JP2009286754A - Emulsion-type hair cosmetic composition - Google Patents
Emulsion-type hair cosmetic composition Download PDFInfo
- Publication number
- JP2009286754A JP2009286754A JP2008143001A JP2008143001A JP2009286754A JP 2009286754 A JP2009286754 A JP 2009286754A JP 2008143001 A JP2008143001 A JP 2008143001A JP 2008143001 A JP2008143001 A JP 2008143001A JP 2009286754 A JP2009286754 A JP 2009286754A
- Authority
- JP
- Japan
- Prior art keywords
- agent
- cosmetic composition
- hair cosmetic
- salt
- examples
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 71
- 239000002537 cosmetic Substances 0.000 title claims abstract description 62
- 150000003839 salts Chemical class 0.000 claims abstract description 75
- 239000002738 chelating agent Substances 0.000 claims abstract description 34
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 22
- 229910017053 inorganic salt Inorganic materials 0.000 claims abstract description 20
- -1 Acyl methyl taurine salt Chemical class 0.000 claims description 28
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 claims description 22
- 239000000118 hair dye Substances 0.000 claims description 14
- 238000004945 emulsification Methods 0.000 claims description 6
- 229940104261 taurate Drugs 0.000 claims description 6
- 239000000839 emulsion Substances 0.000 abstract description 19
- 239000003795 chemical substances by application Substances 0.000 description 96
- 239000000975 dye Substances 0.000 description 16
- 239000004094 surface-active agent Substances 0.000 description 13
- 239000007800 oxidant agent Substances 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 11
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 10
- 235000014113 dietary fatty acids Nutrition 0.000 description 10
- 239000000194 fatty acid Substances 0.000 description 10
- 229930195729 fatty acid Natural products 0.000 description 10
- 239000003638 chemical reducing agent Substances 0.000 description 8
- 230000001590 oxidative effect Effects 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 230000003647 oxidation Effects 0.000 description 7
- 238000007254 oxidation reaction Methods 0.000 description 7
- 229920001296 polysiloxane Polymers 0.000 description 7
- XUMBMVFBXHLACL-UHFFFAOYSA-N Melanin Chemical compound O=C1C(=O)C(C2=CNC3=C(C(C(=O)C4=C32)=O)C)=C2C4=CNC2=C1C XUMBMVFBXHLACL-UHFFFAOYSA-N 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 235000019198 oils Nutrition 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 150000004665 fatty acids Chemical class 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 4
- 235000006708 antioxidants Nutrition 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 239000003002 pH adjusting agent Substances 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- 229960003080 taurine Drugs 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 239000004166 Lanolin Substances 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 150000008051 alkyl sulfates Chemical class 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 3
- 239000003925 fat Substances 0.000 description 3
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 3
- 239000000543 intermediate Substances 0.000 description 3
- 235000019388 lanolin Nutrition 0.000 description 3
- 229940039717 lanolin Drugs 0.000 description 3
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- FECNOIODIVNEKI-UHFFFAOYSA-N 2-[(2-aminobenzoyl)amino]benzoic acid Chemical class NC1=CC=CC=C1C(=O)NC1=CC=CC=C1C(O)=O FECNOIODIVNEKI-UHFFFAOYSA-N 0.000 description 2
- URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 description 2
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 2
- CWLKGDAVCFYWJK-UHFFFAOYSA-N 3-aminophenol Chemical compound NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 description 2
- JOOXCMJARBKPKM-UHFFFAOYSA-N 4-oxopentanoic acid Chemical compound CC(=O)CCC(O)=O JOOXCMJARBKPKM-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 2
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- 102000011782 Keratins Human genes 0.000 description 2
- 108010076876 Keratins Proteins 0.000 description 2
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 2
- JYXGIOKAKDAARW-UHFFFAOYSA-N N-(2-hydroxyethyl)iminodiacetic acid Chemical compound OCCN(CC(O)=O)CC(O)=O JYXGIOKAKDAARW-UHFFFAOYSA-N 0.000 description 2
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical class OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 2
- 239000001099 ammonium carbonate Substances 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical compound CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 2
- 125000005501 benzalkonium group Chemical class 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 229960000541 cetyl alcohol Drugs 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- 229960003067 cystine Drugs 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 229960004585 etidronic acid Drugs 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229960003330 pentetic acid Drugs 0.000 description 2
- CPJSUEIXXCENMM-UHFFFAOYSA-N phenacetin Chemical compound CCOC1=CC=C(NC(C)=O)C=C1 CPJSUEIXXCENMM-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- XXQBEVHPUKOQEO-UHFFFAOYSA-N potassium superoxide Chemical compound [K+].[K+].[O-][O-] XXQBEVHPUKOQEO-UHFFFAOYSA-N 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 2
- 229920001059 synthetic polymer Polymers 0.000 description 2
- 150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- DCCWEYXHEXDZQW-BYPYZUCNSA-N (2s)-2-[bis(carboxymethyl)amino]butanedioic acid Chemical compound OC(=O)C[C@@H](C(O)=O)N(CC(O)=O)CC(O)=O DCCWEYXHEXDZQW-BYPYZUCNSA-N 0.000 description 1
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- OOWQBDFWEXAXPB-IBGZPJMESA-N 1-O-hexadecyl-sn-glycerol Chemical compound CCCCCCCCCCCCCCCCOC[C@@H](O)CO OOWQBDFWEXAXPB-IBGZPJMESA-N 0.000 description 1
- AOSFMYBATFLTAQ-UHFFFAOYSA-N 1-amino-3-(benzimidazol-1-yl)propan-2-ol Chemical compound C1=CC=C2N(CC(O)CN)C=NC2=C1 AOSFMYBATFLTAQ-UHFFFAOYSA-N 0.000 description 1
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- GLXBPZNFNSLJBS-UHFFFAOYSA-N 11-methyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCCCCCCCCCCC(C)C GLXBPZNFNSLJBS-UHFFFAOYSA-N 0.000 description 1
- XPALGXXLALUMLE-UHFFFAOYSA-N 2-(dimethylamino)tetradecanoic acid Chemical compound CCCCCCCCCCCCC(N(C)C)C(O)=O XPALGXXLALUMLE-UHFFFAOYSA-N 0.000 description 1
- NLMKTBGFQGKQEV-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-hexadecoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CCCCCCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO NLMKTBGFQGKQEV-UHFFFAOYSA-N 0.000 description 1
- DMQQXDPCRUGSQB-UHFFFAOYSA-N 2-[3-[bis(carboxymethyl)amino]propyl-(carboxymethyl)amino]acetic acid Chemical compound OC(=O)CN(CC(O)=O)CCCN(CC(O)=O)CC(O)=O DMQQXDPCRUGSQB-UHFFFAOYSA-N 0.000 description 1
- SFAAOBGYWOUHLU-UHFFFAOYSA-N 2-ethylhexyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC SFAAOBGYWOUHLU-UHFFFAOYSA-N 0.000 description 1
- XULHFMYCBKQGEE-UHFFFAOYSA-N 2-hexyl-1-Decanol Chemical compound CCCCCCCCC(CO)CCCCCC XULHFMYCBKQGEE-UHFFFAOYSA-N 0.000 description 1
- OBCSAIDCZQSFQH-UHFFFAOYSA-N 2-methyl-1,4-phenylenediamine Chemical compound CC1=CC(N)=CC=C1N OBCSAIDCZQSFQH-UHFFFAOYSA-N 0.000 description 1
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 description 1
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- UIVPNOBLHXUKDX-UHFFFAOYSA-N 3,5,5-trimethylhexyl 3,5,5-trimethylhexanoate Chemical compound CC(C)(C)CC(C)CCOC(=O)CC(C)CC(C)(C)C UIVPNOBLHXUKDX-UHFFFAOYSA-N 0.000 description 1
- JAUFWPNLLLUYNV-UHFFFAOYSA-N 3-(16-methylheptadecoxy)propane-1,2-diol Chemical compound CC(C)CCCCCCCCCCCCCCCOCC(O)CO JAUFWPNLLLUYNV-UHFFFAOYSA-N 0.000 description 1
- 229940018563 3-aminophenol Drugs 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- DBFYESDCPWWCHN-UHFFFAOYSA-N 5-amino-2-methylphenol Chemical compound CC1=CC=C(N)C=C1O DBFYESDCPWWCHN-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
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- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- FPXLKVLNXFUYQU-UHFFFAOYSA-N CCO.OP(=O)OP(O)=O Chemical compound CCO.OP(=O)OP(O)=O FPXLKVLNXFUYQU-UHFFFAOYSA-N 0.000 description 1
- 239000004343 Calcium peroxide Substances 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 description 1
- SPAGIJMPHSUYSE-UHFFFAOYSA-N Magnesium peroxide Chemical compound [Mg+2].[O-][O-] SPAGIJMPHSUYSE-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- GWFGDXZQZYMSMJ-UHFFFAOYSA-N Octadecansaeure-heptadecylester Natural products CCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC GWFGDXZQZYMSMJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000004264 Petrolatum Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 description 1
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- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
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- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 229910000160 potassium phosphate Inorganic materials 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 1
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- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229940096501 sodium cocoamphoacetate Drugs 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
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- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
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- 235000010265 sodium sulphite Nutrition 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
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- 239000000600 sorbitol Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
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- 239000005720 sucrose Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
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Landscapes
- Cosmetics (AREA)
Abstract
【課題】無機塩及びキレート化剤の塩から選ばれる少なくとも一種を含有する乳化型毛髪化粧料組成物において、耐塩性が向上することにより乳化安定性を向上させることができる乳化型毛髪化粧料組成物を提供する。
【解決手段】乳化型毛髪化粧料組成物において、（Ａ）無機塩及びキレート化剤の塩から選ばれる少なくとも一種、（Ｂ）アシルメチルタウリン塩、並びに（Ｃ）ノニオン性界面活性剤を含有することを特徴とする。好ましくは、乳化型毛髪化粧料組成物中における（Ａ）無機塩及びキレート化剤の塩から選ばれる少なくとも一種の含有量は０．５〜８質量％である。
【選択図】なしIn an emulsified hair cosmetic composition containing at least one selected from inorganic salts and salts of chelating agents, an emulsified hair cosmetic composition capable of improving emulsion stability by improving salt resistance. Offer things.
An emulsified hair cosmetic composition contains (A) at least one selected from inorganic salts and salts of chelating agents, (B) acylmethyltaurine salts, and (C) nonionic surfactants. It is characterized by that. Preferably, the content of at least one selected from (A) an inorganic salt and a salt of a chelating agent in the emulsified hair cosmetic composition is 0.5 to 8% by mass.
[Selection figure] None
Description
本発明は、無機塩及びキレート化剤の塩から選ばれる少なくとも一種を含有する乳化型毛髪化粧料組成物に関し、さらに詳しくは、耐塩性が向上することにより乳化安定性を向上させた乳化型毛髪化粧料組成物に関する。 The present invention relates to an emulsified hair cosmetic composition containing at least one selected from an inorganic salt and a salt of a chelating agent. More specifically, the emulsified hair has improved emulsion stability by improving salt resistance. The present invention relates to a cosmetic composition.
一般に、毛髪の感触向上効果を付与するとともに組成物に所定の粘度を付与するために、例えば界面活性剤及び油性成分等を含有する乳化型毛髪化粧料組成物が知られている。乳化型毛髪化粧料組成物として、例えばヘアケア剤、整髪剤、染毛剤、脱色剤、パーマネントウェーブ剤、縮毛矯正剤及び脱染剤が知られている。 In general, an emulsified hair cosmetic composition containing, for example, a surfactant and an oil component is known in order to impart an effect of improving the feel of hair and to impart a predetermined viscosity to the composition. As an emulsified hair cosmetic composition, for example, a hair care agent, a hair styling agent, a hair dye, a decoloring agent, a permanent wave agent, a hair straightener, and a decoloring agent are known.
それらの乳化型毛髪化粧料組成物は、さらにｐＨ調整剤として無機塩が配合される場合がある。また、例えばパーマネントウェーブ剤及び縮毛矯正剤は、ケラチンのシスチン結合を還元することを目的として無機還元剤が配合されており、その他の乳化型毛髪化粧料組成物も含有成分の酸化防止を目的として、さらに無機還元剤が配合される場合がある。 These emulsified hair cosmetic compositions may further contain an inorganic salt as a pH adjuster. For example, permanent wave agents and hair straighteners are formulated with an inorganic reducing agent for the purpose of reducing the cystine bond of keratin, and other emulsified hair cosmetic compositions are also intended to prevent oxidation of the contained components. In some cases, an inorganic reducing agent is further blended.
従来より、特許文献１に開示されるように、メラニン色素を脱色する成分である酸化剤の分解を抑制するためにキレート化剤の塩を含有する染毛剤及び脱色剤が知られている。
ところが、乳化型毛髪化粧料組成物において、無機塩、例えば無機酸、無機アルカリ、及び無機還元剤、並びにキレート化剤の塩を配合すると、特に乳化型毛髪化粧料組成物の保存時において、経時的に組成物が分離（耐塩性が低下）し、乳化安定性が低下するという問題があった。 However, in the emulsified hair cosmetic composition, when an inorganic salt, for example, an inorganic acid, an inorganic alkali, and an inorganic reducing agent, and a chelating agent salt are blended, the aging time is particularly great during storage of the emulsified hair cosmetic composition. In particular, there was a problem that the composition was separated (salt resistance was lowered) and the emulsion stability was lowered.
本発明は、本発明者らの鋭意研究の結果、無機塩及びキレート化剤の塩から選ばれる少なくとも一種を含有する乳化型毛髪化粧料組成物において、特定の界面活性剤を併用することにより上記問題が解決されることを見出したことによりなされたものである。本発明の目的とするところは、無機塩及びキレート化剤の塩から選ばれる少なくとも一種を含有する乳化型毛髪化粧料組成物において、耐塩性が向上することにより乳化安定性を向上させることができる乳化型毛髪化粧料組成物を提供することにある。 As a result of intensive studies by the present inventors, the present invention provides an emulsified hair cosmetic composition containing at least one selected from inorganic salts and salts of chelating agents by using a specific surfactant in combination. It was made by finding out that the problem can be solved. An object of the present invention is to improve emulsion stability by improving salt resistance in an emulsified hair cosmetic composition containing at least one selected from inorganic salts and salts of chelating agents. The object is to provide an emulsified hair cosmetic composition.
上記の目的を達成するために、請求項１に記載の発明の乳化型毛髪化粧料組成物は、（Ａ）無機塩及びキレート化剤の塩から選ばれる少なくとも一種、（Ｂ）アシルメチルタウリン塩、並びに（Ｃ）ノニオン性界面活性剤を含有することを特徴とする。 In order to achieve the above object, the emulsified hair cosmetic composition of the invention according to claim 1 comprises (A) at least one selected from an inorganic salt and a salt of a chelating agent, and (B) an acylmethyl taurine salt. And (C) a nonionic surfactant.
請求項２に記載の発明は、請求項１に記載の乳化型毛髪化粧料組成物において、前記乳化型毛髪化粧料組成物中における（Ａ）無機塩及びキレート化剤の塩から選ばれる少なくとも一種の含有量が０．５〜８質量％であることを特徴とする。 Invention of Claim 2 is at least 1 type chosen from the salt of (A) inorganic salt and chelating agent in the emulsion type hair cosmetic composition of Claim 1 in the emulsion type hair cosmetic composition of Claim 1. The content of is characterized by being 0.5 to 8% by mass.
請求項３に記載の発明は、請求項１又は請求項２に記載の乳化型毛髪化粧料組成物において、前記乳化型毛髪化粧料組成物中における（Ｃ）ノニオン性界面活性剤の含有量が４〜３０質量％であることを特徴とする。 The invention according to claim 3 is the emulsified hair cosmetic composition according to claim 1 or 2, wherein the content of the (C) nonionic surfactant in the emulsified hair cosmetic composition is the same. It is 4-30 mass%, It is characterized by the above-mentioned.
請求項４に記載の発明は、請求項１から請求項３のいずれか一項に記載の乳化型毛髪化粧料組成物において、前記乳化型毛髪化粧料組成物中における（Ｂ）アシルメチルタウリン塩の含有量に対する（Ｃ）ノニオン性界面活性剤の含有量の質量比が８〜６０であることを特徴とする。 The invention according to claim 4 is the emulsified hair cosmetic composition according to any one of claims 1 to 3, wherein (B) an acylmethyl taurine salt in the emulsified hair cosmetic composition. The mass ratio of the content of (C) nonionic surfactant to the content of is 8 to 60.
請求項５に記載の発明は、請求項１から請求項４のいずれか一項に記載の乳化型毛髪化粧料組成物において、前記乳化型毛髪化粧料組成物は、染毛剤であることを特徴とする。 The invention according to claim 5 is the emulsified hair cosmetic composition according to any one of claims 1 to 4, wherein the emulsified hair cosmetic composition is a hair dye. Features.
本発明によれば、無機塩及びキレート化剤の塩から選ばれる少なくとも一種を含有する乳化型毛髪化粧料組成物において、耐塩性が向上することにより乳化安定性を向上させることができる。 According to the present invention, in an emulsified hair cosmetic composition containing at least one selected from an inorganic salt and a salt of a chelating agent, the emulsion stability can be improved by improving the salt resistance.
（第１実施形態）
以下、本発明に係る乳化型毛髪化粧料組成物を例えば染毛剤（酸化染毛剤）の第１剤に具体化した第１実施形態について詳細に説明する。本実施形態に係る第１剤は、後述する第２剤とともに２剤式の毛髪化粧料組成物として構成される。
(First embodiment)
Hereinafter, a first embodiment in which the emulsified hair cosmetic composition according to the present invention is embodied in, for example, a first agent of a hair dye (oxidative hair dye) will be described in detail. The 1st agent which concerns on this embodiment is comprised as a 2 agent type hair cosmetic composition with the 2nd agent mentioned later.
第１剤は、乳化型の第１剤として構成され、（Ａ）無機塩及びキレート化剤の塩から選ばれる少なくとも一種、（Ｂ）アシルメチルタウリン塩、並びに（Ｃ）ノニオン性界面活性剤を含有し、好ましくは酸化染料及びアルカリ剤を含有している。 The first agent is configured as an emulsified first agent, and comprises (A) at least one selected from inorganic salts and salts of chelating agents, (B) acylmethyl taurate, and (C) nonionic surfactant. Containing, preferably containing an oxidation dye and an alkali agent.
（Ａ）無機塩及びキレート化剤の塩から選ばれる少なくとも一種は、各種目的に応じ第１剤に配合される。例えば、ｐＨ調整剤、酸化防止剤（還元剤）、及び安定剤として第１剤中に配合される。無機塩としては、例えば炭酸塩、炭酸水素塩、リン酸塩、リン酸水素塩、塩化物、亜硫酸塩、亜硫酸水素塩、及びチオ硫酸塩が挙げられる。炭酸塩としては、例えば炭酸ナトリウム、炭酸アンモニウム、及び炭酸カリウムが挙げられる。炭酸水素塩としては、例えば炭酸水素ナトリウム、炭酸水素アンモニウム、及び炭酸水素カリウムが挙げられる。リン酸塩としては、例えばリン酸ナトリウム、及びリン酸カリウムが挙げられる。リン酸水素塩としては、例えばリン酸水素ナトリウム、及びリン酸水素カリウムが挙げられる。塩化物としては、例えば塩化アンモニウム、及び塩化ナトリウムが挙げられる。亜硫酸塩としては、例えば亜硫酸アンモニウム、及び亜硫酸ナトリウムが挙げられる。亜硫酸水素塩としては、例えば亜硫酸水素アンモニウム、及び亜硫酸水素ナトリウムが挙げられる。チオ硫酸塩としては、例えばチオ硫酸アンモニウム、及びチオ硫酸ナトリウムが挙げられる。 (A) At least 1 type chosen from the salt of an inorganic salt and a chelating agent is mix | blended with a 1st agent according to various purposes. For example, it mix | blends in a 1st agent as a pH adjuster, antioxidant (reducing agent), and a stabilizer. Examples of inorganic salts include carbonates, hydrogen carbonates, phosphates, hydrogen phosphates, chlorides, sulfites, hydrogen sulfites, and thiosulfates. Examples of the carbonate include sodium carbonate, ammonium carbonate, and potassium carbonate. Examples of the hydrogen carbonate include sodium hydrogen carbonate, ammonium hydrogen carbonate, and potassium hydrogen carbonate. Examples of the phosphate include sodium phosphate and potassium phosphate. Examples of the hydrogen phosphate include sodium hydrogen phosphate and potassium hydrogen phosphate. Examples of the chloride include ammonium chloride and sodium chloride. Examples of the sulfite include ammonium sulfite and sodium sulfite. Examples of the bisulfite include ammonium bisulfite and sodium bisulfite. Examples of the thiosulfate include ammonium thiosulfate and sodium thiosulfate.
キレート化剤の塩は、染色された毛髪の堅牢性の向上を目的として、又は含有成分の安定性向上を目的として配合される。キレート化剤の塩としては、例えば、アミノカルボン酸系のキレート化剤の塩及びホスホン酸系のキレート化剤の塩が挙げられる。アミノカルボン酸系のキレート化剤としては、例えば、エチレンジアミン四酢酸（ＥＤＴＡ）、ヒドロキシエチルエチレンジアミン三酢酸（ＨＥＤＴＡ）、ジヒドロキシエチルエチレンジアミン二酢酸（ＤＨＥＤＤＡ）、１，３−プロパンジアミン四酢酸（１，３ＰＤＴＡ）、ジエチレントリアミン五酢酸（ＤＴＰＡ）、トリエチレンテトラミン六酢酸（ＴＴＨＡ）、ニトリロ三酢酸（ＮＴＡ）、ヒドロキシエチルイミノ二酢酸（ＨＩＭＤＡ）、Ｌ−アスパラギン酸−Ｎ，Ｎ−二酢酸（ＡＳＤＡ）、及びそれらの誘導体が挙げられる。ホスホン酸系のキレート化剤としては、例えばアミノトリメチレンホスホン酸（ＮＴＭＰ）、ヒドロキシエタンジホスホン酸（ＨＥＤＰ）、及びそれらの誘導体が挙げられる。これらのキレート化剤の塩は単独で含有されてもよいし、二種以上が組み合わされて含有されてもよい。 The salt of the chelating agent is blended for the purpose of improving the fastness of the dyed hair or for the purpose of improving the stability of the contained components. Examples of the chelating agent salt include aminocarboxylic acid type chelating agent salts and phosphonic acid type chelating agent salts. Examples of aminocarboxylic acid-based chelating agents include ethylenediaminetetraacetic acid (EDTA), hydroxyethylethylenediaminetriacetic acid (HEDTA), dihydroxyethylethylenediaminediacetic acid (DHEDDA), 1,3-propanediaminetetraacetic acid (1,3PDTA). ), Diethylenetriaminepentaacetic acid (DTPA), triethylenetetraminehexaacetic acid (TTHA), nitrilotriacetic acid (NTA), hydroxyethyliminodiacetic acid (HIMDA), L-aspartic acid-N, N-diacetic acid (ASDA), and Their derivatives are mentioned. Examples of phosphonic acid-based chelating agents include aminotrimethylene phosphonic acid (NTMP), hydroxyethane diphosphonic acid (HEDP), and derivatives thereof. These chelating agent salts may be contained alone or in combination of two or more.
第１剤中における（Ａ）無機塩及びキレート化剤の塩から選ばれる少なくとも一種の含有量は、使用目的に応じ適宜決定されるが、好ましくは０．５〜８質量％である。（Ａ）無機塩及びキレート化剤の塩から選ばれる少なくとも一種の含有量が０．５〜８質量％の範囲を外れると、第１剤の耐塩性の向上による乳化安定性を向上させることができない場合がある。 The content of at least one selected from (A) an inorganic salt and a salt of a chelating agent in the first agent is appropriately determined according to the purpose of use, but is preferably 0.5 to 8% by mass. (A) When the content of at least one selected from an inorganic salt and a salt of a chelating agent is outside the range of 0.5 to 8% by mass, the emulsion stability can be improved by improving the salt resistance of the first agent. There are cases where it is not possible.
（Ｂ）アシルメチルタウリン塩は、アニオン性界面活性剤の一種であり、後述する（Ｃ）ノニオン性界面活性剤とともに第１剤の乳化安定性に寄与する。（Ｂ）アシルメチルタウリン塩としては、例えばラウロイルメチルタウリン塩、ミリストイルメチルタウリン塩、ステアロイルメチルタウリン塩、及びココイルメチルタウリンが挙げられる。第１剤中における（Ｂ）アシルメチルタウリン塩の含有量は、好ましくは０．１〜５質量％である。（Ｂ）アシルメチルタウリン塩の含有量がこの範囲を外れると、第１剤の耐塩性の向上による乳化安定性を向上させることができない場合がある。 (B) Acylmethyltaurine salt is a kind of anionic surfactant and contributes to the emulsion stability of the first agent together with (C) nonionic surfactant described later. Examples of (B) acylmethyl taurine salts include lauroyl methyl taurine salt, myristoyl methyl taurine salt, stearoyl methyl taurine salt, and cocoyl methyl taurine. The content of (B) acylmethyl taurate in the first agent is preferably 0.1 to 5% by mass. (B) If the content of the acylmethyl taurine salt is out of this range, the emulsion stability due to the improvement of salt resistance of the first agent may not be improved.
（Ｃ）ノニオン性界面活性剤は、（Ｂ）アシルメチルタウリン塩とともに第１剤の乳化安定性に寄与する。（Ｃ）ノニオン性界面活性剤としては、例えばポリオキシアルキレンアルキルエーテル、ポリオキシアルキレンアルケニルエーテル、ポリオキシエチレンソルビタン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、アルキルサッカライド界面活性剤、グリセリン脂肪酸エステル、ポリオキシエチレン硬化ヒマシ油、脂肪酸アルカノールアミド、ポリエーテル変性シリコーン、及びアルキルアミンオキサイドが挙げられる。ポリオキシアルキレンアルキルエーテルとしては、例えばラウレス（ポリオキシエチレン（ＰＯＥ）ラウリルエーテル）、セテス（ポリオキシエチレンセチルエーテル）、ステアレス(ポリオキシエチレンステアリルエーテル)、オレス（ポリオキシエチレンオレイルエーテル）、及びパレスが挙げられる。これらの界面活性剤の具体例の内、一種のみが単独で含有されてもよいし、二種以上が組み合わされて含有されてもよい。 (C) The nonionic surfactant contributes to the emulsion stability of the first agent together with (B) the acylmethyl taurate salt. (C) Nonionic surfactants include, for example, polyoxyalkylene alkyl ethers, polyoxyalkylene alkenyl ethers, polyoxyethylene sorbitan fatty acid esters, sucrose fatty acid esters, sorbitan fatty acid esters, alkyl saccharide surfactants, glycerin fatty acid esters, Examples include polyoxyethylene hydrogenated castor oil, fatty acid alkanolamide, polyether-modified silicone, and alkylamine oxide. Examples of the polyoxyalkylene alkyl ether include laureth (polyoxyethylene (POE) lauryl ether), ceteth (polyoxyethylene cetyl ether), steareth (polyoxyethylene stearyl ether), oleth (polyoxyethylene oleyl ether), and palace. Is mentioned. Among the specific examples of these surfactants, only one kind may be contained alone, or two or more kinds may be contained in combination.
第１剤中における（Ｃ）ノニオン性界面活性剤の含有量は、好ましくは４〜３０質量％、より好ましくは５〜１５質量％である。この配合量が４〜３０質量％の範囲を外れると、第１剤の乳化安定性を向上させることができない場合がある。 Content of (C) nonionic surfactant in a 1st agent becomes like this. Preferably it is 4-30 mass%, More preferably, it is 5-15 mass%. If this blending amount is out of the range of 4 to 30% by mass, the emulsion stability of the first agent may not be improved.
第１剤中における、（Ｂ）アシルメチルタウリン塩の含有量に対する（Ｃ）ノニオン性界面活性剤の含有量の質量比（（Ｃ）／（Ｂ））は、好ましくは８〜６０であり、より好ましくは８〜２０である。この質量比が８〜６０の範囲を外れると、第１剤の乳化安定性を向上させることができない場合がある。 The mass ratio ((C) / (B)) of the content of (C) nonionic surfactant to the content of (B) acylmethyl taurate in the first agent is preferably 8 to 60, More preferably, it is 8-20. If this mass ratio is outside the range of 8 to 60, the emulsion stability of the first agent may not be improved.
アルカリ剤は、第２剤に含有される酸化剤の作用を促進するとともに、毛髪を膨潤させて毛髪への染料の浸透性を向上させることにより、染色性を向上させる。アルカリ剤としては、例えばアンモニア、アルカノールアミン、有機アミン類、無機アルカリ、塩基性アミノ酸、及びそれらの塩が挙げられる。これらは単独で含有されてもよいし、二種以上が組み合わされて含有されてもよい。 The alkali agent promotes the action of the oxidizing agent contained in the second agent and improves the dyeability by swelling the hair and improving the permeability of the dye into the hair. Examples of the alkaline agent include ammonia, alkanolamines, organic amines, inorganic alkalis, basic amino acids, and salts thereof. These may be contained alone or in combination of two or more.
アルカリ剤の含有量は、好ましくは第１剤のｐＨが８〜１２の範囲となる量である。第１剤のｐＨが８未満では、第１剤が第２剤と混合されたときに、第２剤に含有される酸化剤として例えば過酸化水素の作用が十分に促進されない場合がある。第１剤のｐＨが１２を超えると、染毛剤が毛髪に塗布されたときに、毛髪に損傷等の不具合が発生しやすい。 The content of the alkaline agent is preferably such an amount that the pH of the first agent is in the range of 8-12. If the pH of the first agent is less than 8, when the first agent is mixed with the second agent, the action of, for example, hydrogen peroxide as the oxidizing agent contained in the second agent may not be sufficiently promoted. When the pH of the first agent exceeds 12, problems such as damage to the hair tend to occur when the hair dye is applied to the hair.
酸化染料は、第２剤に含有される酸化剤による酸化重合に起因して発色可能な化合物であり、染料中間体及びカプラーに分類される。酸化染料は少なくとも染料中間体を含んでいる。 Oxidative dyes are compounds that can develop color due to oxidative polymerization by an oxidant contained in the second agent, and are classified as dye intermediates and couplers. The oxidation dye contains at least a dye intermediate.
染料中間体としては、例えばｐ−フェニレンジアミン、トルエン−２，５−ジアミン、及びそれらの塩が挙げられる。これらの具体例の内、一種のみが単独で含有されてもよいし、二種以上が組み合わされて含有されてもよい。 Examples of the dye intermediate include p-phenylenediamine, toluene-2,5-diamine, and salts thereof. Among these specific examples, only 1 type may be contained independently and 2 or more types may be combined and contained.
カプラーは、染料中間体と結合することにより発色する。カプラーとしては、例えば５−アミノ−ｏ−クレゾール、ｍ−アミノフェノール、及びそれらの塩が挙げられる。これらの具体例の内、一種のみが単独で含有されてもよいし、二種以上が組み合わされて含有されてもよい。酸化染料は、毛髪の色調を様々に変化させることができることから、好ましくは、染料中間体の前記具体例の中から選ばれる少なくとも一種と、カプラーの前記具体例の中から選ばれる少なくとも一種とから構成される。第１剤は、前記酸化染料以外の染料として、例えば「医薬部外品原料規格」（１９９１年６月発行、薬事日報社）に収載された酸化染料、及び直接染料から選ばれる少なくとも一種を適宜含有してもよい。 Couplers develop color by binding to dye intermediates. Examples of the coupler include 5-amino-o-cresol, m-aminophenol, and salts thereof. Among these specific examples, only 1 type may be contained independently and 2 or more types may be combined and contained. Since the oxidative dye can change the color tone of the hair in various ways, it is preferable that at least one selected from the specific examples of the dye intermediate and at least one selected from the specific examples of the coupler. Composed. The first agent is appropriately selected from dyes other than the above-mentioned oxidation dyes, for example, at least one selected from the oxidation dyes listed in the “Quasi-drug Raw Material Standards” (issued in June 1991, Yakuji Nippo) and direct dyes. You may contain.
第１剤は、必要に応じて、前述した成分以外の成分、例えば水、水溶性高分子化合物、油性成分、多価アルコール、上記以外の界面活性剤、糖、防腐剤、安定剤、上記以外のｐＨ調整剤、植物抽出物、生薬抽出物、ビタミン、香料、上記以外の酸化防止剤、及び紫外線吸収剤を含有してもよい。 The first agent is a component other than the components described above, for example, water, water-soluble polymer compound, oil component, polyhydric alcohol, surfactant other than the above, sugar, preservative, stabilizer, other than the above, as necessary. PH adjusters, plant extracts, herbal extracts, vitamins, fragrances, antioxidants other than those described above, and ultraviolet absorbers may be included.
水は、各成分の可溶化剤として作用する。そのため、第１剤は、好ましくは水を含有する。水溶性高分子化合物としては、アニオン性高分子化合物、カチオン性高分子化合物、非イオン性高分子化合物、及び両性の天然又は合成高分子化合物が挙げられる。非イオン性の合成高分子化合物として、例えばポリエチレングリコールが挙げられる。 Water acts as a solubilizer for each component. Therefore, the first agent preferably contains water. Examples of the water-soluble polymer compound include an anionic polymer compound, a cationic polymer compound, a nonionic polymer compound, and an amphoteric natural or synthetic polymer compound. Examples of the nonionic synthetic polymer compound include polyethylene glycol.
油性成分は、毛髪にうるおい感を付与したり、第１剤を乳化し、粘度を調整したり粘度安定性を向上させたりする。そのため、第１剤は、好ましくは油性成分を含有する。油性成分としては、例えば油脂、ロウ、高級アルコール、炭化水素、高級脂肪酸、アルキルグリセリルエーテル、エステル、及びシリコーンが挙げられる。 The oil component imparts moisture to the hair, or emulsifies the first agent to adjust the viscosity or improve the viscosity stability. Therefore, the first agent preferably contains an oil component. Examples of the oil component include fats and oils, waxes, higher alcohols, hydrocarbons, higher fatty acids, alkyl glyceryl ethers, esters, and silicones.
油脂としては、例えばオリーブ油、ツバキ油、及びシア脂が挙げられる。ロウとしては、例えばミツロウ、キャンデリラロウ、カルナウバロウ、ホホバ油、及びラノリンが挙げられる。高級アルコールとしては、例えばセチルアルコール（セタノール）、２−ヘキシルデカノール、ステアリルアルコール、イソステアリルアルコール、セトステアリルアルコール、オレイルアルコール、アラキルアルコール、ベヘニルアルコール、及び２−オクチルドデカノールが挙げられる。 Examples of the fat include olive oil, camellia oil, and shea fat. Examples of the wax include beeswax, candelilla wax, carnauba wax, jojoba oil, and lanolin. Examples of the higher alcohol include cetyl alcohol (cetanol), 2-hexyldecanol, stearyl alcohol, isostearyl alcohol, cetostearyl alcohol, oleyl alcohol, aralkyl alcohol, behenyl alcohol, and 2-octyldodecanol.
炭化水素としては、例えばパラフィン、マイクロクリスタリンワックス、及びワセリンが挙げられる。高級脂肪酸としては、例えばステアリン酸、イソステアリン酸、オレイン酸、及びラノリン脂肪酸が挙げられる。アルキルグリセリルエーテルとしては、例えばバチルアルコール、キミルアルコール、セラキルアルコール、及びイソステアリルグリセリルエーテルが挙げられる。 Examples of the hydrocarbon include paraffin, microcrystalline wax, and petrolatum. Examples of higher fatty acids include stearic acid, isostearic acid, oleic acid, and lanolin fatty acid. Examples of the alkyl glyceryl ether include batyl alcohol, chimyl alcohol, ceralkyl alcohol, and isostearyl glyceryl ether.
エステルとしては、例えばミリスチン酸イソプロピル、オクタン酸セチル、イソノナン酸イソノニル、ミリスチン酸オクチルドデシル、パルミチン酸イソプロピル、ステアリン酸ステアリル、ミリスチン酸ミリスチル、ミリスチン酸イソトリデシル、及びパルミチン酸２−エチルへキシルが挙げられる。 Examples of the ester include isopropyl myristate, cetyl octanoate, isononyl isononanoate, octyldodecyl myristate, isopropyl palmitate, stearyl stearate, myristyl myristate, isotridecyl myristate, and 2-ethylhexyl palmitate.
シリコーンとしては、例えばジメチルポリシロキサン（ジメチコン）、メチルフェニルポリシロキサン、デカメチルシクロペンタシロキサン、末端水酸基変性ジメチルポリシロキサン、６５０〜１０，０００の平均重合度を有する高重合シリコーン、ポリエーテル変性シリコーン、アミノ変性シリコーン、及びアルキル変性シリコーンが挙げられる。これらの油性成分の具体例の内、一種のみが単独で含有されてもよいし、二種以上が組み合わされて含有されてもよい。 Examples of the silicone include dimethylpolysiloxane (dimethicone), methylphenylpolysiloxane, decamethylcyclopentasiloxane, terminal hydroxyl group-modified dimethylpolysiloxane, highly polymerized silicone having an average degree of polymerization of 650 to 10,000, polyether-modified silicone, Examples include amino-modified silicones and alkyl-modified silicones. Among the specific examples of these oily components, only one kind may be contained alone, or two or more kinds may be contained in combination.
多価アルコールとしては、例えばグリコール、及びグリセリンが挙げられる。グリコールとしては、例えばエチレングリコール、ポリエチレングリコール（ＰＥＧ）、プロピレングリコール、ジプロピレングリコール、及び１，３−ブチレングリコールが挙げられる。グリセリンとしては、例えばグリセリン、ジグリセリン及びポリグリセリンが挙げられる。 Examples of the polyhydric alcohol include glycol and glycerin. Examples of the glycol include ethylene glycol, polyethylene glycol (PEG), propylene glycol, dipropylene glycol, and 1,3-butylene glycol. Examples of glycerin include glycerin, diglycerin and polyglycerin.
界面活性剤は、乳化剤又は各成分の可溶化剤として第１剤を乳化し、粘度を調整したり粘度安定性を向上させたりする。そのため、第１剤は好ましくは界面活性剤を含有する。界面活性剤としては、アニオン性界面活性剤、カチオン性界面活性剤、及び両性界面活性剤が挙げられる。アニオン性界面活性剤としては、例えばアルキルエーテル硫酸塩、アルキル硫酸塩、アルケニルエーテル硫酸塩、アルケニル硫酸塩、オレフィンスルホン酸塩、アルカンスルホン酸塩、飽和又は不飽和脂肪酸塩、アルキル又はアルケニルエーテルカルボン酸塩、α-スルホン脂肪酸塩、Ｎ−アシルアミノ酸型界面活性剤、リン酸モノ又はジエステル型界面活性剤、及びスルホコハク酸エステルが挙げられる。これらの界面活性剤のアニオン基の対イオンとしては、例えばナトリウムイオン、カリウムイオン、及びトリエタノールアミンが挙げられる。アルキル硫酸塩としては、例えばラウリル硫酸ナトリウムが挙げられる。 The surfactant emulsifies the first agent as an emulsifier or a solubilizer of each component, and adjusts the viscosity or improves the viscosity stability. Therefore, the first agent preferably contains a surfactant. Examples of the surfactant include an anionic surfactant, a cationic surfactant, and an amphoteric surfactant. Examples of the anionic surfactant include alkyl ether sulfate, alkyl sulfate, alkenyl ether sulfate, alkenyl sulfate, olefin sulfonate, alkane sulfonate, saturated or unsaturated fatty acid salt, alkyl or alkenyl ether carboxylic acid. Examples include salts, α-sulfone fatty acid salts, N-acyl amino acid type surfactants, phosphate mono- or diester type surfactants, and sulfosuccinates. Examples of the counter ion of the anionic group of these surfactants include sodium ion, potassium ion, and triethanolamine. Examples of the alkyl sulfate include sodium lauryl sulfate.
カチオン性界面活性剤としては、例えばアルキルトリメチルアンモニウム塩、アルケニルトリメチルアンモニウム塩、ジアルキルジメチルアンモニウム塩、ジアルケニルジメチルアンモニウム塩、ラノリン脂肪酸アミドプロピルエチルジメチルアンモニウム、アルキロイルアミドプロピルジメチルアミン、アルキルピリジニウム塩、及びベンザルコニウム塩が挙げられる。これらの界面活性剤のカチオン基の対イオンとしては、例えば塩化物イオン、臭化物イオン、ヨウ化物イオン、アルキル硫酸イオン、及びサッカリンが挙げられる。アルキルトリメチルアンモニウム塩としては、例えば塩化ステアリルトリメチルアンモニウム、塩化セチルトリメチルアンモニウム、及び塩化ラウリルトリメチルアンモニウムが挙げられる。ベンザルコニウム塩としては、例えば塩化ベンザルコニウムが挙げられる。 Examples of cationic surfactants include alkyltrimethylammonium salts, alkenyltrimethylammonium salts, dialkyldimethylammonium salts, dialkenyldimethylammonium salts, lanolin fatty acid amidopropylethyldimethylammonium, alkyloylamidopropyldimethylamine, alkylpyridinium salts, and A benzalkonium salt is mentioned. Examples of the counter ion of the cationic group of these surfactants include chloride ion, bromide ion, iodide ion, alkyl sulfate ion, and saccharin. Examples of the alkyl trimethyl ammonium salt include stearyl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, and lauryl trimethyl ammonium chloride. An example of the benzalkonium salt is benzalkonium chloride.
両性界面活性剤としては、例えばココベタイン、ラウラミドプロピルベタイン、コカミドプロピルベタイン、ラウロアンホ酢酸ナトリウム、ココアンホ酢酸ナトリウム、及びラウリルベタイン（ラウリルジメチルアミノ酢酸ベタイン）が挙げられる。 Examples of amphoteric surfactants include cocobetaine, lauramidopropyl betaine, cocamidopropyl betaine, sodium lauroamphoacetate, sodium cocoamphoacetate, and lauryl betaine (lauryldimethylaminoacetic acid betaine).
糖としては、例えばソルビトール、及びマルトースが挙げられる。防腐剤としては、例えばパラベンが挙げられる。安定剤としては、例えばフェナセチンが挙げられる。ｐＨ調整剤としては、例えば乳酸、レブリン酸、グリコール酸、酒石酸、リンゴ酸、コハク酸、及びクエン酸が挙げられる。酸化防止剤としては、例えばアスコルビン酸が挙げられる。 Examples of the sugar include sorbitol and maltose. Examples of the preservative include parabens. Examples of the stabilizer include phenacetin. Examples of the pH adjuster include lactic acid, levulinic acid, glycolic acid, tartaric acid, malic acid, succinic acid, and citric acid. Examples of the antioxidant include ascorbic acid.
第１剤の剤型は、乳化型の液剤として構成される。乳化型の第１剤中に（Ａ）無機塩及びキレート化剤の塩から選ばれる少なくとも一種が含有される場合であっても、（Ｂ）アシルメチルタウリン塩及び（Ｃ）ノニオン性界面活性剤を配合することにより、乳化型の第１剤の乳化安定性を向上させることができる。 The dosage form of the first agent is configured as an emulsified liquid agent. Even when the emulsification type first agent contains at least one selected from (A) an inorganic salt and a salt of a chelating agent, (B) an acylmethyl taurine salt and (C) a nonionic surfactant By blending, the emulsification stability of the emulsification type first agent can be improved.
（第２実施形態）
以下、本発明に係る乳化型毛髪化粧料組成物を例えば染毛剤の第２剤に具体化した第２実施形態について詳細に説明する。
(Second Embodiment)
Hereinafter, a second embodiment in which the emulsified hair cosmetic composition according to the present invention is embodied in, for example, a second agent of a hair dye will be described in detail.
本実施形態に係る第２剤は、上述した第１剤とともに２剤式の毛髪化粧料組成物として構成される。第２剤は、（Ａ）無機塩及びキレート化剤の塩から選ばれる少なくとも一種、（Ｂ）アシルメチルタウリン塩、並びに（Ｃ）ノニオン性界面活性剤を含有し、好ましくは酸化剤を含有している。（Ａ）無機塩及びキレート化剤の塩から選ばれる少なくとも一種、（Ｂ）アシルメチルタウリン塩、並びに（Ｃ）ノニオン性界面活性剤は、第１実施形態の第１剤と同様の具体例及び配合量が適用される。 The 2nd agent which concerns on this embodiment is comprised as a 2 agent type hair cosmetic composition with the 1st agent mentioned above. The second agent contains (A) at least one selected from an inorganic salt and a salt of a chelating agent, (B) an acylmethyl taurine salt, and (C) a nonionic surfactant, preferably an oxidizing agent. ing. (A) At least one selected from inorganic salts and salts of chelating agents, (B) acylmethyltaurine salts, and (C) nonionic surfactants are the same as the first example of the first embodiment and The amount is applied.
酸化剤は、毛髪に含まれるメラニンを脱色するとともに、染料としての酸化染料を酸化して発色させる。酸化剤としては、例えば過酸化水素、過酸化尿素、過酸化メラミン、過炭酸ナトリウム、過炭酸カリウム、過ホウ酸ナトリウム、過ホウ酸カリウム、過硫酸アンモニウム、過酸化ナトリウム、過酸化カリウム、過酸化マグネシウム、過酸化バリウム、過酸化カルシウム、過酸化ストロンチウム、硫酸塩の過酸化水素付加物、リン酸塩の過酸化水素付加物、及びピロリン酸塩の過酸化水素付加物が挙げられる。第２剤中における酸化剤の含有量は、好ましくは０．１〜１５．０質量％であり、より好ましくは２．０〜９．０質量％であり、最も好ましくは３．０〜６．０質量％である。酸化剤の含有量が０．１質量％未満では、メラニンを十分に脱色することができない場合があるとともに、酸化染料を十分に酸化することができない場合がある。酸化剤の含有量が１５．０質量％を超えると、毛髪に損傷等の不具合が発生するおそれがある。 The oxidizing agent decolorizes melanin contained in the hair, and oxidizes an oxidizing dye as a dye to develop a color. Examples of the oxidizing agent include hydrogen peroxide, urea peroxide, melamine peroxide, sodium percarbonate, potassium percarbonate, sodium perborate, potassium perborate, ammonium persulfate, sodium peroxide, potassium peroxide, magnesium peroxide. , Barium peroxide, calcium peroxide, strontium peroxide, sulfate hydrogen peroxide adduct, phosphate hydrogen peroxide adduct, and pyrophosphate hydrogen peroxide adduct. The content of the oxidizing agent in the second agent is preferably 0.1 to 15.0% by mass, more preferably 2.0 to 9.0% by mass, and most preferably 3.0 to 6. 0% by mass. When the content of the oxidizing agent is less than 0.1% by mass, melanin may not be sufficiently decolored and the oxidation dye may not be sufficiently oxidized. When the content of the oxidizing agent exceeds 15.0% by mass, there is a risk that defects such as damage occur on the hair.
酸化剤として過酸化水素を第２剤に配合する場合、過酸化水素の安定性を向上させるために、好ましくは、第２剤は、安定化剤、例えばエチレングリコールフェニルエーテル（フェノキシエタノール）、ヒドロキシエタンジホスホン酸及びその塩を含有する。ヒドロキシエタンジホスホン酸塩としては、例えばヒドロキシエタンジホスホン酸四ナトリウム、及びヒドロキシエタンジホスホン酸二ナトリウムが挙げられる。第２剤は、染毛剤に一般的に含有され、且つ前述した各成分の作用を阻害しない各成分を含有してもよい。例えば、前述した第１剤に含有される、酸化染料及びアルカリ剤以外の成分を適宜含有してもよい。 When hydrogen peroxide is added to the second agent as an oxidizing agent, the second agent is preferably a stabilizer such as ethylene glycol phenyl ether (phenoxyethanol), hydroxyethane, in order to improve the stability of hydrogen peroxide. Contains diphosphonic acid and its salts. Examples of the hydroxyethane diphosphonate include tetrasodium hydroxyethane diphosphonate and disodium hydroxyethane diphosphonate. The second agent may be contained in hair dyes and may contain components that do not inhibit the action of the components described above. For example, you may contain suitably components other than the oxidation dye and alkali agent which are contained in the 1st agent mentioned above.
第２剤の剤型は、乳化型の液剤として構成される。乳化型の第２剤中に（Ａ）無機塩及びキレート化剤の塩から選ばれる少なくとも一種が含有される場合であっても、（Ｂ）アシルメチルタウリン塩及び（Ｃ）ノニオン性界面活性剤を配合することにより、乳化型の第２剤の耐塩性が向上することにより乳化安定性を向上させることができる。染毛剤の使用時には、第１剤及び第２剤を混合することにより混合物が調製される。次いで、必要量の混合物がコーム（櫛）又は刷毛に付着されて毛髪に塗布される。 The dosage form of the second agent is configured as an emulsified liquid agent. Even when the emulsion-type second agent contains at least one selected from (A) an inorganic salt and a salt of a chelating agent, (B) an acylmethyl taurine salt and (C) a nonionic surfactant By blending, the salt resistance of the emulsification-type second agent is improved, whereby the emulsion stability can be improved. When using the hair dye, a mixture is prepared by mixing the first agent and the second agent. The required amount of the mixture is then applied to the hair, attached to a comb or brush.
本実施形態に係る乳化型毛髪化粧料組成物は以下の利点を有する。
（１）本実施形態に係る乳化型毛髪化粧料組成物は、（Ａ）無機塩及びキレート化剤の塩から選ばれる少なくとも一種、（Ｂ）アシルメチルタウリン塩、並びに（Ｃ）ノニオン性界面活性剤を含有する。したがって、乳化型毛髪化粧料組成物の耐塩性が向上することにより乳化安定性を向上させることができる。
The emulsified hair cosmetic composition according to this embodiment has the following advantages.
(1) The emulsified hair cosmetic composition according to this embodiment comprises (A) at least one selected from inorganic salts and salts of chelating agents, (B) acylmethyl taurate, and (C) nonionic surfactant. Contains agents. Therefore, the emulsion stability can be improved by improving the salt resistance of the emulsified hair cosmetic composition.
（２）好ましくは、乳化型毛髪化粧料組成物中における（Ａ）無機塩及びキレート化剤の塩から選ばれる少なくとも一種の含有量が０．５〜８質量％である。この場合、耐塩性がより向上することにより乳化安定性をより向上させることができる。 (2) Preferably, at least one content selected from (A) an inorganic salt and a salt of a chelating agent in the emulsified hair cosmetic composition is 0.5 to 8% by mass. In this case, the emulsion stability can be further improved by further improving the salt resistance.
（３）好ましくは、乳化型毛髪化粧料組成物中における（Ｃ）ノニオン性界面活性剤の含有量が４〜３０質量％である。この場合、耐塩性がより向上することにより乳化安定性をより向上させることができる。 (3) Preferably, the content of (C) nonionic surfactant in the emulsified hair cosmetic composition is 4 to 30% by mass. In this case, the emulsion stability can be further improved by further improving the salt resistance.
（４）好ましくは、乳化型毛髪化粧料組成物中における（Ｂ）アシルメチルタウリン塩の含有量に対する（Ｃ）ノニオン性界面活性剤の含有量の質量比が８〜６０であることを特徴とする。この場合、耐塩性がより向上することにより乳化安定性をより向上させることができる。 (4) Preferably, the mass ratio of the content of (C) nonionic surfactant to the content of (B) acylmethyl taurine salt in the emulsified hair cosmetic composition is 8 to 60. To do. In this case, the emulsion stability can be further improved by further improving the salt resistance.
前記実施形態は以下のように変更されてもよい。
・上記実施形態において、乳化型毛髪化粧料組成物は、染毛剤の第１剤及び第２剤として適用した。しかしながら、乳化型毛髪化粧料組成物の使用形態としては特に限定されず、（Ａ）無機塩及びキレート化剤の塩から選ばれる少なくとも一種、（Ｂ）アシルメチルタウリン塩、並びに（Ｃ）ノニオン性界面活性剤を一剤中に含有する形態であれば、いずれの乳化型毛髪化粧料組成物にも適用することができる。この乳化型毛髪化粧料組成物は、例えば毛髪の感触向上効果を付与するためのヘアケア剤、例えばシャンプー、リンス、ヘアトリートメント剤、及びヘアクリームとして適用してもよい。この乳化型毛髪化粧料組成物は、整髪剤として適用してもよい。この乳化型毛髪化粧料組成物は、上記以外の染毛剤、例えば酸性染毛料として適用してもよい。この乳化型毛髪化粧料組成物は、例えばアルカリ剤を含有する脱色剤の第１剤、及び酸化剤を配合する脱色剤の第２剤として適用してもよい。この乳化型毛髪化粧料組成物は、例えば還元剤を配合することによりパーマネントウェーブ剤、縮毛矯正剤及び脱染剤として適用してもよい。
The embodiment may be modified as follows.
In the above embodiment, the emulsified hair cosmetic composition was applied as the first agent and the second agent of the hair dye. However, the usage form of the emulsified hair cosmetic composition is not particularly limited, and (A) at least one selected from inorganic salts and salts of chelating agents, (B) acylmethyl taurate, and (C) nonionic properties. As long as the surfactant is contained in one agent, it can be applied to any emulsified hair cosmetic composition. This emulsified hair cosmetic composition may be applied, for example, as a hair care agent for imparting an effect of improving the feel of hair, such as shampoo, rinse, hair treatment agent, and hair cream. This emulsified hair cosmetic composition may be applied as a hair styling agent. The emulsified hair cosmetic composition may be applied as a hair dye other than those described above, for example, an acidic hair dye. This emulsified hair cosmetic composition may be applied, for example, as a decoloring agent first agent containing an alkaline agent and a decoloring agent second agent containing an oxidizing agent. This emulsified hair cosmetic composition may be applied as a permanent wave agent, a hair straightener, and a decoloring agent, for example, by blending a reducing agent.
・乳化型毛髪化粧料組成物は、一剤式及び多剤式の乳化型毛髪化粧料組成物のいずれに適用してもよい。多剤式の乳化型毛髪化粧料組成物に適用する場合、本発明の各必須成分は、保存時の耐塩性向上による乳化安定性を向上する観点から同一剤中に配合されることが好ましい。多剤式の乳化型毛髪化粧料組成物が乳化剤と（Ａ）無機塩及びキレート化剤の塩から選ばれる少なくとも一種が別剤として保存され、混合後にさらに保存される場合、本発明の各必須成分は、混合時に混合物中に含有されていればよいため、複数剤中に別々に配合されてもよい。 The emulsified hair cosmetic composition may be applied to either one-component or multi-component emulsified hair cosmetic composition. When applied to a multi-component emulsified hair cosmetic composition, each essential component of the present invention is preferably blended in the same agent from the viewpoint of improving emulsification stability by improving salt resistance during storage. When the multi-component emulsified hair cosmetic composition contains at least one selected from an emulsifier, a salt of an inorganic salt and a chelating agent as a separate agent, and further preserved after mixing, each essential feature of the present invention Since the components only need to be contained in the mixture at the time of mixing, they may be blended separately in a plurality of agents.
・（Ａ）無機塩及びキレート化剤の塩から選ばれる少なくとも一種は、乳化型毛髪化粧料組成物中において、例えばｐＨ調整剤、酸化防止剤（還元剤）、及び安定剤として配合した。しかしながら、それらの配合目的に限定されるものではなく、その他、例えば乳化型毛髪化粧料組成物がパーマネントウェーブ剤及び縮毛矯正剤である場合、ケラチンのシスチン結合を還元するために無機還元剤として配合される。例えば乳化型毛髪化粧料組成物が脱染剤である場合、酸化染料の酸化重合により生成した多核化合物を還元するために無機還元剤として配合される。 -(A) At least 1 type chosen from the salt of an inorganic salt and a chelating agent was mix | blended, for example as a pH adjuster, antioxidant (reducing agent), and a stabilizer in an emulsified hair cosmetic composition. However, it is not limited to those compounding purposes. In addition, for example, when the emulsified hair cosmetic composition is a permanent wave agent and a hair straightener, as an inorganic reducing agent in order to reduce the cystine bond of keratin. Blended. For example, when the emulsified hair cosmetic composition is a decoloring agent, it is blended as an inorganic reducing agent in order to reduce a polynuclear compound produced by oxidative polymerization of an oxidative dye.
次に、実施例及び比較例を挙げて前記実施形態を更に具体的に説明する。
表１〜４に示す各成分を含有する、染毛剤の第１剤及び第２剤を調製した。表１〜４における各成分を示す欄中の数値は当該欄の成分の含有量を示し、その単位は質量％である。表中「成分」欄における（Ａ）〜（Ｃ）の表記は、本願請求項記載の各成分に対応する化合物を示す。一方、表中「成分」欄におけるａ，ｂの表記は、本願請求項記載の各成分の対比化合物を示す。また、表１〜４において、“ノニオン性界面活性剤の質量比”欄は、第１剤又は第２剤中における（Ｂ）アシルメチルタウリン塩の含有量に対する（Ｃ）ノニオン性界面活性剤の含有量の質量比（Ｃ／Ｂ）を示す。
Next, the embodiment will be described more specifically with reference to examples and comparative examples.
The 1st agent and 2nd agent of the hair dye containing each component shown in Tables 1-4 were prepared. The numerical value in the column which shows each component in Tables 1-4 shows content of the component of the said column, The unit is the mass%. The notation of (A) to (C) in the “component” column in the table indicates a compound corresponding to each component described in the claims of this application. On the other hand, the notation of a and b in the “component” column in the table indicates a comparative compound of each component described in the claims of the present application. In Tables 1 to 4, the column “mass ratio of nonionic surfactant” indicates (C) nonionic surfactant content relative to the content of (B) acylmethyltaurine salt in the first agent or second agent. The mass ratio (C / B) of content is shown.
＜耐塩性（乳化安定性）＞
各例の第１剤及び第２剤を透明なガラス容器に充填し、２５℃×１日放置した後、さらに６０℃×２日放置した。次に、パネラーがガラス容器に充填された各例の第１剤及び第２剤を目視にて観察することにより、界面が生じているか否か（分離しているか否か）を耐塩性として評価した。界面が生じていない場合を「良好」、界面が生じている場合を「悪い」とした。結果を表１〜４に示す。
<Salt resistance (emulsification stability)>
The first agent and the second agent of each example were filled in a transparent glass container, allowed to stand at 25 ° C. for 1 day, and further allowed to stand at 60 ° C. for 2 days. Next, the panelists evaluated the first agent and the second agent of each example filled in a glass container with the naked eye to evaluate whether or not an interface has occurred (whether or not separated) as salt resistance. did. The case where the interface did not occur was determined as “good”, and the case where the interface occurred occurred as “bad”. The results are shown in Tables 1-4.
次に、上記実施形態及び別例から把握できる技術的思想について、以下に追記する。
（ａ）前記無機塩は、炭酸塩、炭酸水素塩、リン酸塩、リン酸水素塩、塩化物、亜硫酸塩、亜硫酸水素塩、及びチオ硫酸塩から選ばれる少なくとも一種である前記毛髪化粧料組成物。
Next, the technical idea that can be grasped from the above embodiment and other examples will be described below.
(A) The hair cosmetic composition wherein the inorganic salt is at least one selected from carbonates, bicarbonates, phosphates, hydrogen phosphates, chlorides, sulfites, hydrogen sulfites, and thiosulfates. object.
（ｂ）前記アシルメチルタウリン塩は、ラウロイルメチルタウリン塩、ミリストイルメチルタウリン塩、ステアロイルメチルタウリン塩、及びココイルメチルタウリンから選ばれる少なくとも一種である前記毛髪化粧料組成物。 (B) The hair cosmetic composition, wherein the acylmethyl taurine salt is at least one selected from lauroyl methyl taurine salt, myristoyl methyl taurine salt, stearoyl methyl taurine salt, and cocoyl methyl taurine.
Claims (5)
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