as sodium ascorbate to fruit juice depending on the conditions of use. The browning substance is generated by the oxidation of ascorbic acid itself, and on the contrary, the browning proceeds (3) In the calcium-enriched fruit juice beverage in which calcium is added to the fruit juice beverage, the calcium promotes the progress of the browning (4 ) In general, calcium salt has a unique flavor, so it can be used in beverages for purposes other than calcium enrichment. In light of this, the addition of ascorbic acid and calcium to juice drinks could have a negative impact on the browning and flavor. In addition, by blending so as to be a specific ratio with respect to the total amount of the fruit juice beverage, browning of the fruit juice beverage can be effectively suppressed, and at the blending concentration of calcium ascorbate, the flavor of the fruit juice beverage The present inventors have found that it is possible to suppress the influence as much as possible and maintain the original flavor of the fruit juice beverage, and have made the present invention.
本発明の容器詰め果汁飲料におけるpHは3.0以上4.6未満に調整することが好ましい。本発明の容器詰め果汁飲料は、各種果汁飲料に適用して、褐変の抑制と果汁飲料本来の香味を維持した容器詰め果汁飲料として提供することができるが、経時的な褐変が進行することで商品価値を低下させてしまうといった問題が特に顕著な混濁りんご果汁や混濁ホワイトグレープフルーツ果汁など乳白色系の混濁果汁を使用した場合に適用して、その顕著な改善効果を得た商品として提供することができる。 It is preferable to adjust pH in the container stuffed fruit juice drink of this invention to 3.0 or more and less than 4.6. The container-packed fruit juice beverage of the present invention can be applied to various fruit juice drinks and can be provided as a container-packed fruit juice beverage that maintains the original flavor of the fruit juice beverage while suppressing browning. It can be applied to milky white turbid juices such as turbid apple juice and turbid white grapefruit juice, which are particularly problematic in reducing product value, and can be provided as a product that has achieved a significant improvement effect. it can.
本発明は、容器詰め果汁飲料の製造において、アスコルビン酸カルシウムを、果汁飲料全量に対して0.05〜1重量%配合することからなる褐変の抑制と果汁飲料本来の香味を維持した容器詰め果汁飲料の製造方法の発明を包含する。また、本発明は、容器詰め果汁飲料において、アスコルビン酸カルシウムを、果汁飲料全量に対して0.05〜1重量%配合することからなる容器詰め果汁飲料の褐変の抑制と果汁飲料本来の香味を維持する方法の発明を包含する。 In the production of a container-packed fruit juice, the present invention is a container-packed fruit juice that suppresses browning and maintains the original flavor of the fruit drink by mixing calcium ascorbate in an amount of 0.05 to 1% by weight with respect to the total amount of the fruit drink. The invention of the manufacturing method of a drink is included. In addition, the present invention provides a container-packed juice drink that suppresses the browning of the container-packed fruit drink and contains the original flavor of the fruit juice drink by mixing calcium ascorbate in an amount of 0.05 to 1% by weight with respect to the total amount of the fruit juice drink. The invention of the method of maintaining is included.
すなわち具体的には本発明は、(1)アスコルビン酸カルシウムを配合させることにより褐変が抑制された容器詰め果汁飲料や、(2)アスコルビン酸カルシウムを、果汁飲料全量に対して0.05〜1重量%配合させることを特徴とする上記(1)記載の容器詰め果汁飲料や、(3)果汁飲料のpHを3.0以上4.6未満に調整したことを特徴とする上記(1)又は(2)記載の容器詰め果汁飲料や、(4)使用する果汁が、混濁果汁であることを特徴とする上記(1)〜(3)のいずれか記載の容器詰め果汁飲料や、(5)容器詰め果汁飲料の製造において、アスコルビン酸カルシウムを、果汁飲料全量に対して0.05〜1重量%配合したことを特徴とする褐変が抑制された容器詰め果汁飲料の製造方法や、(6)容器詰め果汁飲料において、アスコルビン酸カルシウムを、果汁飲料全量に対して0.05〜1重量%配合したことを特徴とする容器詰め果汁飲料の褐変を抑制する方法からなる。 That is, the present invention specifically relates to (1) container-packed fruit juice in which browning is suppressed by adding calcium ascorbate, and (2) calcium ascorbate to 0.05 to 1 with respect to the total amount of fruit drink. (1) or (1) or (3) above, wherein the pH of the container-packed fruit drink described in (1) above or (3) the fruit juice drink is adjusted to 3.0 or more and less than 4.6. (2) The container-packed fruit juice beverage according to (2), (4) the container-packed fruit juice drink according to any one of (1) to (3) above, wherein the fruit juice used is turbid fruit juice, or (5) In the manufacture of container-packed fruit juice beverages, a method for producing a container-packed fruit juice drink in which browning is suppressed, characterized in that calcium ascorbate is blended in an amount of 0.05 to 1% by weight based on the total amount of the fruit juice drink, (6) Containerized fruit juice drink Fraud and mitigating risk calcium ascorbate comprises a method of inhibiting browning of packaged fruit juice beverage characterized in that it is blended 0.05% by weight relative to the juice the total amount.
本発明により、容器詰め果汁飲料において特に問題となる流通時の経時的な褐変を効果的に抑制し、果汁飲料本来の香味を維持した容器詰め果汁飲料、及びその製造方法を提供する。 According to the present invention, a container-packed fruit juice that effectively suppresses browning over time during distribution, which is a particular problem in container-packed fruit drinks, and maintains the original flavor of the fruit drink, and a method for producing the same are provided.
本発明は、アスコルビン酸カルシウムを、果汁飲料全量に対して0.05〜1重量%配合させることにより、褐変が抑制され、果汁飲料本来の香味が維持された容器詰め果汁飲料、及び該容器詰め果汁飲料を製造する方法からなる。 The present invention is a container-packed fruit juice beverage in which browning is suppressed and the original flavor of the fruit juice drink is maintained by adding calcium ascorbate to 0.05 to 1% by weight with respect to the total amount of the fruit juice beverage, and the container filling It consists of the method of manufacturing a fruit juice drink.
本発明における容器詰め果汁飲料とは、果汁を使用した容器詰め飲料全般を指し、果汁の含有率については特に限定されないが、本発明が特に有効に適用される果汁含有率としては、10%以上である。 The container-packed fruit juice in the present invention refers to all container-packed drinks using fruit juice, and the content ratio of fruit juice is not particularly limited, but the fruit juice content ratio to which the present invention is particularly effectively applied is 10% or more. It is.
本発明の容器詰め果汁飲料に使用する原料果汁の種類(グレープフルーツ、レモン、ライム、ウメ、りんご、もも、バナナ、マンゴー、オレンジ、パインアップルなど)、性状・状態(透明/混濁、濃縮/非濃縮など)は、特に限定されないが、本発明が特に有効に適用される原料果汁としては、混濁果汁であり、より有効に適用される原料果汁としては、乳白色系の混濁果汁であり、更に有効に適用される原料果汁としては、混濁りんご果汁、混濁グレープフルーツ果汁である。また、これらは、単独或いは2種類以上を組み合わせて使用することができる。 Types of raw fruit juice used in the containerized fruit juice beverage of the present invention (grapefruit, lemon, lime, plum, apple, peach, banana, mango, orange, pineapple, etc.), properties and conditions (transparent / turbid, concentrated / non-condensed) Concentration, etc.) is not particularly limited, but the raw material juice to which the present invention is particularly effectively applied is a turbid fruit juice, and the raw material juice to which the present invention is more effectively applied is a milky white turbid fruit juice, and further effective The raw material juices applied to the above are turbid apple juice and turbid grapefruit juice. Moreover, these can be used individually or in combination of 2 or more types.
本発明において配合するアスコルビン酸カルシウムの添加率は、使用する原料果汁の種類や含有率にもよるが、果汁飲料全量に対して、0.05〜1重量%又は、0.05以上1重量%未満である。より好ましくは、0.2〜0.8重量%である。アスコルビン酸カルシウムの添加率が0.05重量%より少ない場合は、優れた褐変抑制効果が期待できず、1重量%より多い場合は、アスコルビン酸カルシウム自体の香味の影響が大きくなり、果汁飲料本来の香味が損なわれる。また、酸味も弱く感じられるようになるため、香味上好ましくない。 The addition rate of calcium ascorbate to be blended in the present invention is 0.05 to 1% by weight or 0.05 to 1% by weight with respect to the total amount of the fruit juice beverage, although it depends on the type and content of the raw material juice used. Is less than. More preferably, it is 0.2 to 0.8% by weight. When the addition rate of calcium ascorbate is less than 0.05% by weight, an excellent browning inhibitory effect cannot be expected, and when it is more than 1% by weight, the influence of the flavor of calcium ascorbate itself increases, The flavor of is impaired. Moreover, since the acidity is felt weak, it is not preferable in terms of flavor.
本発明における容器詰め果汁飲料のpHは、使用する原料果汁の種類や含有率にもよるが、3.0以上4.6未満に調整されることが好ましく、より好ましくは、3.5以上4.6未満である。pHが3.0より低い場合は、アスコルビン酸カルシウム添加による優れた褐変抑制効果が期待できず、pHが4.6以上の場合は、微生物増殖危害の観点から殺菌強度を上げる必要性があり、殺菌処理により褐変が進行する他、果汁飲料本来の香味への悪影響も懸念される。 The pH of the container-packed fruit juice in the present invention is preferably adjusted to 3.0 or more and less than 4.6, more preferably 3.5 or more and 4 although it depends on the type and content of the raw fruit juice used. Less than .6. If the pH is lower than 3.0, an excellent browning suppression effect due to the addition of calcium ascorbate cannot be expected. If the pH is 4.6 or more, it is necessary to increase the bactericidal strength from the viewpoint of microbial growth hazard. In addition to the progress of browning by sterilization, there is a concern about the adverse effect on the original flavor of fruit juice drinks.
本発明における容器詰め果汁飲料は、アスコルビン酸カルシウムを果汁飲料全量に対して特定の割合で配合し、容器詰め果汁飲料の褐変の抑制を図る他、その他の添加物については、通常、容器詰め果汁飲料の製造に際して用いられる添加物を適宜添加することができる。例えば、甘み付与のために砂糖、果糖、ブドウ糖などの糖類やアセスルファムカリウム、スクラロース、ステビア、アスパルテーム、ネオテームなどの高甘味度甘味料、酸味付与のためにクエン酸、リンゴ酸、酒石酸などの酸味料、色調調整のためにカロテノイド系、アントシアニン系などの着色料、香り付与のために香料、爽快感付与のために二酸化炭素などを添加することができる。また、ビタミン類などの栄養素も必要に応じて、適宜添加することができる。 The container-packed fruit juice in the present invention contains calcium ascorbate in a specific ratio with respect to the total amount of the fruit juice drink, and aims to suppress browning of the container-packed fruit drink. Additives used in the production of beverages can be added as appropriate. For example, sugars such as sugar, fructose, and glucose for imparting sweetness, high sweetness sweeteners such as acesulfame potassium, sucralose, stevia, aspartame, and neotame, and acidulants such as citric acid, malic acid, and tartaric acid for imparting sourness Further, a colorant such as carotenoid or anthocyanin for color tone adjustment, a fragrance for imparting fragrance, or carbon dioxide for imparting a refreshing feeling can be added. In addition, nutrients such as vitamins can be added as needed.
本発明における容器詰果汁飲料の製造方法は、果汁を使用した飲料に通常適用される製造方法に従って行われ(「最新ソフトドリンクス」(社)全国清涼飲料工業会/(財)日本炭酸飲料検査協会 監修 P330-364)、適宜、PETボトル、缶、壜、紙などの容器に充填して、商品化することができる。 The method for producing a containerized fruit juice drink according to the present invention is carried out in accordance with a production method usually applied to drinks using fruit juice ("Latest Soft Drinks" (National Soft Drinks Industry Association / Japan Carbonated Beverage Inspection). Supervised by the Association P330-364), can be commercialized by filling containers such as PET bottles, cans, bottles, and papers as appropriate.
本発明における褐変の抑制効果については、パネラーによる官能評価の他、L*a*b*を用いて評価を行うことができる。L*は色の明るさを示し、a*及びb*は色の方向(+a*は赤方向、−a*は緑方向、+b*は黄方向、−b*は青方向)を示す。 About the browning suppression effect in this invention, it can evaluate using L * a * b * other than the sensory evaluation by a panelist. L * indicates the brightness of the color, and a * and b * indicate the color direction (+ a * is the red direction, -a * is the green direction, + b * is the yellow direction, and -b * is the blue direction).
以下、実施例により本発明をより具体的に説明するが、本発明の技術的範囲はこれらの例示に限定されるものではない。 EXAMPLES Hereinafter, although an Example demonstrates this invention more concretely, the technical scope of this invention is not limited to these illustrations.
(アスコルビン酸の種類による褐変抑制効果及び香味への影響確認)
配合1−1〜配合1−4の原料についてそれぞれ混合・加熱殺菌した液が容器に充填されたものをサンプルとした(表1)。保存開始前及び5℃・50℃でそれぞれ10日保存したサンプルについて、パネラー5名にて、外観(色調)・香味について官能評価を実施した。外観(色調)評価(*1)及び香味評価(*2)は、表2の評価基準を用いて行い、評価点を平均化した。また、同サンプルについて、L*a*b* (L*a*b*測定機器:ミノルタ株式会社製分光測色計)及びpHを測定した。L*a*b*の中から、外観(色調)変化の指標として、a*を選定し、配合1−1の保存開始前サンプルを対照にその他サンプルとの差(△(デルタ)a*)を算出した。結果を以下に示す。(表3)
(Confirmation of browning-inhibiting effect and flavor on ascorbic acid type)
Samples prepared by mixing and heat-sterilizing the ingredients 1-1 to 1-4 were filled in containers (Table 1). About the sample preserve | saved for 10 days at 5 degreeC and 50 degreeC, respectively before storage start, sensory evaluation was implemented about the external appearance (color tone) and flavor by five panelists. Appearance (color tone) evaluation (* 1) and flavor evaluation (* 2) were performed using the evaluation criteria in Table 2, and the evaluation points were averaged. Further, L * a * b * (L * a * b * measuring instrument: spectrocolorimeter manufactured by Minolta Co., Ltd.) and pH of the sample were measured. A * is selected from L * a * b * as an index of appearance (color tone) change, and the difference from the other samples (△ (delta) a * ) is compared with the sample before the start of storage of Formulation 1-1. Was calculated. The results are shown below. (Table 3)
官能評価(外観(色調))について、配合1−1〜配合1−4の保存開始前及び5℃10日保存品ではいずれも良好であった。50℃10日保存品ではいずれも褐変が確認されたが、配合1−1が最も褐変しており、次いで配合1−2が、最後に同レベルで配合1−3と配合1−4が続いた。官能評価(香味)について、配合1−1の保存開始前及び5℃10日保存品では良好であった。配合1−2は酸味の増加、配合1−3は酸味の低下と塩味の付加、配合1−4は酸味の低下が確認されたが、これらの中では配合1−4の香味が比較的良好であった。50℃10日保存品では保存開始前及び5℃10日保存品で確認された傾向に加え、いずれもフレッシュ感の低下が確認されたが、配合1−1は特にフレッシュ感の低下が大きかった。 With respect to sensory evaluation (appearance (color tone)), the pre-storage preservation of Formulation 1-1 to Formulation 1-4 and the product stored at 5 ° C. for 10 days were all good. Although browning was confirmed in all products stored at 50 ° C. for 10 days, Formulation 1-1 was the most browned, followed by Formulation 1-2, followed by Formulation 1-3 and Formulation 1-4 at the same level. It was. About sensory evaluation (flavor), it was favorable in the pre-storage preservation | save of the mixing | blending 1-1, and a 5 degreeC 10 day storage goods. Formulation 1-2 increased acidity, Formulation 1-3 decreased acidity and added saltiness, and Formulation 1-4 decreased acidity, but among these, the flavor of Formulation 1-4 was relatively good Met. In addition to the tendency confirmed in the product stored at 50 ° C. for 10 days before storage and the product stored at 5 ° C. for 10 days, a decrease in the fresh feeling was confirmed in all cases, but in Formulation 1-1, the decrease in the fresh feeling was particularly large. .
△a*について、配合1−1の保存開始前と比較し、配合1−1の5℃10日保存品、配合1−2〜配合1−4の保存開始前及び5℃10日保存品ではいずれも大きな変化はなかった。50℃10日保存品ではいずれも増加したが、配合1−1の値が最も高く、次いで配合1−2が、最後にほぼ同値で配合1−3と配合1−4が続いた。 About △ a * , compared to before storage start of formulation 1-1, 5 ° C 10 day storage product of formulation 1-1, before storage start of formulation 1-2 to formulation 1-4 and 5 ° C 10 day storage product None of them changed significantly. In the products stored at 50 ° C. for 10 days, both values increased, but the value of Formulation 1-1 was the highest, followed by Formulation 1-2, and finally Formulation 1-3 and Formulation 1-4 followed by almost the same value.
(アスコルビン酸カルシウムの添加率違いによる褐変抑制効果及び香味への影響確認)
配合2−1〜配合2−8の原料についてそれぞれ混合・加熱殺菌した液が容器に充填されたものをサンプルとした(表4)。保存開始前及び5℃・50℃でそれぞれ10日保存したサンプルについて、パネラー5名にて、外観(色調)・香味について官能評価を実施した。外観(色調)評価(*3)及び香味評価(*4)は、表5の評価基準を用いて行い、評価点を平均化した。また、同サンプルについて、L*a*b* (L*a*b*測定機器:ミノルタ株式会社製分光測色計)及びpHを測定した。L*a*b*の中から、外観(色調)変化の指標として、a*を選定し、配合2−1の保存開始前サンプルを対照にその他サンプルとの差(△a*)を算出した。結果を以下に示す。(表6)
(Confirmation of browning suppression effect and flavor effect due to difference in calcium ascorbate addition rate)
Samples prepared by mixing and heat-sterilizing the raw materials of Formulation 2-1 to Formulation 2-8 were filled in containers (Table 4). About the sample preserve | saved for 10 days at 5 degreeC and 50 degreeC, respectively before storage start, sensory evaluation was implemented about the external appearance (color tone) and flavor by five panelists. Appearance (color tone) evaluation (* 3) and flavor evaluation (* 4) were performed using the evaluation criteria in Table 5, and the evaluation points were averaged. Further, L * a * b * (L * a * b * measuring instrument: spectrocolorimeter manufactured by Minolta Co., Ltd.) and pH of the sample were measured. From L * a * b * , a * was selected as an index of appearance (color tone) change, and the difference from the other samples (Δa * ) was calculated using the pre-storage sample of Formulation 2-1 as a control. . The results are shown below. (Table 6)
官能評価(外観(色調))について、配合2−1〜配合2−8の保存開始前及び5℃10日保存品ではいずれも良好であった。50℃10日保存品ではいずれも褐変が確認されたが、配合2−1と配合2−2が最も褐変しており、配合2−3〜配合2−8はアスコルビン酸カルシウムの添加率が高くなるにつれ、その程度に差異はあるもののいずれも褐変が抑制されていることが確認された。官能評価(香味)について、配合2−1と配合2−2の保存開始前及び5℃10日保存品では良好であった。配合2−3〜配合2−8はアスコルビン酸カルシウムの添加率が高くなるにつれ、その程度に差異はあるもののいずれも酸味の低下が、さらに配合2−7と配合2−8はえぐみの付加が確認された。50℃10日保存品では保存開始前及び5℃10日保存品で確認された傾向に加え、いずれもフレッシュ感の低下が確認されたが、配合2−1と配合2−2は特にフレッシュ感の低下が大きかった。 With respect to sensory evaluation (appearance (color tone)), all of the products prior to the start of storage of Formulation 2-1 to Formulation 2-8 and those stored at 5 ° C. for 10 days were good. Although browning was confirmed in all products stored at 50 ° C. for 10 days, Formulation 2-1 and Formulation 2-2 were most browned, and Formulation 2-3 to Formulation 2-8 had a high addition rate of calcium ascorbate. As it turned out, it was confirmed that browning was suppressed in all cases although there was a difference in the degree. About sensory evaluation (flavor), it was favorable in the pre-storage preservation | save of the mixing | blending 2-1 and the mixing | blending 2-2, and a 5 degreeC 10 day storage goods. As for the compound 2-3 to the compound 2-8, as the addition rate of calcium ascorbate increases, the degree of sourness decreases, although there is a difference in the degree of the addition. Was confirmed. In addition to the tendency confirmed in the products stored at 50 ° C. for 10 days before storage and the products stored at 5 ° C. for 10 days, both of them showed a decrease in freshness. However, Formulation 2-1 and Formulation 2-2 were particularly fresh. The drop in was large.
△a*について、配合2−1の保存開始前と比較し、配合2−1の5℃10日保存品、配合2−2〜配合2−8の保存開始前及び5℃10日保存品ではいずれも大きな変化はなかった。50℃10日保存品ではいずれも増加したが、配合2−1と配合2−2の値が高く、配合2−3〜配合2−8はアスコルビン酸カルシウムの添加率が高くなるにつれ、その値が低くなる傾向にあった。 About Δa * , compared to before storage start of Formulation 2-1, 5 ° C 10 day storage product of Formulation 2-1, Formulation 2-2 to Formulation 2-8 before storage start and 5 ° C 10 day storage product None of them changed significantly. Although it increased in all products stored at 50 ° C. for 10 days, the values of Formulation 2-1 and Formulation 2-2 were high, and the values of Formulation 2-3 to Formulation 2-8 increased as the calcium ascorbate addition rate increased. Tended to be lower.
(使用果汁の種類の違いによるアスコルビン酸カルシウムの褐変抑制効果及び香味への影響確認)
配合3−1〜配合3−3、配合3−1’〜配合3−3’の原料についてそれぞれ混合・加熱殺菌した液が容器に充填されたものをサンプルとした(表7)。保存開始前及び5℃・50℃でそれぞれ10日保存したサンプルについて、パネラー5名にて、外観(色調)・香味について官能評価を実施した。外観(色調)評価(*5)及び香味評価(*6)は、表8の評価基準を用いて行い、評価点を平均化した。また、同サンプルについて、L*a*b* (L*a*b*測定機器:ミノルタ株式会社製分光測色計)及びpHを測定した。L*a*b*の中から、外観(色調)変化の指標として、配合3−1と配合3−1’においては、a*を、配合3−2と配合3−2’、配合3−3と配合3−3’においては、b*を選定し、それぞれ配合3−1〜配合3−3の保存開始前サンプルを対照にその他サンプルとの差(△a*あるいは△b*)を算出した。結果を以下に示す(表9)。
(Confirmation of browning inhibitory effect of calcium ascorbate and the effect on flavor depending on the type of fruit juice used)
Samples prepared by mixing and heat-sterilizing the raw materials of Formulation 3-1 to Formulation 3-3 and Formulation 3-1 ′ to Formulation 3-3 ′, respectively, in containers were used as samples (Table 7). About the sample preserve | saved for 10 days at 5 degreeC and 50 degreeC, respectively before storage start, sensory evaluation was implemented about the external appearance (color tone) and flavor by five panelists. Appearance (color tone) evaluation (* 5) and flavor evaluation (* 6) were performed using the evaluation criteria in Table 8, and the evaluation points were averaged. Further, L * a * b * (L * a * b * measuring instrument: spectrocolorimeter manufactured by Minolta Co., Ltd.) and pH of the sample were measured. As an index of appearance (color tone) change from L * a * b * , in Formulation 3-1 and Formulation 3-1 ′, a * is Formulation 3-2, Formulation 3-2 ′, Formulation 3- 3 and Formulation 3-3 ′, b * is selected, and the difference (Δa * or Δb * ) from the other samples is calculated with reference to the pre-storage samples of Formulation 3-1 to Formulation 3-3, respectively. did. The results are shown below (Table 9).
官能評価(外観(色調))について、配合3−1の保存開始前、配合3−1’の保存開始前及び5℃10日保存品では良好であった。配合3−1の5℃・50℃10日保存品、配合3−1’の50℃10日保存品ではいずれも褐変が確認されたが、配合3−1の50℃10日保存品が最も褐変しており、次いで配合3−1’の50℃10日保存品が、最後に配合3−1の5℃10日保存品が続いた。配合3−2’の保存開始前及び5℃10日保存品では良好であった。配合3−2の保存開始前及び5・50℃10日保存品、配合3−2’の50℃10日保存品ではいずれも褐変が確認されたが、配合3−2の50℃10日保存品が最も褐変しており、次いで同レベルで配合3−2の5℃10日保存品と3−2’の50℃10日保存品が、最後に配合3−2の保存開始前が続いた。配合3−3’の保存開始前及び5℃10日保存品では良好であった。配合3−3の保存開始前及び5・50℃10日保存品、配合3−3’の50℃10日保存品ではいずれも褐変が確認されたが、配合3−3の50℃10日保存品が最も褐変しており、次いで同レベルで配合3−3の5℃10日保存品と3−3’の50℃10日保存品が、最後に配合3−3の保存開始前が続いた。 The sensory evaluation (appearance (color tone)) was good before the start of storage of Formulation 3-1, before the start of storage of Formulation 3-1 ', and at 5 ° C for 10 days. Browning was confirmed in the product of Formulation 3-1, which was stored at 5 ° C / 50 ° C for 10 days, and the product of Formulation 3-1 ', which was stored at 50 ° C for 10 days. The product was browned, followed by the product of Formulation 3-1 ′ stored at 50 ° C. for 10 days, and finally the product of Formulation 3-1 stored at 5 ° C. for 10 days. It was good for the compound 3-2 ′ before storage and for 10 days at 5 ° C. Before the start of storage of Formulation 3-2 and at 5 · 50 ° C. for 10 days, and for Formula 3-2 ′ at 50 ° C. for 10 days, browning was confirmed, but Formulation 3-2 was stored at 50 ° C. for 10 days. The product is the most browned, and then at the same level, the compound 3-2 stored at 5 ° C. for 10 days and the product stored at 3-2 ′ at 50 ° C. for 10 days lastly before the start of storage of the compound 3-2 . It was good for the product of Formulation 3-3 'before storage start and at 5 ° C for 10 days. Before the start of storage of Formulation 3-3 and 5 · 50 ° C for 10 days, and for Formulation 3-3 ′ at 50 ° C for 10 days, browning was confirmed, but Formulation 3-3 was stored at 50 ° C for 10 days. The product was most browned, followed by the product at 5 ° C. for 10 days and the product 3-3 ′ stored at 50 ° C. for 10 days at the same level. .
官能評価(香味)について、配合3−1の保存開始前及び5℃10日保存品では良好であったが、配合3−1’の保存開始前及び5℃10日保存品では酸味の低下が確認された。50℃10日保存品ではいずれもフレッシュ感の低下が確認されたが、配合3−1は配合3−1’よりフレッシュ感の低下が大きかった。配合3−2の保存開始前及び5℃10日保存品では良好であったが、配合3−2’の保存開始前及び5℃10日保存品では酸味の低下が確認された。50℃10日保存品ではいずれもフレッシュ感の低下が確認された。配合3−3の保存開始前及び5℃10日保存品では良好であったが、配合3−3’の保存開始前及び5℃10日保存品では酸味の低下が確認された。50℃10日保存品ではいずれもフレッシュ感の低下が確認されたが、配合3−3は配合3−3’よりフレッシュ感の低下が大きかった。 About sensory evaluation (flavor), it was good before the start of storage of Formulation 3-1 and a product stored at 5 ° C. for 10 days, but the sourness decreased in the product before storage of Formulation 3-1 ′ and stored at 5 ° C. for 10 days. confirmed. A decrease in the fresh feeling was confirmed in all the products stored at 50 ° C. for 10 days, but the decrease in fresh feeling was greater in Formulation 3-1 than in Formulation 3-1 ′. Before the start of storage of Formulation 3-2 and a product stored at 5 ° C. for 10 days, it was good, but a decrease in sourness was confirmed before the start of storage of Formulation 3-2 ′ and a product stored at 5 ° C. for 10 days. A decrease in freshness was confirmed in all products stored at 50 ° C. for 10 days. Before the start of storage of Formulation 3-3 and the product stored at 5 ° C. for 10 days, it was good. However, before the start of storage of Formulation 3-3 ′ and the product stored at 5 ° C. for 10 days, a decrease in sourness was confirmed. A decrease in the fresh feeling was confirmed in the products stored at 50 ° C. for 10 days, but the decrease in the fresh feeling was greater in Formulation 3-3 than in Formulation 3-3 ′.
△a*について、配合3−1の保存開始前と比較し、配合3−1の5℃10日保存品、
配合3−1’の保存開始前及び5℃10日保存品ではいずれも大きな変化はなかった。50℃10日保存品ではいずれも増加したが、配合3−1’は配合3−1の値より低くなった。
△b*について、配合3−2の保存開始前と比較し、配合3−2の5℃10日保存品では大きな変化はなかったが、配合3−2’の保存開始前及び5℃10日保存品ではいずれも減少した。50℃10日保存品ではいずれも増加したが、配合3−2は配合3−2’の値より高くなった。配合3−3の保存開始前と比較し、配合3−3の5・50℃10日保存品ではいずれも減少したが、50℃10日保存品は5℃10日保存品より値が低くなった。配合3−3’の保存開始前及び5・50℃10日保存品ではいずれも増加したが、50℃10日保存品は保存開始前及び5℃10日保存品より値が低くなった。
About △ a * , compared with before the start of storage of Formulation 3-1, 5 ° C 10 day storage product of Formulation 3-1,
There was no big change in the compound 3-1 ′ before the start of storage and the product stored at 5 ° C. for 10 days. In the products stored at 50 ° C. for 10 days, all increased, but the formulation 3-1 ′ was lower than the value of the formulation 3-1.
Δb * was not significantly changed in the product stored at 5 ° C. for 10 days in Formulation 3-2 as compared to that in Formulation 3-2 before storage start, but before the storage start of Formulation 3-2 ′ and at 5 ° C. for 10 days. All of the preserved products decreased. Although all increased in the 50 degreeC 10 day preservation | save goods, the mixing | blending 3-2 became higher than the value of the mixing | blending 3-2 '. Compared to the pre-storage start of Formulation 3-3, all of the products stored at 550 ° C for 10 days of Formulation 3-3 decreased, but the values of the product stored at 50 ° C for 10 days were lower than those stored at 5 ° C for 10 days. It was. Both the pre-storage and pre-storage products at 550 ° C. for 10 days increased in Formulation 3-3 ′, but the values for the storage at 50 ° C. for 10 days were lower than those before the storage start and for storage at 5 ° C. for 10 days.
(pHの違いによるアスコルビン酸カルシウムの褐変抑制効果確認)
配合4−1〜配合4−4の原料についてそれぞれ混合・加熱殺菌した液が容器に充填されたものをサンプルとした(表10)。保存開始前及び5℃・50℃で10日保存したサンプルについて、パネラー5名にて、外観(色調)について官能評価を実施した。外観(色調)評価(*7)は、表11の評価基準を用いて行い、評価点を平均化した。また、同サンプルについて、L*a*b* (L*a*b*測定機器:ミノルタ株式会社製分光測色計)及びpHを測定した。L*a*b*の中から、外観(色調)変化の指標として、a*を選定し、配合4−1の保存開始前サンプルを対照にその他サンプルとの差(△a*)を算出した。結果を以下に示す。(表12)
(Confirmation of browning suppression effect of calcium ascorbate due to pH difference)
Samples prepared by mixing and heat-sterilizing the raw materials of Formulation 4-1 to Formulation 4-4 were filled in containers (Table 10). About the sample preserve | saved for 10 days at 5 degreeC * 50 degreeC before the preservation | save start, sensory evaluation was implemented about the external appearance (color tone) by five panelists. Appearance (color tone) evaluation (* 7) was performed using the evaluation criteria shown in Table 11, and the evaluation points were averaged. Further, L * a * b * (L * a * b * measuring instrument: spectrocolorimeter manufactured by Minolta Co., Ltd.) and pH of the sample were measured. From L * a * b * , a * was selected as an index of appearance (color tone) change, and the difference from the other samples (Δa * ) was calculated with reference to the pre-storage sample of formulation 4-1 . The results are shown below. (Table 12)
官能評価(外観(色調))について、配合4−1〜配合4−4の保存開始前及び5℃10日保存品ではいずれも良好であった。50℃10日保存品ではいずれも褐変が確認されたが、配合4−2が最も褐変しており、次いで配合4−1、配合4−3、配合4−4と続いた。 Regarding sensory evaluation (appearance (color tone)), all of the products before storage start of Formulation 4-1 to Formulation 4-4 and those stored at 5 ° C. for 10 days were good. Although browning was confirmed in all products stored at 50 ° C. for 10 days, Formulation 4-2 was most browned, followed by Formulation 4-1, Formulation 4-3, and Formulation 4-4.
△a*について、配合4−1の保存開始前と比較し、配合4−2〜配合4−4の保存開
始前及び5℃10日保存品ではいずれも大きな変化はなかった。50℃10日保存品ではいずれも増加したが、配合4−2の値が最も高く、次いで配合4−1、配合4−3、配合4−4と続いた。
About (DELTA) a * , compared with before the preservation | save start of the mixing | blending 4-1, there was no big change in all before the storage start of the mixing | blending 4-2 to the mixing | blending 4-4 and a 5 degreeC 10 day storage goods. All of the products stored at 50 ° C. for 10 days increased, but the value of Formulation 4-2 was the highest, followed by Formulation 4-1, Formulation 4-3, and Formulation 4-4.
本発明は、容器詰め果汁飲料において特に問題となる流通時の経時的な褐変を効果的に抑制し、果汁飲料本来の香味を維持した容器詰め果汁飲料、及びその製造方法を提供することができる。
INDUSTRIAL APPLICABILITY The present invention can provide a container-packed fruit juice that effectively suppresses browning over time during distribution, which is a particular problem in container-packed fruit juice drinks, and maintains the original flavor of the fruit juice drink, and a method for producing the same. .
Claims (6)
A method for suppressing browning of a container-packed fruit juice beverage, characterized in that, in a container-packed fruit juice beverage, calcium ascorbate is mixed in an amount of 0.05 to 1% by weight based on the total amount of the fruit juice beverage.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2016042813A (en) * | 2014-08-21 | 2016-04-04 | ポッカサッポロフード&ビバレッジ株式会社 | Non-carbonated beverage, and method for producing the same, and method of inhibiting change in composition of retronasal aroma in non-carbonated beverage |
| JP2016096797A (en) * | 2014-11-25 | 2016-05-30 | アサヒ飲料株式会社 | Turbid fruit juice beverage |
| WO2016189631A1 (en) * | 2015-05-25 | 2016-12-01 | 花王株式会社 | Beer-flavored beverage |
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| JP2016214236A (en) * | 2016-04-05 | 2016-12-22 | 花王株式会社 | Beer taste beverage |
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| JP2016042813A (en) * | 2014-08-21 | 2016-04-04 | ポッカサッポロフード&ビバレッジ株式会社 | Non-carbonated beverage, and method for producing the same, and method of inhibiting change in composition of retronasal aroma in non-carbonated beverage |
| JP2016096797A (en) * | 2014-11-25 | 2016-05-30 | アサヒ飲料株式会社 | Turbid fruit juice beverage |
| WO2016189631A1 (en) * | 2015-05-25 | 2016-12-01 | 花王株式会社 | Beer-flavored beverage |
| JPWO2016189631A1 (en) * | 2015-05-25 | 2017-06-22 | 花王株式会社 | Beer taste drink |
| WO2016203662A1 (en) * | 2015-06-19 | 2016-12-22 | 花王株式会社 | Beer-flavored beverage |
| JP2017018085A (en) * | 2015-06-19 | 2017-01-26 | 花王株式会社 | Beer taste beverage |
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| JP2016214236A (en) * | 2016-04-05 | 2016-12-22 | 花王株式会社 | Beer taste beverage |
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