JP2009242314A - Sun-screening cosmetic - Google Patents
Sun-screening cosmetic Download PDFInfo
- Publication number
- JP2009242314A JP2009242314A JP2008091898A JP2008091898A JP2009242314A JP 2009242314 A JP2009242314 A JP 2009242314A JP 2008091898 A JP2008091898 A JP 2008091898A JP 2008091898 A JP2008091898 A JP 2008091898A JP 2009242314 A JP2009242314 A JP 2009242314A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- sunscreen
- sunscreen cosmetic
- oil
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 56
- 238000012216 screening Methods 0.000 title abstract 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 34
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 21
- 239000000194 fatty acid Substances 0.000 claims abstract description 21
- 229930195729 fatty acid Natural products 0.000 claims abstract description 21
- 239000011787 zinc oxide Substances 0.000 claims abstract description 17
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 16
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 13
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000010696 ester oil Substances 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 239000007762 w/o emulsion Substances 0.000 claims abstract description 6
- 230000000475 sunscreen effect Effects 0.000 claims description 58
- 239000000516 sunscreening agent Substances 0.000 claims description 58
- FDATWRLUYRHCJE-UHFFFAOYSA-N diethylamino hydroxybenzoyl hexyl benzoate Chemical compound CCCCCCOC(=O)C1=CC=CC=C1C(=O)C1=CC=C(N(CC)CC)C=C1O FDATWRLUYRHCJE-UHFFFAOYSA-N 0.000 claims description 18
- 229960001630 diethylamino hydroxybenzoyl hexyl benzoate Drugs 0.000 claims description 18
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- FMJSMJQBSVNSBF-UHFFFAOYSA-N octocrylene Chemical group C=1C=CC=CC=1C(=C(C#N)C(=O)OCC(CC)CCCC)C1=CC=CC=C1 FMJSMJQBSVNSBF-UHFFFAOYSA-N 0.000 claims description 9
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- 125000000217 alkyl group Chemical group 0.000 description 5
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
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- 238000011109 contamination Methods 0.000 description 3
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- 235000017709 saponins Nutrition 0.000 description 3
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- 238000012360 testing method Methods 0.000 description 3
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- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- GHOKWGTUZJEAQD-ZETCQYMHSA-N (D)-(+)-Pantothenic acid Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCC(O)=O GHOKWGTUZJEAQD-ZETCQYMHSA-N 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
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Images
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Abstract
Description
本発明は日焼け止め化粧料に関するものである。さらに詳しくは、衣服への二次付着による汚着を防止する日焼け止め化粧料に関する。 The present invention relates to a sunscreen cosmetic. More specifically, the present invention relates to a sunscreen cosmetic that prevents contamination due to secondary adhesion to clothes.
日焼け止め化粧料による重要な紫外線吸収波長領域は、ＵＶ−Ａ領域（３２０〜４００ｎｍ）とＵＶ−Ｂ領域（２９０〜３２０ｎｍ）である。そして、ＵＶ−Ａ領域の紫外線は皮膚を黒化させるが、ＵＶ−Ｂ領域の紫外線のようにサンバーンを起こし、皮膚の老化を促進させるものではないと考えられていた。 The important ultraviolet absorption wavelength regions by sunscreen cosmetics are the UV-A region (320 to 400 nm) and the UV-B region (290 to 320 nm). The ultraviolet rays in the UV-A region darken the skin, but it was thought that sunburn occurred like the ultraviolet rays in the UV-B region and did not promote skin aging.
ところが近年になって、ＵＶ−Ｂ領域の紫外線が比較的、皮膚の表面部分にとどまるのに対して、ＵＶ−Ａ領域の紫外線が、皮膚の深部にまで達し、皮膚の老化はもとより皮膚癌を誘発する原因となることが分かってきた。このように、日焼け止め化粧料には特にＵＶ−Ａ領域の紫外線吸収への要求が高まっている。 However, in recent years, ultraviolet rays in the UV-B region stay relatively on the surface of the skin, whereas ultraviolet rays in the UV-A region reach the deep part of the skin, causing skin cancer as well as skin aging. It has been found to be a cause of triggering. Thus, there is an increasing demand for sunscreen cosmetics, particularly in the UV-A region.
ＵＶ−Ａ領域に有用な紫外線吸収剤の一つに、ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシルが存在する。また、周知の紫外線吸収剤として、オクチルメトキシシンナメート（ｐ−メトキシケイ皮酸−２−エチルヘキシル）、オクトクリレンが存在する。 One useful UV absorber for the UV-A region is hexyl diethylaminohydroxybenzoyl benzoate. Moreover, octyl methoxycinnamate (p-methoxycinnamate-2-ethylhexyl) and octocrylene are known UV absorbers.
ところで、日焼け止め化粧料における重要な課題に、紫外線吸収剤の着色に基づく衣服に二次付着した場合の汚着（即ち染着性）の問題がある。 By the way, an important problem in sunscreen cosmetics is the problem of staining (ie, dyeing properties) when they are secondarily attached to clothes based on the coloring of the UV absorber.
そして、ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシルは、有用なＵＶ−Ａ領域の紫外線吸収剤ではあるが、二次付着により汚着する。したがって、ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシルは日焼け止め化粧料に高配合することが出来ない。 And diethylaminohydroxybenzoyl hexyl benzoate is a useful UV-A UV absorber, but it is contaminated by secondary adhesion. Therefore, diethylaminohydroxybenzoyl hexyl benzoate cannot be highly blended in sunscreen cosmetics.
これに対して、ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシルと特定のベンゾトリアゾール誘導体とを組み合わせて日焼け止め化粧料に配合することにより、汚着防止を図る技術が開発されている（特許文献１）。 On the other hand, a technique for preventing antifouling has been developed by combining diethylaminohydroxybenzoyl hexyl benzoate and a specific benzotriazole derivative in a sunscreen cosmetic (Patent Document 1).
また、オクチルメトキシシンナメートやオクトクリレンは日焼け止め化粧料に有用な紫外線吸収剤ではある。ところが、オクチルメトキシシンナメートは容易に着色して汚着の原因となる。これに対して、オクチルメトキシシンナメートと特定のベンゾトリアゾール誘導体とを組み合わせて配合することにより、オクチルメトキシシンナメートの汚着（着色性）を防ぎ、かつＵＶ−Ａ領域においても優れた紫外線吸収効果を発揮させる技術が開発されている（特許文献２）。 Octyl methoxycinnamate and octocrylene are useful UV absorbers for sunscreen cosmetics. However, octylmethoxycinnamate is easily colored and causes staining. In contrast, by combining octyl methoxycinnamate and a specific benzotriazole derivative in combination, octyl methoxy cinnamate is prevented from being stained (colorability) and has an excellent ultraviolet absorption effect in the UV-A region. A technique for exhibiting the above has been developed (Patent Document 2).
一方、ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシルを配合した油中水型乳化組成物からなる日焼け止め化粧料は公知である（特許文献３）。そして、日焼け止め化粧料には、紫外線防御効果を上げるために、紫外線吸収剤と共に、紫外線散乱剤として酸化亜鉛及び／又は酸化チタンの粉末を配合することが多い。 On the other hand, sunscreen cosmetics comprising a water-in-oil emulsion composition containing diethylaminohydroxybenzoyl hexyl benzoate are known (Patent Document 3). And in order to raise an ultraviolet-ray protective effect, in many sunscreen cosmetics, the powder of a zinc oxide and / or a titanium oxide is mix | blended as an ultraviolet-ray scattering agent with an ultraviolet absorber.
本発明者らは、日焼け止め化粧料について汚着防止の観点から鋭意研究を重ねた結果、
ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシルを含有する日焼け止め化粧料において、
（１）エステル結合を二つ以上有するエステル油と、
（２）脂肪酸以外で疎水化処理をした酸化亜鉛及び／又は酸化チタンと
を配合し、
（３）さらに油中水型乳化組成物
からなる日焼け止め化粧料を調製すると、衣服に二次付着した汚着を洗濯により容易に除去できることを見出し、本発明を完成するに至った。
As a result of earnest research on the sunscreen cosmetics from the viewpoint of anti-staining,
In a sunscreen cosmetic containing diethylaminohydroxybenzoyl hexyl benzoate,
(1) an ester oil having two or more ester bonds;
(2) Blending with zinc oxide and / or titanium oxide hydrophobized with other than fatty acids,
(3) When a sunscreen cosmetic comprising a water-in-oil emulsified composition is further prepared, it has been found that the secondary adhesion on clothes can be easily removed by washing, and the present invention has been completed.
本発明の目的は、ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシルを含有する日焼け止め化粧料において、衣服の汚着（染着性）を改善した日焼け止め化粧料を提供することにある。さらには、広いＵＶ領域にて高い紫外線防効果を発揮する日焼け止め化粧料を提供することにもある。 The objective of this invention is providing the sunscreen cosmetics which improved the stain | pollution | contamination (dyeing property) of clothes in the sunscreen cosmetics containing diethylaminohydroxybenzoyl hexyl benzoate. Furthermore, it is also providing the sunscreen cosmetics which show a high ultraviolet-ray prevention effect in a wide UV region.
すなわち本発明は、
ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシルを含有する日焼け止め化粧料において、
（１）エステル結合を二つ以上有するエステル油と、
（２）脂肪酸以外で疎水化処理をした酸化亜鉛及び／又は酸化チタンと
を配合し、
（３）さらに油中水型乳化組成物に調製すること
を特徴とする日焼け止め化粧料を提供するものである。
That is, the present invention
In a sunscreen cosmetic containing diethylaminohydroxybenzoyl hexyl benzoate,
(1) an ester oil having two or more ester bonds;
(2) Blending with zinc oxide and / or titanium oxide hydrophobized with other than fatty acids,
(3) A sunscreen cosmetic characterized in that it is further prepared into a water-in-oil emulsion composition.
また本発明は、前記脂肪酸がステアリン酸及び／又はミリスチン酸であることを特徴とする上記の日焼け止め化粧料を提供するものである。 The present invention also provides the sunscreen cosmetic described above, wherein the fatty acid is stearic acid and / or myristic acid.
さらに本発明は、さらに（４）オクチルメトキシシンナメート及び／又はオクトクリレンを配合することを特徴とする上記の日焼け止め化粧料を提供するものである。 The present invention further provides the sunscreen cosmetic described above, further comprising (4) octylmethoxycinnamate and / or octocrylene.
また、本発明は、前記ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシルの配合量が、日焼け止め化粧料全量に対して１〜５質量％であることを特徴とする上記の日焼け止め化粧料を提供するものである。 The present invention also provides the sunscreen cosmetic described above, wherein the amount of hexyl diethylaminohydroxybenzoyl benzoate is 1 to 5% by mass based on the total amount of the sunscreen cosmetic. .
（１）本発明の日焼け止め化粧料は、ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシルの衣服に対する汚着を低減する。したがって、日焼け止め化粧料に高配合することが可能となる。
さらにオクチルメトキシシンナメートを配合した場合であっても衣服に対する汚着を低減する。
（２）本発明の日焼け止め化粧料は、広いＵＶ領域にて高い紫外線防御効果を発揮する。
(1) The sunscreen cosmetic of the present invention reduces the adhesion of diethylaminohydroxybenzoyl hexyl benzoate to clothes. Therefore, it can be highly blended in sunscreen cosmetics.
Furthermore, even when octyl methoxycinnamate is blended, the adhesion to clothes is reduced.
(2) The sunscreen cosmetic of the present invention exhibits a high ultraviolet protection effect in a wide UV region.
以下、本発明について詳述する。 Hereinafter, the present invention will be described in detail.
「ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシル」
本発明に用いるジエチルアミノヒドロキシベンゾイル安息香酸ヘキシルは、下記式で示されるＵＶ−Ａ領域の紫外線吸収剤である。本発明においては、市販品（ユビナールＡ plus：ＢＡＳＦ製）を好ましく利用できる。
Diethylaminohydroxybenzoyl hexyl benzoate used in the present invention is an ultraviolet absorber in the UV-A region represented by the following formula. In the present invention, commercially available products (Ubinar A plus: manufactured by BASF) can be preferably used.
ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシル配合量は適宜決定されるが、日焼け止め化粧料全量に対して１〜５質量％であることが好ましい。 Although the amount of diethylaminohydroxybenzoyl hexyl benzoate is appropriately determined, it is preferably 1 to 5% by mass relative to the total amount of the sunscreen cosmetic.
「エステル結合を二つ以上有するエステル油」
本発明に好ましく用いるエステル油は、ジネオペンタン酸トリプロピレングリコール、セバシン酸ジイソプロピル、トリ２−エチルヘキサン酸グリセリル、テトラ２−エチルヘキサン酸、コハク酸ジエチルヘキシルの一種又は二種以上である。特に好ましくは、セバシン酸ジイソプロピル及びジネオペンタン酸トリプロピレングリコールである。
"Ester oil with two or more ester bonds"
The ester oil preferably used in the present invention is one or more of tripropylene glycolineopentanoate, diisopropyl sebacate, glyceryl tri-2-ethylhexanoate, tetra-2-ethylhexanoic acid, and diethylhexyl succinate. Particularly preferred are diisopropyl sebacate and tripropylene glycol dineopentanoate.
エステル結合を２つ以上有するエステル油の配合量は、日焼け止め化粧料全量に対して１．５〜２０質量％であり、好ましくは５〜１５質量％である。 The compounding quantity of the ester oil which has two or more ester bonds is 1.5-20 mass% with respect to the total amount of sunscreen cosmetics, Preferably it is 5-15 mass%.
「（脂肪酸以外により疎水化処理をした）酸化亜鉛及び／又は酸化チタン」
脂肪酸以外の疎水化処理剤により疎水化処理をした酸化亜鉛及び／又は酸化チタンを配合すると、本発明の効果が良好に発揮される。
酸化亜鉛及び／又は酸化チタンの疎水化処理剤の種類としては、脂肪酸、高級脂肪酸、高級アルコール、炭化水素、トリグリセライド、エステル、シリコーンオイル、シリコーン樹脂、フッ素化合物が挙げられる。
本発明において、使用されない疎水化処理剤は脂肪酸であるが、その中でも最も好ましくない脂肪酸は、ステアリン酸、ミリスチン酸である。
一方、脂肪酸以外であって本発明に好ましく用いる疎水化処理剤は、アルキルトリエトキシシラン、アルキルトリメトキシシラン、パーフルオロアルキルリン酸、（アクリル酸アルキル／ジメチルシリコーン）コポリマー、パルミチン酸デキストリン、トリエトキシシリルエチルポリジメチルシロキシエチルヘキシルジメチコン、メチコン、ジメチコン、高分子シリコーン、アクリロイルジメチルタウレートナトリウム／メタクリルアミドラウリル酸コポリマーである。
なお、本発明では疎水化処理をしていない酸化亜鉛及び／又は酸化チタンを配合しても良い。
"Zinc oxide and / or titanium oxide (hydrophobized with other than fatty acids)"
When the zinc oxide and / or titanium oxide hydrophobized with a hydrophobizing agent other than fatty acid is blended, the effect of the present invention is exhibited well.
Examples of the hydrophobizing agent for zinc oxide and / or titanium oxide include fatty acids, higher fatty acids, higher alcohols, hydrocarbons, triglycerides, esters, silicone oils, silicone resins, and fluorine compounds.
In the present invention, the hydrophobizing agent that is not used is a fatty acid, but among these, the most undesirable fatty acids are stearic acid and myristic acid.
On the other hand, the hydrophobizing agents preferably used in the present invention other than fatty acids are alkyltriethoxysilane, alkyltrimethoxysilane, perfluoroalkylphosphoric acid, (alkyl acrylate / dimethylsilicone) copolymer, dextrin palmitate, triethoxy Silylethylpolydimethylsiloxyethylhexyl dimethicone, methicone, dimethicone, polymeric silicone, sodium acryloyldimethyltaurate / methacrylamide lauryl acid copolymer.
In the present invention, zinc oxide and / or titanium oxide that has not been hydrophobized may be blended.
脂肪酸以外で疎水化処理をした（又は如何なる疎水化処理もしていない）酸化亜鉛及び／又は酸化チタンの配合量は、日焼け止め化粧料全量に対して１〜３０質量％である。 The blending amount of zinc oxide and / or titanium oxide that has been hydrophobized other than fatty acids (or not hydrophobized) is 1 to 30% by mass with respect to the total amount of the sunscreen cosmetic.
「オクチルメトキシシンナメート及び／又はオクトクリレン」
上記は周知の紫外線吸収剤であり任意配合成分であるが、本発明の効果を損なうことなく、本発明の日焼け止め化粧料に配合してその紫外線吸収効果を増大することが出来る。
そして、オクチルメトキシシンナメートによる汚着が生じた場合であっても洗浄により汚着を除去できる。
特にＵＶ−Ｂ領域の紫外線吸収効果のためにはオクトクリレンが好ましい。
"Octylmethoxycinnamate and / or octocrylene"
The above are well-known ultraviolet absorbers and optional ingredients, but can be added to the sunscreen cosmetics of the present invention to increase the ultraviolet absorption effect without impairing the effects of the present invention.
Even if the octyl methoxycinnamate is contaminated, it can be removed by washing.
In particular, octocrylene is preferable for the ultraviolet absorption effect in the UV-B region.
オクチルメトキシシンナメートの配合量は、日焼け止め化粧料全量に対して、０〜１５質量％である。
オクトクリレンの配合量は、日焼け止め化粧料全量に対して、０〜１０質量％である。
両者を同時に配合する場合は、その合計量が日焼け止め化粧料全量に対して、０〜１５質量％であることが好ましい。
The amount of octyl methoxycinnamate is 0 to 15% by mass based on the total amount of the sunscreen cosmetic.
The blending amount of octocrylene is 0 to 10% by mass with respect to the total amount of the sunscreen cosmetic.
When mix | blending both simultaneously, it is preferable that the total amount is 0-15 mass% with respect to the sunscreen cosmetics whole quantity.
「日焼け止め化粧料を油中水型乳化組成物に調製すること」
本発明の日焼け止め化粧料は、上記必須成分以外に、通常化粧料に用いられる成分、例えば、美白剤、保湿剤、酸化防止剤、アルコール類、増粘剤、色剤、各種の粉末成分、各種の油性成分、各種の水性成分を必要に応じて適宜配合して、常法により油中水型乳化組成物に調製することができる。
"Preparing sunscreen cosmetics into a water-in-oil emulsion composition"
In addition to the above essential components, the sunscreen cosmetics of the present invention are usually used in cosmetics, such as whitening agents, moisturizers, antioxidants, alcohols, thickeners, colorants, various powder components, Various oily components and various aqueous components can be appropriately blended as necessary, and can be prepared into a water-in-oil emulsion composition by a conventional method.
乳化剤は任意である。乳化剤としては、ＰＯＥ・メチルポリシロキサン共重合体、シリコーン鎖分岐型ＰＯＥ・メチルポリシロキサン共重合体、架橋型ＰＯＥ・メチルポリシロキサン共重合体、アルキル・ＰＯＥ共変性メチルポリシロキサン共重合体、シリコーン鎖分岐型アルキル・ＰＯＥ共変性メチルポリシロキサン共重合体、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ポリオキシエチレングリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステルが挙げられる。
これらの中で本発明に好ましい乳化剤は、アルキル・ＰＯＥ共変性メチルポリシロキサン共重合体である。
The emulsifier is optional. As the emulsifier, POE / methyl polysiloxane copolymer, silicone chain branched POE / methyl polysiloxane copolymer, cross-linked POE / methyl polysiloxane copolymer, alkyl / POE co-modified methyl polysiloxane copolymer, silicone Examples include a chain-branched alkyl / POE co-modified methylpolysiloxane copolymer, glycerin fatty acid ester, polyglycerin fatty acid ester, polyoxyethylene glycerin fatty acid ester, sorbitan fatty acid ester, and polyoxyethylene sorbitan fatty acid ester.
Among these, the preferred emulsifier for the present invention is an alkyl / POE co-modified methyl polysiloxane copolymer.
本発明の効果を損なわない範囲で配合可能な成分の具体例を以下に示す。 Specific examples of components that can be blended within a range not impairing the effects of the present invention are shown below.
デカメチルシクロペンタシロキサン、イソノナン酸イソノニル、ジメチルポリシロキサン、ヘプタメチルオクチルトリシロキサン、トリメチルシロキシケイ酸、流動パラフィン、スクワラン、アボカド油、マカデミアナッツ油、トウモロコシ油、オリーブ油、ナタネ油、月見草油、ヒマシ油、ヒマワリ油、茶実油、コメヌカ油、ホホバ油、カカオ脂、ヤシ油、スクワレン、牛脂、モクロウ、ミツロウ、キャンデリラロウ、カルナバロウ、鯨ロウ、ラノリン、流動パラフィン、ポリオキシエチレン（８モル）オレイルアルコールエーテル、モノオレイン酸グリセリル、シクロメチコン、ジメチルポリシロキサン、ジフェニルポリシロキサンなどの油分。
カプリルアルコール、ラウリルアルコール、ミリスチルアルコール、セチルアルコール、コレステロール、フィトステロールなどの高級アルコール。
カプリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘニン酸、ラノリン脂肪酸、リノール酸、リノレン酸などの高級脂肪酸。
ポリエチレングリコール、グリセリン、ソルビトール、キシリトール、マルチトール、ムコ多糖、ヒアルロン酸、コンドロイチン硫酸、キトサンなどの保湿剤。
メチルセルロース、エチルセルロース、アラビアガム、ポリビニルアルコールなどの増粘剤。
エタノール、１，３−ブチレングリコールなどの水相を構成する液体。
ブチルヒドロキシトルエン、トコフェロール、フィチン酸などの酸化防止剤。
安息香酸、サリチル酸、ソルビン酸、パラオキシ安息香酸エステル（エチルパラベン、ブチルパラベンなど）、ヘキサクロロフェンなどの抗菌防腐剤。
グリシン、アラニン、バリン、ロイシン、セリン、トレオニン、フェニルアラニン、チロシン、アスパラギン酸、アスパラギン、グルタミン、タウリン、アルギニン、ヒスチジンなどのアミノ酸と塩酸塩。
アシルサルコシン酸（例えばラウロイルサルコシンナトリウム）、グルタチオン、クエン酸、リンゴ酸、酒石酸、乳酸などの有機酸。
ビタミンＡ及びその誘導体、ビタミンＢ６塩酸塩、ビタミンＢ６トリパルミテート、ビタミンＢ６ジオクタノエート、ビタミンＢ２及びその誘導体、ビタミンＢ１２、ビタミンＢ１５及びその誘導体などのビタミンＢ類、アスコルビン酸、アスコルビン酸リン酸エステル（塩）、アスコルビン酸ジパルミテートなどのビタミンＣ類、α−トコフェロール、β−トコフェロール、γ−トコフェロール、ビタミンＥアセテート、ビタミンＥニコチネートなどのビタミンＥ類、ビタミンＤ類、ビタミンＨ、パントテン酸、パンテチンなどのビタミン類。
ニコチン酸アミド、ニコチン酸ベンジル、γ−オリザノール、アラントイン、グリチルリチン酸（塩）、グリチルレチン酸及びその誘導体、ヒノキチオール、ムシジン、ビサボロール、ユーカリプトール、チモール、イノシトール、サポニン類（サイコサポニン、ニンジンサポニン、ヘチマサポニン、ムクロジサポニンなど）、パントテニルエチルエーテル、エチニルエストラジオール、トラネキサム酸、セファランチン、プラセンタエキスなどの各種薬剤。
ギシギシ、クララ、コウホネ、オレンジ、セージ、タイム、ノコギリソウ、ゼニアオイ、センキュウ、センブリ、トウキ、トウヒ、バーチ、スギナ、ヘチマ、マロニエ、ユキノシタ、アルニカ、ユリ、ヨモギ、シャクヤク、アロエ、クチナシ、サワラなどの有機溶剤、アルコール、多価アルコール、水、水性アルコールなどで抽出した天然エキス。
ステアリルトリメチルアンモニウムクロライド、塩化ベンザルコニウム、ラウリルアミンオキサイドなどのカチオン界面活性剤。
エデト酸二ナトリウム、エデト酸三ナトリウム、クエン酸ナトリウム、ポリリン酸ナトリウム、メタリン酸ナトリウム、グルコン酸等の金属封鎖剤。
Decamethylcyclopentasiloxane, isononyl isononanoate, dimethylpolysiloxane, heptamethyloctyltrisiloxane, trimethylsiloxysilicic acid, liquid paraffin, squalane, avocado oil, macadamia nut oil, corn oil, olive oil, rapeseed oil, evening primrose oil, castor oil, Sunflower oil, tea seed oil, rice bran oil, jojoba oil, cacao butter, palm oil, squalene, beef tallow, owl, beeswax, candelilla wax, carnauba wax, whale wax, lanolin, liquid paraffin, polyoxyethylene (8 mol) oleyl alcohol Oils such as ether, glyceryl monooleate, cyclomethicone, dimethylpolysiloxane, diphenylpolysiloxane.
Higher alcohols such as capryl alcohol, lauryl alcohol, myristyl alcohol, cetyl alcohol, cholesterol, phytosterol.
Higher fatty acids such as capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, lanolin fatty acid, linoleic acid, linolenic acid.
Moisturizers such as polyethylene glycol, glycerin, sorbitol, xylitol, maltitol, mucopolysaccharide, hyaluronic acid, chondroitin sulfate and chitosan.
Thickeners such as methylcellulose, ethylcellulose, gum arabic, and polyvinyl alcohol.
A liquid constituting an aqueous phase such as ethanol or 1,3-butylene glycol.
Antioxidants such as butylhydroxytoluene, tocopherol and phytic acid.
Antibacterial preservatives such as benzoic acid, salicylic acid, sorbic acid, paraoxybenzoic acid esters (such as ethylparaben and butylparaben), and hexachlorophene.
Amino acids and hydrochlorides such as glycine, alanine, valine, leucine, serine, threonine, phenylalanine, tyrosine, aspartic acid, asparagine, glutamine, taurine, arginine, histidine.
Organic acids such as acyl sarcosine acid (eg, lauroyl sarcosine sodium), glutathione, citric acid, malic acid, tartaric acid, lactic acid.
Vitamin A and its derivatives, vitamin B6 hydrochloride, vitamin B6 tripalmitate, vitamin B6 dioctanoate, vitamin B2 and its derivatives, vitamin B such as vitamin B12, vitamin B15 and its derivatives, ascorbic acid, ascorbic acid phosphate ( Salt), vitamin C such as ascorbic acid dipalmitate, α-tocopherol, β-tocopherol, γ-tocopherol, vitamin E acetate, vitamin E such as vitamin E nicotinate, vitamin D, vitamin H, pantothenic acid, pantethine, etc. Vitamins.
Nicotinamide, benzyl nicotinate, γ-oryzanol, allantoin, glycyrrhizic acid (salt), glycyrrhetinic acid and its derivatives, hinokitiol, mucidin, bisabolol, eucalyptol, thymol, inositol, saponins (psychosaponin, carrot saponin, loofah) Various drugs such as saponin, muclodisaponin, etc.), pantothenyl ethyl ether, ethinyl estradiol, tranexamic acid, cephalanthin, placenta extract.
Bark, Clara, Kouhone, Orange, Sage, Thyme, Yarrow, Zeniahoi, Senkyu, Assembly, Spruce, Spruce, Birch, Horsetail, Loofah, Marronie, Yukishinoshita, Arnica, Lily, Mugwort, Peonies, Aloe, Gardenia, Sawara Natural extract extracted with solvent, alcohol, polyhydric alcohol, water, aqueous alcohol.
Cationic surfactants such as stearyltrimethylammonium chloride, benzalkonium chloride, and laurylamine oxide.
Metal sequestering agents such as disodium edetate, trisodium edetate, sodium citrate, sodium polyphosphate, sodium metaphosphate and gluconic acid.
本発明の日焼け止め化粧料は、軟膏、クリーム、乳液、ローション等の製品形態が挙げられる。 Examples of the sunscreen cosmetics of the present invention include product forms such as ointments, creams, emulsions, lotions and the like.
次に実施例を挙げて本発明をさらに具体的に説明する。本発明はこれによって限定されるものではない。配合量は特に断りのない限り全量に対する質量％である。 Next, the present invention will be described more specifically with reference to examples. The present invention is not limited thereby. A compounding quantity is the mass% with respect to the whole quantity unless there is particular notice.
各表に示す日焼け止め油中水型乳化化粧料（乳液状のサンスクリーン）を常法により製造した。下記の方法により汚着に対する洗浄除去効果を確認した。 Sunscreen oil-in-water emulsified cosmetics (milky sunscreen) shown in each table were produced by a conventional method. The cleaning removal effect against the adhesion was confirmed by the following method.
「汚着（染着性）の測定方法」
図１に示すように、サンプルを腕に厚めに塗布し、ブロード綿の中央に転写にし（転写量約０．０６ｇ）、一日室内に放置した後、通常の衣類用洗剤＊１を使用して洗濯し、分光測色計（ミノルタ（株）：現コニカミノルタセンシング（株）製CM-2002）で、トＥ及びトＹＩを測定した。結果を各表及び各図に示す。
＊１：アタック（花王株式会社）
"Measurement method for staining (dyeability)"
As shown in Fig. 1, apply the sample thickly to the arm, transfer it to the center of broad cotton (transfer amount: about 0.06g), leave it in the room for a day, and then use a normal laundry detergent * 1. The toe and YI were measured with a spectrocolorimeter (Minolta Co., Ltd .: current Konica Minolta Sensing Co., Ltd. CM-2002). The results are shown in each table and each figure.
* 1: Attack (Kao Corporation)
（Ａ）エステル結合を二つ以上有するエステル油の配合量とジエチルアミノヒドロキシベンゾイル安息香酸ヘキシルの配合量を変化させた試験
(A) Test in which the blending amount of ester oil having two or more ester bonds and the blending amount of hexyl diethylaminohydroxybenzoyl benzoate were changed
（Ｂ）酸化亜鉛及び／又は酸化チタンの疎水化処理剤の種類を変化させた試験
(B) Test in which the type of the hydrophobizing agent for zinc oxide and / or titanium oxide was changed
（Ｃ）酸化亜鉛及び／又は酸化チタンの疎水化処理剤の種類を、アルキルトリエトキシシラン処理酸化亜鉛に固定して、エステル結合を二つ以上有するエステル油の種類を変化させた試験
上記結果を図２〜４に示す。本発明の日焼け止め化粧料によれば、ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシルに起因する汚着は低減する。 The above results are shown in FIGS. According to the sunscreen cosmetic of the present invention, the contamination due to hexyl diethylaminohydroxybenzoyl benzoate is reduced.
以下に本願発明の日焼け止め化粧料の処方例を挙げる。いずれも汚着防止効果があり、優れた紫外線防御効果吸を発揮する日焼け止め化粧料である。 The prescription example of the sunscreen cosmetics of this invention is given to the following. All of these are sunscreen cosmetics that have an anti-fouling effect and exhibit an excellent UV protection effect.
実施例１８：Ｗ／Ｏ型日焼け止め化粧料（サンスクリーン）
デカメチルシクロペンタンシロキサン １８ 質量％
ジメチルポリシロキサン ２
ラウリルＰＥＧ−９ポリジメチルシロキシエチルジメチコン １．５
トリメチルシロキシケイ酸 ５
ポリオキシエチレン・メチルポリシロキサン共重合体 ０．５
セバシン酸ジイソプロピル １５
パラメトキシ桂皮酸２−エチルヘキシル ７．５
ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシル ２
ジメチルジステアリルアンモニウムヘクトライト ０．２
パルミチン酸デキストリン処理酸化亜鉛 １５
精製水 残余
エデト酸三ナトリウム ０．０５
ジプロピレングリコール ５
パラベン ０．２５
グリセリン ２
エタノール ２
フェノキシエタノール ０．３
Example 18: W / O type sunscreen cosmetic (sunscreen)
Decamethylcyclopentanesiloxane 18% by mass
Lauryl PEG-9 polydimethylsiloxyethyl dimethicone 1.5
Polyoxyethylene / methylpolysiloxane copolymer 0.5
Diisopropyl sebacate 15
2-Ethylhexyl paramethoxycinnamate 7.5
Dimethyl distearyl ammonium hectorite 0.2
Zinc oxide treated with dextrin palmitate 15
Purified water Residual trisodium edetate 0.05
Paraben 0.25
Phenoxyethanol 0.3
実施例１９：Ｗ／Ｏ型日焼け止め化粧料（サンスクリーン）
デカメチルシクロペンタンシロキサン １８ 質量％
ジメチルポリシロキサン ２
ラウリルＰＥＧ−９ポリジメチルシロキシエチルジメチコン １．５
トリメチルシロキシケイ酸 ５
ポリオキシエチレン・メチルポリシロキサン共重合体 ０．５
ジネオペンタン酸トリプロピレングリコール １５
パラメトキシ桂皮酸２−エチルヘキシル ７．５
ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシル ２
ジメチルジステアリルアンモニウムヘクトライト ０．２
アルキルトリエトキシシラン処理酸化亜鉛 １５
精製水 残余
エデト酸三ナトリウム ０．０５
ジプロピレングリコール ５
パラベン ０．２５
グリセリン ２
エタノール ２
フェノキシエタノール ０．３
Example 19: W / O type sunscreen cosmetic (sunscreen)
Decamethylcyclopentanesiloxane 18% by mass
Lauryl PEG-9 polydimethylsiloxyethyl dimethicone 1.5
Polyoxyethylene / methylpolysiloxane copolymer 0.5
Dineopentanoic acid tripropylene glycol 15
2-Ethylhexyl paramethoxycinnamate 7.5
Dimethyl distearyl ammonium hectorite 0.2
Alkyltriethoxysilane-treated zinc oxide 15
Purified water Residual trisodium edetate 0.05
Paraben 0.25
Phenoxyethanol 0.3
実施例２０：Ｗ／Ｏ型日焼け止め化粧料（サンスクリーン）
デカメチルシクロペンタンシロキサン １８ 質量％
ジメチルポリシロキサン ２
ラウリルＰＥＧ−９ポリジメチルシロキシエチルジメチコン １．５
トリメチルシロキシケイ酸 ５
ポリオキシエチレン・メチルポリシロキサン共重合体 ０．５
トリ２−エチルヘキサン酸グリセリル １．５
オクトクリレン ７．５
ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシル ０．５
ジメチルジステアリルアンモニウムヘクトライト ０．２
フッ素処理酸化亜鉛 １５
精製水 残余
エデト酸三ナトリウム ０．５
ジプロピレングリコール ５
パラベン ０．２５
グリセリン ２
エタノール ２
フェノキシエタノール ０．３
Example 20: W / O type sunscreen cosmetic (sunscreen)
Decamethylcyclopentanesiloxane 18% by mass
Lauryl PEG-9 polydimethylsiloxyethyl dimethicone 1.5
Polyoxyethylene / methylpolysiloxane copolymer 0.5
Glyceryl tri-2-ethylhexanoate 1.5
Octocrylene 7.5
Diethylaminohydroxybenzoyl hexyl benzoate 0.5
Dimethyl distearyl ammonium hectorite 0.2
Fluorine-treated zinc oxide 15
Purified water Residual trisodium edetate 0.5
Paraben 0.25
Phenoxyethanol 0.3
実施例２１：Ｗ／Ｏ型日焼け止め化粧料（サンスクリーン）
デカメチルシクロペンタンシロキサン １８ 質量％
ジメチルポリシロキサン ２
セチルジメチコンコポリオール １．５
トリメチルシロキシケイ酸 ５
ポリオキシエチレン・メチルポリシロキサン共重合体 ０．５
テトラ２−エチルヘキサン酸ペンタエリスリチル １０
ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシル ５
ジメチルジステアリルアンモニウムヘクトライト ０．２
炭酸ジカプリリル １０
高分子シリコーン処理酸化亜鉛 １５
精製水 残余
エデト酸三ナトリウム ０．０５
ジプロピレングリコール ５
パラベン ０．２５
グリセリン ２
エタノール ２
フェノキシエタノール ０．３
Example 21: W / O type sunscreen cosmetic (sunscreen)
Decamethylcyclopentanesiloxane 18% by mass
Cetyl dimethicone copolyol 1.5
Polyoxyethylene / methylpolysiloxane copolymer 0.5
Tetra-2-ethylhexanoic acid pentaerythrityl 10
Dimethyl distearyl ammonium hectorite 0.2
Dicaprylyl carbonate 10
High molecular silicone-treated zinc oxide 15
Purified water Residual trisodium edetate 0.05
Paraben 0.25
Phenoxyethanol 0.3
実施例２２：Ｗ／Ｏ型日焼け止め化粧料（サンスクリーン）
デカメチルシクロペンタンシロキサン ５ 質量％
ラウリルＰＥＧ−９ポリジメチルシロキシエチルジメチコン １．５
オクトクリレン １０
テトラ２−エチルヘキサン酸ペンタエリスリチル ５
ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシル ５
ジメチルジステアリルアンモニウムヘクトライト ０．６
セバシン酸ジイソプロピル １０
アルキルトリエトキシシラン処理酸化チタン １５
精製水 残余
エデト酸三ナトリウム ０．１
ジプロピレングリコール ５
パラベン ０．３
グリセリン １０
エタノール ３
フェノキシエタノール ０．３５
ペルミチン酸イソプロピル １５
Example 22: W / O type sunscreen cosmetic (sunscreen)
Lauryl PEG-9 polydimethylsiloxyethyl dimethicone 1.5
Octocrylene 10
Tetra-2-
Dimethyl distearyl ammonium hectorite 0.6
Diisopropyl sebacate 10
Alkyltriethoxysilane-treated titanium oxide 15
Purified water Residual trisodium edetate 0.1
Paraben 0.3
Glycerin 10
Phenoxyethanol 0.35
Isopropyl permitate 15
本発明によれば、ジエチルアミノヒドロキシベンゾイル安息香酸ヘキシルを含有する日焼け止め化粧料において、衣服の汚着（染着性）を改善した日焼け止め化粧料を提供することが可能となる。 According to the present invention, in a sunscreen cosmetic containing diethylaminohydroxybenzoyl hexyl benzoate, it is possible to provide a sunscreen cosmetic with improved clothing adhesion (dyeability).
Claims (4)
（１）エステル結合を二つ以上有するエステル油と、
（２）脂肪酸以外で疎水化処理をした酸化亜鉛及び／又は酸化チタンと
を配合し、
（３）さらに油中水型乳化組成物に調製すること
を特徴とする日焼け止め化粧料。 In a sunscreen cosmetic containing diethylaminohydroxybenzoyl hexyl benzoate,
(1) an ester oil having two or more ester bonds;
(2) Blending with zinc oxide and / or titanium oxide hydrophobized with other than fatty acids,
(3) A sunscreen cosmetic characterized in that it is further prepared into a water-in-oil emulsion composition.
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| JP2008091898A JP4827877B2 (en) | 2008-03-31 | 2008-03-31 | Sunscreen cosmetics |
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| JP2008091898A JP4827877B2 (en) | 2008-03-31 | 2008-03-31 | Sunscreen cosmetics |
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| JP4827877B2 JP4827877B2 (en) | 2011-11-30 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011117976A1 (en) * | 2010-03-24 | 2011-09-29 | 株式会社 資生堂 | Sunscreen cosmetic |
| JP2013028558A (en) * | 2011-07-28 | 2013-02-07 | Pola Chemical Industries Inc | Emulsion type cosmetic |
| JP2015091894A (en) * | 2009-11-06 | 2015-05-14 | 花王株式会社 | Emulsified cosmetics |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102015219009A1 (en) * | 2015-10-01 | 2017-04-06 | Beiersdorf Ag | Sunscreen with reduced textile staining by Diethylamino Hydroxybenzoyl Hexyl Benzoate |
| DE102017201235A1 (en) | 2017-01-26 | 2018-07-26 | Beiersdorf Ag | Use of dimethylaminohydroxybenzoylhexylbenzoate in cosmetic sunscreens |
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| JP2013028558A (en) * | 2011-07-28 | 2013-02-07 | Pola Chemical Industries Inc | Emulsion type cosmetic |
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