JP2012062583A - Black silica coated yarn and manufacturing method for the same - Google Patents
Black silica coated yarn and manufacturing method for the same Download PDFInfo
- Publication number
- JP2012062583A JP2012062583A JP2010205429A JP2010205429A JP2012062583A JP 2012062583 A JP2012062583 A JP 2012062583A JP 2010205429 A JP2010205429 A JP 2010205429A JP 2010205429 A JP2010205429 A JP 2010205429A JP 2012062583 A JP2012062583 A JP 2012062583A
- Authority
- JP
- Japan
- Prior art keywords
- black silica
- yarn
- synthetic resin
- coated
- black
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 142
- 239000000377 silicon dioxide Substances 0.000 title claims abstract description 71
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 29
- 239000000057 synthetic resin Substances 0.000 claims abstract description 29
- 238000001035 drying Methods 0.000 claims description 11
- 239000002245 particle Substances 0.000 claims description 8
- 230000002093 peripheral effect Effects 0.000 claims description 8
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 10
- 230000005855 radiation Effects 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 4
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 3
- 230000001747 exhibiting effect Effects 0.000 abstract description 3
- 239000002781 deodorant agent Substances 0.000 abstract 1
- 235000019645 odor Nutrition 0.000 description 9
- 238000005259 measurement Methods 0.000 description 8
- 239000000835 fiber Substances 0.000 description 7
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 7
- 239000000843 powder Substances 0.000 description 6
- 229920000728 polyester Polymers 0.000 description 5
- 239000000306 component Substances 0.000 description 4
- 239000008358 core component Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229920002302 Nylon 6,6 Polymers 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 229920002292 Nylon 6 Polymers 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000001877 deodorizing effect Effects 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 2
- 229910001950 potassium oxide Inorganic materials 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 241000005398 Figaro Species 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 150000001718 carbodiimides Chemical class 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000005338 heat storage Methods 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007721 medicinal effect Effects 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000035900 sweating Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Description
本発明は、主として衣料品などに縫着されている商標や製造者名を表示する織ネームあるいは刺繍ワッペンなどの糸に用いるのに適したブラックシリカコーティング糸およびその製造方法に関するものであり、さらに詳しくは、ブラックシリカの持つ特有の効果が発揮できるようにしたブラックシリカコーティング糸とその製造方法に関するものである。 The present invention relates to a black silica-coated yarn suitable for use as a yarn such as a woven name or an embroidery patch displaying a trademark or a manufacturer name sewn mainly in clothing and the like, and a method for producing the same. Specifically, the present invention relates to a black silica-coated yarn capable of exhibiting the unique effects of black silica and a method for producing the same.
従来から、金属酸化物であるセラミックスなどの遠赤外線を放出する物質を繊維に混入したり、付着したりして遠赤外線による保温効果や血行促進効果などを期待した繊維製品は種々提案されているが、いずれの製品においてもその効果は満足できるものではなかった。 Conventionally, various fiber products have been proposed in which a material that emits far-infrared rays, such as ceramics that are metal oxides, is mixed in or adhered to the fiber and is expected to have a heat retention effect or blood circulation promotion effect by the far-infrared rays. However, the effect was not satisfactory in any product.
そこで、常温で高い遠赤外線の放射作用を有するブラックシリカ（黒鉛珪石）を、平均粒径が１０μｍ以下で、０．１〜１５重量％含有する繊維が提案されており、防寒衣料、スポーツ衣料、レジャー用品などの用途に適する蓄熱保温性に優れた繊維として知られている（例えば、特許文献１参照）。 Therefore, fibers containing black silica (graphite silica) having a high far-infrared radiation action at room temperature and having an average particle size of 10 μm or less and 0.1 to 15% by weight have been proposed, winter clothing, sports clothing, It is known as a fiber excellent in heat storage and heat retention suitable for uses such as leisure goods (see, for example, Patent Document 1).
しかしながら、前記特許文献１の繊維は、繊維断面が芯成分と鞘成分からなる芯鞘型複合構造であり、その芯成分の中心にブラックシリカの粉末を充填して封印してあることから、洗濯しても剥離して落ちることがない長所はあっても、ブラックシリカは芯成分の中にあることから、遠赤外線放射の放射率が少なくて効果が低いという問題点があった。また、極めて細い繊維の中心にブラックシリカの微粉末を規定量充填するのは大変難しく、手間のかかる作業であり、工程が複雑化して生産効率が向上しないといった問題点があった。 However, the fiber of Patent Document 1 has a core-sheath type composite structure in which the fiber cross section is composed of a core component and a sheath component, and the core component is filled with black silica powder and sealed. Even though it has the advantage that it does not peel off even when it is peeled off, black silica is in the core component, so there is a problem that the emissivity of far-infrared radiation is small and the effect is low. Moreover, it is very difficult to fill a predetermined amount of fine powder of black silica in the center of an extremely thin fiber, which is a laborious operation, and there is a problem that the process is complicated and the production efficiency is not improved.
本発明は、上記のような問題点を解決することを課題として開発されたもので、ブラックシリカの持つ特有の遠赤外線放射による温熱効果と、消臭抗菌効果が発揮できるブラックシリカコーティング糸と、製造工程の簡略化に伴い生産効率が向上して安価に供給できて経済的なブラックシリカコーティング糸を得る方法を提供することを目的とするものである。 The present invention was developed with the object of solving the above-mentioned problems, a black silica-coated yarn capable of exhibiting a thermal effect due to the characteristic far-infrared radiation of black silica, and a deodorizing antibacterial effect, An object of the present invention is to provide a method for obtaining an economical black silica-coated yarn which can be supplied at a low cost with improved production efficiency as the manufacturing process is simplified.
上記の課題を解決し、その目的を達成する手段として、本発明は、マルチフィラメント糸にブラックシリカを混入する合成樹脂を被覆したことを特徴とするブラックシリカコーティング糸を開発し、採用した。 As means for solving the above-mentioned problems and achieving the object, the present invention has developed and adopted a black silica-coated yarn characterized in that a multifilament yarn is coated with a synthetic resin mixed with black silica.
上記のように構成したブラックシリカコーティング糸において、前記ブラックシリカを混入する合成樹脂は、単糸と単糸の間および単糸と単糸の外周面に塗布されていることを特徴とするブラックシリカコーティング糸、および前記ブラックシリカは、平均粒子径５０μｍで、１〜５０重量％含有されていることを特徴とするブラックシリカコーティング糸を開発し、採用した。 In the black silica coated yarn configured as described above, the synthetic resin mixed with the black silica is applied between the single yarn and the single yarn and on the outer peripheral surface of the single yarn and the single yarn. The coated yarn and the black silica were developed and adopted as a black silica coated yarn characterized in that the average particle diameter was 50 μm and contained in an amount of 1 to 50% by weight.
また、本発明は、マルチフィラメント糸を、ブラックシリカの混入した合成樹脂槽に通して、単糸と単糸の間および単糸と単糸の外周面にブラックシリカの混入する合成樹脂を塗布した後、乾燥熱処理を施してブラックシリカの混入した合成樹脂を被覆することを特徴とするブラックシリカコーティング糸の製造方法を開発し、採用した。 In the present invention, the multifilament yarn is passed through a synthetic resin tank mixed with black silica, and a synthetic resin mixed with black silica is applied between the single yarn and the single yarn and on the outer peripheral surface of the single yarn and the single yarn. Thereafter, a method for producing a black silica-coated yarn was developed and adopted, which was subjected to a dry heat treatment to coat a synthetic resin mixed with black silica.
上記のように構成したブラックシリカコーティング糸の製造方法において、樹脂塗布後、乾燥炉に導入して１３０〜１５０℃の乾燥と、１５０〜２００℃の熱処理を同じ炉内で行い、炉内の滞留時間を１０〜３０秒以内とすることを特徴とするブラックシリカコーティング糸の製造方法を開発し、採用した。 In the method for producing a black silica coated yarn constructed as described above, after resin application, the product is introduced into a drying furnace, dried at 130 to 150 ° C. and heat treated at 150 to 200 ° C. in the same furnace, and stayed in the furnace. A method for producing a black silica coated yarn characterized in that the time is within 10 to 30 seconds was developed and adopted.
上記ブラックシリカとは、北海道桧山郡上ノ国町で産出する黒色の天然鉱石であり、数億年前に堆積した珪素類が地殻変動により地表に隆起したもので、その成分は、二酸化ケイ素が主成分であり、他に炭素、酸化アルミニウム、酸化カリウム、酸化チタン、酸化第二鉄、酸化マグネシウムなどからなり、常温で強い遠赤外線を放射する特質を持つことが知られている。 The above black silica is a black natural ore produced in Kaminokuni-cho, Hiyama-gun, Hokkaido. Silicon deposited in the hundreds of millions of years has risen to the surface due to crustal movement, and its component is mainly silicon dioxide. In addition, it is known to have characteristics of radiating strong far-infrared rays at room temperature, consisting of carbon, aluminum oxide, potassium oxide, titanium oxide, ferric oxide, magnesium oxide, and the like.
ブラックシリカの混入する合成樹脂によって被覆される糸は、太さの均一な多数のフィラメント単糸を平行に集束して構成されたマルチフィラメントが適しており、ポリエステル、ナイロン６、ナイロン６６などのポリアミド、ポリエチレン、ポリプロピレン、ポリアクリロニトリルなどの合成繊維が挙げられるが、その中でもポリエステル、ポリアミドが好適である。 A multifilament made up of a number of filaments of uniform thickness, which are gathered in parallel, is suitable for the yarn covered with the synthetic resin mixed with black silica. Polyamide such as polyester, nylon 6, nylon 66, etc. , Synthetic fibers such as polyethylene, polypropylene, polyacrylonitrile, etc., among which polyester and polyamide are preferred.
糸の形態としては、塗布されるブラックシリカ混入の合成樹脂がマルチフィラメント単糸と単糸の間に入り込んで内部まで浸透しやすく、また、マルチフィラメント単糸と単糸の外周面にもブラックシリカの混入する合成樹脂を塗布しやすいことから、原糸あるいは仮撚り糸であることが望ましい。 As for the form of the yarn, the synthetic resin mixed with black silica is easy to penetrate between the multifilament single yarn and the single yarn, and the black silica is also applied to the outer peripheral surface of the multifilament single yarn and the single yarn. Since it is easy to apply a synthetic resin mixed with the yarn, it is desirable to use a raw yarn or false twisted yarn.
マルチフィラメント糸の断面形状は、円形でも非円形でも任意の形状が可能である。マルチフィラメント糸の太さも任意であるが、通常は５５〜３３０ｄｔｅｘの範囲が使用可能である。 The cross-sectional shape of the multifilament yarn can be any shape, circular or non-circular. Although the thickness of the multifilament yarn is also arbitrary, a range of 55 to 330 dtex is usually usable.
マルチフィラメント単糸と単糸の間およびマルチフィラメント単糸と単糸の外周面に塗布される合成樹脂は、フィラメント糸との接着性およびブラックシリカ粉末との混錬性を考量して、ポリウレタン、アクリル、ナイロン６、ナイロン６６などのポリアミド、ポリエステルなどの合成樹脂を用いるのが好適である。これらの合成樹脂は通常、水分散体であるが、有機溶媒に溶かしたものを用いることもできる。また、これらの合成樹脂は必要に応じて、メラミン、イソシアネート、カルボジイミド、エポキシ系の架橋剤で架橋させることにより皮膜強度が上がり、洗濯による樹脂脱落を防止している。 The synthetic resin applied between the multifilament single yarn and the single yarn and the outer surface of the multifilament single yarn and the single yarn is polyurethane, considering the adhesiveness with the filament yarn and the kneadability with the black silica powder. It is preferable to use a synthetic resin such as acrylic, nylon 6, polyamide 66 such as nylon 66, or polyester. These synthetic resins are usually aqueous dispersions, but those dissolved in an organic solvent can also be used. Further, these synthetic resins are cross-linked with melamine, isocyanate, carbodiimide, and epoxy-based cross-linking agents as necessary to increase the film strength and prevent the resin from falling off by washing.
マルチフィラメント糸に被覆される合成樹脂には平均粒子径が約５０μｍのブラックシリカが１〜５０重量％含有されているのが好ましい。粒子径が５０μｍ以下になると、ブラックシリカの持つ特有の効果が期待できない。５０μｍ以上になると、合成樹脂槽の中で沈降し、付着の均一性が保てないので適さない。また、ブラックシリカの含有量が１重量％以下になると、ブラックシリカの持つ特有の効果が低下する。５０重量％以上になると、皮膜強度が弱くなって洗濯等で剥離する虞れがあるので適しない。 The synthetic resin coated on the multifilament yarn preferably contains 1 to 50% by weight of black silica having an average particle diameter of about 50 μm. When the particle diameter is 50 μm or less, the unique effect of black silica cannot be expected. When the thickness is 50 μm or more, it settles in the synthetic resin tank and the uniformity of adhesion cannot be maintained, which is not suitable. On the other hand, when the content of black silica is 1% by weight or less, the specific effect of black silica is lowered. If it is 50% by weight or more, the film strength is weak, and there is a possibility of peeling off by washing or the like.
合成樹脂塗布後、乾燥炉に導入して乾燥する温度は、１３０〜１５０℃の乾燥が好適である。１３０℃以下であれば乾燥が不充分で適さず、１５０℃を超えると皮膜に気泡が入る虞れがあり、皮膜が安定しないので適さない。また、その後の熱処理温度は、１５０〜２００℃が適している。１５０℃以下では、皮膜の硬化が不充分で適さず、２００℃以上では糸を弱体化する虞れがあることから適さない。さらに、乾燥処理と熱処理を同じ炉内で１０〜３０秒の滞留時間とするのが良い。１０秒以下になると乾燥が充分でなくなり、３０秒を越えると生産効率が悪くなるので適さない。 The temperature at which the synthetic resin is applied and then introduced into a drying furnace and dried is preferably 130 to 150 ° C. If it is 130 ° C. or lower, drying is insufficient and unsuitable, and if it exceeds 150 ° C., there is a possibility that bubbles may enter the film, and the film is not stable. Moreover, 150-200 degreeC is suitable for the heat processing temperature after that. If it is 150 ° C. or lower, the film is insufficiently cured, and if it is 200 ° C. or higher, the yarn may be weakened. Furthermore, it is preferable that the drying process and the heat treatment are performed in the same furnace with a residence time of 10 to 30 seconds. If it is less than 10 seconds, drying is not sufficient, and if it exceeds 30 seconds, the production efficiency is deteriorated, which is not suitable.
本発明のブラックシリカコーティング糸は、マルチフィラメント糸にブラックシリカを混入する合成樹脂を被覆してあり、従来のような芯成分と鞘成分からなる芯鞘型複合構造芯糸の中ではなく、マルチフィラメント糸の内面および外周面に付着するブラックシリカから遠赤外線を放射することから、安定した高い放射率となる。また、ブラックシリカは、合成樹脂に混入されていることから、洗濯などによっても剥がれることなく、長期に亘って遠赤外線放射機能を保有するものである。そして、織りネームなどの糸として使用すると、遠赤外線放射により蓄熱保温され、健康増進効果や医療効果に優れると共に、消臭抗菌作用があることから、発汗に起因する不快臭を消臭することができ衛生的になる。 The black silica coated yarn of the present invention is a multifilament yarn coated with a synthetic resin mixed with black silica, and is not a core-sheath type composite structure core yarn composed of a core component and a sheath component as in the prior art. Since far infrared rays are radiated from the black silica adhering to the inner surface and outer peripheral surface of the filament yarn, a stable high emissivity is obtained. Further, since black silica is mixed in a synthetic resin, it has a far infrared radiation function over a long period of time without being peeled off even by washing. And when used as yarns such as weaving names, heat is stored by far-infrared radiation, it has excellent health promotion effects and medical effects, and has a deodorizing and antibacterial action, so it can deodorize unpleasant odors caused by sweating. Can be hygienic.
また、本発明のブラックシリカコーティング糸の製造方法によれば、マルチフィラメント糸を、ブラックシリカの混入した合成樹脂槽に通すという簡単な方法により、マルチフィラメント糸の内面と外周面にブラックシリカの含有する合成樹脂を塗布できる。また、乾燥炉に導入してマルチフィラメント糸の表面と合成樹脂を溶着して一体被覆化することから、合成樹脂が剥離することのないブラックシリカコーティング糸を容易に得ることができる。 Further, according to the method for producing a black silica-coated yarn of the present invention, the inclusion of black silica on the inner surface and the outer peripheral surface of the multifilament yarn is achieved by a simple method of passing the multifilament yarn through a synthetic resin tank mixed with black silica. A synthetic resin can be applied. Moreover, since it introduce | transduces into a drying furnace and welds the surface of a multifilament thread | yarn and a synthetic resin, and integrally coat | covers, the black silica coating thread | yarn which a synthetic resin does not peel can be obtained easily.
以下に、本発明の実施の形態を添付の図１に基づいて説明すれば、１は多数のフィラメント単糸２，２……２を平行に集束して構成されたポリエステルマルチフィラメント糸であり、ブラックシリカ粉末３を混入するウレタン樹脂４をフィラメント単糸２と単糸２の間およびフィラメント単糸２と単糸２の外周面に塗布して被覆したものであり、ブラックシリカは平均粒子径が５０μｍで、１〜５０重量％含有している。 Hereinafter, an embodiment of the present invention will be described with reference to the attached FIG. 1. A polyester multifilament yarn 1 is formed by converging a large number of filament single yarns 2, 2... 2 in parallel. The urethane resin 4 mixed with the black silica powder 3 is coated between the filament single yarn 2 and the single yarn 2 and on the outer peripheral surface of the filament single yarn 2 and the single yarn 2, and the black silica has an average particle diameter. It is 1 to 50% by weight at 50 μm.
ここで用いるブラックシリカ３の成分組成は、二酸化ケイ素８２．５％、酸化アルミニウム８．４％、酸化カリウム３．３％、炭素３．２％、酸化チタン０．８％、酸化第二鉄０．８％、酸化マグネシウム０．４％、三酸化硫黄０．１％、酸化ナトリウム０．０２％、塩素０．０１％、フッ素０．０１％、（社団法人 日本海事検定協会 理化学分析センター）などからなっている。 The component composition of the black silica 3 used here is silicon dioxide 82.5%, aluminum oxide 8.4%, potassium oxide 3.3%, carbon 3.2%, titanium oxide 0.8%, ferric oxide 0 .8%, Magnesium oxide 0.4%, Sulfur trioxide 0.1%, Sodium oxide 0.02%, Chlorine 0.01%, Fluorine 0.01%, (Nippon Kaiji Kyokai Association Physical and Chemical Analysis Center), etc. It is made up of.
つぎに、本発明に係るブラックシリカコーティング糸１の製造方法を具体的実施例で説明すると、多数のフィラメント単糸２，２……２を束ねて形成した５５ｄｔｅｘのポリエステルマルチフィラメント糸１をボビン５から引き出し、平均粒子径が５０μｍで１００ｇのブラックシリカ粉末３を３リットルの水溶性ウレタン樹脂４の中に入れ、混合撹拌してブラックシリカ粉末３が均一に分散するウレタン樹脂槽６の中を通過させ、ウレタン樹脂４がマルチフィラメント単糸２と単糸２の間に入り込み内部まで浸透すると共に、マルチフィラメント単糸２と単糸２の外周面にも塗布した後、ウレタン樹脂槽６の上方部に配設したフェルトからなる上下挟着部７，７で余分なウレタン樹脂４を落として付着量を調整する。 Next, the production method of the black silica coated yarn 1 according to the present invention will be described in a specific example. A 55 dtex polyester multifilament yarn 1 formed by bundling a large number of filament single yarns 2, 2,. The black silica powder 3 having an average particle diameter of 50 μm and 100 g is put into 3 liters of water-soluble urethane resin 4 and mixed and stirred to pass through a urethane resin tank 6 in which the black silica powder 3 is uniformly dispersed. The urethane resin 4 enters between the multifilament single yarn 2 and the single yarn 2 and penetrates to the inside, and is also applied to the outer peripheral surface of the multifilament single yarn 2 and the single yarn 2, and then the upper portion of the urethane resin tank 6. The excess urethane resin 4 is dropped at the upper and lower sandwiching portions 7 and 7 made of felt arranged in (1) to adjust the adhesion amount.
その後、乾燥炉８内に導入されて、前半の乾燥処理室８ａでは１３０〜１５０℃で、後半の熱処理室８ｂでは１５０〜２００℃で熱処理が行われて、ポリエステルマルチフィラメント糸１と、その表面に付着するウレタン樹脂４が一体溶着して被覆されたブラックシリカコーティング糸１となり、ボビン９に巻き取られるものである。得られたブラックシリカコーティング糸１には、平均粒子径が５０μｍのブラックシリカが１〜５０重量％含有していた。 After that, the polyester multifilament yarn 1 and its surface are introduced into the drying furnace 8 and heat-treated at 130 to 150 ° C. in the first half of the drying chamber 8a and at 150 to 200 ° C. in the latter half of the heat treatment chamber 8b. A black silica coated yarn 1 is formed by integrally welding the urethane resin 4 adhering to the yarn and is wound around a bobbin 9. The obtained black silica-coated yarn 1 contained 1 to 50% by weight of black silica having an average particle diameter of 50 μm.
このブラックシリカコーティング糸１を、経糸および緯糸として、縦３０ｍｍ、横９０ｍｍの帯状体の織ネームを作り、市販のカッターシャツの襟刳りと袖口に縫い込んだ試験シャツを男女４人が試着し、数時間通常のワークをした後に、それぞれのシャツの臭いを測定した。比較に使用した、織ネームを縫いこんでいないシャツをブランクシャツとし、これとの比較測定を行った。
＊試着条件；４時間試着（高温多湿時試着、男子：温度２８℃、湿度６１％、女子：温度３１℃、湿度３０％）
＊測定用チャンバ；透明アクリル容器（３０ｃｍ×３０ｃｍ×３０ｃｍ）
＊臭い測定器；男子用（神栄（株）製吸引式臭い測定器）
女子用（フィガロ技研（株）半導体式高感度ガスセンサＴＧ２６０２）
＊測定条件：試着後、対象のシャツを測定用チャンバに入れ、２分後に臭いを測定。
シャツＡ：女性用織ネーム付きシャツ１枚、ブランクシャツ１枚
シャツＢ：男性用織ネーム付きシャツ１枚、ブランクシャツ１枚
Four men and women tried on a test shirt that was made with a woven name of 30 mm in length and 90 mm in width as a warp and weft, and sewn into the collar and cuffs of a commercially available cutter shirt. After normal work for several hours, the odor of each shirt was measured. The shirt which did not sew woven name used for the comparison was made into the blank shirt, and the comparison measurement with this was performed.
* Try-on conditions: Try-on for 4 hours (high-temperature and high-temperature try-on, boy: temperature 28 ° C, humidity 61%, girl: temperature 31 ° C, humidity 30%)
* Measurement chamber; transparent acrylic container (30cm x 30cm x 30cm)
* Odor measuring device: For boys (Shinei Co., Ltd. suction type odor measuring device)
For Women (Figaro Giken Co., Ltd. Semiconductor High Sensitivity Gas Sensor TG2602)
* Measurement conditions: After trying on, put the target shirt in the measurement chamber and measure the odor after 2 minutes.
Shirt A: 1 shirt with woven name for women, 1 blank shirt Shirt B: 1 shirt with woven name for men, 1 blank shirt
測定結果
女性用シャツの臭い測定
測定結果
男性用シャツの臭い測定
以上、本発明の主要な実施の形態について説明したが、本発明は上記実施の形態に限らず、本発明の目的を達成でき、かつ本発明の要旨を逸脱しない範囲内で種々の変更が可能である。 As mentioned above, although main embodiment of this invention was described, this invention is not limited to the said embodiment, A various change is possible within the range which can achieve the objective of this invention and does not deviate from the summary of this invention. It is.
本発明のブラックシリカコーティング糸は、衣料品に縫着されている織ネームや刺繍ワッペン、ラベルなどの糸として用いれば有効に利用できるものでる。 The black silica-coated yarn of the present invention can be effectively used when used as a yarn for woven names, embroidery patches, labels, and the like sewn on clothing.
１ マルチフィラメント糸
２ 単糸
３ ブラックシリカ
４ 合成樹脂
６ 合成樹脂槽
８ 乾燥炉
1 Multifilament yarn
2 Single yarn
3 Black silica 4 Synthetic resin
6 Synthetic resin tank 8 Drying furnace
Claims (5)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010205429A JP2012062583A (en) | 2010-09-14 | 2010-09-14 | Black silica coated yarn and manufacturing method for the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010205429A JP2012062583A (en) | 2010-09-14 | 2010-09-14 | Black silica coated yarn and manufacturing method for the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2012062583A true JP2012062583A (en) | 2012-03-29 |
Family
ID=46058580
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010205429A Pending JP2012062583A (en) | 2010-09-14 | 2010-09-14 | Black silica coated yarn and manufacturing method for the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2012062583A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20210156046A (en) * | 2020-06-17 | 2021-12-24 | 주식회사 오아시스 | Sofa sewing thread |
| WO2024094357A1 (en) * | 2022-11-01 | 2024-05-10 | The Swatch Group Research And Development Ltd | Composite textile yarn, method for producing such a composite textile yarn, textile article made from such composite textile yarns |
| WO2025182363A1 (en) * | 2024-03-01 | 2025-09-04 | 株式会社レゾナック | Heat storage material and method for producing heat storage material |
-
2010
- 2010-09-14 JP JP2010205429A patent/JP2012062583A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20210156046A (en) * | 2020-06-17 | 2021-12-24 | 주식회사 오아시스 | Sofa sewing thread |
| KR102344367B1 (en) | 2020-06-17 | 2021-12-29 | 주식회사 오아시스 | Sofa sewing thread |
| WO2024094357A1 (en) * | 2022-11-01 | 2024-05-10 | The Swatch Group Research And Development Ltd | Composite textile yarn, method for producing such a composite textile yarn, textile article made from such composite textile yarns |
| WO2025182363A1 (en) * | 2024-03-01 | 2025-09-04 | 株式会社レゾナック | Heat storage material and method for producing heat storage material |
| JP7736107B1 (en) * | 2024-03-01 | 2025-09-09 | 株式会社レゾナック | Heat storage material and method for manufacturing heat storage material |
| JP7736113B1 (en) * | 2024-03-01 | 2025-09-09 | 株式会社レゾナック | Structural material and manufacturing method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2021169692A (en) | Silk performance garments and products, and how to manufacture them | |
| Almeida et al. | Health and safety concerns of textiles with nanomaterials | |
| JP2012062583A (en) | Black silica coated yarn and manufacturing method for the same | |
| CN109642353A (en) | Object filled with fiber and the fibre for having used it | |
| JP7015697B2 (en) | Multi-layered woven and knitted fabrics and textiles | |
| US20260022500A1 (en) | Novel Yarn and Fabric | |
| CN109736002A (en) | A kind of protective gloves and its weaving method | |
| JP2008303472A (en) | Warp / weft fabric | |
| CN107747155B (en) | Aloe fiber and bamboo fiber interwoven fabric and weaving method thereof | |
| JPH07316923A (en) | Anti-bacterial and anti-mold polyester multifilament yarn and its preparation | |
| WO2004088016A1 (en) | Fiber materials having improved qualities required for clothes and method of improving the same | |
| JPS6245340B2 (en) | ||
| CN206607374U (en) | A kind of MULTILAYER COMPOSITE spins | |
| CN115287803A (en) | Antibacterial deodorizing self-heating functional liner cloth | |
| JP4067547B2 (en) | Functional fiber, functional yarn and fabric material | |
| KR100504674B1 (en) | A quick absorption & dry fabric having the self temperature control function | |
| CN116427078A (en) | A kind of processing method of skin-friendly antiallergic polyester/silk fiber core-spun suede fabric | |
| Rukhaya et al. | Durable aroma finishing of wool fabric with microencapsulated vetiver essential oil and assessment of its properties | |
| JPWO2017199421A1 (en) | Functional fiber and method for producing the same | |
| JP6266953B2 (en) | Deodorant fiber structure and textile product | |
| JP2020007661A (en) | Deodorant fabrics and clothing | |
| KR20060002633A (en) | Black Mud Coated Fabric | |
| JP2003328215A (en) | Dust-free clothing containing recovered polyester and excellent in comfortability for wearing and see-through- preventing property | |
| KR100442013B1 (en) | Method for processing textile and/or textile goods by using nephrite water | |
| KR101817319B1 (en) | Method for manufacturing of aroma diffusing polyester staple fiber and itself |