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Publication number
JP2011150020A5
JP2011150020A5 JP2010009365A JP2010009365A JP2011150020A5 JP 2011150020 A5 JP2011150020 A5 JP 2011150020A5 JP 2010009365 A JP2010009365 A JP 2010009365A JP 2010009365 A JP2010009365 A JP 2010009365A JP 2011150020 A5 JP2011150020 A5 JP 2011150020A5
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Japan
Prior art keywords
toner
image
toner particles
developing
white
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JP2010009365A
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Japanese (ja)
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JP5434620B2 (en
JP2011150020A (en
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Priority claimed from JP2010009365A external-priority patent/JP5434620B2/en
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Publication of JP2011150020A5 publication Critical patent/JP2011150020A5/ja
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Description

上記課題は、以下の手段により解決される。即ち、
請求項1に係る発明は、
白色の着色剤を含む第1トナー粒子と、
前記第1トナー粒子よりも少ない着色剤量で着色剤を含む又は着色剤を含まない第2トナー粒子であって、含有量が全トナー粒子に対して1個数%以上30個数%以下である第2トナー粒子と、
を有する静電荷像現像用白色トナー。
The above problem is solved by the following means. That is,
The invention according to claim 1
First toner particles comprising a white colorant;
A second toner particle containing a colorant in a smaller colorant amount than the first toner particles or containing no colorant , wherein the content is 1% by number to 30% by number with respect to all toner particles. Two toner particles ;
A white toner for developing an electrostatic charge image.

請求項に係る発明は、
前記第1トナー粒子と前記第2トナー粒子とが、同一種類の結着樹脂を含む請求項1に記載の静電荷像現像用白色トナー。
The invention according to claim 2
The white toner for developing electrostatic images according to claim 1, wherein the first toner particles and the second toner particles contain the same type of binder resin.

請求項に係る発明は、
前記第1トナー粒子と前記第2トナー粒子とが離型剤を含み、且つ前記第2トナー粒子の離型剤量が前記第1トナー粒子の離型剤量よりも多い請求項1又は2に記載の静電荷像現像用白色トナー。
The invention according to claim 3
The includes a first toner particles and the second toner particles a release agent, and to claim 1 or 2 larger than the release agent of the release agent amount the first toner particles of the second toner particles 2. A white toner for developing an electrostatic charge image.

請求項に係る発明は、
前記第1トナー粒子の体積平均粒径をD50w、前記第2トナー粒子の体積平均粒径をD50cとしたとき、D50w=D50c±0.5μmの関係を満たす請求項1〜のいずれか1項に記載の静電荷像現像用白色トナー。
The invention according to claim 4
D50w the volume average particle diameter of the first toner particles, when the volume average particle diameter of the second toner particles and D50c, any one of claim 1 to 3 satisfying the relation of D50w = D50c ± 0.5μm 2. A white toner for developing electrostatic images as described in 1.

請求項に係る発明は、
請求項1〜のいずれか1項に記載の静電荷像現像用白色トナーを少なくとも含む静電荷像現像剤。
The invention according to claim 5
An electrostatic charge image developer comprising at least the white toner for developing an electrostatic charge image according to any one of claims 1 to 4 .

請求項に係る発明は、
請求項1〜のいずれか1項に記載の静電荷像現像用白色トナーを収納し、
画像形成装置に着脱されるトナーカートリッジ。
The invention according to claim 6
Containing the white toner for developing an electrostatic charge image according to any one of claims 1 to 4 ,
A toner cartridge to be attached to and detached from the image forming apparatus.

請求項に係る発明は、
請求項に記載の静電荷像現像剤を収納し、潜像保持体上に形成された静電潜像を前記静電荷像現像剤により現像してトナー像を形成する現像手段を備え、
画像形成装置に着脱されるプロセスカートリッジ。
The invention according to claim 7 provides:
A developing unit that stores the electrostatic image developer according to claim 5 and that develops an electrostatic latent image formed on the latent image holding member with the electrostatic image developer to form a toner image,
A process cartridge attached to and detached from the image forming apparatus.

請求項に係る発明は、
請求項1〜のいずれか1項に記載の静電荷像現像用白色トナーによる白色トナー画像を、被転写体に形成する第1画像形成手段と、
静電荷像現像用カラートナーによるカラー画像を、前記被転写体に形成する第2画像形成手段と、
を備える画像形成装置。
The invention according to claim 8 provides:
A first image forming unit that forms a white toner image by the white toner for developing an electrostatic charge image according to any one of claims 1 to 4 on a transfer target;
A second image forming means for forming a color image with a color toner for developing an electrostatic image on the transfer member;
An image forming apparatus comprising:

請求項1に係る発明によれば、第1トナー粒子よりも少ない着色剤量で着色剤を含む又は着色剤を含まない第2トナー粒子を有さない場合に比べ、折り曲げ強度が高い白色トナー画像が得られる。
請求項に係る発明によれば、第2トナー粒子の含有量が全トナー粒子に対して上記範囲外に比べ、白色度及び隠蔽性の高い白色トナー画像が得られる。
請求項に係る発明によれば、第1トナー粒子と第2トナー粒子とが同一種類の結着樹脂を含まない場合に比べ、折り曲げ強度が高い白色トナー画像が得られる。

請求項に係る発明によれば、第2トナー粒子の離型剤量が第1トナー粒子の離型剤量よりも少ない場合に比べ、摺擦性の高い白色トナー画像が得られる。
請求項に係る発明によれば、第1トナー粒子及び第2トナー粒子の体積平均粒径の関係が上記関係を満たさない場合に比べ、折り曲げ強度が高い白色トナー画像が得られる。
請求項5、6、7、8に係る発明によれば、第1トナー粒子よりも少ない着色剤量で着色剤を含む又は着色剤を含まない第2トナー粒子を有さない静電荷像現像用白色トナーを適用した場合に比べ、曲げ強度が高い白色トナー画像が得られる。
According to the first aspect of the present invention, the white toner image has a higher bending strength than the case where the second toner particles containing the colorant or containing no colorant are contained in a smaller amount of the colorant than the first toner particles. Is obtained.
According to the first aspect of the invention, it is possible to obtain a white toner image having a higher whiteness and concealment than the content of the second toner particles out of the above range with respect to all toner particles.
According to the second aspect of the present invention, a white toner image having a higher bending strength can be obtained than when the first toner particles and the second toner particles do not contain the same type of binder resin.

According to the third aspect of the present invention, a white toner image having a higher rubbing property can be obtained than when the amount of the release agent of the second toner particles is smaller than the amount of the release agent of the first toner particles.
According to the fourth aspect of the invention, a white toner image having a high bending strength can be obtained as compared with the case where the relationship between the volume average particle diameters of the first toner particles and the second toner particles does not satisfy the above relationship.
According to the inventions according to claims 5 , 6 , 7, and 8 , for developing an electrostatic charge image that has a colorant amount smaller than that of the first toner particles and that contains no colorant or no second toner particles. A white toner image having a higher bending strength can be obtained than when white toner is applied.

(静電荷像現像用白色トナー)
本実施形態に係る静電荷像現像用白色トナー(以下、単に「白色トナー」と称する)は、白色の着色剤を含む第1トナー粒子(以下、便宜上、白色トナー粒子と称する)と、第1トナー粒子よりも少ない着色剤量で着色剤を含む又は着色剤を含まない第2トナー粒子(以下、便宜上、透明トナー粒子と称する)と、を含んで構成される。
但し、本実施形態に係る白色トナーでは、第2トナー粒子の含有量は、全トナー粒子に対して1個数%以上30個数%以下である。
(White toner for developing electrostatic images)
The white toner for developing an electrostatic charge image (hereinafter simply referred to as “white toner”) according to the present embodiment includes a first toner particle containing a white colorant (hereinafter referred to as white toner particle for convenience) and a first toner. And a second toner particle containing a colorant or containing no colorant (hereinafter referred to as transparent toner particles for the sake of convenience) in a smaller amount of colorant than the toner particles.
However, in the white toner according to the present embodiment, the content of the second toner particles is 1% by number or more and 30% by number or less with respect to all the toner particles.

以下、実施例及び比較例を挙げ、本実施形態をより具体的に詳細に説明するが、本実施形態はこれらの実施例に何ら限定されるものではない。但し、実施例6及び9は、参考例に該当する。なお、「部」とは、特に断りがない限り、「質量部」を意味する。 Hereinafter, although an Example and a comparative example are given and this embodiment is described in detail in detail, this embodiment is not limited to these Examples at all. However, Examples 6 and 9 correspond to reference examples. The “part” means “part by mass” unless otherwise specified.

Claims (8)

白色の着色剤を含む第1トナー粒子と、
前記第1トナー粒子よりも少ない着色剤量で着色剤を含む又は着色剤を含まない第2トナー粒子であって、含有量が全トナー粒子に対して1個数%以上30個数%以下である第2トナー粒子と、
を有する静電荷像現像用白色トナー。
First toner particles comprising a white colorant;
A second toner particle containing a colorant in a smaller colorant amount than the first toner particles or containing no colorant , wherein the content is 1% by number to 30% by number with respect to all toner particles. Two toner particles ;
A white toner for developing an electrostatic charge image.
前記第1トナー粒子と前記第2トナー粒子とが、同一種類の結着樹脂を含む請求項に記載の静電荷像現像用白色トナー。 The white toner for developing electrostatic images according to claim 1 , wherein the first toner particles and the second toner particles contain the same type of binder resin. 前記第1トナー粒子と前記第2トナー粒子とが離型剤を含み、且つ前記第2トナー粒子の離型剤量が前記第1トナー粒子の離型剤量よりも多い請求項1又は2に記載の静電荷像現像用白色トナー。 The includes a first toner particles and the second toner particles a release agent, and to claim 1 or 2 larger than the release agent of the release agent amount the first toner particles of the second toner particles 2. A white toner for developing an electrostatic charge image. 前記第1トナー粒子の体積平均粒径をD50w、前記第2トナー粒子の体積平均粒径をD50cとしたとき、D50w=D50c±0.5μmの関係を満たす請求項1〜のいずれか1項に記載の静電荷像現像用白色トナー。 D50w The volume average particle diameter of the first toner particles, when the volume average particle diameter of the second toner particles and D50c, any one of claim 1 to 3 satisfying the relation of D50w = D50c ± 0.5μm 2. A white toner for developing electrostatic images as described in 1. 請求項1〜のいずれか1項に記載の静電荷像現像用白色トナーを少なくとも含む静電荷像現像剤。 An electrostatic charge image developer comprising at least the white toner for developing an electrostatic charge image according to any one of claims 1 to 4 . 請求項1〜のいずれか1項に記載の静電荷像現像用白色トナーを収納し、
画像形成装置に着脱されるトナーカートリッジ。
Containing the white toner for developing an electrostatic charge image according to any one of claims 1 to 4 ,
A toner cartridge to be attached to and detached from the image forming apparatus.
請求項に記載の静電荷像現像剤を収納し、潜像保持体上に形成された静電潜像を前記静電荷像現像剤により現像してトナー像を形成する現像手段を備え、
画像形成装置に着脱されるプロセスカートリッジ。
A developing unit that stores the electrostatic image developer according to claim 5 and that develops an electrostatic latent image formed on the latent image holding member with the electrostatic image developer to form a toner image,
A process cartridge attached to and detached from the image forming apparatus.
請求項1〜のいずれか1項に記載の静電荷像現像用白色トナーによる白色トナー画像を、被転写体に形成する第1画像形成手段と、
静電荷像現像用カラートナーによるカラー画像を、前記被転写体に形成する第2画像形成手段と、
を備える画像形成装置。
A first image forming unit that forms a white toner image by the white toner for developing an electrostatic charge image according to any one of claims 1 to 4 on a transfer target;
A second image forming means for forming a color image with a color toner for developing an electrostatic image on the transfer member;
An image forming apparatus comprising:
JP2010009365A 2010-01-19 2010-01-19 White toner for developing electrostatic image, electrostatic image developer, toner cartridge, process cartridge, and image forming apparatus Expired - Fee Related JP5434620B2 (en)

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Applications Claiming Priority (1)

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JP2010009365A JP5434620B2 (en) 2010-01-19 2010-01-19 White toner for developing electrostatic image, electrostatic image developer, toner cartridge, process cartridge, and image forming apparatus

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JP2011150020A JP2011150020A (en) 2011-08-04
JP2011150020A5 true JP2011150020A5 (en) 2013-03-07
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JP6260808B2 (en) * 2012-06-11 2018-01-17 株式会社リコー White toner for developing electrostatic image and method for producing the same, developer using the white toner, and image forming apparatus
WO2014077171A1 (en) * 2012-11-16 2014-05-22 富士フイルム株式会社 White photosensitive resin composition, white cured film, white pattern, and method for producing white pattern
JP6167869B2 (en) * 2013-11-15 2017-07-26 富士ゼロックス株式会社 Electrostatic image developer, process cartridge, image forming method, and image forming apparatus
JP6676909B2 (en) * 2015-09-28 2020-04-08 富士ゼロックス株式会社 White toner, white toner set, colored toner set, developer, cartridge, image forming method, and image forming apparatus
JP2017120323A (en) * 2015-12-28 2017-07-06 富士ゼロックス株式会社 Toner for electrostatic charge image development, electrostatic charge image developer, toner cartridge, process cartridge, image forming apparatus, and image forming method
JP6872113B2 (en) * 2016-12-08 2021-05-19 富士フイルムビジネスイノベーション株式会社 Toner set, developer set, toner cartridge set, image forming apparatus and image forming method
JP7222808B2 (en) * 2019-05-20 2023-02-15 キヤノン株式会社 white toner
JP7364498B2 (en) * 2020-03-04 2023-10-18 シャープ株式会社 Two-component developer and its manufacturing method
JP7004054B2 (en) * 2020-12-04 2022-02-10 富士フイルムビジネスイノベーション株式会社 White toner, electrostatic charge image developer, toner cartridge, process cartridge, image forming device and image forming method

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JPH05107798A (en) * 1991-10-18 1993-04-30 Minolta Camera Co Ltd White toner for developing electrostatic charge image
JPH10260554A (en) * 1997-03-18 1998-09-29 Kao Corp White toner and method for producing the same
JP3351347B2 (en) * 1997-12-19 2002-11-25 富士ゼロックス株式会社 Image forming method
JP2002108021A (en) * 2000-09-28 2002-04-10 Konica Corp White toner and image forming apparatus
JP4525506B2 (en) * 2005-07-25 2010-08-18 富士ゼロックス株式会社 Toner for developing electrostatic image, developer for developing electrostatic image, and image forming method
JP2008197592A (en) * 2007-02-16 2008-08-28 Ricoh Co Ltd Developing device, process cartridge, and image forming apparatus

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