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JP2008133428A - Alternative emulsified fuel and preparation process thereof - Google Patents

Alternative emulsified fuel and preparation process thereof Download PDF

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Publication number
JP2008133428A
JP2008133428A JP2007193450A JP2007193450A JP2008133428A JP 2008133428 A JP2008133428 A JP 2008133428A JP 2007193450 A JP2007193450 A JP 2007193450A JP 2007193450 A JP2007193450 A JP 2007193450A JP 2008133428 A JP2008133428 A JP 2008133428A
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oil
weight
carbide
mixture
bunker
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Gil-Yeop Song
キル−ヨプ ソン
Chun-Ho Lee
チュン−ホ イ
Jae-Kuk Kim
ジェ−グク キム
In-Kui Choi
イン−キ チェ
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Korea X Oil Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/32Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
    • C10L1/328Oil emulsions containing water or any other hydrophilic phase
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/12Inorganic compounds
    • C10L1/1216Inorganic compounds metal compounds, e.g. hydrides, carbides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/12Inorganic compounds
    • C10L1/1225Inorganic compounds halogen containing compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/24Mixing, stirring of fuel components
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/34Applying ultrasonic energy

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide an alternative emulsified fuel for the cost reduction at the field site by using a bunker fuel oil C and carbide as main raw materials and mixing water therewith. <P>SOLUTION: An alternative emulsified fuel is prepared by mixing 70-80 wt.% of a bunker fuel oil C and 20-30 wt.% of an aqueous carbide solution, followed by subjecting the resulting mixture to heating and agitating, irradiating thereto a 20 KHz-1 MHz supersonic wave for 20-30 minutes for inducing ionic bondings in the mixture, and subjecting the mixture to the high speed revolution in an emulsifying machine, to prevent the oil/water separation thereof from occurring, wherein 0.5-2 pts.wt. of a calcium chloride is used as an emulsifier relative to 100 pts.wt. of the mixture of the bunker fuel oil C and an aqueous carbide solution, the aqueous carbide solution is prepared by dissolving 0.1-1% of a carbide in water. The alternative emulsified fuel can be supplied inexpensively for air heating in winter for horticulture or flowery plants, drying agricultural and fishery products, or for industrial use. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、代替乳化燃料及びその製造方法に関する。より詳細には、バンカーC油とカーバイド水溶液とを混合して加熱し、真空混合機の回転によってイオン結合を誘導し、及び超音波を照射して油水分離が起きないように乳化機内で高速回転させることによって製造され、産業用や農水産物の乾燥に利用される低廉な代替乳化燃料及びその製造方法に関する。   The present invention relates to an alternative emulsified fuel and a method for producing the same. More specifically, bunker C oil and an aqueous carbide solution are mixed and heated, ionic bonds are induced by rotation of the vacuum mixer, and high-speed rotation is performed in the emulsifier so that oil-water separation does not occur by irradiating ultrasonic waves. The present invention relates to a low-cost alternative emulsified fuel that is manufactured by making it available and used for drying industrial and agricultural and marine products, and a method for manufacturing the same.

代替燃料とは、ガソリンなどの価格が高く、埋蔵量が限定された石油エネルギーの代わりに産業や多様な用途として使うための燃料を言い、本発明では、特に産業用や農水産物の乾燥時に有用に使われうる代替乳化燃料に関する。   An alternative fuel is a fuel that is used for various purposes and industries instead of petroleum energy, which has a high price such as gasoline and has limited reserves. In the present invention, it is useful especially for drying industrial products and agricultural and marine products. The present invention relates to an alternative emulsified fuel that can be used.

このような代替燃料は、国内の高油価によって多くの産業現場で負担を抱いている問題点を解決するために、その代案として提案されている。
現在、各種の産業現場で多くのボイラー暖房油が必要となる。現在使用中である練炭及びバンカーC油をエネルギーとして使う場合は、環境問題が深刻で長期間にわたる使用が不可能であり、灯油及び軽油などの暖房油は産業現場でコスト高が深刻であるために、さらに低廉な産業燃料の開発が要求されている実情である。
Such alternative fuels have been proposed as an alternative to solve the problems that are burdened in many industrial sites due to high oil prices in the country.
Currently, many boiler heating oils are required in various industrial sites. When briquettes and bunker C oil currently in use are used as energy, environmental problems are serious and cannot be used over a long period of time, and heating oil such as kerosene and light oil is very expensive at industrial sites. Furthermore, there is a demand for the development of cheaper industrial fuels.

しかし、実に石油などの油価は持続的に上昇しているが、それほどの効率を奏しうる代替燃料は提示されていない。
特に、廃油及びバンカーC油などの低廉な燃料を加工して環境にやさしい代替燃料として新たに活用できる方案が要求されている。
米国特許第5,993,496号明細書 米国特許第4,347,061号明細書
However, although oil prices such as oil have continued to rise, no alternative fuel that can achieve such efficiency has been proposed.
In particular, there is a demand for a method that can process inexpensive fuels such as waste oil and bunker C oil and use them as environmentally friendly alternative fuels.
US Pat. No. 5,993,496 US Pat. No. 4,347,061

本発明は、前述したような従来技術の問題点を解決するために案出されたものであって、バンカーC油(bunker fuel oil C)及びカーバイド(CaC)を主原料にして水(HO)を混合して産業現場でのコストダウンするために提供される代替乳化燃料を提供することを目的とする。 The present invention has been devised to solve the problems of the prior art as described above, and is based on water (H) using bunker fuel oil C and carbide (CaC 2 ) as main raw materials. An object of the present invention is to provide an alternative emulsified fuel provided for mixing 2 O) to reduce the cost in the industrial field.

また、本発明は、水を十分に混合して水と油とが高度に凝集された状態の化合物として共に燃焼される代替乳化燃料を提示することによって、製造コスト及び供給コストを低めて産業現場の費用負担を軽減させうる代替燃料を提示することを目的とする。   The present invention also provides an alternative emulsified fuel that is thoroughly mixed with water and combusted together as a highly agglomerated compound of water and oil, thereby reducing manufacturing and supply costs to the industrial site. The purpose is to present an alternative fuel that can reduce the cost burden.

本発明は、前述したような目的を解決するために案出されたものであって、本発明による代替乳化燃料は、バンカーC油70〜80重量%とカーバイド0.1〜1重量%を水に溶解してなされたカーバイド水溶液20〜30重量%とを混合してなされた混合物100重量部に対して、塩化カルシウム0.5〜2重量部が混合されていることを特徴とする。   The present invention has been devised in order to solve the above-mentioned object, and the alternative emulsified fuel according to the present invention contains 70 to 80% by weight of bunker C oil and 0.1 to 1% by weight of carbide. 0.5 to 2 parts by weight of calcium chloride is mixed with 100 parts by weight of a mixture formed by mixing 20 to 30% by weight of an aqueous solution of carbide formed by dissolving in 1%.

また、本発明による代替乳化燃料の製造方法は、バンカーC油70〜80重量%とカーバイド水溶液20〜30重量%とを混合して加熱した後に撹拌する段階と、前記撹拌された混合物を20KHz〜1MHzの超音波を20〜30分間照射する段階と、前記混合物バンカーC油とカーバイド水溶液との混合物100重量部に対して乳化剤として塩化カル
シウム0.5〜2重量部を混合した後、乳化機内で1000〜1200rpmで高速回転させて乳化処理する段階と、を含んでなることを特徴とする。
Further, the method for producing an alternative emulsified fuel according to the present invention comprises a step of mixing and heating 70 to 80% by weight of bunker C oil and 20 to 30% by weight of an aqueous carbide solution, and stirring the stirred mixture from 20 KHz to In the emulsifying machine, 0.5 to 2 parts by weight of calcium chloride as an emulsifier is mixed with 100 parts by weight of the mixture of the bunker C oil and the aqueous carbide solution, after irradiating ultrasonic waves of 1 MHz for 20 to 30 minutes. And a step of emulsifying by rotating at a high speed of 1000 to 1200 rpm.

前述したように構成される本発明によれば、産業現場の高費用を本発明による代替乳化燃料を用いて十分に減らしうる。
また、軽油などの高価のエネルギーを節約でき、練炭及びバンカーC油のように燃焼後に発生する環境汚染物質を大幅に減らしうる。
According to the present invention configured as described above, the high cost of the industrial field can be sufficiently reduced by using the alternative emulsified fuel according to the present invention.
Further, expensive energy such as light oil can be saved, and environmental pollutants generated after combustion such as briquettes and bunker C oil can be greatly reduced.

また、水がおおよそ20〜30重量%が投入された化合物を作ることによって、その分量ほどが代替燃料として転換され、高価の油を節約できる代替燃料を提供する。
前述したような効果は、本発明による効果の一部に過ぎず、当業者ならば、本発明の技術的思想の範疇を外れない範囲内でいくらでも変更実施が可能である。
Further, by making a compound in which approximately 20 to 30% by weight of water is added, the amount is converted as an alternative fuel, thereby providing an alternative fuel that can save expensive oil.
The effects as described above are only a part of the effects of the present invention, and those skilled in the art can make any number of modifications without departing from the scope of the technical idea of the present invention.

以下、添付された図面を参照しながら本発明を一実施形態による代替乳化燃料及びその製造方法を詳しく説明すれば、次のようである。
先ず、本発明の一実施形態で混合される原料を説明すれば、次のようである。
本発明による代替乳化燃料を製造するためには、先ず、バンカーC油と、水にカーバイドを溶解して作ったカーバイド水溶液と、塩化カルシウム(CaCl)、そして、超音波機などを準備する。
Hereinafter, an alternative emulsified fuel and a method of manufacturing the same according to an embodiment of the present invention will be described in detail with reference to the accompanying drawings.
First, raw materials to be mixed in one embodiment of the present invention will be described as follows.
In order to produce an alternative emulsified fuel according to the present invention, first, bunker C oil, an aqueous carbide solution prepared by dissolving carbide in water, calcium chloride (CaCl 2 ), and an ultrasonic machine are prepared.

本発明に使われる塩化カルシウムとカーバイド水溶液は、バンカーC油などの粘性を落とす役割を果たし、超音波は、後で混合される物質どうしで化学反応を起こして油水分離が起きないようにする役割を果たす。   The calcium chloride and carbide aqueous solution used in the present invention plays a role of reducing the viscosity of bunker C oil and the like, and the ultrasonic wave plays a role in preventing chemical separation between substances mixed later and preventing oil-water separation. Fulfill.

本発明でバンカーC油、カーバイド水溶液、塩化カルシウムが混合される割合を説明すれば、次のようである。
本発明による代替乳化燃料は、バンカーC油70〜80重量%とカーバイド水溶液20〜30重量%とからなる混合物100重量部に対して、塩化カルシウム0.5〜2重量部が混合されている。カーバイド水溶液は、カーバイド0.1〜1重量%を水(HO)99〜99.9重量%に溶解して製造されたものを使う。
The ratio of the bunker C oil, the aqueous carbide solution, and calcium chloride in the present invention will be described as follows.
In the alternative emulsified fuel according to the present invention, 0.5 to 2 parts by weight of calcium chloride is mixed with 100 parts by weight of a mixture of 70 to 80% by weight of bunker C oil and 20 to 30% by weight of an aqueous carbide solution. The carbide aqueous solution is prepared by dissolving 0.1 to 1% by weight of carbide in 99 to 99.9% by weight of water (H 2 O).

前記のようなバンカーC油とカーバイド水溶液との混合割合は、水がおおよそ20〜30重量%程度が投入された化合物を製造することでそれほどを代替燃料として切換えて製造コストを節減するためのことであり、水の混合量が多すぎる場合、燃料としての効率が落ちるために前記のような混合割合が適当である。   The mixing ratio of the bunker C oil and the carbide aqueous solution as described above is to reduce the manufacturing cost by switching so much as an alternative fuel by producing a compound in which about 20 to 30% by weight of water is added. In the case where the amount of water mixed is too large, the above-mentioned mixing ratio is appropriate because the efficiency as fuel decreases.

また、塩化カルシウムは、互いに混合しないバンカーC油と水とを安定したエマルション状態を維持させる乳化剤としての役割を果たし、前記のような混合割合で混合すれば十分な乳化役割を果たす。   In addition, calcium chloride serves as an emulsifier that maintains a stable emulsion state of bunker C oil and water that are not mixed with each other.

このような割合で作られた代替乳化燃料は、燃料の効率が高く、燃焼時に発生する煤煙が少なくて効果的な代替燃料として使用が可能である。
次に、本発明による代替乳化燃料の製造方法をその望ましい実施形態によって説明する。
The alternative emulsified fuel produced at such a ratio has high fuel efficiency and can be used as an effective alternative fuel with less soot generated during combustion.
Next, a method for producing an alternative emulsified fuel according to the present invention will be described according to preferred embodiments.

図1には、本発明による代替乳化燃料を製造する工程を概略的に表わした図面が図示されている。
本発明では、バンカーC油70〜80重量%、カーバイド水溶液20〜30重量%とを
混合する。バンカーC油とカーバイド水溶液とを混合すれば、通常的に混合される物質が自発的には均一に結合がなされない。したがって、バンカーC油70〜80重量%とカーバイド水溶液20〜30重量%とを混合した後に混合される物質間に化学結合を促進するために混合物を70ないし100℃で加熱し、80〜90℃に加熱することがさらに望ましい。
FIG. 1 schematically illustrates a process for producing an alternative emulsified fuel according to the present invention.
In the present invention, 70 to 80% by weight of bunker C oil and 20 to 30% by weight of an aqueous carbide solution are mixed. If the bunker C oil and the aqueous carbide solution are mixed, the normally mixed substances are not spontaneously bonded uniformly. Accordingly, the mixture is heated at 70 to 100 ° C. to promote chemical bonding between the substances to be mixed after mixing 70 to 80% by weight of Bunker C oil and 20 to 30% by weight of an aqueous carbide solution. It is more desirable to heat to

このように加熱処理と共に真空混合機で90ないし120rpmで10ないし30分間真空状態で混合させる。
このとき、各化合物を構成する成分間には、80〜90℃に加熱処理と真空混合機で加えられる回転によってイオン結合がより一層活発に誘導されることが公知である。
In this way, the mixture is mixed in a vacuum state at 90 to 120 rpm for 10 to 30 minutes together with the heat treatment.
At this time, it is known that ionic bonds are more actively induced between components constituting each compound by heat treatment at 80 to 90 ° C. and rotation applied by a vacuum mixer.

約30分程度加熱した後、前記混合物を超音波機を通過させながら20KHz〜1MHzの超音波を20〜30分間照射してバンカーC油などにおける粘性を低め、分子間の運動を活発にして分子相互間に化学結合をより一層促進させることが望ましい。   After heating for about 30 minutes, the mixture is passed through an ultrasonic machine and irradiated with ultrasonic waves of 20 KHz to 1 MHz for 20 to 30 minutes to reduce the viscosity in the bunker C oil, etc. It is desirable to further promote chemical bonding between each other.

以後、前記のように超音波を照射させてイオン結合が十分になされた後には、バンカーC油とカーバイドとの混合物に乳化剤として塩化カルシウム(CaCl)を混合して乳化機に入れて高速回転させて乳化処理を行う。このとき、塩化カルシウムの混合割合は、バンカーC油とカーバイド水溶液との混合物100重量部に対して約0.5〜2重量%を混合することが望ましい。 Thereafter, after sufficient ion binding is achieved by irradiating with ultrasonic waves as described above, calcium chloride (CaCl 2 ) is mixed as an emulsifier with a mixture of bunker C oil and carbide and put into an emulsifier to rotate at high speed. And emulsifying. At this time, the mixing ratio of calcium chloride is desirably about 0.5 to 2% by weight with respect to 100 parts by weight of the mixture of the bunker C oil and the aqueous carbide solution.

本発明の望ましい実施形態では、塩化カルシウムをバンカーC油とカーバイド水溶液との混合物に超音波を照射させた後、乳化機に入れる前に添加したが、塩化カルシウムはバンカーC油とカーバイド水溶液と混合する時に同時に混合することも可能である。   In a preferred embodiment of the present invention, calcium chloride is added to the mixture of bunker C oil and an aqueous carbide solution after irradiating the ultrasonic wave and before entering the emulsifier, but the calcium chloride is mixed with the bunker C oil and the aqueous carbide solution. It is also possible to mix at the same time.

このように、バンカーC油とカーバイド水溶液とを加熱及び回転してイオン結合が十分になされた後には、この混合物に乳化剤として塩化カルシウムを添加して乳化機内で高速、例えば、1000ないし1200rpmで所定時間に回転させて乳化処理を行う。このとき、油と水とが区別できず、水分子はさらに小さな水分子に分離され、油分子と結合がなされ、別に水分子どうしで凝集がなされる状態である油水分離が発生しない。   In this way, after the bunker C oil and the aqueous carbide solution are heated and rotated to sufficiently bond ions, calcium chloride is added as an emulsifier to the mixture and a predetermined speed is set in the emulsifier, for example, 1000 to 1200 rpm. Emulsify by rotating over time. At this time, oil and water cannot be distinguished, and water molecules are separated into smaller water molecules, combined with oil molecules, and oil-water separation, which is a state where water molecules are separately aggregated, does not occur.

このような混合割合と製造工程で燃料を作って見たところ、燃料の効率が高く、燃焼時に発生する煤煙などが著しく減ることと表われた。
一方、カーバイド水溶液を作る時に入る多量の水は、バンカーC油及び塩化カルシウムなどに混合される物質と化学反応を起こして代替燃料として転換がなされ、これにより、軽油や灯油などの燃料を代替する代替燃料が製造される。
When fuel was made with such a mixing ratio and manufacturing process, it was found that the efficiency of the fuel was high, and soot generated during combustion was significantly reduced.
On the other hand, a large amount of water entering when making an aqueous carbide solution undergoes a chemical reaction with substances mixed with bunker C oil and calcium chloride, and is converted as an alternative fuel, thereby replacing fuels such as light oil and kerosene. Alternative fuel is produced.

前記段階を経れば、本発明による乳化代替燃料が作られ、他の従来技術とは異なってカーバイド水溶液を準備する段階で多量の水が代替燃料として転換される効果をもたらす。
前述したように、本発明は、バンカーC油とカーバイド水溶液と塩化カルシウムとを混合して加熱撹拌させた後、20KHz〜1MHzの超音波を照射してイオン結合を誘導した後、油水分離が起きないように乳化機内で高速回転させてなされるものであって、従来の石油などの燃料を代替しうる乳化燃料である。
Through the above steps, an emulsified alternative fuel according to the present invention is produced, and unlike other prior art, a large amount of water is converted as an alternative fuel in the step of preparing an aqueous carbide solution.
As described above, according to the present invention, bunker C oil, an aqueous carbide solution, and calcium chloride are mixed and heated and stirred, and after irradiating an ultrasonic wave of 20 KHz to 1 MHz to induce ionic bonds, oil-water separation occurs. This is an emulsified fuel that is rotated at high speed in an emulsifier so that it can replace a conventional fuel such as petroleum.

本発明は、代替乳化燃料及びその製造方法に関連する技術分野に適用されうる。   The present invention can be applied to technical fields related to alternative emulsified fuels and production methods thereof.

本発明による代替乳化燃料の製造工程を概略的に表わしたフローチャート。The flowchart which represented roughly the manufacturing process of the alternative emulsification fuel by this invention.

Claims (4)

バンカーC油70〜80重量%と、カーバイド0.1〜1重量%を水に溶解したカーバイド水溶液20〜30重量%とを混合した混合物100重量部に対して、塩化カルシウム0.5〜2重量部が混合されていることを特徴とする代替乳化燃料。 Calcium chloride 0.5 to 2 weight with respect to 100 weight parts of a mixture of 70 to 80 weight% bunker C oil and 20 to 30 weight% carbide aqueous solution in which 0.1 to 1 weight% carbide is dissolved in water. An alternative emulsified fuel characterized in that parts are mixed. バンカーC油70〜80重量%とカーバイド水溶液20〜30重量%とを混合して加熱及び撹拌する工程と、
前記撹拌された混合物のイオン結合を誘導するために20KHz〜1MHzの超音波を20〜30分間照射する工程と、
前記混合物の油水分離が生じないようにバンカーC油とカーバイド水溶液との混合物100重量部に対して乳化剤として塩化カルシウム0.5〜2重量部を混合した後、乳化機内で1000〜1200rpmで高速回転させて乳化処理する工程とを備えることを特徴とする代替乳化燃料の製造方法。
Mixing and heating and stirring 70-80% by weight of bunker C oil and 20-30% by weight of an aqueous carbide solution;
Irradiating with ultrasonic waves of 20 KHz to 1 MHz for 20 to 30 minutes to induce ionic bonding of the stirred mixture;
After mixing 0.5 to 2 parts by weight of calcium chloride as an emulsifier with 100 parts by weight of a mixture of bunker C oil and an aqueous carbide solution so that oil / water separation of the mixture does not occur, the mixture is rotated at 1000 to 1200 rpm in an emulsifier. And an emulsification treatment step, and a method for producing an alternative emulsified fuel.
前記カーバイド水溶液は、カーバイド0.1〜1重量%を水99〜99.9重量%に溶解してなることを特徴とする請求項2に記載の代替乳化燃料の製造方法。 The method for producing an alternative emulsified fuel according to claim 2, wherein the carbide aqueous solution is obtained by dissolving 0.1 to 1% by weight of carbide in 99 to 99.9% by weight of water. 前記加熱及び撹拌する工程は、撹拌機で80〜90℃に加熱しながら90ないし120rpmで10ないし30分間撹拌することを特徴とする請求項2または3に記載の代替乳化燃料の製造方法。 The method for producing an alternative emulsified fuel according to claim 2 or 3, wherein in the heating and stirring step, stirring is performed at 90 to 120 rpm for 10 to 30 minutes while heating to 80 to 90 ° C with a stirrer.
JP2007193450A 2006-11-28 2007-07-25 Alternative emulsified fuel and preparation process thereof Pending JP2008133428A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56159291A (en) * 1980-05-12 1981-12-08 Hirakawa Tekkosho:Kk Removal of sulfur oxide and nitrogen oxide
JPH1121571A (en) * 1997-07-07 1999-01-26 Torao Hashimoto W/o heavy oil/water emulsion fuel, additive therefor, emulsifying equipment and method for combusting heavy oil
WO2004004881A1 (en) * 2002-07-09 2004-01-15 Toshiba Plant Systems & Services Corporation Liquid mixing apparatus and method of liquid mixing
JP2006111666A (en) * 2004-10-12 2006-04-27 Jfe Engineering Kk Emulsion fuel production method, emulsion fuel production apparatus, and emulsion fuel utilization apparatus equipped with the emulsion fuel production apparatus.

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1233278A (en) * 1968-10-23 1971-05-26
KR880000066B1 (en) * 1985-05-13 1988-02-22 주식회사 삼아상역 Apparatus for manufacturing substituting oil of heavy oil
JPH01313594A (en) * 1988-06-10 1989-12-19 Kao Corp Ultraheavy oil emulsion fuel
JP3236249B2 (en) * 1997-09-03 2001-12-10 廣次 野原 Oil-water emulsion fuel
CN1134532C (en) * 1998-07-03 2004-01-14 株式会社吴竹精升堂 Water-in-oil emulsified fuel oil

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56159291A (en) * 1980-05-12 1981-12-08 Hirakawa Tekkosho:Kk Removal of sulfur oxide and nitrogen oxide
JPH1121571A (en) * 1997-07-07 1999-01-26 Torao Hashimoto W/o heavy oil/water emulsion fuel, additive therefor, emulsifying equipment and method for combusting heavy oil
WO2004004881A1 (en) * 2002-07-09 2004-01-15 Toshiba Plant Systems & Services Corporation Liquid mixing apparatus and method of liquid mixing
JP2006111666A (en) * 2004-10-12 2006-04-27 Jfe Engineering Kk Emulsion fuel production method, emulsion fuel production apparatus, and emulsion fuel utilization apparatus equipped with the emulsion fuel production apparatus.

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