JP2011111668A - Steel having excellent stability in rolling fatigue life - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a steel which exhibits satisfactory grindability when worked into a product shape, and stably obtains a satisfactory rolling fatigue life. <P>SOLUTION: The steel has a composition containing each of 0.65 to 1.10% C, 0.05 to 1.0% Si, 0.1 to 2% Mn, ≤0.05% (not including 0%) P, ≤0.05% S, 0.15 to 2.0% Cr, 0.01 to 0.1% Al, ≤0.025 N, ≤0.002% (not including 0%) Ti and ≤0.0025% O, and the balance comprising iron with inevitable impurities, wherein an average diameter of an equivalent circle of Al based nitrogen compounds dispersed into the steel is ≥60 nm, a number density of the Al based nitrogen compounds with a diameter of an equivalent circle of 25 to 200 nm is ≥1.1 piece/μm<SP>2</SP>, also, an area ratio of cementite is ≤12%, and an average diameter of an equivalent circle of the cementite is ≤0.60 μm. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

  The present invention relates to steel materials applied to bearing parts and machine structural parts used in automobiles, various industrial machines, etc., and particularly when used as the above-mentioned various members, good rolling fatigue life is stable. The obtained steel material is concerned.

  Parts such as bearings and crankshafts are important parts that support the rotating parts and sliding parts of machinery, and the contact surface pressure is considerably high and the external force may fluctuate. In many cases, excellent durability is required for the steel material.

  In recent years, these requirements have become stricter year by year as the performance and weight of machinery have been improved. In order to improve the durability of shaft parts, it is important to improve the technology related to lubricity, but it is particularly important that the steel material has excellent rolling fatigue characteristics.

  As steel materials used for bearings, high-carbon chromium bearing steels such as SUJ2 as defined in JIS G 4805 (1999) have been used as bearing materials used in various fields such as automobiles and various industrial machines. Has been. However, since bearings are used in harsh environments such as inner and outer rings and rolling elements such as ball bearings and roller bearings with extremely high contact surface pressure, fatigue failure is likely to occur due to very fine defects (inclusions, etc.). There is a problem. In order to solve this problem, attempts have been made to improve the steel for bearings in order to increase the rolling fatigue life itself and reduce the number of maintenance operations.

  For example, in Patent Document 1, the content of Ti and Al in the bearing material is specified, and the amount of fine Ti carbide, Ti carbonitride, Al nitride, etc. is determined by performing heat treatment after spheroidizing annealing. It has been proposed to improve the rolling fatigue life by controlling and refining the prior austenite crystal grains (former γ crystal grains).

  In the above technique, the rolling fatigue life is improved, but the Ti content is very high at 0.26% or more, which not only increases the cost but also reduces the workability. is there. In addition, coarse TiN is likely to be produced during casting, and the formation of this precipitate will cause variations in fatigue life, and it is actually desired to realize a steel material with excellent stability in rolling fatigue life. is there.

  By the way, in the case of making a final product as a bearing, after being processed into a predetermined part shape, it is generally quenched and tempered and the surface thereof is polished. For these reasons, it is necessary for the steel for bearings to have excellent “abrasiveness”. This polishing property is contradictory to the ease of polishing during polishing (that is, the polishing efficiency is good) and the surface property after polishing (that is, the surface roughness is low). It will be judged from both characteristics. Of these, it is known that improving the surface properties also affects the stability of the rolling fatigue life.

  As a bearing steel having excellent abrasiveness, for example, a technique as disclosed in Patent Document 2 has been proposed. In this technique, the chemical component composition of the steel material is defined, and TiN having a maximum diameter of 10 μm or less is dispersed in the steel to improve both the polishing efficiency and the surface property. However, this technique basically disperses TiN, and this TiN tends to become coarse, and as a result, the fatigue life tends to vary.

Japanese Patent No. 3591236 JP 2006-1118030 A

  The present invention has been made in view of such circumstances, and its purpose is to improve the abrasiveness when processing into a product shape and to stably obtain a good rolling fatigue life. To provide steel.

The steel materials according to the present invention that have achieved the above-mentioned object are: C: 0.65 to 1.10% (meaning of mass%, the same applies hereinafter), Si: 0.05 to 1.0%, Mn: 0 0.1 to 2%, P: 0.05% or less (excluding 0%), S: 0.05% or less (not including 0%), Cr: 0.15 to 2.0%, Al: 0 0.01 to 0.1%, N: 0.025% or less (not including 0%), Ti: 0.002% or less (not including 0%), and O: 0.0025% or less (including 0%) The number of Al-based nitrogen compounds having an equivalent circle diameter of 25 to 200 nm and an average equivalent circle diameter of the Al-based nitrogen compound dispersed in the steel is 60 nm or more. The density is 1.1 pieces / μm ² or more and the area ratio of cementite is 12% or less. It has a gist in that the average equivalent circle diameter of the tight is 0.60 μm or less.

The above "equivalent circle diameter" refers to the diameter of a circle that is assumed to have the same area by paying attention to the size of an Al-based nitrogen compound or cementite. A transmission electron microscope (TEM) Or an Al-based nitrogen compound or cementite found on the observation surface of a scanning electron microscope (SEM). In addition, the Al-based nitrogen compounds targeted in the present invention include not only AlN, but also those containing a part of elements such as Mn, Cr, S and Si (total content up to about 30%). It is. Furthermore, the above-mentioned cementite is intended to include not only Fe ₃ C but also those containing a part of elements such as Mn and Cr (total content up to about 20%).

  Further, in the steel material of the present invention, if necessary, as another element, (a) Cu: 0.25% or less (not including 0%), Ni: 0.25% or less (not including 0%) And Mo: one or more selected from the group consisting of 0.25% or less (not including 0%), (b) Nb: 0.5% or less (not including 0%), V: 0.5% 1 or more selected from the group consisting of the following (excluding 0%) and B: 0.005% or less (not including 0%), (c) Ca: 0.05% or less (not including 0%) ), REM: 0.05% or less (not including 0%), Mg: 0.02% or less (not including 0%), Li: 0.02% or less (not including 0%), and Zr: 0 .One or more selected from the group consisting of 2% or less (not including 0%), (d) Pb: 0.5% or less (not including 0%), Bi It is also useful to contain one or more selected from the group consisting of 0.5% or less (excluding 0%) and Te: 0.1% or less (not including 0%), etc. The properties of the steel material are further improved depending on the components to be added.

  According to the present invention, by appropriately adjusting the chemical component composition, appropriately dispersing an appropriately sized Al-based nitrogen compound in the steel material, and defining the area ratio and size of cementite, the product shape It is possible to realize a steel material with excellent abrasiveness when rolling into a steel and excellent stability in rolling fatigue life, so that when this steel material is applied to bearings, etc., it can exhibit a stable rolling fatigue life. Become.

It is a graph which shows the relationship between the number density of Al type nitrogen compound, and steel material surface roughness Rt. It is a graph which shows the relationship between the magnitude | size (circle equivalent diameter) of Al type nitrogen compound, and steel material surface roughness Rt. It is a graph which shows the relationship between steel material surface roughness Rt and a lifetime inclination. It is a graph which shows the relationship between a cementite area ratio and polishing efficiency. It is a graph which shows the relationship between the magnitude | size (equivalent circle diameter) of cementite, and polishing efficiency.

  The present inventors have studied from various angles for the purpose of realizing a steel material that can improve the grindability when processed into a product shape and has excellent stability of rolling fatigue life. And the knowledge that satisfying the following requirements (A) to (E) was effective in improving the abrasiveness and rolling fatigue life of the steel material was obtained.

(A) Disperse a large amount of a predetermined amount of an Al-based nitrogen compound, increase the strength of the parent phase (mainly martensite) through dispersion strengthening, and reduce the hardness difference from hard inclusions (cementite). The surface properties can be made good (that is, good rolling fatigue life can be stably obtained)
(B) In order to strengthen dispersion by the Al-based nitrogen compound, it is necessary to define the amount (number density) and size of the Al-based nitrogen compound;
(C) In order to achieve the degree of dispersion (number density) in the Al-based nitrogen compound, it is important to strictly control the content of Al and N in the steel, and in the manufacturing process of the steel material, It is useful to increase the cooling rate after removing the temperature range of 850 to 650 ° C., which is the precipitation temperature range of the Al-based nitrogen compound, after hot rolling,
(D) In order to improve the abrasiveness of the steel material, it is effective to make the area ratio and size (equivalent circle diameter) of cementite within a predetermined range, and the size of the Al-based nitrogen compound is also after polishing. Affecting the surface properties (surface roughness after polishing) of
(E) It is effective to appropriately control the spheroidizing heat treatment (spheroidizing annealing) before processing the part shape in order to make the area ratio and size (equivalent circle diameter) of cementite within a predetermined range.

Based on the above findings, the inventors of the present invention have further conducted intensive research in order to realize the abrasiveness of the steel material and the stability of the rolling fatigue life. As a result, the Al and N contents in the steel material are strictly defined, the production conditions are controlled, the average equivalent circle diameter dispersed in the steel after quenching and tempering is 60 nm or more, and the equivalent circle diameter is 25. If the number density of the Al-based nitrogen compound of ˜200 nm is 1.1 pieces / μm ² or more, the area ratio of cementite is 12% or less, and the average equivalent circle diameter is 0.60 μm or less. The present inventors have found that the abrasiveness of the steel material and the stability of the rolling fatigue life can be remarkably improved, and the present invention has been completed.

  In the steel material of the present invention, it is an important requirement to appropriately control the number density of the Al-based nitrogen compound having an average particle diameter of 25 to 200 nm, but the strength of the matrix (mainly martensite) is enhanced by the dispersion strengthening. The surface property can be improved by reducing the hardness difference from the hard inclusions (cementite). For this purpose, it is necessary to appropriately control the size of the target Al-based nitrogen compound. If this size (equivalent circle diameter) is smaller than 25 nm or larger than 200 nm, the effect of dispersion strengthening is exhibited. Can not do.

When the number density of the Al-based nitrogen compound as described above is less than 1.1 / μm ² , the strength improvement effect by dispersion strengthening cannot be effectively exhibited. The number density of the Al-based nitrogen compound is preferably 1.3 pieces / μm ² or more (more preferably 1.5 pieces / μm ² or more). The upper limit of the number density of the Al-based nitrogen compound is not particularly limited, but if it is too large, the crystal grains become coarse, an incompletely quenched phase (for example, fine pearlite or bainite phase) is generated, and rolling fatigue occurs. Since there is a possibility that the life may not be stable, it is preferably 6.0 pieces / μm ² or less, more preferably 5.0 pieces / μm ² or less.

  Also, since the average size of the Al-based nitrogen compound also affects the surface properties after polishing (surface roughness after polishing), the average equivalent circle diameter of the Al-based nitrogen compound dispersed in the steel after quenching and tempering is determined. It is also important that the thickness be 60 nm or more. That is, by setting the average equivalent circle diameter of the Al-based nitrogen compound to 60 nm or more, the surface properties are improved (surface roughness is reduced) because the effect of dispersion strengthening can be sufficiently exhibited. The size of the Al-based nitrogen compound is preferably 70 nm or more (more preferably 80 nm or more).

  In the steel material of the present invention, in order to improve the abrasiveness of the steel material, it is necessary to make the cementite area ratio and size (equivalent circle diameter) within a predetermined range. As the amount of cementite increases, the polishing efficiency decreases. From such a viewpoint, the area ratio of cementite needs to be 12% or less. The area ratio of cementite is preferably 11% or less (more preferably 10% or less). The lower limit of the area ratio of cementite is not particularly limited, but if it becomes too small, the rolling fatigue life is likely to deteriorate and become unstable, so it is preferably 5% or more, more preferably 6%. That's it.

  Further, when the cementite is small in size, it easily falls off during polishing, and the adverse effect on polishing properties (polishing efficiency) is reduced. For these reasons, it is necessary that the cementite has an average equivalent circle diameter of 0.60 μm or less. The size of cementite is preferably 0.50 μm or less (more preferably 0.40 μm or less) in terms of average equivalent circle diameter. The lower limit of the cementite size is not particularly limited, but if it becomes too small, the rolling fatigue life may deteriorate and become unstable, and therefore it is preferably 0.1 μm or more, more preferably 0. .15 μm or more.

  In the steel material of the present invention, the chemical component composition (C, Si, Mn, P, S, Cr, Al, N, Ti, O) including the above-described Al and N contents needs to be appropriately adjusted. However, the reasons for limiting the ranges of these components are as follows.

[C :: 0.65 to 1.10%]
C is an essential element for increasing the quenching hardness and maintaining the strength at room temperature and high temperature to impart wear resistance. In order to exert such an effect, C must be contained in an amount of 0.65% or more, preferably 0.8% or more (more preferably 0.95% or more). However, if the C content is excessively large, giant carbides are likely to be generated, which adversely affects the abrasiveness and rolling fatigue characteristics. Therefore, the C content is 1.10% or less, preferably 1.05. % Or less (more preferably 1.0% or less).

[Si: 0.05-1.0%]
Si is an element useful for improving the solid solution strengthening and hardenability of the matrix. In order to exert such effects, it is necessary to contain Si by 0.05% or more, preferably 0.1% or more (more preferably 0.15% or more). However, if the Si content becomes too large, the workability and machinability are remarkably lowered, so the Si content is 1.0% or less, preferably 0.9% or less (more preferably 0.8% or less). Should be suppressed.

[Mn: 0.1 to 2%]
Mn is an element useful for improving the solid solution strengthening and hardenability of the matrix. In order to exert such an effect, it is necessary to contain Mn in an amount of 0.1% or more, preferably 0.15% or more (more preferably 0.2% or more). However, since the workability and machinability are remarkably lowered when the Mn content is excessively increased, the Mn content should be suppressed to 2% or less, preferably 1.6% or less (more preferably 1.2% or less). It is.

[P: 0.05% or less (excluding 0%)]
P is an element inevitably contained as an impurity, but it is desirable to reduce it as much as possible because it segregates at the grain boundary and lowers the workability, but extremely reducing causes an increase in steelmaking cost. . For these reasons, the P content is set to 0.05% or less. Preferably, it is good to reduce to 0.04% or less (more preferably 0.03% or less).

[S: 0.05% or less (excluding 0%)]
S is an element that is inevitably contained as an impurity, but precipitates as MnS, and it is desirable to reduce it as much as possible in order to reduce the rolling fatigue life. However, extreme reduction leads to an increase in steelmaking costs. Become. For these reasons, the S content is set to 0.05% or less. Preferably, it is good to reduce to 0.04% or less (more preferably 0.03% or less).

[Cr: 0.15 to 2.0%]
Cr is an element that combines with C to form carbides, imparts wear resistance, and contributes to improving hardenability. In order to exert such an effect, the Cr content needs to be 0.15% or more. Preferably it is 0.5% or more (more preferably 0.9% or more). However, when the Cr content is excessive, coarse carbides are generated and the rolling fatigue life is decreased. Therefore, the Cr content is 2.0% or less. Preferably it is 1.8% or less (more preferably 1.6% or less).

[Al: 0.01 to 0.1%]
Al is an element that plays an important role in the steel material of the present invention, and when it is combined with N, it is finely dispersed in the steel as an Al-based nitrogen compound, and is important for reducing the strength difference of the matrix by dispersion strengthening. Element. In order to produce a fine Al-based nitrogen compound, it is necessary to contain at least 0.01% or more. However, when the Al content becomes excessive and exceeds 0.1%, the size and number of Al-based nitrogen compounds that are precipitated increase, and the surface properties during polishing deteriorate. The preferable lower limit of the Al content is 0.013% (more preferably 0.015% or more), and the preferable upper limit is 0.08% (more preferably 0.05% or less).

[N: 0.025% or less (excluding 0%)]
N, like Al, is an element that plays an important role in the steel material of the present invention, and is an important element for reducing the strength difference of the matrix due to fine dispersion of the Al-based nitrogen compound. However, if the N content becomes excessive and exceeds 0.025%, the size and number density of the precipitated Al-based nitrogen compound increase, and the surface properties during polishing deteriorate. The preferable lower limit of the N content is 0.005% (more preferably 0.006% or more), and the preferable upper limit is 0.02% (more preferably 0.015% or less).

[Ti: 0.002% or less (excluding 0%)]
Ti is a harmful element that has a large adverse effect on the surface properties during polishing because Ti is likely to combine with N in the steel to produce coarse TiN, and it is desirable to reduce it as much as possible. This will increase the cost. For these reasons, the Ti content needs to be 0.002% or less. In addition, the upper limit with preferable Ti content is 0.0019%.

[O: 0.0025% or less (excluding 0%)]
O has a large effect on the form of impurities in steel and forms inclusions such as Al ₂ O ₃ and SiO ₂ that adversely affect rolling fatigue characteristics. Doing so will increase the steelmaking cost. For these reasons, the O content needs to be 0.0025% or less. In addition, the upper limit with preferable O content is 0.002% (more preferably 0.0015% or less).

  The contained elements specified in the present invention are as described above, and the balance is iron and unavoidable impurities, and as the unavoidable impurities, mixing of elements brought in depending on the situation of raw materials, materials, manufacturing facilities, etc. can be allowed. In order to increase the rolling fatigue life, the following elements can be positively contained within a specified range.

[Selected from the group consisting of Cu: 0.25% or less (not including 0%), Ni: 0.25% or less (not including 0%), and Mo: 0.25% or less (not including 0%) One or more types]
Cu, Ni, and Mo are all elements that act as a hardenability improving element of the parent phase and contribute to improving rolling fatigue characteristics by increasing hardness. All of these effects are effectively exhibited by containing 0.03% or more. However, if any content exceeds 0.25%, the workability deteriorates.

[Nb: 0.5% or less (not including 0%), V: 0.5% or less (not including 0%) and B: 0.005% or less (not including 0%) One or more types]
Nb, V, and B are all effective elements for bonding with N to form a nitrogen compound to adjust the grain size and improve the rolling fatigue life. However, if Nb and V exceed 0.5% and B exceeds 0.005%, the crystal grains become finer and an incompletely quenched phase is likely to be generated. A more preferable upper limit is 0.3% (more preferably 0.1% or less) for Nb and V, and 0.003% (more preferably 0.001% or less) for B.

[Ca: 0.05% or less (not including 0%), REM: 0.05% or less (not including 0%), Mg: 0.02% or less (not including 0%), Li: 0.0. 02% or less (not including 0%) and Zr: one or more selected from the group consisting of 0.2% or less (not including 0%)]
Ca, REM (rare earth element), Mg, Li, and Zr are all elements that spheroidize oxide inclusions and contribute to improving the rolling fatigue life. These effects are effectively exhibited by containing 0.0005% or more in Ca and REM and 0.0001% or more in Mg, Li, and Zr. However, even if it is contained excessively, the effect is saturated, and an effect commensurate with the content cannot be expected, which is uneconomical. More preferable upper limits are 0.03% (more preferably 0.01% or less) for Ca and REM, 0.01% (more preferably 0.005% or less) for Mg and Li, and 0.15 for Zr. % (More preferably 0.10% or less).

[Pb: selected from the group consisting of 0.5% or less (not including 0%), Bi: 0.5% or less (not including 0%), and Te: 0.1% or less (not including 0%) One or more types]
Pb, Bi, and Te are all machinability improving elements. These effects are effectively exhibited by containing 0.01% or more of Pb and Bi and 0.0001% or more of Te. However, if the content of Pb and Bi exceeds 0.5% or the content of Te exceeds 0.1%, production problems such as generation of rolling flaws occur. A more preferable upper limit is 0.3% (more preferably 0.2% or less) for Pb and Bi, and 0.075% (more preferably 0.05% or less) for Te.

In the steel material of the present invention, in order to disperse the fine Al-based nitrogen compound in the steel after quenching and tempering, a slab satisfying the above component composition is used in the steel material production process, and the cooling rate after rolling is controlled. This is very important. The Al-based nitrogen compound that precipitates in the cooling process after rolling remains in the same state even after the subsequent spheroidizing annealing, parts processing, quenching / tempering process. Therefore, the temperature range from 850 to 650 ° C., which is the precipitation temperature range of the Al-based nitrogen compound, is set to a range of 0.1 to 0.7 ° C./second in terms of the primary cooling rate (average cooling rate), from less than 650 ° C. to room temperature. By cooling the secondary cooling rate (average cooling rate) up to (25 ° C.) at 1 ° C./second or more, an Al-based nitrogen compound having an equivalent circle diameter of 25 nm or more and 200 nm or less in the steel after quenching and tempering. It is possible to disperse 1.1 / μm ² or more and 6.0 / μm ² or less.

When the primary cooling rate is less than 0.1 ° C./second, the Al-based nitrogen compound becomes coarse, and when it exceeds 0.7 ° C./second, the circle-equivalent diameter of the Al-based nitrogen compound is less than 25 nm. The number density of the size becomes less than 1.1 pieces / μm ² , and a desired size cannot be obtained. Further, by setting the secondary cooling rate below 650 ° C. to 1 ° C./second or more, coarsening of the Al-based nitrogen compound can be suppressed, and the size thereof can be controlled.

  After performing the rolling process as described above, spheroidizing annealing is performed prior to forming into a predetermined part shape, but in order to control the area ratio of cementite and its size to an appropriate range. Further, it is necessary to appropriately control the spheroidizing annealing conditions (particularly the cooling rate after heating). In spheroidizing annealing, it is usually heated to 780 to 810 ° C. and held for a predetermined time (holding time: about 2 to 6 hours) and then cooled. The cooling conditions at this time are as follows: Average cooling rate from temperature to 750 ° C: 25-35 ° C / hour, (2) Average cooling rate from 750 ° C to 730 ° C: 3-7 ° C / hour, and (3) Average from 730 ° C to 680 ° C By controlling the cooling rate: 25 to 35 ° C./hour, the form of cementite can be controlled as described above.

  By controlling the average cooling rate from the heating and holding temperature to 750 ° C. and from 730 ° C. to 680 ° C. to 25 to 35 ° C./hour, the particle size (equivalent circle diameter) of cementite can be reduced. If the average cooling rate at this time is less than 25 ° C./hour, the cementite is coarsened and the particle size of the cementite is coarsened. On the other hand, when the average cooling rate is higher than 35 ° C./hour, regenerated pearlite is generated, quenching becomes uneven, and the life becomes unstable.

  On the other hand, by controlling the average cooling rate from 750 ° C. to 730 ° C. at 3 to 7 ° C./hour, the area ratio of cementite can be suppressed to 12% or less, and the average equivalent circle diameter of cementite can be made 0.60 μm or less. If the average cooling rate at this time is less than 3 ° C./hour, the amount of cementite generated increases, and the area ratio of cementite exceeds 12%. On the other hand, when the average cooling rate is higher than 7 ° C./hour, regenerated pearlite is generated, quenching becomes uneven, and the life becomes unstable.

  The steel material of the present invention is processed into a predetermined part shape after the spheroidizing annealing as described above, and is subsequently quenched and tempered to be manufactured into a bearing part or the like. It includes both linear and bar shapes that can be applied to such production, and the size can also be appropriately determined according to the final product.

  Hereinafter, the present invention will be described in more detail by way of examples.However, the present invention is not limited by the following examples as a matter of course, and may be implemented with modifications within a range that can meet the gist of the preceding and following descriptions. Of course, they are all possible and are included in the technical scope of the present invention.

  Steel materials (test Nos. 1 to 24) having various chemical compositions shown in Table 1 below were heated to 1100 to 1300 ° C. in a heating furnace or a soaking furnace, and then subjected to split rolling at 900 to 1200 ° C. Then, after heating to 900-1100 degreeC, it rolled (including the forging imitating rolling) and produced the round bar material of 70 mm in diameter. After rolling, the material is cooled at various average cooling rates from 850 to 650 ° C. (Table 2 below), and from 650 ° C. to room temperature (25 ° C.) at an average cooling rate of 1 ° C./sec. Or the forging material was obtained.

  After the rolled material or forged material is heated to 795 ° C. and held for a predetermined time (holding time: 2 to 6 hours), (1) an average cooling rate up to 750 ° C., (2) from 750 ° C. to 730 ° C. After performing spheroidizing annealing with various changes in the average cooling rate and (3) the average cooling rate from 730 ° C. to 680 ° C. (Table 2 below), the skin was cut by cutting. Thereafter, a disk (test piece) having a diameter of 60 mm and a thickness of 5 mm was cut out, subjected to oil quenching after heating at 840 ° C. for 30 minutes, and tempered at 160 ° C. for 120 minutes.

  Finally, finish polishing was performed to prepare a test piece having a surface roughness Rt (maximum cross-sectional roughness) of 0.45 μm or less.

  When using the test piece obtained above, the number, size, cementite area ratio, cementite size (equivalent circle diameter) of the Al-based nitrogen compound was measured under the following conditions, and when polished under the following conditions: The surface roughness (Rt) after polishing and polishing efficiency were measured, and the life inclination was further measured.

[Measurement of number and size of Al-based nitrogen compounds]
As a method for confirming the dispersion state of the Al-based nitrogen compound, the test piece after the heat treatment was cut, this section was polished, carbon was then deposited on the surface, and FE-TEM (field emission transmission electron microscope) was used. Replica observation was performed. At this time, components of an Al-based nitrogen compound containing Al and N were specified by TEM EDX (energy dispersive X-ray detector), and the field of view was observed at a magnification of 30000 times. At this time, 1 field of view is set to 16.8 μm ^2, and arbitrary 3 fields of view are observed (total 50.4 μm ² ), and particle analysis software [“Particle Analysis III for Windows. Version 3.00 SUMITOMO METAL TECHNOLOGY” (trade name) ] And the average equivalent circle diameter and the number (number is converted per μm ² ).

[Measurement of area ratio and size of cementite]
(A) The test piece was cut perpendicular to the longitudinal direction.
(B) The resin was embedded in a resin so that the cross section could be observed, and polishing with emery paper, diamond buffing, and electrolytic polishing were sequentially performed to finish the observation surface as a mirror surface.
(C) Corroded with nital (3% nitric acid ethanol solution).
(D) The position of D / 4 (D is a diameter) of the test piece (disk) was observed at an SEM magnification of 2000 times and photographed at four locations.
(E) Using the above particle analysis software [“Particle analysis III for Windows. The area ratio was obtained, and the average value of the four fields of view was defined as the area ratio of cementite. Also, the equivalent circle diameter was calculated from the size of each cementite, and the average value of the four fields of view was obtained (adopted as “average equivalent circle diameter”).

[Surface roughness after polishing, polishing efficiency]
From the position of D / 4 (D is the diameter) of the test piece (disk) obtained above, a cross section: a 4 mm × 4 mm square bar (length: 5 mm) is cut out, and a cross section (4 mm × 5 mm surface) is cut out. The test surface was embedded in a bakelite resin, and using an automatic polishing machine (“Tegura Fall / Tegura Force”, trade name: manufactured by Marumoto Struers), load: 30 N, polishing speed: 3 m / second (both rough polishing and finish polishing) Polishing was performed under the conditions of Rough polishing was performed with # 180 water-resistant paper for 10 minutes, and final polishing was performed with diamond paste (diamond buff) for 1 hour. After rough polishing, an indentation of Vickers was applied, the dimensions were measured, and after final polishing, the dimensions of the indentation of Vickers were re-measured and converted into a polishing amount (μm / hour) as an index of polishing efficiency. It can be determined that the polishing efficiency is good when the polishing amount is 0.40 μm / hour or more.

  Moreover, the surface roughness (maximum cross-sectional roughness Rt: JIS B0601) was calculated | required about the test piece after the said grinding | polishing. At this time, the reference length: 0.25 mm, the number of sections: 5, the cut-off value λc of the contour curve filter: 0.25 mm, and the cut-off value λs: 0.0025 mm. It can be judged that the surface properties are excellent when the roughness after polishing is 0.40 μm or less in Rt.

[Measurement of life inclination]
Using a thrust type rolling fatigue tester, rolling was performed using 16 samples for each steel material (test piece) under conditions of repetition rate: 1500 rpm, surface pressure: 5.3 GPa, number of interruptions: 2 × 10 ⁸ times. Dynamic fatigue characteristics were implemented. The value of the wiper coefficient m was used as an index of fatigue life stability. This value is the slope (lifetime slope) of the approximate curve when the test result is plotted on the wiper probability paper. The larger the value of this slope, the better the fatigue life stability, and when the life slope was 0.6 or more, it was evaluated that the life stability was excellent.

  The number, size (average circle equivalent diameter), cementite area ratio, cementite size (average circle equivalent diameter) of Al-based nitrogen compounds in each steel material are shown in Table 3 below, and surface roughness Rt after polishing and polishing efficiency The life inclination is shown in Table 4 below.

  From these results, it can be considered as follows. That is, test no. 3, 4, and 6 to 19 satisfy the requirements defined in the present invention (chemical component composition, size, number of Al-based nitrogen compounds, cementite area ratio, size), and all are polished. It can be seen that the roughness Rt and the polishing efficiency are also good (polishing efficiency judgment “◯”), and the stability of the rolling fatigue life is good (life inclination judgment “◯”) (overall judgment “◯”).

  In contrast, test no. In the cases of 1, 2, 5, 20-24, since any of the requirements defined in the present invention is not met, at least one of the roughness Rt after polishing, the polishing efficiency, and the life inclination is deteriorated (overall) Judgment “×”).

  Test No. In Nos. 1 and 2, the cooling rate condition after rolling is not appropriate, so the number density or size of the Al-based nitrogen compound is not appropriate, and the post-polishing roughness Rt is rough.

  Test No. In No. 5, since the primary cooling rate after rolling and the spheroidizing conditions are not appropriate, the number density and size of the Al-based nitrogen compound are not appropriate, and the area ratio of cementite is large, and the roughness after polishing is large. Rt becomes coarse and the polishing efficiency is low (polishing efficiency judgment “x”).

  Test No. Nos. 20, 22, and 23 do not satisfy the chemical component composition defined in the present invention, and the area ratio of cementite is excessive, and the polishing efficiency is reduced in all cases (polishing efficiency determination “×” ").

  Test No. In No. 21, since the C content is excessive, the area ratio and size of cementite are excessive, and the polishing efficiency is reduced (Polishing efficiency judgment “x”).

  Test No. In the case of No. 24, since the Ti content is excessive, the number density of the Al-based nitrogen compound is lowered correspondingly, and the cementite is excessive in size, and the life inclination is deteriorated. (Life inclination judgment “×”).

  Of the data shown above, test no. Based on the results of 1 to 5, the relationship between the number density of the Al-based nitrogen compound and the steel surface roughness Rt is shown in FIG. 1, and the relationship between the size of the Al-based nitrogen compound (equivalent circle diameter) and the steel surface roughness Rt is shown in FIG. As shown in FIG. 2, it can be seen that good surface properties (Rt 0.40 μm or less) can be achieved by appropriately controlling the number density and size of the Al-based nitrogen compound.

  Test No. above. Based on the results of 1 to 5, the relationship between the steel surface roughness Rt and the life inclination is shown in FIG. 3. By making the surface properties good, the life stability (life inclination is 0.6 or more) is achieved. I understand that

  Similarly, FIG. 4 shows the relationship between the cementite area ratio and polishing efficiency, and FIG. 5 shows the relationship between the cementite size (average circle equivalent diameter) and polishing efficiency. It can be seen that good polishing efficiency is achieved by controlling.

Claims (5)

C: 0.65 to 1.10% (meaning of mass%, the same shall apply hereinafter), Si: 0.05 to 1.0%, Mn: 0.1 to 2%, P: 0.05% or less (0% ), S: 0.05% or less (excluding 0%), Cr: 0.15-2.0%, Al: 0.01-0.1%, N: 0.025% or less ( 0% not included), Ti: 0.002% or less (not including 0%) and O: 0.0025% or less (not including 0%), respectively, the balance being iron and inevitable impurities, steel The average equivalent circle diameter of the Al-based nitrogen compound dispersed therein is 60 nm or more, the number density of Al-based nitrogen compounds having an equivalent circle diameter of 25 to 200 nm is 1.1 / μm ² or more, and the cementite The area ratio is 12% or less and the average equivalent circle diameter of cementite is 0.60 μm or less. Excellent steel stability of the rolling fatigue life to symptoms.   Further, as other elements, Cu: 0.25% or less (not including 0%), Ni: 0.25% or less (not including 0%) and Mo: 0.25% or less (not including 0%) The steel material excellent in stability of the rolling fatigue life of Claim 1 containing 1 or more types selected from the group which consists of.   Further, as other elements, Nb: 0.5% or less (not including 0%), V: 0.5% or less (not including 0%), and B: 0.005% or less (not including 0%) The steel material excellent in stability of the rolling fatigue life of Claim 1 or 2 containing 1 or more types selected from the group which consists of.   Further, as other elements, Ca: 0.05% or less (not including 0%), REM: 0.05% or less (not including 0%), Mg: 0.02% or less (not including 0%) , Li: 0.02% or less (not including 0%) and Zr: 0.2% or less (not including 0%), including at least one selected from the group consisting of Steel material with excellent stability of rolling fatigue life as described in 1.   Further, as other elements, Pb: 0.5% or less (not including 0%), Bi: 0.5% or less (not including 0%), and Te: 0.1% or less (not including 0%) The steel material excellent in stability of the rolling fatigue life in any one of Claims 1-4 containing 1 or more types selected from the group which consists of.

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