JP2010111639A - Process for producing ketone compound and process for producing electricity storage device - Google Patents

Abstract

一般式（２）：
【化２】

【選択図】なしA low-cost method for producing a ketone compound and a method for producing an electricity storage device capable of easily and reliably producing a ketone compound are provided.
A precursor compound having a structure represented by the following general formula (1) is immersed in an aprotic solvent to produce a ketone compound having a structure represented by the following general formula (2).
General formula (1):
[Chemical 1]

General formula (2):
[Chemical formula 2]

[Selection figure] None

Description

  The present invention relates to a method for producing a ketone compound and a method for producing an electricity storage device.

  Organic compounds can form various structures compared to inorganic compounds by changing the length and branching of the carbon skeleton (carbon chain) in various ways. Realizing various physical properties by changing the structure can do. Among them, an organic compound having a ketone group (C═O) (hereinafter, “ketone compound”) is one of highly useful organic compounds, and is used in various fields. Examples of the method for synthesizing a ketone compound include a method in which an ether compound is reacted with another organic compound in the presence of a radical initiator (see, for example, Patent Document 1). In addition, a method of oxidizing an alcohol using a hexavalent chromium compound, a method of providing a ketone group in an organic compound molecule using 1,3-dithiane, a method of cleaving glycol, an alkene using ozone Examples thereof include a cleavage method or a Friedel-Crafts reaction using an aromatic ring. And either of the said methods is employ | adopted according to the structure of the target ketone compound and precursor compound.

  Among ketone compounds, organic compounds having three or more ketone groups in the molecule are used as materials for antibacterial compounds and herbicides. Examples of the compound having three or more ketone groups in the molecule include 1,2,3-indantrione having a structure represented by the above chemical formula (A).

  A method for producing an organic compound (hereinafter referred to as “cyclic triketone compound”) containing three ketone groups containing a ring structure in the molecule and continuous in the molecule, as represented by the above 1,2,3-indanetrione For example, a method is known in which a precursor compound in which two hydroxyl groups are bonded to one carbon atom in a molecule is heated at a high temperature to produce a triketone compound from the precursor compound by a dehydration reaction (for example, non-patent literature). 1). As an example, a reaction for producing 1,2,3-indanetrione from ninhydrin which is a precursor compound is shown in the following reaction formula (B). In the reaction formula (B), a dehydration reaction is caused by heating under vacuum conditions.

As uses other than the above of a ketone compound, the use to the electrode active material for electrical storage devices using oxidation reduction ability is proposed. For example, it has been proposed to use a quinone compound having two ketone groups in an aromatic ring as an electrode active material. Specifically, an organic compound in which two ketone groups are arranged in the para position on the aromatic ring, or an organic compound in which two ketone groups are arranged in the ortho position on the aromatic ring are used as an electrode active material for an aqueous secondary battery. (For example, refer to Patent Document 2). The electrode reaction in the secondary battery is based on the addition and desorption of protons from the ketone group. By using this electrode active material, a secondary battery excellent in reversibility can be obtained.
However, in these aqueous secondary batteries, the battery voltage is generally about 1 to 2 V, which is lower than the battery voltage 3 to 4 V of the lithium secondary battery which is a non-aqueous battery, which is similar to the lithium secondary battery. It is difficult to obtain a high energy density.

The use of the organic compound as an electrode active material for a non-aqueous lithium secondary battery, which is expected to have a higher energy density than an aqueous secondary battery, has been studied. For example, it has been proposed to use a quinone compound as an electrode active material of an electricity storage device provided with a nonaqueous electrolytic solution in which a lithium salt is dissolved in an organic solvent. Specifically, it has been proposed to use a quinone compound in which two ketone groups are arranged in the ortho position on an aromatic ring as an electrode active material of a non-aqueous electrolyte secondary battery (see, for example, Patent Document 3). In addition, it has been proposed to use a polymer obtained by polymerizing a quinone compound in which two ketone groups are arranged in the para position on an aromatic ring as an electrode active material of a non-aqueous electrolyte secondary battery (for example, Patent Document 4). reference).
Japanese Patent Laid-Open No. 2008-24746 Japanese Patent No. 3045750 Japanese Patent No. 1469326 JP-A-10-154512 W. Adam and WS Patterson, Journal of Organic Chemistry 1995, 60, 7769-7773

As described above, when a ketone compound is produced by a conventional dehydration reaction of a precursor compound, a heating step or a catalytic reaction step is required. It is also necessary to prepare the apparatus for heating or use of the catalyst. This complicates the process and increases the manufacturing cost.
Accordingly, an object of the present invention is to provide a low-cost method for producing a ketone compound and a method for producing an electricity storage device that can easily and reliably produce a ketone compound in order to solve the above-described conventional problems. .

  In the method for producing a ketone compound of the present invention, a precursor compound having a structure represented by the following general formula (1) is immersed in an aprotic solvent, and the ketone compound having a structure represented by the following general formula (2) It is characterized by manufacturing.

In general formulas (1) and (2), R ₁ and R ₂ are each independently a hydrogen atom, a fluorine atom, a cyano group, an alkyl group having 1 to 4 carbon atoms, an alkenyl group having 2 to 8 carbon atoms, A cycloalkyl group having 3 to 10 carbon atoms, a cycloalkenyl group having 3 to 10 carbon atoms, an aryl group, or an aralkyl group, the alkyl group having 1 to 8 carbon atoms, the alkenyl group having 2 to 8 carbon atoms, and the carbon number The cycloalkyl group having 3 to 10 carbon atoms, the cycloalkenyl group having 3 to 10 carbon atoms, the aryl group, and the aralkyl group are at least one selected from the group consisting of a fluorine atom, a nitrogen atom, an oxygen atom, a sulfur atom, and a silicon atom. it may contain species which may be the ring formed by R ₁ and R _2, R ₁ and R ₂ may further comprise a ketone group.

The precursor compound having a structure represented by the general formula (1) is a precursor compound having a structure represented by the following general formula (3),
The ketone compound having a structure represented by the general formula (2) is preferably a ketone compound having a structure represented by the following general formula (4).

  In the general formulas (3) and (4), X is a saturated or unsaturated hydrocarbon having 2 to 4 carbon atoms, and at least one of the carbon atoms is a nitrogen atom, an oxygen atom, a sulfur atom, And may be substituted with at least one selected from the group consisting of silicon atoms. In addition, the saturated hydrocarbon and the unsaturated hydrocarbon include a fluorine atom, a cyano group, an alkyl group having 1 to 6 carbon atoms, an alkenyl group having 2 to 6 carbon atoms, and 3 carbon atoms as a hydrogen atom substituent. May contain a cycloalkyl group having 8 to 8 carbon atoms, a cycloalkenyl group having 3 to 8 carbon atoms, an aryl group, or an aralkyl group, the alkyl group, an alkenyl group having 2 to 6 carbon atoms, and 3 to 3 carbon atoms. The cycloalkyl group having 8 carbon atoms, the cycloalkenyl group having 3 to 8 carbon atoms, the aryl group, and the aralkyl group are at least one selected from the group consisting of a fluorine atom, a nitrogen atom, an oxygen atom, a sulfur atom, and a silicon atom. May be included.

The precursor compound having a structure represented by the general formula (3) is a precursor compound having a structure represented by the following general formula (5),
The ketone compound having a structure represented by the general formula (4) is preferably a ketone compound having a structure represented by the following general formula (6).

In general formulas (5) and (6), R _{3 to} R ₆ are each independently a hydrogen atom, a fluorine atom, a cyano group, an alkyl group having 1 to 4 carbon atoms, or an alkenyl having 2 to 4 carbon atoms. A group, a cycloalkyl group having 3 to 6 carbon atoms, a cycloalkenyl group having 3 to 6 carbon atoms, an aryl group, or an aralkyl group,
The alkyl group, the alkenyl group having 2 to 4 carbon atoms, the cycloalkyl group having 3 to 6 carbon atoms, the cycloalkenyl group having 3 to 6 carbon atoms, the aryl group, and the aralkyl group are a fluorine atom, a nitrogen atom, You may contain at least 1 sort (s) chosen from the group which consists of an oxygen atom, a sulfur atom, and a silicon atom.

The first method for producing an electricity storage device of the present invention is a method for producing an electricity storage device comprising a positive electrode, a negative electrode, and a non-aqueous electrolyte,
A first step of immersing a precursor compound having a structure represented by the following general formula (3) in an aprotic solvent to produce a ketone compound having a structure represented by the following general formula (4);
A second step of producing an electrode containing the ketone compound as an active material;
Including
The electrode is at least one of the positive electrode and the negative electrode.

  In the general formulas (3) and (4), X is a saturated or unsaturated hydrocarbon having 2 to 4 carbon atoms, and at least one of the carbon atoms is a nitrogen atom, an oxygen atom, a sulfur atom, And may be substituted with at least one selected from the group consisting of silicon atoms. In addition, the saturated hydrocarbon and the unsaturated hydrocarbon include a fluorine atom, a cyano group, an alkyl group having 1 to 6 carbon atoms, an alkenyl group having 2 to 6 carbon atoms, and 3 carbon atoms as a hydrogen atom substituent. May contain a cycloalkyl group having 8 to 8 carbon atoms, a cycloalkenyl group having 3 to 8 carbon atoms, an aryl group, or an aralkyl group, the alkyl group, an alkenyl group having 2 to 6 carbon atoms, and 3 to 3 carbon atoms. The cycloalkyl group having 8 carbon atoms, the cycloalkenyl group having 3 to 8 carbon atoms, the aryl group, and the aralkyl group are at least one selected from the group consisting of a fluorine atom, a nitrogen atom, an oxygen atom, a sulfur atom, and a silicon atom. May be included. )

The aprotic solvent is preferably the same as the non-aqueous solvent contained in the non-aqueous electrolyte.
The present invention provides a second method for producing an electricity storage device of the present invention, which is a method for producing an electricity storage device comprising a positive electrode, a negative electrode, and a non-aqueous electrolyte,
A first step of producing a precursor electrode containing a precursor compound having a structure represented by the following general formula (3);
A second step in which the precursor electrode is immersed in an aprotic solvent to produce an electrode containing a ketone compound having a structure represented by the following general formula (4) as an active material;
Including
The electrode is at least one of the positive electrode and the negative electrode.

In the general formulas (3) and (4), X is a saturated or unsaturated hydrocarbon having 2 to 4 carbon atoms, and at least one of the carbon atoms is a nitrogen atom, an oxygen atom, a sulfur atom, And may be substituted with at least one selected from the group consisting of silicon atoms. In addition, the saturated hydrocarbon and the unsaturated hydrocarbon include a fluorine atom, a cyano group, an alkyl group having 1 to 6 carbon atoms, an alkenyl group having 2 to 6 carbon atoms, and 3 carbon atoms as a hydrogen atom substituent. May contain a cycloalkyl group having 8 to 8 carbon atoms, a cycloalkenyl group having 3 to 8 carbon atoms, an aryl group, or an aralkyl group, the alkyl group, an alkenyl group having 2 to 6 carbon atoms, and 3 to 3 carbon atoms. The cycloalkyl group having 8 carbon atoms, the cycloalkenyl group having 3 to 8 carbon atoms, the aryl group, and the aralkyl group are at least one selected from the group consisting of a fluorine atom, a nitrogen atom, an oxygen atom, a sulfur atom, and a silicon atom. May be included.
The aprotic solvent is preferably the same as the non-aqueous solvent contained in the non-aqueous electrolyte.

A third method for producing an electricity storage device of the present invention is a method for producing an electricity storage device comprising a positive electrode, a negative electrode, and a non-aqueous electrolyte,
A first step of producing a precursor electrode containing a precursor compound having a structure represented by the general formula (3);
After housing the electrode group including the precursor electrode in a battery case, a nonaqueous electrolytic solution including an aprotic solvent is injected, and the precursor compound in the precursor electrode is reacted with the aprotic solvent. A second step of producing an electrode containing, as an active material, a ketone compound having a structure represented by the following general formula (4);
Including
The electrode is at least one of the positive electrode and the negative electrode.

  In the general formulas (3) and (4), X is a saturated or unsaturated hydrocarbon having 2 to 4 carbon atoms, and at least one of the carbon atoms is a nitrogen atom, an oxygen atom, a sulfur atom, And may be substituted with at least one selected from the group consisting of silicon atoms. In addition, the saturated hydrocarbon and the unsaturated hydrocarbon include a fluorine atom, a cyano group, an alkyl group having 1 to 6 carbon atoms, an alkenyl group having 2 to 6 carbon atoms, and 3 carbon atoms as a hydrogen atom substituent. May contain a cycloalkyl group having 8 to 8 carbon atoms, a cycloalkenyl group having 3 to 8 carbon atoms, an aryl group, or an aralkyl group, the alkyl group, an alkenyl group having 2 to 6 carbon atoms, and 3 to 3 carbon atoms. The cycloalkyl group having 8 carbon atoms, the cycloalkenyl group having 3 to 8 carbon atoms, the aryl group, and the aralkyl group are at least one selected from the group consisting of a fluorine atom, a nitrogen atom, an oxygen atom, a sulfur atom, and a silicon atom. May be included.

According to the present invention, a ketone compound can be efficiently produced by a simple method in which a specific precursor compound is immersed in an aprotic solvent. Conventional heating and catalytic reaction steps are not required. Moreover, there is no need to install a heating device or the like. For this reason, a process can be simplified and manufacturing cost can be reduced.
Also in the method for manufacturing an electricity storage device, the catalyst reaction step and the heating step can be omitted from the conventional production process of the electricity storage device, the process can be simplified, and the production cost can be reduced.

  The present invention relates to a method for producing a ketone compound having a structure represented by the following general formula (2) (hereinafter referred to as ketone compound (2)), and a precursor having a structure represented by the following general formula (1). It is characterized in that the body compound (hereinafter referred to as precursor compound (1)) is immersed in an aprotic solvent.

In formulas (1) and (2), R ₁ and R ₂ are each independently a hydrogen atom, a fluorine atom, a cyano group, an alkyl group having 1 to 4 carbon atoms, an alkenyl group having 2 to 8 carbon atoms, carbon A cycloalkyl group having 3 to 10 carbon atoms, a cycloalkenyl group having 3 to 10 carbon atoms, an aryl group, or an aralkyl group, the alkyl group having 1 to 8 carbon atoms, the alkenyl group having 2 to 8 carbon atoms, and the carbon number 3 -10 cycloalkyl group, C3-C10 cycloalkenyl group, aryl group, and aralkyl group are at least one selected from the group consisting of fluorine atom, nitrogen atom, oxygen atom, sulfur atom, and silicon atom R ₁ and R ₂ may form a ring, and R ₁ and R ₂ may further contain a ketone group.
For example, four or more ketone groups may be successively bonded by the three ketone groups in the formula (2) and one or more ketone groups in R ₁ and R ₂ . Further, R ₁ and R ₂ may include a structure in which three ketone groups are bonded in succession.

The precursor compound (1) includes a structure in which one carbon atom is bonded to two ketone groups and two hydroxyl groups in the molecule. When the precursor compound (1) is immersed in an aprotic solvent such as propylene carbonate, the precursor compound (1) undergoes a dehydration reaction in the aprotic solvent and exists in the precursor compound (1) 2 By removing H ₂ O from one hydroxyl group, a ketone compound (2) in which three ketone groups are successively bonded is obtained. The dehydration reaction proceeds at room temperature, using only an aprotic solvent, without requiring heating or a catalyst. In order to accelerate the dehydration reaction, it is preferable to stir the aprotic solvent. The dehydration reaction is shown in the following formula (1a).

  The method for producing a ketone compound of the present invention is a simple method of immersing in an aprotic solvent, and does not require a conventional heating step or catalytic reaction step. Further, there is no need to provide a heating device. For this reason, the manufacturing process of a ketone compound can be simplified and manufacturing cost can be reduced.

The aprotic solvent referred to here is an organic solvent, and refers to a solvent having a very weak property of releasing a proton (H ⁺ ) or donating a hydrogen bond. An aprotic solvent such as propylene carbonate or ethyl methyl carbonate may be used alone, or two or more kinds may be used in combination. In order to dehydrate the precursor compound in the aprotic solvent, the amount of water in the aprotic solvent is preferably less than 100 ppm.

When a ketone compound is used as an electrode active material for an electricity storage device, from the viewpoint of the structural stability and electrochemical properties of the ketone compound, the ketone compound (2) includes a ring structure in the molecule, and the ring has at least three ketone groups. Is a cyclic triketone compound containing an adjacent structure.
When a ketone compound is used as the electrode active material for an electricity storage device, as the aprotic solvent, a nonaqueous solvent such as propylene carbonate or ethyl methyl carbonate used for the nonaqueous electrolytic solution of the electricity storage device may be used.

  Examples of the electricity storage device include a primary battery, a secondary battery, a capacitor, an electrolytic capacitor, a sensor, or an electrochromic element. In addition, the triketone compound solution in which the triketone compound is dissolved in a solvent is supplied to the electrode using a liquid supply means, and a redox flow type electric storage device that can be charged and discharged in a state where the electrode active material is dissolved in the solvent can be mentioned. .

Examples of the cyclic triketone compound include compounds having a structure represented by the following general formula (4) (hereinafter referred to as ketone compound (4)).
The ketone compound (4) is obtained by immersing a precursor compound having a structure represented by the following formula (3) (hereinafter referred to as precursor compound (3)) in an aprotic solvent.

  In formulas (3) and (4), X is a saturated or unsaturated hydrocarbon having 2 to 4 carbon atoms, and at least one of the carbon atoms is a nitrogen atom, an oxygen atom, a sulfur atom, and It may be substituted with at least one selected from the group consisting of silicon atoms. In addition, the saturated hydrocarbon and the unsaturated hydrocarbon include a fluorine atom, a cyano group, an alkyl group having 1 to 6 carbon atoms, an alkenyl group having 2 to 6 carbon atoms, and 3 carbon atoms as a hydrogen atom substituent. A cycloalkyl group having 6 to 6 carbon atoms, a cycloalkenyl group having 3 to 8 carbon atoms, an aryl group, or an aralkyl group, the alkyl group, an alkenyl group having 2 to 6 carbon atoms, and 3 to 3 carbon atoms. The cycloalkyl group having 8 carbon atoms, the cycloalkenyl group having 3 to 8 carbon atoms, the aryl group, and the aralkyl group are at least one selected from the group consisting of a fluorine atom, a nitrogen atom, an oxygen atom, a sulfur atom, and a silicon atom. May be included.

  Examples of the ketone compound (4) include a triketone compound having a 5-membered ring structure having a structure represented by the following general formula (6) (hereinafter referred to as a triketone compound (6)). The triketone compound (6) can be obtained by immersing a precursor compound having a structure represented by the following general formula (5) (hereinafter referred to as precursor compound (5)) in an aprotic solvent.

In formulas (5) and (6), R _{3 to} R ₆ are each independently a hydrogen atom, a fluorine atom, a cyano group, an alkyl group having 1 to 4 carbon atoms, or an alkenyl group having 2 to 4 carbon atoms. , A cycloalkyl group having 3 to 6 carbon atoms, a cycloalkenyl group having 3 to 6 carbon atoms, an aryl group, or an aralkyl group,
The alkyl group, the alkenyl group having 2 to 4 carbon atoms, the cycloalkyl group having 3 to 6 carbon atoms, the cycloalkenyl group having 3 to 6 carbon atoms, the aryl group, and the aralkyl group are a fluorine atom, a nitrogen atom, You may contain at least 1 sort (s) chosen from the group which consists of an oxygen atom, a sulfur atom, and a silicon atom. R _{3 to} R ₆ in the formulas (5) and (6) are preferably substituents having a high electron-withdrawing property. More specifically, an aryl group such as a phenyl group, a cyano group, or a fluoro group is preferable.

  Examples of the triketone compound (6) include 1,2,3-indanetrione (hereinafter referred to as a ketone compound (8)) having a structure represented by the following general formula (8). A ketone compound (8) is obtained by immersing ninhydrin having a structure represented by the following general formula (7) in an aprotic solvent.

The ketone compound obtained by the production method of the present invention may be a multimer in which a ketone compound of the above general formula (4), (6) or (8) is combined as a basic unit (monomer). May be a polymer in which a plurality of is bonded. In the case of a multimer or a polymer, a larger number of reaction electrons can be obtained.
The multimer here refers to a compound containing at least two or more basic units (monomers), and is generally a compound formed by bonding about 2 to 50 basic units.
Further, the polymer as used herein refers to a compound having a molecular weight of 10,000 or more, and the upper limit is not particularly limited, but a compound having a molecular weight of 1,000,000 or less is generally used.
For example, examples of the multimer include ketone compounds having a structure represented by the following chemical formulas (9) to (11).

  The above chemical formulas (9) to (11) are obtained by immersing precursor compounds having structures represented by the following chemical formulas (12) to (14) in an aprotic solvent, respectively.

  Further, the ketone compound obtained by the production method of the present invention may be a compound having one site where at least three ketone groups are adjacent to each other in the molecule, or a compound having a plurality of the above sites. Examples of the compound having a plurality of the sites include ketone compounds having a structure represented by the chemical formula (15). In this case, a compound having a structure represented by the chemical formula (16) may be used as the precursor compound.

Hereinafter, the manufacturing method of the electrical storage device of this invention is demonstrated.
(1) Manufacturing method of 1st electrical storage device The manufacturing method of the 1st electrical storage device of this invention is related with the manufacturing method of the electrical storage device which comprises a positive electrode, a negative electrode, and a non-aqueous electrolyte,
A first step of immersing the precursor compound (3) in an aprotic solvent to produce a ketone compound (4);
A second step of producing an electrode containing the ketone compound as an active material;
Including
It is characterized in that the electrode is used for at least one of the positive electrode and the negative electrode.
The ketone compound which is an electrode active material can be manufactured easily and reliably by the above method, and a conventional heating step or catalytic reaction step is not required. Further, there is no need to provide a heating device or the like. For this reason, the manufacturing process of an electrical storage device can be simplified and manufacturing cost can be reduced.
In addition, since there is no influence on the electricity storage device due to the remaining aprotic solvent, it is preferable to use the same aprotic solvent as the nonaqueous solvent used for the nonaqueous electrolytic solution.

Hereinafter, an embodiment of a method for manufacturing a first power storage device of the present invention will be described with reference to a flowchart of the method for manufacturing a first power storage device of the present invention shown in FIG.
<Process (A1): Immersion process>
The precursor compound (3) is immersed in an aprotic solvent to produce a ketone compound (4). The amount of water in the aprotic solvent is preferably 100 ppm or less. One kind of aprotic solvent used in the production may be used, or two or more kinds may be mixed and used.
The aprotic solvent is preferably the same as the nonaqueous solvent in the nonaqueous electrolytic solution used for the electricity storage device because there is no influence on the electricity storage device due to the remaining aprotic solvent.
In a nonaqueous electrolyte battery, a nonaqueous electrolyte composed of a nonaqueous solvent other than water and a supporting salt dissolved in the nonaqueous solvent is used.
The time for immersing the precursor compound in the aprotic solvent may be appropriately determined according to the amount of the precursor compound, the type and amount of the aprotic solvent, and the immersion conditions.
What is necessary is just to change immersion conditions suitably. It can be determined that the ketone compound was obtained by carrying out cyclic voltammetry using an electrode (working electrode) containing a ketone compound and a non-aqueous electrolyte and confirming the redox reaction by the ketone compound.

<Process (A2): Electrode manufacturing process>
An electrode containing the obtained ketone compound as an active material is produced. As an electrode manufacturing process, a method commonly used in this field may be used. For example, an electrode mixture is obtained by adding a binder and a conductive material to the obtained ketone compound, and this electrode mixture is applied onto a current collector to form an electrode mixture layer on the current collector. Get an electrode.

<Process (A3): Storage device assembly process>
An electrical storage device is assembled using the obtained electrode.
An electricity storage device manufactured by the method for manufacturing an electricity storage device of the present invention includes a positive electrode, a negative electrode, a separator disposed between the positive electrode and the negative electrode, and a non-aqueous electrolyte. The electrode obtained above is used for at least one of the positive electrode and the negative electrode.
The assembly process of the electricity storage device may be a process commonly used in this field. For example, it includes a step of producing an electrode group by interposing a separator between the positive electrode and the negative electrode, a step of housing this electrode group in a battery case, injecting a non-aqueous electrolyte, and a step of sealing the battery case. The non-aqueous electrolyte is usually injected at normal temperature and normal pressure. However, when the viscosity of the non-aqueous electrolyte is high, the non-aqueous electrolyte may be injected in a heated or pressurized state.

Next, components of the electricity storage device will be described.
The positive electrode includes a positive electrode current collector and a positive electrode active material layer formed on the positive electrode current collector. What is necessary is just to use what is used regularly in this field | area as a positive electrode current collecting plate. For example, a porous or non-porous sheet or film made of a metal material such as nickel, aluminum, gold, silver, copper, stainless steel, or aluminum alloy may be used. The sheet-like material or film-like material is, for example, a metal foil or a mesh body. In order to strengthen the bond between the positive electrode active material layer and the positive electrode current collector, the positive electrode current collector layer and the positive electrode current collector may be chemically or physically bonded.

  When the ketone compound obtained using the production method of the present invention is used as a positive electrode active material, a material capable of occluding and releasing Li ions is used as the negative electrode active material. For example, the negative electrode active material includes carbon, graphitized carbon (graphite), carbon compounds such as amorphous carbon, lithium metal, lithium-containing composite nitrides, lithium-containing titanium compounds, Si, Si oxides, Si alloys, etc. Compounds, Sn, or Sn compounds such as Sn oxides or S alloys are used.

  Electron conduction aids and ion conduction aids are used to reduce electrode resistance. As the electron conduction auxiliary agent, those commonly used in this field may be used. For example, a carbon material such as carbon black, graphite, or acetylene black, or a conductive polymer compound such as polyaniline, polypyrrole, or polythiophene. Is mentioned. What is necessary is just to use a thing normally used in this field as an ion conduction auxiliary agent, For example, gel electrolytes, such as polymethylmethacrylate and polymethylmethacrylate, are mentioned.

  The binder is used for improving the binding property of the constituent material of the electrode. As the binder, those commonly used in this field may be used. For example, polyvinylidene fluoride, vinylidene fluoride-hexafluoropropylene copolymer, vinylidene fluoride-tetrafluoroethylene copolymer, polytetrafluoroethylene, Examples thereof include styrene-butadiene copolymer rubber, polypropylene, polyethylene, and polyimide.

  The negative electrode includes a negative electrode current collector and a negative electrode active material layer formed on the negative electrode current collector. For the negative electrode current collector, a metal material suitable for the power storage device configuration may be selected from the metal materials that can be used for the positive electrode current collector described above. As with the positive electrode current collector, a carbon material such as carbon is applied to the surface of the negative electrode current collector to reduce the resistance value, impart a catalytic effect, and strengthen the bond between the negative electrode active material layer and the negative electrode current collector. You may plan.

When the ketone compound obtained by using the production method of the present invention is used as a negative electrode active material, examples of the positive electrode active material include lithium-containing metal oxides such as LiCoO ₂ , LiNiO ₂ , LiMn ₂ O ₄ , activated carbon, oxidation A reducible organic compound is used. As the organic compound capable of oxidation and reduction, an organic compound having a π-electron conjugated cloud represented by tetrathiafulvalene in the molecule and an organic compound having a stable radical represented by a nitroxy radical in the molecule are used. As the electron conduction auxiliary agent, the ion conduction auxiliary agent, and the binder for the negative electrode, the same materials as the electron conduction auxiliary agent, the ion conduction auxiliary agent, and the binder for the positive electrode may be used.

  For the separator, for example, a microporous sheet or film having a predetermined ion permeability, mechanical strength, and insulation is used. As the separator, for example, a woven fabric or a non-woven fabric is used. Various resin materials are used for the separator, but it is preferable to use polyolefin such as polyethylene and polypropylene from the viewpoint of durability, shutdown function, and safety of the electricity storage device. Note that the shutdown function is a function of blocking the reaction of the electricity storage device by closing the through-hole when the amount of heat generated by the electricity storage device is significantly increased, thereby reducing the ion permeability.

As the non-aqueous electrolyte, for example, a liquid electrolyte or a gel electrolyte is used.
The liquid non-aqueous electrolyte includes a non-aqueous solvent and a supporting salt that is soluble in the non-aqueous solvent. As the supporting salt, a supporting salt usually used for a lithium ion battery or a non-aqueous electric double layer capacitor may be used. For example, the supporting salt which consists of the following cations and anions is mentioned. As the cation, for example, an alkali metal cation such as lithium, sodium, or potassium, an alkaline earth metal cation such as magnesium, or a quaternary ammonium cation such as tetraethylammonium or 1,3-ethylmethylimidazolium can be used. . These cations may be used alone or in combination of two or more. Examples of the anion include halide anion, perchlorate anion, trifluoromethanesulfonate anion, tetraborofluoride anion, trifluorophosphorus hexafluoride anion, bis (trifluoromethanesulfonyl) imide anion, or bis (perfluoroethylsulfonyl). An imide anion is mentioned. These anions may be used alone or in combination of two or more. The supporting salt is preferably a lithium salt composed of a lithium cation and the above anion.

When the supporting salt is liquid, the supporting salt and the solvent may or may not be mixed. When the supporting salt is in a solid state, it is preferable to use the supporting salt dissolved in a solvent.
As the solvent, a non-aqueous solvent used for a lithium ion battery or a non-aqueous electric double layer capacitor may be used. For example, ethylene carbonate, propylene carbonate, dimethyl carbonate, diethyl carbonate, methyl ethyl carbonate, γ-butyrolactone, tetrahydrofuran, dioxolane, sulfolane, dimethylformamide, and acetonitrile are used. These non-aqueous solvents may be used alone or in combination of two or more.

  As the gel electrolyte, for example, a mixture of a resin material, a non-aqueous solvent, and a supporting salt is used. Examples of the resin material include polyacrylonitrile, a copolymer of ethylene and acrylonitrile, and a polymer obtained by crosslinking these. As the non-aqueous solvent, for example, a low molecular weight aprotic solvent such as ethylene carbonate or propylene carbonate is used. As the supporting salt, the same salts as described above can be used. The gel electrolyte can also serve as a separator.

(2) Manufacturing method of 2nd electrical storage device The manufacturing method of the 2nd electrical storage device of this invention is related with the manufacturing method of the electrical storage device which comprises a positive electrode, a negative electrode, and nonaqueous electrolyte,
A first step of producing a precursor electrode containing the precursor compound (3);
A second step of immersing the precursor electrode in an aprotic solvent to produce an electrode containing the ketone compound (4) as an active material;
Including
It is characterized in that the electrode is used for at least one of the positive electrode and the negative electrode.
The ketone compound which is an electrode active material can be manufactured easily and reliably by the above method, and a conventional heating step or catalytic reaction step is not required. Further, there is no need to provide a heating device or the like. For this reason, the manufacturing process of an electrical storage device can be simplified and manufacturing cost can be reduced.
In addition, since there is no influence on the electricity storage device due to the remaining aprotic solvent, it is preferable to use the same aprotic solvent as the nonaqueous solvent used for the nonaqueous electrolytic solution.

Hereinafter, an embodiment of a method for manufacturing a second power storage device of the present invention will be described with reference to a flowchart of the method for manufacturing a second power storage device of the present invention shown in FIG.
<Process (B1): Precursor electrode manufacturing process>
A precursor electrode containing the precursor compound (3) is produced. For example, the precursor compound (3), a binder, an electron conduction auxiliary agent, and an ion conduction auxiliary agent are added, and the precursor mixture is applied onto the current collector, and the precursor mixture layer is formed on the current collector. The precursor electrode formed with is manufactured.

<Process (B2): Immersion process>
The obtained precursor electrode is immersed in an aprotic solvent, and the precursor compound contained in the precursor electrode is subjected to a dehydration reaction to produce an electrode containing the ketone compound (4) as an active material.
In order to quickly impregnate the entire precursor electrode with the aprotic solvent, in step (B2), deaeration may be performed once to reduce the pressure, and then the pressure may be returned to normal pressure.

<Process (B3): Storage device assembly process>
In the step (B3), the power storage device may be assembled by the same method as in the above step (A3).

(2) Manufacturing method of the 3rd electrical storage device of this invention The manufacturing method of the 3rd electrical storage device of this invention is the following.
Regarding a method for producing an electricity storage device comprising a positive electrode, a negative electrode and a non-aqueous electrolyte,
A first step of producing a precursor electrode comprising a precursor compound having a structure represented by the general formula (3);
After housing the electrode group including the precursor electrode in a battery case, a nonaqueous electrolytic solution including an aprotic solvent is injected, and the precursor compound in the precursor electrode is reacted with the aprotic solvent. A second step of producing an electrode containing, as an active material, a ketone compound having a structure represented by the general formula (4),
Including
It is characterized in that the electrode is used for at least one of the positive electrode and the negative electrode.
The ketone compound which is an electrode active material can be manufactured easily and reliably by the above method, and a conventional heating step or catalytic reaction step is not required. Further, there is no need to provide a heating device or the like. The liquid injection process of the second process also serves as a ketone compound manufacturing process. For this reason, the manufacturing process of an electrical storage device can be simplified and manufacturing cost can be reduced.

Hereinafter, an embodiment of a method for manufacturing a third power storage device of the present invention will be described with reference to the flowchart of the method for manufacturing a third power storage device of the present invention shown in FIG.
<Process (C1): Precursor electrode manufacturing process>
In the step (C1), a method similar to that in the above step (B1) may be used.

<Process (C2): Storage device assembly process>
An electrode group consisting of a pair of electrodes and a separator, in which at least one of the pair of electrodes is a precursor electrode, is housed in a battery case, and then a non-aqueous electrolyte is injected into the battery case (a liquid injection step). Examples of the combination of the pair of electrodes include a precursor positive electrode and a negative electrode, a positive electrode and a precursor negative electrode, a precursor positive electrode and a precursor negative electrode.
In the liquid injection step, since the precursor electrode is immersed in a nonaqueous electrolytic solution containing an aprotic solvent, the precursor compound contained in the precursor electrode undergoes a dehydration reaction to obtain a ketone compound (4). Thus, an electrode containing the ketone compound (4) as an active material is produced in the liquid injection process. This electrode is used as at least one of a positive electrode and a negative electrode. Except for the above, the power storage device may be assembled by the same method as in the step (A3).
In the above method, since the liquid injection process also serves as the dipping process, it is not necessary to separately provide the dipping process, and the manufacturing process of the electricity storage device can be simplified.

Examples of the present invention will be described in detail below, but the present invention is not limited to these examples.
Example 1
0.2 parts by weight of ninhydrin (manufactured by Aldrich) as a precursor compound was charged into 100 parts by weight of propylene carbonate as an aprotic solvent in a polypropylene container, and stirred for 5 minutes (immersion step). This dipping step was performed in a glow box equipped with a gas purifier, and the inside of the glow hop was at room temperature of 25 ° C. and an argon atmosphere.

<< Comparative Example 1 >>
Ninhydrin was heated to 300 ° C. under vacuum to obtain 1,2,3-indantrione, which is a cyclic triketone compound. To 100 parts by weight of propylene carbonate, 0.2 part by weight of 1,2,3-indantrione was added and stirred for 5 minutes.

[Evaluation 1]
In Example 1 and Comparative Example 1, the organic compounds in propylene carbonate were evaluated by ultraviolet / visible spectroscopy. This evaluation was performed immediately after stirring for 5 minutes.
After propylene carbonate in which an organic compound was immersed was placed in a quartz glass container for ultraviolet / visible spectroscopy, the absorption spectrum of each solution was measured in a specified wavelength range. The wavelength range was appropriately adjusted in the range of 1010 nm to 190 nm according to the range measured by the absorption spectrum of each solution. This evaluation was performed in the above-mentioned glow box.

  The absorption spectrum of ultraviolet / visible light of Example 1 and Comparative Example 1 is shown in FIGS. As shown in FIG. 4, in the propylene carbonate of Example 1, the peak of the absorption spectrum was confirmed in 550 nm-600 nm. As shown in FIG. 5, in the case of propylene carbonate containing 1,2,3-indantrione, the peak of the absorption spectrum was confirmed at 550 nm to 600 nm as in FIG. This peak is derived from the structure of 1,2,3-indantrione. From the above results, in the method of Example 1, it was confirmed that ninhydrin in propylene carbonate was changed to 1,2,3-indanetrione. Table 1 shows the absorption spectrum intensities of Example 1 and Comparative Example 1 at 550 nm to 600 nm.

  As shown in Table 1, the peak intensity of the absorption spectrum at 550 nm to 600 nm in Example 1 is the peak intensity of the absorption spectrum at 550 nm to 600 nm in propylene carbonate containing 1,2,3-indantrione of Comparative Example 1. It turns out that it is comparable. Since the absorption spectrum intensity is proportional to the solute concentration in the solvent, it has been confirmed that the conversion rate from ninhydrin to 1,2,3-indanetrione is almost 100%.

  From the above results, it was confirmed that the ketone compound can be produced by immersing the precursor compound in an aprotic solvent. Further, it was found that the ketone compound can be obtained in a short time at room temperature in the method for producing a ketone compound of the present invention. In the method for producing a ketone compound of the present invention, the method for producing a ketone compound of the present invention is useful from the viewpoint of reducing the production cost and simplifying the process without using a catalyst or heat treatment under vacuum. It was shown that.

Example 2
A three-electrode power storage device shown in FIG. 6 was manufactured by the method for manufacturing a power storage device of the present invention. FIG. 6 is a schematic configuration diagram of the electricity storage device. The electricity storage device was produced in a glow box equipped with a gas purification device. The inside of the glow box was at room temperature (25 ° C.) and an argon atmosphere.

  A glass cell 67 having a first electrode storage portion 67a and a second electrode storage portion 67c for storing electrodes, and a communication portion 67b communicating between the electrode storage portions was prepared. A non-aqueous electrolyte 61 was placed in the second storage portion 67 c of the cell 67. As the non-aqueous electrolyte 61, propylene carbonate in which lithium boron fluoride having a concentration of 1 mol / L was dissolved was used. In the first electrode storage portion 67 a of the cell 67, a nonaqueous electrolytic solution obtained by adding 1 mmol / L of ninhydrin as a precursor compound to the nonaqueous electrolytic solution having the same composition as the nonaqueous electrolytic solution 61 was put. At this time, the dehydration reaction of ninhydrin was caused by propylene carbonate in the non-aqueous electrolyte, and 1,2,3-indantrione was produced as a cyclic triketone compound. In this way, a nonaqueous electrolytic solution 65 in which 1 mmol / L of the cyclic triketone compound was dissolved was obtained. In the first electrode housing portion 67a, a positive electrode 62 for redoxing the dissolved cyclic triketone compound was disposed. A glassy carbon electrode (manufactured by BAS) having a diameter of 3 mmφ was used for the positive electrode 62. A negative electrode 63 and a reference electrode 64 are arranged in the second electrode storage portion 67c. The negative electrode 63 used was a 10 mm square mesh nickel current collector plate with a metal lithium plate (thickness 300 μm) attached thereto. As the reference electrode 64, a 7 mm square mesh nickel current collector plate with metal lithium (300 μm) attached thereto was used. The positive electrode 62 was immersed in the nonaqueous electrolytic solution 65, and the negative electrode 63 and the reference electrode 64 were immersed in the nonaqueous electrolytic solution 61. The non-aqueous electrolyte solution 61 and the non-aqueous electrolyte solution 65 were isolated by the glass filter 66 (separator) provided in the communication part 67b. In this way, the cyclic triketone compound constituted an electricity storage device A that was not mixed with the non-aqueous electrolyte 61 on the negative electrode side.

<< Comparative Example 2 >>
Ninhydrin was heated to 300 ° C. under vacuum to obtain 1,2,3-indantrione, which is a cyclic triketone compound. Nonaqueous electrolysis in which 1 mmol / L of 1,2,3-indandrione is added to the first electrode storage portion 67 of the cell 67 in place of the nonaqueous electrolyte 65 in addition to the nonaqueous electrolyte 61 having the same composition as the nonaqueous electrolyte 61. Put the liquid. Except for this, an electricity storage device B was produced in the same manner as in Example 2.

[Evaluation 2]
The electricity storage devices A and B obtained by the production methods of Example 2 and Comparative Example 2 were evaluated as follows. This evaluation was performed in the glow box. The evaluation was performed immediately after manufacturing the electricity storage device.
The potential of the positive electrode of the electricity storage device was scanned, and the reduction (discharge) reaction and oxidation (charge) reaction of the positive electrode active material were evaluated. Specifically, in the potential range of 1.0 to 4.0 V with respect to the lithium reference electrode standard, the potential is scanned from the natural potential (equilibrium potential) to the discharge side (base direction), and then the charge side (precious direction). ) Was electronically scanned. Then, the potential was scanned 3 times in the specified potential range. The scanning potential range was appropriately adjusted within a range of 1.0 to 4.0 V including a potential at which a peak corresponding to the oxidation-reduction reaction of the positive electrode active material was observed. The scanning speed was 20 mV / sec. Since the current was not stable during the initial potential scan, current-potential curves during the third round-trip potential scan are shown in FIGS.

  FIG. 7 shows a cyclic voltammogram in the case of the electricity storage device A, and FIG. 8 shows a cyclic voltammogram in the case of the electricity storage device B. As shown in FIGS. 7 and 8, in the electricity storage devices A and B, a two-stage oxidation-reduction reaction was confirmed. Table 2 shows the oxidation-reduction potentials of the positive electrodes in the electricity storage devices A and B.

As shown in Table 2, the electricity storage device A had almost the same oxidation-reduction potential as the electricity storage device B. From the above results, it was confirmed that the electricity storage device A obtained by the manufacturing method of the present invention performs the same operation as the electricity storage device B.
In the method for manufacturing the electricity storage device A, the heating step of ninhydrin unlike the method for producing the electricity storage device B is not required. Moreover, in the manufacturing method of the electrical storage device A, the liquid injection process also serves as the manufacturing process of the cyclic triketone compound. From this, it was confirmed that in the method for producing the electricity storage device A, the cyclic triketone compound can be produced easily and reliably, and at the same time, the production process can be simplified and the production cost can be reduced.
In Example 2 of the present invention, the power storage device was manufactured by the third power storage device manufacturing method of the present invention, but the power storage device was manufactured by the first and second power storage device manufacturing methods of the present invention. However, the same result as above can be obtained.

  The electricity storage device obtained by the production method of the present invention is suitably used as a power source for various portable electronic devices and transportation devices or an uninterruptible power supply.

It is a flowchart of the manufacturing process of the electrical storage device in Embodiment 1 of this invention. It is a flowchart of the manufacturing process of the electrical storage device in Embodiment 2 of this invention. It is a flowchart of the manufacturing process of the electrical storage device in Embodiment 3 of this invention. It is an absorption spectrum of the ultraviolet-visible spectroscopy of the organic compound in the solvent of Example 1 of this invention. It is an absorption spectrum of the ultraviolet and visible spectroscopy of the organic compound in the solvent of the conventional comparative example 1. It is a schematic block diagram of the electrical storage device of Example 2 of this invention. It is a cyclic voltammogram of the electrical storage device of Example 2 of the present invention. 10 is a cyclic voltammogram of a conventional electricity storage device of Comparative Example 2.

Explanation of symbols

61 Nonaqueous Electrolyte 62 Positive Electrode 63 Negative Electrode 64 Reference Electrode 65 Nonaqueous Electrolyte Containing Cyclic Triketone Compound 66 Glass Filter 67a First Electrode Storage Unit 67b Connection Unit 67c Second Electrode Storage Unit

Claims (8)

A ketone compound characterized in that a precursor compound having a structure represented by the following general formula (1) is immersed in an aprotic solvent to produce a ketone compound having a structure represented by the following general formula (2) Manufacturing method.
General formula (1):

General formula (2):

(In the formulas (1) and (2), R ₁ and R ₂ are each independently a hydrogen atom, a fluorine atom, a cyano group, an alkyl group having 1 to 4 carbon atoms, an alkenyl group having 2 to 8 carbon atoms, A cycloalkyl group having 3 to 10 carbon atoms, a cycloalkenyl group having 3 to 10 carbon atoms, an aryl group, or an aralkyl group, the alkyl group having 1 to 8 carbon atoms, the alkenyl group having 2 to 8 carbon atoms, and the carbon number The cycloalkyl group having 3 to 10 carbon atoms, the cycloalkenyl group having 3 to 10 carbon atoms, the aryl group, and the aralkyl group are at least one selected from the group consisting of a fluorine atom, a nitrogen atom, an oxygen atom, a sulfur atom, and a silicon atom. may contain species which may be the ring formed by R ₁ and R _2, R ₁ and R ₂ may further comprise a ketone group.) The precursor compound having a structure represented by the general formula (1) is a precursor compound having a structure represented by the following general formula (3),
The method for producing a ketone compound according to claim 1, wherein the ketone compound having a structure represented by the general formula (2) is a ketone compound having a structure represented by the following general formula (4).
General formula (3):

General formula (4):

(In the formulas (3) and (4), X is a saturated or unsaturated hydrocarbon having 2 to 4 carbon atoms, and at least one of the carbon atoms is a nitrogen atom, an oxygen atom, a sulfur atom, In addition, the saturated hydrocarbon and the unsaturated hydrocarbon may be substituted with a fluorine atom, a cyano group, or a carbon atom of 1 as a substituent of a hydrogen atom. -6 alkyl groups, alkenyl groups having 2 to 6 carbon atoms, cycloalkyl groups having 3 to 8 carbon atoms, cycloalkenyl groups having 3 to 8 carbon atoms, aryl groups, or aralkyl groups. The alkyl group, the alkenyl group having 2 to 6 carbon atoms, the cycloalkyl group having 3 to 8 carbon atoms, the cycloalkenyl group having 3 to 8 carbon atoms, the aryl group, and the aralkyl group are fluorine. Child, nitrogen atom, oxygen atom, sulfur atom, and may include at least one selected from the group consisting of a silicon atom.) The precursor compound having a structure represented by the general formula (3) is a precursor compound having a structure represented by the following general formula (5),
The method for producing a ketone compound according to claim 2, wherein the ketone compound having a structure represented by the general formula (4) is a ketone compound having a structure represented by the following general formula (6).
General formula (5):

General formula (6):

(In Formula (5) and (6), R < ₃ > -R < ₆ > is respectively independently a hydrogen atom, a fluorine atom, a cyano group, a C1-C4 alkyl group, and a C2-C4 alkenyl. Group, a cycloalkyl group having 3 to 6 carbon atoms, a cycloalkenyl group having 3 to 6 carbon atoms, an aryl group, or an aralkyl group, the alkyl group, an alkenyl group having 2 to 4 carbon atoms, and the number of carbon atoms The cycloalkyl group having 3 to 6 carbon atoms, the cycloalkenyl group having 3 to 6 carbon atoms, the aryl group, and the aralkyl group are at least one selected from the group consisting of a fluorine atom, a nitrogen atom, an oxygen atom, a sulfur atom, and a silicon atom. May contain seeds.) A method for producing an electricity storage device comprising a positive electrode, a negative electrode, and a non-aqueous electrolyte,
A first step of immersing a precursor compound having a structure represented by the following general formula (3) in an aprotic solvent to produce a ketone compound having a structure represented by the following general formula (4);
A second step of producing an electrode containing the ketone compound as an active material;
Including
The method of manufacturing an electricity storage device, wherein the electrode is at least one of the positive electrode and the negative electrode.
General formula (3):

General formula (4):

(In the formulas (3) and (4), X is a saturated or unsaturated hydrocarbon having 2 to 4 carbon atoms, and at least one of the carbon atoms is a nitrogen atom, an oxygen atom, a sulfur atom, In addition, the saturated hydrocarbon and the unsaturated hydrocarbon may be substituted with a fluorine atom, a cyano group, or a carbon atom of 1 as a substituent of a hydrogen atom. -6 alkyl groups, alkenyl groups having 2 to 6 carbon atoms, cycloalkyl groups having 3 to 8 carbon atoms, cycloalkenyl groups having 3 to 8 carbon atoms, aryl groups, or aralkyl groups. The alkyl group, the alkenyl group having 2 to 6 carbon atoms, the cycloalkyl group having 3 to 8 carbon atoms, the cycloalkenyl group having 3 to 8 carbon atoms, the aryl group, and the aralkyl group are fluorine. Child, nitrogen atom, oxygen atom, sulfur atom, and may include at least one selected from the group consisting of a silicon atom.)   The method for manufacturing an electricity storage device according to claim 4, wherein the aprotic solvent is the same as the nonaqueous solvent contained in the nonaqueous electrolytic solution. A method for producing an electricity storage device comprising a positive electrode, a negative electrode, and a non-aqueous electrolyte,
A first step of producing a precursor electrode containing a precursor compound having a structure represented by the following general formula (3);
A second step in which the precursor electrode is immersed in an aprotic solvent to produce an electrode containing a ketone compound having a structure represented by the following general formula (4) as an active material;
Including
The method of manufacturing an electricity storage device, wherein the electrode is at least one of the positive electrode and the negative electrode.
General formula (3):

General formula (4):

(In the formulas (3) and (4), X is a saturated or unsaturated hydrocarbon having 2 to 4 carbon atoms, and at least one of the carbon atoms is a nitrogen atom, an oxygen atom, a sulfur atom, In addition, the saturated hydrocarbon and the unsaturated hydrocarbon may be substituted with a fluorine atom, a cyano group, or a carbon atom of 1 as a substituent of a hydrogen atom. -6 alkyl groups, alkenyl groups having 2 to 6 carbon atoms, cycloalkyl groups having 3 to 8 carbon atoms, cycloalkenyl groups having 3 to 8 carbon atoms, aryl groups, or aralkyl groups. The alkyl group, the alkenyl group having 2 to 6 carbon atoms, the cycloalkyl group having 3 to 8 carbon atoms, the cycloalkenyl group having 3 to 8 carbon atoms, the aryl group, and the aralkyl group are fluorine. Child, nitrogen atom, oxygen atom, sulfur atom, and may include at least one selected from the group consisting of a silicon atom.)   The method for manufacturing an electricity storage device according to claim 6, wherein the aprotic solvent is the same as the nonaqueous solvent contained in the nonaqueous electrolytic solution. A method for producing an electricity storage device comprising a positive electrode, a negative electrode and a non-aqueous electrolyte,
A first step of producing a precursor electrode containing a precursor compound having a structure represented by the general formula (3);
After housing the electrode group including the precursor electrode in a battery case, a nonaqueous electrolytic solution including an aprotic solvent is injected, and the precursor compound in the precursor electrode is reacted with the aprotic solvent. A second step of producing an electrode containing, as an active material, a ketone compound having a structure represented by the following general formula (4);
Including
The method for manufacturing an electricity storage device, wherein the electrode is at least one of the positive electrode and the negative electrode.
General formula (3):

General formula (4):

(In the formulas (3) and (4), X is a saturated or unsaturated hydrocarbon having 2 to 4 carbon atoms, and at least one of the carbon atoms is a nitrogen atom, an oxygen atom, a sulfur atom, In addition, the saturated hydrocarbon and the unsaturated hydrocarbon may be substituted with a fluorine atom, a cyano group, or a carbon atom of 1 as a substituent of a hydrogen atom. -6 alkyl groups, alkenyl groups having 2 to 6 carbon atoms, cycloalkyl groups having 3 to 8 carbon atoms, cycloalkenyl groups having 3 to 8 carbon atoms, aryl groups, or aralkyl groups. The alkyl group, the alkenyl group having 2 to 6 carbon atoms, the cycloalkyl group having 3 to 8 carbon atoms, the cycloalkenyl group having 3 to 8 carbon atoms, the aryl group, and the aralkyl group are fluorine. Child, nitrogen atom, oxygen atom, sulfur atom, and may include at least one selected from the group consisting of a silicon atom.)

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