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JP2010501733A - Steel for producing a mechanical member having higher strength and capable of breaking and separating, and processing method - Google Patents

Steel for producing a mechanical member having higher strength and capable of breaking and separating, and processing method Download PDF

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JP2010501733A
JP2010501733A JP2009525910A JP2009525910A JP2010501733A JP 2010501733 A JP2010501733 A JP 2010501733A JP 2009525910 A JP2009525910 A JP 2009525910A JP 2009525910 A JP2009525910 A JP 2009525910A JP 2010501733 A JP2010501733 A JP 2010501733A
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steel
chemical composition
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cooling
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ディーデリヒス ローマン
シュテューバー アクセル
ランゲ ロベルト
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Georgsmarienhuette GmbH
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/48Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)
  • Heat Treatment Of Articles (AREA)
  • Forging (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

本発明は、化学組成が質量パーセントで以下の含有率:0.40%≦C≦0.60%、0.20%≦Si≦1.00%、0.50%≦Mn≦1.50%、0%≦Cr≦1.00%、0%≦Ni≦0.50%、0%≦Mo≦0.20%、0%≦Nb≦0.050%、0%≦V≦0.30%、0%≦Al≦0.05%、0.005%≦N≦0.020%(この際、残分は鉄、および精錬条件による不純物、および残留物質から成る)を有することを特徴とする、少なくとも2の破断分離可能な部材から成る、より強度の高い、破断分離可能な機械部材のための鋼、および加工方法に関する。  In the present invention, the chemical composition has a mass percentage of the following contents: 0.40% ≦ C ≦ 0.60%, 0.20% ≦ Si ≦ 1.00%, 0.50% ≦ Mn ≦ 1.50% 0% ≦ Cr ≦ 1.00%, 0% ≦ Ni ≦ 0.50%, 0% ≦ Mo ≦ 0.20%, 0% ≦ Nb ≦ 0.050%, 0% ≦ V ≦ 0.30% , 0% ≦ Al ≦ 0.05%, 0.005% ≦ N ≦ 0.020% (in this case, the balance is composed of iron, impurities due to refining conditions, and residual substances) , A steel for a higher strength, separable mechanical member comprising at least two breakable separable members, and a processing method.

Description

本発明は、より強度の高い、破断分離可能な機械部材を製造するための鋼、および加工方法に関する。この素材は例えば、クラッキングコンロッドを製造するために開発した。   The present invention relates to a steel for manufacturing a mechanical member having higher strength and capable of breaking and separating, and a processing method. This material was developed, for example, to produce cracking connecting rods.

鋼は、鍛造またはその他の熱間成形に適していなければならない。鍛造熱から制御しながら冷却することよって、750N/mm2超の降伏強度、1000〜1200N/mm2の引張強度、10%超の破断点伸び、および25%超の断面収縮率を有する、ほぼパーライト構造を調整しなければならない。特に重要なのは、破断分離に適していることである。 The steel must be suitable for forging or other hot forming. I'll be cooled while controlling the forging heat, 750 N / mm 2 greater than the yield strength, tensile strength of 1000~1200N / mm 2, elongation at break of greater than 10%, and having a cross-sectional shrinkage of greater than 25 percent, almost The pearlite structure must be adjusted. Of particular importance is its suitability for break separation.

所望の特性は、特殊カーバイド(Sondercarbid)(炭化ニオブ、および炭化バナジウム)の析出、ならびに硫化マンガンの析出によるパーライト構造の適切な調整によって、相応して調整することができる化学組成によって、原材料の製造における、ならびに部材の仕上げ鍛造(熱機械的処理)における熱変形の間、適切に温度管理することによって、行われた鍛造後もしくは熱変形後に熱処理を調整することによって達成することができる。   The desired properties are the production of raw materials by the chemical composition that can be adjusted accordingly by the appropriate adjustment of the pearlite structure by precipitation of special carbides (niobium carbide and vanadium carbide) and manganese sulfide. This can be achieved by adjusting the heat treatment after the forging performed or after the thermal deformation by appropriately controlling the temperature during thermal deformation in the forging as well as in the finish forging (thermomechanical treatment) of the member.

これまでこの使用目的のためには、例えば約0.7%のC、0.5〜0.9%のMn、0.06%〜0.07%のS、および場合によっては0.1〜0.2%のV(C70S6、70MnVS4)のほぼ共析組成の鋼か、または約0.4%のC、約1%のMn、0.06〜0.07%のS、および約0.3%のV(36MnVS4)の平均炭素含分のほぼ共析組成の鋼を、技術的な顧客マニュアルに従って使用する。   So far for this purpose of use, for example, about 0.7% C, 0.5-0.9% Mn, 0.06% -0.07% S, and in some cases 0.1-0.1% 0.2% V (C70S6, 70MnVS4) nearly eutectoid steel, or about 0.4% C, about 1% Mn, 0.06-0.07% S, and about 0.0. An approximately eutectoid steel with an average carbon content of 3% V (36MnVS4) is used according to the technical customer manual.

これらの鋼は炭化バナジウムならびに硫化マンガンによってほぼパーライト構造を有し、かつ機械的特性の点で既定値を満たす。公知の材料変法の欠点は、従来の材料変法が高価な、かつ不足がちな合金材の原料を多く消費することにある。とりわけバナジウムは現在、析出硬化されるフェライト−パーライト鋼(AFP鋼)の領域においてますます使用され、このことによってバナジウムはますます不足がちな材料になっている。   These steels have a pearlite structure with vanadium carbide and manganese sulfide, and satisfy the predetermined values in terms of mechanical properties. A disadvantage of the known material modification is that the conventional material modification consumes a large amount of raw materials for alloy materials which are expensive and tend to be insufficient. In particular, vanadium is now increasingly used in the field of precipitation-hardened ferritic-pearlite steel (AFP steel), which makes vanadium an increasingly prone material.

本発明の目的は、強度(および疲労強度)に関して要求される機械的特性を有し、かつ付加的に引っ張り試験における良好な引張強度特性と、同時に良好なクラッキング性とを統合させた、新規の鋼の提案による前述の欠点の回避である。同時にこの鋼は、良好にストランド注型可能であり、かつ鍛造可能であるのが望ましい。さらに新規の鋼は、バナジウム含分をニオブにより部分的に置換することによって、相応して適合された変形法、および冷却法で公知の鋼より原料を節約して製造可能であるのが望ましい。   The object of the present invention is to provide a novel material that has the required mechanical properties with respect to strength (and fatigue strength), and additionally integrates good tensile strength properties in tensile testing and at the same time good cracking properties. It is the avoidance of the aforementioned drawbacks by the proposal of steel. At the same time, it is desirable that the steel be well castable and forged. Furthermore, it is desirable that the new steel can be produced by replacing the vanadium content partially with niobium, with correspondingly adapted deformation methods and cooling methods, saving raw materials over known steels.

降伏強度に対する高い値は、化学的な基本組成に加えて、可能な限り細かく分散させた、特殊なカーバイドを形成するニオブの、およびバナジウムのカーバイドを析出させることによって得られる。このために、最後の熱変形工程の前に、存在するカーバイドを溶解させることが必要となり、ならびに熱変形の間、および引き続いた冷却の間に制御された温度管理が必要となる。細かく分散された析出はとりわけ、低い最終変形温度において、引き続き直ちに冷却を加速することによって得ることができる。これによって特に、降伏強度が高められ、ひいては降伏強度比が決定的に改善される。   High values for yield strength are obtained by precipitating niobium and vanadium carbides that form special carbides, dispersed as finely as possible, in addition to the basic chemical composition. This necessitates the dissolution of the existing carbides prior to the final heat deformation step, and a controlled temperature management during heat deformation and subsequent cooling. Finely dispersed precipitates can be obtained, inter alia, by immediately accelerating cooling at low final deformation temperatures. This in particular increases the yield strength and thus improves the yield strength ratio decisively.

引張強度は、0.5%のC、0.6%のSi、1.0%のMn、0.23%のCr、0.2%のNi、および0.14%のVという基本組成によって規定される基本値から、熱変形後に直ちに冷却を加速することによって同様に所望の範囲に調整することができる。   Tensile strength is determined by the basic composition of 0.5% C, 0.6% Si, 1.0% Mn, 0.23% Cr, 0.2% Ni, and 0.14% V. From the specified basic value, it can be adjusted to a desired range in the same manner by accelerating cooling immediately after thermal deformation.

靭性の固有値はとりわけ、0.06%〜0.07%の硫黄を適切に加えて合金化することによって限定する。この意味において同様に、炭素含分と比較的高い窒素含分が肯定的に作用する。   The intrinsic value of toughness is limited, inter alia, by appropriate addition of 0.06% to 0.07% sulfur and alloying. In this sense as well, the carbon content and the relatively high nitrogen content act positively.

素材の良好なクラッキング性に決定的なのは、マクロスコピックな変形をしない結晶破壊である。これは、高い炭素含分、高い窒素含分、および高い硫黄含分、および比較的僅少なクロム含分、比較的僅少なニッケル含分、および比較的僅少なモリブデン含分という合金構想によって設定する。   What is decisive for the good cracking property of the material is crystal fracture without macroscopic deformation. This is set by the alloy concept of high carbon content, high nitrogen content, and high sulfur content, and relatively little chromium content, relatively little nickel content, and relatively little molybdenum content. .

解決法によれば本発明は、質量パーセントで以下の化学組成:
0.4%≦C≦0.6%;0.2%≦Si≦1.0%;0.5%≦Mn≦1.5%;0%≦Cr≦1.0%;0%≦Ni≦0.5%;0%≦Mo≦0.2%;0%≦Nb≦0.05%;0%≦V≦0.3%;0%≦Al≦0.05%;0.005%≦N≦0.020%(この際、残分は鉄、および精錬条件による不純物から成る)
を有する、自動車工業のための、破断分離可能な部材を製造するための鋼に関する。
According to the solution, the present invention has the following chemical composition in weight percent:
0.4% ≦ C ≦ 0.6%; 0.2% ≦ Si ≦ 1.0%; 0.5% ≦ Mn ≦ 1.5%; 0% ≦ Cr ≦ 1.0%; 0% ≦ Ni ≦ 0.5%; 0% ≦ Mo ≦ 0.2%; 0% ≦ Nb ≦ 0.05%; 0% ≦ V ≦ 0.3%; 0% ≦ Al ≦ 0.05%; 0.005% ≦ N ≦ 0.020% (in this case, the balance consists of iron and impurities due to refining conditions)
The invention relates to a steel for producing a break-separable member for the automotive industry.

従来の変法の欠点は?
・部分的に、0.29%V(36MnVS4)によるコストの高い合金フラックス(LZ)
・特許された鋼材料に対してほとんど代替物にならない
新規の変法の利点は?
・より僅少な合金コスト(わずかに0.14%のV)
・顧客が、特許された唯一の鋼材料に依存しない
What are the disadvantages of the traditional variants?
-Partially expensive alloy flux (LZ) with 0.29% V (36MnVS4)
• What are the advantages of the new variant that is hardly a substitute for the patented steel material?
・ Lower alloy costs (only 0.14% V)
・ Customers do not depend on the only patented steel material

Claims (15)

少なくとも2の破断分離可能な部材から成ることを特徴とする、より強度の高い、破断分離可能な機械部材のための鋼、および加工方法において、該鋼の化学組成が質量パーセントで以下の含分:
0.40%≦C≦0.60%
0.20%≦Si≦1.00%
0.50%≦Mn≦1.50%
0%≦Cr≦1.00%
0%≦Ni≦0.50%
0%≦Mo≦0.20%
0%≦Nb≦0.050%
0%≦V≦0.30%
0%≦Al≦0.05%
0.005%≦N≦0.020%
(この際、残分は鉄、および精錬条件による不純物と残留物質から成る)を有することを特徴とする、より強度の高い、破断分離可能な機械部材のための鋼、および加工方法。
A steel for a stronger, breakable separable mechanical member, characterized in that it comprises at least two breakable separable members, and a processing method, wherein the chemical composition of the steel is :
0.40% ≦ C ≦ 0.60%
0.20% ≦ Si ≦ 1.00%
0.50% ≦ Mn ≦ 1.50%
0% ≦ Cr ≦ 1.00%
0% ≦ Ni ≦ 0.50%
0% ≦ Mo ≦ 0.20%
0% ≦ Nb ≦ 0.050%
0% ≦ V ≦ 0.30%
0% ≦ Al ≦ 0.05%
0.005% ≦ N ≦ 0.020%
A steel for a mechanical member having a higher strength and capable of being separated by breakage, and a processing method, characterized in that the residue comprises iron and impurities and residual substances due to refining conditions.
前記鋼の化学組成が、以下の
0.10%≦V≦0.20%
に当てはまることを特徴とする、請求項1に記載の鋼。
The steel has a chemical composition of the following 0.10% ≦ V ≦ 0.20%
The steel according to claim 1, characterized in that:
前記鋼の化学組成が、以下の
0.020%≦Nb≦0.030%
に当てはまることを特徴とする、請求項1または2に記載の鋼。
The steel has a chemical composition of 0.020% ≦ Nb ≦ 0.030% as follows:
3. Steel according to claim 1 or 2, characterized in that
前記鋼の化学組成が、以下の
0.010%≦N≦0.020%
に当てはまることを特徴とする、請求項1から3までのいずれか1項に記載の鋼。
The chemical composition of the steel is 0.010% ≦ N ≦ 0.020% as follows:
The steel according to any one of claims 1 to 3, characterized in that:
前記鋼の化学組成が、以下の
0.45%≦C≦0.55%
0.50%≦Si≦0.70%
0.90%≦Mn≦1.10%
0.10%≦Cr≦0.40%
0.10%≦Ni≦0.30%
0.10%≦V≦0.20%
0.010%≦Al≦0.020%
0.020%≦Nb≦0.030%
0.010%≦N≦0.020%
に当てはまることを特徴とする、請求項1から4までのいずれか1項に記載の鋼。
The chemical composition of the steel is 0.45% ≦ C ≦ 0.55% as follows:
0.50% ≦ Si ≦ 0.70%
0.90% ≦ Mn ≦ 1.10%
0.10% ≦ Cr ≦ 0.40%
0.10% ≦ Ni ≦ 0.30%
0.10% ≦ V ≦ 0.20%
0.010% ≦ Al ≦ 0.020%
0.020% ≦ Nb ≦ 0.030%
0.010% ≦ N ≦ 0.020%
The steel according to any one of claims 1 to 4, characterized in that:
前記鋼の化学組成が、以下の
0.45%≦C≦0.55%
0.50%≦Si≦0.70%
0.90%≦Mn≦1.10%
0.10%≦Cr≦0.40%
0.10%≦Ni≦0.30%
0.10%≦V≦0.20%
0.010%≦Al≦0.020%
0.020%≦Nb≦0.030%
0.010%≦N≦0.020%
0.020%≦Ti≦0.030%
に当てはまることを特徴とする、請求項1から4までのいずれか1項に記載の鋼。
The chemical composition of the steel is 0.45% ≦ C ≦ 0.55% as follows:
0.50% ≦ Si ≦ 0.70%
0.90% ≦ Mn ≦ 1.10%
0.10% ≦ Cr ≦ 0.40%
0.10% ≦ Ni ≦ 0.30%
0.10% ≦ V ≦ 0.20%
0.010% ≦ Al ≦ 0.020%
0.020% ≦ Nb ≦ 0.030%
0.010% ≦ N ≦ 0.020%
0.020% ≦ Ti ≦ 0.030%
The steel according to any one of claims 1 to 4, characterized in that:
前記鋼の化学組成が、以下の
0.45%≦C≦0.55%
0.50%≦Si≦0.70%
0.90%≦Mn≦1.10%
0.30%≦Cr≦0.40%
0%≦Ni≦0.20%
0.10%≦V≦0.20%
0.010%≦Al≦0.020%
0.020%≦Nb≦0.030%
0.015%≦N≦0.020%
に当てはまることを特徴とする、請求項1から4までのいずれか1項に記載の鋼。
The chemical composition of the steel is 0.45% ≦ C ≦ 0.55% as follows:
0.50% ≦ Si ≦ 0.70%
0.90% ≦ Mn ≦ 1.10%
0.30% ≦ Cr ≦ 0.40%
0% ≦ Ni ≦ 0.20%
0.10% ≦ V ≦ 0.20%
0.010% ≦ Al ≦ 0.020%
0.020% ≦ Nb ≦ 0.030%
0.015% ≦ N ≦ 0.020%
The steel according to any one of claims 1 to 4, characterized in that:
鍛造と制御された冷却の後、特殊カーバイドの析出によるほぼパーライト構造を有する、自動車構造のための破断分離可能な部材を製造するための、請求項1から7までのいずれか1項に記載の鋼の使用。   8. A process according to any one of claims 1 to 7 for producing a break-separable member for an automobile structure having a substantially pearlite structure by precipitation of special carbides after forging and controlled cooling. Use of steel. 変形温度から制御しながら冷却した後、降伏強度が750N/mm2超であることを特徴とする、請求項8に記載の部材。 The member according to claim 8, wherein the yield strength is more than 750 N / mm 2 after cooling while controlling from the deformation temperature. 変形温度から制御しながら冷却した後、引張強度が950N/mm2超、かつ1200N/mm2未満であることを特徴とする、請求項9に記載の部材。 The member according to claim 9, wherein the member has a tensile strength of more than 950 N / mm 2 and less than 1200 N / mm 2 after cooling while controlling from the deformation temperature. 変形温度から制御しながら冷却した後、破断点伸びが10%超であることを特徴とする、請求項10に記載の部材。   The member according to claim 10, wherein the member has an elongation at break of more than 10% after being cooled while being controlled from the deformation temperature. 変形温度から制御しながら冷却した後、断面収縮率が25%超であることを特徴とする、請求項11に記載の部材。   12. The member according to claim 11, wherein after cooling while controlling from the deformation temperature, the cross-sectional shrinkage ratio is more than 25%. 破断分離可能であることを特徴とする、請求項12に記載の部材。   The member according to claim 12, wherein the member can be separated by breaking. 誘導加熱焼入れに適していることを特徴とする、請求項13に記載の部材。   The member according to claim 13, which is suitable for induction heating and quenching. 機械的特性を、鍛造の原材料においても、また部材においても熱機械的処理によって調整することができることを特徴とする、請求項14に記載の部材。   15. The member according to claim 14, characterized in that the mechanical properties can be adjusted both in the forging raw material and in the member by thermomechanical treatment.
JP2009525910A 2006-09-01 2007-07-27 Steel for producing a mechanical member having higher strength and capable of breaking and separating, and processing method Pending JP2010501733A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102006041146A DE102006041146A1 (en) 2006-09-01 2006-09-01 Steel and processing methods for the manufacture of high-strength fracture-breakable machine components
PCT/DE2007/001337 WO2008028447A1 (en) 2006-09-01 2007-07-27 Steel, and processing method for the production of higher-strength fracture-splittable machine components

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JP2010501733A true JP2010501733A (en) 2010-01-21

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