JP2010222323A - Makeup remover cosmetic composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a makeup remover cosmetic composition which quickly conforms with the whole makeup, shows little stickiness, is mild to the skin, and has excellent detergent efficiency. <P>SOLUTION: The makeup remover cosmetic composition includes (i) 0.5 to 40 wt.% of polyol; (ii) 0.5 to 40 wt.% of mono-, di-, and tri-glycerides of saturated or unsaturated fatty acid in which ethylene oxide is addition-polymerized; and (iii) water. The makeup remover cosmetic composition quickly conforms with the whole makeup, shows little stickiness, is mild to the skin, and has excellent detergent efficiency. <P>COPYRIGHT: (C)2011,JPO&amp;INPIT

Description

  The present invention relates to a makeup remover cosmetic composition having excellent cleaning efficacy. More specifically, the present invention relates to a makeup remover cosmetic composition that is foamy, quickly adapts to the entire makeup, has less stickiness, is mild to the skin, and has an excellent cleaning effect.

As for makeup cosmetics such as foundations, lipsticks, and eye makeup, products with good makeup that are resistant to breakage of moisture and sebum are increasing. Therefore, removal of makeup cosmetics has become a daily problem for many women, and further improvement in performance and efficiency are desired with makeup removers (makeup removers).
In order to remove makeup cosmetics, cleansing agents that mainly contain nonionic surfactants are widely used in order to wash away the oils for removing makeup.

  The cleansing agent uses a large amount of oil, which may cause problems such as stickiness on the hands and face and excessive removal of sebum contained in the skin along with makeup cosmetics. There was a problem such as being bulky.

It is generally said that cold cream is suitable for improving this problem. Exemplary embodiments of this technique are both reported in US Pat. No. 5,160,739 and US Pat. No. 5,798,111 to Kanga et al. However, since cold cream is relatively oily, it is necessary to spread it so that the hands and face are sticky, and because it has high viscosity, it can be applied to the face with both hands.

  Another approach is a product reinforced with a large amount of foaming surfactant. In particular, they are formulated with a substantial amount of anionic surfactant and in some products are provided in the form of an aerosol. An example of this technique is disclosed in JP-A-2003-81764. It discloses a combination of a talc-supported phosphate ester surfactant and an alkyl polyglycoside surfactant in the form of a propellant-driven aerosol. Although a system containing a large amount of an anionic surfactant is excellent in terms of detergency, it has a problem that mildness to the skin is insufficient.

  In another approach, a make-up remover containing a triisostearate ester of glycerol in a polyol is reported in JP-A-2006-241151. However, in order to formulate a large amount of triisostearate ester of glycerol, it is necessary to make the product oily or to have a high viscosity. It cannot be resolved. By making the amount of triisostearate ester of glycerol low, the viscosity can be lowered, and by using it in a container having a foaming mechanism, it is possible to use it in a foam that is easy to handle and does not stick, but in proportion Detergency is reduced.

US Pat. No. 5,160,739 US Pat. No. 5,798,111 JP 2003-81764 A JP 2006-241151 A

  Thus, the problem addressed by the present invention is to provide a make-up remover that is not only quick-familiar with the overall make-up, less sticky and mild to the skin, but also has excellent cleaning efficacy.

  As a result of intensive studies on the above problems, the present inventors have found that a combination of a saturated or unsaturated fatty acid mono-, di- and triglyceride with ethylene oxide and a combination of one or more polyols is foamy and quick. The present invention has been completed by finding out that it is familiar to the entire make-up, has less stickiness, is mild to the skin, and has an excellent cleaning effect.

That is, this invention relates to the makeup remover cosmetic composition as described in the following (1)-(9).
(1) (i) 0.5 to 40% by weight of polyol;
(Ii) 0.5 to 40% by weight of a saturated or unsaturated fatty acid mono-, di- and triglyceride obtained by addition polymerization of ethylene oxide; and (iii) a makeup remover cosmetic composition comprising water object.
(2) The makeup remover cosmetic composition according to (1), wherein the makeup remover cosmetic composition according to (1) is filled in a container having a foaming mechanism that foams during injection.
(3) Ethylene oxide is added to the mono-, di-, and triglycerides of saturated or unsaturated fatty acids and ethylene oxide is added to the mono-, di-, and triglycerides of saturated or unsaturated fatty acids having 2 to 12 carbon atoms. The make-up remover cosmetic composition according to (1), which is obtained by molar addition polymerization.
(4) The polyol is propylene glycol, glycerol, 1,4-butanediol, 1,3-butanediol, 1,2-butanediol, 1-6-hexanediol, 1,2-hexanediol, 3-methyl The make-up remover according to (1), which is a monomer polyol selected from the group consisting of -1,3-butanediol, 2-methyl-1,3-propanediol, sorbitol and mixtures thereof Cosmetic composition.
(5) The polyol is a polymer polyol selected from the group consisting of polypropylene glycol, polyethylene glycol, dipropylene glycol, diglycerol, polyglycerol, trimethylene glycol, dipentaerythritol and mixtures thereof. Makeup remover cosmetic composition according to (1).
(6) The makeup remover according to (1), further comprising 0.01 to 20% by weight of an anionic surfactant, a cationic surfactant, a nonionic surfactant or an amphoteric surfactant Cosmetic composition.
(7) The make-up according to (1), wherein the saturated or unsaturated fatty acid mono-, di- and triglycerides obtained by addition polymerization of ethylene oxide are polyoxyethylene (capryl / capric acid) glyceryl. Remover cosmetic composition.
(8) The makeup remover cosmetic composition according to (1), further comprising at least one ethyl alcohol or isopropyl alcohol.
(9) Hydrocarbons such as liquid paraffin and squalane, natural fats and oils such as jojoba oil, olive oil, macadamia nut oil, isotridecyl isononanoate, isononyl isononanoate, isopropyl myristate, diethyl sebacate, cetyl isooctanoate, octyl palmitate, tri 2 -Further comprising at least one oil selected from the group consisting of organic acid ester oils such as glyceryl ethylhexanoate, tricapryl / glyceryl caprate, silicone oils such as methylphenylpolysiloxane and methylpolysiloxane. The makeup remover cosmetic composition as described in (1), which is characterized in that

  The make-up remover cosmetic composition of the present invention provides a make-up remover that can be foamed, quickly adapted to the entire make-up, less sticky and mild to the skin, as well as having an excellent cleaning effect. be able to.

  The composition of the present invention is usually an aqueous medium or an emulsion of water. The amount of water ranges from 20 to 99% by weight of the composition, preferably from 30 to 80%, and optimally from 40 to 60%.

  The polyol used in the makeup remover cosmetic composition of the present invention is a monomer or a polymer. The monomer polyol has 1 to 20 carbon atoms and 2 to 10 hydroxyls. Examples of the monomer polyol include propylene glycol, glycerol, 1,4-butanediol, 1, 3-butanediol, 1,2-butanediol, 1-6-hexanediol, 1,2-hexanediol, 3-methyl-1,3-butanediol, 2-methyl-1,3-propanediol, sorbitol or The mixture is mentioned. Of the above monomer polyols, 3-methyl-1,3-butanediol is particularly preferred.

  Examples of the polymer polyol include polypropylene glycol, polyethylene glycol, dipropylene glycol, diglycerol, polyglycerol, trimethylene glycol, dipentaerythritol, and mixtures thereof. Of the above polymer polyols, dipropylene glycol and polyethylene glycol are particularly preferred, the latter having a molecular weight of about 200 to about 5000, preferably about 300 to about 1000.

  The amount of polyol used ranges from 0.5 to 40% by weight, preferably from 2 to 25% by weight, optimally from 10 to 25% by weight.

The saturated or unsaturated fatty acid mono-, di-, and triglycerides used in the make-up remover cosmetic composition of the present invention are addition-polymerized with ethylene oxide. The fatty acid preferably has 2 to 12 carbon atoms or a mixture thereof. More preferably, it is a product obtained by addition polymerization of ethylene oxide to mono-, di- and triglycerides of saturated fatty acids of 4 to 12 or a mixture thereof, optimally 8 to 10 or a mixture thereof. The average added mole number of the ethylene oxide is preferably 1 to 50, more preferably 2 to 30, and most preferably 4 to 8.
Examples of the above-mentioned mono-, di- and triglycerides of saturated or unsaturated fatty acids obtained by addition polymerization of ethylene oxide include PEG-7 (capryl / capric acid) glycerides, PEG-4 (capryl / capric acid) glyceryl, PEG -6 (capryl / capric acid) glyceryl, PEG-8 (capryl / capric acid) glyceryl, or PEG-6 glyceryl caprate. Of those exemplified above, PEG-7 (capryl / capric acid) glycerides is most preferred for the make-up remover cosmetic composition of the present invention. This PEG-7 (capryl / capric acid) glyceride is sold by Cognis Japan Ltd. under the registered trademark Cetol HE 810 and is available. The amount of saturated or unsaturated fatty acid mono-, di- and triglycerides obtained by addition polymerization of ethylene oxide used in the makeup remover cosmetic composition of the present invention is, for example, 0.5 to 40% by weight, preferably Is in the range of 2-30% by weight, optimally 5-15% by weight.

Surfactants can also be used in the make-up remover cosmetic composition of the present invention.
Examples of the surfactant include an anionic surfactant, a cationic surfactant, an amphoteric surfactant, and a nonionic surfactant.
Examples of the anionic surfactant include fatty acid salts such as potassium laurate and potassium myristate; alkyl sulfates such as sodium lauryl sulfate, triethanolamine lauryl sulfate or ammonium lauryl sulfate; sodium laureth sulfate or triethanol laureth sulfate Polyoxyethylene alkyl sulfates such as amines; sodium cocoyl methyl taurine, potassium cocoyl methyl taurine, sodium lauroyl methyl taurine, sodium myristoyl methyl taurine, sodium lauroyl methyl alanine, sodium lauroyl sarcosine, lauroyl sarcosine triethanolamine or sodium methyl alanine lauroyl glutamate Acyl N-methyl amino acid salt such as cocoyl glutamic acid Acyl amino acid salts such as thorium, triethanolamine cocoyl glutamate, sodium lauroyl glutamate, sodium myristoyl glutamate, sodium stearoyl glutamate, ditriethanolamine palmitoyl aspartate or cocoylalanine triethanolamine; polyoxyethylene alkyl ether acetates such as sodium laureth acetate Succinic acid ester salts such as lauroyl monoethanolamide sodium succinate; fatty acid alkanolamide ether carboxylates; acyl lactates; polyoxyethylene fatty amine sulfates; fatty acid alkanolamide sulfates; hardened coconut oil fatty acid glycerin sodium sulfate, etc. Fatty acid glyceride sulfate; alkylbenzene polyoxyethylene sulfate; α-olefins Olefin sulfonates such as sodium sulfonate; alkyl sulphosuccinates such as disodium lauryl sulfosuccinate or dioctyl sodium sulfosuccinate; disodium laureth sulfosuccinate, monolauroyl monoethanolamide sodium polyoxyethylene sulfosuccinate or lauryl polypropylene glycol sulfosuccinic acid Alkyl ether sulfosuccinates such as sodium; acyl isethionates; alkyl ether phosphates such as sodium laureth phosphate, sodium dilaureth phosphate, sodium trilaureth phosphate or sodium monooles phosphate; or alkyl phosphate esters such as potassium lauryl phosphate Salt.

  Examples of the cationic surfactant include alkyltrimethylammonium chloride such as behentrimonium chloride, steartrimonium chloride, cetrimonium chloride or lauryltrimonium chloride; alkyltrimethylammonium bromide such as stearyltrimonium bromide; Dialkyldimethylammonium chloride such as monium chloride or dicocodimonium chloride; fatty acid amidoamines such as stearamidepropyldimethylamine or stearamideethyldiethylamine and salts thereof; alkyl ether amines such as stearoxypropyldimethylamine; salts or quaternary salts thereof; Ethyl sulfate long chain branched fatty acid (12-31) aminopropyl ethyl dimethyl ammonium, ethyl sulfate Fatty acid amide-type quaternary ammonium salts such as phosphorus fatty acid aminopropylethyldimethylammonium; polyoxyethylene alkylamines, salts or quaternary salts thereof; alkylamine salts; fatty acid amidoguanidinium salts; alkyl etheramine ammonium salts; Benzalkonium salt; Pyridinium salt such as cetylpyridinium chloride; Imidazolinium salt; Alkylisoquinolinium salt; Dialkyl morpholinium salt; Polyamine fatty acid derivative; Or aminopropyl dimethicone or amodimethicone Amino-modified silicone, cation-modified silicone, cation-modified silicone, polyether-modified silicone, amino-modified silicone or polyether-modified silicone That.

  Examples of the amphoteric surfactant include N-alkyl-N, N-dimethylamino acid betaines such as lauryl betaine (lauryldimethylaminoacetic acid betaine); fatty acid amide alkyl-N such as cocamidopropyl betaine or lauramidopropyl betaine. N-dimethylamino acid betaine; imidazoline-type betaines such as sodium cocoamphoacetate or sodium lauroamphoacetate; alkylsulfobetaines such as alkyldimethyltaurine; sulfate-type betaines such as alkyldimethylaminoethanol sulfate; alkyldimethylaminoethanol phosphate Phosphate betaine; sphingophospholipids such as phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine or sphingomyelin, lysoleciti , Hydrogenated soybean phospholipid, partially hydrogenated soybean phospholipid, hydrogenated egg yolk phospholipids, phospholipids such as partially hydrogenated egg yolk phospholipid or hydroxylated lecithin; or silicone amphoteric surfactant, and the like.

  Examples of the nonionic surfactant include laureth (polyoxyethylene lauryl ether), ceteth (polyoxyethylene cetyl ether), steareth (polyoxyethylene stearyl ether), behenes (polyoxyethylene behenyl ether), Polyoxyethylene alkyl ethers having various polyoxyethylene addition numbers such as isosteares (polyoxyethylene isostearyl ether), octyldecesses (polyoxyethylene octyldodecyl ether); polyoxyethylene alkylphenyl ether; polyoxyethylene-cured castor Oil, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil monoisostearate, polyoxyethylene hydrogenated castor oil triisostearate, polyoxyethylene hydrogenated castor oil Castor oil and hydrogenated castor oil derivatives such as di-oil monopyroglutamic acid monoisostearic acid diester, polyoxyethylene hydrogenated castor oil maleic acid; polyoxyethylene phytosterol; polyoxyethylene cholesterol; polyoxyethylene cholestanol; polyoxyethylene lanolin; poly Oxyethylene reduced lanolin; polyoxyethylene / polyoxypropylene cetyl ether, polyoxyethylene / polyoxypropylene 2-decyltetradecyl ether, polyoxyethylene / polyoxypropylene monobutyl ether, polyoxyethylene / polyoxypropylene hydrogenated lanolin, Polyoxyethylene polyoxypropylene alkyl ethers such as polyoxyethylene polyoxypropylene glycerin ether; Siethylene polyoxypropylene glycol; (poly) glycerin polyoxypropylene glycol such as PPG-9 diglyceryl; glyceryl stearate, glyceryl isostearate, glyceryl palmitate, glyceryl myristate, glyceryl oleate, glyceryl coconut oil, mono cottonseed oil Glycerin fatty acid partial esters such as fatty acid glycerin, monoerucic acid glycerin, sesquioleate glycerin, α, α'-oleic acid pyroglutamate glycerin, monostearate glycerin malate; stearate polyglyceryl-2, stearate polyglyceryl-3 Acid polyglyceryl-4, stearate polyglyceryl-5, stearate polyglyceryl-6, stearate polyglyceryl-8, stearin Polyglyceryl-10, polyglyceryl-6 distearate, polyglyceryl-10 distearate, polyglyceryl-2 tristearate, polyglyceryl-10 decastearate, polyglyceryl-2 isostearate, polyglyceryl-3 isostearate, polyglyceryl-4 isostearate, isostearic acid Polyglyceryl-5, polyglyceryl isostearate 6, polyglyceryl isostearate, polyglyceryl-10 isostearate, polyglyceryl-2 diisostearate (diglyceryl diisostearate), polyglyceryl-3 diisostearate, polyglyceryl-10 diisostearate, polyglyceryl tetraisostearate -2, polyglyceryl decaisostearate-10, oleic acid poly Liglyceryl-2, polyglyceryl-3 oleate, polyglyceryl-4 oleate, polyglyceryl-5 oleate, polyglyceryl-6 oleate, polyglyceryl-8 oleate, polyglyceryl-10 oleate, polyglyceryl-6 dioleate, trioleic acid Polyglyceryl fatty acid esters such as polyglyceryl-2 and dekaleate polyglyceryl-10; ethylene glycol monofatty acid esters such as ethylene glycol monostearate; propylene glycol monofatty acid esters such as propylene glycol monostearate; pentaerythritol partial fatty acid ester; sorbitol moiety Fatty acid ester; Maltitol partial fatty acid ester; Maltitol ether; Sorbitan monooleate, Sorbitan monoisostea Sorbitan fatty acids such as salts, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate, diglycerol sorbitan penta-2-ethylhexylate, diglycerol sorbitan tetra-2-ethylhexylate Esters; sugar derivatives partial esters such as sucrose fatty acid esters, methyl glucoside fatty acid esters, and undecylenic acid trehalose; alkyl glucosides such as caprylyl glucoside; alkyl polyglycosides; lanolin alcohols; reduced lanolins; Polyisoethylene fatty acid mono and die such as diisostearate, polyoxyethylene monooleate, polyoxyethylene dioleate Polyoxyethylene / propylene glycol fatty acid ester; polyoxyethylene glycerin monostearate, polyoxyethylene glycerin monoisostearate, polyoxyethylene glycerin fatty acid ester such as polyoxyethylene monooleate; polyoxyethylene sorbitan monooleate Polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan fatty acid esters such as polyoxyethylene sorbitan tetraoleate; polyoxyethylene sorbitol monolaurate, polyoxyethylene sorbitol monooleate, polyoxy Polyoxyethylene such as ethylene sorbitol pentaoleate and polyoxyethylene sorbitol monostearate Lensorbitol fatty acid ester; polyoxyethylene methyl glucoside fatty acid ester; polyoxyethylene alkyl ether fatty acid ester; polyoxyethylene animal and vegetable oils such as polyoxyethylene sorbitol beeswax; isostearyl glyceryl ether, chimyl alcohol, seraalkyl alcohol, batyl alcohol Polyglyceryl alkyl ethers; polyoxyethylene alkylamines; tetrapolyoxyethylene / tetrapolyoxypropylene-ethylenediamine condensates; natural surfactants such as saponins and sophorolipids; polyoxyethylene fatty acid amides Coconut oil fatty acid monoethanolamide (cocamide MEA), coconut oil fatty acid diethanolamide (cocamide DEA), lauric acid Ethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitic acid monoethanolamide (partamic acid MEA), palmitic acid diethanolamide (partamic acid DEA), palm oil fatty acid methylethanol Fatty acid alkanolamides such as amides (cocamidomethyl MEA); alkyl dimethylamine oxides such as lauramine oxide, cocamamine oxide, stearamine oxide, and behenamine oxide; alkyl ethoxy dimethyl amine oxides; polyoxyethylene alkyl mercaptans; Polyether-modified silicone such as polyol, polysiloxane / oxyalkylene copolymer, polyglycerin-modified silicone , Silicone-based nonionic surfactants such as sugar-modified silicone.

In addition, humectants and skin benefit agents can also be used in the makeup remover cosmetic composition of the present invention. Examples of the skin effect agent include fatty acids or fats having 10 to 22 carbon atoms such as stearyl alcohol, cetyl alcohol, isostearyl alcohol, lauryl alcohol, myristyl alcohol, palmityl alcohol, oleyl alcohol, behenyl alcohol or mixtures thereof. Alcohols; fatty acids such as stearic acid, isosteric acid, lauric acid, myristic acid, palmitic acid, oleic acid or behenic acid; hydrocarbons such as liquid paraffin or squalane; natural fats and oils such as jojoba oil, olive oil or macadamia nut oil; Isotridecyl isononanoate, isononyl isononanoate, isopropyl myristate, diethyl sebacate, cetyl isooctanoate, octyl palmitate, tri-2-ethylhexa Organic acid ester oil such as glyceryl acid or tricapryl / glyceryl caprate, silicone oil such as methylphenylpolysiloxane or methylpolysiloxane, polyols such as propylene glycol copolymer and polymers thereof; diethylene glycol monoethyl ether (ethoxydiglycol) ), Glycol alkyl ethers such as ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol dibutyl ether; (eicosandioic acid / tetradecanedioic acid) water-soluble esters such as polyglyceryl-10, tetradecanedioic acid polyglyceryl-10; sorbitol , Xylitol, erythritol, mannitol, maltitol and other sugar alcohols; glucose, fructose, galactose Mannose, threose, xylose, arabinose, fucose, ribose, deoxyribose, maltose, trehalose, lactose, raffinose, gluconic acid, glucuronic acid, cyclodextrins (α-, β-, γ-cyclodextrin, maltosylated, hydroxy Modified cyclodextrins such as alkylation), β-glucan, chitin, chitosan, heparin and derivatives, sugars such as pectin, arabinogalactan, dextrin, dextran, glycogen, ethyl glucoside, glucosyl ethyl methacrylate polymer or copolymer, and Derivatives thereof: hyaluronic acid, sodium hyaluronate; chondroitin sulfate sodium; mucoitin sulfate, caronine sulfate, kerato sulfate, dermatan sulfate; Fucoidan; Tuberose polysaccharide, naturally-occurring polysaccharide; Organic acids such as citric acid, tartaric acid and lactic acid and salts thereof; Urea; 2-pyrrolidone-5-carboxylic acid and salts thereof such as sodium; Betaine (trimethylglycine) , Proline, hydroxyproline, lysine, serine, glycine, alanine, phenylalanine, tyrosine, β-alanine, threonine, glutamic acid, glutamine, asparagine, aspartic acid, cysteine, cystine, methionine, leucine, isoleucine, valine, tryptophan, histidine, taurine Amino acids and salts thereof; collagen, fish-derived collagen, atelocollagen, gelatin, elastin, collagen-degrading peptide, hydrolyzed collagen, hydroxypropylammonium chloride-hydrolyzed collagen , Elastin degrading peptide, keratin degrading peptide, hydrolyzed keratin, conchiolin degrading peptide, hydrolyzed conchiolin, silk proteolytic peptide, hydrolyzed silk, lauroyl hydrolyzed silk sodium, soybean proteolytic peptide, wheat proteolytic peptide, hydrolyzed wheat protein Protein peptides such as casein-degrading peptides and acylated peptides and derivatives thereof; acylated peptides such as palmitoyl oligopeptide, palmitoyl pentapeptide, palmitoyl tetrapeptide; silylated peptides; lactic acid bacteria culture solution, yeast extract, eggshell membrane Protein, bovine submandibular gland mucin, hypotaurine, sesameignan glycoside, glutathione, albumin, whey; choline chloride, phosphorylcholine; placental extract, aerustin, collagen, aloe extract, hamamelis , Animal and plant extract components such as loofah water, dipotassium glycyrrhizinate, chamomile extract, licorice extract, comfrey extract, silk extract, Izayoi rose extract, yarrow extract, eucalyptus extract, merirot extract, natural ceramide (type 1, 2, 3, 4, 5, 6), ceramides such as hydroxyceramide, pseudoceramide, glycosphingolipid, ceramide and sugar-ceramide-containing extract.
The amount of the humectant / skin effect agent used is in the range of 0.1 to 10% by weight, preferably 0.5 to 8% by weight, and most preferably 1 to 5% by weight.

  Moreover, antiseptic | preservative and antibacterial agent can also be used for the makeup remover cosmetic composition of this invention. Examples of the preservative include, for example, phenoxyethanol, methylparaben, ethylparaben, propylparaben, butylparaben, benzoate, DMDM hydantoin and mixtures thereof, isothiazoline-on derivatives such as trichlorosan such as methylchloroisothiazolinone and methylisothiazolinone Halogenated bisphenols, acid amides, quaternary ammonium salts; trichlorocarbanide, zinc pyrithione, benzalkonium chloride, benzethonium chloride, sorbic acid, chlorhexidine, chlorhexidine gluconate, halocarban, hexachlorophene, hinokitiol; phenol, isopropylphenol , Other pheno such as cresol, thymol, parachlorophenol, phenylphenol, sodium phenylphenol S; phenylethyl alcohol, photosensitive Motorui, antibacterial zeolite, and silver ions. In addition, the usage-amount of the said antiseptic | preservative and antibacterial agent is 0.0001 to 1 weight%.

  A chelating agent can also be used in the makeup remover cosmetic composition of the present invention. Examples of the chelating agent include edetate (ethylenediaminetetraacetate) such as EDTA, EDTA2Na, EDTA3Na or EDTA4Na; hydroxyethylethylenediamine triacetate such as HEDTA3Na; pentetate (diethylenetriaminepentaacetate); phytic acid Or phosphonic acids such as etidronic acid and salts thereof; polyamino acids such as polyaspartic acid or polyglutamic acid; phosphoric acids such as sodium polyphosphate, sodium metaphosphate or phosphoric acid; amino acids such as alanine or dihydroxyethylglycine; Examples thereof include organic acids such as sodium acid, sodium citrate, citric acid, alanine, dihydroxyethylglycine, gluconic acid, ascorbic acid, succinic acid, and tartaric acid.

  Moreover, a pH adjuster can also be used as a further component in the makeup remover cosmetic composition of the present invention. Examples of the pH adjuster include citric acid, sodium citrate, lactic acid, sodium lactate, glycolic acid, succinic acid, acetic acid, sodium acetate, malic acid, tartaric acid, fumaric acid, phosphoric acid, hydrochloric acid, sulfuric acid, and monoethanol. Amine, diethanolamine, triethanolamine, isopropanolamine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-hydroxymethyl-1,3-propanediol, arginine, hydroxylation Sodium or potassium hydroxide is mentioned.

  Optional secondary ingredients that can be used in the make-up remover cosmetic composition of the present invention include, for example, colorants or flavoring agents.

  The make-up remover cosmetic composition of the present invention preferably comprises heating a predetermined amount of water to preferably 40 ° C. to 60 ° C., adding a predetermined amount of components, and then raising the temperature to preferably 70 ° C. to 80 ° C. It can prepare by cooling to room temperature-30 degreeC after confirming that the added component melt | dissolved completely.

  In a preferred embodiment of the use of the make-up remover cosmetic composition of the present invention, the make-up remover cosmetic composition of the present invention is filled in a container having a foaming mechanism that foams at the time of jetting, and the amount used is as described above. It is preferable to pick up the foam obtained by pushing the lever of the container twice a day, and apply it to the face. Depending on the nature of the skin, it may be increased or decreased. A commercially available pump can be used as the container having a foaming mechanism that foams at the time of jetting. For example, an F5L pump former three-point mesh (manufactured by Daiwa Steel Co., Ltd.) and a foam pump PF-03 ( Kono Resin Co., Ltd.), Yoshino Kogyo Co., Ltd., and domestic and overseas pump bottle manufacturers can be used as foam pumps and former pumps.

  The present invention will be described by way of examples and test examples which are typical makeup remover cosmetic compositions of the present invention, but these are only examples and do not limit the scope of the present invention.

Example 1
A predetermined amount of water (69.8 g) shown in the column of Example 1 in Table 1 below was charged into a beaker. Next, a predetermined amount of the remaining components shown in Table 1 below was added while stirring with a stirrer and heating at 50 ° C. Next, the liquid temperature is set to 72 ° C., and after confirming that each added component is completely dissolved, the temperature of the obtained solution is cooled to 30 ° C. The obtained composition was filled in a container having a foaming mechanism.

なお、比較例１及び２の処方について、実施例１と同様に調製した。

The formulations of Comparative Examples 1 and 2 were prepared in the same manner as in Example 1.

(Test Example 1)
A sensory test was performed on the formulations of Example 1 and Comparative Examples 1 and 2. The formulations of Example 1 and Comparative Examples 1 and 2 were each filled into a container having a foaming mechanism, used for 12 female subjects, using 2 pushes per time and once a day for each formulation. The makeup removal test was performed for 2 days, with 2 points for the most detergency, 1 point for the next, and 0 for the least detergency. The average score of each evaluation score is shown in Table 2.

  From the results shown in Table 2, it is clear that the composition of Example 1 comprising PEG-7 (capryl / capric acid) glyceriz of the present invention has an excellent make-up cleaning effect.

(Test Example 2)
About the make-up remover of Example 1, soft and soft foam face wash (manufactured by Kumano Yushi Co., Ltd.) (Comparative Example 3), cleansing oil (manufactured by Kumano Yushi Co., Ltd.) (Comparative Example 4), feeling of use and makeup Familiarity, detergency, and moist feeling after use were tested on 10 female subjects. The make-up remover of Example 1 and the soft and soft foam face wash (Comparative Example 3) were filled in a three-point mesh F5L pump former (manufactured by Yamato Seisaku Co., Ltd.), a cleansing oil (Comparative). Example 4) used a normal pump. Each test was used with 2 pushes, and once a day, each formulation was tested for make-up removal for 2 days and evaluated as 1 point for good and 0 point for poor. The total score of each evaluation score is shown in Table 3.
For Comparative Examples 3 and 4, commercially available products were used.

  From the results shown in Table 3, the makeup remover cosmetic composition provided by the present invention is a cosmetic formulation characterized in that it is foamed when filled in a container having a foaming mechanism and sprayed. It is clear that it has a good cleaning power and familiarity with the same cleansing oil as a basic cleansing oil. Further, it is possible to improve the moist feeling after use, which is a drawback of the makeup remover having an oil agent as a basic composition, and to maintain a moist feeling after use.

Examples 2-5
The makeup remover cosmetic compositions of Examples 2-5 were prepared in the same manner as the preparation method of Example 1.

The makeup remover cosmetic composition of the present invention can fully utilize its merit by providing a makeup remover that is foamy and excellent in detergency. That is, since it can be foamed, the surface area and volume of the makeup remover can be increased, and a small amount can be applied quickly and uniformly to the entire face. Therefore, the following advantages can be provided.
(1) It is economical because a make-up remover can be used in a small amount.
(2) Since the make-up remover is used in a small amount, the risk of irritation to the facial skin can be reduced.
(3) It is not necessary to spread with both hands like existing cleansing oil, and can be easily applied with one hand.
(4) The hand is not sticky and the liquid does not easily drip.

Claims (9)

(I) 0.5 to 40% by weight of polyol;
(Ii) 0.5 to 40% by weight of a saturated or unsaturated fatty acid mono-, di- and triglyceride obtained by addition polymerization of ethylene oxide; and (iii) a makeup remover cosmetic composition comprising water object.   The makeup remover cosmetic composition according to claim 1, wherein the makeup remover cosmetic composition according to claim 1 is filled in a container having a foaming mechanism that foams when jetted.   Addition polymerization of ethylene oxide to mono-, di- and triglycerides of saturated or unsaturated fatty acids results in addition polymerization of 1 to 50 mol of ethylene oxide to mono-, di- and triglycerides of saturated or unsaturated fatty acids having 2 to 12 carbon atoms. The make-up remover cosmetic composition according to claim 1, wherein   The polyol is propylene glycol, glycerol, 1,4-butanediol, 1,3-butanediol, 1,2-butanediol, 1-6-hexanediol, 1,2-hexanediol, 3-methyl-1, 2. A makeup remover cosmetic composition according to claim 1, which is a monomeric polyol selected from the group consisting of 3-butanediol, 2-methyl-1,3-propanediol, sorbitol and mixtures thereof. .   The said polyol is a polymer polyol selected from the group consisting of polypropylene glycol, polyethylene glycol, dipropylene glycol, diglycerol, polyglycerol, trimethylene glycol, dipentaerythritol and mixtures thereof. Makeup remover cosmetic composition as described in 1.   The makeup remover cosmetic composition according to claim 1, further comprising 0.01 to 20% by weight of an anionic surfactant, a cationic surfactant, a nonionic surfactant or an amphoteric surfactant. .   The makeup remover cosmetic composition according to claim 1, wherein the saturated or unsaturated fatty acid mono-, di- and triglycerides obtained by addition polymerization of ethylene oxide are polyoxyethylene (capryl / capric acid) glyceryl. object.   The makeup remover cosmetic composition according to claim 1, further comprising at least one ethyl alcohol or isopropyl alcohol.   Hydrocarbons such as liquid paraffin and squalane, natural fats such as jojoba oil, olive oil and macadamia nut oil, isotridecyl isononanoate, isononyl isononanoate, isopropyl myristate, diethyl sebacate, cetyl isooctanoate, octyl palmitate, tri-2-ethylhexane It further comprises at least one oil agent selected from the group consisting of organic acid ester oils such as glyceryl acid, tricapryl / glyceryl caprate, silicone oils such as methylphenylpolysiloxane and methylpolysiloxane. The make-up remover cosmetic composition according to claim 1.