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JP2010060229A - Electrode operating method for burned ash melting furnace - Google Patents

Electrode operating method for burned ash melting furnace Download PDF

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JP2010060229A
JP2010060229A JP2008227704A JP2008227704A JP2010060229A JP 2010060229 A JP2010060229 A JP 2010060229A JP 2008227704 A JP2008227704 A JP 2008227704A JP 2008227704 A JP2008227704 A JP 2008227704A JP 2010060229 A JP2010060229 A JP 2010060229A
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electrode
graphite electrode
retracted position
time
incineration ash
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Susumu Shimura
進 志村
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Daido Steel Co Ltd
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Abstract

【課題】電極の止電を長時間行った場合にもCOガスの発生を低く抑えることができる。
【解決手段】燃焼空気を吹き込みつつ、昇降動可能な黒鉛電極3に通電して当該黒鉛電極3からの放電によって焼却灰Aを溶融する焼却灰溶融炉において、黒鉛電極3に通電し放電を生じさせる操業位置Xよりも上方に第1退避位置Yと第2退避位置Zを設定し、相対的に短時間の通常止電時には黒鉛電極3を第1退避位置Yへ上昇させるとともに、相対的に長時間の非定常止電時には黒鉛電極3を第1退避位置Yよりも上方の第2退避位置Zへ上昇させる。
【選択図】 図1
The generation of CO gas can be kept low even when the electrode is stopped for a long time.
In an incineration ash melting furnace in which incineration ash A is melted by discharging electric current from a graphite electrode 3 capable of moving up and down while blowing combustion air and discharging from the graphite electrode 3, electric power is supplied to the graphite electrode 3 to cause discharge. The first retracted position Y and the second retracted position Z are set above the operation position X to be operated, and the graphite electrode 3 is raised to the first retracted position Y at the time of normal power failure for a relatively short time. At the time of unsteady power stop for a long time, the graphite electrode 3 is raised to the second retracted position Z above the first retracted position Y.
[Selection] Figure 1

Description

本発明は焼却灰溶融炉の電極操作方法に関し、特に、COの排出を抑制できる電極操作方法に関する。   The present invention relates to an electrode operation method for an incineration ash melting furnace, and more particularly to an electrode operation method capable of suppressing CO emission.

ごみ焼却灰や下水・し尿・汚泥焼却灰等を減容し無害化する焼却灰溶融炉が知られており、その一例が特許文献1に開示されている。開示された焼却灰溶融炉では、炉蓋を上下方向へ貫通させて複数の黒鉛電極を設け、これら黒鉛電極から生じるアーク放電によって焼却灰を加熱し溶融している。この際、炉内へは燃焼空気が吹き込まれて、溶融時に発生する可燃性ガスが燃焼させられ、排ガスとして排出される。
特開平7−280448
An incineration ash melting furnace is known that reduces the volume of waste incineration ash, sewage, human waste, sludge incineration ash, etc. to make them harmless, and an example thereof is disclosed in Patent Document 1. In the disclosed incineration ash melting furnace, a plurality of graphite electrodes are provided by vertically passing the furnace lid, and the incineration ash is heated and melted by arc discharge generated from these graphite electrodes. At this time, combustion air is blown into the furnace, combustible gas generated at the time of melting is burned, and discharged as exhaust gas.
JP-A-7-280448

ところで、上記従来の焼却灰溶融炉において、炉蓋を貫通して炉内へ突出する黒鉛電極は、放電に伴う消耗以外に炉内雰囲気によって酸化消耗させられる。炉内温度は通常1000℃以上の高温となっているため、電極の黒鉛酸化により発生するガスは通常はCO2になる。ところが、排ガスダクトの点検や耐火物の部分交換等によって長時間電極通電を停止(止電)すると、炉内温度が低下するために黒鉛酸化により発生するガスがCO2まで酸化せず、COにとどまって排ガス中のCO濃度が高くなるという問題があった。   By the way, in the conventional incineration ash melting furnace, the graphite electrode that penetrates the furnace lid and protrudes into the furnace is oxidized and consumed by the atmosphere in the furnace in addition to the consumption accompanying the discharge. Since the furnace temperature is usually 1000 ° C. or higher, the gas generated by graphite oxidation of the electrode is usually CO 2. However, if electrode energization is stopped for a long time (stopping electricity) by inspection of the exhaust gas duct or partial replacement of the refractory, etc., the temperature generated in the furnace decreases and the gas generated by graphite oxidation does not oxidize to CO2, but remains in CO. As a result, there is a problem that the CO concentration in the exhaust gas becomes high.

本発明はこのような課題を解決するもので、電極の止電を長時間行った場合にもCOの発生を低く抑えることができる焼却灰溶融炉の電極操作方法を提供することを目的とする。   This invention solves such a subject, and it aims at providing the electrode operating method of the incineration ash melting furnace which can suppress generation | occurrence | production of CO low, even when the electrode is stopped for a long time. .

上記目的を達成するために、本発明では、燃焼空気を吹き込みつつ、昇降動可能な黒鉛電極(3)に通電して当該黒鉛電極(3)からの放電によって焼却灰(A)を溶融する焼却灰溶融炉において、黒鉛電極(3)に通電し放電を生じさせる操業位置(X)よりも上方に第1退避位置(Y)と第2退避位置(Z)を設定し、相対的に短時間の通常止電時には黒鉛電極(3)を第1退避位置(Y)へ上昇させるとともに、相対的に長時間の非定常止電時には黒鉛電極(3)を第1退避位置(Y)よりも上方の第2退避位置(Z)へ上昇させる。   In order to achieve the above object, in the present invention, incineration in which incineration ash (A) is melted by discharge from the graphite electrode (3) by energizing the graphite electrode (3) that can be moved up and down while blowing combustion air. In the ash melting furnace, the first retraction position (Y) and the second retraction position (Z) are set above the operation position (X) where the graphite electrode (3) is energized to generate a discharge, and the time is relatively short. The graphite electrode (3) is raised to the first retracted position (Y) at the time of normal power stop, and the graphite electrode (3) is moved above the first retracted position (Y) at the time of unsteady power stop for a relatively long time. To the second retracted position (Z).

本発明において、相対的に短時間の通常止電時には黒鉛電極は、ベースメタルMに電極下端が付着固化せずかつ通電復帰に時間を要しない第1退避位置へ上昇させられる。相対的に長時間の非定常止電時には黒鉛電極は上記第1退避位置よりも上方の第2退避位置へ上昇させられ、この位置では黒鉛電極の炉体内への露出長さが短くなるから、雰囲気温度が低下した状態での電極炭素分の酸化消耗は最小限に抑えられ、排ガス中のCO濃度が低く抑えられる。   In the present invention, the graphite electrode is raised to the first retraction position where the lower end of the electrode does not adhere to the base metal M and does not require time to return to energization at the time of normal stopping for a relatively short time. At the time of non-stationary power interruption for a relatively long time, the graphite electrode is raised to the second retracted position above the first retracted position, and at this position, the exposed length of the graphite electrode into the furnace body becomes short, Oxidation consumption of the electrode carbon in a state where the ambient temperature is lowered is minimized, and the CO concentration in the exhaust gas is kept low.

なお、上記カッコ内の符号は、後述する実施形態に記載の具体的手段との対応関係を示すものである。   In addition, the code | symbol in the said parenthesis shows the correspondence with the specific means as described in embodiment mentioned later.

以上のように、本発明の焼却灰溶融炉の電極操作方法によれば、電極の止電を長時間行った場合にもCOの発生を低く抑えることができる。   As described above, according to the electrode operating method for the incineration ash melting furnace of the present invention, the generation of CO can be suppressed even when the electrode is stopped for a long time.

図1は焼却灰溶融炉の一例を示す概略断面図である。図1において、上方へ開放する容器状の炉体1は炉蓋2で閉鎖されている。炉蓋2には空冷された複数の電極管21(図はそのうち一本のみを示す)が上下方向へ貫設されており、これら電極管21にそれぞれ黒鉛電極3が昇降動可能に挿通されている。黒鉛電極3は公知の電極昇降装置4に保持されて昇降作動させられる。電極昇降装置4は上下方向の三位置で黒鉛電極を選択的に位置決めできるように設定されている。三位置とは、後述する操業位置X、第1退避位置Y、第2退避位置Zで、この順に高くなっている。なお、上記三位置への黒鉛電極の位置決めはリミットスッチ等で検出することによって行う。   FIG. 1 is a schematic sectional view showing an example of an incineration ash melting furnace. In FIG. 1, a container-like furnace body 1 opened upward is closed by a furnace lid 2. A plurality of air-cooled electrode tubes 21 (only one of which is shown in the figure) are vertically penetrated in the furnace lid 2, and the graphite electrodes 3 are inserted through these electrode tubes 21 so as to be movable up and down. Yes. The graphite electrode 3 is held by a known electrode lifting device 4 and is moved up and down. The electrode lifting device 4 is set so that the graphite electrode can be selectively positioned at three positions in the vertical direction. The three positions are an operation position X, a first retraction position Y, and a second retraction position Z, which will be described later, and are higher in this order. The graphite electrode is positioned at the three positions by detecting it with a limit switch or the like.

焼却灰の溶融を行う通常運転時には、黒鉛電極3は図1に示すように最下位置の操業位置Xで保持されており、通電によって黒鉛電極3の下端と炉体1内に貯留された溶融したベースメタルMとの間でアーク放電Dを生じている。なお、操業位置Xは、黒鉛電極3の下端がベースメタルMの溶融面から上方へLX離れて位置するように設定されており、この状態では黒鉛電極3はLYの長さで炉体1内に露出している。操業位置XでのLXの一例は20〜30mm、LYは1580〜1570mmである。   During normal operation in which the incinerated ash is melted, the graphite electrode 3 is held at the lowest operating position X as shown in FIG. 1 and melted in the lower end of the graphite electrode 3 and the furnace body 1 by energization. An arc discharge D is generated between the base metal M and the base metal M. The operation position X is set so that the lower end of the graphite electrode 3 is positioned LX upward from the melting surface of the base metal M. In this state, the graphite electrode 3 has a length of LY and is in the furnace body 1. Is exposed. An example of LX at the operation position X is 20 to 30 mm, and LY is 1580 to 1570 mm.

炉蓋2には焼却灰供給口22が開口しており、ここから炉体1内へ投入供給された焼却灰Aが電極3のアーク熱によって加熱され溶融される。炉体1の側壁には燃焼空気供給口11が開口して、これより炉体1内へ燃焼空気Bが供給されており、溶融時に発生する可燃性ガスは燃焼空気Bによって燃焼させられる。この時生じる排ガスCは、炉蓋2に開口するガス排出口23を経て炉体1外へ排出される。なお、図1ではベースメタル表面を覆うスラグ層や炉体に設けられる出滓口は図示を省略してある。   An incineration ash supply port 22 is opened in the furnace lid 2, and the incineration ash A supplied and supplied from here into the furnace body 1 is heated and melted by the arc heat of the electrode 3. A combustion air supply port 11 is opened in the side wall of the furnace body 1, and the combustion air B is supplied into the furnace body 1 from this, and the combustible gas generated at the time of melting is combusted by the combustion air B. The exhaust gas C generated at this time is discharged out of the furnace body 1 through a gas discharge port 23 opened in the furnace lid 2. In FIG. 1, the slag layer that covers the surface of the base metal and the tap holes provided in the furnace body are not shown.

表1には、通常運転時の炉内雰囲気温度と排ガスC中のCO、CO2、O2の各ガス濃度の一例を示す。なお、表中のCO、CO2濃度はO212%換算値である。これによると、炉内雰囲気温度は1000〜1300℃を維持し、CO濃度は27ppmで、旧厚生省の「ごみ処理に係るダイオキシン類発生防止等ガイドライン」に示されたO212%換算でのCOの4時間平均規制値である30ppm以下を満足している。   Table 1 shows an example of the furnace atmosphere temperature during normal operation and the gas concentrations of CO, CO2, and O2 in the exhaust gas C. The CO and CO2 concentrations in the table are O2 12% equivalent values. According to this, the atmospheric temperature in the furnace is maintained at 1000 to 1300 ° C., the CO concentration is 27 ppm, and 4% of CO in terms of 12% of O2 shown in the “Guidelines for Prevention of Dioxins Concerning Garbage Disposal” The time average regulation value of 30 ppm or less is satisfied.

Figure 2010060229
Figure 2010060229

新たな黒鉛電極の継ぎ足し等のために10分程度の電極通電の停止(通常止電)を行うことがあるが、この際には、図2に示すように、黒鉛電極3を第1退避位置Yまで上昇させる。この第1退避位置Yは、ベースメタルMに電極下端が付着固化せず、かつ通電復帰に時間を要しないような、ベースメタルMの溶融面に近い上方位置であり、この場合のLXの一例は300mm程度、LYは1300mm程度である。   In order to add a new graphite electrode or the like, the electrode energization may be stopped for about 10 minutes (normal power stop). In this case, as shown in FIG. 2, the graphite electrode 3 is moved to the first retracted position. Raise to Y. The first retreat position Y is an upper position close to the melting surface of the base metal M so that the lower end of the electrode does not adhere and solidify on the base metal M, and it does not take time to return to energization. An example of LX in this case Is about 300 mm, and LY is about 1300 mm.

表2には、通常止電時の炉内雰囲気温度と排ガスC中の各ガス濃度の時間変化の一例を示す。なお、CO、CO2の濃度はO212%換算の瞬時値である。これによると、止電後15分で炉内雰囲気温度は850℃に低下し、CO濃度は35ppmに増加するが、4時間平均では30ppm以下となる。したがって、10分程度の通常止電であればCO濃度が問題になることは無い。   Table 2 shows an example of a change over time in the furnace atmosphere temperature and the concentration of each gas in the exhaust gas C at the normal power stop. The concentrations of CO and CO2 are instantaneous values in terms of O2 12%. According to this, the furnace atmosphere temperature dropped to 850 ° C. and the CO concentration increased to 35 ppm 15 minutes after the power stop, but the average for 4 hours is 30 ppm or less. Therefore, the CO concentration does not become a problem if the power is stopped for about 10 minutes.

Figure 2010060229
Figure 2010060229

ところが、排ガスダクトの清掃や耐火物の交換等によって半日程度と長時間の電極通電の停止(非定常止電)を行うと、黒鉛電極を第1退避位置に保持した状態では表2に示すように、時間の経過と雰囲気温度の低下とともに次第に排ガスC中のCO濃度が増加し、止電が30分以上になると4時間平均でのCO濃度が上記ガイドライン規制値の30ppmを大きく超えてしまう。なお、止電が90分以上になると雰囲気温度の低下によって黒鉛電極の炭素分の蒸発量が減り、CO濃度は低下し始めるが、その低下割合は小さく、4時間平均のCO濃度は30ppmを超えたままとなる。   However, when the electrode energization is stopped for about half a day (unsteady power stop) by cleaning the exhaust gas duct or replacing the refractory, as shown in Table 2, the graphite electrode is held at the first retracted position. In addition, the CO concentration in the exhaust gas C gradually increases with the passage of time and the atmospheric temperature, and when the static electricity is stopped for 30 minutes or more, the 4-hour average CO concentration greatly exceeds the guideline regulation value of 30 ppm. When the static electricity is stopped for 90 minutes or more, the evaporation amount of carbon in the graphite electrode decreases due to the decrease in the atmospheric temperature, and the CO concentration starts to decrease, but the decrease rate is small, and the average CO concentration for 4 hours exceeds 30 ppm. Will remain.

そこで、本実施形態では、長時間の非定常止電を行う場合には図3に示すように黒鉛電極3を第2退避位置Zまで上昇させる。第2退避位置ZにおけるLXは例えば1000mm程度、LYは600mm程度である。なお、LYを小さくした方が炉体1内への電極露出面積が小さくなって好ましいが、灼熱した黒鉛電極3の下端が上昇接近することによる電極管21周囲の機構部への熱的影響との兼ね合いを考慮する必要がある。   Therefore, in the present embodiment, when performing unsteady power interruption for a long time, the graphite electrode 3 is raised to the second retracted position Z as shown in FIG. LX at the second retracted position Z is, for example, about 1000 mm, and LY is about 600 mm. Although it is preferable to reduce LY since the exposed area of the electrode into the furnace body 1 is reduced, the thermal influence on the mechanical part around the electrode tube 21 due to the lower end of the heated graphite electrode 3 rising and approaching It is necessary to consider the trade-off.

第2退避位置Zでは黒鉛電極3の炉体1内への露出長さLYが短くなるから、雰囲気温度が低下した状態での電極炭素分の酸化消耗は最小限に抑えられる。この結果、表3に示すように排ガスC中のCO濃度は、止電後30分、60分、90分と経過してもO212%換算値の4時間平均値は前述のガイドライン規制値の30ppm以下を維持する。なお、表3中のCO濃度は止電後30分、60分の瞬時値が30ppmを越えているが、4時間平均値は30ppm以下となる。   At the second retreat position Z, the exposed length LY of the graphite electrode 3 into the furnace body 1 is shortened, so that the oxidative consumption of the electrode carbon in the state where the ambient temperature is lowered is minimized. As a result, as shown in Table 3, the CO concentration in the exhaust gas C is 30 ppm, 30 minutes, 60 minutes, 90 minutes after the power stop, and the 4-hour average value of O212% converted value is 30 ppm of the above-mentioned guideline regulation value. Maintain the following: In addition, the CO concentration in Table 3 is 30 minutes after stopping electricity, and the instantaneous value for 60 minutes exceeds 30 ppm, but the average value for 4 hours is 30 ppm or less.

Figure 2010060229
Figure 2010060229

本発明の一実施例における、通常運転時の焼却灰溶融炉の概略断面図である。It is a schematic sectional drawing of the incineration ash melting furnace at the time of normal operation in one Example of this invention. 通常止電時の焼却灰溶融炉の概略断面図である。It is a schematic sectional drawing of the incineration ash melting furnace at the time of a normal power stop. 非定常止電時の焼却灰溶融炉の概略断面図である。It is a schematic sectional drawing of the incineration ash melting furnace at the time of unsteady electric stop.

符号の説明Explanation of symbols

1…炉体、2…炉蓋、22…焼却灰供給口、23…ガス排出口、3…黒鉛電極、4…電極昇降装置、X…操業位置、Y…第1退避位置、Z…第2退避位置。   DESCRIPTION OF SYMBOLS 1 ... Furnace body, 2 ... Furnace lid, 22 ... Incineration ash supply port, 23 ... Gas discharge port, 3 ... Graphite electrode, 4 ... Electrode raising / lowering device, X ... Operation position, Y ... 1st evacuation position, Z ... 2nd Retraction position.

Claims (1)

燃焼空気を吹き込みつつ、昇降動可能な黒鉛電極に通電して当該黒鉛電極からの放電によって焼却灰を溶融する焼却灰溶融炉において、前記黒鉛電極に通電し放電を生じさせる操業位置よりも上方に第1退避位置と第2退避位置を設定し、通常止電時には前記黒鉛電極を前記第1退避位置へ上昇させるとともに、非定常止電時には前記黒鉛電極を前記第1退避位置よりも上方の前記第2退避位置へ上昇させることを特徴とする焼却灰溶融炉の電極操作方法。 In an incineration ash melting furnace that energizes a graphite electrode that can be moved up and down while blowing combustion air and melts the incineration ash by discharge from the graphite electrode, above the operation position that energizes the graphite electrode to cause discharge A first retracted position and a second retracted position are set, and the graphite electrode is raised to the first retracted position during a normal power stop, and the graphite electrode is moved above the first retracted position during an unsteady power stop. A method for operating an electrode of an incineration ash melting furnace, wherein the electrode is moved to a second retreat position.
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56102608A (en) * 1980-01-18 1981-08-17 Daido Steel Co Ltd Melting disposal furnace
JPS61143994A (en) * 1984-12-18 1986-07-01 川崎製鉄株式会社 Initial operation monitoring for refining arc furnace
JPH05109477A (en) * 1991-10-17 1993-04-30 Daido Steel Co Ltd Slag adhesion prevention method
JP2003083517A (en) * 2001-09-10 2003-03-19 Hitachi Metals Ltd Waste plasma melting method and waste plasma melting device
JP2003302034A (en) * 2002-04-11 2003-10-24 Ebara Corp Melting furnace and incineration ash melting method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56102608A (en) * 1980-01-18 1981-08-17 Daido Steel Co Ltd Melting disposal furnace
JPS61143994A (en) * 1984-12-18 1986-07-01 川崎製鉄株式会社 Initial operation monitoring for refining arc furnace
JPH05109477A (en) * 1991-10-17 1993-04-30 Daido Steel Co Ltd Slag adhesion prevention method
JP2003083517A (en) * 2001-09-10 2003-03-19 Hitachi Metals Ltd Waste plasma melting method and waste plasma melting device
JP2003302034A (en) * 2002-04-11 2003-10-24 Ebara Corp Melting furnace and incineration ash melting method

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