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JP2009016570A - Method for producing transparent electromagnetic shielding member - Google Patents

Method for producing transparent electromagnetic shielding member Download PDF

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JP2009016570A
JP2009016570A JP2007176578A JP2007176578A JP2009016570A JP 2009016570 A JP2009016570 A JP 2009016570A JP 2007176578 A JP2007176578 A JP 2007176578A JP 2007176578 A JP2007176578 A JP 2007176578A JP 2009016570 A JP2009016570 A JP 2009016570A
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shielding member
electromagnetic wave
wave shielding
transparent
pattern
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Yuichi Miyazaki
祐一 宮崎
Hideki Imamura
秀機 今村
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Dai Nippon Printing Co Ltd
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Abstract

【課題】透明基材上に導電性インキを用いた印刷によるメッシュパターンをベースにして、プラズマディスプレイの前面などに用いることができる電磁波シールド性の高い透明性を有する電磁波シールド部材の製造方法、及び電磁波シールド部材を提供すること。
【解決手段】透明基材上に導電性インキを用いて印刷により、開口部を囲繞する線部を平面内において2次元配列してなるメッシュパターンが形成された電磁波シールド用部材の製造方法であって、該パターン印刷面に対し垂直な方向の磁界をかけることで誘導加熱処理を行う、透明性を有する電磁波シールド部材の製造方法、及び該製造方法で得られる電磁波シールド部材である。
【選択図】なし
A method for producing an electromagnetic wave shielding member having a high electromagnetic wave shielding property, which can be used on the front surface of a plasma display, etc., based on a mesh pattern obtained by printing using a conductive ink on a transparent substrate, and To provide an electromagnetic shielding member.
A method for manufacturing an electromagnetic shielding member in which a mesh pattern formed by two-dimensionally arranging line portions surrounding an opening portion in a plane by printing using a conductive ink on a transparent substrate is provided. Thus, there are a method for producing a transparent electromagnetic wave shielding member that performs induction heating treatment by applying a magnetic field in a direction perpendicular to the pattern printing surface, and an electromagnetic wave shielding member obtained by the production method.
[Selection figure] None

Description

本発明は、各種ディスプレイの前面に配置する透明性を有する電磁波シールド部材の製造方法に関する。   The present invention relates to a method for manufacturing a transparent electromagnetic wave shielding member disposed on the front surface of various displays.

PDP(プラズマディスプレイパネル)、CRT(ブラウン管)ディスプレイ等、各種画像表示装置(ディスプレイ)から発生する電磁波をシールドするために、ディスプレイの前面に実質的に透明な電磁波シールド部材が配置される。
そのような実質透明な電磁波シールド部材として代表的なものは、銀、ITO(酸化インジウム錫)等のスパッタ薄膜からなる透明導電体薄膜(特許文献1参照)、銅等の高導電性金属粒子とバインダー樹脂からなる導電性インキ(導電性ペースト)を印刷してストライプ(平行線群)状に形成してなる導電性インキパターン印刷物(特許文献2参照)などがある。これらのうち、銀スパッタ薄膜はコストが高く、また全面を被覆しているため電磁波遮蔽性(導電性)を高めようと厚膜化すると透明性が低下し、又透明性を高めようと薄膜化すると逆に電磁波遮蔽性(導電性)が低下し、透明性と電磁波遮蔽性との両立性に劣る。
一方、導電性インキパターン印刷物は開口部分があるため透明性は高い。しかし、高導電性物質の銀粒子同士の接触を電気絶縁性のバインダー樹脂が遮断するため、銀本来の高導電性が発揮されないという問題があった。
また、このバインダー樹脂による、導電性インキ自体の導電性低下を改善する方法として、透明基材上に、金属微粒子とバインダー樹脂とからなる導電性インキを塗布してメッシュパターンを形成し、焼成するという方法は以前からあり、焼成することで絶縁体であるバインダー樹脂を除去して金属微粒子同士が接触し、更に金属微粒子同士が融着して抵抗が下がるためシールド性が改善される。しかし、透明性基材にも高熱がかかるため、ガラス基板や耐熱性フィルムなどを基材とするものに限定され、コスト高であった。
また、導電性インキを加熱して導電性を向上させる方法において、基材への熱の影響を最小化出来る方法として、絶縁体基材上に金属成分と有機成分からなる粒子を主成分とする金属コロイド液を塗布、乾燥して形成された金属微粒子を含有する導電性塗膜に通電しそのジュール熱で焼結するという導電性被膜の作製方法(特許文献3参照)が開示されており、通電方法としては誘導電流が適用可能と記載されている。しかし現実には、かかる方法は、全面ベタ(全面にわたって被覆する形態を言う)で形成された塗膜に対しては十分な渦電流が流れるため、有効性を発揮する。しかし、前記の如く全面ベタでは透明性がないため、さらに、本願発明者らが試作実験を試みた結果、図1(d)に示すような透視性の細線パターン形状について適用しようとした場合には、次に説明するように、原理的に誘導電流による加熱をすることはできない場合が有ることが判明した。
ここで、誘導加熱について図1に基づいて簡単に説明する。一般に、ある程度厚みのある金属板を加熱する場合、図1(a)に示すように板面に平行な磁界をかけると、板の断面の外周を一周するように渦電流が流れ発熱するが、金属板の厚みが数十μm程度の薄さになると、図1(b)に示すように板の表裏で流れる電流が相殺してしまい、加熱が難しくなる。したがって、金属箔を加熱する場合は図1(c)に示すように箔面に垂直な磁界をかけ、箔の面内を渦電流が流れるようにする必要がある。しかしながら、透視性の電磁波遮蔽用に平行線群パターンの如く導電性インキ層を細く薄い線に形成した場合では、図1(d)に示すように、線内で電流が相殺して加熱ができないという問題があることが判明した。
In order to shield electromagnetic waves generated from various image display devices (displays) such as a PDP (plasma display panel) and a CRT (CRT) display, a substantially transparent electromagnetic wave shielding member is disposed on the front surface of the display.
Typical examples of such a substantially transparent electromagnetic wave shielding member include transparent conductive thin films made of sputtered thin films such as silver and ITO (indium tin oxide) (see Patent Document 1), highly conductive metal particles such as copper, and the like. There is a printed conductive ink pattern (see Patent Document 2) formed by printing a conductive ink (conductive paste) made of a binder resin to form a stripe (parallel line group). Of these, the sputtered silver thin film is expensive, and since it covers the entire surface, transparency increases when the film is thickened to increase electromagnetic wave shielding (conductivity), and thinned to increase transparency. Then, on the contrary, the electromagnetic wave shielding property (conductivity) is lowered, and the compatibility between transparency and electromagnetic wave shielding property is inferior.
On the other hand, since the printed conductive ink pattern has an opening, the transparency is high. However, since the electrically insulating binder resin blocks the contact between silver particles of a highly conductive material, there is a problem that the high conductivity inherent to silver is not exhibited.
Also, as a method for improving the decrease in the conductivity of the conductive ink itself due to the binder resin, a conductive ink composed of metal fine particles and a binder resin is applied on a transparent substrate to form a mesh pattern, followed by firing. This method has been used for a long time, and by firing, the binder resin, which is an insulator, is removed and the metal fine particles come into contact with each other. However, since high heat is applied to the transparent base material, it is limited to those using a glass substrate or a heat resistant film as a base material, and the cost is high.
In addition, in a method for improving conductivity by heating conductive ink, as a method for minimizing the influence of heat on the substrate, particles composed of a metal component and an organic component are mainly used on an insulator substrate. A method for producing a conductive coating (see Patent Document 3) is disclosed in which a conductive coating containing metal fine particles formed by applying and drying a metal colloid liquid is energized and sintered by its Joule heat. As an energization method, it is described that an induced current is applicable. However, in reality, this method is effective because a sufficient eddy current flows for a coating film formed with a solid surface (referring to a form covering the entire surface). However, as described above, since the entire surface is not transparent, the inventors of the present application have tried a prototype experiment, and as a result, when trying to apply to a transparent thin line pattern shape as shown in FIG. As described below, it has been found that there is a case where heating by an induced current cannot be performed in principle.
Here, induction heating will be briefly described with reference to FIG. In general, when heating a metal plate having a certain thickness, when a magnetic field parallel to the plate surface is applied as shown in FIG. 1 (a), an eddy current flows around the outer periphery of the cross section of the plate to generate heat. When the thickness of the metal plate is about several tens of μm, the currents flowing on the front and back of the plate cancel each other as shown in FIG. 1B, and heating becomes difficult. Therefore, when heating the metal foil, it is necessary to apply a magnetic field perpendicular to the foil surface as shown in FIG. 1C so that an eddy current flows in the surface of the foil. However, in the case where the conductive ink layer is formed in a thin and thin line like a parallel line group pattern for shielding transparent electromagnetic waves, as shown in FIG. It turned out that there was a problem.

特開平5−323101号公報JP-A-5-323101 特許第3425400号Japanese Patent No. 3425400 特開2004−79243号公報JP 2004-79243 A

透明基材上に導電性インキを用いた印刷による細線パターンをベースにして、プラズマディスプレイの前面などに用いることができる高い導電性を有する電磁波シールド部材の製造方法を提供することを目的とする。   An object of the present invention is to provide a method for producing an electromagnetic shielding member having high conductivity that can be used on the front surface of a plasma display, etc., based on a thin line pattern obtained by printing using a conductive ink on a transparent substrate.

本発明者らは、透明基材上に導電性インキを用いて、細線からなる光透過領域のある実質的に透明なパターンを印刷するに当り、印刷パターンとしては、渦(うず)電流加熱の際に閉回路をなす様に、開口部を囲繞する線部をその構成単位とし、しかも該構成単位を2次元方向に配列したメッシュ(網目)構造とすることにより、印刷面内全面で渦電流が均一な分布で流れるようにメッシュ面に直交する方向に交流磁界を掛けて誘導加熱を行うことで、透明基材への熱の影響を最小限化した上で、導電性インキを集中的に且つ全面均一に加熱して、金属粒子同士を接触部において溶着せしめて、導電性材料の電気抵抗を下げシールド性を向上できること、即ち、ミクロ的に見た時の導電性パターンの線が細くとも、マクロ的に見て2次元的に均一なメッシュ状の導電性パターンを選択し、且つ渦電流が該メッシュ面内において流れる様にするのであれば、線幅が数μm〜数十μmの線で構成されたメッシュ構造であっても、誘導加熱が可能であることを見出し、本発明を完成した。 When printing a substantially transparent pattern having a light transmission region composed of fine lines using a conductive ink on a transparent substrate, the present inventors have used a eddy current heating as a printing pattern. In order to form a closed circuit, the line portion surrounding the opening is a structural unit, and a mesh (mesh) structure in which the structural units are arranged in a two-dimensional direction makes it possible to generate eddy currents over the entire printed surface. Inductive heating is performed by applying an alternating magnetic field in a direction perpendicular to the mesh surface so that the ink flows in a uniform distribution, and the conductive ink is concentrated while minimizing the effect of heat on the transparent substrate. In addition, it is possible to heat the entire surface uniformly so that the metal particles are welded to each other at the contact portion, thereby reducing the electric resistance of the conductive material and improving the shielding property, that is, even if the conductive pattern line is thin when viewed microscopically. , Macroscopically and two-dimensionally If a single mesh-like conductive pattern is selected and an eddy current is allowed to flow in the mesh plane, even a mesh structure composed of lines with a line width of several μm to several tens of μm The inventors have found that induction heating is possible and completed the present invention.

すなわち本発明は、
(1)透明基材上に導電性インキを用いて印刷により、開口部を囲繞する線部を平面内において2次元配列してなるメッシュパターンが形成された電磁波シールド用部材の製造方法であって、該パターン印刷面に対して、垂直な方向の磁界をかけることで誘導加熱処理を行うことを特徴とする透明性を有する電磁波シールド部材の製造方法、
(2)導電性インキが、金、銀、銅、鉄、ニッケル、又はアルミニウムの金属微粒子を含んでいる前記(1)に記載の透明性を有する電磁波シールド部材の製造方法、
(3)透明基材上に、固形分100質量部のうち金属微粒子40〜99質量部を均一分散させた、固形分20〜90質量パーセントの導電性インキを用いて印刷し、溶剤を乾燥した後、誘導加熱処理を行うことを特徴とする前記(2)に記載の透明性を有する電磁波シールド部材の製造方法、
(4)透明基材の少なくとも印刷される側の面に、下地層が存在している前記(1)〜(3)のいずれかに記載の電磁波シールド部材の製造方法、
(5)透明基材が樹脂フィルムであり、誘導加熱装置に対してロールトゥロールで連続的に通過させる前記(1)〜(4)のいずれかに記載の透明性を有する電磁波シールド部材の製造方法、
(6)透明基材がポリエチレンテレフタレートフィルムである前記(5)に記載の透明性を有する電磁波シールド部材の製造方法、及び
(7)前記(1)〜(6)のいずれかに記載の製造方法で得られた透明性を有する電磁波シールド部材、
を提供するものである。
That is, the present invention
(1) An electromagnetic shielding member manufacturing method in which a mesh pattern formed by two-dimensionally arranging line portions surrounding an opening portion in a plane by printing using a conductive ink on a transparent substrate is provided. A method of manufacturing a transparent electromagnetic wave shielding member, wherein induction heating treatment is performed by applying a magnetic field in a perpendicular direction to the pattern printing surface,
(2) The method for producing a transparent electromagnetic wave shielding member according to (1), wherein the conductive ink contains metal fine particles of gold, silver, copper, iron, nickel, or aluminum,
(3) On the transparent substrate, printing was performed using conductive ink having a solid content of 20 to 90 mass percent, in which 40 to 99 mass parts of metal fine particles were uniformly dispersed in 100 mass parts of solid content, and the solvent was dried. Thereafter, induction heating treatment is performed, the method for producing a transparent electromagnetic wave shielding member according to (2),
(4) The method for producing an electromagnetic wave shielding member according to any one of (1) to (3), wherein a base layer is present on at least a surface of the transparent substrate to be printed,
(5) Manufacture of the electromagnetic wave shielding member which has transparency in any one of said (1)-(4) which a transparent base material is a resin film, and lets it pass continuously with a roll-to-roll with respect to an induction heating apparatus. Method,
(6) The manufacturing method of the electromagnetic wave shielding member having transparency according to (5), wherein the transparent substrate is a polyethylene terephthalate film, and (7) the manufacturing method according to any one of (1) to (6). An electromagnetic shielding member having transparency obtained in
Is to provide.

透明基材の上に、導電性粒子を含有する導電性インキを用いたメッシュ(網目)状の導電性パターンを形成し、誘導加熱による熱処理で電気抵抗を下げることで、透明性と電磁波遮蔽性とが両立する。また、本発明の製造方法は瞬間加熱が可能であるため、加熱装置の予備時間が必要でなく、また発熱効率が高いため、加熱工程でのランニングコストを抑えることができる。しかも導電性インキ層のみを直接加熱するため、透明基材に与える熱
の影響を最小化できる。
By forming a mesh-like conductive pattern using conductive ink containing conductive particles on a transparent substrate, and reducing the electrical resistance by heat treatment by induction heating, transparency and electromagnetic wave shielding And both. In addition, since the production method of the present invention can be instantaneously heated, the preliminary time of the heating device is not required, and since the heat generation efficiency is high, the running cost in the heating process can be suppressed. In addition, since only the conductive ink layer is directly heated, the influence of heat on the transparent substrate can be minimized.

本発明の透明性を有する電磁波シールド部材の製造方法は、透明基材上に導電性インキを用いて印刷により、開口部を囲繞する線部を平面内において2次元配列してなるメッシュパターンが形成された電磁波シールド用透明部材の製造方法であって、該パターン印刷面に対し垂直な方向の磁界をかけることで誘導加熱処理を行うものである。
以下、本発明を詳細に説明する。
According to the method for producing a transparent electromagnetic shielding member of the present invention, a mesh pattern formed by two-dimensionally arranging line portions surrounding an opening portion in a plane is formed by printing using a conductive ink on a transparent substrate. In this method for producing an electromagnetic wave shielding transparent member, induction heating treatment is performed by applying a magnetic field in a direction perpendicular to the pattern printing surface.
Hereinafter, the present invention will be described in detail.

〔透明基材〕
透明基材としては、少なくとも可視光線領域で透明な基材が使用可能であり、ポリエチレンテレフタレート(PET)、ポリエチレンナフタレート(PEN)等のポリエステル樹脂、ポリアクリル酸メチル、ポリメタクリル酸メチル等のアクリル樹脂、ポリカーボネート(PC)、ポリイミド(PI)などの樹脂からなる透明シート(ないしはフィルム)又は透明板や、ソーダ硝子、カリ硝子、硼珪酸硝子、鉛硝子等からなる透明板などが使用可能である。
なお、印刷法として、誘導加熱により電気抵抗を下げた導電性パターンを、離型性基材上に一旦形成し、しかる後に別途他の透明基材に転写して用いる、いわゆる転写印刷法を採用する場合には、最初の離型性基材は必ずしも透明である必要はなく、耐熱性と離型性さえ良好であれば、通常のフィルムや板など、転写に適した基材も使用可能である。
また、透明基材と印刷された導電ペーストの間には、各種機能を持たせた下地層があってもよい。各種機能の例としては、易接着プライマー塗工処理などによる密着性改善、耐久性改善、印刷性改善、耐熱性改善、耐溶剤性改善等が挙げられる。
さらにまた、透明基材は、なるべく耐熱温度が高いものが好ましいが、必要な処理温度や用いる冷却方法、およびコストなどを勘案して、適したものを選択すればよい。
例えば透明基材としては、透明性、機械的強度、耐熱性、コスト等のバランスに優れることから、特にポリエチレンテレフタレート(PET)が奨用できる。
なお、透明基材の厚さは、用途に応じたものとすればよく、特に制限はないが、透明樹脂シートからなる場合は、通常10〜500μm程度であり、透明樹脂板やガラス板である場合は、通常1〜5mm程度が好適である。
(Transparent substrate)
As the transparent substrate, a substrate transparent at least in the visible light region can be used. Polyester resins such as polyethylene terephthalate (PET) and polyethylene naphthalate (PEN), acrylic such as polymethyl acrylate and polymethyl methacrylate A transparent sheet (or film) or transparent plate made of resin such as resin, polycarbonate (PC), polyimide (PI), or a transparent plate made of soda glass, potassium glass, borosilicate glass, lead glass, or the like can be used. .
As a printing method, a so-called transfer printing method is used in which a conductive pattern with reduced electrical resistance by induction heating is once formed on a releasable substrate and then transferred to another transparent substrate. In this case, the first releasable substrate does not necessarily need to be transparent, and if the heat resistance and releasability are good, a substrate suitable for transfer, such as a normal film or plate, can be used. is there.
Moreover, there may be an underlayer having various functions between the transparent substrate and the printed conductive paste. Examples of the various functions include adhesion improvement by easy adhesion primer coating treatment, durability improvement, printability improvement, heat resistance improvement, solvent resistance improvement and the like.
Furthermore, the transparent substrate preferably has a heat-resistant temperature as high as possible, but a suitable one may be selected in consideration of a necessary processing temperature, a cooling method to be used, costs, and the like.
For example, as a transparent substrate, polyethylene terephthalate (PET) is particularly recommended because of its excellent balance of transparency, mechanical strength, heat resistance, cost, and the like.
The thickness of the transparent substrate is not particularly limited as long as it depends on the application, but when it is made of a transparent resin sheet, it is usually about 10 to 500 μm and is a transparent resin plate or glass plate. In the case, about 1 to 5 mm is usually preferable.

〔導電性インキ〕
本発明の電磁波シールド部材の製造方法に用いられる導電性インキ(導電性ペーストとも言うことがある。)は、バインダー樹脂を溶剤に溶解した溶液に導電性微粒子を均一に分散させた、以下のようなものである。
なお、市販の銀ペーストや銅ペーストのような導電性粒子を含むペーストが使用可能であり、また、低温焼成が可能ないわゆるナノメートルサイズの導電性粒子からなるインキを用いることもできる。
導電性粒子としては、金、銀、白金、銅、鉄、ニッケル、錫、又はアルミニウムなどの単体或いはこれらを含む合金からなる高電導性の金属微粒子やコロイド、シリカ、アルミナ等の非導電性無機物粒子の表面に該金属を被覆したもの、加熱による化学反応により導電性を発現する様な材料などが使用できる。
印刷によりメッシュパターンを形成した直後の状態で、誘導加熱が可能な程度の導電性が発現するものが好ましいが、電気化学処理や薬品処理などの前処理により導電性が発現するものであってもよい。また、これらの粒子を適宜組み合わせてもよい。粒子のサイズはペースト化(インキ化)できる程度には小さいほうがよく、通常は100μm以下の粒径が好ましいが、メッシュパターンの線幅よりは十分に小さい方が好ましく、通常は10μm以下であることが好ましい。また形状は、球状、回転楕円体状、多面体状、塊状、鱗片状、円盤状、繊維状ないし針状など特に制限はなく、各種形状、粒径などを持った粒子を適宜混合して用いてもよい。なお、粒径は、球以外の形状の場合は、回転楕円体の場合
は最大長径、多面体の場合は外接球の直径、或いは最大の対角線長、繊維状ないし針状の場合は長手方向(長軸方向)の長さ等で評価する。
導電性ペーストを用いる場合、バインダー樹脂としては、導電性微粒子及び透明基材に接着性を有する樹脂であればよく、アクリル樹脂、ポリエステル樹脂、エチレン−酢酸ビニル共重合体樹脂、ウレタン樹脂、フェノール樹脂、エポキシ樹脂、セルロース系樹脂等を用いることができる。
溶剤としては、バインダー樹脂を溶解するものであれば特に制限はない。また、銀のナノメートルサイズ粒子のような微細な粒子を用いる場合は、凝集を抑えるための分散剤などが添加される。
[Conductive ink]
The conductive ink (sometimes referred to as conductive paste) used in the method for producing an electromagnetic wave shielding member of the present invention is obtained by uniformly dispersing conductive fine particles in a solution in which a binder resin is dissolved in a solvent. Is something.
A paste containing conductive particles such as a commercially available silver paste or copper paste can be used, and ink made of so-called nanometer-sized conductive particles that can be fired at a low temperature can also be used.
The conductive particles include gold, silver, platinum, copper, iron, nickel, tin, aluminum alone, or highly conductive metal fine particles or colloids made of an alloy containing these, non-conductive inorganic substances such as silica and alumina. A material in which the surface of the particle is coated with the metal, a material that develops conductivity by a chemical reaction by heating, or the like can be used.
It is preferable that the conductive material is developed to the extent that induction heating is possible immediately after the mesh pattern is formed by printing, but the conductive material may be developed by pretreatment such as electrochemical treatment or chemical treatment. Good. Moreover, you may combine these particle | grains suitably. The size of the particles should be small enough to be pasted (inked). Usually, a particle size of 100 μm or less is preferable, but it is preferably sufficiently smaller than the line width of the mesh pattern, and usually 10 μm or less. Is preferred. Also, the shape is not particularly limited, such as spherical, spheroid, polyhedral, lump, scale, disk, fiber or needle shape, and particles having various shapes, particle sizes, etc. are appropriately mixed and used. Also good. Note that the particle diameter is the maximum long diameter in the case of a spheroid, the diameter of a circumscribed sphere in the case of a polyhedron, or the maximum diagonal length in the case of a shape other than a sphere, or the longitudinal direction (long) in the case of a fibrous or needle shape. Axis length) etc. are evaluated.
When the conductive paste is used, the binder resin may be any resin that has adhesiveness to the conductive fine particles and the transparent substrate, such as an acrylic resin, a polyester resin, an ethylene-vinyl acetate copolymer resin, a urethane resin, and a phenol resin. An epoxy resin, a cellulose resin, or the like can be used.
The solvent is not particularly limited as long as it can dissolve the binder resin. In addition, when fine particles such as silver nanometer size particles are used, a dispersant or the like for suppressing aggregation is added.

本発明で用いられる導電性インキは、固形分100質量部のうち金属微粒子40〜99質量部を均一分散させた、固形分20〜90質量パーセントの導電性インキであることが好ましい。
上記のような本発明で用いられる導電性インキ(ペースト)としては、FA−333〔藤倉化成(株)製〕などの市販の銀ペースト、ACP−051〔(株)アサヒ化学研究所製〕などの市販の銅ペーストを用いることもできるが、導電性インキの塗工適性調整のため、導電性微粒子の形状や粒径を調整したり、バインダー樹脂比率を調整したり、固形分を調整して使用することが好ましい。またこれらの導電性インキには、例えばインキの塗工適性調整、インキの安定性改善、導電性微粒子結着体の強度改善や基材との密着改善、導電性微粒子結着体の空隙調整、導電性微粒子結着体の色味調整などの各種目的に応じて、別途フィラー(充填剤ないしは体質顔料)や添加剤を追加したりしてもよい。
なお、フィラーは球状、回転楕円体状、多面体状、截頭多面体状、塊状、鱗片状、円盤状、繊維状などの各種形状から選ぶことができる。導電性インキの粘度については特に制限はなく、用いる印刷方法や材料によって適宜選択すればよい。
The conductive ink used in the present invention is preferably a conductive ink having a solid content of 20 to 90 mass percent in which 40 to 99 mass parts of fine metal particles are uniformly dispersed in 100 mass parts of the solid content.
As the conductive ink (paste) used in the present invention as described above, a commercially available silver paste such as FA-333 (manufactured by Fujikura Kasei Co., Ltd.), ACP-051 (manufactured by Asahi Chemical Laboratory Co., Ltd.), etc. Commercially available copper paste can be used, but to adjust the coating suitability of the conductive ink, the shape and particle size of the conductive fine particles can be adjusted, the binder resin ratio can be adjusted, and the solid content can be adjusted. It is preferable to use it. In addition, these conductive inks include, for example, adjustment of ink coating suitability, improvement of ink stability, improvement of strength of conductive fine particle binders and improvement of adhesion to base materials, adjustment of voids of conductive fine particle binders, A filler (filler or extender pigment) or an additive may be added separately according to various purposes such as color adjustment of the conductive fine particle binder.
The filler can be selected from various shapes such as a spherical shape, a spheroid shape, a polyhedron shape, a truncated polyhedron shape, a lump shape, a scale shape, a disk shape, and a fiber shape. There is no restriction | limiting in particular about the viscosity of electroconductive ink, What is necessary is just to select suitably with the printing method and material to be used.

〔パターン形状〕
本発明の透明性電磁波シールド部材は、導電性を保ちつつ透明性を確保する必要があるため、導電性インキ層は、細かい線部を間に透光性の非形成部を介して、配列したパターン状に形成する。但し、かかるパターンとしては、前述の様に、平行線群(ストライプ、縞)のパターンであると渦電流による加熱が有効に発現しないため、開口部を囲繞する線部を繰返し単位とし、これを渦電流に対する閉回路を構成するようにする。且つ、該繰返し単位(単位格子)を平面内において2次元配列(例えば縦横方向に配列)して該電磁波シールド部材上の所望の領域を被覆したようなメッシュパターン形状にすればよい。かかる配列により渦電流は該電磁波シールド部材上の全域にわたって、少なくとも均一ないし略均一な分布で流れ、渦電流のジュール熱により導電性インキ層は全面にわたって実質上均一に加熱される。パターン形状としては、開口部の形状は任意で特に限定されず、例えば、正三角形等の三角形、正方形、長方形、菱形、台形等の四角形、六角形、等の多角形、円形、楕円形などであり、それが格子模様、ハニカム模様、ランダム網目(メッシュ)模様などのパターン状に2次元配列したものを挙げることができる。
[Pattern shape]
Since the transparent electromagnetic wave shielding member of the present invention needs to ensure transparency while maintaining conductivity, the conductive ink layer is arranged with a fine line portion interposed between non-transparent non-forming portions. Form in a pattern. However, as described above, as described above, since heating due to eddy current does not effectively occur when the pattern is a group of parallel lines (stripes, stripes), the line portion surrounding the opening is used as a repeating unit. A closed circuit for eddy current is constructed. In addition, the repeating units (unit lattices) may be two-dimensionally arranged (for example, arranged in the vertical and horizontal directions) in a plane to form a mesh pattern shape that covers a desired region on the electromagnetic wave shielding member. With this arrangement, the eddy current flows at least uniformly or substantially uniformly over the entire area of the electromagnetic shielding member, and the conductive ink layer is heated substantially uniformly over the entire surface by the Joule heat of the eddy current. As the pattern shape, the shape of the opening is not particularly limited, and for example, a triangle such as a regular triangle, a square such as a square, a rectangle, a rhombus, a trapezoid, a polygon such as a hexagon, a circle, an ellipse, etc. There are two-dimensionally arranged patterns such as a lattice pattern, a honeycomb pattern, and a random mesh pattern.

導電性インキ層を、全面にわたって実質上均一に加熱せしめるためには、閉回路を構成する単位格子を平面内において2次元配列することに加えて、更に該単位格子として等方性の高い形状とすることが好ましい。例えば、四角形の場合で言うと、長方形よりも正方形の方が好ましい。
透明性すなわち光透過性の点からは、線幅は細い方が、又開口率は大きい方が好ましい。
一方、該パターンの耐久強度、高導電性(高電磁シールド性)の発現、及び渦電流による加熱効率の点からは、線幅は太い方が、又開口率は小さい方が好ましい。両者の両立のためには、線幅が5μm〜50μmで、開口率が60〜90%であることが好ましい。
これらのパターンは、渦電流を均一に流すために図2(a)において渦電流を矢印で示
すようになるべくパターン印刷面内の方向による異方性、例えば該パターン面内に図示の如く直交座標o−x−yのx軸、y軸を採った場合に、x軸方向とy軸方向とで線幅、形状、周期等の異方性が少ないことが必要である。開口部を囲繞する線部を繰返単位とし、これを2次元方向(例えば、図2(a)ではx軸方向、及びy軸方向)に配列すれば、この条件は満たされる。この様にすると、z軸(図2では紙面に直交)方向に交流磁界を掛けた場合に、パターン面内に十分な渦電流が流れ、其のジュール熱による加熱量も大きくなる。一方、図2(c)に模式的に示すようにメッシュパターンであっても開口部が大きいと渦電流が流れ難いので、開口部は前記の如く、開口率90%以下、線幅5μm以上にすることが好ましい。また、図2(b)に示すストライプパターン(平行線群)などは、閉回路が形成されず、渦電流が流れないため、誘導加熱が難しい。
なお、ここでパターン印刷面とは、パターン印刷した導電性インキ層を載置する表面及びこれと平行な面を意味する。導電性インキパターンのインキ厚み(該パターンの突出高さ)の分布が無視できる場合は、導電性インキパターン表面における包絡面と実質一致する。図2で言うとxy平面がこれに相当する。又、該パターン印刷面は通常は平面であるが、湾曲した曲面であっても良い。
In order to heat the conductive ink layer substantially uniformly over the entire surface, in addition to two-dimensionally arranging the unit cells constituting the closed circuit in a plane, the unit cell has a more isotropic shape. It is preferable to do. For example, in the case of a quadrangle, a square is preferable to a rectangle.
From the viewpoint of transparency, that is, light transmittance, it is preferable that the line width is narrower and the aperture ratio is larger.
On the other hand, from the viewpoint of the durability of the pattern, the development of high conductivity (high electromagnetic shielding properties), and the heating efficiency by eddy current, it is preferable that the line width is thick and the aperture ratio is small. In order to achieve both, it is preferable that the line width is 5 μm to 50 μm and the aperture ratio is 60 to 90%.
In order to allow the eddy current to flow uniformly, these patterns have anisotropy depending on the direction in the pattern printing surface as shown by arrows in FIG. 2A, for example, orthogonal coordinates as shown in the pattern surface. When the x-axis and y-axis of oxy are taken, it is necessary that the anisotropy such as line width, shape, period, etc. is small in the x-axis direction and the y-axis direction. This condition is satisfied if the line portion surrounding the opening is a repeating unit and is arranged in a two-dimensional direction (for example, the x-axis direction and the y-axis direction in FIG. 2A). In this way, when an alternating magnetic field is applied in the z-axis (perpendicular to the paper surface in FIG. 2) direction, a sufficient eddy current flows in the pattern surface, and the heating amount by the Joule heat increases. On the other hand, as shown schematically in FIG. 2 (c), even if it is a mesh pattern, if the opening is large, it is difficult for eddy currents to flow. It is preferable to do. In addition, the stripe pattern (parallel line group) shown in FIG. 2B is not formed with a closed circuit, and eddy current does not flow, so that induction heating is difficult.
Here, the pattern printing surface means a surface on which the pattern-printed conductive ink layer is placed and a surface parallel to the surface. When the distribution of the ink thickness (projection height of the pattern) of the conductive ink pattern can be ignored, it substantially matches the envelope surface on the surface of the conductive ink pattern. In FIG. 2, the xy plane corresponds to this. The pattern printing surface is usually a flat surface, but it may be a curved surface.

〔印刷法〕
導電性インキを透明基材上にメッシュパターン状に印刷する印刷法は特に制限されないが、導電性インキの性状により適宜選択される。
粒径がナノメートルサイズの金属微粒子を用いる場合は一般に導電性インキの粘度が低く、インクジェット印刷、グラビア印刷、フレキソ印刷などが適しており、サブミクロン〜ミクロン程度の金属微粒子を用いる場合は一般に導電性インキの粘度が高く、グラビア印刷、フレキソ印刷、シルクスクリーン印刷などの印刷法やディスペンサーなどが適している。なお、導電性インキの粘度が低い場合には、印刷後のパターンの広がりを抑えるように基材に下地層を設けてもよい。
印刷後、たとえば100〜150℃程度で熱風乾燥して、溶剤を揮散させた後に、後述する誘導加熱装置に挿通して、電磁誘導電流(渦電流)のジュール熱により加熱され、印刷された金属微粒子を融着させる。なお、導電性インキに含有される金属微粒子が、鉄等の強磁性体でもある場合には、渦電流による加熱に加えて、磁区(磁気能率)の固有周波数に共鳴する周波数を選択することにより、磁区のヒステリシス損失による加熱も併用することが可能である。
あるいは、印刷後溶剤をある程度揮散させた後、誘導加熱装置に挿通して、電磁誘導電流による加熱によりインキ中の金属微粒子を融着させつつ、残留溶剤の揮散を同時にすることもできる。
[Printing method]
The printing method for printing the conductive ink on the transparent substrate in a mesh pattern is not particularly limited, but is appropriately selected depending on the properties of the conductive ink.
When using fine metal particles with a nanometer size, the viscosity of the conductive ink is generally low, and ink jet printing, gravure printing, flexographic printing, etc. are suitable. When using fine metal particles with submicron to micron size, it is generally conductive. The viscosity of the reactive ink is high, and printing methods such as gravure printing, flexographic printing, silk screen printing, and dispensers are suitable. In addition, when the viscosity of conductive ink is low, you may provide a base layer in a base material so that the spreading of the pattern after printing may be suppressed.
After printing, for example, after drying with hot air at about 100 to 150 ° C. to volatilize the solvent, the printed metal is inserted through an induction heating device described later and heated by Joule heat of electromagnetic induction current (eddy current) The fine particles are fused. When the metal fine particles contained in the conductive ink are also ferromagnetic materials such as iron, in addition to heating by eddy current, by selecting a frequency that resonates with the natural frequency of the magnetic domain (magnetic efficiency) It is also possible to use heating due to magnetic domain hysteresis loss.
Alternatively, after the solvent is volatilized to some extent after printing, it is inserted into an induction heating device, and the residual solvent can be volatilized simultaneously while fusing the metal fine particles in the ink by heating with an electromagnetic induction current.

〔誘導加熱〕
本発明の電磁波シールド部材の製造方法において、印刷された導電性パターンによる導電層の厚みは基本的に最大数十μm程度の薄物なので、渦電流を流すためには図1(c)に示すようにパターン印刷面を透過する方向に磁界をかける必要があるため、誘導加熱にはトランスバース型加熱コイルを使用する。尚、パターン印刷面を透過する磁界は、該パターン印刷面と直交する成分が実用上十分な程度に有れば良いため、必ずしも完全に磁界とパターン印刷面とが直交しなくても良い。
加える交流磁界は、その周波数、及び強度を、使用する導電性インキの材料とパターン、及び所望の加熱の程度、及び加熱様式(渦電流加熱、ヒステリシス損失加熱)に応じて適宜選定する。また、透明基材の不要な加熱を防ぐため、基材(誘電体)の誘電損失による発熱を誘起しない周波数を選択する(通常、誘導加熱と誘電加熱の周波数帯域は異なることが多い)。
誘導加熱の際の交流磁界の周波数は、通常、50Hz〜1MHz程度である。
加熱時には導電性パターン自身のみが発熱するが、この熱の一部は基材にも伝導するため、基材への熱ダメージが問題になる場合には適宜、基材の冷却(放熱)をする。冷却方
法には特に制限がなく、空冷や、液体/固体との接触により冷却をすればよいが、誘導加熱時の磁界の影響を受けない/与えないことが必要であり、金属などの良導体は使用に適さない。なお、均一に加熱するためには、加熱されるべき基材を、ロールトゥロール等の手段で、トランスバース型加熱コイルによる磁界の中を一定速度で通過させるのが好ましい。なお、ここで言うロールトゥロールとは加工すべき材料(本発明で言えば、透明性基材、電磁波シールド部材等)を帯状のシートの形状で用意し、巻取(ロール)に巻き取った形態で保管、搬送し、加工時に該巻取から帯状のシートを巻出して所定の加工(本発明で言えば、印刷、誘導加熱等)を行い、再度巻き取って搬送、保管する加工方法を言う。
また、誘導電流を効果的に生じさせるためには、加熱前のパターンの表面抵抗は小さいほうが好ましく、10Ω/□以下であることが好ましい。表面抵抗が高すぎると誘導される電流が小さくなり、発熱効率が著しく低下する。
[Induction heating]
In the manufacturing method of the electromagnetic wave shielding member of the present invention, the thickness of the conductive layer by the printed conductive pattern is basically a thin object of about several tens of micrometers at maximum, so as shown in FIG. Therefore, a transverse type heating coil is used for induction heating. Note that the magnetic field transmitted through the pattern printing surface only needs to have a component that is orthogonal to the pattern printing surface to a practically sufficient level. Therefore, the magnetic field and the pattern printing surface do not necessarily have to be completely orthogonal.
The frequency and intensity of the alternating magnetic field to be applied are appropriately selected according to the material and pattern of the conductive ink to be used, the desired degree of heating, and the heating mode (eddy current heating, hysteresis loss heating). In addition, in order to prevent unnecessary heating of the transparent substrate, a frequency that does not induce heat generation due to dielectric loss of the substrate (dielectric material) is selected (usually, the frequency band of induction heating and dielectric heating is often different).
The frequency of the alternating magnetic field during induction heating is usually about 50 Hz to 1 MHz.
Only the conductive pattern itself generates heat during heating, but part of this heat is also conducted to the base material. Therefore, when thermal damage to the base material becomes a problem, the base material is appropriately cooled (heat radiation). . There is no particular restriction on the cooling method, and it is sufficient to cool by air cooling or contact with liquid / solid, but it is necessary not to be affected by or not affected by the magnetic field during induction heating. Not suitable for use. In addition, in order to heat uniformly, it is preferable to pass the base material to be heated through a magnetic field generated by a transverse heating coil at a constant speed by means such as roll-to-roll. The roll-to-roll referred to here is a material to be processed (in the present invention, a transparent base material, an electromagnetic wave shielding member, etc.) prepared in the form of a belt-like sheet and wound up on a roll (roll). A processing method of storing and transporting in a form, unwinding a belt-like sheet from the winding during processing, performing predetermined processing (in this invention, printing, induction heating, etc.), winding up again, transporting and storing To tell.
Moreover, in order to generate an induced current effectively, the surface resistance of the pattern before heating is preferably small, and is preferably 10Ω / □ or less. If the surface resistance is too high, the induced current is reduced and the heat generation efficiency is significantly reduced.

本発明の電磁波シールド部材の製造方法は、誘導加熱により導電性パターン自体を発熱させるため、基材への熱ダメージを低減させることができる。
さらに、通電によるジュール熱で加熱するなどの方法は短時間で加熱できるというメリットがあるが、発熱するレベルの大電流を供給する端子と導電性パターン印刷面との接触を均一に取ることが難しく、特にロールトゥロールのような連続印刷では難しいが、本発明の製造方法は、誘導加熱による非接触加熱であり、導電性パターンが面内のx及びy方向に異方性の少ない開口部を有したパターンのものに対して、印刷面に垂直な磁界をかける方式なので、導電性パターンを瞬時に加熱することができる。
さらに、必ずしも導電材料の融着温度まで上げる必要はなく、それよりも低い温度でも導電性を改善することができる。詳細な機構は不明であるが、バインダー樹脂等の融解や分解による粒子の再配置とそれに伴う粒子の接触性改善や、粒子表面の被覆物の除去による接触抵抗の低減、バインダー樹脂中に残っている残留溶剤の乾固による粒子の緻密化、あるいは、粒子同士の接点に集中した電流によるミクロ的な融着等が考えられる。
さらにまた、本発明の製造方法によれば、基材上の導電性パターンのみを選択的に瞬時に加熱することができ、基材の冷却と併用することで基材へのダメージを最低限に抑えることができる。もちろん、基材として耐熱性の基材を用いてもよく、耐熱性基材の上にパターンを印刷して加熱した後、別の透明基材上に接着剤等を用いて転写してもよい。
なお、必要に応じて、誘導加熱により導電性インキ印刷パターンの導電性を向上せしめた電磁波シールド部材に対して、更に公知の電解メッキ、或いは無電解メッキを行い、該導電性インキ印刷パターンの表面上に、銅等の高導電性金属を析出させて、更に導電性を向上させることもできる。
また、本発明による電磁波シールド部材は、必要に応じて、更に、反射防止フィルタ、近赤外線吸收フィルタ、着色フィルタ、紫外線吸收フィルタ等の他のフィルタ部材と積層した形態で、PDP等のディスプレイ装置の画面の前面に設置することができる。
Since the method for producing an electromagnetic wave shielding member of the present invention causes the conductive pattern itself to generate heat by induction heating, thermal damage to the substrate can be reduced.
Furthermore, methods such as heating with energized Joule heat have the advantage of being able to heat in a short time, but it is difficult to make uniform contact between the terminals that supply large currents that generate heat and the printed surface of the conductive pattern. In particular, although it is difficult to perform continuous printing such as roll-to-roll, the manufacturing method of the present invention is non-contact heating by induction heating, and the conductive pattern has openings with less anisotropy in the x and y directions in the plane. Since a magnetic field perpendicular to the printing surface is applied to the pattern having the conductive pattern, the conductive pattern can be heated instantaneously.
Furthermore, it is not always necessary to raise the fusion temperature of the conductive material, and the conductivity can be improved even at a lower temperature. Although the detailed mechanism is unknown, the rearrangement of particles by melting and decomposition of the binder resin, etc. and the improvement of the contact property of the particles, the reduction of the contact resistance by removing the coating on the particle surface, the remaining in the binder resin It is conceivable that the particles become dense due to the drying of the residual solvent, or the micro fusion by the current concentrated at the contact point between the particles.
Furthermore, according to the manufacturing method of the present invention, only the conductive pattern on the substrate can be selectively heated instantaneously, and the damage to the substrate can be minimized by using it together with the cooling of the substrate. Can be suppressed. Of course, a heat resistant substrate may be used as the substrate, and after printing and heating a pattern on the heat resistant substrate, it may be transferred onto another transparent substrate using an adhesive or the like. .
In addition, if necessary, a known electrolytic plating or electroless plating is further performed on the electromagnetic wave shielding member whose conductivity is improved by induction heating, and the surface of the conductive ink printing pattern is obtained. On top of this, a highly conductive metal such as copper can be deposited to further improve the conductivity.
In addition, the electromagnetic wave shielding member according to the present invention may be laminated with other filter members such as an antireflection filter, a near infrared absorption filter, a colored filter, and an ultraviolet absorption filter, if necessary, in a display device such as a PDP. Can be installed on the front of the screen.

以下、実施例を挙げて、本発明をより具体的に説明する。
実施例1
平均粒径約1μmの銀粒子92質量部とポリエステル系のバインダー樹脂8質量部、溶剤としてエチレングリコールモノブチルエーテルアセテートからなる導電性インキ(ペースト)を調製し、100mm厚、100mm×100mmの大きさの2軸延伸PETからなる透明基材上に、シルクスクリーン印刷法にて、線幅30μm、ピッチ135μm、厚み25μmで開口率60.5%の図2(a)の如き正方格子状のメッシュパターンを形成した。次いでこれを150℃で熱風乾燥して溶剤を揮散させた。このメッシュ状電磁波シールド部材は実質透明であり、これをベークライト製の放熱板の上に乗せ、トランスバース型加熱コイルにて、所定の条件で2秒間誘導加熱したところ、パターン部分の色が瞬時に変化し、誘導加熱前の電磁波シールド部材と比較して表面抵抗は42%低減し、0.3Ω/□であった。
Hereinafter, the present invention will be described more specifically with reference to examples.
Example 1
A conductive ink (paste) composed of 92 parts by mass of silver particles having an average particle diameter of about 1 μm, 8 parts by mass of a polyester-based binder resin, and ethylene glycol monobutyl ether acetate as a solvent is prepared, and has a thickness of 100 mm and a size of 100 mm × 100 mm. A square lattice mesh pattern as shown in FIG. 2A having a line width of 30 μm, a pitch of 135 μm, a thickness of 25 μm and an aperture ratio of 60.5% is formed on a transparent substrate made of biaxially stretched PET. Formed. Next, this was dried with hot air at 150 ° C. to evaporate the solvent. This mesh-like electromagnetic wave shielding member is substantially transparent. When this is placed on a Bakelite heat sink and heated by induction using a transverse heating coil for 2 seconds under predetermined conditions, the color of the pattern portion instantly appears. The surface resistance was reduced by 42% compared with the electromagnetic wave shielding member before induction heating, and was 0.3Ω / □.

実施例2
実施例1の導電性インキ(ペースト)に替えて、平均粒径が50nm以下の銀粒子を含有する銀ナノペーストを用い、75μm厚のポリイミドシートからなる透明基材上に、インクジェット印刷法にて線幅30μm、一辺が100μmで開口率60.0%のハニカム形状(亀甲格子)のメッシュパターンを印刷した。この基材をトランスバース型加熱コイルにて所定の条件で1秒間誘導加熱したところ、パターン部分が瞬時に変色し、パターン部分の体積抵抗率が10-6Ω・cmのオーダーを示した。
Example 2
In place of the conductive ink (paste) of Example 1, silver nanopaste containing silver particles having an average particle size of 50 nm or less was used, and an ink jet printing method was used on a transparent substrate made of a polyimide sheet having a thickness of 75 μm. A honeycomb-shaped (turtle shell lattice) mesh pattern having a line width of 30 μm, a side of 100 μm, and an aperture ratio of 60.0% was printed. When this base material was induction-heated with a transverse type heating coil for 1 second under predetermined conditions, the pattern portion was instantly discolored, and the volume resistivity of the pattern portion was on the order of 10 −6 Ω · cm.

比較例1
格子状メッシュパターンではなく、図2(b)の如く、y方向のみに走行する線幅30μm、ピッチ75μmの平行線群からなるストライプパターンを形成した以外は実施例1と同様にして透明シートを作成した。次いで、このストライプパターン透明基材を実施例1と同様に誘導加熱したところ、まったく加熱ができなかった。従って、表面抵抗を低減することはできなかった。
Comparative Example 1
A transparent sheet was formed in the same manner as in Example 1 except that a stripe pattern consisting of parallel line groups having a line width of 30 μm and a pitch of 75 μm running only in the y direction as shown in FIG. Created. Subsequently, when this stripe pattern transparent base material was induction-heated in the same manner as in Example 1, it could not be heated at all. Therefore, the surface resistance could not be reduced.

本発明の電磁波シールド部材の製造方法は、導電性インキを透明基材に直接メッシュパターンを印刷し、しかる後、誘導加熱により導電性パターン自体を発熱させ導電性粒子を融着させるため、基材への熱ダメージを低減させつつ、表面抵抗を低減した電磁波シールド部材を得ることができ、各種ディスプレイの前面に配置する透明性を有する電磁波シールド部材の製造方法、及び電磁波シールド部材として有効に利用できる。   In the method for producing an electromagnetic wave shielding member of the present invention, a conductive ink is directly printed on a transparent substrate, and then the conductive pattern is heated by induction heating to fuse the conductive particles. An electromagnetic shielding member with reduced surface resistance can be obtained while reducing thermal damage to the surface, and can be effectively used as a method for producing an electromagnetic shielding member having transparency and disposed on the front surface of various displays, and as an electromagnetic shielding member. .

金属板に対する磁界の方向と渦電流の関係の説明図である。(a)通常厚みの金属板の側面、(b)薄い厚みの金属板の側面、(c)薄い金属板の垂直面、(d)線幅の狭い回路配線の垂直面。It is explanatory drawing of the relationship between the direction of the magnetic field with respect to a metal plate, and an eddy current. (A) Side surface of normal thickness metal plate, (b) Side surface of thin metal plate, (c) Vertical surface of thin metal plate, (d) Vertical surface of circuit wiring with narrow line width. 形状の異なる各種メッシュパターンの印刷面に垂直に磁場をかけた場合の説明図である。(a)メッシュパターンが、線部で囲繞された閉回路の単位格子をx方向及びy方向に周期的に配列した均一なメッシュパターンの例、(b)直線部をx方向にのみ配列したストライプの例、(c)正方格子であるが、開口率が大きすぎ、導電部の密度が低い例。It is explanatory drawing at the time of applying a magnetic field perpendicularly | vertically to the printing surface of various mesh patterns from which a shape differs. (A) An example of a uniform mesh pattern in which a mesh pattern is a uniform mesh pattern in which unit cells of a closed circuit surrounded by a line portion are periodically arranged in the x and y directions, and (b) a stripe in which straight portions are arranged only in the x direction. (C) An example of a square lattice, but the aperture ratio is too large and the density of the conductive portion is low.

Claims (7)

透明基材上に導電性インキを用いて印刷により、開口部を囲繞する線部を平面内において2次元配列してなるメッシュパターンが形成された電磁波シールド用部材の製造方法であって、該パターン印刷面に対して、垂直な方向の磁界をかけることで誘導加熱処理を行うことを特徴とする透明性を有する電磁波シールド部材の製造方法。   A method for producing an electromagnetic wave shielding member in which a mesh pattern formed by two-dimensionally arranging line portions surrounding an opening portion in a plane by printing using a conductive ink on a transparent substrate, the pattern A method for producing a transparent electromagnetic wave shielding member, wherein induction heat treatment is performed by applying a magnetic field in a perpendicular direction to a printed surface. 導電性インキが、金、銀、銅、鉄、ニッケル、又はアルミニウムの金属微粒子を含んでいる請求項1に記載の透明性を有する電磁波シールド部材の製造方法。   The method for producing a transparent electromagnetic wave shielding member according to claim 1, wherein the conductive ink contains metal fine particles of gold, silver, copper, iron, nickel, or aluminum. 透明基材上に、固形分100質量部のうち金属微粒子40〜99質量部を均一分散させた、固形分20〜90質量パーセントの導電性インキを用いて印刷し、溶剤を乾燥した後、誘導加熱処理を行うことを特徴とする請求項2に記載の透明性を有する電磁波シールド部材の製造方法。   On a transparent base material, printing is performed using conductive ink having a solid content of 20 to 90 mass percent, in which 40 to 99 mass parts of metal fine particles are uniformly dispersed in 100 mass parts of solid content, and after the solvent is dried, induction is performed. The method for producing a transparent electromagnetic wave shielding member according to claim 2, wherein heat treatment is performed. 透明基材の少なくとも印刷される側の面に、下地層が存在している請求項1〜3のいずれかに記載の透明性を有する電磁波シールド部材の製造方法。   The manufacturing method of the electromagnetic wave shielding member which has transparency in any one of Claims 1-3 in which the base layer exists in the surface at the side by which the transparent base material is printed at least. 透明基材が樹脂フィルムであり、誘導加熱装置に対してロールトゥロールで連続的に通過させる請求項1〜4のいずれかに記載の透明性を有する電磁波シールド部材の製造方法。   The manufacturing method of the electromagnetic wave shielding member which has transparency in any one of Claims 1-4 which a transparent base material is a resin film, and lets it pass continuously with a roll toe roll with respect to an induction heating apparatus. 透明基材がポリエチレンテレフタレートフィルムである請求項5に記載の透明性を有する電磁波シールド部材の製造方法。   The method for producing a transparent electromagnetic wave shielding member according to claim 5, wherein the transparent substrate is a polyethylene terephthalate film. 請求項1〜6のいずれかに記載の製造方法で得られた透明性を有する電磁波シールド部材。 The electromagnetic wave shielding member which has the transparency obtained with the manufacturing method in any one of Claims 1-6.
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