JP2013060401A - Agricultural pesticide containing biological pesticide and chemical pesticide - Google Patents
Agricultural pesticide containing biological pesticide and chemical pesticide Download PDFInfo
- Publication number
- JP2013060401A JP2013060401A JP2011201170A JP2011201170A JP2013060401A JP 2013060401 A JP2013060401 A JP 2013060401A JP 2011201170 A JP2011201170 A JP 2011201170A JP 2011201170 A JP2011201170 A JP 2011201170A JP 2013060401 A JP2013060401 A JP 2013060401A
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- Prior art keywords
- pesticide
- pseudomonas
- agrochemical
- agricultural
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000126 substance Substances 0.000 title abstract description 22
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- 241001291486 Pseudomonas rhodesiae Species 0.000 claims abstract description 7
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Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
本発明は、農薬に関する。より詳細に、本発明は、化学農薬の使用量を減らしても十分な農薬効力を示し且つ安全性の高い、生物農薬および化学農薬を含有する農薬に関する。 The present invention relates to an agrochemical. More specifically, the present invention relates to a pesticide containing a biological pesticide and a chemical pesticide that exhibits sufficient pesticide efficacy even when the amount of the chemical pesticide used is reduced and is highly safe.
農薬としては、化学農薬、生物農薬などが知られている。化学農薬は、天然または人工的に合成された化合物を含有する農薬である。化学農薬は農園芸作物に寄生する種々の病原菌、害虫等に対して優れた防除効果を示すものが多く、農園芸用殺菌剤、殺虫剤、殺ダニ剤等として広く使用され、農作物の増産に大きく寄与してきた。しかしながら、化学農薬を使用しすぎると、環境に対して影響を与えるおそれがある。また耐性菌や抵抗性害虫が出現し易く、化学農薬の大量使用には制限がある。 Chemical pesticides and biological pesticides are known as pesticides. Chemical pesticides are pesticides that contain natural or artificially synthesized compounds. Many chemical pesticides show excellent control effects against various pathogens and pests parasitic on agricultural and horticultural crops, and are widely used as agricultural and horticultural fungicides, insecticides, acaricides, etc. It has contributed greatly. However, too much chemical pesticide may affect the environment. In addition, resistant bacteria and resistant pests are likely to appear, and there is a limit to the use of large amounts of chemical pesticides.
一方、生物農薬は、微生物を含有する農薬である。生物農薬は、環境汚染が極めて少なく、生態系に調和し、かつ防除効果の優れたものが多い。例えば、トリコデルマ属、シュードモナス属、バチルス属等に属する微生物を用いた生物農薬が挙げられる。しかし、生物農薬は、効力を示す病害の範囲が狭い。また殺菌用生物農薬は予防活性に優れていても治療活性に乏しい。 On the other hand, a biopesticide is a pesticide containing microorganisms. Many biological pesticides have very little environmental pollution, are in harmony with the ecosystem, and have excellent control effects. Examples thereof include biological pesticides using microorganisms belonging to the genus Trichoderma, Pseudomonas, Bacillus and the like. However, biopesticides have a narrow range of diseases that show efficacy. In addition, biocidal pesticides have poor therapeutic activity even though they have excellent preventive activity.
化学農薬と生物農薬のそれぞれの長所と短所とを補うために、生物農薬と化学農薬とを併用することが試みられている。生物農薬に化学農薬を混用した例としては、植物病害防除効果を有するゲオトリクム属糸状菌に、殺菌剤チオファネートメチル、プロシミドン、フルジオキソニル等を併用した例(特許文献1)や、除草効果を有するドレックスレラ属糸状菌に除草剤ハロスルフロンメチルを併用した例(特許文献2)などがある。 In order to make up for the advantages and disadvantages of chemical pesticides and biological pesticides, attempts have been made to use biological pesticides and chemical pesticides in combination. Examples of biochemical pesticides mixed with chemical pesticides include the combination of fungicides thiophanate methyl, procimidone, fludioxonil, etc. with Geotricum filamentous fungi having a plant disease control effect (Patent Document 1), and drex rera spp having a herbicidal effect. Examples include the use of the herbicide halosulfuron methyl in combination with the fungus (Patent Document 2).
しかし、生物農薬は、微生物が生存している状態において、活性を発揮するものが大半である。そのため、生物農薬に、化学農薬、特に殺菌剤や有機溶剤を多量に含有する化学農薬製剤を混用または同時併用すると、生物農薬中の微生物が死滅したり、増殖が抑制されたりして、生物農薬の効力が減殺されることが多い。例えば、細菌を用いた微生物農薬には、オキソリニック酸などの殺菌剤は併用できないことが知られている。具体的には、非病原性エルビニア カロトボラを含有する「バイオキーパー水和剤」(登録商標)は、オキソリニック酸、ストレプトマイシン、トリアジン、フルアジナム、銅剤、乳剤タイプの殺虫剤などと混用できない(非特許文献1)。 However, most biological pesticides exhibit activity when microorganisms are alive. Therefore, when a chemical pesticide, especially a chemical pesticide preparation containing a large amount of bactericides or organic solvents, is mixed or used together with a biopesticide, the microorganisms in the biopesticide are killed or the growth is suppressed. The effectiveness of is often diminished. For example, it is known that microbial pesticides using bacteria cannot be used in combination with bactericides such as oxolinic acid. Specifically, “Biokeeper wettable powder” (registered trademark) containing non-pathogenic erbinia carotobola cannot be mixed with oxolinic acid, streptomycin, triazine, fluazinam, copper, emulsion type insecticides, etc. (non-patented) Reference 1).
本発明の課題は、化学農薬の使用量を減らしても十分な農薬効力を示し且つ安全性の高い、生物農薬および化学農薬を含有する農薬を提供することである。 An object of the present invention is to provide a pesticide containing a biological pesticide and a chemical pesticide that exhibits sufficient pesticide efficacy even when the amount of the chemical pesticide used is reduced and is highly safe.
シュードモナス属に属する微生物で農園芸用殺菌剤として用いられる菌株として、例えば、シュードモナス ロデシア FERM BP−10912(特許文献3)、シュードモナス ロデシア FERM P−21748(特許文献4)等が知られている。シュードモナス ロデシア FERM BP−10912は、ザントモナス属、エルビニア属、シュードモナス属などによる細菌病を中心とする植物病害に効果を示す。シュードモナス ロデシア FERM P−21748は、灰色かび病、うどんこ病、ピシウム病など糸状菌による植物病害に効果を示す。 As strains used as agricultural and horticultural fungicides in microorganisms belonging to the genus Pseudomonas, for example, Pseudomonas rhodesia FERM BP-10912 (patent document 3), Pseudomonas rhodesia FERM P-21748 (patent document 4) and the like are known. Pseudomonas rhodesia FERM BP-10912 is effective for plant diseases such as bacterial diseases caused by Zanthomonas, Erbinia, Pseudomonas and the like. Pseudomonas rhodesia FERM P-21748 has an effect on plant diseases caused by filamentous fungi such as gray mold, powdery mildew, and pyrium.
本発明者は、上記課題を解決するために鋭意検討した結果、農薬活性を有する化合物と、シュードモナス属(Pseudomonas)に属する微生物とを併用すると、化学農薬の使用量が少なくても十分な病害防除などの農薬効力を示し且つ安全性が増すことを見出した。本発明は、この知見に基づいて完成するに至ったものである。 As a result of intensive studies to solve the above problems, the present inventor has found that when a compound having agrochemical activity and a microorganism belonging to the genus Pseudomonas are used in combination, sufficient disease control can be achieved even if the amount of chemical pesticide used is small. It was found that the agrochemical efficacy such as, and the safety is increased. The present invention has been completed based on this finding.
すなわち、本発明は、以下のものを含む。
〔1〕 シュードモナス属(Pseudomonas)に属する微生物と農薬活性を有する化合物とを含有する農薬。
〔2〕 シュードモナス属に属する微生物が植物病害に対する防除能を有する微生物である前記〔1〕に記載の農薬。
〔3〕 シュードモナス属に属する微生物がシュードモナス ロデシア(Pseudomonas rhodesiae)である、前記〔1〕に記載の農薬。
〔4〕 シュードモナス属に属する微生物が、シュードモナス ロデシア FERM BP−10912またはシュードモナス ロデシア FERM BP−10912の変異株である、前記〔1〕に記載の農薬。
That is, the present invention includes the following.
[1] An agrochemical containing a microorganism belonging to the genus Pseudomonas and a compound having an agrochemical activity.
[2] The agrochemical according to [1], wherein the microorganism belonging to the genus Pseudomonas is a microorganism having an ability to control plant diseases.
[3] The agrochemical according to [1], wherein the microorganism belonging to the genus Pseudomonas is Pseudomonas rhodesiae.
[4] The agrochemical according to [1], wherein the microorganism belonging to the genus Pseudomonas is a mutant of Pseudomonas rhodesia FERM BP-10912 or Pseudomonas rhodesia FERM BP-10912.
〔5〕 農薬活性を有する化合物が、ストロビルリン系殺菌剤、カーバメート系殺菌剤、ジカルボキシイミド系殺菌剤、アゾール系殺菌剤、アニライド系殺菌剤、クロロタロニル、メパニピリム、イミノクタジン、シフルフェナミド、ポリオキシン、キノメチオナート、シモキサニル、ベンチアバリカルブ−イソプロピル、マンジプロパミド、アミスルブロム、ファモキサドン、フルオピコリド、オキソリニック酸、 マクロライド系殺虫殺ダニ剤、ニコチノイド系殺虫剤、有機リン系殺虫剤、ピレスロイド系殺虫剤、クロルフェナピル、ビフェナゼート、チアメトキサム、ピメトロジン、カルタップ、エトキサゾール、フルベンジアミド、およびフロニカミドからなる群から選ばれる少なくとも1種である前記〔1〕〜〔4〕のいずれかひとつに記載の農薬。 [5] A compound having an agrochemical activity is a strobilurin fungicide, a carbamate fungicide, a dicarboximide fungicide, an azole fungicide, an anilide fungicide, chlorothalonil, mepanipyrim, iminocazine, cyflufenamide, polyoxin, quinomethionate, simoxanil , Bench Avaricarb-Isopropyl, Mandipropamide, Amisulbrom, Famoxadone, Fluopicolide, Oxolinic Acid, Macrolide Insecticide, Nicotinoid Insecticide, Organophosphorus Insecticide, Pyrethroid Insecticide, Chlorfenapyr, Bifenazate, Thiamethoxam, Pymetrozine Any one of the above-mentioned [1] to [4], which is at least one selected from the group consisting of quinato, cartap, etoxazole, fulvendiamide, and flonicamid Pesticides described in 1.
〔6〕 農薬活性を有する化合物が、アゾキシストロビン、クレソキシムメチル、ジエトフェンカルブ、チオファネートメチル、プロシミドン、クロロタロニル、トリフルミゾール、メプロニル、メパニピリム、イミノクタジンアルベシル酸塩、シフルフェナミド、ベノミル、ポリオキシン、キノメチオナート、シアゾファミド、ピリベンカルブ、シモキサニル、ベンチアバリカルブ−イソプロピル、マンジプロパミド、アミスルブロム、ファモキサドン、フルオピコリド、プロパモカルブ塩酸塩、ベンチアバリカルブ、オキソリニック酸、 エマメクチンベンゾエート、イミダクロプリド、アセタミプリド、クロチアニジン、ジノテフラン、クロルフェナピル、スピノサド、ビフェナゼート、アセフェート、チアメトキサム、ピメトロジン、カルタップ、エトキサゾール、トラロメトリン、フルベンジアミド、およびフロニカミドからなる群から選ばれる少なくとも1種である前記〔1〕〜〔4〕のいずれかひとつに記載の農薬。 [6] Compounds having agrochemical activity are azoxystrobin, cresoxime methyl, dietofencarb, thiophanate methyl, procymidone, chlorothalonil, triflumizole, mepronil, mepanipyrim, iminoctazine albesylate, ciflufenamide, benomyl, polyoxin, quinomethionate, ciazofamide, pyricarbbu , Simoxanyl, Bench Avaricarb-Isopropyl, Mandipropamide, Amisulbrom, Famoxadone, Flupicolide, Propamocarb Hydrochloride, Bench Avaricarb, Oxolinic Acid, Emamectin Benzoate, Imidacloprid, Acetamiprid, Clothianidin, Dinotefuran, Chlorfenapirto, Fenosapyrote , Pymetrozine, The agrochemical according to any one of [1] to [4], which is at least one selected from the group consisting of cartap, etoxazole, tralomethrin, fulvendiamide, and flonicamid.
〔7〕 農薬活性を有する化合物が、イミノクタジンアルベシル酸塩、ベンチアバリカルブ−イソプロピル、オキソリニック酸、アセタミプリド、ジノテフラン、およびエマメクチンベンゾエートからなる群から選ばれる少なくとも1種である前記〔1〕〜〔4〕のいずれかひとつに記載の農薬。 [7] The above [1] to [1], wherein the compound having pesticidal activity is at least one selected from the group consisting of iminoctadine albecylate, benchavaricarb-isopropyl, oxolinic acid, acetamiprid, dinotefuran, and emamectin benzoate. 4] The agrochemical according to any one of 4).
〔8〕 シュードモナス属(Pseudomonas)に属する微生物と農薬活性を有する化合物とを農園芸作物に施用することを含む農園芸作物の病害防除方法。 [8] A method for controlling diseases of agricultural and horticultural crops, which comprises applying a microorganism belonging to the genus Pseudomonas and a compound having agrochemical activity to agricultural and horticultural crops.
本発明の農薬は、化学農薬の使用量が少なくても十分な農薬効力を示し且つ安全性が高い。本発明の農薬を用いることによって、各種農園芸作物の栽培における農薬施用作業の安全性を向上させ労力を低減させることができる。 The pesticide of the present invention exhibits sufficient pesticide efficacy and high safety even when the amount of chemical pesticide used is small. By using the agrochemical of the present invention, it is possible to improve the safety of pesticide application work in the cultivation of various agricultural and horticultural crops and reduce the labor.
本発明の農薬は、シュードモナス属に属する微生物(以下、微生物Pと表記することがある。)と農薬活性を有する化合物(以下、化合物Aと表記することがある。)とを含有するものである。本発明の農薬は、微生物Pと化合物Aとが単に混ぜ合わさっただけのもの(例えば、微生物Pの粒剤と化合物Aの粒剤との混合物)であってもよいし、渾然一体となったもの(例えば、微生物Pと化合物Aとが一緒に溶媒に溶解されたものなど)であってもよい。 The agricultural chemical of the present invention contains a microorganism belonging to the genus Pseudomonas (hereinafter sometimes referred to as microorganism P) and a compound having an agricultural chemical activity (hereinafter sometimes referred to as compound A). . The agrochemical of the present invention may be one in which microorganism P and compound A are simply mixed (for example, a mixture of granules of microorganism P and granules of compound A). For example, the microorganism P and the compound A may be dissolved together in a solvent.
(シュードモナス属に属する微生物)
本発明の農薬に用いられる有効成分の一つは、シュードモナス属に属する微生物である。このうち、植物病害、節足動物、線虫、軟体動物等の有害動物、雑草等に対する防除能;もしくは植物に対する成長促進・保護能を有する微生物が好ましい。具体的な菌株としては、シュードモナス ロデシア(Pseudomonas rhodesiae)、シュードモナス フルオレセンス(Pseudomonas fluorescens)、シュードモナス プチダ(Pseudomonas putida)、シュードモナス オーレオファシエンス(Pseudomonas aureofaciens)、シュードモナス アルカリゲネス(Pseudomonas alcaligenes)、シュードモナス シリンゲ(Pseudomonas syringae)、Pseudomonas sp. CAB−02菌株、Pseudomonas sp. HR1000菌株、Pseudomonas CNCM I−804菌株、Pseudomonas sp. CGF878菌株、Pseudomonas sp. CGF7菌株または上記各菌の変異株等が挙げられる。
(Microorganism belonging to the genus Pseudomonas)
One of the active ingredients used in the agricultural chemical of the present invention is a microorganism belonging to the genus Pseudomonas. Of these, microorganisms having a control ability against plant diseases, harmful animals such as arthropods, nematodes, mollusks, weeds, etc .; or a growth promotion / protection ability against plants are preferable. Specific strains include Pseudomonas rhodesiae, Pseudomonas fluorescens, Pseudomonas putida, Pseudomonas aureofaciens, Pigenudomonas algenous almonds, Pseudomonas syringae), Pseudomonas sp. CAB-02 strain, Pseudomonas sp. HR1000 strain, Pseudomonas CNCM I-804 strain, Pseudomonas sp. CGF878 strain, Pseudomonas sp. CGF7 strain or mutant strains of each of the above-mentioned strains.
前記シュードモナス属に属する微生物のうち、植物病害に対する防除能を有する微生物が好ましい。そのうちで、シュードモナス ロデシア(Pseudomonas rhodesiae)が好ましく、シュードモナス ロデシア FERM BP−10912、シュードモナス ロデシア FERM P−21748、またはこれらの変異株がより好ましく、シュードモナス ロデシア FERM BP−10912またはそれの変異株がさらに好ましい。 Of the microorganisms belonging to the genus Pseudomonas, microorganisms having an ability to control plant diseases are preferable. Among them, Pseudomonas rhodesiae is preferable, Pseudomonas rhodesia FERM BP-10912, Pseudomonas rhodesia FERM P-21748, or a mutant thereof is more preferable, Pseudomonas rhodesia FERM BP-10912 or a mutant thereof is more preferable.
(農薬活性を有する化合物)
本発明の農薬に用いられる有効成分のもう一つは、農薬活性を有する化合物である。農薬活性を有する化合物は、特に限定されないが、例えば、殺菌、殺虫、殺ダニ、除草、植物成長調整などの活性を有する化合物が挙げられる。
(Compound with agrochemical activity)
Another active ingredient used in the agricultural chemical of the present invention is a compound having an agricultural chemical activity. Although the compound which has agrochemical activity is not specifically limited, For example, the compound which has activities, such as bactericidal, insecticidal, acaricidal, herbicidal, plant growth adjustment, is mentioned.
なかでも、より優れた活性が得られることから、
ストロビルリン系殺菌剤、カーバメート系殺菌剤、ジカルボキシイミド系殺菌剤、アゾール系殺菌剤、アニライド系殺菌剤、クロロタロニル、メパニピリム、イミノクタジン、シフルフェナミド、ポリオキシン、キノメチオナート、シモキサニル、ベンチアバリカルブ−イソプロピル、マンジプロパミド、アミスルブロム、ファモキサドン、フルオピコリド、オキソリニック酸、 マクロライド系殺虫殺ダニ剤、ニコチノイド系殺虫剤、有機リン系殺虫剤、ピレスロイド系殺虫剤、クロルフェナピル、ビフェナゼート、チアメトキサム、ピメトロジン、カルタップ、エトキサゾール、フルベンジアミド、およびフロニカミド からなる群から選ばれる少なくとも1種が好ましく、
Among them, because superior activity can be obtained,
Strobilurin fungicide, carbamate fungicide, dicarboximide fungicide, azole fungicide, anilide fungicide, chlorothalonil, mepanipyrim, iminotadine, cyflufenamide, polyoxin, quinomethionate, simoxanyl, bench acarbcarb-isopropyl, mandipropamide, Amisulbrom, famoxadone, fluopiclide, oxolinic acid, macrolide insecticide, acaricide, nicotinoid insecticide, organophosphorus insecticide, pyrethroid insecticide, chlorfenapyr, bifenazate, thiamethoxam, pymetrozine, cartap, etoxazole, flubenzamide, and flonicamid At least one selected from the group consisting of:
アゾキシストロビン、クレソキシムメチル、ジエトフェンカルブ、チオファネートメチル、プロシミドン、クロロタロニル、トリフルミゾール、メプロニル、メパニピリム、イミノクタジンアルベシル酸塩、シフルフェナミド、ベノミル、ポリオキシン、キノメチオナート、シアゾファミド、ピリベンカルブ、シモキサニル、ベンチアバリカルブ−イソプロピル、マンジプロパミド、アミスルブロム、ファモキサドン、フルオピコリド、プロパモカルブ塩酸塩、ベンチアバリカルブ、オキソリニック酸、 エマメクチンベンゾエート、イミダクロプリド、アセタミプリド、クロチアニジン、ジノテフラン、クロルフェナピル、スピノサド、ビフェナゼート、アセフェート、チアメトキサム、ピメトロジン、カルタップ、エトキサゾール、トラロメトリン、フルベンジアミド、およびフロニカミドからなる群から選ばれる少なくとも1種がより好ましく、 Azoxystrobin, cresoxime methyl, dietofencarb, thiophanate methyl, procymidone, chlorothalonil, triflumizole, mepronil, mepanipyrim, iminotazine arbesylate, cyflufenamide, benomyl, polyoxin, quinomethionate, cyazofamide, pyribencarb, simoxanyl Mandipropamide, Amisulbrom, Famoxadone, Flupicolide, Propamocarb Hydrochloride, Bench Avaricarb, Oxolinic Acid, Emamectin Benzoate, Imidacloprid, Acetamiprid, Clothianidin, Dinotefuran, Chlorfenapyr, Spinosad, Bifenazate, Acephate Toramethototoxate, Toxametotoxate Metorin, more preferably at least one selected from the group consisting of flubendiamide, and flonicamid,
イミノクタジンアルベシル酸塩、ベンチアバリカルブ−イソプロピル、オキソリニック酸、アセタミプリド、ジノテフラン、およびエマメクチンベンゾエートからなる群から選ばれる少なくとも1種が特に好ましい。 Particularly preferred is at least one selected from the group consisting of iminoctadine albesylate, bench avaricarb-isopropyl, oxolinic acid, acetamiprid, dinotefuran, and emamectin benzoate.
本発明の農薬において、シュードモナス属に属する微生物と、農薬活性を有する化合物との配合割合は、特に限定されないが、微生物P:化合物Aの質量比で、通常、1:1000〜1000:1、好ましくは1:100〜100:1、より好ましくは1:10〜10:1、特に好ましくは1:5〜5:1である。 In the agrochemical of the present invention, the mixing ratio of the microorganism belonging to the genus Pseudomonas and the compound having agrochemical activity is not particularly limited, but it is usually 1: 1000 to 1000: 1, preferably the mass ratio of microorganism P: compound A. Is 1: 100 to 100: 1, more preferably 1:10 to 10: 1, particularly preferably 1: 5 to 5: 1.
本発明に係る農薬の製造方法としては、例えば、(a)微生物Pと、化合物Aとを、それぞれ別々に製剤化し、これら製剤を混合することを含む方法、(b)化合物Aを製剤化し、該製剤に微生物P菌体を混合することを含む方法、(c)微生物Pを製剤化し、該製剤に化合物Aを混合することを含む方法、(d)微生物Pと化合物Aとを混合して、該混合物を製剤化することを含む方法などがある。これらのうち、微生物Pへの悪影響が少ないという観点で、方法(a)または方法(b)が好ましい。 Examples of the method for producing an agrochemical according to the present invention include: (a) a method that includes separately formulating the microorganism P and the compound A, respectively, and mixing these formulations; (b) formulating the compound A; A method comprising mixing microorganism P cells with the preparation, (c) a method comprising formulating microorganism P and mixing compound A with the preparation, and (d) mixing microorganism P and compound A. And a method comprising formulating the mixture. Among these, the method (a) or the method (b) is preferable from the viewpoint that the adverse effect on the microorganism P is small.
本発明の農薬には、本発明の効果に影響を与えない範囲において、肥料、固体担体、増粘剤、界面活性剤、展着剤、溶剤などが含まれていてもよい。 The agrochemical of the present invention may contain a fertilizer, a solid carrier, a thickener, a surfactant, a spreading agent, a solvent and the like as long as the effect of the present invention is not affected.
肥料としては、堆肥、油粕、魚粉、牛糞、鶏糞等あるいはこれらを加工してなる有機資材;硫酸アンモニウム、硝酸アンモニウム、硝酸石灰、尿素等の窒素肥料;過リン酸石灰、リン酸第一アンモニウム、熔成リン肥等のリン酸肥料;塩化カリウム、硫酸カリウム、硝酸カリウム等のカリ肥料;苦土石灰等の苦土肥料;消石灰等の石灰肥料;ケイ酸カリウム等のケイ酸肥料;ホウ酸塩等のホウ素肥料;各種無機肥料を含有してなる化成肥料;等が挙げられる。
固体担体としては、大豆粒、小麦粉などの植物性粉末;二酸化ケイ素、珪藻土、燐灰石、石こう、タルク、ベントナイト、パイロフィライト、クレー、目土などの鉱物性微粉末等が挙げられる。
As fertilizers, compost, oil cake, fish meal, cow dung, chicken dung, etc. or organic materials made by processing these; nitrogen fertilizers such as ammonium sulfate, ammonium nitrate, lime nitrate, urea; lime superphosphate, monoammonium phosphate, molten Phosphoric fertilizers such as phosphorus fertilizers; Potassium fertilizers such as potassium chloride, potassium sulfate, and potassium nitrate; Mashed fertilizers such as limestone lime; Lime fertilizers such as slaked lime; Silicate fertilizers such as potassium silicate; Boron fertilizers such as borate Chemical fertilizers containing various inorganic fertilizers; and the like.
Examples of the solid carrier include vegetable powders such as soybean grains and wheat flour; mineral fine powders such as silicon dioxide, diatomaceous earth, apatite, gypsum, talc, bentonite, pyrophyllite, clay, and earth.
添加剤としては、安息香酸ソーダ、尿素、芒硝などの有機および無機化合物など;ナタネ油、大豆油、ヒマワリ油、ヒマシ油、マツ(pine)油、綿実油、並びにこれらの油の誘導体や、これらの油濃縮物などが挙げられる。
溶剤としては、ケロシン、キシレン;ソルベントナフサなどの石油留分;シクロヘキサン、シクロヘキサノン、ジメチルホルムアミド、ジメチルスルホキシド、アルコール、アセトン、メチルイソブチルケトン、鉱物油、植物油、水などが挙げられる。
Additives include organic and inorganic compounds such as sodium benzoate, urea, and mirabilite; rapeseed oil, soybean oil, sunflower oil, castor oil, pine oil, cottonseed oil, and derivatives of these oils, An oil concentrate etc. are mentioned.
Examples of the solvent include kerosene, xylene; petroleum fractions such as solvent naphtha; cyclohexane, cyclohexanone, dimethylformamide, dimethyl sulfoxide, alcohol, acetone, methyl isobutyl ketone, mineral oil, vegetable oil, water, and the like.
界面活性剤としては、例えば、ポリオキシエチレンが付加したアルキルフェニルエーテル、ポリオキシエチレンが付加したアルキルエーテル、ポリオキシエチレンが付加した高級脂肪酸エステル、ポリオキシエチレンが付加したソルビタン高級脂肪酸エステル、ポリオキシエチレンが付加したトリスチリルフェニルエーテルなどの非イオン性界面活性剤、ポリオキシエチレンが付加したアルキルフェニルエーテルの硫酸エステル塩、アルキルベンゼンスルホン酸塩、高級アルコールの硫酸エステル塩、アルキルナフタレンスルホン酸塩、ポリカルボン酸塩、リグニンスルホン酸塩、アルキルナフタレンスルホン酸塩のホルムアルデヒド縮合物、イソブチレン−無水マレイン酸共重合体などを挙げることができる。 Examples of the surfactant include alkyl phenyl ether added with polyoxyethylene, alkyl ether added with polyoxyethylene, higher fatty acid ester added with polyoxyethylene, sorbitan higher fatty acid ester added with polyoxyethylene, polyoxyethylene Nonionic surfactants such as tristyrylphenyl ether with addition of ethylene, sulfates of alkylphenyl ethers with addition of polyoxyethylene, alkylbenzene sulfonates, sulfates of higher alcohols, alkylnaphthalene sulfonates, poly Examples thereof include a carboxylate, a lignin sulfonate, a formaldehyde condensate of an alkyl naphthalene sulfonate, and an isobutylene-maleic anhydride copolymer.
微生物P、化合物Aまたはそれら混合物の製剤化によって得られる剤形は、特に制限されず、通常の農園芸用農薬のとり得る形態、例えば、粉剤、水和剤、水溶剤、乳剤、フロアブル剤、顆粒剤、粒剤等の形態を採用することができる。
化合物Aの剤形は、粉剤、水和剤、水溶剤、フロアブル剤または顆粒剤が好ましい。また、化合物Aの剤形が乳剤、液剤等である場合には、これを水で所定濃度に希釈したのちに、微生物P菌体または微生物Pを含有する製剤と混合することが好ましい。
The dosage form obtained by formulation of microorganism P, compound A or a mixture thereof is not particularly limited, and can be a form that can be taken by ordinary agricultural and horticultural agricultural chemicals, such as powders, wettable powders, water solvents, emulsions, flowables, Forms such as granules and granules can be employed.
The dosage form of Compound A is preferably a powder, wettable powder, aqueous solvent, flowable or granule. Further, when the dosage form of Compound A is an emulsion, liquid, or the like, it is preferably diluted with water to a predetermined concentration and then mixed with a microorganism P cell or a preparation containing microorganism P.
製剤化された本発明の農薬に含まれる農薬活性を有する化合物の濃度は、前述した製剤の形態により種々の濃度を採りうる。例えば、水和剤においては、好ましくは0.1〜80重量%、より好ましくは1〜60質量%の濃度で、 乳剤においては、好ましくは0.01〜50質量%、より好ましくは0.1〜30質量%の濃度で、 粒剤においては、好ましくは0.01〜80質量%、より好ましくは、0.1〜60質量%の濃度で、 フロアブル剤においては、好ましくは0.1〜70重量%、より好ましくは1〜50重量%の濃度で用いられる。 The concentration of the compound having pesticidal activity contained in the formulated pesticide of the present invention can be various depending on the form of the preparation described above. For example, the wettable powder is preferably 0.1 to 80% by weight, more preferably 1 to 60% by weight, and the emulsion is preferably 0.01 to 50% by weight, more preferably 0.1 to 0.1% by weight. In a granule, the concentration is preferably 0.01 to 80% by mass, more preferably 0.1 to 60% by mass, and the flowable agent is preferably 0.1 to 70% by mass. It is used at a concentration of wt%, more preferably 1 to 50 wt%.
製剤化された農薬は、そのまま、若しくは水で所定の濃度に希釈して、溶解液、懸濁液あるいは乳濁液として、植物に散布したり、土壌に潅注、混和または散布したりすることによって使用される。本発明の農薬を圃場に適用するに当たっては、通常、1ヘクタール当たり有効成分(微生物Pと化合物Aとの合計量で)10〜1000gの量が施用される。 Formulated pesticides can be used as is, or diluted to a certain concentration with water and sprayed as a solution, suspension or emulsion on plants, or by irrigation, mixing or spraying on soil. used. When the agricultural chemical of the present invention is applied to a field, an amount of 10 to 1000 g of active ingredient (total amount of microorganism P and compound A) is usually applied per hectare.
本発明の農薬は、多くの農園芸植物の病害に対して著効を有する。本発明の農薬が効果を示す農園芸植物の病害としては、例えば、
「テンサイ」の、褐斑病(Cercospora beticola)、黒根病(Aphanomyces cochlioides)、根腐病(Thanatephorus cucumeris)、葉腐病(Thanatephorus cucumeris);
「ラッカセイ」の、褐斑病(Mycosphaerella arachidis、黒渋病(Mycosphaerella berkeleyi);
「キュウリ」の、うどんこ病(Sphaerotheca fuliginea)、べと病(Pseudoperonospora cubensis)、つる枯病(Mycosphaerella melonis)、つる割病(Fusarium oxysporum)、菌核病(Sclerotinia sclerotiorum)、灰色かび病(Botrytis cinerea)、炭そ病(Colletotrichum orbiculare)、黒星病(Cladosporium cucumerinum)、褐斑病(Corynespora cassicola)、苗立枯病(Pythium debaryanam、Rhizoctonia solani Kuhn)、斑点細菌病(Pseudomonas syringae pv. Lachrymans);
The agrochemical of the present invention has a significant effect on diseases of many agricultural and horticultural plants. As diseases of agricultural and horticultural plants for which the agricultural chemical of the present invention is effective, for example,
"Sugar beet" of brown spot (Cercospora beticola), black root (Aphanomyces cochlioides), root rot (Thanatephorus cucumeris), leaf rot (Thanatephorus cucumeris);
"Peanut" brown spot disease (Mycosphaerella arachidis, black astringency (Mycosphaerella berkeleyi);
Cucumber's powdery mildew (Sphaerotheca fuliginea), downy mildew (Pseudoperonospora cubensis), vine blight (Mycosphaerella melonis), vine split disease (Fusarium oxysporum), mycorrhizal disease (Sclerotinia sclerotiorum), gray mold disease (Botrytis) cinerea), anthracnose (Colletotrichum orbiculare), black spot (Cladosporium cucumerinum), brown spot (Corynespora cassicola), seedling blight (Pythium debaryanam, Rhizoctonia solani Kuhn), spot bacterial disease (Pseudomonas syringae pv. Lachrys)
「トマト」の、灰色かび病(Botrytis cinerea)、葉かび病(Cladosporium fulvum)、疫病(Phytophthora infestans)、青枯病(Ralstonia solanacearum)、かいよう病(Clavibacter michiganensis subsp. michigaensis)、茎えそ細菌病(Pseudomonas corrugata);
「ナス」の、灰色かび病(Botrytis cinerea)、黒枯病(Corynespora melongenae)、うどんこ病(Erysiphe cichoracearum)、すすかび病(Mycovellosiella nattrassii)、褐斑細菌病(Pseudomonas cichorii);
「イチゴ」の、灰色かび病(Botrytis cinerea)、うどんこ病(Sohaerotheca humuli)、炭そ病(Colletotrichum acutatum、Colletotrichum fragariae)、疫病(Phytophthora cactorum);
"Tomato", gray mold (Botrytis cinerea), leaf mold (Cladosporium fulvum), plague (Phytophthora infestans), bacterial wilt (Ralstonia solanacearum), scab (Clavibacter michiganensis subsp. Michigaensis) (Pseudomonas corrugata);
"Nas", gray mold disease (Botrytis cinerea), black blight disease (Corynespora melongenae), powdery mildew (Erysiphe cichoracearum), mildew disease (Mycovellosiella nattrassii), brown spot bacterial disease (Pseudomonas cichorii);
"Strawberries" of gray mold disease (Botrytis cinerea), powdery mildew (Sohaerotheca humuli), anthracnose (Colletotrichum acutatum, Colletotrichum fragariae), plague (Phytophthora cactorum);
「タマネギ」の、灰色腐敗病(Botrytis allii)、灰色かび病(Botrytis cinerea)、白斑葉枯病(Botrytis squamosa)、べと病(Peronospora destructor);
「キャベツ」の、根こぶ病(Plasmodiophora brassicae)、軟腐病(Erwinia carotovora)、べと病(Peronospora parasitica)、黒腐病(Xanthomonas campestris pv. campestris);
「ダイコン」の、根腐病(Rhizoctonia solani)、白さび病(Albugo macrospora)、黒斑細菌病(Pseudomonas syringae pv. Maculicola);
「インゲン」の、菌核病(Sclerotinia sclerotiorum)、灰色かび病(Botrytis cinerea)、かさ枯病(Pseudomonas syringae pv. Phaseolicola);
"Onion" of gray rot (Botrytis allii), gray mold (Botrytis cinerea), white leaf blight (Botrytis squamosa), downy mildew (Peronospora destructor);
"Cabbage", root-knot disease (Plasmodiophora brassicae), soft rot disease (Erwinia carotovora), downy mildew (Peronospora parasitica), black rot (Xanthomonas campestris pv. Campestris);
"Radish" of root rot (Rhizoctonia solani), white rust (Albugo macrospora), black spot bacterial disease (Pseudomonas syringae pv. Maculicola);
"Green beans", mycosis (Sclerotinia sclerotiorum), gray mold (Botrytis cinerea), blight (Pseudomonas syringae pv. Phaseolicola);
「りんご」の、うどんこ病(Podosphaera leucotricha)、黒星病(Venturia inaequalis)、モニリア病(Monilinia mali)、黒点病(Mycosphaerella pomi)、腐らん病(Valsa mali)、斑点落葉病(Alternaria mali)、赤星病(Gymnosporangium yamadae)、輪紋病(Botryosphaeria berengeriana)、炭そ病(Glomerella cingulata、Colletotrichum acutatum)、褐斑病(Diplocarpon mali)、すす点病(Zygophiala jamaicensis)、すす斑病(Gloeodes pomigena);
「カキ」の、うどんこ病(Phyllactinia kakicola)、炭そ病(Gloeosporium kaki)、角斑落葉病(Cercospora kaki);
"Apple" powdery mildew (Podosphaera leucotricha), black spot disease (Venturia inaequalis), monilia disease (Monilinia mali), black spot disease (Mycosphaerella pomi), rot disease (Valsa mali), spotted leaf disease (Alternaria mali), red star Diseases (Gymnosporangium yamadae), ring rot (Botryosphaeria berengeriana), anthracnose (Glomerella cingulata, Colletotrichum acutatum), brown spot (Diplocarpon mali), soot spot (Zygophiala jamaicensis), soot spot (Gloeodes pomigena)
"Oysters" of powdery mildew (Phyllactinia kakicola), anthracnose (Gloeosporium kaki), deciduous leaf spot (Cercospora kaki);
「モモ」の、灰星病(Monilinia fructicola)、黒星病(Cladosporium carpophilum)、ホモプシス腐敗病(Phomopsis sp.)、穿孔細菌病(Xanthomonas campestris pv. pruni);
「オウトウ」の、灰星病(Monilinia fructicola)
「ブドウ」の、灰色かび病(Botrytis cinerea)、うどんこ病(Uncinula necator)、晩腐病(Glomerella cingulata、Colletotrichum acutatum)、べと病(Plasmopara viticola)、黒とう病(Elsinoe ampelina)、褐斑病(Pseudocercospora vitis)、黒腐病(Guignardia bidwellII);
「ナシ」の、黒星病(Venturia nashicola)、赤星病(Gymnosporangium asiaticum)、黒斑病(Alternaria kikuchiana)、輪紋病(Botryosphaeria berengeriana)、うどんこ病(Phyllactinia mali);
"Peach" of ash scab (Monilinia fructicola), black scab (Cladosporium carpophilum), homopsis rot (Phomopsis sp.), Perforated bacterial disease (Xanthomonas campestris pv. Pruni);
"Ototo", Monilinia fructicola
"Grape": gray mold (Botrytis cinerea), powdery mildew (Uncinula necator), late rot (Glomerella cingulata, Colletotrichum acutatum), downy mildew (Plasmopara viticola), black scab (Elsinoe ampelina), brown spot Disease (Pseudocercospora vitis), black rot (Guignardia bidwellII);
"Pear" of black streak (Venturia nashicola), red streak (Gymnosporangium asiaticum), black spot (Alternaria kikuchiana), ring rot (Botryosphaeria berengeriana), powdery mildew (Phyllactinia mali);
「チャ」の、輪斑病(Pestalotia theae)、炭そ病(Colletotrichum theae-sinensis);
「カンキツ」の、そうか病(Elsinoe fawcetti)、青かび病(Penicillium italicum)、緑かび病(Penicillium digitatum)、灰色かび病(Botrytis cinerea)、黒点病(Diaporthe citri)、かいよう病(Xanthomonas campestris pv. Citri);
「コムギ」の、うどんこ病(Erysiphe graminis f.sp.tritici)、赤かび病(Gibberella zeae)、赤さび病(Puccinia recondita)、褐色雪腐病(Pythium iwayamai)、紅色雪腐病(Monographella nivalis)、眼紋病(Pseudocercosporella herpotrichoides)、葉枯病(Septoria tritici)、ふ枯病(Leptosphaeria nodorum)、雪腐小粒菌核病(Typhula incarnata)、雪腐大粒菌核病(Myriosclerotinia borealis)、立枯病(Gaeumanomyces graminis);
"Cha", ring spot disease (Pestalotia theae), anthracnose (Colletotrichum theae-sinensis);
In Citrus, common scab (Elsinoe fawcetti), blue mold (Penicillium italicum), green mold (Penicillium digitatum), gray mold (Botrytis cinerea), black spot (Diaporthe citri), scab (Xanthomonas campestris pv. Citri);
"Wheat" powdery mildew (Erysiphe graminis f.sp.tritici), red mold (Gibberella zeae), red rust (Puccinia recondita), brown snow rot (Pythium iwayamai), red snow rot (Monographella nivalis) , Eye spot disease (Pseudocercosporella herpotrichoides), leaf blight disease (Septoria tritici), blight disease (Leptosphaeria nodorum), snow rot microbe sclerosis (Typhula incarnata), snow rot microbe sclerosis (Myriosclerotinia borealis), blight (Gaeumanomyces graminis);
「オオムギ」の、斑葉病(Pyrenophora graminea)、雲形病(Rhynchosporium secalis)、裸黒穂病(Ustilago tritici、U.nuda);
「イネ」の、いもち病(Pyricularia oryzae)、紋枯病(Rhizoctonia solani)、馬鹿苗病(Gibberella fujikuroi)、ごま葉枯病(Cochliobolus miyabeanus)、苗立枯病(Pythium graminicola)、白葉枯病(Xanthomonas oryzae)、苗立枯細菌病(Burkholderia plantarii)、褐条病(Acidovorax avenae)、もみ枯細菌病(Burkholderia glumae);
「タバコ」の、菌核病(Sclerotinia sclerotiorum)、うどんこ病(Erysiphe cichoracearum);
「チューリップ」の、灰色かび病(Botrytis cinerea);
"Barley", leafy leaf disease (Pyrenophora graminea), cloud shape disease (Rhynchosporium secalis), naked smut (Ustilago tritici, U.nuda);
For rice, rice blast (Pyricularia oryzae), blight (Rhizoctonia solani), idiot seedling (Gibberella fujikuroi), sesame leaf blight (Cochliobolus miyabeanus), seedling blight (Pythium graminicola), white leaf blight ( Xanthomonas oryzae), seedling blight (Burkholderia plantarii), brown streak (Acidovorax avenae), blight blight (Burkholderia glumae);
"Tobacco", Sclerotinia sclerotiorum, powdery mildew (Erysiphe cichoracearum);
Botrytis cinerea of “tulips”;
「ベントグラス」の、雪腐大粒菌核病(Sclerotinia borealis)、赤焼病(Pythium aphanidermatum)、かさ枯病(Pseudomonas syringae pv. atropurpurea)、ベントグラス褐条病(Acidovorax avenae subsp. avenae);
「オーチャードグラス」の、うどんこ病(Erysiphe graminis);
「ダイズ」の、紫斑病(Cercospora kikuchii)、べと病(Peronospora Manshurica)、茎疫病(Phytophthora sojae);
「ジャガイモ」の、疫病(Phytophthore infestans);
などが挙げられる。
"Bentgrass", Snow rot large sclerotia nuclear disease (Sclerotinia borealis), red blight (Pythium aphanidermatum), dry blight (Pseudomonas syringae pv. Atropurpurea), bentgrass brown streak (Acidovorax avenae subsp. Avenae);
Powdery mildew (Erysiphe graminis) from “Orchardgrass”;
"Soybean" purpura (Cercospora kikuchii), downy mildew (Peronospora Manshurica), stem rot (Phytophthora sojae);
Phytophthore infestans of “potato”;
Etc.
次に、実施例を示して、本発明をさらに詳細に説明する。ただし、本発明は下記の実施例に限定されるものではない。 Next, an Example is shown and this invention is demonstrated further in detail. However, the present invention is not limited to the following examples.
(生存率試験)
表1に記載した各農薬活性化合物を活性成分とする市販の化学農薬製剤を、表1に記載した各最終濃度となるように滅菌水で希釈した。該希釈液に、シュードモナス ロデシア FERM BP−10912菌体を含有する水和剤を、希釈倍率1000倍となるように添加し混ぜ合わせた。各混合液を25℃で1時間静置した。次いで滅菌水で適宜希釈し、標準寒天培地(日水製薬社製)に塗抹し、25℃で一昼夜培養した。生育したコロニー数を計測し、無添加におけるコロニー数に対して、各農薬製剤を添加した場合のコロニー数の比率を、生存率として表1に示した。
(Survival test)
Commercially available chemical pesticide preparations containing each pesticidal active compound described in Table 1 as an active ingredient were diluted with sterilized water so that the final concentrations described in Table 1 were obtained. A wettable powder containing Pseudomonas rhodesia FERM BP-10912 cells was added to the diluted solution so that the dilution ratio was 1000 times and mixed. Each liquid mixture was left still at 25 degreeC for 1 hour. Next, the mixture was appropriately diluted with sterilized water, smeared on a standard agar medium (manufactured by Nissui Pharmaceutical Co., Ltd.), and cultured at 25 ° C. overnight. The number of grown colonies was counted, and the ratio of the number of colonies when each agricultural chemical preparation was added to the number of colonies without addition was shown in Table 1 as the survival rate.
上記の市販農薬製剤は、シュードモナス ロデシア FERM BP−10912株の生存に対してほとんど影響を与えず、混用および同時併用が可能であることが示された。
このことから、本発明の農薬においては、生物農薬の併用によって化学農薬の使用量を減らすことができるので、十分な農薬効力を示しつつ、安全性が増すことがわかる。
It was shown that the above-mentioned commercially available agricultural chemical preparations hardly affect the survival of Pseudomonas rhodesia FERM BP-10912 strain and can be used in combination and simultaneously.
From this, in the agrochemical of this invention, since the usage-amount of a chemical agrochemical can be reduced by combined use with a bioagrochemical, it turns out that safety | security increases, showing sufficient agrochemical efficacy.
Claims (8)
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| JP2011201170A JP2013060401A (en) | 2011-09-14 | 2011-09-14 | Agricultural pesticide containing biological pesticide and chemical pesticide |
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