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JP2009114440A - Resin composition for pavement, asphalt composition for pavement, and method for producing the same - Google Patents

Resin composition for pavement, asphalt composition for pavement, and method for producing the same Download PDF

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JP2009114440A
JP2009114440A JP2008269033A JP2008269033A JP2009114440A JP 2009114440 A JP2009114440 A JP 2009114440A JP 2008269033 A JP2008269033 A JP 2008269033A JP 2008269033 A JP2008269033 A JP 2008269033A JP 2009114440 A JP2009114440 A JP 2009114440A
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resin composition
paving
weight
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vinyl acetate
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JP5499456B2 (en
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Toshiyuki Hakata
俊之 博多
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Toda Kogyo Corp
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/04Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D131/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
    • C09D131/02Homopolymers or copolymers of esters of monocarboxylic acids
    • C09D131/04Homopolymers or copolymers of vinyl acetate
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/26Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0846Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
    • C08L23/0853Ethene vinyl acetate copolymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D153/00Coating compositions based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D153/00Coating compositions based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D153/02Vinyl aromatic monomers and conjugated dienes
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C7/00Coherent pavings made in situ
    • E01C7/08Coherent pavings made in situ made of road-metal and binders
    • E01C7/30Coherent pavings made in situ made of road-metal and binders of road-metal and other binders, e.g. synthetic material, i.e. resin
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0075Uses not provided for elsewhere in C04B2111/00 for road construction
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/24Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L57/00Compositions of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C08L57/02Copolymers of mineral oil hydrocarbons

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Road Paving Structures (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a resin composition for pavement, which is melted in a short time, has excellent wettability and adhesion to aggregates and allows a load surface to have excellent durability and be free from problems such as deformation during summer season and cracks during winter season. <P>SOLUTION: The resin composition for pavement comprises, at the least, an ethylene-vinyl acetate copolymer having 25-45 wt.% vinyl acetate content, 40-100°C melting temperature and ≥400 g/10 minutes melt flow rate, petroleum process oil having 20-40% carbon content (CA) derived from an aromatic ring, and a teleblock polymer. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は、耐久性に優れ、特に低温での舗装強度に優れ、且つ、夏場の変形抵抗性にも優れた舗装用樹脂組成物に関するものである。   The present invention relates to a resin composition for paving which is excellent in durability, particularly excellent in pavement strength at a low temperature, and excellent in deformation resistance in summer.

近年、歩道や広場、橋面などの舗装面を美観上から様々な色に着色する場合や、横断歩道やトンネル等のように交通安全対策上から着色する場合、あるいは、道路の分岐点やバスストップ等のように道路の機能を高める目的から着色する場合等、様々なケースでいわゆる着色舗装が成されている。   In recent years, when pavement surfaces such as sidewalks, squares, and bridges are colored in various colors from an aesthetic point of view, or when colored from traffic safety measures such as pedestrian crossings and tunnels, or at road junctions and buses So-called colored pavement is formed in various cases, such as when coloring for the purpose of enhancing the function of the road such as a stop.

一般的に、着色舗装には、有色骨材を用いるものと、結合材に顔料を使用するものとがある。   In general, colored pavements include those using colored aggregates and those using pigments as binders.

前者においては、シリカサンドや石灰岩のような天然物や明色骨材と言われる人工のものがある。これらはいずれも白色であり、高価なものが多い。   In the former, there are natural products such as silica sand and limestone, and artificial materials called light-colored aggregates. These are all white and are often expensive.

一方、後者においては、加熱アスファルト混合物に顔料を混合する方法があるが、そもそも加熱アスファルト自体が暗褐色を呈しているので、顔料を添加してもその顔料が持つ本来の色彩あるいは明るさを呈することは難しい。   On the other hand, in the latter, there is a method of mixing a pigment with a heated asphalt mixture, but since the heated asphalt itself has a dark brown color, the original color or brightness of the pigment is exhibited even if the pigment is added. It ’s difficult.

このような問題を解決する目的で、従来のアスファルトバインダーに石油系樹脂やエポキシ樹脂のような合成樹脂を添加してバインダー組成物の色を薄くすることで顔料等による着色を可能とすることができるが、十分とは言えない。   For the purpose of solving such problems, it is possible to add a synthetic resin such as a petroleum resin or an epoxy resin to a conventional asphalt binder to reduce the color of the binder composition, thereby enabling coloring with a pigment or the like. Yes, but not enough.

また、石油系樹脂やスチレン系合成ポリマー、あるいはエチレン系コポリマーのような熱可塑性エラストマーと石油系重質油とを混合したいわゆる合成バインダーは、顔料等との混合によりきれいなカラー舗装用の混合物を得る事が可能となる。   In addition, so-called synthetic binders, which are a mixture of a thermoplastic elastomer such as petroleum resin, styrene synthetic polymer, or ethylene copolymer, and petroleum heavy oil, obtain a clean color paving mixture by mixing with pigments. Things will be possible.

例えば、特許文献1(特開2000−230122号公報)には、天然アスファルトや石油アスファルトにSBSのような熱可塑性エラストマーや、相溶化剤として石油系オイルと相分離抑制剤として油性界面活性剤を混合した改質アスファルトに関して報告されている。ただ、耐久性、特に低温での強度向上は不十分であり、さらに、界面活性剤の使用に基づき発泡の問題や、舗装面における経時的なマイグレーションが生じたりして、必ずしも耐久性に優れた舗装を提供できるものではない。さらに、バインダー自体の透明性が不十分であり、顔料と混合した場合にクリヤーな発色は得られない。   For example, Patent Document 1 (Japanese Patent Application Laid-Open No. 2000-230122) discloses natural asphalt and petroleum asphalt with a thermoplastic elastomer such as SBS, a petroleum oil as a compatibilizer and an oily surfactant as a phase separation inhibitor. Reported on mixed modified asphalt. However, durability, especially strength improvement at low temperature, is insufficient, and furthermore, due to the use of surfactants, foaming problems and migration over time on the pavement surface occur, and it is always excellent in durability. It cannot provide pavement. Further, the transparency of the binder itself is insufficient, and a clear color cannot be obtained when mixed with a pigment.

また、特許文献2(特開平4−359063号公報)には、芳香族系プロセスオイルにジシクロペンタジエン系石油樹脂、およびSBSやSISのようなテレブロックポリマーおよび酢酸ビニルの含有量が4〜20%のエチレン酢酸ビニル共重合体を混合した、着色舗装用結合材組成物に関して報告されている。ただし、このバインダーにおいても、アスファルト混合物の変形抵抗性は向上するが、耐久性、特に低温での強度向上は不十分である。   Patent Document 2 (Japanese Patent Laid-Open No. 4-359063) discloses that aromatic process oil contains dicyclopentadiene petroleum resin, teleblock polymer such as SBS and SIS, and vinyl acetate in a content of 4 to 20%. % Colored pavement binder composition mixed with ethylene vinyl acetate copolymer. However, even with this binder, the deformation resistance of the asphalt mixture is improved, but the durability, particularly the strength at low temperatures, is insufficient.

また、特許文献3(特開平5−302072号公報)には、芳香族系重質鉱油と石油樹脂とSBS、SISのような熱可塑性エラストマーと、メルトフローレートが15〜400g/10minのエチレン酢酸ビニル共重合体と、ワックス性物質からなるバインダー組成物に関して報告がなされている。また、60℃粘度が高く、かつ高温粘度が高く、変形抵抗性に優れたアスファルト混合物を提供でき、また圧縮強度も向上すると報告されているが、逆に低温での強度に関しては十分なものとは言えない。   Patent Document 3 (Japanese Patent Laid-Open No. 5-302072) discloses aromatic heavy mineral oil, petroleum resin, thermoplastic elastomer such as SBS and SIS, and ethylene acetic acid having a melt flow rate of 15 to 400 g / 10 min. There have been reports on a binder composition comprising a vinyl copolymer and a waxy substance. In addition, it has been reported that an asphalt mixture having a high viscosity at 60 ° C., a high temperature viscosity, and excellent deformation resistance can be provided, and the compressive strength is improved, but conversely, the strength at low temperature is sufficient. I can't say that.

特開2000−230122号公報JP 2000-230122 A 特開平4−359063号公報Japanese Patent Laid-Open No. 4-359063 特開平5−302072号公報JP-A-5-302072

長期貯蔵において相分離を起こさず、変形抵抗性にも優れ、さらに低温での舗装強度を向上させることができる舗装用樹脂組成物を提供することを目的とする。   It is an object of the present invention to provide a resin composition for paving that does not cause phase separation during long-term storage, has excellent deformation resistance, and can improve the paving strength at low temperatures.

前記技術的課題は、次の通りの本発明によって達成できる。   The technical problem can be achieved by the present invention as follows.

即ち、本発明は、酢酸ビニルの含有量が25〜45重量%であって溶融温度が40〜100℃であってメルトフローレートが400g/10min以上であるエチレン酢酸ビニル共重合体と、芳香族環由来の炭素の含有量(CA)が20〜40重量%である石油系プロセスオイルと、テレブロックポリマーとを少なくとも含むことを特徴とする舗装用樹脂組成物である(本発明1)。   That is, the present invention relates to an ethylene vinyl acetate copolymer having a vinyl acetate content of 25 to 45% by weight, a melting temperature of 40 to 100 ° C., and a melt flow rate of 400 g / 10 min or more, and an aromatic A paving resin composition comprising at least a petroleum-based process oil having a ring-derived carbon content (CA) of 20 to 40% by weight and a teleblock polymer (Invention 1).

また、本発明は、エチレン酢酸ビニル共重合体の含有量が2〜30重量%、石油系プロセスオイルの含有量が20〜80重量%、テレブロックポリマーの含有量が2〜20重量%である本発明1記載の舗装用樹脂組成物である(本発明2)。   In the present invention, the ethylene vinyl acetate copolymer content is 2 to 30% by weight, the petroleum process oil content is 20 to 80% by weight, and the teleblock polymer content is 2 to 20% by weight. It is the resin composition for pavement of this invention 1 (this invention 2).

また、本発明は、テレブロックポリマーが、スチレン−ブタジエン−スチレン(SBS)及び/又はスチレン−イソブチレン−スチレン(SIS)である本発明1の舗装用樹脂組成物である(本発明3)。   Moreover, this invention is the resin composition for pavements of this invention 1 whose teleblock polymer is styrene-butadiene-styrene (SBS) and / or styrene-isobutylene-styrene (SIS) (this invention 3).

また、本発明は、軟化点が80〜110℃であって酸価が0.5mgKOH/g以下である芳香族系石油樹脂を20重量%未満添加した本発明1の舗装用樹脂組成物である(本発明4)。   Further, the present invention is the resin composition for paving of the present invention 1, wherein an aromatic petroleum resin having a softening point of 80 to 110 ° C. and an acid value of 0.5 mg KOH / g or less is added in an amount of less than 20% by weight. (Invention 4).

また、本発明は、酸価が1.0〜70mgKOH/gであるポリオレフィン系ワックスを0〜10重量%添加した本発明1の舗装用樹脂組成物である(本発明5)。   Moreover, this invention is the resin composition for pavements of this invention 1 which added 0-10 weight% of polyolefin-type wax whose acid value is 1.0-70 mgKOH / g (this invention 5).

また、本発明は、ポリオレフィン系ワックスが、酸化ポリエチレンであることを特徴とする本発明4の舗装用樹脂組成物である(本発明6)。   In addition, the present invention is the resin composition for paving according to the fourth invention, wherein the polyolefin wax is polyethylene oxide (the sixth invention).

また、本発明は、形状がペレット状である本発明1〜6のいずれかに記載の舗装用樹脂組成物である(本発明7)。   Moreover, this invention is the resin composition for pavements in any one of this invention 1-6 whose shape is a pellet form (this invention 7).

また、本発明は、本発明1乃至7のいずれかに記載の舗装用樹脂組成物3〜10重量%と骨材97〜90重量%とからなることを特徴とする舗装用アスファルト組成物である(本発明8)。   The present invention also provides a paving asphalt composition comprising 3 to 10% by weight of the paving resin composition according to any one of the present inventions 1 to 7 and 97 to 90% by weight of aggregate. (Invention 8).

また、本発明は、舗装用樹脂組成物と骨材とを150〜200℃で混合してなることを特徴とする本発明8記載の舗装用アスファルト組成物である(本発明9)。   Moreover, this invention is the asphalt composition for pavements of this invention 8 characterized by mixing the resin composition for pavements and an aggregate at 150-200 degreeC (this invention 9).

また、本発明は、本発明7のペレット状の舗装用樹脂組成物と骨材とを計量機を通さずに直接ミキサーに投入し、150〜200℃で混合することを特徴とする舗装用アスファルト組成物の製造方法(本発明10)。   Further, the present invention is a paving asphalt characterized in that the pelletized paving resin composition of the present invention 7 and aggregate are directly fed into a mixer without passing through a measuring machine and mixed at 150 to 200 ° C. A method for producing the composition (Invention 10).

また、本発明は、骨材を予め160〜220℃に加熱することを特徴とする本発明10の舗装用アスファルト組成物の製造方法である(本発明11)。   Moreover, this invention is a manufacturing method of the asphalt composition for pavements of this invention 10 which heats an aggregate to 160-220 degreeC previously (this invention 11).

本発明に係る舗装用樹脂組成物は、短時間で溶融し、かつ骨材への濡れ性及び接着性に優れ、夏期の路面の変形や冬期のひび割れが抑制され、殊に、特に低温での舗装強度に優れるという耐久性に優れた路面を与えることができる。   The resin composition for paving according to the present invention melts in a short time and is excellent in wettability and adhesiveness to aggregates, is suppressed in the summer road surface deformation and winter cracks, especially at low temperatures. It is possible to provide a road surface with excellent durability such as excellent pavement strength.

さらに、ペレット状の樹脂組成物は、保存中あるいは運搬中にお互いに付着したりミキサーに付着したりせず、短時間で溶融するようにチップ状の形状を持っており、また、顔料と当該樹脂組成物の混合物においては、顔料を投入時の粉塵等の問題のない作業性の良い舗装用材料を提供することができる。   Furthermore, the pellet-shaped resin composition does not adhere to each other or adhere to the mixer during storage or transportation, and has a chip-like shape so as to melt in a short time. In the mixture of resin compositions, it is possible to provide a pavement material having good workability without problems such as dust at the time of adding a pigment.

本発明の構成をより詳しく説明すれば、次の通りである。   The configuration of the present invention will be described in more detail as follows.

本発明に係る舗装用樹脂組成物は、少なくとも、エチレン酢酸ビニル共重合体、石油系プロセスオイル及びテレブロックポリマーからなる。   The resin composition for paving according to the present invention comprises at least an ethylene vinyl acetate copolymer, a petroleum process oil, and a teleblock polymer.

本発明におけるエチレン酢酸ビニル共重合体は、酢酸ビニルの含有量が25重量%以上45重量%以下である。酢酸ビニルの含有量が25重量%未満の場合には、得られた樹脂組成物の柔軟性が不十分となり、舗装後の路面のひび割れの原因となる。特に、冬場において顕著となる。一方、酢酸ビニルの含有量が45重量%を越える場合には、舗装用樹脂組成物のバインダーとしての軟化点が低下し、変形抵抗性が低下し、夏場の轍の原因となる。好ましくは酢酸ビニルの含有量が27重量%〜45重量%であり、より好ましくは30重量%〜42重量%である   The ethylene vinyl acetate copolymer in the present invention has a vinyl acetate content of 25 wt% or more and 45 wt% or less. When the content of vinyl acetate is less than 25% by weight, the obtained resin composition has insufficient flexibility, which causes cracks on the road surface after paving. This is particularly noticeable in winter. On the other hand, when the content of vinyl acetate exceeds 45% by weight, the softening point as a binder of the resin composition for pavement is lowered, the deformation resistance is lowered, and it causes summer drought. Preferably, the vinyl acetate content is 27% to 45% by weight, more preferably 30% to 42% by weight.

本発明におけるエチレン酢酸ビニル共重合体の溶融温度は40℃以上100℃以下である。エチレン酢酸ビニル共重合体の溶融温度が40℃未満の場合には、舗装用樹脂組成物のバインダーとしての軟化点が低下し、変形抵抗性が低下し、夏場の轍の原因となる。一方、溶融温度が100℃を越える場合には、溶融させて骨材と混合する温度及び時間が長く必要であり、作業性に問題を生じる。エチレン酢酸ビニル共重合体の溶融温度は好ましくは50℃以上90℃以下である。   The melting temperature of the ethylene vinyl acetate copolymer in the present invention is 40 ° C. or higher and 100 ° C. or lower. When the melting temperature of the ethylene-vinyl acetate copolymer is lower than 40 ° C., the softening point as a binder of the resin composition for paving is lowered, the deformation resistance is lowered, and it causes summer drought. On the other hand, when the melting temperature exceeds 100 ° C., it takes a long time and time for melting and mixing with the aggregate, causing a problem in workability. The melting temperature of the ethylene vinyl acetate copolymer is preferably 50 ° C. or higher and 90 ° C. or lower.

本発明におけるエチレン酢酸ビニル共重合体のメルトフローレート(190℃、荷重21.18N、JIS K6924−1に基づく表記)は400g/10min以上である。エチレン酢酸ビニル共重合体のメルトフローレートが400g/10min未満の場合には、溶融させて骨材と混合する温度及び時間が長く必要であり、作業性に問題を生じる。さらに、テレブロックボリマー、石油系プロセスオイルとの相溶性に問題を生じ、長期貯蔵時の相分離の現象を起こす原因となる。一方、エチレン酢酸ビニル共重合体のメルトフローレートが3000g/10minを越える場合には、舗装後の路面のひび割れの原因となることがある。エチレン酢酸ビニル共重合体のメルトフローレートは好ましくは420〜2000g/10minである。   The melt flow rate (190 ° C., load 21.18 N, notation based on JIS K6924-1) of the ethylene vinyl acetate copolymer in the present invention is 400 g / 10 min or more. When the melt flow rate of the ethylene vinyl acetate copolymer is less than 400 g / 10 min, it takes a long temperature and time for melting and mixing with the aggregate, which causes a problem in workability. In addition, there is a problem in compatibility with teleblock polymer and petroleum-based process oil, which causes phase separation during long-term storage. On the other hand, when the melt flow rate of the ethylene vinyl acetate copolymer exceeds 3000 g / 10 min, it may cause cracks on the road surface after paving. The melt flow rate of the ethylene vinyl acetate copolymer is preferably 420 to 2000 g / 10 min.

本発明におけるエチレン酢酸ビニル共重合体の舗装用樹脂組成物(全バインダー組成)中における比率は2重量%〜30重量%が好ましい。エチレン酢酸ビニル共重合体の比率が2重量%未満の場合には、望ましい強度が得られない。一方、エチレン酢酸ビニル共重合体の比率が30重量%を越える場合には、変形抵抗性が低下する。エチレン−酢酸ビニル共重合体の比率は、より好ましくは5〜30重量%であり、より好ましくは10〜28重量%である。   The ratio of the ethylene vinyl acetate copolymer in the present invention in the resin composition for paving (total binder composition) is preferably 2% by weight to 30% by weight. When the ratio of the ethylene vinyl acetate copolymer is less than 2% by weight, the desired strength cannot be obtained. On the other hand, when the ratio of the ethylene vinyl acetate copolymer exceeds 30% by weight, the deformation resistance decreases. The ratio of the ethylene-vinyl acetate copolymer is more preferably 5 to 30% by weight, and more preferably 10 to 28% by weight.

石油系プロセスオイルとしては、引火点が260℃以上のものが好ましい。石油系プロセスオイルとしては潤滑油、重質鉱油等を用いることができる。   The petroleum process oil preferably has a flash point of 260 ° C. or higher. As the petroleum process oil, lubricating oil, heavy mineral oil, or the like can be used.

本発明においては、芳香族環由来の炭素の含有量(全炭素中の芳香族環由来の炭素含有量:CA)が20重量%以上40%重量以下の石油系プロセスオイルを用いる。芳香族環由来の炭素の含有量が20重量%未満では、テレブロックコポリマーとの相溶性が不十分であり、一方、芳香族環由来の炭素の含有量が40重量%を越えるとエチレン−酢酸ビニル共重合体との相溶性が不十分となる。石油系プロセスオイルにおける芳香族環由来の炭素の含有量(CA)は、23〜40重量%が好ましく、より好ましくは25〜38重量%が好ましい。   In the present invention, petroleum-based process oil having an aromatic ring-derived carbon content (aromatic ring-derived carbon content in all carbons: CA) of 20 wt% to 40 wt% is used. If the content of carbon derived from the aromatic ring is less than 20% by weight, the compatibility with the teleblock copolymer is insufficient. On the other hand, if the content of carbon derived from the aromatic ring exceeds 40% by weight, ethylene-acetic acid is used. The compatibility with the vinyl copolymer becomes insufficient. The content (CA) of carbon derived from the aromatic ring in the petroleum-based process oil is preferably 23 to 40% by weight, more preferably 25 to 38% by weight.

石油系プロセスオイルの舗装用樹脂組成物(全バインダー組成)中における比率は、20重量%〜80重量%が好ましい。石油系プロセスオイルの比率が20重量%未満では、舗装用樹脂組成物のバインダーとしての粘度が高くなりすぎて、作業性に問題を生じる。一方、80重量%を越える場合には、強度面で問題を生じる。石油系プロセスオイルの比率はより好ましくは30〜70重量%である。   The ratio of the petroleum-based process oil in the paving resin composition (total binder composition) is preferably 20% by weight to 80% by weight. When the ratio of the petroleum-based process oil is less than 20% by weight, the viscosity of the resin composition for paving becomes too high as a binder, causing a problem in workability. On the other hand, if it exceeds 80% by weight, there is a problem in strength. The ratio of petroleum-based process oil is more preferably 30 to 70% by weight.

本発明におけるテレブロックポリマーとしては、スチレン−ブタジエン−スチレン(SBS)、スチレン−イソブチレン−スチレン(SIS)、スチレン−エチレン−ブタジエン−スチレン(SEBS)のようなブロックコポリマーが好ましい。スチレンの比率が15〜30重量%で、平均分子量は10,000〜300,000が好ましい。   As the teleblock polymer in the present invention, block copolymers such as styrene-butadiene-styrene (SBS), styrene-isobutylene-styrene (SIS), and styrene-ethylene-butadiene-styrene (SEBS) are preferable. The ratio of styrene is preferably 15 to 30% by weight, and the average molecular weight is preferably 10,000 to 300,000.

テレブロックポリマーの舗装用樹脂組成物(全バインダー組成)中における比率は、2.0重量%〜20重量%が好ましい。2重量%未満では、変形抵抗性が低下し、一方、20重量%を越える場合には、舗装用樹脂組成物のバインダーとしての粘度が高くなりすぎて、作業性に問題を生じる。さらに、軟化点が高くなりすぎることと、低温での強度が低下する。テレブロックポリマーの舗装用樹脂組成物(全バインダー組成)中における比率はより好ましくは2.0〜18重量%であり、更により好ましくは2.0〜15重量%である。   The ratio of the teleblock polymer in the resin composition for paving (total binder composition) is preferably 2.0% by weight to 20% by weight. If it is less than 2% by weight, the deformation resistance is lowered. On the other hand, if it exceeds 20% by weight, the viscosity of the resin composition for paving becomes too high as a binder, causing a problem in workability. Furthermore, the softening point becomes too high, and the strength at low temperatures decreases. The ratio of the teleblock polymer in the resin composition for paving (total binder composition) is more preferably 2.0 to 18% by weight, still more preferably 2.0 to 15% by weight.

本発明における芳香族系石油樹脂としては、軟化点が80℃〜110℃が好ましい。80℃未満の場合には、軟化点が低くなり変形抵抗性が低下する。一方、110℃を越える場合には、溶融させて骨材と混合する温度及び時間が長く必要であり、作業性に問題を生じる。芳香族系石油樹脂の軟化点は、更に好ましくは、80〜100℃である。   The aromatic petroleum resin in the present invention preferably has a softening point of 80 ° C to 110 ° C. When it is less than 80 ° C., the softening point is lowered and the deformation resistance is lowered. On the other hand, when the temperature exceeds 110 ° C., the temperature and time for melting and mixing with the aggregate are required to be long, causing a problem in workability. The softening point of the aromatic petroleum resin is more preferably 80 to 100 ° C.

本発明における芳香族系石油樹脂としては、160℃での溶融粘度が100〜1000cpsの範囲にあることが好ましく、更に好ましくは、100〜800cpsである。100cps未満の場合には、舗装した路面の耐久性に問題を生じる。一方、1000cpsを越える場合には、骨材への濡れ性及び接着性が悪く、舗装した路面の耐久性に問題を生じる。   The aromatic petroleum resin in the present invention preferably has a melt viscosity at 160 ° C. in the range of 100 to 1000 cps, more preferably 100 to 800 cps. If it is less than 100 cps, there is a problem with the durability of the paved road surface. On the other hand, if it exceeds 1000 cps, the wettability and adhesiveness to the aggregate are poor, causing a problem in the durability of the paved road surface.

本発明における芳香族系石油樹脂としては、C9留分を原料とした芳香族系石油樹脂で、軟化点が80℃〜110℃、酸価が0.5mgKOH/g以下のものが好ましい。また、フェノールやカテコール等で変性されたもの等を用いることができる。   The aromatic petroleum resin in the present invention is preferably an aromatic petroleum resin using a C9 fraction as a raw material, having a softening point of 80 ° C. to 110 ° C. and an acid value of 0.5 mgKOH / g or less. In addition, those modified with phenol or catechol can be used.

本発明における芳香族系石油樹脂の舗装用樹脂組成物(全バインダー組成)中における比率は20重量%未満が好ましい。20重量%以上の場合には、低温での強度が低下する。   The ratio of the aromatic petroleum resin in the resin composition for paving (total binder composition) in the present invention is preferably less than 20% by weight. In the case of 20% by weight or more, the strength at low temperature decreases.

ポリオレフィン系ワックスとしては、酸価が1.0〜70mgKOH/gである酸化ポリエチレン系ワックスが好ましい。   As the polyolefin wax, an oxidized polyethylene wax having an acid value of 1.0 to 70 mgKOH / g is preferable.

ポリオレフィン系ワックスの舗装用樹脂組成物(全バインダー組成)中における比率は、0重量%〜10重量%が好ましい。10重量%を越える場合には、低温での強度が低下する。   The ratio of the polyolefin wax in the resin composition for paving (total binder composition) is preferably 0% by weight to 10% by weight. When it exceeds 10% by weight, the strength at low temperature is lowered.

本発明におけるポリオレフィン系ワックスとしては、酸化ポリエチレン、ポリプロピレンワックス、ポリエチレンワックス、変性ポリオレフィンワックス等を用いることができ、これらは単独で、または必要に応じて、2種以上組み合わせて用いられるが、舗装後の路面のひび割れ等が起こり難く耐久性の高い点で、特に酸化ポリエチレンが好ましい。   As the polyolefin-based wax in the present invention, oxidized polyethylene, polypropylene wax, polyethylene wax, modified polyolefin wax and the like can be used, and these can be used alone or in combination of two or more as required. In particular, polyethylene oxide is preferable because it is difficult to cause cracks on the road surface and has high durability.

本発明において、必要に応じて顔料を添加してもよい。顔料は、無機顔料または有機顔料のいずれでも限定されるものではない。特に、耐熱性や耐候性の面から、無機顔料が好ましい。   In the present invention, a pigment may be added as necessary. The pigment is not limited to either an inorganic pigment or an organic pigment. In particular, an inorganic pigment is preferable from the viewpoints of heat resistance and weather resistance.

無機顔料としては、黄色含水酸化鉄(ゲーサイト)、赤色酸化鉄(ベンガラ)、緑色酸化クロム、白色酸化チタン等が使用できる。また、耐熱性を向上した顔料を用いることもできる。更に、炭酸カルシウム、タルク、クレイ等の体質顔料を使用することもできる。これらを2種以上組み合わせて使用することもできる。   As the inorganic pigment, yellow hydrous iron oxide (goethite), red iron oxide (Bengara), green chromium oxide, white titanium oxide, and the like can be used. A pigment having improved heat resistance can also be used. Further, extender pigments such as calcium carbonate, talc, and clay can be used. Two or more of these may be used in combination.

また、フェライト等の磁性粒子を用いることにより、磁気誘導等の磁性に基づく機能を付与することができる。   Further, by using magnetic particles such as ferrite, a function based on magnetism such as magnetic induction can be imparted.

顔料の含有量は、通常、樹脂組成物100重量部に対し5〜50重量部が好ましい。5重量部未満では顔料を添加する効果が十分でなく、一方、50重量部を越えると骨材への濡れ性が不十分となり、骨材との接着性に問題を生じることがある。   The content of the pigment is usually preferably 5 to 50 parts by weight with respect to 100 parts by weight of the resin composition. If the amount is less than 5 parts by weight, the effect of adding the pigment is not sufficient. On the other hand, if the amount exceeds 50 parts by weight, the wettability to the aggregate becomes insufficient, which may cause a problem in the adhesion to the aggregate.

また、ペレット状の舗装用樹脂組成物同士の付着を一層防止する目的で、上記の無機顔料や炭酸カルシウムやクレイ、タルク、ケイ砂、ベントナイト等の安価な鉱物、あるいは、ステアリン酸マグネシウム、ステアリン酸カルシウム、ステアリン酸バリウム等の滑材を添加することもできる。これらの付着防止用の粉末は、1種あるいは2種以上を組み合わせて使用することができる。より効果的には、得られたペレット状の舗装用樹脂組成物の表面に付着させることであり、例えば、押し出し機からでてきたストランドに振り掛けた後、必要な大きさの小塊状にしたり、あるいは小塊状にした後に振り掛けたりするような方法が有効である。   In addition, for the purpose of further preventing adhesion between pellet-shaped paving resin compositions, the above-mentioned inorganic pigments, inexpensive minerals such as calcium carbonate, clay, talc, silica sand, bentonite, or magnesium stearate, calcium stearate A lubricant such as barium stearate can also be added. These powders for preventing adhesion can be used alone or in combination of two or more. More effectively, it is to adhere to the surface of the obtained pellet-shaped resin composition for paving, for example, after sprinkling on the strand coming from the extruder, into a small lump of the required size, Alternatively, a method of sprinkling after making a small lump is effective.

これら付着防止用の粉末の添加量は、通常、舗装用樹脂組成物100重量部に対し0.1〜5重量部である。   The addition amount of these adhesion preventing powders is usually 0.1 to 5 parts by weight with respect to 100 parts by weight of the resin composition for paving.

顔料の場合には、特に問題はないが、滑材を使用する場合にはできるだけ使用量は少なくした方が好ましい。従って、5重量部以下が好ましい。一方、0.1重量部未満では十分な添加効果が得られない。   In the case of a pigment, there is no particular problem, but when a lubricant is used, it is preferable to reduce the amount used as much as possible. Therefore, 5 parts by weight or less is preferable. On the other hand, if it is less than 0.1 parts by weight, a sufficient addition effect cannot be obtained.

次に、本発明に係る舗装用樹脂組成物の製造方法について述べる。   Next, the manufacturing method of the resin composition for paving which concerns on this invention is described.

本発明における舗装用樹脂組成物は、エチレン酢酸ビニル共重合体、テレブロックコポリマー及び石油系プロセスオイル、更に、必要により、芳香族系石油樹脂及びその他の添加物をそれぞれ所望の比率で混合して、均一な組成のバインダーを得られるものであり、従来、公知の方法を用いればよい。   The resin composition for paving in the present invention comprises an ethylene vinyl acetate copolymer, a teleblock copolymer and a petroleum process oil, and further, if necessary, an aromatic petroleum resin and other additives mixed in a desired ratio. A binder having a uniform composition can be obtained, and conventionally known methods may be used.

あるいは、同じく各原料を混合したものを押し出し成形機にて、100〜200℃に加熱して混練する。工業的には、一軸や二軸の押出し機で混練し、冷却した後、ペレタイザーにより望ましい大きさに粉砕して、ペレット状のものを調製することができる。   Or what mixed each raw material similarly is knead | mixed by heating at 100-200 degreeC with an extrusion molding machine. Industrially, it can be kneaded with a uniaxial or biaxial extruder, cooled, and then pulverized to a desired size by a pelletizer to prepare a pellet.

ペレットの大きさは、2mm〜30mm程度の大きさである。2mm未満では樹脂組成物同士の付着が起こりやすくなり、一方、30mmを越えては骨材と混合して合材を作製する際に、やや溶解作業時間が長くかかるという問題が生じる。   The size of the pellet is about 2 mm to 30 mm. When the thickness is less than 2 mm, the resin compositions tend to adhere to each other. On the other hand, when the thickness exceeds 30 mm, a problem arises that it takes a long time to dissolve the mixture when mixed with aggregate.

本発明に係る舗装用アスファルト組成物は、上記舗装用樹脂組成物3〜10重量%と骨材97〜90重量%とからなる。舗装用樹脂組成物の量が3重量%未満では舗装用アスファルト組成物の強度が弱く、ひび割れ等を生じやすく、一方、10重量%を越えると夏場の舗装面のわだち掘れなどの問題が生じやすくなる。   The asphalt composition for paving according to the present invention comprises 3 to 10% by weight of the resin composition for paving and 97 to 90% by weight of aggregate. If the amount of the resin composition for pavement is less than 3% by weight, the strength of the asphalt composition for pavement is weak and easily causes cracks. On the other hand, if it exceeds 10% by weight, problems such as rutting of the pavement surface in summer tend to occur. Become.

舗装用アスファルト組成物の好ましい調製方法は、包装形態の舗装用樹脂組成物を計量機を通さずに直接ミキサーに投入して150〜200℃、より好ましくは150〜180℃で骨材と混合する方法である。150℃未満では得られたアスファルト組成物を用いて施工する際の作業性が低下するという問題が生じる場合があり、一方、200℃を越えると樹脂の一部劣化や顔料の変色等の問題が生じる場合がある。
混合時間は30〜60秒程度である。30秒未満では混合が不十分となる場合があり、一方、60秒を越えても効果に変わりがなく、却って作業性が低下する。この場合、骨材は予め160〜220℃に加熱してミキサーに投入することにより、舗装用樹脂組成物が短時間で溶融し、骨材を十分に濡らすことができる。160℃未満又は220℃を越えると、上記好ましい混合温度に調節することが困難となる。
A preferable method for preparing the asphalt composition for paving is to put the resin composition for paving in a packaging form directly into a mixer without passing through a measuring machine, and mix with the aggregate at 150 to 200 ° C, more preferably 150 to 180 ° C. Is the method. If the temperature is lower than 150 ° C., there may be a problem that workability when the obtained asphalt composition is used is reduced. On the other hand, if the temperature exceeds 200 ° C., problems such as partial deterioration of the resin and discoloration of the pigment may occur. May occur.
The mixing time is about 30 to 60 seconds. If it is less than 30 seconds, mixing may be insufficient. On the other hand, if it exceeds 60 seconds, the effect is not changed, and workability is deteriorated. In this case, the aggregate is preheated to 160 to 220 ° C. and charged into the mixer, whereby the resin composition for paving melts in a short time and the aggregate can be sufficiently wetted. If it is less than 160 ° C. or exceeds 220 ° C., it becomes difficult to adjust to the preferable mixing temperature.

また、舗装用樹脂組成物が顔料を含有する場合には、顔料だけをミキサーに投入する必要がなく、従って、顔料の粉塵に起因する健康上及び環境への悪影響がないので、顔料を含有する舗装用樹脂組成物を用いるのが好ましい。   Further, when the resin composition for paving contains a pigment, it is not necessary to add only the pigment to the mixer, and therefore there is no adverse health and environmental impact caused by the dust of the pigment. It is preferable to use a resin composition for paving.

本発明においては、特定のエチレン酢酸ビニル共重合体と石油系プロセスオイルとテレブロックコポリマーとの組成とすることによって、短時間で溶融し、かつ骨材への濡れ性及び接着性に優れ、さらに、夏期の路面の変形や冬期のひび割れ等の問題のない耐久性に優れた路面を与えることができる。   In the present invention, the composition of a specific ethylene vinyl acetate copolymer, petroleum-based process oil, and teleblock copolymer melts in a short time and is excellent in wettability and adhesiveness to aggregate, It is possible to provide a road surface having excellent durability without problems such as deformation of the road surface in summer and cracks in winter.

また、ペレット状の舗装用樹脂組成物では、保存中あるいは運搬中にお互いに付着したりミキサーに付着したりせず、短時間で溶融させることができる。   In addition, the pelletized resin composition for paving does not adhere to each other or adhere to the mixer during storage or transportation, and can be melted in a short time.

さらに、本発明のペレット状の小塊状の舗装用樹脂組成物は所定容量のポリ袋などに包装できるので、包装形態から直接ミキサーに投入することにより同時に計量されるので、計量機を通す必要がなく、従って、計量機や配管等の洗浄が不要で作業性が高められる。
更に、顔料を含有する該樹脂組成物においては、別途顔料をミキサーに投入する必要がないので、粉塵に起因する健康上や環境上の問題がなく、作業性の良好な舗装用樹脂組成物を提供することができる。
Furthermore, since the pellet-shaped small block paving resin composition of the present invention can be packaged in a predetermined amount of plastic bag or the like, since it is simultaneously weighed by putting it into the mixer directly from the packaging form, it is necessary to pass through a measuring machine. Therefore, it is not necessary to clean the weighing machine and the piping, and the workability is improved.
Furthermore, in the resin composition containing a pigment, since it is not necessary to add a pigment separately to the mixer, there is no health or environmental problem caused by dust, and a paving resin composition with good workability is obtained. Can be provided.

<作用>
まず、本発明において重要な点は、特定のエチレン酢酸ビニル共重合体と石油系プロセスオイルとテレブロックコポリマーとからなる組成物であり、短時間で溶融し、かつ骨材への濡れ性及び接着性に優れ、さらに、夏期の路面の変形や冬期のひび割れ等の問題のない耐久性に優れた路面を与えることができる点である。また、長期貯蔵においても、相分離が起こらず組成の均一性が維持できる点である。
<Action>
First, an important point in the present invention is a composition comprising a specific ethylene vinyl acetate copolymer, a petroleum-based process oil, and a teleblock copolymer, which melts in a short time and has wettability and adhesion to aggregate. Furthermore, it is possible to provide a road surface excellent in durability and free from problems such as deformation of the road surface in summer and cracks in winter. In addition, even during long-term storage, phase separation does not occur and composition uniformity can be maintained.

さらに、必要に応じて、特定の石油樹脂やポリオレフィン系ワックスを添加することで、強度等の物性向上や、ペレット化を容易にさせうる効果が得られる点である。   Further, if necessary, the addition of a specific petroleum resin or polyolefin-based wax can improve the physical properties such as strength and can easily produce pellets.

以下、本発明を実施例及び比較例に基づいて、更に詳細に説明するが、本発明はこれらにより何ら制限されるものではない。   EXAMPLES Hereinafter, although this invention is demonstrated further in detail based on an Example and a comparative example, this invention is not restrict | limited at all by these.

樹脂組成物の評価は、JIS K2207「石油アスファルト」に記載されている方法に依った。
すなわち、軟化点、針入度、伸度および溶融性の各項目について、測定した。
The evaluation of the resin composition was based on the method described in JIS K2207 “Petroleum Asphalt”.
That is, each item of softening point, penetration, elongation, and meltability was measured.

低温性は、各樹脂組成物5gをアルミホイル上に載せた状態で、130℃のホットプレート上で加熱溶融したものを、4℃の低温庫に一晩放置した後、手で割れるか否かを試験した。
割れない ; ○
割れる ; ×
The low-temperature property is whether or not the resin composition 5 g on the aluminum foil is heated and melted on a 130 ° C. hot plate and left in a low-temperature storage at 4 ° C. overnight and then cracked by hand. Was tested.
Does not break; ○
Break, ×

また、骨材との混合物に関しては、マーシャル安定度試験、水浸マーシャル安定度試験について評価を行った。
マーシャル安定度試験は「舗装試験法便覧」に記載されている方法に依った。
Moreover, regarding the mixture with an aggregate, the Marshall stability test and the water immersion Marshall stability test were evaluated.
The Marshall stability test was based on the method described in “Handbook of Pavement Test Methods”.

試験供試体の調製条件は次の通りで行った。
骨材として6号砕石48%、荒砂23%、細砂23%および上記で得られた樹脂組成物6%からなる混合物を150〜160℃で混合し、130〜140℃で締め固めを行った。締め固め回数は両面それぞれ50回行った。
The test specimens were prepared under the following conditions.
A mixture composed of 48% No. 6 crushed stone, 23% rough sand, 23% fine sand and 6% of the resin composition obtained as above was mixed at 150 to 160 ° C. and compacted at 130 to 140 ° C. . The number of compactions was 50 times on both sides.

上記の調製条件によって得られた供試体をそのままマーシャル安定度試験を行うのに加えて、60℃の恒温水槽中で2日間浸漬した後、マーシャル安定度試験を行った。
さらに、次式により残留安定度を算出した。
残留安定度(%)=[60℃・48時間水浸後の安定度/安定度]×100
In addition to directly performing the Marshall stability test on the specimen obtained under the above preparation conditions, the specimen was immersed in a constant temperature water bath at 60 ° C. for 2 days, and then the Marshall stability test was performed.
Furthermore, the residual stability was calculated by the following formula.
Residual stability (%) = [stability after water immersion at 60 ° C. for 48 hours / stability] × 100

次に、6号砕石80.3%、粗骨材11.7%、石粉3.2%及び上記で得られた樹脂組成物4.8%からなる混合物を150〜160℃で混合し、130〜140℃で締め固めを行なった。締め固め回数は両面それぞれ50回行なった。   Next, a mixture comprising 80.3% of No. 6 crushed stone, 11.7% of coarse aggregate, 3.2% of stone powder and 4.8% of the resin composition obtained above was mixed at 150 to 160 ° C., and 130 Compaction was performed at ˜140 ° C. The number of compactions was 50 times on each side.

上記によって得られた供試体を−20℃に放置し、ロサンゼルス試験機(粗骨材のすり減り試験法に規定する機械)を用いて、剛球を使用しないでドラムを300回転させ、試験後の損失量を測定した。(カンタブロ試験)   The specimen obtained as described above was allowed to stand at −20 ° C., and the drum was rotated 300 times without using a hard ball using a Los Angeles tester (a machine specified in the coarse aggregate abrasion test method), and the loss after the test. The amount was measured. (Cantablo test)

実施例1
エチレン−酢酸ビニル共重合体としてウルトラセン726(商品名;(株)東ソー製;酢酸ビニル含有量31重量%、メルトフローレイト700g/10min)210g、テレブロックポリマーとしてアサプレンT−411(商品名;旭化成工業(株)製:SBS,スチレン比率;30%,メルトフローレート;<1g/10min)100gおよび石油系プロセスオイルとしてリフレッシュスーパーE(商品名;昭和シェル石油(株)製)690gを攪拌機付きの反応容器を用いて混合し、樹脂組成物(A)を得た。
得られた樹脂組成物(A)は、軟化点58.5℃、針入度48、伸度68cmであった。
Example 1
Ultracene 726 (trade name; manufactured by Tosoh Corporation; vinyl acetate content 31% by weight, melt flow rate 700 g / 10 min) 210 g as an ethylene-vinyl acetate copolymer, Asaprene T-411 (trade name; Asahi Kasei Kogyo Co., Ltd .: SBS, styrene ratio: 30%, melt flow rate: <1 g / 10 min) 100 g and petroleum process oil Refresh Super E (trade name; Showa Shell Sekiyu K.K.) 690 g with a stirrer Were mixed using a reaction vessel of No. 1 to obtain a resin composition (A).
The obtained resin composition (A) had a softening point of 58.5 ° C., a penetration of 48, and an elongation of 68 cm.

実施例2、4、比較例1〜4
エチレン−酢酸ビニル共重合体の種類及び量、テレブロックポリマーの種類及び量、石油系プロセスオイルの種類及び量、芳香族系石油樹脂の種類及び量、さらには、ポリオレフィン系ワックスの種類及び量を種々変化させた以外は実施例1と同様にして樹脂組成物の調製を行った。
Examples 2 and 4 and Comparative Examples 1 to 4
Type and amount of ethylene-vinyl acetate copolymer, type and amount of teleblock polymer, type and amount of petroleum process oil, type and amount of aromatic petroleum resin, and type and amount of polyolefin wax A resin composition was prepared in the same manner as in Example 1 except that various changes were made.

実施例3
実施例1と同様にして種々の樹脂を混合した後、180℃で樹脂を溶融させた後、5℃程度まで冷却し、5mm×20mmのチップ状に切断した。
Example 3
After mixing various resins in the same manner as in Example 1, the resin was melted at 180 ° C., cooled to about 5 ° C., and cut into chips of 5 mm × 20 mm.

実勢例5
実施例3と同様にして種々の樹脂を混合した後、180℃で樹脂を溶融させた後、5℃程度まで冷却し、5mm×10mmのチップ状に切断した
Case 5
After mixing various resins in the same manner as in Example 3, the resin was melted at 180 ° C., cooled to about 5 ° C., and cut into chips of 5 mm × 10 mm.

各種原料の諸特性を表1に、このときの製造条件を表2に及び得られた樹脂組成物の諸特性を表3に示す。   Various properties of various raw materials are shown in Table 1, production conditions at this time are shown in Table 2, and various properties of the obtained resin composition are shown in Table 3.

Figure 2009114440
Figure 2009114440

Figure 2009114440
Figure 2009114440

Figure 2009114440
Figure 2009114440

表3に示すとおり、本発明に係る舗装用樹脂組成物は、溶融性や低温での耐折性に優れることが明らかとなった。   As shown in Table 3, it became clear that the resin composition for paving according to the present invention is excellent in meltability and folding resistance at low temperatures.

<水浸マーシャル安定度試験>
骨材として6号砕石48%、荒砂23%、細砂23%及び上記で得られた各樹脂組成物6%からなる混合物を150〜160℃で混合し、130〜140℃で締め固めを行った。締め固め回数は両面それぞれ50回行った。
得られた混合物の特性を表4に示す。
<Water immersion marshall stability test>
Aggregate 48% crushed stone, 23% rough sand, 23% fine sand, and 6% of each resin composition obtained above were mixed at 150-160 ° C and compacted at 130-140 ° C. It was. The number of compactions was 50 times on both sides.
The properties of the resulting mixture are shown in Table 4.

<低温カンタブロ試験>
6号砕石80.3%、粗骨材11.7%、石粉3.2%及び上記で得られた各樹脂組成物4.8%からなる混合物を150〜160℃で混合し、130〜140℃で締め固めを行なった。締め固め回数は両面それぞれ50回行なった。
<Low temperature cantabro test>
A mixture of No. 6 crushed stone 80.3%, coarse aggregate 11.7%, stone powder 3.2% and each resin composition 4.8% obtained above was mixed at 150 to 160 ° C., and 130 to 140 Compaction was performed at ° C. The number of compactions was 50 times on each side.

上記によって得られた供試体を−20℃に放置し、ロサンゼルス試験機(粗骨材のすり減り試験法に規定する機械)を用いて、剛球を使用しないでドラムを300回転させ、試験後の損失量を測定した(カンタブロ試験)。
得られた混合物の特性を表5に示す。
The specimen obtained as described above was allowed to stand at −20 ° C., and the drum was rotated 300 times without using a hard ball using a Los Angeles tester (a machine specified in the coarse aggregate abrasion test method), and the loss after the test. The amount was measured (cantabulo test).
The properties of the resulting mixture are shown in Table 5.

Figure 2009114440
Figure 2009114440

Figure 2009114440
Figure 2009114440

表5の結果から、本発明に係る舗装用樹脂組成物は、低温カンタブロ試験において、損失量が30%以下と小さく、比較例に比べて優れた特性を有することが明らかである。   From the results in Table 5, it is clear that the resin composition for paving according to the present invention has a loss amount as small as 30% or less in the low-temperature cantabulo test, and has excellent characteristics as compared with the comparative example.

本発明に係る舗装用樹脂組成物は、短時間で溶融し、かつ骨材への濡れ性及び接着性に優れ、さらに、夏期の路面の変形や冬期のひび割れ等の問題のない耐久性に優れた路面を与えることができる。   The resin composition for paving according to the present invention melts in a short time and is excellent in wettability and adhesiveness to the aggregate, and further excellent in durability without problems such as road surface deformation in summer and cracks in winter. Can give a rough road surface.

さらに、樹脂組成物として、保存中あるいは運搬中にお互いに付着したりミキサーに付着したりせず、短時間で溶融するようにチップ状の形状を持っており、また、顔料と当該樹脂組成物の混合物においては、顔料を投入時の粉塵等の問題のない作業性の良いペレット状の舗装用材料も提供できる。   Furthermore, the resin composition has a chip-like shape so that it does not adhere to each other or adhere to the mixer during storage or transportation, and melts in a short time. Also, the pigment and the resin composition In this mixture, it is possible to provide a pavement-shaped paving material having good workability without problems such as dust when the pigment is added.

Claims (11)

酢酸ビニルの含有量が25〜45重量%であって溶融温度が40〜100℃であってメルトフローレートが400g/10min以上であるエチレン酢酸ビニル共重合体と、芳香族環由来の炭素の含有量(CA)が20〜40%である石油系プロセスオイルと、テレブロックポリマーとを少なくとも含むことを特徴とする舗装用樹脂組成物。 Ethylene vinyl acetate copolymer having a vinyl acetate content of 25 to 45% by weight, a melting temperature of 40 to 100 ° C. and a melt flow rate of 400 g / 10 min or more, and an aromatic ring-derived carbon content A paving resin composition comprising at least a petroleum-based process oil having a quantity (CA) of 20 to 40% and a teleblock polymer. エチレン酢酸ビニル共重合体の含有量が2〜30重量%、石油系プロセスオイルの含有量が20〜80重量%、テレブロックポリマーの含有量が2〜20重量%である請求項1記載の舗装用樹脂組成物。 The pavement according to claim 1, wherein the content of ethylene vinyl acetate copolymer is 2 to 30% by weight, the content of petroleum-based process oil is 20 to 80% by weight, and the content of teleblock polymer is 2 to 20% by weight. Resin composition. テレブロックポリマーが、スチレン−ブタジエン−スチレン(SBS)及び/又はスチレン−イソブチレン−スチレン(SIS)である請求項1記載の舗装用樹脂組成物。 The resin composition for pavements according to claim 1, wherein the teleblock polymer is styrene-butadiene-styrene (SBS) and / or styrene-isobutylene-styrene (SIS). 軟化点が80〜110℃であって酸価が0.5mgKOH/g以下である芳香族系石油樹脂を20重量%未満添加した請求項1記載の舗装用樹脂組成物。 The resin composition for paving according to claim 1, wherein an aromatic petroleum resin having a softening point of 80 to 110 ° C and an acid value of 0.5 mgKOH / g or less is added in an amount of less than 20% by weight. 酸価が1.0〜70mgKOH/gであるポリオレフィン系ワックスを0〜10重量%添加した請求項1記載の舗装用樹脂組成物。 The resin composition for pavements according to claim 1, wherein 0 to 10% by weight of a polyolefin wax having an acid value of 1.0 to 70 mgKOH / g is added. ポリオレフィン系ワックスが、酸化ポリエチレンであることを特徴とする請求項5記載の舗装用樹脂組成物。 6. The resin composition for paving according to claim 5, wherein the polyolefin wax is polyethylene oxide. 形状がペレット状である請求項1〜6のいずれかに記載の舗装用樹脂組成物。 The resin composition for paving according to any one of claims 1 to 6, wherein the shape is a pellet. 請求項1乃至7のいずれかに記載の舗装用樹脂組成物3〜10重量%と骨材97〜90重量%とからなる舗装用アスファルト組成物。 An asphalt composition for paving comprising 3 to 10% by weight of the resin composition for paving according to any one of claims 1 to 7 and 97 to 90% by weight of aggregate. 舗装用樹脂組成物と骨材とを150〜200℃で混合してなることを特徴とする請求項8記載の舗装用アスファルト組成物。 The paving asphalt composition according to claim 8, wherein the paving resin composition and the aggregate are mixed at 150 to 200 ° C. 請求項7記載のペレット状の舗装用樹脂組成物と骨材とを計量機を通さずに直接ミキサーに投入し、150〜200℃で混合することを特徴とする舗装用アスファルト組成物の製造方法。 A method for producing a paving asphalt composition, wherein the pellet-shaped paving resin composition and aggregate according to claim 7 are directly fed into a mixer without passing through a measuring machine and mixed at 150 to 200 ° C. . 骨材を予め160〜220℃に加熱することを特徴とする請求項10記載の舗装用アスファルト組成物の製造方法。
The method for producing an asphalt composition for pavement according to claim 10, wherein the aggregate is heated to 160 to 220 ° C in advance.
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