JP2009022161A - Bacteriostatic composition for food and bacteriostatic method. - Google Patents
Bacteriostatic composition for food and bacteriostatic method. Download PDFInfo
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- JP2009022161A JP2009022161A JP2007170272A JP2007170272A JP2009022161A JP 2009022161 A JP2009022161 A JP 2009022161A JP 2007170272 A JP2007170272 A JP 2007170272A JP 2007170272 A JP2007170272 A JP 2007170272A JP 2009022161 A JP2009022161 A JP 2009022161A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract
【課題】微生物が増殖しやすい食品に対しても、食品の鮮度や品質を良好に保持することができる食品の静菌用組成物及び静菌方法を提供する。
【解決手段】酢酸1質量部に対して酢酸ナトリウムを9質量部を超えて13質量部以下含有することで、食品に優れた静菌効果を付与する。
【選択図】なし
Disclosed are a food bacteriostatic composition and a bacteriostatic method capable of maintaining good freshness and quality of foods even for foods in which microorganisms are likely to grow.
By containing sodium acetate in an amount exceeding 9 parts by mass and not more than 13 parts by mass with respect to 1 part by mass of acetic acid, an excellent bacteriostatic effect is imparted to food.
[Selection figure] None
Description
本発明は、食品の静菌用組成物及び静菌方法に関する。 The present invention relates to a bacteriostatic composition for food and a bacteriostatic method.
環境衛生が改善される中、今日においても、大腸菌や腸炎ビブリオなどによる食中毒の発生が絶えない。また、乳酸菌などのように、乳製品や漬物など多くの食品加工に利用されている一方、食品に酸味や酸臭を与えたりガスを発生したりするなど、食品の変質・腐敗等の原因となるものも存在する。そこで、食品分野においては、こういった微生物の繁殖を抑え、食品の保存性を向上させることが求められている。 As environmental sanitation is improved, food poisoning due to E. coli and Vibrio parahaemolyticus continues to occur today. In addition, it is used for many food processing such as lactic acid bacteria and dairy products, while it causes acidity and acid smell to the food and generates gas. There are also. Therefore, in the food field, there is a demand for suppressing the propagation of such microorganisms and improving the preservation of food.
そのための方法として、例えば、酢酸と酢酸ナトリウムと炭酸ナトリウムとを配合した水溶液で生野菜などの食品を処理するもの(特許文献1)や、酢酸と酢酸ナトリウムとを含むpH5.8〜6.4の水溶液で生野菜を処理するもの(特許文献2)などが提案されている。また、醸造酢に酢酸ナトリウムを添加して酢酸酸度2.6重量%、pH5.0に調製した魚用調味液で魚体を処理するものも提案されている(特許文献3)。 As a method therefor, for example, a food such as raw vegetables treated with an aqueous solution containing acetic acid, sodium acetate and sodium carbonate (Patent Document 1), or pH 5.8 to 6.4 containing acetic acid and sodium acetate. The thing (patent document 2) etc. which process raw vegetables with the aqueous solution of this are proposed. Moreover, what treats a fish body with the seasoning liquid for fish prepared by adding sodium acetate to brewing vinegar and adjusting the acetic acid degree to 2.6 weight% and pH5.0 is proposed (patent document 3).
しかしながら、上記特許文献1及び特許文献2では、生野菜に対する褐変の抑制は期待できるものの、生野菜に比べて細菌等が非常に繁殖しやすい食品、例えば、生肉や生魚などの他の食品については検討されておらず、これらの食品の保存性を向上できるとはいえなかった。 However, in Patent Document 1 and Patent Document 2 described above, although suppression of browning of raw vegetables can be expected, for foods in which bacteria and the like are very easy to reproduce compared to raw vegetables, for example, other foods such as raw meat and raw fish It has not been studied, and it cannot be said that the preservability of these foods can be improved.
また、特許文献3は、酢締め用であるため酸味がきつく、酢締めを目的としない食品の鮮度保持用には適していなかった。すなわち、特許文献3の組成物では、酸味によって食材本来の風味を損ねてしまうし、また、生の食品に用いた場合には、食品の酸変性の原因となっていた。さらに、乳酸菌のように低pHでも増殖可能な微生物に対しては、その増殖を十分に抑制できず、異臭や変色等の原因となっていた。 Moreover, since patent document 3 is for vinegar fastening, it has a sour taste and was not suitable for maintaining the freshness of foods not intended for vinegar fastening. That is, in the composition of patent document 3, the original flavor of foodstuffs is impaired by acidity, and when used for raw food, it causes acid modification of the food. Furthermore, for microorganisms that can grow even at a low pH, such as lactic acid bacteria, the growth could not be sufficiently suppressed, causing a strange odor or discoloration.
そこで、本発明は、微生物が増殖しやすい食品に対しても、食品の鮮度や品質を良好に保持することができる食品の静菌用組成物及び静菌方法を提供することを一つの目的とする。また、耐酸性を有する微生物の増殖も抑制することのできる食品の静菌用組成物及び静菌方法を提供することを他の一つの目的とする。さらに、保存性に優れた食品及びその製造方法を提供することを他の一つの目的とする。 Accordingly, one object of the present invention is to provide a bacteriostatic composition and a bacteriostatic method for food that can maintain good freshness and quality of the food even for foods in which microorganisms are likely to grow. To do. Another object of the present invention is to provide a bacteriostatic composition and bacteriostatic method for foods that can also suppress the growth of acid-resistant microorganisms. Furthermore, it is another object to provide a food having excellent storage stability and a method for producing the same.
本発明者らは、酢酸と酢酸ナトリウムとの配合比に着目し、これについて種々検討したところ、酢酸に対する酢酸ナトリウムの含有比率を所定範囲にすることにより、生魚、海藻等といった水産物や生肉などのように微生物が非常に繁殖しやすい食品に対しても、異味異臭を与えることなく優れた保存性を付与できること、また、酸に弱い微生物の増殖を抑制するだけでなく、乳酸菌のように耐酸性の微生物の増殖の抑制にも効果的であることを見出し、本発明を完成した。本発明によれば、以下の手段が提供される。 The present inventors paid attention to the blending ratio of acetic acid and sodium acetate, and variously studied this. By setting the content ratio of sodium acetate to acetic acid within a predetermined range, fish and seafood such as raw fish and seaweed, raw meat, etc. In addition to being able to give excellent preservation without giving off a nasty smell, not only suppressing the growth of microorganisms that are vulnerable to acids, but also acid-resistant like lactic acid bacteria As a result, the present invention was completed. According to the present invention, the following means are provided.
本発明によれば、食品の静菌用組成物であって、酢酸1質量部に対して酢酸ナトリウムを9質量部を超えて13質量部以下含有する、組成物が提供される。 According to the present invention, there is provided a composition for bacteriostatic bacteriolysis, which comprises sodium acetate in an amount exceeding 9 parts by mass and not more than 13 parts by mass with respect to 1 part by mass of acetic acid.
本組成物は、酢酸1質量部に対して酢酸ナトリウムを9.5質量部以上11質量部以下含有するものとすることもできる。また、酢酸濃度が0.1質量%以上2質量%以下であるものとしてもよい。 This composition can also contain 9.5 mass parts or more and 11 mass parts or less of sodium acetate with respect to 1 mass part of acetic acid. The acetic acid concentration may be 0.1% by mass or more and 2% by mass or less.
また、本組成物は、静菌対象が、少なくとも耐酸性を有する微生物であるものとしてもよい。このとき、前記耐酸性を有する微生物が乳酸菌であってもよい。 In the present composition, the bacteriostatic target may be a microorganism having at least acid resistance. At this time, the acid-resistant microorganism may be a lactic acid bacterium.
本発明によれば、上記いずれかの静菌用組成物中に調味成分を含有する、調味液が提供される。 According to this invention, the seasoning liquid which contains a seasoning component in one of the said bacteriostatic compositions is provided.
本発明によれば、食品の静菌方法であって、上記いずれかに記載の静菌用組成物又は調味液を用いて食品を処理する処理工程、を備える、静菌方法が提供される。 According to this invention, it is a bacteriostatic method, Comprising: The bacteriostatic method provided with the process process which processes a foodstuff using the composition for bacteriostasis or the seasoning liquid in any one of the said.
本静菌方法において、前記処理工程は、前記食品の少なくとも表面に前記組成物又は前記調味液を接触させる工程であるものとしてもよい。また、前記処理工程は、前記食品中の酢酸濃度が0.1質量%以上0.2質量%以下になるよう前記食品に前記組成物又は前記調味液を添加する工程であるものとすることもできる。 In this bacteriostatic method, the treatment step may be a step of bringing the composition or the seasoning liquid into contact with at least the surface of the food. Moreover, the said process process shall be a process of adding the said composition or the said seasoning liquid to the said food so that the acetic acid concentration in the said food may be 0.1 to 0.2 mass%. it can.
本発明によれば、上記いずれかに記載の組成物又は調味液を含む、食品が提供される。 According to this invention, the foodstuff containing the composition or seasoning liquid in any one of the above is provided.
本食品において、食品が生の水産物又は食肉であるものとしてもよい。また、前記食品は液状体としての前記組成物又は前記調味液に漬した状態であり、前記食品中の酢酸濃度が0.1質量%以上0.2質量%以下としてもよい。 In the present food, the food may be raw marine products or meat. Moreover, the said foodstuff is the state immersed in the said composition or said seasoning liquid as a liquid body, and the acetic acid concentration in the said foodstuff is good also as 0.1 mass% or more and 0.2 mass% or less.
本発明によれば、食品の製造方法であって、上記いずれかに記載の組成物又は調味液を用いて食品を処理する処理工程、を備える、製造方法が提供される。 According to this invention, it is a manufacturing method of foodstuff, Comprising: The manufacturing method provided with the process process of processing foodstuffs using the composition or seasoning liquid in any one of the said is provided.
本発明によれば、酢酸と酢酸ナトリウムとを上記比率で含有していることから、刺身、生わかめなどの水産物等のように、微生物が非常に繁殖しやすい食品に対しても、異味異臭を与えることなく優れた保存性を付与することができる。これにより、保存性に優れた食品を提供することができる。また、乳酸菌のように、耐酸性を有する微生物の増殖も効果的に抑制できる。しかも、人体に対する安全性も高い。 According to the present invention, since it contains acetic acid and sodium acetate in the above-mentioned ratio, it also has a nasty smell and odor even for foods where microorganisms are very prone to breed, such as marine products such as sashimi and raw seaweed. Excellent storage stability can be imparted without giving. Thereby, the food excellent in preservability can be provided. Moreover, the growth of microorganisms having acid resistance such as lactic acid bacteria can be effectively suppressed. Moreover, it is highly safe for the human body.
本発明によれば、食品の静菌用組成物及び静菌方法のほか、調味液並びにこれらを用いて処理した食品及びその製造方法が提供される。以下、本発明の実施の形態について詳細に説明する。なお、以下に示す形態は、本発明の好ましい形態であるが、本発明を限定するものではない。 According to the present invention, in addition to a bacteriostatic composition and a bacteriostatic method for food, a seasoning liquid, a food processed using these, and a method for producing the same are provided. Hereinafter, embodiments of the present invention will be described in detail. In addition, although the form shown below is a preferable form of this invention, this invention is not limited.
(静菌用組成物)
本組成物は、食品の鮮度や品質等の劣化を抑制し、その保存性を向上させるために用いる。本組成物を適用可能な食品の種類は特に限定せず、例えば、野菜、豆類、芋類、山菜、果物、畜肉、鶏肉、水産物、穀類などの各種食材の非調理品であってもよいし、惣菜、ご飯類、麺類、菓子類、スープ類、乳製品、豆腐類などといった調理済み又は半調理済みの食品であってもよい。好ましくは、生鮮食品又は惣菜である。また、生鮮食品のうち、生の畜肉、鶏肉及び水産物がより好ましく、生魚、生わかめ等の生の水産物がさらに好ましい。特に、水産物は、生食が好まれる一方、微生物が非常に繁殖しやすい。このため、食中毒の防止はもちろん、食品の変色や食味の低下等を抑制する観点からも保存性を向上させる必要性が高い。本組成物によれば、このように微生物が非常に増殖しやすい食品に対しても、食品の保存性を効果的に向上させることができる。特に、室温での保存性を向上できる点において優れている。
(Bacteriostatic composition)
This composition is used for suppressing deterioration of food freshness, quality and the like, and improving its storage stability. The type of food to which the present composition can be applied is not particularly limited, and may be, for example, uncooked products of various ingredients such as vegetables, beans, potatoes, wild vegetables, fruits, livestock meat, chicken, marine products, and cereals. It may be a cooked or semi-cooked food such as sugar beet, rice, noodles, confectionery, soups, dairy products, and tofu. Preferably, it is a fresh food or a side dish. In addition, among fresh foods, raw livestock meat, chicken and marine products are more preferable, and raw fishery products such as raw fish and raw seaweed are more preferable. In particular, while marine products are preferred for raw food, microorganisms are very easy to propagate. For this reason, there is a high need for improving the storage stability from the viewpoint of preventing food poisoning, as well as suppressing discoloration of food, deterioration of taste, and the like. According to this composition, the preservability of food can be effectively improved even for foods in which microorganisms are very prone to grow. In particular, it is excellent in that the storage stability at room temperature can be improved.
本組成物の形態は特に限定しない。粉末状、液状、ペースト状などあらゆる形態を採ることができる。好ましくは、液状である。 The form of this composition is not specifically limited. Any form such as powder, liquid, and paste can be employed. Preferably, it is liquid.
(酢酸及び酢酸ナトリウム)
本組成物は、酢酸と酢酸ナトリウムとを含有する。本組成物における両者の比率は、酢酸1質量部に対し、酢酸ナトリウムが9質量部を超えて13質量部以下であるのが好ましい。酢酸ナトリウムが9質量部以下であると、一般生菌、特に乳酸菌の増殖を十分に抑えることができず不適である。また、13質量部を超えると、酢酸ナトリウム由来の苦味を呈し、食味に違和感を与えてしまう。より好ましくは、酢酸1質量部に対し、酢酸ナトリウムが9.5質量部以上11.0質量部以下であり、さらに好ましくは、9.8質量部以上10.5質量部以下である。
(Acetic acid and sodium acetate)
The composition contains acetic acid and sodium acetate. It is preferable that the ratio of both in this composition is 13 mass parts or less with respect to 1 mass part of acetic acid, sodium acetate exceeds 9 mass parts. When the amount of sodium acetate is 9 parts by mass or less, the growth of general live bacteria, particularly lactic acid bacteria cannot be sufficiently suppressed, which is inappropriate. Moreover, when it exceeds 13 mass parts, the bitterness derived from sodium acetate will be exhibited and a taste will be uncomfortable. More preferably, sodium acetate is 9.5 mass parts or more and 11.0 mass parts or less with respect to 1 mass part of acetic acid, More preferably, it is 9.8 mass parts or more and 10.5 mass parts or less.
本組成物中における酢酸及び酢酸ナトリウムの濃度は、両者を上記比率で含有している限り特に限定しない。好ましくは、酢酸濃度が0.1質量%以上2質量%以下である。酢酸濃度が0.1質量%未満であると、微生物の増殖に対して十分な抑制効果が得られない。また、酢酸濃度が2質量%を超えると、酢酸由来の酸味と酢酸ナトリウム由来の苦味とが現れ、食味に違和感を与えてしまう。より好ましくは、0.1質量%以上1.2質量%以下である。 The concentration of acetic acid and sodium acetate in the composition is not particularly limited as long as both are contained in the above ratio. Preferably, the acetic acid concentration is 0.1% by mass or more and 2% by mass or less. When the acetic acid concentration is less than 0.1% by mass, a sufficient inhibitory effect on the growth of microorganisms cannot be obtained. On the other hand, if the acetic acid concentration exceeds 2% by mass, the acidity derived from acetic acid and the bitterness derived from sodium acetate appear, giving a sense of incongruity to the taste. More preferably, they are 0.1 mass% or more and 1.2 mass% or less.
また、酢酸及び酢酸ナトリウムの濃度は、本組成物による食品の処理方法や処理時間等によって適宜設定してもよい。例えば、本組成物による処理が短時間の場合(例えば、数秒〜数時間)には、酢酸濃度が1質量%以上2質量%以下であることが好ましい。処理時間が短い場合、酢酸濃度が1質量%未満では、微生物の増殖に対する十分な抑制効果が得られない。また、酢酸濃度が2質量%を超えると、酢酸及び酢酸ナトリウムにより食品に異味異臭を与えてしまう。より好ましくは、1質量%以上1.2質量%以下である。 Moreover, you may set suitably the density | concentration of an acetic acid and sodium acetate with the processing method, processing time, etc. of the foodstuff by this composition. For example, when the treatment with the present composition is for a short time (for example, several seconds to several hours), the acetic acid concentration is preferably 1% by mass or more and 2% by mass or less. When the treatment time is short, if the acetic acid concentration is less than 1% by mass, a sufficient inhibitory effect on the growth of microorganisms cannot be obtained. On the other hand, if the acetic acid concentration exceeds 2% by mass, an off-flavor will be given to the food by acetic acid and sodium acetate. More preferably, they are 1 mass% or more and 1.2 mass% or less.
短時間での処理が好適な食品としては、例えば、生の状態で提供される食品や、浸漬液中での保管が不適な食品等が挙げられる。具体的には、例えば、生鮮食品(生魚、野菜、根菜類、豆類、果物、カット野菜、カットフルーツなど)や、一次加工食品(例えば、スライス肉、挽き肉、カット肉などの食肉、刺身や寿司種の水産物など)、二次加工食品(例えば、ハム、ウインナー、ベーコンなどの非加熱食肉加工品や、魚肉ハム、魚肉練り製品などの魚肉加工品など)等が挙げられる。 Examples of foods suitable for treatment in a short time include foods that are provided in a raw state and foods that are unsuitable for storage in an immersion liquid. Specifically, for example, fresh foods (raw fish, vegetables, root vegetables, beans, fruits, cut vegetables, cut fruits, etc.) and primary processed foods (eg, meat such as sliced meat, minced meat, cut meat, sashimi and sushi) And other processed foods such as non-heated meat products such as ham, wiener and bacon, and processed fish products such as fish ham and fish paste products).
一方、本組成物による処理が長時間の場合(例えば、数時間〜数日)、食品の保存性を向上させるには、酢酸濃度が0.1質量%以上0.2質量%以下であることが好ましい。酢酸濃度が0.1質量%未満では、微生物の増殖に対する十分な抑制効果が得られない。また、酢酸濃度が0.2質量%を超えると、酢酸及び酢酸ナトリウムにより食品に異味異臭を与えてしまう。より好ましくは、0.10質量%以上0.12質量%以下である。 On the other hand, when the treatment with the composition is for a long time (for example, several hours to several days), the acetic acid concentration is 0.1% by mass or more and 0.2% by mass or less in order to improve the storage stability of the food. Is preferred. When the acetic acid concentration is less than 0.1% by mass, a sufficient inhibitory effect on the growth of microorganisms cannot be obtained. On the other hand, if the acetic acid concentration exceeds 0.2% by mass, an off-flavor is given to the food by acetic acid and sodium acetate. More preferably, it is 0.10 mass% or more and 0.12 mass% or less.
長時間での処理が好適な食品としては、例えば、液体による食感の変化が小さい食品や浸漬液中での保管が可能な食品(例えば、生牡蠣、しらうお、めかぶ、もずく、いくら等の水産物や、漬物、豆腐、缶・瓶詰製品など)や、本組成物を用いて調理又は半調理された食品(例えば、惣菜、ご飯類、スープ類、菓子類、生肉や生魚などを用いた半調理品など)等が挙げられる。 Examples of foods that can be treated for a long time include foods that have little change in texture due to liquids, and foods that can be stored in an immersion liquid (for example, raw oysters, shirouo, mekabu, mozuku, how much, etc. Marine products, pickles, tofu, cans, bottled products, etc.) and foods cooked or semi-cooked using this composition (for example, prepared foods, rice, soups, confectionery, raw meat or fresh fish, etc.) Etc.).
本組成物中の酢酸濃度を上記濃度とする場合、食品と接触させるとき又は接触させた後の濃度が上記濃度であればよい。したがって、本組成物は、濃縮した状態で提供されるものであってもよい。濃縮状態で提供される場合、酢酸及び酢酸ナトリウムの濃度が所望の濃度になるよう、使用時に例えば水などによって濃縮物を希釈することにより、上記と同様の防腐効果を得ることができる。 When the concentration of acetic acid in the composition is the above concentration, the concentration may be the above concentration when contacting with food or after contacting. Therefore, the present composition may be provided in a concentrated state. When provided in a concentrated state, the same preservative effect as described above can be obtained by diluting the concentrate with water, for example, at the time of use so that the concentration of acetic acid and sodium acetate becomes a desired concentration.
このように、本組成物によれば、食品の保存性を向上させるための手段として多量の酸による処理を要しない。このため、食品の酸変性を抑止することができる。また、食材本来の風味も損ねない。したがって、食品の鮮度保持用に適している。 Thus, according to the present composition, treatment with a large amount of acid is not required as a means for improving the preservability of food. For this reason, the acid modification | denaturation of foodstuffs can be suppressed. In addition, the original flavor of the ingredients is not impaired. Therefore, it is suitable for maintaining the freshness of food.
本組成物において、酢酸及び酢酸ナトリウムを含有させるための形態は特に限定しない。酢酸の場合、例えば、氷酢酸、食酢、調味酢などといった、少なくとも酢酸を一成分として含有する1又は2以上の材料を用いてもよい。食品への味、香りの影響等を考慮すると、好ましくは、醸造酢や合成酢などの食酢であり、より好ましくは、米酢、穀物酢、果実酢などの醸造酢である。また、酢酸ナトリウムの場合、酢酸ナトリウムを一成分として含有する1又は2以上の材料を用いてもよいし、あるいは、酢酸を含む組成物中にナトリウム塩を添加してもよい。用いるナトリウム塩は特に限定せず、例えば、炭酸ナトリウムや炭酸水素ナトリウム、水酸化ナトリウムなどが挙げられる。これらのうち、炭酸水素ナトリウムを用いることが好ましい。 In the present composition, the form for containing acetic acid and sodium acetate is not particularly limited. In the case of acetic acid, for example, one or two or more materials containing at least acetic acid as one component, such as glacial acetic acid, vinegar, and seasoned vinegar, may be used. Considering the influence on the taste and aroma of foods, vinegars such as brewed vinegar and synthetic vinegar are preferred, and brewed vinegars such as rice vinegar, grain vinegar and fruit vinegar are more preferred. In the case of sodium acetate, one or more materials containing sodium acetate as a component may be used, or a sodium salt may be added to a composition containing acetic acid. The sodium salt to be used is not particularly limited, and examples thereof include sodium carbonate, sodium hydrogen carbonate, and sodium hydroxide. Of these, it is preferable to use sodium bicarbonate.
なお、本組成物を製造するには、例えば、水(水道水、精製水、蒸留水など)に上記材料を常温下又は加温下で混合することにより行うことができる。 In addition, in order to manufacture this composition, it can carry out by mixing the said material under normal temperature or heating, for example to water (tap water, purified water, distilled water, etc.).
(静菌対象)
本組成物による静菌対象としての微生物の種類は特に限定しない。例えば、サルモネラ属菌、ブドウ球菌、病原大腸菌、腸炎ビブリオ、ボツリヌス菌、ウエルシュ菌、セレウス菌などの食中毒原因菌;乳酸菌や枯草菌、シュードモナス菌などのように、病原性はほとんどないが腐敗に関与する細菌;酵母やカビなどの菌類等が挙げられる。なお、これらのうち、1種又は複数の微生物を本組成物の静菌対象とすることができる。
(Bacteriostatic target)
The kind of microorganisms as a bacteriostatic object by this composition is not specifically limited. For example, food poisoning bacteria such as Salmonella, Staphylococcus, pathogenic Escherichia coli, Vibrio parahaemolyticus, Clostridium botulinum, Clostridium perfringens, Bacillus cereus, etc .; Bacteria such as yeasts and molds. Of these, one or more microorganisms can be the bacteriostatic target of the present composition.
本組成物は、酢酸と酢酸ナトリウムとを上記比率で含むことにより、耐酸性を有する微生物の静菌用として用いることができる。好ましくは、耐酸性を有する微生物と耐酸性を有さない微生物との静菌用として用いる。すなわち、本組成物によれば、酢酸や酢酸ナトリウムによる異味異臭を食品に与えることなく且つ食品に変性を起こさせることなく、低pH(例えば、pH5以下)での増殖が困難な微生物(例えば、サルモネラ属菌、ブドウ球菌、病原大腸菌、腸炎ビブリオ、枯草菌など)と、乳酸菌のように耐酸性を持つ微生物とを静菌できる。特に、生の水産物で非常に繁殖しやすい腸炎ビブリオと乳酸菌とを同時に静菌できる点で有用である。 This composition can be used for bacteriostatic use of acid-resistant microorganisms by containing acetic acid and sodium acetate in the above ratio. Preferably, it is used for bacteriostasis between a microorganism having acid resistance and a microorganism having no acid resistance. That is, according to the present composition, microorganisms that are difficult to grow at a low pH (for example, pH 5 or less) without giving the food an unpleasant odor due to acetic acid or sodium acetate and without causing the food to denature. Salmonella spp., Staphylococcus, pathogenic E. coli, Vibrio parahaemolyticus, Bacillus subtilis, etc.) and acid-resistant microorganisms such as lactic acid bacteria can be bacteriostatic. In particular, it is useful in that it can be bacteriostatic at the same time Vibrio parahaemolyticus and lactic acid bacteria that are very easy to reproduce with raw marine products.
(調味成分及び調味液)
本組成物においては、静菌効果が得られる限り、酢酸及び酢酸ナトリウム以外の成分を含有していてもよい。このような成分としては、例えば、調味成分や食品添加物などが挙げられる。特に、調味成分を含有することにより、食品に対する調味づけと保存性の向上とを同時に行うことができる。また、保存性に優れた調味液及び食品の保存性を向上させることのできる調味液を提供することができる。本発明の調味液によれば、酢酸と酢酸ナトリウムとを上記比率で含むことから、調味液本来の味に影響を及ぼすこともないし、人体に対して悪影響を及ぼすこともない。
(Seasoning ingredients and seasoning liquid)
In this composition, as long as the bacteriostatic effect is acquired, components other than acetic acid and sodium acetate may be contained. Examples of such components include seasoning ingredients and food additives. In particular, by containing a seasoning component, seasoning of food and improvement of storage stability can be performed simultaneously. Moreover, the seasoning liquid excellent in preservability and the seasoning liquid which can improve the preservability of a foodstuff can be provided. According to the seasoning liquid of the present invention, since acetic acid and sodium acetate are contained in the above ratio, the original taste of the seasoning liquid is not affected, and the human body is not adversely affected.
調味成分としては特に限定せず、例えば、醤油、砂糖、鰹節、味醂、食塩、酒等が挙げられる。これらのうち、少なくとも醤油を用いることが好ましい。また、食品添加物としては、甘味料、保存料、酸化防止剤、着色料、香料、増粘剤、膨張剤、乳化剤、ビタミン、アミノ酸、ミネラルなど種々のものが挙げられる。なお、調味成分や食品添加物は、1又は複数の成分を含有させてもよい。 The seasoning component is not particularly limited, and examples thereof include soy sauce, sugar, bonito, miso, salt, and sake. Of these, at least soy sauce is preferably used. Examples of food additives include sweeteners, preservatives, antioxidants, colorants, fragrances, thickeners, swelling agents, emulsifiers, vitamins, amino acids, minerals, and the like. In addition, the seasoning ingredient and the food additive may contain one or more ingredients.
本発明の調味液を用いることにより、種々の食品の味付け等に用いることができる。例えば、鉄火丼やてこね寿司の具材である生魚の切り身の味付けや、しらうおやわかめ、めかぶ、もずくなどの味付け、野菜や魚介類などを使った和え物の味付け等に用いることができる。本調味液で味付けされた食品は、本調味液により十分な静菌効果が付与されていることから、保存性に優れている。 By using the seasoning liquid of the present invention, it can be used for seasoning various foods. For example, it can be used for seasoning raw fish fillets that are ingredients of iron-fired sushi and tepone sushi, seasoning of shiraoi seaweed, mekabu, mozuku, etc., seasoning of seasoned dishes using vegetables, seafood and the like. The food seasoned with this seasoning liquid is excellent in preservability since a sufficient bacteriostatic effect is imparted by the seasoning liquid.
(食品の静菌方法)
本発明の静菌方法は、組成物を用いて食品を処理する処理工程を備える。本組成物を用いて食品を処理するための形態は、少なくとも食品の表面に本組成物を接触可能であれば特に限定せず、各種処理方法を適用できる。例えば、本組成物中に食品を数秒から数日間浸漬してもよいし、食品に本組成物を噴霧又は塗布してもよい。あるいは、食品中に本組成物を添加してもよいし、本組成液を用いて調理又は半調理してもよい。好ましくは、本組成物中に浸漬するか、あるいは本組成物を添加するものである。
(Food bacteriostatic method)
The bacteriostatic method of this invention is equipped with the process process which processes foodstuffs using a composition. The form for treating food with the present composition is not particularly limited as long as the composition can be contacted with at least the surface of the food, and various treatment methods can be applied. For example, the food may be immersed in the composition for a few seconds to several days, or the composition may be sprayed or applied to the food. Or you may add this composition in a foodstuff, and you may cook or semi-cooking using this composition liquid. Preferably, the composition is immersed in the composition or the composition is added.
本組成物を用いて食品を加工するにあたり、本組成物が食品の少なくとも表面全体に均一に接触されることが好ましい。例えば、本組成物中に食品を浸漬する場合、本組成物を食品の表面全体に均一に接触させるには、本組成物中に食品全体が浸漬可能な量の組成物を用いて処理することが好ましい。このときの浸漬温度や浸漬時間等の条件は特に限定せず、用いる食品の種類や調理方法、組成物の濃度等に応じて適宜設定できる。 In processing food using the present composition, it is preferable that the present composition is uniformly contacted with at least the entire surface of the food. For example, when food is immersed in the composition, in order to bring the composition uniformly into contact with the entire surface of the food, the composition may be treated with an amount of the composition that allows the entire food to be immersed in the composition. Is preferred. Conditions such as immersion temperature and immersion time at this time are not particularly limited, and can be appropriately set according to the type of food to be used, the cooking method, the concentration of the composition, and the like.
例えば、浸漬時間については、数秒から数日とすることができる。すなわち、浸漬の形態は、本組成液中に食品をさっと潜らせる程度であってもよいし、長時間浸するものであってもよい。このとき、酢酸及び酢酸ナトリウムの濃度が高いほど本組成物による処理時間を長くしてもよい。例えば、酢酸濃度が1質量%以上2質量%以下の組成液を用いる場合、食品本来の風味や食感を変化させないようにしつつ十分な静菌効果を得るには、処理時間が5秒以上30分以下であることが好ましい。より好ましくは、30秒以上15分以下である。また、酢酸濃度が0.1質量%以上0.2質量%以下の組成液を用いる場合には、処理時間が12時間以上であることが好ましい。 For example, the immersion time can be several seconds to several days. That is, the form of immersion may be such that the food is quickly hidden in the composition liquid, or may be immersed for a long time. At this time, you may lengthen the processing time by this composition, so that the density | concentration of an acetic acid and sodium acetate is high. For example, when using a composition liquid having an acetic acid concentration of 1% by mass or more and 2% by mass or less, a treatment time of 5 seconds or more and 30 seconds is required to obtain a sufficient bacteriostatic effect without changing the original flavor and texture of the food. Preferably it is less than or equal to minutes. More preferably, it is 30 seconds or more and 15 minutes or less. Moreover, when using the composition liquid whose acetic acid density | concentration is 0.1 to 0.2 mass%, it is preferable that processing time is 12 hours or more.
一方、本組成物を食品中に添加する場合、処理温度や組成物の添加量等の各条件は特に限定せず、用いる食品の種類や調理方法、組成物の濃度等に応じて適宜設定できる。食品への添加の形態は特に限定しない。本組成物が液状体の場合、例えば、食品がひたひたになる程度に本組成物を添加してもよいし、あるいは、少量の本組成物を食品にかけた程度であってもよい。また、本組成物が粉末状の場合、食品にふりかけたり、まぶしたりしてもよい。食品本来の風味を変化させないようにしつつ十分な静菌効果を得るには、食品中の酢酸濃度が0.1質量%以上0.2質量%以下になるよう添加することが好ましく、0.10質量%以上0.12質量%以下であることがより好ましい。 On the other hand, when this composition is added to food, the conditions such as the treatment temperature and the amount of the composition added are not particularly limited, and can be appropriately set according to the type of food used, the cooking method, the concentration of the composition, etc. . The form of addition to food is not particularly limited. When the present composition is a liquid, for example, the present composition may be added to such an extent that the food becomes depleted, or a small amount of the present composition may be applied to the food. Moreover, when this composition is a powder form, you may sprinkle on foodstuffs or may apply. In order to obtain a sufficient bacteriostatic effect without changing the original flavor of the food, it is preferable to add the acetic acid in the food so that the concentration of acetic acid is 0.1% by mass or more and 0.2% by mass or less. More preferably, it is at least 0.12% by mass.
(静菌用組成物を含む食品)
本発明の食品は、上述した本発明の静菌用組成物を含むものである。したがって、本食品は、保存性に非常に優れている。特に、食肉や水産物などのように、細菌等が非常に増殖しやすい生鮮食材を好ましく用いることができる。
(Food containing bacteriostatic composition)
The food of the present invention comprises the above-mentioned bacteriostatic composition of the present invention. Therefore, this food is very excellent in preservability. In particular, a fresh food material such as a meat or a fishery product in which bacteria and the like are easily proliferated can be preferably used.
本発明の食品が静菌用組成物を含む形態は特に限定しない。例えば、浸漬、噴霧、塗布又は添加等により食品中に静菌用組成物を含有させてもよい。あるいは、本組成液を用いて調理又は半調理してもよい。好ましくは、本組成物中に食品を浸漬するか、あるいは本組成物を食品に添加したものである。 The form in which the food of the present invention contains a bacteriostatic composition is not particularly limited. For example, the bacteriostatic composition may be contained in the food by dipping, spraying, coating, or addition. Or you may cook or semi-cooking using this composition liquid. Preferably, the food is immersed in the composition or the composition is added to the food.
本食品は、上述した本組成物の液状体に浸した状態で提供されてもよいし、食品の表面の一部又は全部を本組成物で濡らしただけの状態で提供されてもよい。なお、ここでいう「本組成物に浸した状態」とは、食品の一部又は全部が本組成物に浸された状態であればよく、例えば、和え物やおひたしなども含む。 The food may be provided in a state of being dipped in the liquid of the composition described above, or may be provided in a state in which a part or all of the surface of the food is only wetted with the composition. The “state dipped in the present composition” herein may be a state in which a part or all of the food is dipped in the present composition, and includes, for example, seasoned foods and meals.
本食品が本組成物に浸けた状態で提供される場合、加工食品中の酢酸濃度及び酢酸ナトリウム濃度は、食品に施す酸味の程度に応じて適宜設定すればよい。食品本来の風味を変化させないようにしつつ十分な静菌効果を得るには、加工食品中の酢酸濃度が0.1質量%以上0.2質量%以下であることが好ましく、0.10質量%以上0.12質量%以下であることがより好ましい。 When the present food is provided in a state of being soaked in the present composition, the acetic acid concentration and sodium acetate concentration in the processed food may be appropriately set according to the degree of sourness applied to the food. In order to obtain a sufficient bacteriostatic effect without changing the original flavor of the food, the acetic acid concentration in the processed food is preferably 0.1% by mass or more and 0.2% by mass or less, and 0.10% by mass. More preferably, it is 0.12 mass% or less.
本発明の食品は、用いる食材の全部が本組成物を含むものであってもよいし、複数の食材のうちの一部が本組成物を含むものであってもよい。本組成物を含む食材であれば、常温でも優れた保存性を有することから、低温での保存により食感や風味が低下しやすい食材(例えば、炊飯米や餅など)と一緒に提供することができる。すなわち、生鮮食材などのように、通常、低温(例えば、4℃以下)で保存される食材であっても、本組成物を含むことにより常温での保存が可能なため、低温での保存に適さない食材と組み合わせた場合には、その食品は常温での保存が可能になる。したがって、このような食品に対しても、良好な風味と保存性とを兼ね備えさせることができる。 As for the foodstuff of this invention, all the ingredients to be used may contain this composition, and one part of several foodstuffs may contain this composition. If it is a food containing this composition, it has excellent storability even at room temperature, so it should be provided together with a food (such as cooked rice or rice bran) whose texture and flavor tend to be reduced by storage at low temperatures. Can do. That is, even if the food is normally stored at a low temperature (for example, 4 ° C. or lower) such as fresh food, it can be stored at room temperature by including this composition, so it can be stored at a low temperature. When combined with unsuitable ingredients, the food can be stored at room temperature. Therefore, even such foods can have both a good flavor and storage stability.
このような形態としては、例えば、弁当などのように、種々の食材が組み合わされたものに好ましく適用することができる。本組成物を含む食材としては、加熱に適さない食材(例えば、刺身など)を用いることが好ましい。本組成物を含むことにより、常温での保存が可能になるため、例えば、鉄火丼やてこね寿司などのように、加熱が不適な具材と、低温での保存が不適な炊飯米とが組み合わされたものであっても、保存性と風味との両者を良好に維持することができる。 As such a form, it can apply preferably to what combined various foodstuffs, such as a lunch box, for example. As the food material containing the present composition, it is preferable to use a food material (eg, sashimi) that is not suitable for heating. By including this composition, it becomes possible to store at room temperature.For example, ingredients that are not suitable for heating, such as iron-fired salmon and tetsune sushi, and cooked rice that is not suitable for storage at low temperatures. Even if it is combined, both the storage stability and the flavor can be maintained well.
なお、本発明の加工食品は、従来食品に適用されている保存加工又は包装を施すことができる。例えば、冷凍食品、冷蔵食品、レトルトパウチ品、缶詰、凍結乾燥品、真空包装品等とすることができる。 In addition, the processed food of this invention can give the preservation | save processing or packaging currently applied to the foodstuff. For example, frozen foods, refrigerated foods, retort pouch products, canned foods, freeze-dried products, vacuum packaged products, and the like can be used.
(食品の製造方法)
本発明の食品の製造方法は、本発明の静菌用組成物で食品を処理する処理工程を備えるものである。本製造方法における組成物には、既に説明した本発明の組成物において用いられる成分や用途などをそのまま適用することができる。したがって、本製造方法によれば、微生物が非常に繁殖しやすい食品に対しても十分な防腐効果が付与された食品を製造することができる。
(Food manufacturing method)
The manufacturing method of the foodstuff of this invention is equipped with the process process which processes foodstuffs with the bacteriostatic composition of this invention. The components and uses used in the composition of the present invention described above can be applied as they are to the composition in the production method. Therefore, according to this production method, it is possible to produce a food that has a sufficient antiseptic effect even with respect to foods in which microorganisms are very easy to reproduce.
以下、本発明を具体例を挙げて説明するが、本発明は以下に例示する具体例に限定されるものではない。 Hereinafter, the present invention will be described with specific examples. However, the present invention is not limited to the specific examples illustrated below.
[静菌用組成物の調製]
酢酸濃度が1%、酢酸ナトリウム濃度が0〜10%の各整数値となる11種の静菌用組成物を調製した。静菌用組成物の調製は、上記各濃度になるよう、市販の業務用食酢(酢酸濃度10%、内堀醸造社製)と炭酸水素ナトリウムとを蒸留水に加えることにより行った。これにより、実施例1及び比較例1〜10の静菌用組成物を得た。
[Preparation of bacteriostatic composition]
Eleven types of bacteriostatic compositions having an integer value of 1% acetic acid and 0-10% sodium acetate were prepared. The bacteriostatic composition was prepared by adding commercially available vinegar for commercial use (acetic acid concentration 10%, manufactured by Uchibori Shuzo Co., Ltd.) and sodium hydrogen carbonate to distilled water so as to achieve the above-mentioned concentrations. This obtained the bacteriostatic composition of Example 1 and Comparative Examples 1-10.
[本組成物による加工食品の製造]
得られた各静菌用組成物(実施例1及び比較例1〜10)を用いて食品の静菌処理を行った。具体的には、生の白身魚(鯛)1kgを水で丁寧に洗浄したのち10gの大きさにスライスし、これを試料として用いた。スライスした試料の一片(10g)を各静菌用組成物1L中に室温でさっと潜らせ、10℃で48時間保存した。その後、試料を生理食塩水90ml中に入れ、ストマッカーで30秒間破砕して懸濁液を得た。懸濁液1mlを生理食塩水で希釈したのち、この希釈液1mlを一般生菌、大腸菌群及び乳酸菌のそれぞれに対する選択分離培地(日水製薬社製)に加え、38℃で48時間恒温器で培養した。その後、資料1gあたりの一般生菌数、大腸菌群数及び乳酸菌数を測定した。これらの結果を表1に示す。
[Production of processed foods with this composition]
The bacteriostatic treatment of the food was performed using each of the obtained bacteriostatic compositions (Example 1 and Comparative Examples 1 to 10). Specifically, 1 kg of raw white fish (fish) was carefully washed with water and then sliced to a size of 10 g and used as a sample. A slice (10 g) of the sliced sample was quickly submerged in 1 L of each bacteriostatic composition at room temperature and stored at 10 ° C. for 48 hours. Thereafter, the sample was put in 90 ml of physiological saline and crushed with a stomacher for 30 seconds to obtain a suspension. After diluting 1 ml of the suspension with physiological saline, 1 ml of this diluted solution is added to a selective separation medium (manufactured by Nissui Pharmaceutical Co., Ltd.) for each of general viable bacteria, coliform bacteria and lactic acid bacteria, and incubated at 38 ° C. for 48 hours. Cultured. Thereafter, the number of general viable bacteria, coliforms and lactic acid bacteria per gram of the material was measured. These results are shown in Table 1.
表1に示すように、実施例1(酢酸濃度1%、酢酸ナトリウム濃度10%)では、一般生菌数、大腸菌群数及び乳酸菌数のすべてにおいて菌数が10以下であり、試料の褐変も起きなかった。これに対し、比較例1〜9では、大腸菌群数は10以下に抑制されたものの、一般生菌数及び乳酸菌数は、いずれも102以上となった。また、比較例10においては、一般生菌数、大腸菌群数及び乳酸菌数のすべてにおいて103以上となった。これらのことから、酢酸と酢酸ナトリウムとを質量比1:10で含有する静菌用組成物は、食品に対して優れた静菌効果を付与できることがわかった。この静菌効果は、乳酸菌において良好な結果が得られた。さらに、本組成物は、刺身等のように非常に腐りやすい食品に対しても良好な静菌効果を付与できることがわかった。 As shown in Table 1, in Example 1 (acetic acid concentration 1%, sodium acetate concentration 10%), the number of bacteria in all of the general viable cell count, coliform group count and lactic acid bacteria count is 10 or less, and the browning of the sample also I didn't get up. On the other hand, in Comparative Examples 1-9, although the number of coliforms was suppressed to 10 or less, the number of general viable bacteria and the number of lactic acid bacteria were both 10 2 or more. In Comparative Example 10, the number of general viable bacteria, coliforms, and lactic acid bacteria was 10 3 or more. From these results, it was found that a bacteriostatic composition containing acetic acid and sodium acetate in a mass ratio of 1:10 can impart an excellent bacteriostatic effect on food. This bacteriostatic effect was good for lactic acid bacteria. Furthermore, this composition was found to be able to impart a good bacteriostatic effect even to foods that are very perishable, such as sashimi.
実施例2においては、実施例1で良好な静菌結果が得られた静菌用組成物(酢酸1%、酢酸ナトリウム10%)を用いて、実施例1とは異なる食品の静菌処理を行った。試料としては、マグロ1kgを水で丁寧に洗浄したのち10gの大きさにスライスしたものを用いた。この試料1Kgに対し、実施例1の静菌用組成物5L中に18℃で浸漬して静菌処理を施した。浸漬時間は、それぞれ0分、1分、10分、15分とした。浸漬時間が経過したのち、実施例1と同様にして一般生菌数、大腸菌群数及び乳酸菌数を測定した。なお、本実施例では、保存温度を10℃又は室温とした。また、保存温度を10℃としたときの試料の褐変の発生状況についても観察した。これらの結果を表2に示す。 In Example 2, the bacteriostatic treatment of food different from Example 1 was carried out using the bacteriostatic composition (acetic acid 1%, sodium acetate 10%) from which good bacteriostatic results were obtained in Example 1. went. As a sample, 1 kg of tuna was carefully washed with water and then sliced to a size of 10 g. Bacteriostatic treatment was performed on 1 kg of this sample by dipping in 5 L of the bacteriostatic composition of Example 1 at 18 ° C. The immersion times were 0 minutes, 1 minute, 10 minutes, and 15 minutes, respectively. After the immersing time, the number of viable bacteria, the number of coliforms and the number of lactic acid bacteria were measured in the same manner as in Example 1. In this example, the storage temperature was 10 ° C. or room temperature. Further, the occurrence of browning of the sample when the storage temperature was 10 ° C. was also observed. These results are shown in Table 2.
表2に示すように、実施例1の静菌用組成物中に浸漬した場合(浸漬時間1分、10分、15分)、いずれにおいても、一般生菌数及び大腸菌群数は102〜103のオーダーであり、乳酸菌数は10〜100程度であった。このような静菌効果は、静菌用組成物での処理後の保存温度が10℃の場合にも室温の場合にも見られた。また、10℃で保存したときには、試料の褐変も発生せず、マグロ独特の新鮮な赤みを呈していた。これに対し、静菌用組成物中に浸漬しなかった場合(浸漬時間0分)には、10℃で保存したときには試料の褐変は起きなかったものの、一般生菌数、大腸菌群数及び乳酸菌数は、多数の菌が増殖し測定不能であった。これらのことから、本発明の静菌用組成物は、食品に対して優れた静菌効果を付与できることがわかった。また、浸漬処理が短時間であっても食品の保存性を十分に向上できることがわかった。 As shown in Table 2, when immersed in the bacteriostatic composition of Example 1 (immersion time 1 minute, 10 minutes, 15 minutes), the number of general viable bacteria and the number of E. coli groups were 10 2 to The order was 10 3 and the number of lactic acid bacteria was about 10-100. Such a bacteriostatic effect was observed both when the storage temperature after treatment with the bacteriostatic composition was 10 ° C. and at room temperature. Moreover, when it preserve | saved at 10 degreeC, the browning of the sample did not generate | occur | produce and the tuna peculiar fresh redness was exhibited. In contrast, when not immersed in the bacteriostatic composition (immersion time 0 minutes), the sample did not brown when stored at 10 ° C., but the number of general viable bacteria, coliforms and lactic acid bacteria The number was not measurable due to the growth of many bacteria. From these results, it was found that the bacteriostatic composition of the present invention can impart an excellent bacteriostatic effect to foods. In addition, it was found that the preservability of food can be sufficiently improved even if the immersion treatment is performed for a short time.
実施例3においては、くきわかめ1Kg及びしらうお1Kgを混合し、これを試料として用いた。この試料中に実施例1の静菌用組成物200mlを加えてかき混ぜ、組成物中に漬け込んだ。その後、保存時間を24時間及び48時間とした以外は実施例1と同様にして一般生菌数及び大腸菌群数を測定した。また、試料の褐変の発生状況についても観察した。その結果を表3に示す。 In Example 3, 1 kg of Kukiwakame and 1 kg of shirauo were mixed and used as a sample. In this sample, 200 ml of the bacteriostatic composition of Example 1 was added, stirred, and immersed in the composition. Thereafter, the number of viable bacteria and the number of coliforms were measured in the same manner as in Example 1 except that the storage time was 24 hours and 48 hours. In addition, the occurrence of browning of the sample was also observed. The results are shown in Table 3.
表3に示すように、一般生菌数及び大腸菌群数は102〜103程度であった。菌数については、保存期間が24時間のときよりも48時間のときの方が多かったが、試料の褐変は両者において発生しなかった。この結果から、保存時間が長いほど細菌が増殖する傾向にあるものの、48時間が経過した後であっても優れた静菌効果を得ることができることがわかった。 As shown in Table 3, the number of general viable bacteria and coliforms was about 10 2 to 10 3 . Regarding the number of bacteria, the storage period was 48 hours more than 24 hours, but the browning of the samples did not occur in both cases. From this result, it was found that although the bacterium has a tendency to grow as the storage time increases, an excellent bacteriostatic effect can be obtained even after 48 hours.
実施例4においては、生かき1Kgを試料として用いた。この試料中に実施例1の静菌用組成物100mlを加え、組成物中に漬け込んだ。その後、保存時間を24時間及び48時間とした以外は実施例1と同様にして一般生菌数及び大腸菌群数を測定した。また、試料の褐変の発生状況についても観察した。その結果を表4に示す。 In Example 4, 1 kg of raw kaki was used as a sample. 100 ml of the bacteriostatic composition of Example 1 was added to this sample and immersed in the composition. Thereafter, the number of viable bacteria and the number of coliforms were measured in the same manner as in Example 1 except that the storage time was 24 hours and 48 hours. In addition, the occurrence of browning of the sample was also observed. The results are shown in Table 4.
表4に示すように、一般生菌数及び大腸菌群数は102又は103のオーダーであった。菌数については、保存期間が24時間のときよりも48時間のときの方が多かったが、試料の褐変は両者において発生しなかった。この結果から、保存時間が長いほど細菌が増殖する傾向にあるものの、48時間が経過した後であっても十分な静菌効果を得ることができることがわかった。 As shown in Table 4, viable cell count and the number of the coliform bacteria were on the order of 10 2 or 10 3. Regarding the number of bacteria, the storage period was 48 hours more than 24 hours, but the browning of the samples did not occur in both cases. From this result, it was found that although the bacteria tend to grow as the storage time increases, a sufficient bacteriostatic effect can be obtained even after 48 hours.
実施例5においては、高野豆腐(乾燥した状態で1Kgずつ)を試料として用いた。また、静菌用組成物としては、調味成分(醤油、みりん、化学調味料、上白糖を使用)を含む調味液としての実施例1及び比較例5(酢酸濃度1%、酢酸ナトリウム濃度5%)を用いた。さらに、比較例として、静菌用組成物を含まない調味液を用意した。まず、各調味液5L中に試料を浸漬し、45分間蒸煮した。これにより、試料は5Kgとなった。この試料10gを用い、保存温度を35℃とした以外は実施例1と同様にして一般生菌数及び乳酸菌群数を測定した。その結果を表5に示す。 In Example 5, Koya tofu (1 kg each in a dry state) was used as a sample. In addition, as a bacteriostatic composition, Example 1 and Comparative Example 5 (acetic acid concentration 1%, sodium acetate concentration 5%) as seasonings containing seasoning ingredients (use soy sauce, mirin, chemical seasoning, and super white sugar) ) Was used. Furthermore, as a comparative example, a seasoning liquid not containing the bacteriostatic composition was prepared. First, the sample was immersed in 5 L of each seasoning liquid and cooked for 45 minutes. Thereby, the sample became 5 kg. Using 10 g of this sample, the number of viable bacteria and the number of lactic acid bacteria were measured in the same manner as in Example 1 except that the storage temperature was 35 ° C. The results are shown in Table 5.
表5に示すように、実施例1の静菌用組成物では、一般生菌数が9.4×102、乳酸菌群数が9.4×10であった。これに対し、比較例5の静菌用組成物では、一般生菌数が5.0×106、乳酸菌群数が5.0×105であり、実施例1の静菌用組成物を用いた場合に比べて105倍以上の菌が増殖した。また、静菌用組成物を含まない場合には、一般生菌数及び乳酸菌数は、多数の菌が増殖し測定不能であった。これらの結果から、酢酸と酢酸ナトリウムとを質量比1:10で含有する静菌用組成物(実施例1)は、両者を1:5の質量比で含有する静菌用組成物(比較例5)よりも、食品に対して優れた静菌効果を付与できることがわかった。また、惣菜に適用した場合にも、優れた静菌効果が得られることがわかった。 As shown in Table 5, the bacteriostatic composition of Example 1 had a general viable count of 9.4 × 10 2 and a lactic acid bacteria count of 9.4 × 10. In contrast, the bacteriostatic composition of Comparative Example 5 had a general viable count of 5.0 × 10 6 and a lactic acid bacteria group count of 5.0 × 10 5 , and the bacteriostatic composition of Example 1 More than 10 5 times as many bacteria as compared with the case of using. When the bacteriostatic composition was not included, the number of general viable bacteria and lactic acid bacteria could not be measured due to the growth of many bacteria. From these results, the bacteriostatic composition (Example 1) containing acetic acid and sodium acetate in a mass ratio of 1:10 is a bacteriostatic composition (comparative example) containing both in a mass ratio of 1: 5. It was found that an excellent bacteriostatic effect can be imparted to food than 5). It was also found that an excellent bacteriostatic effect can be obtained when applied to sugar beet.
Claims (13)
酢酸1質量部に対して酢酸ナトリウムを9質量部を超えて13質量部以下含有する、組成物。 A bacteriostatic composition for foods,
The composition which contains 13 mass parts or less of sodium acetate exceeding 9 mass parts with respect to 1 mass part of acetic acid.
請求項1〜5のいずれかに記載の組成物又は請求項6に記載の調味液を用いて食品を処理する処理工程、を備える、静菌方法。 A bacteriostatic method of food,
A bacteriostatic method comprising a treatment step of treating a food using the composition according to any one of claims 1 to 5 or the seasoning liquid according to claim 6.
前記食品中の酢酸濃度が0.1質量%以上0.2質量%以下である、請求項10又は11に記載の食品。 The food is in a state immersed in the composition or the seasoning liquid as a liquid,
The foodstuff of Claim 10 or 11 whose acetic acid concentration in the said foodstuff is 0.1 to 0.2 mass%.
請求項1〜5のいずれかに記載の組成物又は請求項6に記載の調味液を用いて食品を処理する処理工程、を備える、製造方法。 A method for producing food,
A manufacturing method provided with the process of processing a foodstuff using the composition in any one of Claims 1-5, or the seasoning liquid of Claim 6.
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| JP2023003562A (en) * | 2021-06-24 | 2023-01-17 | キユーピー株式会社 | Method for producing packed boiled eggs |
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