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JP2008280057A - Drinking water in container and method for filling drinking water in container - Google Patents

Drinking water in container and method for filling drinking water in container Download PDF

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Publication number
JP2008280057A
JP2008280057A JP2007124476A JP2007124476A JP2008280057A JP 2008280057 A JP2008280057 A JP 2008280057A JP 2007124476 A JP2007124476 A JP 2007124476A JP 2007124476 A JP2007124476 A JP 2007124476A JP 2008280057 A JP2008280057 A JP 2008280057A
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container
drinking water
hydrogen
gas
mixed
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Hidemi Kubo
秀美 久保
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MELODIAN MENTE KK
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MELODIAN MENTE KK
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Abstract

<P>PROBLEM TO BE SOLVED: To provide drinking water in a container and a method for filling drinking water in a container in which hydrogen gas in the content filling the container can be prevented from being released into a head space of the container. <P>SOLUTION: Drinking water in a container of this invention is drinking water 16 put in a container 10, mixed and filled with hydrogen gas, and mixture gas 20 containing hydrogen of lower than 4% is filled in an upper space 18 within the container generated at liquid surface or surface of the drinking water 16 and sealingly closed. A method for filling drinking water in the container of this invention includes the step of mixing hydrogen of lower than 4% within the upper space in the container generated at the liquid surface or surface of drinking water, replacing it with the mixture gas and filling it and the step of sealingly closing mixture gas including hydrogen within the upper space in the container. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

この発明は、容器入り飲料水および容器に飲料水を充填する方法に関し、特に、例えば水素ガスを混合・封入させた清涼飲料水を充填された容器入り飲料水および容器に飲料水を充填する方法に関する。   The present invention relates to a container-filled drinking water and a method for filling a container with drinking water, and in particular, for example, a container-filled drinking water filled with soft drink mixed with hydrogen gas and sealed, and a method for filling a container with drinking water. About.

従来より、水素ガスを含有させた飲料がある。   Conventionally, there is a beverage containing hydrogen gas.

特開2004‐351399号公報JP 2004-351399 A

一般的には、アルミニウム製のボトル缶で飲料等を製造する場合、ボトル缶のヘッドスペース、すなわち、容器内上部空間中には、炭酸飲料の場合においては、充填した内容物中の炭酸ガスが充満し密封強度を保っており、又、非炭酸飲料の場合は、窒素ガスを別途封入することにより密封強度を保たせている。
ところが、水素ガスを混合・封入させた飲料の場合、通常のボトル缶製造工程のままでは、容器に充填後、ヘッドスペース中に、飲料に封入している水素ガスが抜け出してしまい、その結果、経時的には飲料としては水素ガスを含有していないものになってしまうおそれがある。
それゆえに、この発明の主たる目的は、容器内に充填された内容物中の水素ガスを容器のヘッドスペース中に逃がさないようにすることができる、容器入り飲料水及び容器に飲料水を充填する方法を提供することである。
In general, when a beverage or the like is produced with an aluminum bottle can, the head space of the bottle can, that is, the upper space in the container, in the case of a carbonated beverage, carbon dioxide in the filled contents is contained. In the case of non-carbonated beverages, the sealing strength is maintained by separately filling nitrogen gas.
However, in the case of a beverage in which hydrogen gas is mixed and sealed, in the normal bottle can manufacturing process, after filling the container, the hydrogen gas sealed in the beverage escapes into the head space, and as a result, Over time, the beverage may become one that does not contain hydrogen gas.
Therefore, the main object of the present invention is to fill the container with drinking water and the container so that the hydrogen gas in the contents filled in the container does not escape into the head space of the container. Is to provide a method.

この発明にかかる容器入り飲料水は、容器に入れられ、水素ガスを混合・封入させた飲料水において、前記飲料水の液面又は表面に生ずる容器内上部空間に、水素を4%未満含む混合ガスを充填され密封された、容器入り飲料水である。
この発明の請求項2にかかる容器入り飲料水は、容器は、口が細くなったボトル缶であり、口にはキャップがねじ留めされたものである、請求項1に記載の容器入り飲料水である。
この発明の請求項3にかかる容器入り飲料水は、混合ガスは、水素を窒素ガスに4%未満混合された、請求項1又は請求項2に記載の容器入り飲料水である。
この発明の請求項4にかかる容器に飲料水を充填する方法は、水素ガスを混合・封入させた飲料水を容器に充填するステップと、前記飲料水の液面又は表面に生ずる容器内上部空間内に、水素を4%未満混合し、混合ガスに置換して、充満させるステップと、水素を含む混合ガスを容器内上部空間内に密封するステップとを含む、容器に飲料水を充填する方法である。
The drinking water in a container according to the present invention is a mixing water containing less than 4% of hydrogen in an upper space in the container generated in the liquid surface or surface of the drinking water in the drinking water mixed and sealed with hydrogen gas. Bottled water filled with gas and sealed.
The drinking water contained in a container according to claim 2 of the present invention is a bottled can having a narrow mouth and a cap screwed to the mouth. It is.
The container-containing drinking water according to claim 3 of the present invention is the container-containing drinking water according to claim 1 or claim 2, wherein the mixed gas is a mixture of less than 4% of hydrogen with nitrogen gas.
According to a fourth aspect of the present invention, there is provided a method for filling a container with drinking water, the step of filling the container with drinking water mixed and sealed with hydrogen gas, and the upper space in the container formed on the surface or surface of the drinking water. A method of filling a container with drinking water, comprising the steps of: mixing less than 4% of hydrogen and replacing the gas with a mixed gas, and filling the mixed gas containing hydrogen into the upper space in the container. It is.

現代の研究成果によれば、過度の運動、ストレス、飲酒、喫煙等の要因で、体内に活性酸素という身体に有害な物質ができるが、水素ガスを摂取することにより、この有害な活性酸素が中和され、無害なものに変換するということが言われている。本発明によれば、容器内に充てんされた水素ガスを含有した清涼飲料水等の内容物から、重要な水素ガスが抜け出ることなく、清涼飲料水等の内容物に含有された水素ガスを摂取することができる、容器入り飲料水及び容器に飲料水を充填する方法を得ることができる。   According to the results of modern research, excessive oxygen, stress, drinking, smoking, and other factors can create a reactive substance in the body called active oxygen. It is said to be neutralized and converted into harmless. According to the present invention, the hydrogen gas contained in the contents such as soft drinks is ingested without escaping the important hydrogen gas from the contents such as soft drinks containing the hydrogen gas filled in the container. It is possible to obtain drinking water in a container and a method of filling the container with drinking water.

この発明の上述の目的、その他の目的、特徴および利点は、図面を参照して行う以下の発明を実施するための最良の形態の説明から一層明らかとなろう。   The above-described object, other objects, features, and advantages of the present invention will become more apparent from the following description of the best mode for carrying out the invention with reference to the drawings.

この発明にかかる容器10は、口が細くなったアルミニウム製ボトル缶であり、口12にはキャップ14がねじ留めされたものである。
この容器10には、水素ガスを混合・封入させた飲料水16が充填されている。前記飲料水16の液面又は表面に生ずる容器内上部空間(ヘッドスペース)18に、水素を4%未満混合した混合ガスを充填され密封されている。
混合ガスは、水素を窒素ガスに4%未満混合されている。
但し、通常、水素は可燃性ガスのため、水素混合ガスは、水素を4%未満含む混合ガスにする必要があり、水素が4%〜74%の濃度のものは爆発の危険がある。
A container 10 according to the present invention is an aluminum bottle can with a narrow mouth, and a cap 14 is screwed to the mouth 12.
The container 10 is filled with drinking water 16 in which hydrogen gas is mixed and sealed. A container upper space (head space) 18 formed on the liquid surface or surface of the drinking water 16 is filled with a mixed gas containing less than 4% hydrogen and sealed.
The mixed gas is a mixture of less than 4% hydrogen with nitrogen gas.
However, since hydrogen is usually a flammable gas, the hydrogen mixed gas needs to be a mixed gas containing less than 4% of hydrogen, and if hydrogen has a concentration of 4% to 74%, there is a risk of explosion.

次に、容器に飲料水を充填する方法について説明する。
まず、水素ガスを混合・封入させた飲料水、例えば水素ガスを混合封入させた水、水素ガスを混合封入させたスポーツドリンク、水素ガスを封入させた美容飲料を、容器10に充填する(ステップ101)。
容器10は、口12が細くなったアルミニウム製ボトル缶であり、口12にはキャップ14がねじ留めされたものである。
Next, a method for filling a container with drinking water will be described.
First, the container 10 is filled with drinking water in which hydrogen gas is mixed and sealed, for example, water in which hydrogen gas is mixed and sealed, a sports drink in which hydrogen gas is mixed and sealed, and a beauty beverage in which hydrogen gas is sealed (step) 101).
The container 10 is an aluminum bottle can having a narrow mouth 12, and a cap 14 is screwed to the mouth 12.

次に、水素と窒素との混合ガスを、口12から容器10内に噴射して、先に充填された飲料水16の水素ガスが抜け出ることを防ぐ(ステップ102)。   Next, a mixed gas of hydrogen and nitrogen is injected into the container 10 from the mouth 12 to prevent the hydrogen gas of the drinking water 16 previously filled from escaping (step 102).

次に、液体窒素を口12から容器10内に注入し、容器10が凹むことを防ぐようにするとともに、後に注入する水素ガスと混合して、混合ガスとなる(ステップ103)。   Next, liquid nitrogen is injected into the container 10 from the mouth 12 to prevent the container 10 from being recessed, and mixed with hydrogen gas to be injected later to become a mixed gas (step 103).

次に、前記飲料水の液面又は表面に生ずる容器内上部空間18内に、容器10の口12から水素と窒素との混合ガスを吹き込む(ステップ104)。
このとき、水素ガスは、4%未満を窒素ガスと混合された、水素と窒素との混合ガスに置換して、充満する。
但し、通常、水素は可燃性ガスのため、水素混合ガスは、水素を4%未満含む混合ガスにする必要があり、水素が4%〜74%の濃度のものは爆発の危険がある。
Next, a mixed gas of hydrogen and nitrogen is blown from the mouth 12 of the container 10 into the container upper space 18 generated on the surface or surface of the drinking water (step 104).
At this time, hydrogen gas is filled by substituting less than 4% with a mixed gas of hydrogen and nitrogen mixed with nitrogen gas.
However, since hydrogen is usually a flammable gas, the hydrogen mixed gas needs to be a mixed gas containing less than 4% of hydrogen, and if hydrogen has a concentration of 4% to 74%, there is a risk of explosion.

次に、容器10の口12にキャップ14をねじ留めして水素と窒素とを含む混合ガスを容器内上部空間18内に密封する(ステップ105)。
このとき、キャップ14の周辺にも水素と窒素との混合ガスを噴射しながら、キャップ14をねじ留めすれば、より正確に適量の水素ガスを容器に入れることができる(ステップ106)。
Next, the cap 14 is screwed to the mouth 12 of the container 10 to seal the mixed gas containing hydrogen and nitrogen in the upper space 18 in the container (step 105).
At this time, if the cap 14 is screwed while jetting a mixed gas of hydrogen and nitrogen also around the cap 14, an appropriate amount of hydrogen gas can be put into the container more accurately (step 106).

水素ガスは、飲料水中に0.4ppm以上の濃度で混合分散しており、この混合分散している水素ガスが経時的に内容物たる飲料水中で安定性を有することが必須条件になるが、ヘッドスペースに水素ガスを含有する気体を吹き込むことにより、水素ガスが混合、封入された内容物たる飲料水とヘッドスペースに平衡状態ができて、内容物たる飲料水中の水素ガスがヘッドスペースに逃げることなく安定性を向上させることができる。
これは、飲料水中の水素ガスの分圧とヘッドスペース中の水素ガスの分圧差を利用して、ヘッドスペース中への内容物たる飲料水からの水素ガスの移行を止めるものと推定される。
容器にキャップをねじ留めする工程までのタイミングで、本件発明の方法にて、キャップおよびヘッドスペースにこの混合ガスを噴射し、置換することにより、経時的に安定性を有する水素ガスを含有した内容物を充填して容器入り飲料水を製造することが可能となる。
Hydrogen gas is mixed and dispersed at a concentration of 0.4 ppm or more in drinking water, and it is an essential condition that this mixed and dispersed hydrogen gas has stability in the drinking water as the contents over time. By blowing a gas containing hydrogen gas into the headspace, the hydrogen gas is mixed and sealed, and the drinking water as the contents and the headspace are in equilibrium, and the hydrogen gas in the drinking water as the contents escapes to the headspace. The stability can be improved without any problems.
This is presumed to stop the transfer of hydrogen gas from the drinking water, which is the contents, into the head space by using the partial pressure difference between the hydrogen gas in the drinking water and the hydrogen gas in the head space.
Content containing hydrogen gas having stability over time by injecting and replacing this mixed gas into the cap and the headspace by the method of the present invention at the timing until the cap is screwed to the container. It becomes possible to produce a potable drinking water by filling the product.

本件発明にかかる水素ガスを混合・封入した清涼飲料水には、現在、アルミ製ボトル型の缶容器で商品化されている、各種清涼飲料水例えば水、果汁飲料、コーヒー飲料等、全てに応用が可能である。 The soft drink mixed and encapsulated with hydrogen gas according to the present invention is currently commercialized in aluminum bottle-type can containers, and is applied to all kinds of soft drinks such as water, fruit juice drinks, coffee drinks, etc. Is possible.

飲料水入り容器の断面図解図である。It is a cross-sectional schematic solution figure of a container with drinking water. 容器に飲料水及び混合ガスを充填する方法を示す図解図である。It is an illustration figure which shows the method of filling a container with drinking water and mixed gas.

符号の説明Explanation of symbols

10 容器
12 口
14 キャップ
16 飲料水
18 容器内上部空間
20 水素と窒素との混合ガス
22 窒素
10 Container 12 Port 14 Cap 16 Drinking Water 18 Upper Space in Container 20 Mixed Gas of Hydrogen and Nitrogen 22 Nitrogen

Claims (4)

容器に入れられ、水素ガスを混合・封入させた飲料水において、
前記飲料水の液面又は表面に生ずる容器内上部空間に、水素を4%未満含む混合ガスを充填され密封された、容器入り飲料水。
In drinking water that is put in a container and mixed and sealed with hydrogen gas,
Containerd drinking water filled with a mixed gas containing less than 4% hydrogen and sealed in the upper space in the container generated on the surface or surface of the drinking water.
容器は、口が細くなったボトル缶であり、口にはキャップがねじ留めされたものである、請求項1に記載の容器入り飲料水。   The container-containing drinking water according to claim 1, wherein the container is a bottle can having a narrow mouth, and a cap is screwed to the mouth. 混合ガスは、水素を窒素ガスに4%未満混合された、請求項1又は請求項2に記載の容器入り飲料水。   The mixed gas is potable drinking water according to claim 1 or 2, wherein less than 4% of hydrogen is mixed with nitrogen gas. 水素ガスを混合・封入させた飲料水を容器に充填するステップと、
前記飲料水の液面又は表面に生ずる容器内上部空間内に、水素を4%未満混合し、混合ガスに置換して、充満させるステップと、
水素を含む混合ガスを容器内上部空間内に密封するステップとを含む、容器に飲料水を充填する方法。
Filling the container with drinking water mixed and sealed with hydrogen gas;
In the upper space in the container generated at the liquid level or surface of the drinking water, hydrogen is mixed with less than 4%, and is replaced with a mixed gas to be filled.
Sealing the mixed gas containing hydrogen into the upper space in the container.
JP2007124476A 2007-05-09 2007-05-09 Drinking water in container and method for filling drinking water in container Pending JP2008280057A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011087547A (en) * 2009-10-26 2011-05-06 Future Solution:Kk Beverage container for hydrogen-containing beverage, and method for producing hydrogen-containing beverage
JP2017000089A (en) * 2015-06-11 2017-01-05 株式会社 伊藤園 Method for producing packed food and drink and method for suppressing deterioration in the quality of the packed food and drink
JP2017123854A (en) * 2017-02-13 2017-07-20 株式会社 伊藤園 Oxidation degradation inhibitor of lipid and oxidation degradation inhibition method of lipid
JP2017196586A (en) * 2016-04-28 2017-11-02 奥長良川名水株式会社 Hydrogen water
WO2018179304A1 (en) * 2017-03-30 2018-10-04 株式会社伊藤園 Method for controlling flavor balance of liquid food or beverage
TWI679940B (en) * 2017-03-30 2019-12-21 日商伊藤園股份有限公司 Method for adjusting flavor balance of liquid food and drink
JP2020114259A (en) * 2020-04-30 2020-07-30 株式会社 伊藤園 Bottled hydrogen-containing beverage and method for producing the same
CN112645268A (en) * 2019-10-11 2021-04-13 湖南福氢科技有限公司 Drinking water bucket for storing and drinking hydrogen-rich water

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011087547A (en) * 2009-10-26 2011-05-06 Future Solution:Kk Beverage container for hydrogen-containing beverage, and method for producing hydrogen-containing beverage
JP2017000089A (en) * 2015-06-11 2017-01-05 株式会社 伊藤園 Method for producing packed food and drink and method for suppressing deterioration in the quality of the packed food and drink
JP2017196586A (en) * 2016-04-28 2017-11-02 奥長良川名水株式会社 Hydrogen water
JP2017123854A (en) * 2017-02-13 2017-07-20 株式会社 伊藤園 Oxidation degradation inhibitor of lipid and oxidation degradation inhibition method of lipid
WO2018179304A1 (en) * 2017-03-30 2018-10-04 株式会社伊藤園 Method for controlling flavor balance of liquid food or beverage
JPWO2018179304A1 (en) * 2017-03-30 2019-04-25 株式会社 伊藤園 Taste balance adjustment method of liquid food and drink
TWI679940B (en) * 2017-03-30 2019-12-21 日商伊藤園股份有限公司 Method for adjusting flavor balance of liquid food and drink
CN112645268A (en) * 2019-10-11 2021-04-13 湖南福氢科技有限公司 Drinking water bucket for storing and drinking hydrogen-rich water
JP2020114259A (en) * 2020-04-30 2020-07-30 株式会社 伊藤園 Bottled hydrogen-containing beverage and method for producing the same
JP7080275B2 (en) 2020-04-30 2022-06-03 株式会社 伊藤園 Beverages containing hydrogen in containers and their manufacturing methods

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