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JP2008202128A - ERW steel pipe for expanded oil well with excellent pipe expansion performance and corrosion resistance and method for producing the same - Google Patents

ERW steel pipe for expanded oil well with excellent pipe expansion performance and corrosion resistance and method for producing the same Download PDF

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JP2008202128A
JP2008202128A JP2007042288A JP2007042288A JP2008202128A JP 2008202128 A JP2008202128 A JP 2008202128A JP 2007042288 A JP2007042288 A JP 2007042288A JP 2007042288 A JP2007042288 A JP 2007042288A JP 2008202128 A JP2008202128 A JP 2008202128A
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steel pipe
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JP5014831B2 (en
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Taro Muraki
太郎 村木
Hitoshi Asahi
均 朝日
Hidefumi Tsugihara
英文 次原
Shuji Iwamoto
修治 岩本
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Nippon Steel Corp
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Abstract

【課題】高拡管率での拡管が可能であり、拡管後の、油井内の腐食環境における耐硫化物応力割れ性に優れる拡管油井用電縫鋼管及びその製造方法を提供する。
【解決手段】質量%で、C:0.01〜0.3%、Si:0.01〜0.7%、Mn:0.5〜2.0%、Nb:0.005〜0.1%、Ti:0.005〜0.05%、Al:0.002〜0.1%、Ca:0.0005〜0.008%を含有し、P:0.10%以下、S :0.005%以下、O:0.0040%以下に制限し、Si/Mn:0.005〜1.5を満足し、残部がFe及び不可避的不純物からなることを特徴とする拡管性能及び耐食性に優れた拡管油井用電縫鋼管。更に、Cr:0.5%以下を含有し、Si/(Mn+Cr):0.005〜1.5を満足することが好ましい。
【選択図】なし
The present invention provides an electric-welded steel pipe for an expanded oil well that can be expanded at a high expansion ratio and has excellent resistance to sulfide stress cracking in a corrosive environment in the oil well after the expansion, and a method for manufacturing the same.
SOLUTION: In mass%, C: 0.01 to 0.3%, Si: 0.01 to 0.7%, Mn: 0.5 to 2.0%, Nb: 0.005 to 0.1 %, Ti: 0.005-0.05%, Al: 0.002-0.1%, Ca: 0.0005-0.008%, P: 0.10% or less, S: 0.0. 005% or less, O: 0.0040% or less, Si / Mn: 0.005 to 1.5 is satisfied, and the balance is composed of Fe and inevitable impurities. Excellent tube expansion performance and corrosion resistance ERW steel pipe for expanded oil wells. Furthermore, it is preferable to contain Cr: 0.5% or less and to satisfy Si / (Mn + Cr): 0.005-1.5.
[Selection figure] None

Description

本発明は、油井又はガス井(以下、これらを総称して単に「油井」という)に用いられる電縫鋼管に関し、詳細には、油井内で鋼管を拡管加工し、そのままケーシング、チュービングとして使用することができる、拡管性能及び耐食性に優れた拡管油井用電縫鋼管に関するものである。   The present invention relates to an electric resistance steel pipe used for an oil well or a gas well (hereinafter collectively referred to simply as “oil well”), and more specifically, the steel pipe is expanded in the oil well and used as a casing or tubing as it is. The present invention relates to an electric resistance welded steel pipe for a pipe expansion well that is excellent in pipe expansion performance and corrosion resistance.

従来、油井の掘削は、地層の表層部から開始して、所定の深度に到達するとケーシングを挿入し、掘り進みながら外径の小さいケーシングの挿入を繰り返していた。そのため、深く掘削する必要がある場合は、油井の外径方向の掘削面積が広くなり、掘削費用および工期が嵩み、経済的に不利であった。近年、油井に挿入されたケーシングを油井内で拡管することによって、掘削面積を低減し、かつ掘削工期を大幅に短縮可能な工法が提案されている。   Conventionally, excavation of an oil well starts from the surface layer portion of the formation, and when a predetermined depth is reached, a casing is inserted, and insertion of a casing having a small outer diameter is repeated while digging. Therefore, when deep drilling is necessary, the drilling area in the outer diameter direction of the oil well is widened, and the drilling cost and construction period are increased, which is economically disadvantageous. In recent years, a construction method has been proposed in which a casing inserted into an oil well is expanded in the well to reduce a drilling area and significantly shorten a drilling period.

これはエクスパンダブル・チューブラと呼ばれる技術であり、ケーシングに好適な鋼管として、拡管性能及び耐食性に優れた鋼管が提案されている(例えば、特許文献1)。この鋼管は、結晶粒径と降伏強度との関係を適正な範囲としたものである。特許文献1は継目無鋼管の耐食性の向上を図る技術であり、電縫鋼管への適用も示唆されてはいるものの、電縫溶接部を有する電縫鋼管の拡管性能、更に拡管後の電縫溶接部の腐食環境における割れについて考慮されたものではない。
特開2002−266055号公報
This is a technique called expandable tubular, and a steel pipe excellent in pipe expansion performance and corrosion resistance has been proposed as a steel pipe suitable for a casing (for example, Patent Document 1). In this steel pipe, the relationship between the crystal grain size and the yield strength is in an appropriate range. Patent Document 1 is a technique for improving the corrosion resistance of seamless steel pipes, and although it is suggested to be applied to ERW steel pipes, pipe expansion performance of ERW steel pipes having ERW welds, and ERW after pipe expansion It does not take into account cracks in the corrosive environment of the weld.
JP 2002-266055 A

本発明は、エクスパンダブル・チューブラのケーシングに使用される電縫鋼管、即ち、拡管性能に優れる拡管油井用電縫鋼管及びその製造方法を提供するものである。特に、拡管後に、油井内の腐食環境で使用されても、電縫溶接部に硫化物応力割れを生じることのない、耐食性に優れた拡管油井用電縫鋼管及びその製造方法を提供するものである。   The present invention provides an electric resistance welded steel pipe used for an expandable tubular casing, that is, an electric resistance welded steel pipe for expanded oil wells having excellent pipe expansion performance, and a method for producing the same. In particular, it provides an electric resistance welded steel pipe for expanded oil wells that has excellent corrosion resistance and does not cause sulfide stress cracking in an electric resistance welded part even if it is used in a corrosive environment in an oil well after pipe expansion. is there.

本発明は、鋼の酸素量を制限し、Si量とMn量との比、更に、選択的にCrを含有する際のSi量とMn量及びCr量との比を特定の範囲として、電縫溶接部における酸化物の形態を制御し、優れた拡管性能を有し、更に、拡管後、油井内という厳しい腐食環境で使用された際の硫化物応力割れの発生を防止した電縫鋼管であり、その要旨は以下のとおりである。
(1)質量%で、C:0.01〜0.30%、Si:0.01〜0.70%、Mn:0.5〜2.0%、Nb:0.005〜0.100%、Ti:0.005〜0.050%、Al:0.002〜0.100%、Ca:0.0005〜0.0080%を含有し、P:0.10%以下、S:0.005%以下、O:0.0040%以下に制限し、Si/Mn:0.02〜1.50を満足し、残部がFe及び不可避的不純物からなり、電縫衝合部の溶接欠陥面積率が0.10%以下であることを特徴とする拡管性能及び耐食性に優れた拡管油井用電縫鋼管。
(2)質量%で、C:0.01〜0.30%、Si:0.01〜0.70%、Mn:0.5〜2.0%、Nb:0.005〜0.100%、Ti:0.005〜0.050%、Al:0.002〜0.100%、Ca:0.0005〜0.0080%を含有し、P:0.10%以下、S:0.005%以下、O:0.0040%以下に制限し、更に、Cr:0.50%以下を含有し、Si/(Mn+Cr):0.02〜1.50を満足し、電縫衝合部の溶接欠陥面積率が0.10%以下であることを特徴とする拡管性能及び耐食性に優れた拡管油井用電縫鋼管。
(3)質量%で、B:0.0035%以下を含有することを特徴とする上記(1)又は(2)に記載の拡管性能及び耐食性に優れた拡管油井用電縫鋼管。
(4)質量%で、Cu:0.50%以下、Ni:0.50%以下の一方又は双方を含有することを特徴とする上記(1)〜(3)の何れか1項に記載の拡管性能及び耐食性に優れた拡管油井用電縫鋼管。
(5)質量%で、Mo:1.00%以下、W:0.50%以下、V:0.005〜0.200%の1種又は2種以上を含有することを特徴とする上記(1)〜(4)の何れか1項に記載の拡管性能及び耐食性に優れた拡管油井用電縫鋼管。
(6)質量%で、REM:0.0005〜0.0100%を含有することを特徴とする上記(1)〜(5)の何れか1項に記載の拡管性能及び耐食性に優れた拡管油井用電縫鋼管。
(7)母材の金属組織のフェライト分率が50〜95%であることを特徴とする上記(1)〜(6)の何れか1項に記載の拡管性能及び耐食性に優れた拡管油井用電縫鋼管。
(8)上記(7)に記載の電縫鋼管の製造方法であって、上記(1)〜(6)の何れか1項に記載の成分からなる鋼板を管状に成形して突き合わせ部を電縫溶接し、Ac変態点〜Ac変態点に加熱し、冷却することを特徴とする拡管性能及び耐食性に優れた拡管油井用電縫鋼管の製造方法。
The present invention limits the amount of oxygen in steel, the ratio between the Si amount and the Mn amount, and the ratio of the Si amount, the Mn amount and the Cr amount when selectively containing Cr as a specific range. This is an electric resistance steel pipe that controls the form of oxide in the seam welded portion, has excellent pipe expansion performance, and further prevents the occurrence of sulfide stress cracking when used in a severe corrosive environment in an oil well after pipe expansion. Yes, the summary is as follows.
(1) By mass%, C: 0.01 to 0.30%, Si: 0.01 to 0.70%, Mn: 0.5 to 2.0%, Nb: 0.005 to 0.100% Ti: 0.005 to 0.050%, Al: 0.002 to 0.100%, Ca: 0.0005 to 0.0080%, P: 0.10% or less, S: 0.005 %, O: 0.0040% or less, Si / Mn: 0.02 to 1.50 is satisfied, the balance is made of Fe and inevitable impurities, and the weld defect area ratio of the electro-welding joint is An electric-welded steel pipe for an expanded oil well having excellent pipe expansion performance and corrosion resistance, characterized by being 0.10% or less.
(2) By mass%, C: 0.01 to 0.30%, Si: 0.01 to 0.70%, Mn: 0.5 to 2.0%, Nb: 0.005 to 0.100% Ti: 0.005 to 0.050%, Al: 0.002 to 0.100%, Ca: 0.0005 to 0.0080%, P: 0.10% or less, S: 0.005 %, O: 0.0040% or less, further containing Cr: 0.50% or less, satisfying Si / (Mn + Cr): 0.02-1.50, An electric resistance welded steel pipe for expanded oil wells having excellent pipe expansion performance and corrosion resistance, wherein the weld defect area ratio is 0.10% or less.
(3) The electric-welded steel pipe for an expanded oil well having excellent pipe expansion performance and corrosion resistance according to the above (1) or (2), characterized by containing B: 0.0035% or less by mass%.
(4) The composition according to any one of the above (1) to (3), wherein one or both of Cu: 0.50% or less and Ni: 0.50% or less are contained. ERW steel pipe for pipe expansion well with excellent pipe expansion performance and corrosion resistance.
(5) The above-mentioned, characterized by containing one or more of Mo: 1.00% or less, W: 0.50% or less, and V: 0.005 to 0.200% by mass% ( The electric resistance welded steel pipe for an expanded oil well having excellent pipe expansion performance and corrosion resistance according to any one of 1) to (4).
(6) A pipe expansion well having excellent pipe expansion performance and corrosion resistance according to any one of the above (1) to (5), characterized by containing REM: 0.0005 to 0.0100% in mass%. ERW steel pipe.
(7) The ferrite fraction of the metal structure of the base material is 50 to 95%, and is for a pipe expansion well excellent in pipe expansion performance and corrosion resistance according to any one of (1) to (6) above ERW steel pipe.
(8) A method for producing an electric resistance welded steel pipe according to (7) above, in which a steel plate comprising the component according to any one of (1) to (6) is formed into a tubular shape, and the butt portion is electrically connected. A method for producing an electric-welded steel pipe for an expanded oil well having excellent pipe expansion performance and corrosion resistance, characterized by sewing welding, heating to an Ac 1 transformation point to an Ac 3 transformation point, and cooling.

本発明によれば、高い拡管率での拡管が可能であり、拡管後、油井内という厳しい腐食環境で使用されても、電縫溶接部に硫化物応力割れを生じない、耐食性に優れた拡管油井用電縫鋼管及びその製造方法の提供が可能になり、産業上の貢献が極めて顕著である。   According to the present invention, it is possible to expand at a high expansion ratio, and even after being expanded, even if it is used in a severe corrosive environment such as in an oil well, it does not cause sulfide stress cracking in the ERW weld, and has excellent corrosion resistance. It is possible to provide an electric well welded steel pipe and a method for producing the same, and the industrial contribution is extremely remarkable.

本発明者は、継目無鋼管よりも製造コストが安い電縫溶接鋼管を拡管油井用鋼管として使用する際に、特に問題になる拡管性能と、拡管後の電縫溶接部の腐食環境における割れについて検討を行った。先ず、C:0.01〜0.30%、Si:0.01〜0.70%、Mn:0.5〜2.0%、Nb:0.005〜0.100%、Ti:0.005〜0.050%、Al:0.002〜0.10%、Ca:0.0005〜0.0080%を含有し、P:0.10%以下、S:0.005%以下、O:0.0040%以下に制限した鋼板、更に、Cr:0.50%以下を含有する鋼板を電縫溶接し、電縫鋼管を製造した。   The present inventor is concerned with the pipe expansion performance that is particularly problematic when using an electric resistance welded steel pipe, which is cheaper to manufacture than a seamless steel pipe, as a steel pipe for expanded oil wells, and cracks in the corrosive environment of the electric resistance welded portion after the pipe expansion. Study was carried out. First, C: 0.01 to 0.30%, Si: 0.01 to 0.70%, Mn: 0.5 to 2.0%, Nb: 0.005 to 0.100%, Ti: 0.00. 005 to 0.050%, Al: 0.002 to 0.10%, Ca: 0.0005 to 0.0080%, P: 0.10% or less, S: 0.005% or less, O: A steel plate restricted to 0.0040% or less and further a steel plate containing Cr: 0.50% or less were electro-welded to produce an electric-welded steel pipe.

次に、これらの電縫鋼管の端部に円錐状の試験治具を押し込み、拡管前後の鋼管端部の内径の変化率である拡管率を10%、17%、28%として拡管した。拡管後、鋼管の電縫溶接部の割れ、即ち、拡管割れの有無を目視により確認した。更に、電縫溶接部に割れが発生していない鋼管の端部から、周方向を長手方向とし、溶接部が中央になるように、試験片を採取した。試験片を、油井内の腐食環境を模擬した溶液中に浸漬し、硫化物応力割れの有無を確認した。   Next, a conical test jig was pushed into the end portions of these electric resistance welded steel pipes, and the pipe expansion ratios of the inner diameter of the steel pipe end portions before and after the pipe expansion were expanded to 10%, 17%, and 28%. After pipe expansion, the presence or absence of cracks in the ERW welded portion of the steel pipe, that is, pipe expansion cracks, was visually confirmed. Furthermore, the test piece was extract | collected from the edge part of the steel pipe which has not generate | occur | produced the crack in an electric-welding welding part so that the circumferential direction may be made into the longitudinal direction and a welding part may become a center. The test piece was immersed in a solution simulating the corrosive environment in the oil well, and the presence or absence of sulfide stress cracking was confirmed.

なお、油井内の腐食環境を模擬した溶液とは、5%のNaClを含む0.5%酢酸溶液に硫化水素ガスを分圧0.1MPaで飽和させたNACE環境である。また、硫化物応力割れの有無は、NACE環境中で397MPaの応力を負荷し、720時間保持した後に確認した。   The solution simulating the corrosive environment in the oil well is a NACE environment in which hydrogen sulfide gas is saturated at a partial pressure of 0.1 MPa in a 0.5% acetic acid solution containing 5% NaCl. The presence or absence of sulfide stress cracking was confirmed after applying a stress of 397 MPa in a NACE environment and holding it for 720 hours.

図1及び2に、Si/(Mn+Cr)と、拡管割れの発生の有無、及び拡管後の電縫溶接部の硫化物応力割れ発生の有無を示す。図1及び2は、縦軸を拡管率、横軸をSi/(Mn+Cr)とし、拡管による割れが発生したものを×、拡管による割れの発生がなく、硫化物応力割れが発生したものを●、発生していないものを○で示している。なお、図1及び2において、Crを含有しない鋼のSi/(Mn+Cr)は、Crを0として、Si/Mnを求めた。   1 and 2 show Si / (Mn + Cr), the presence or absence of occurrence of pipe expansion cracks, and the presence or absence of occurrence of sulfide stress cracks in the ERW welds after pipe expansion. 1 and 2, the vertical axis represents the tube expansion ratio, the horizontal axis represents Si / (Mn + Cr), x indicates that cracking occurred due to expansion, and x indicates that no cracking occurred due to expansion and sulfide stress cracking occurred. Those that have not occurred are indicated by ○. 1 and 2, the Si / (Mn + Cr) of the steel not containing Cr was calculated by setting Cr to 0.

図1及び2は、拡管割れ、腐食環境中での硫化物応力割れを生じないSi/Mn又はSi/(Mn+Cr)の下限及び上限をそれぞれ示すものである。図1から、Si/Mn又はSi/(Mn+Cr)の下限を0.02以上とし、図2からSi/Mn又はSi/(Mn+Cr)の上限を1.50以下とすれば、拡管後、腐食環境中で硫化物応力割れを生じないことがわかる。更に、拡管割れの発生を抑制し、拡管性能を向上させるには、Si/Mn又はSi/(Mn+Cr)を0.03〜1.00とすることが好ましく、更に好ましい範囲は、0.05〜0.50であることがわかる。   FIGS. 1 and 2 show the lower and upper limits of Si / Mn or Si / (Mn + Cr), respectively, which do not cause expansion cracking and sulfide stress cracking in a corrosive environment. From FIG. 1, if the lower limit of Si / Mn or Si / (Mn + Cr) is 0.02 or more, and if the upper limit of Si / Mn or Si / (Mn + Cr) is 1.50 or less from FIG. It can be seen that no sulfide stress cracking occurs. Furthermore, in order to suppress the occurrence of pipe expansion cracks and improve the pipe expansion performance, Si / Mn or Si / (Mn + Cr) is preferably 0.03 to 1.00, and more preferably 0.05 to It turns out that it is 0.50.

拡管性能及び耐食性に及ぼすSi/Mn又はSi/(Mn+Cr)の影響を明確にするため、電縫鋼管の電縫溶接部の組織を光学顕微鏡で観察した。その結果、Crを含有しない鋼で、Si/Mnを0.02〜1.50とすれば、電縫溶接部へのSiO、MnOの2元系混合酸化物の残留を抑制できることがわかった。同様に、Crを含有する鋼では、Si/(Mn+Cr)を0.02〜1.50とすることにより、電縫溶接部へのSiO、MnO、Crの3元系混合酸化物の残留を抑制できることがわかった。 In order to clarify the influence of Si / Mn or Si / (Mn + Cr) on the pipe expansion performance and corrosion resistance, the structure of the ERW welded portion of the ERW steel pipe was observed with an optical microscope. As a result, it was found that if the Si / Mn is 0.02 to 1.50 with Cr-free steel, the residual of the binary mixed oxide of SiO 2 and MnO in the ERW weld can be suppressed. . Similarly, in steel containing Cr, by setting Si / (Mn + Cr) to 0.02 to 1.50, a ternary mixed oxide of SiO 2 , MnO, and Cr 2 O 3 to the ERW weld is used. It was found that the residual of can be suppressed.

これは、Crを含有しない鋼は、Si/Mnを0.02〜1.50とすることにより、SiO、MnOの2元系混合酸化物の融点が低下して1600℃以下になり、電縫溶接の際に溶接部から液相として排出されるためである。同様に、Crを含有する鋼では、Si/(Mn+Cr)を0.02〜1.50とすることにより、SiO、MnO、Crの3元系混合酸化物の融点が1600℃以下になり、液相として電縫溶接部から排出され、酸化物の残留を抑制することができる。 This is because steel containing no Cr has a Si / Mn ratio of 0.02 to 1.50, so that the melting point of the binary mixed oxide of SiO 2 and MnO is lowered to 1600 ° C. or less. This is because the liquid phase is discharged from the welded portion during the sewing welding. Similarly, in steel containing Cr, the melting point of the ternary mixed oxide of SiO 2 , MnO, and Cr 2 O 3 is 1600 ° C. or less by setting Si / (Mn + Cr) to 0.02 to 1.50. Thus, it is discharged from the ERW weld as a liquid phase, and the residual oxide can be suppressed.

また、Si/Mn、Si/(Mn+Cr)を更に好適な範囲に制御すると、酸化物の融点が低下し、電縫溶接部から酸化物を確実に排出することが可能になり、拡管性能が向上し、拡管率を高めても良好な耐食性を維持することができる。Si/Mn、Si/(Mn+Cr)を0.03〜1.00、更に好ましくは0.05〜0.50にすれば、電縫溶接部への酸化物の残留を確実に防止することが可能になり、拡管性能が向上する。   In addition, when Si / Mn and Si / (Mn + Cr) are controlled within a more suitable range, the melting point of the oxide is lowered, and the oxide can be discharged reliably from the ERW welded portion, improving the pipe expansion performance. And even if it raises a pipe expansion rate, favorable corrosion resistance can be maintained. If Si / Mn and Si / (Mn + Cr) are set to 0.03 to 1.00, more preferably 0.05 to 0.50, it is possible to reliably prevent oxide from remaining in the ERW weld. As a result, tube expansion performance is improved.

Si/Mn又はSi/(Mn+Cr)を適正な範囲に制御した電縫鋼管では、酸化物の残留が抑制されているので、酸化物に起因する欠陥の発生が抑制される。即ち、電縫溶接部への酸化物の残留は、電縫衝合部の溶接欠陥面積率によって判定することができる。電縫衝合部の割れは、酸化物に起因するものであり、溶接欠陥面積率が0.10%以下であれば、優れた拡管性能及び耐食性が得られる。したがって、溶接欠陥面積率は0.10%以下とする。また、溶接欠陥面積率が0.10%超の場合、電縫衝合部の機械的特性が十分満足せず、さらに種々の試験にて破裂する恐れもある。   In the ERW steel pipe in which Si / Mn or Si / (Mn + Cr) is controlled within an appropriate range, the residual oxide is suppressed, so that the generation of defects due to the oxide is suppressed. That is, the residue of the oxide in the electric seam welded portion can be determined by the weld defect area ratio of the electric seam abutting portion. The cracks in the electric seam abutting portion are caused by oxides, and if the weld defect area ratio is 0.10% or less, excellent pipe expansion performance and corrosion resistance can be obtained. Therefore, the weld defect area ratio is set to 0.10% or less. Further, when the weld defect area ratio is more than 0.10%, the mechanical characteristics of the electro-welding abutting portion are not sufficiently satisfied, and further, there is a possibility of rupture in various tests.

電縫衝合部の溶接欠陥面積率の測定方法について説明する。破断面が溶接方向に平行になるように、電縫溶接部にノッチを設けたシャルピー衝撃試験片を作製し、延性破面率が100%となる温度でシャルピー衝撃試験を実施する。破断後のシャルピー試験片の破面を光学顕微鏡にて観察し、割れの面積を測定する。割れの面積を観察面の面積で除した値を百分率で表した数値が溶接欠陥面積率である。   A method for measuring the weld defect area ratio of the electric seam abutting portion will be described. A Charpy impact test piece provided with a notch in the ERW weld is prepared so that the fracture surface is parallel to the welding direction, and the Charpy impact test is performed at a temperature at which the ductile fracture surface ratio becomes 100%. The fracture surface of the Charpy specimen after fracture is observed with an optical microscope, and the area of the crack is measured. A value obtained by dividing the area of the crack by the area of the observation surface in percentage is the weld defect area ratio.

以下、本発明の成分組成について説明する。   Hereinafter, the component composition of the present invention will be described.

Cは、鋼の焼入れ性を向上させ、強度を高める基本元素であり、0.01%以上の添加が必要である。一方、C量が多すぎると、焼き割れを誘発するため、上限を0.30%以下とする。   C is a basic element that improves the hardenability of the steel and increases the strength, and it is necessary to add 0.01% or more. On the other hand, if the amount of C is too large, a cracking is induced, so the upper limit is made 0.30% or less.

Siは、脱酸元素であり、含有量が0.01%未満であると、鋼中の酸素量が増加して、電縫溶接部に粗大な酸化物系の介在物を生じる。一方、Si量が0.70%より多すぎても、溶接部に酸化物を生じて油井内での割れを発生させる。したがって、Si量を0.01〜0.70%とする。   Si is a deoxidizing element. If the content is less than 0.01%, the amount of oxygen in the steel increases, and coarse oxide-based inclusions are generated in the ERW weld. On the other hand, even if the amount of Si is more than 0.70%, an oxide is generated in the welded portion and cracks are generated in the oil well. Therefore, the Si amount is set to 0.01 to 0.70%.

Mnは、SをMnSとして無害化させる元素であり、焼入れ性の向上にも寄与する。この効果を得るためには、Mnを0.5%以上添加することが必要である。一方、Mnは耐硫化物応力割れ抵抗性に有害であるので、上限を2.0%以下とする。   Mn is an element that renders S harmless as MnS, and contributes to improvement of hardenability. In order to obtain this effect, it is necessary to add 0.5% or more of Mn. On the other hand, Mn is harmful to the resistance to sulfide stress cracking, so the upper limit is made 2.0% or less.

Si及びMnは、上述のように、電縫溶接部の介在物の形態を制御するために極めて重要な元素であり、Si/Mnを0.02〜1.50の範囲とすることが必要である。また、耐食性を維持しながら、拡管性能を向上させるには、Si/Mnを0.03〜1.00とすることが好ましく、更に好適な範囲は0.05〜0.50である。   As described above, Si and Mn are extremely important elements for controlling the form of inclusions in the ERW weld, and Si / Mn needs to be in the range of 0.02 to 1.50. is there. Moreover, in order to improve pipe expansion performance, maintaining corrosion resistance, it is preferable to make Si / Mn 0.03-1.00, and a more suitable range is 0.05-0.50.

Nb及びTiは、炭化物、窒化物を生成し、特に適量を含有させることにより、TiN、NbCを形成し、電縫溶接部の結晶粒の粗大化を防止し、拡管性能及び拡管後の耐硫化物応力割れ性の向上に有効な元素である。一方、適正量を超えて過度に含有させると、炭化物、窒化物が粗大になり、靭性を損なう。したがって、Nb及びTiの添加量は、それぞれ、0.005〜0.100%及び0.005〜0.050%とする。   Nb and Ti generate carbides and nitrides, and by containing appropriate amounts, TiN and NbC are formed, preventing coarsening of the crystal grains in the ERW welds, pipe expansion performance and sulfidation resistance after pipe expansion It is an effective element for improving physical stress cracking. On the other hand, if it is contained excessively beyond the appropriate amount, carbides and nitrides become coarse and toughness is impaired. Therefore, the addition amounts of Nb and Ti are 0.005 to 0.100% and 0.005 to 0.050%, respectively.

Alは、脱酸剤として使用される元素であり、酸素量を減少させて電縫溶接部への酸化物の生成を抑制するために、0.002%以上の添加が必要である。一方、0.100%を超える過剰なAlを含有させると粗大な介在物を生じて、拡管性能及び拡管後の耐硫化物応力割れ性の低下させるため、上限を0.100%以下とすることが必要である。   Al is an element used as a deoxidizer, and it is necessary to add 0.002% or more in order to reduce the amount of oxygen and suppress the formation of oxide in the ERW weld. On the other hand, if excessive Al exceeding 0.100% is contained, coarse inclusions are produced and the expansion performance and the resistance to sulfide stress cracking after expansion are reduced. is required.

Caは、CaSを生成して硫化物の形態制御に寄与し、耐硫化物応力割れ性の向上に有効な元素である。この効果を得るには、Caを0.0005%以上含有させることが必要である。一方、0.0080%超えるCaを含有させると、介在物が多量に生成し、孔食の起点となり、耐食性が低下するため上限を0.0080%以下とする。   Ca is an element that generates CaS and contributes to the control of the form of sulfide, and is effective in improving the resistance to sulfide stress cracking. In order to acquire this effect, it is necessary to contain 0.0005% or more of Ca. On the other hand, if Ca is contained in excess of 0.0080%, a large amount of inclusions are generated, which becomes a starting point of pitting corrosion, and the corrosion resistance is lowered, so the upper limit is made 0.0080% or less.

Sは、不純物であり、MnSを形成して耐硫化物応力割れ性を損なうため、上限を0.005%以下に制限する。   S is an impurity, and forms MnS to impair sulfide stress cracking resistance. Therefore, the upper limit is limited to 0.005% or less.

Pも不純物であり、粒界に偏析して耐硫化物応力割れ性を低下させるため、上限を0.10%以下に制限する。   P is also an impurity, and segregates at the grain boundaries to reduce the resistance to sulfide stress cracking, so the upper limit is limited to 0.10% or less.

Oは、特に、電縫溶接部に酸化物を発生させ、その結果溶接欠陥を形成させることによって耐硫化物応力割れ性を低下させるため、0.0040%以下に制限することが必要である。また、0.0040%超の酸素を含有すると、Sを固定するために添加したCaが酸化物となり、母材に、圧延方向に延伸した非金属介在物、例えば、MnSなどの硫化物が生じ、耐硫化物応力割れ性が低下する。酸素量を0.0025%以下に制限すると、母材に生成する非金属介在物の最大長径を小さくすることが可能になり、母材からの硫化物応力割れ性の発生を防止できる。したがって、酸素量は0.0025%以下に制限することが更に好ましい。   O particularly needs to be limited to 0.0040% or less in order to reduce the resistance to sulfide stress cracking by generating an oxide in the ERW weld and consequently forming a weld defect. In addition, when oxygen exceeds 0.0040%, Ca added to fix S becomes an oxide, and non-metallic inclusions extending in the rolling direction, for example, sulfides such as MnS, are generated in the base material. , The resistance to sulfide stress cracking is reduced. When the amount of oxygen is limited to 0.0025% or less, it becomes possible to reduce the maximum major axis of non-metallic inclusions generated in the base material, and to prevent the occurrence of sulfide stress cracking from the base material. Therefore, it is more preferable to limit the oxygen amount to 0.0025% or less.

Crは、焼入れ性を向上させ、強度を確保するために有効な元素である。Crは、過剰に添加すると、HAZの靭性が劣化するため、上限を0.50%以下とすることが好ましい。また、Crを添加する場合には、電縫溶接部への酸化物の残留を抑制するため、Si/(Mn+Cr)を0.02〜1.50の範囲として、添加することが好ましい。また、Si/(Mn+Cr)を0.03〜1.00、更に好適には0.05〜0.50にすると、耐食性を維持しながら、拡管性能を向上させることができる。   Cr is an effective element for improving hardenability and ensuring strength. When Cr is added excessively, the toughness of HAZ deteriorates, so the upper limit is preferably made 0.50% or less. In addition, when adding Cr, it is preferable to add Si / (Mn + Cr) in the range of 0.02 to 1.50 in order to suppress residual oxide in the ERW weld. Further, when Si / (Mn + Cr) is set to 0.03 to 1.00, more preferably 0.05 to 0.50, the pipe expansion performance can be improved while maintaining the corrosion resistance.

更に、拡管性能を向上させるために、Bを添加しても良い。
Bは焼入性を高める元素であり、拡管性能の向上に有効であるが、0.0035%超を含有すると、靭性が劣化することがある。したがって、B添加量の上限は、0.0035%以下が好ましい。
Furthermore, B may be added to improve the tube expansion performance.
B is an element that enhances hardenability and is effective in improving the pipe expansion performance. However, when it exceeds 0.0035%, the toughness may be deteriorated. Therefore, the upper limit of the B addition amount is preferably 0.0035% or less.

更に、耐硫化物応力割れ性を向上させるために、Cu、Ni、Mo、W、V、REMの1種又は2種以上を添加しても良い。   Further, in order to improve sulfide stress cracking resistance, one or more of Cu, Ni, Mo, W, V, and REM may be added.

Cu及びNiは、腐食環境下において硫化皮膜を形成し、これにより鋼中への水素侵入が抑制され、耐硫化物応力割れ性が向上する。一方、0.50%超を添加すると鋳片割れなど発生することがあるため、0.50%以下の添加が好ましい。   Cu and Ni form a sulfide film in a corrosive environment, thereby suppressing hydrogen intrusion into the steel and improving sulfide stress cracking resistance. On the other hand, if more than 0.50% is added, slab cracking may occur, so addition of 0.50% or less is preferable.

Moは、耐硫化物応力割れ性を高め、焼入れ性も向上させる元素であるが、1.00%を超えて添加しても効果が飽和する。また、0.50%超を添加すると、MoCが析出して靱性が劣化することがあるため、上限を0.50%以下とすることが好ましい。なお、耐硫化物応力割れ性を高めるには、0.15%以上の添加が好ましい。 Mo is an element that enhances the resistance to sulfide stress cracking and improves the hardenability, but the effect is saturated even if added over 1.00%. Further, the addition 0.50 percent, since the toughness Mo 2 C is precipitated sometimes deteriorates, so the upper limit is preferably made 0.50% or less. In addition, in order to improve sulfide stress cracking resistance, addition of 0.15% or more is preferable.

Wは、炭化物を生じて拡散性水素を捕捉し、耐硫化物応力割れ性を高め、焼入性を向上させる元素であるが、0.50%超添加すると靭性が低下することがある。したがって、上限を0.50%以下とすることが好ましい。   W is an element that generates carbides and traps diffusible hydrogen, improves resistance to sulfide stress cracking, and improves hardenability, but if added over 0.50%, toughness may be reduced. Therefore, the upper limit is preferably 0.50% or less.

Vは、微細な炭化物、窒化物を形成して拡散性水素を捕捉し、耐硫化物応力割れ性の向上に有効な元素である。この効果を得るには、Vを0.005%以上添加することが好ましい。一方、Vを0.200%超添加すると、炭化物、窒化物が粗大化して、靭性を損なうことがあるため、上限を0.200%以下とすることが好ましい。   V is an element that forms fine carbides and nitrides to capture diffusible hydrogen and is effective in improving the resistance to sulfide stress cracking. In order to acquire this effect, it is preferable to add V 0.005% or more. On the other hand, if V is added in excess of 0.200%, carbides and nitrides are coarsened and the toughness may be impaired, so the upper limit is preferably made 0.200% or less.

REMは、不純物元素(P、S、O)とそれらの析出物(介在物)の形態の制御を目的として添加される元素である。不純物を安定で無害な析出物として固定し、強度と靭性を向上させるには、REMを0.0005%以上添加することが好ましい。一方、REMの添加量が0.0100%を超えると、介在物が増加して、靭性を損なうことがある。したがって、REMの含有量は0.0005〜0.0100%以下とすることが好ましい。   REM is an element added for the purpose of controlling the form of impurity elements (P, S, O) and their precipitates (inclusions). In order to fix impurities as stable and harmless precipitates and improve strength and toughness, it is preferable to add REM 0.0005% or more. On the other hand, if the amount of REM added exceeds 0.0100%, inclusions may increase and the toughness may be impaired. Therefore, the REM content is preferably 0.0005 to 0.0100% or less.

母材に存在する非金属介在物は機械的特性やSSCなどの耐食性試験時に破壊の起点となりうる。母材に存在する非金属介在物の単体の最大長径が300μm超では、腐食環境が厳しくなると、破壊発生の起点となり、耐応力腐食割れ性を損なうことがある。したがって、非金属介在物の最大長径は300μm以下とすることが好ましい。圧延方向に延伸する非金属介在物は、主にMnSであり、その最大長径は、CaSを生成させてSを有効に固定することにより、短くすることができる。したがって、非金属介在物の最大長径を300μm以下とするには、酸素量を0.0040以下に低下させて、Caを適正量添加すれば良い。   Non-metallic inclusions present in the base material can be the starting point of fracture during corrosion resistance tests such as mechanical properties and SSC. When the maximum major axis of the non-metallic inclusions present in the base material exceeds 300 μm, if the corrosive environment becomes severe, it may become a starting point of occurrence of breakage and may impair the stress corrosion cracking resistance. Therefore, the maximum major axis of the nonmetallic inclusion is preferably 300 μm or less. Nonmetallic inclusions extending in the rolling direction are mainly MnS, and the maximum major axis can be shortened by generating CaS and fixing S effectively. Therefore, in order to make the maximum major axis of the non-metallic inclusions 300 μm or less, the oxygen amount is reduced to 0.0040 or less, and an appropriate amount of Ca may be added.

母材のフェライトの面積率は光学顕微鏡にて観察した組織を画像処理にて解析した。フェライト分率が50%未満の場合、一様で十分な拡管ができずに限界拡管率が低下することがある。またフェライト分率が95%超では油井管に必要な引張強度や圧縮強度が得られないことがある。したがって、フェライト分率は50〜95%であることが好ましい。母材のフェライト分率は、後述するように、電縫鋼管の熱処理条件によって50〜95%にすることができる。   The area ratio of ferrite of the base material was analyzed by image processing of the structure observed with an optical microscope. If the ferrite fraction is less than 50%, uniform and sufficient tube expansion cannot be performed, and the limit tube expansion rate may be lowered. On the other hand, if the ferrite fraction exceeds 95%, the tensile strength and compressive strength required for oil well pipes may not be obtained. Therefore, the ferrite fraction is preferably 50 to 95%. As described later, the ferrite fraction of the base material can be 50 to 95% depending on the heat treatment conditions of the ERW steel pipe.

次に、本発明の電縫鋼管の製造方法について説明する。   Next, the manufacturing method of the ERW steel pipe of this invention is demonstrated.

電縫鋼管の素材となる鋼板は、常法によって製造することができる。即ち、鋼の溶製及び鋳造を常法で行い、得られた鋼片を熱間圧延し、冷却して鋼板とする。なお、鋳造は、生産性の観点から、連続鋳造が好ましい。熱間圧延の条件は、特に規定する必要はなく、素材である鋼片の形状及び厚みと熱間圧延後の鋼板の板厚、目的とする機械特性を考慮して、条件を決定すれば良い。熱間圧延後は空冷でも良いが、加速冷却を行うことが好ましい。加速冷却は、水冷、ミスト冷却、送風など、目的とする機械特性を考慮して、適宜選択することができる。   The steel plate used as the material of the electric resistance welded steel pipe can be manufactured by a conventional method. That is, melting and casting of steel is performed by a conventional method, and the obtained steel piece is hot-rolled and cooled to obtain a steel plate. The casting is preferably continuous casting from the viewpoint of productivity. The hot rolling conditions do not need to be specified in particular, and the conditions may be determined in consideration of the shape and thickness of the steel slab, the thickness of the steel sheet after hot rolling, and the desired mechanical properties. . Although air cooling may be performed after hot rolling, accelerated cooling is preferably performed. Accelerated cooling can be appropriately selected in consideration of target mechanical characteristics such as water cooling, mist cooling, and air blowing.

上述の方法によって得られた鋼板を造管し、突合せ部を電縫溶接して、電縫鋼管を製造する。電縫鋼管の造管では、熱延鋼板を、ロール成形などの冷間曲げ加工によって管状に成形し、入熱、鋼板の突き合わせ角度(V角)、鋼板の通板速度等を制御して、電縫溶接する。   A steel plate obtained by the above-described method is piped, and the butt portion is electro-welded and an electric-welded steel pipe is manufactured. In pipe making of ERW steel pipe, hot rolled steel sheet is formed into a tube by cold bending process such as roll forming, and heat input, butt angle (V angle) of steel sheet, sheet feeding speed of steel sheet, etc. are controlled, ERW welding.

更に、電縫鋼管には熱処理を施すことが好ましい。加熱温度は、鋼の組織がフェライトとオーステナイトの2相となる温度領域、即ち、Ac変態点からAc変態点の間とすることが好ましい。加熱温度によって、フェライト分率を調整することができ、Ac変態点からAc変態点の間に加熱すると、フェライト分率を50〜95%にすることができる。その後の冷却時には加熱、保持により生成したフェライト分率を維持するよう冷却すれば良い。そのため、加熱、保持後には、加速冷却を行うことが好ましい。加速冷却は、水冷、ミスト冷却、送風など、目的とする機械特性を考慮して、適宜選択することができる。 Furthermore, it is preferable to heat-treat the ERW steel pipe. The heating temperature is preferably in a temperature region in which the steel structure has two phases of ferrite and austenite, that is, between the Ac 1 transformation point and the Ac 3 transformation point. The ferrite fraction can be adjusted by the heating temperature, and when heated between the Ac 1 transformation point and the Ac 3 transformation point, the ferrite fraction can be 50 to 95%. What is necessary is just to cool so that the ferrite fraction produced | generated by heating and holding | maintenance may be maintained at the time of subsequent cooling. Therefore, it is preferable to perform accelerated cooling after heating and holding. Accelerated cooling can be appropriately selected in consideration of target mechanical characteristics such as water cooling, mist cooling, and air blowing.

なお、Ac変態点及びAc変態点は、合金元素の含有量により、次の計算式によって求めることができる。
Ac=723−10.7Mn−16.9Ni+29.1Si+16.9Cr
+6.38W
Ac=910−203C1/2−15.2Ni+44.7Si+104V
+31.5Mo+13.1W
The Ac 1 transformation point and the Ac 3 transformation point can be obtained by the following calculation formulas depending on the alloy element content.
Ac 1 = 723-10.7Mn-16.9Ni + 29.1Si + 16.9Cr
+ 6.38W
Ac 3 = 910-203C 1/2 -15.2Ni + 44.7Si + 104V
+ 31.5Mo + 13.1W

表1に示す化学成分の鋼を溶製し、鋳造して得られた鋼片を熱間圧延して鋼板とし、更に、鋼板を管状に成形して突合せ部を電縫溶接した。表1の空欄は、選択元素が無添加であることを意味し、下線は、本発明の範囲外であることを意味する。表1の鋼番号がN〜Tの鋼は、選択的に添加されたCr、B、Cu、Ni、Mo、W、Vを過剰に含有する例である。また、Crの添加の有無に応じて、Si/Mn、Si/(Cr+Mn)の何れかを求め、表1に示した。表1において、Crを含有する鋼の「Si/Mn」欄、Crを含有しない鋼の「Si/(Cr+Mn)」欄には、「−」を示した。   Steel pieces obtained by melting and casting the chemical components shown in Table 1 were hot-rolled into steel plates, and the steel plates were formed into a tubular shape, and the butt joints were electro-welded. The blank in Table 1 means that the selected element is not added, and the underline means outside the scope of the present invention. Steels with steel numbers N to T in Table 1 are examples containing excessively added selectively added Cr, B, Cu, Ni, Mo, W, and V. In addition, depending on whether Cr was added or not, either Si / Mn or Si / (Cr + Mn) was determined and shown in Table 1. In Table 1, “-” is shown in the “Si / Mn” column of steel containing Cr and the “Si / (Cr + Mn)” column of steel not containing Cr.

得られた電縫鋼管の外径は193mmであり、これらを表2に示した温度に加熱し、冷却した。熱処理後の電縫鋼管から、電縫溶接部にノッチを設けたシャルピー衝撃試験片を採取し、延性破面率が100%となる温度でシャルピー衝撃試験を実施し、破断後のシャルピー試験片の破面を光学顕微鏡にて観察して、溶接欠陥面積率を測定した。また、母材の金属組織を光学顕微鏡によって観察し、延伸した非金属介在物の長径を測定し、最大値を求めて表2の「介在物長さ」欄に示した。   The outer diameter of the obtained electric resistance welded steel pipe was 193 mm, and these were heated to the temperatures shown in Table 2 and cooled. A Charpy impact test piece with a notch in the ERW weld is taken from the ERW steel pipe after the heat treatment, and a Charpy impact test is conducted at a temperature at which the ductile fracture surface ratio becomes 100%. The fracture surface was observed with an optical microscope, and the weld defect area ratio was measured. Further, the metal structure of the base material was observed with an optical microscope, the major axis of the stretched nonmetallic inclusion was measured, and the maximum value was obtained and shown in the “inclusion length” column of Table 2.

電縫鋼管の端部から、内面に円錐状の拡管用治具を挿入し、端部の拡管率を10%、17%、28%として拡管した。割れが発生しなかった最大の拡管率(限界拡管率という。)を、表2に「拡管率」として示した。表2に示した限界拡管率で拡管した鋼管の端部から、周方向を長手方向とし、母材から引張試験片を採取した。引張試験を行って、0.2%耐力を測定し、結果を表2の「拡管後YS」に示した。   A conical tube expansion jig was inserted into the inner surface from the end of the ERW steel tube, and the tube was expanded at a tube expansion rate of 10%, 17%, and 28%. The maximum tube expansion rate at which no cracks occurred (referred to as the limit tube expansion rate) is shown in Table 2 as “tube expansion rate”. From the end of the steel pipe expanded at the limit expansion rate shown in Table 2, the circumferential direction was taken as the longitudinal direction, and tensile specimens were collected from the base material. A tensile test was performed to measure the 0.2% proof stress, and the results are shown in “YS after tube expansion” in Table 2.

更に、表2に示した限界拡管率で拡管した鋼管の端部から、周方向を長手方向とし、溶接部が試験片の中央部になるように、平行部の外径が6mmの定荷重SSC試験片を採取し、ゲージ長を30mmとして、定荷重SSC試験を行った。試験環境は上述のNACE環境とし、397MPaの応力を負荷して720時間保持し、破断の有無を評価した。表2の耐食性の欄に、720時間保持して破断しなかったものを「○」で示し、破断したものを「×」で示した。   Furthermore, from the end of the steel pipe expanded at the limit expansion ratio shown in Table 2, the constant direction SSC with the outer diameter of the parallel part being 6 mm so that the circumferential direction is the longitudinal direction and the welded part is the center part of the test piece A test piece was collected and a constant load SSC test was performed with a gauge length of 30 mm. The test environment was the above-mentioned NACE environment, a stress of 397 MPa was applied and held for 720 hours, and the presence or absence of fracture was evaluated. In the column of corrosion resistance in Table 2, those that were not broken after being held for 720 hours were indicated by “◯”, and those that were broken were indicated by “x”.

表2に示したように、製造No.1〜13は本発明例であり、限界拡管率が17%以上と高く、拡管後YSが550MPa以上であり、かつ拡管後の耐食性、即ち耐応力腐食性が良好である。一方、製造No.14〜22は比較例であり、限界拡管率が低く、拡管後のSSC試験で、割れが生じており、耐食性も低下している。   As shown in Table 2, the production No. Reference numerals 1 to 13 are examples of the present invention, the limit tube expansion rate is as high as 17% or more, the YS after tube expansion is 550 MPa or more, and the corrosion resistance after tube expansion, that is, the stress corrosion resistance is good. On the other hand, production No. 14-22 is a comparative example, the limit pipe expansion rate is low, the crack has arisen in the SSC test after pipe expansion, and corrosion resistance is also falling.

Figure 2008202128
Figure 2008202128

Figure 2008202128
Figure 2008202128

耐硫化物応力割れ性が良好なSi/(Mn+Cr)の下限を示す図である。It is a figure which shows the minimum of Si / (Mn + Cr) with favorable sulfide stress cracking resistance. 耐硫化物応力割れ性が良好なSi/(Mn+Cr)の上限を示す図である。It is a figure which shows the upper limit of Si / (Mn + Cr) with favorable sulfide stress cracking resistance.

Claims (8)

質量%で、
C :0.01〜0.30%、
Si:0.01〜0.70%、
Mn:0.5〜2.0%、
Nb:0.005〜0.100%、
Ti:0.005〜0.050%、
Al:0.002〜0.100%、
Ca:0.0005〜0.0080%
を含有し、
P :0.10%以下、
S :0.005%以下、
O :0.0040%以下
に制限し、
Si/Mn:0.02〜1.50
を満足し、残部がFe及び不可避的不純物からなり、電縫衝合部の溶接欠陥面積率が0.10%以下であることを特徴とする拡管性能及び耐食性に優れた拡管油井用電縫鋼管。
% By mass
C: 0.01 to 0.30%
Si: 0.01-0.70%,
Mn: 0.5 to 2.0%
Nb: 0.005 to 0.100%,
Ti: 0.005 to 0.050%,
Al: 0.002 to 0.100%,
Ca: 0.0005 to 0.0080%
Containing
P: 0.10% or less,
S: 0.005% or less,
O: limited to 0.0040% or less,
Si / Mn: 0.02-1.50
, The balance is Fe and inevitable impurities, and the weld defect area ratio of the electro-welding joint is 0.10% or less. .
質量%で、
C :0.01〜0.30%、
Si:0.01〜0.70%、
Mn:0.5〜2.0%、
Nb:0.005〜0.100%、
Ti:0.005〜0.050%、
Al:0.002〜0.100%、
Ca:0.0005〜0.0080%
を含有し、
P :0.10%以下、
S :0.005%以下、
O :0.0040%以下
に制限し、更に、
Cr:0.50%以下
を含有し、
Si/(Mn+Cr):0.02〜1.50
を満足し、電縫衝合部の溶接欠陥面積率が0.10%以下であることを特徴とする拡管性能及び耐食性に優れた拡管油井用電縫鋼管。
% By mass
C: 0.01 to 0.30%
Si: 0.01-0.70%,
Mn: 0.5 to 2.0%
Nb: 0.005 to 0.100%,
Ti: 0.005 to 0.050%,
Al: 0.002 to 0.100%,
Ca: 0.0005 to 0.0080%
Containing
P: 0.10% or less,
S: 0.005% or less,
O: limited to 0.0040% or less, and
Cr: 0.50% or less,
Si / (Mn + Cr): 0.02-1.50
Satisfying the above, and the weld defect area ratio of the ERW abutting portion is 0.10% or less, and an ERW steel pipe for expanded oil wells having excellent pipe expansion performance and corrosion resistance.
質量%で、
B :0.0035%以下
を含有することを特徴とする請求項1又は2に記載の拡管性能及び耐食性に優れた拡管油井用電縫鋼管。
% By mass
B: 0.0035% or less, The electric-welded steel pipe for pipe expansion wells having excellent pipe expansion performance and corrosion resistance according to claim 1 or 2.
質量%で、
Cu:0.50%以下、
Ni:0.50%以下
の一方又は双方を含有することを特徴とする請求項1〜3の何れか1項に記載の拡管性能及び耐食性に優れた拡管油井用電縫鋼管。
% By mass
Cu: 0.50% or less,
Ni: 0.50% or less of one or both are contained, The electric resistance welded steel pipe for pipe expansion wells excellent in pipe expansion performance and corrosion resistance of any one of Claims 1-3 characterized by the above-mentioned.
質量%で、
Mo:1.00%以下、
W :0.50%以下、
V :0.005〜0.200%
の1種又は2種以上を含有することを特徴とする請求項1〜4の何れか1項に記載の拡管性能及び耐食性に優れた拡管油井用電縫鋼管。
% By mass
Mo: 1.00% or less,
W: 0.50% or less,
V: 0.005 to 0.200%
1 type or 2 types or more of these are contained, The electric-welding steel pipe for pipe expansion wells excellent in pipe expansion performance and corrosion resistance of any one of Claims 1-4 characterized by the above-mentioned.
質量%で、
REM:0.0005〜0.0100%
を含有することを特徴とする請求項1〜5の何れか1項に記載の拡管性能及び耐食性に優れた拡管油井用電縫鋼管。
% By mass
REM: 0.0005 to 0.0100%
The electric-welded steel pipe for expanded oil wells according to any one of claims 1 to 5, which has excellent expanded performance and corrosion resistance.
母材の金属組織のフェライト分率が50〜95%であることを特徴とする請求項1〜6の何れか1項に記載の拡管性能及び耐食性に優れた拡管油井用電縫鋼管。   The electric resistance steel pipe for an expanded oil well having excellent pipe expansion performance and corrosion resistance according to any one of claims 1 to 6, wherein the ferrite fraction of the metal structure of the base material is 50 to 95%. 請求項7に記載の電縫鋼管の製造方法であって、請求項1〜6の何れか1項に記載の成分からなる鋼板を管状に成形して突き合わせ部を電縫溶接し、Ac変態点〜Ac変態点に加熱し、冷却することを特徴とする拡管性能及び耐食性に優れた拡管油井用電縫鋼管の製造方法。 A method for producing an ERW steel pipe according to claim 7, wherein the steel sheet comprising the component according to any one of claims 1 to 6 is formed into a tubular shape, and the butt portion is electro-welded, and the Ac 1 transformation is performed. A method for producing an electric-welded steel pipe for pipe expansion wells excellent in pipe expansion performance and corrosion resistance, characterized by heating to point to Ac 3 transformation point and cooling.
JP2007042288A 2007-02-22 2007-02-22 ERW steel pipe for expanded oil well with excellent pipe expansion performance and corrosion resistance and method for producing the same Expired - Fee Related JP5014831B2 (en)

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JP2011246793A (en) * 2010-05-31 2011-12-08 Jfe Steel Corp Method for manufacturing welded steel pipe for oil well superior in pipe expanding property and low temperature toughness, and welded steel pipe
CN106011638A (en) * 2016-05-18 2016-10-12 宝鸡石油钢管有限责任公司 Expansion casing for heavy oil thermal recovery well and manufacturing method of expansion casing
WO2018042522A1 (en) * 2016-08-30 2018-03-08 新日鐵住金株式会社 Oil well pipe for expandable tubular
CN109680209A (en) * 2018-11-07 2019-04-26 林州凤宝管业有限公司 A kind of N80 grade of steel Micro Alloying Oil Tube Steel and its method for preparing oil pipe

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JP2000234140A (en) * 1998-12-14 2000-08-29 Nippon Steel Corp Boiler steel excellent in ERW weldability and ERW boiler steel pipe using the same
WO2004001076A1 (en) * 2002-06-19 2003-12-31 Nippon Steel Corporation Oil well steel pipe excellent in crushing resistance characteristics after pipe expansion

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011246793A (en) * 2010-05-31 2011-12-08 Jfe Steel Corp Method for manufacturing welded steel pipe for oil well superior in pipe expanding property and low temperature toughness, and welded steel pipe
CN106011638A (en) * 2016-05-18 2016-10-12 宝鸡石油钢管有限责任公司 Expansion casing for heavy oil thermal recovery well and manufacturing method of expansion casing
WO2018042522A1 (en) * 2016-08-30 2018-03-08 新日鐵住金株式会社 Oil well pipe for expandable tubular
JPWO2018042522A1 (en) * 2016-08-30 2019-03-28 新日鐵住金株式会社 Oil well pipe for expandable tubular
CN109680209A (en) * 2018-11-07 2019-04-26 林州凤宝管业有限公司 A kind of N80 grade of steel Micro Alloying Oil Tube Steel and its method for preparing oil pipe

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