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JP2011137760A - Outdoor structure - Google Patents

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JP2011137760A
JP2011137760A JP2009298895A JP2009298895A JP2011137760A JP 2011137760 A JP2011137760 A JP 2011137760A JP 2009298895 A JP2009298895 A JP 2009298895A JP 2009298895 A JP2009298895 A JP 2009298895A JP 2011137760 A JP2011137760 A JP 2011137760A
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corrosion
sensor
outdoor structure
environment
resistance
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Shinsaku Dobashi
晋作 土橋
Chisato Tsukahara
千幸人 塚原
Kazuhiro Takeda
一弘 竹田
Yasushi Okano
靖 岡野
Ryosuke Notomi
良介 納富
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Mitsubishi Heavy Industries Ltd
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Mitsubishi Heavy Industries Ltd
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Priority to JP2009298895A priority Critical patent/JP2011137760A/en
Priority to ES10196801T priority patent/ES2399855T3/en
Priority to EP20100196801 priority patent/EP2339325B8/en
Priority to DK10196801T priority patent/DK2339325T3/en
Publication of JP2011137760A publication Critical patent/JP2011137760A/en
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Abstract

<P>PROBLEM TO BE SOLVED: To provide an outdoor structure equipped with a corrosion detector capable of preventing injury from salt, while monitoring the change of injury from salt with the passage of time, at all times. <P>SOLUTION: The corrosion detector 10A, provided in the outdoor structure, includes a corrosion sensor 110 for monitoring corrosion environment, an ammeter 115 for measuring the corrosion current produced in the corrosion sensor 110 and a variable resistor 11 for altering the corrosion current; and when the corrosion environment is measured, the variable resistor 11 is changed so that the corrosion current maintains substantially a constant value (e.g., 100 nA). <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

本発明は、塩害等による腐食を事前に検知することができる腐食検知装置を備えた屋外構造物に関する。   The present invention relates to an outdoor structure provided with a corrosion detection device capable of detecting in advance corrosion due to salt damage or the like.

例えば風車等の屋外構造物は、海上や沿岸で設置するので、風車の外部塗装や、風車の内部に設けたトランス、制御盤等が塩害により腐食することが懸念されている。
そのため、装置内部の材質、塗装に即した塩害予測が必要となってきている。
For example, since outdoor structures such as windmills are installed on the sea or on the coast, there is a concern that external coating of the windmill, transformers provided inside the windmill, control panels, etc. may be corroded by salt damage.
For this reason, it is necessary to predict salt damage according to the material inside the device and the coating.

その評価方法としてJISZ2371「塩水噴霧試験方法」及びJISK5621「複合サイクル試験」等が確立されている(非特許文献1、2)。   As evaluation methods thereof, JISZ2371 “salt spray test method”, JISK5621 “combined cycle test” and the like have been established (Non-patent Documents 1 and 2).

また、近年塩害腐食量を予測するセンサとして腐食センサの提案がある(特許文献1)。   In recent years, a corrosion sensor has been proposed as a sensor for predicting the amount of salt corrosion (Patent Document 1).

この腐食センサについて説明すると、二つの異種金属(基板と導電部)を互いに絶縁部で絶縁した状態とし、両者の端部を環境へ露出すると、その環境に応じて両金属間を水膜が連結するので腐食電流が流れる。この電流は卑な金属の腐食速度に対応するので、その腐食センサとして用いられている。   Explaining this corrosion sensor: When two dissimilar metals (substrate and conductive part) are insulated from each other by insulating parts, and both ends are exposed to the environment, a water film is connected between the two metals according to the environment. Corrosion current flows. Since this current corresponds to the corrosion rate of the base metal, it is used as the corrosion sensor.

この腐食センサは、「大気腐食モニタ」(Atmospheric Corrosion Monitor)あるいはACM型腐食センサと称されている。
このセンサの一例を図3乃至図5に示す。図3及び図4に示すように、ACM型腐食センサ(以下、「腐食センサ」という。)110は、厚さ0.8mmの炭素鋼板を64mm×64mmに切り出し、基板111としており、この基板111の上に、厚膜IC用精密スクリーン印刷機を用いて絶縁ペースト(厚さ30〜35μm:SiO2)の絶縁部112を塗布し、硬化させている。
続いて、導電ペースト(厚さ30〜40μm、フィラー:Ag)を、基板111との絶緑が保たれるように、絶縁部112のパターン上に積層印刷し、硬化させて導電部113とし、腐食センサを構成している(非特許文献3)。
ここで、前記基板111を第1の導電部とすると共に、導電部113を所定間隔を持って複数設けられる直線状の第2の導電部としている。
This corrosion sensor is called “Atmospheric Corrosion Monitor” or ACM type corrosion sensor.
An example of this sensor is shown in FIGS. As shown in FIGS. 3 and 4, the ACM type corrosion sensor (hereinafter referred to as “corrosion sensor”) 110 cuts out a carbon steel plate having a thickness of 0.8 mm into a 64 mm × 64 mm substrate as a substrate 111. An insulating portion 112 of an insulating paste (thickness 30 to 35 μm: SiO 2 ) is applied and cured using a precision screen printer for thick film ICs.
Subsequently, a conductive paste (thickness 30 to 40 μm, filler: Ag) is laminated and printed on the pattern of the insulating portion 112 so as to maintain the greenness with the substrate 111, and cured to form the conductive portion 113. A corrosion sensor is configured (Non-patent Document 3).
Here, the substrate 111 is a first conductive portion, and the conductive portions 113 are a plurality of linear second conductive portions provided at a predetermined interval.

そして、図5に示すように、湿度や海塩(塩化物イオン等)等の水膜114により、導電部113と基板111とが短絡し、これに起因するFe−Agのガルバニック対の腐食電流を電流計115で計測している。なお、図3中、符号116a、116bは端子である。炭素鋼板(Fe)表面の露出部がセンサのアノード(陽極)となり、導電ペースト(Ag)がカソード(陰極)となる。
このガルバニック対の腐食電流は、鋼材料や亜鉛材料の腐食量に対して相関があることから、腐食速度を定量評価できるものである。
Then, as shown in FIG. 5, the conductive portion 113 and the substrate 111 are short-circuited by the water film 114 such as humidity or sea salt (chloride ion or the like), and the corrosion current of the Fe-Ag galvanic pair resulting from this. Is measured by an ammeter 115. In FIG. 3, reference numerals 116a and 116b denote terminals. The exposed portion of the carbon steel plate (Fe) surface becomes the anode (anode) of the sensor, and the conductive paste (Ag) becomes the cathode (cathode).
The corrosion current of the galvanic pair has a correlation with the corrosion amount of the steel material or the zinc material, so that the corrosion rate can be quantitatively evaluated.

また、前記ACM型腐食センサを用いた、太陽光発電システム部材の塩害腐食量予測法が提案され、湿度と測定電流値及び海塩付着量との関係図より、海塩付着量を推定することが提案されている(非特許文献4及び5)。   Further, a method for predicting the amount of salt damage corrosion of photovoltaic power generation system members using the ACM type corrosion sensor is proposed, and the amount of sea salt attached is estimated from the relationship diagram between humidity, measured current value, and amount of sea salt attached. Has been proposed (Non-Patent Documents 4 and 5).

特開2008−157647号公報JP 2008-157647 A

JISZ2371JISZ2371 JISK5621JISK5621 http://www.nims.go.jp/mdss/corrosion/ACM/ACM1.htmhttp://www.nims.go.jp/mdss/corrosion/ACM/ACM1.htm 松下電工技法(Nov.2002) p79−85Matsushita Electric Works (Nov. 2002) p79-85 材料と環境「ACMセンサによる環境腐食性評価」 54、3Materials and environment "Evaluation of environmental corrosivity by ACM sensor" 54, 3

しかしながら、JISZ2371規格及びJISK5621規格試験においては、試験環境が実際の環境と一致していないので、試験精度が悪いという問題がある。   However, in the JISZ2371 standard test and the JISK5621 standard test, there is a problem that the test accuracy is poor because the test environment does not match the actual environment.

前記ACM型腐食センサは、自己腐食型のセンサであるので、長時間使用していくとセンサ自身の劣化により、基板である炭素鋼板の腐食が生じることで、絶縁層と剥離が生じ、センサ性能を維持できないという問題がある。   Since the ACM type corrosion sensor is a self-corrosion type sensor, if it is used for a long period of time, the carbon steel plate as a substrate is corroded due to deterioration of the sensor itself, resulting in separation from the insulating layer, and sensor performance. There is a problem that cannot be maintained.

しかしながら、ACM型腐食センサは、腐食しなければ、腐食環境の測定精度が悪くなる場合があるので、センサの長寿命化という目的のために、センサの腐食を抑制しすぎると、腐食環境そのものの測定自体が実施できなくなる、という問題もある。
よって、腐食環境に応じてセンサの長寿命化を図ることが切望されている。
However, if the ACM type corrosion sensor does not corrode, the measurement accuracy of the corrosive environment may deteriorate. For the purpose of extending the life of the sensor, if the corrosion of the sensor is excessively suppressed, There is also a problem that the measurement itself cannot be performed.
Therefore, it is eagerly desired to extend the life of the sensor according to the corrosive environment.

本発明は、前記問題に鑑み、腐食環境に応じてセンサの長寿命化を図ることができる腐食検知装置を備えた屋外構造物を提供することを課題とする。   In view of the above problems, an object of the present invention is to provide an outdoor structure provided with a corrosion detection device capable of extending the life of a sensor according to a corrosive environment.

上述した課題を解決するための本発明の第1の発明は、腐食環境を監視する腐食センサと、前記腐食センサで発生する腐食電流を計測する電流計と、前記腐食電流を変更する可変抵抗とを有する腐食検知装置を備えた屋外構造物にある。   A first invention of the present invention for solving the above-described problems includes a corrosion sensor for monitoring a corrosive environment, an ammeter for measuring a corrosion current generated in the corrosion sensor, and a variable resistor for changing the corrosion current. An outdoor structure with a corrosion detector having

第2の発明は、第1の発明において、さらに、腐食センサの設置環境を計測する環境モニタを有することを特徴とする屋外構造物にある。   A second invention is the outdoor structure according to the first invention, further comprising an environment monitor for measuring an installation environment of the corrosion sensor.

第3の発明は、第2の発明において、環境モニタが、湿度計、温度計、照度計の少なくとも1つであることを特徴とする屋外構造物にある。   A third invention is the outdoor structure according to the second invention, wherein the environmental monitor is at least one of a hygrometer, a thermometer, and an illuminometer.

本発明によれば、腐食環境に応じてセンサの長寿命化を図ることができる。   According to the present invention, it is possible to extend the life of the sensor according to the corrosive environment.

図1は、実施例1に係る腐食検知装置の概略図である。FIG. 1 is a schematic diagram of a corrosion detection apparatus according to the first embodiment. 図2は、実施例2に係る腐食検知装置の概略図である。FIG. 2 is a schematic diagram of the corrosion detection apparatus according to the second embodiment. 図3は、従来技術に係る腐食センサの平面図である。FIG. 3 is a plan view of a corrosion sensor according to the prior art. 図4は、従来技術に係る腐食センサの概略図である。FIG. 4 is a schematic view of a corrosion sensor according to the prior art. 図5は、従来技術の腐食時における概略図である。FIG. 5 is a schematic view of the prior art during corrosion.

以下、この発明につき図面を参照しつつ詳細に説明する。なお、この実施例によりこの発明が限定されるものではない。また、下記実施例における構成要素には、当業者が容易に想定できるもの、あるいは実質的に同一のものが含まれる。   Hereinafter, the present invention will be described in detail with reference to the drawings. Note that the present invention is not limited to the embodiments. In addition, constituent elements in the following embodiments include those that can be easily assumed by those skilled in the art or those that are substantially the same.

本発明による実施例に係る腐食検知装置を備えた屋外構造物について、図面を参照して説明する。図1は、本実施例に係る屋外構造物に備えられる腐食検知装置10Aは、腐食環境を監視する腐食センサ110と、腐食センサ110で発生する腐食電流を計測する電流計115と、前記腐食電流を変更する可変抵抗11とを有するものである。   An outdoor structure provided with a corrosion detector according to an embodiment of the present invention will be described with reference to the drawings. FIG. 1 shows a corrosion detector 10A provided in an outdoor structure according to the present embodiment. A corrosion sensor 110 for monitoring a corrosive environment, an ammeter 115 for measuring a corrosion current generated in the corrosion sensor 110, and the corrosion current. And a variable resistor 11 for changing the.

そして、腐食環境を計測する際に、腐食電流が略一定の値(例えば100nA)を維持するように、可変抵抗11を変化させるようにしている。   When the corrosive environment is measured, the variable resistor 11 is changed so that the corrosive current is maintained at a substantially constant value (for example, 100 nA).

これにより、腐食センサ110の劣化状態を常に一定とすることができ、その後の寿命を予測することができる。   Thereby, the deterioration state of the corrosion sensor 110 can always be made constant, and the lifetime after that can be predicted.

すなわち、腐食センサ110の積算電気量が1クーロンに達した場合に、劣化寿命と判断すると仮定すると、それまでの使用時間を乗じて現在の積算電気量を求め、その差分が余寿命となる。
これにより、腐食環境に応じてセンサの長寿命化を図ることができる。
That is, when it is assumed that when the accumulated electric quantity of the corrosion sensor 110 reaches 1 coulomb, it is determined that the life is deteriorated, the current accumulated electric quantity is obtained by multiplying the previous use time, and the difference becomes the remaining life.
Thereby, the lifetime of the sensor can be extended according to the corrosive environment.

本発明による実施例に係る腐食検知装置を備えた屋外構造物について、図面を参照して説明する。図2は、本実施例に係る屋外構造物に備えられる腐食検知装置10Bは、実施例1の装置において、さらに腐食センサ110の設置環境を計測する環境モニタ20を有するようにしている。   An outdoor structure provided with a corrosion detector according to an embodiment of the present invention will be described with reference to the drawings. In FIG. 2, the corrosion detection device 10 </ b> B provided in the outdoor structure according to the present embodiment has an environment monitor 20 that measures the installation environment of the corrosion sensor 110 in the device of the first embodiment.

ここで、前記環境モニタ20としては、例えば湿度計20A、温度計20B、照度計20Cの少なくとも1つを挙げることができる。   Here, examples of the environmental monitor 20 include at least one of a hygrometer 20A, a thermometer 20B, and an illuminance meter 20C.

例えば、湿度計20Aを用いて計測する場合には、腐食センサ110の近傍において、湿度計20Aを設けるようにしている。   For example, when measuring using the hygrometer 20A, the hygrometer 20A is provided in the vicinity of the corrosion sensor 110.

そして、湿度計20Aで湿度を計測し、その計測結果を、例えば3つの領域、湿度I(30%未満)と、湿度II(30〜70%)、湿度III(70%以上)に分類する。
湿度I〜IIIに応じて、抵抗I(抵抗が低い:A点)、抵抗II(抵抗が中位:B点)、抵抗III(抵抗が高い:C点)を設定する。
そして、湿度計20Aでの計測した湿度に応じて、内部抵抗を変更(A、B、C点のいずれか)する。この結果、所定の腐食電流値(例えば100nA)に近似する値とし、さらに所定の腐食電流値(100nA)に近づけるように、内部抵抗を微調整する。
Then, the humidity is measured by the hygrometer 20A, and the measurement results are classified into, for example, three regions, humidity I (less than 30%), humidity II (30 to 70%), and humidity III (70% or more).
Resistance I (low resistance: point A), resistance II (resistance is middle: point B), and resistance III (high resistance: point C) are set according to the humidity I to III.
Then, the internal resistance is changed (any one of points A, B, and C) according to the humidity measured by the hygrometer 20A. As a result, the internal resistance is finely adjusted so as to approximate a predetermined corrosion current value (for example, 100 nA), and to approach the predetermined corrosion current value (100 nA).

この結果、環境に応じて、抵抗を設定し、常に一定の腐食電流が流れるようにすることで、余寿命を予測することができる。   As a result, the remaining life can be predicted by setting the resistance according to the environment so that a constant corrosion current always flows.

これにより、例えば、タンカーなどのように、一度航海に出ると、母港に戻るまでは、腐食センサの交換ができない場合には、長寿命化を図ることで、センサの交換を行うことなく、長期間の腐食環境のモニタリングが可能となる。   Thus, for example, if a corrosion sensor cannot be replaced until it returns to the home port once it has been sailed, such as a tanker, it is possible to extend the service life without changing the sensor. It becomes possible to monitor the corrosive environment during the period.

環境モニタ20が温度を計測する場合は、温度計20Bで温度を計測し、その計測結果が、例えば3つの領域、温度I(0度未満)と、温度II(0〜40度)、温度III(40度以上)に分類する。
温度I〜IIIに応じて、抵抗I(抵抗が低い:A点)、抵抗II(抵抗が中位:B点)、抵抗III(抵抗が高い:C点)を設定するようにすればよい。
When the environmental monitor 20 measures the temperature, the temperature is measured by the thermometer 20B, and the measurement results are, for example, three regions, temperature I (less than 0 degrees), temperature II (0 to 40 degrees), and temperature III. Classify (over 40 degrees).
According to the temperatures I to III, the resistance I (low resistance: point A), the resistance II (resistance is middle: point B), and the resistance III (high resistance: point C) may be set.

環境モニタ20が照度を計測する場合は、照度計20Cで照度を計測し、その計測結果を、例えば3つの領域、照度I(10ルクス未満)と、照度II(10〜5000ルクス)、照度III(5000ルクス以上)に分類する。
照度I〜IIIに応じて、抵抗I(抵抗が低い:A点)、抵抗II(抵抗が中位:B点)、抵抗III(抵抗が高い:C点)を設定するようにすればよい。
When the environmental monitor 20 measures the illuminance, the illuminance is measured by the illuminometer 20C, and the measurement results are obtained by, for example, three areas, illuminance I (less than 10 lux), illuminance II (10 to 5000 lux), and illuminance III. Classify (more than 5000 lux).
According to the illuminances I to III, the resistance I (low resistance: A point), the resistance II (resistance is middle: B point), and the resistance III (high resistance: C point) may be set.

以上は、本発明の屋外構造物として、例えばタンカーを例示したが、本発明は、これに限定されるものではなく、海岸等の塩害対策が必要な例えば風力発電装置、橋梁設備や太陽電池設備、発電プラント設備、鉄筋建造物、鉄道設備等にも適用することができる。さらに、車両、船舶等の移動体の塩害対策に適用することもできる。   The above is an example of a tanker as an outdoor structure according to the present invention. It can also be applied to power plant equipment, reinforcing steel building, railway equipment, etc. Furthermore, it can also be applied to salt damage countermeasures for moving bodies such as vehicles and ships.

以上のように、本発明に係る腐食検知装置を備えた屋外構造物は、腐食環境に応じてセンサの長寿命化を図ることができる、例えば風力発電装置の構成部材の劣化の判断に用いて適している。   As described above, the outdoor structure provided with the corrosion detection device according to the present invention can extend the life of the sensor according to the corrosive environment. For example, the outdoor structure is used for determining deterioration of components of the wind power generation device. Is suitable.

10A、10B 腐食検知装置
20 環境モニタ
20A 湿度計
20B 温度計
20C 照度計
10A, 10B Corrosion detector 20 Environmental monitor 20A Hygrometer 20B Thermometer 20C Illuminance meter

Claims (3)

腐食環境を監視する腐食センサと、
前記腐食センサで発生する腐食電流を計測する電流計と、
前記腐食電流を変更する可変抵抗とを有する腐食検知装置を備えたことを特徴とする屋外構造物。
A corrosion sensor that monitors the corrosive environment;
An ammeter for measuring the corrosion current generated by the corrosion sensor;
An outdoor structure comprising a corrosion detection device having a variable resistance for changing the corrosion current.
請求項1において、
さらに、腐食センサの設置環境を計測する環境モニタを有することを特徴とする屋外構造物。
In claim 1,
Furthermore, the outdoor structure characterized by having an environmental monitor which measures the installation environment of a corrosion sensor.
請求項2において、
環境モニタが、湿度計、温度計、照度計の少なくとも1つであることを特徴とする屋外構造物。
In claim 2,
An outdoor structure, wherein the environmental monitor is at least one of a hygrometer, a thermometer, and an illuminometer.
JP2009298895A 2009-12-28 2009-12-28 Outdoor structure Withdrawn JP2011137760A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2009298895A JP2011137760A (en) 2009-12-28 2009-12-28 Outdoor structure
ES10196801T ES2399855T3 (en) 2009-12-28 2010-12-23 Corrosion sensor for exterior structure
EP20100196801 EP2339325B8 (en) 2009-12-28 2010-12-23 Corrosion sensor for outdoor structure
DK10196801T DK2339325T3 (en) 2009-12-28 2010-12-23 Corrosion sensor for outdoor structure

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JP2019032277A (en) * 2017-08-09 2019-02-28 株式会社シュリンクス Environmental monitoring sensor and environmental monitoring device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019032277A (en) * 2017-08-09 2019-02-28 株式会社シュリンクス Environmental monitoring sensor and environmental monitoring device

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