JP2008133240A - Method for preventing insect pest damage - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for preventing the insect pest damages of plant seeds, their grown plants, stored grains, stored beans, stored fruits, stored vegetables, stored feeds, stored flowering plants, and/or exported or imported woods, by an application method such as a spraying treatment, a smearing treatment, a dipping treatment, a dust-coating treatment, a coating treatment, a fumigation/smoking treatment, or a pressure-injection. <P>SOLUTION: This method for preventing the insect pest damages is characterized by applying a composition containing at least one chloronicotinyl-based insecticide and at least one pyrethrin or synthetic pyrethroid as active ingredients to plant seeds, stored grains, stored beans, stored fruits, stored vegetables, stored feeds, stored flowering plants, and/or exported or imported woods. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

  The present invention relates to a composition containing at least one chloronicotinyl insecticide and at least one pyrethrin or synthetic pyrethroid as an active ingredient in plant seeds, stored grains, stored beans, stored fruits, stored vegetables, stored feed, stored The present invention relates to a method for preventing damage to insects by applying to flower buds and import / export wood.

  Pest control is extremely important for agriculture. Pest damage can occur not only in the above-ground parts of plants but also in soil. Most of the damage in the soil is caused by eating pests that damage the roots, i.e. plant roots, or by entering plant pathogens from damaged sites that have been harmed by the pests.

  Seed germination, sprouting, and initial plant growth are particularly important because the roots and stems of the growing plants are small and the entire plant can wither even in small amounts of damage. Control of pests that attack seeds and plant parts on the ground during the initial stage of plant growth has been variously studied in the agricultural field. Currently, it is common to apply pesticides mainly to soil or foliage to control pests that harm crops after germination.

  The foliage treatment needs to be performed when pests are present in order to be most effective. For this reason, there are cases where the effect cannot be exerted when the chemical treatment is difficult due to rainfall or the like. Furthermore, in order to efficiently control pests, it is necessary to closely observe the occurrence of pests. It is known that a synthetic pyrethroid agent exhibits an excellent control effect against lepidopterous pests such as weevil by applying to the soil surface as such a foliar treatment agent or at the time of sowing. However, since this type of insecticide is extremely toxic to aquatic organisms such as fish, great attention must be paid to spillage during soil surface treatment or foliage spraying or transfer to water due to drift.

  It has also been found that when two or more pesticide compositions are used, a greater control effect can be obtained than when each one pesticide is used alone. For example, a composition of fenpropatoline and hexythiazox against spider mites is given as an example. Similar examples include phosmet and diflubenzuron (US Pat. No. 4,382,927), O-ethyl-O- [4- (methylthio) phenyl] -S-propylphosphodithioate and N ′-(4-chloro -O-tolyl) -N, N-dimethylformamidine (U.S. Pat. No. 4,053,595), Bacillus thuringiensis and chlordimeform (U.S. Pat. No. 3,937,813), decamethrin and optionally propoxur. Containing dichlorvos (US Pat. No. 4,863,909), fenvalerate and phosmet (US Pat. No. 4,263,287), hosalon and malathion (US Pat. No. 4,064,237), etc. Has been reported. However, these compositions are applied to plants in the form of foliage application or granule treatment to soil.

  At present, the technology for protecting plants from damage caused by pests by plant foliage treatment and seed treatment is rapidly progressing, but some problems can still be pointed out. For example, it is useful if the amount of pesticide used can be further reduced. In addition, it is useful if it is possible to protect the crops in a wider range than the effect of a plant introduced with a gene to produce an agrochemical active substance or an insecticidal active substance alone.

  Chloronicotinyl insecticides such as imidacloprid, thiacloprid, clothianidin, thiamethoxam, nitenpyram, and acetamiprid are applied as an insecticidal compound, such as foliage spraying treatment, submerged spraying treatment, etc. Hemiptera pests such as cotton aphids, stag beetles, southern stink bugs, Coleoptera such as rice weevil, horned beetle, diptera such as house flies and leafhoppers, thrips such as thrips, and thrips It is known to be effective against lepidopterous insects. A method of treating seeds with a mixed composition of clothianidin and pyrethroid among these compound groups is described in JP-T-2004-522699. However, the description is limited to the seed treatment of teflutrin, and there is no description suggesting that pest damage can be prevented by applying it to stored cereals, stored beans, stored fruits, stored vegetables, stored feed, and stored florets. Furthermore, although seed treatment with lambda cihalothrin alone is described, there is no description showing that seed treatment is useful in combination with clothianidin. A method for treating seeds with a mixed composition of thiamethoxam and pyrethroid is described in WO2002-030201. However, the description is limited to the seed treatment of teflutrin, and there is no description suggesting that pest damage can be prevented by applying it to stored cereals, stored beans, stored fruits, stored vegetables, stored feed, and stored florets. Further, although seed treatment with lambda cihalothrin alone is described, there is no description showing that seed treatment is useful in combination with thiamethoxam.

Thus, in any document, the composition of chloronicotinyl insecticide and pyrethroid is sprayed on stored cereals, stored beans, stored fruits, stored vegetables, stored feed, stored flower buds, and imported / exported wood, There is a description showing that pest damage to plants and plants grown from these can be prevented by application methods such as smearing treatment, dipping treatment, powder coating treatment, coating treatment, fumigation / smoke treatment, pressure injection, etc. Absent.
U.S. Pat. No. 4,382,927 U.S. Pat. No. 4,053,595 U.S. Pat. No. 3,937,813 U.S. Pat. No. 4,863,909 U.S. Pat. No. 4,263,287 U.S. Pat. No. 4,064,237 JP-T-2004-522699 WO2002-030201

  The object of the present invention is to provide plant seeds, plants grown from them, and stored cereals by application methods such as spraying, smearing, dipping, dressing, coating, fumigation / smoke treatment, and pressure injection. It is intended to provide a method for preventing pest damage on stored beans, stored fruits, stored vegetables, stored feed, stored flower buds, and imported / exported wood.

  As a result of intensive studies in view of such circumstances, the present inventors have found that a composition comprising at least one chloronicotinyl insecticide and at least one pyrethrin or synthetic pyrethroid as an active ingredient is sprayed, smeared, or immersed. The present inventors have found a method that shows a high preventive effect on a plurality of pests at a low dose by application methods such as treatment, powder coating treatment, coating treatment, fumigation / smoke treatment, and pressure injection.

  That is, the present invention relates to Formula 1 (Formula 1)

[Wherein X represents CH or N;
Y represents a nitro group or a cyano group;
R ¹ represents a 2-chloro-5-pyridyl group, a 2-chloro-5-thiazolyl group;
R ² is hydrogen, methyl group, ethyl group;
R ³ represents a methyl group or a group represented by NHR ⁴ or SR ⁵ (where R ⁴ represents hydrogen, a methyl group or an ethyl group, and R ⁵ represents a methyl group or an ethyl group);
Or R ² and R ⁴ together represent an ethylene group, a trimethylene group, a group represented by CH ₂ OCH ₂ , or a group represented by CH ₂ N (R ⁶ ) CH ₂ (where R ⁶ represents C _{1 -6 represents} an alkyl group);
Or R ² and R ⁵ together represent an ethylene group]
2-allyl-4-hydroxy of 2,2-dimethyl-3- (2-methylpropenyl) -cyclopropanecarboxylic acid comprising at least one compound selected from the group consisting of compound [I] -3-Methyl-2-cyclopenten-1-one ester, 2,2-dimethyl-3- (2-methylpropenyl) -cyclopropanecarboxylic acid (2-methyl-1-propenyl) -2-methoxy-4- Oxo-3- (2propenyl) -2-cyclopenten-1-yl ester, fenvalerate, esfenvalerate, permethrin, cypermethrin, beta-cypermethrin, thetacypermethrin, zeta-cypermethrin, deltamethrin, fenpropatoline, Tau-fulvalinate, tefluthrin, flucitrinate, flumethrin, Flutrin, betacyfluthrin, transfluthrin, acrinatrin, alpha-cypermethrin, tralomethrin, cycloprotorin, cyhalothrin, lambda cihalothrin, bifenthrin, cadetrin, resmethrin, violesmethrin, tetramethrin, phenothrin, empentrin, pratrithrin, proretrin Seed, stored cereals, stored beans, stored fruit, storage, containing at least one pyrethrin or synthetic pyrethroid selected from the group consisting of alletrin, bioalletrin, etofenprox, silafluophene and mixtures thereof as an active ingredient It is a method for preventing pest damage characterized by being applied to vegetables, stored feed, stored flower buds, and imported / exported wood.

  The method of the present invention has a high preventive effect on pest damage occurring on plant seeds, plants grown from plant seeds, stored cereals, stored beans, stored fruits, stored vegetables, stored feed, stored flower buds, and imported / exported wood. Indicates. This method is effective in reducing the amount of treatment, and is more advantageous in terms of phytotoxicity to the seed than treating each of them alone.

Specific examples of pests that cause damage that can be prevented by the method of the present invention include:
Orthoptera (orthoptera): as BLATTIDAE, American cockroach (Periplaneta americana), black cockroach (Periplaneta fuliginosa), Yamato cockroach (Periplaneta japonica), etc., as BLATTELLIDAE, German cockroach (Blattella germanica), Hime German cockroach (Blattella lituricollis), etc., as TETTIGONIIDAE , Homocoryphis jezoensis, Hokurorihus lineosus, etc., GRYLLOTALIDIDAE, etc., Gryllotalpa sp., Etc., ACIDIDAE, Nago (Oxya hyla intricata), Kobaneinago (Oxya yezoensis), etc.,
Termites (ISOPTERA): Cryptoptermes domesticus, Copterterms formosanus, Reticulitermes formosanus, Odontotermes, etc.
Thysanoptera (THYSANOPTERA): as THRIPIDAE, grasses thrips (Anaphothrips obscurus), thorns but-thrips (Chirothrips manicatus), tea Roh black thrips (Dendrothrips minowai), Hirazuhanaazamiuma (Frankliniella intonsa), lily flower thrips (Frankliniella lilivora), Croton thrips ( Heliotrips haemorrhoidalis, Microcephalotrips abdominalis, Soybean thrips (Mycterothrips glycines), Pseudodendroth ips mori), yellow tea thrips (Scirtothrips dorsalis), red Obi thrips (Selenothrips rubrocinctus), rice thrips (Stenchaetothrips biformis), green onions black thrips (Thrips alliorum), loquat Hana thrips (Thrips coloratus), Yellow Hana thrips (Thrips flavas) , Hana thrips (Trips palae), Thrips nigropirusus, (Thrips palmi), Cyclelini larva ps setosus), gladiolus thrips (Thrips simplex), green onion thrips (Thrips tabaci) and the like,
As PHLAEOTHRIPIDAE, rice Kuda thrips (Haplothrips aculeatus), Sina Kuda thrips (Haplothrips chinensis), Hana Kuda thrips (Haplothrips kurdjumovi), clover Kuda thrips (Haplothrips nigar), Castanopsis tailed Kuda thrips ((Leeuwania pasanii), hex Kuda thrips (Liothrips floridensis), Lithripps vaneeckei, Lithototrips pasaniae, Phytothrips diospyrosi, etc.
HEMIPTERA: As PENTATOMIDAE, Carpocoris purpureipennis, T. terridium moth, D. moss. Eysarcoris lewisi), Scarab beetle (Eysarcoris parvus), Shirahoshi stink bug (Eysarcoris ventralis), Glutenia physalis (Glaucias submuctus) Worms (Halyomorpha mista), Inekamemushi (Lagynotomus elongatus), order Hemiptera (Nezara antennata), southern green stink bug (Nezara viridula), Piezodorus stink bug (Piezodorus hybneri), Plautia crossota stali (Plautia stali), rice black bug (Scotinophara lurida) , Iwasaki stink bug (Stariodes iwasakii), etc.
As COREIDAE, Akathocoris sorididus, Anopheles helicopter (Acanthocoris striicoris), Akaterochoris tersitoris (Cretus puntiger), Cestus urchini (Cetus urushimushi)
As ALYDIDAE, Leptocorisa acuta, Leptocorisa chinensis, Leptocorisa oratorius, Riptoratus, etc.
As RHOPALIDAE, red beetle helicopter (Aeschynteles maculatus), red beetle helicopter (Liorhyssus hyalinus), etc.,
As LYGAEIDAE, Caveerus saccharivorus, Hosochobane moth, Macros obumbilus, Pirobrachius uridus
As PYRRHOCORIDAE, red beetle bugs (Dysdercus singulatus), red beetle bugs (Dysdercus poecilis), etc.,
As TINGIDAE, Kikugunbai (Galeatus spinifrons), Yanagigunbai (Metasalis populi), Kusugunbai (Stephanitis fasciicarina), Nashigunbai (Stephanitis Sashi), Tsutsujigunbai (Stephanitis pyrioides), Himegunbai (Uhlerites debile), Kurumigunbai (Uhlerites latius) or the like,
As MIRIDAE, Acyrthosiphon Miridae (Adelphocoris lineolatus), butyrate beard black Miridae (Adelphocoris triannulatus), Koaokasumikame (Apolygus lucorum), blacktip reef shark Ao Miridae (Apolygus spinolai), red-spotted Miridae Creontiades pallidifer), tobacco Miridae (Cyrtopeltis tennuis), Ookuro Tobika turtle (Ectometopterus micanthulus), Black-headed turtle (Halticiellus insularis), Apple-headed turtle (Heterocordylus flavipes), Makiba-kasumi turtle (Lygus disponsi), Madara Kasumi turtle (Lygus saundersi), sugar beet Miridae (orthotylus flavosparsus), Mugikasumikame (Stenodema calcaratum), lid streaks Kasumi turtle (Stenotus binotatus), red streaks Kasumi turtle (Stenotus rubrovittatus), mouse Mont green Miridae (Taylorilygus pallidulus), Trigonotylus caelestialium (Trigonotylus coesteriaium) etc.,
As CICADIDAE, large brown cicada (Graptopsaltria nigrofuscata), etc., as APHROPHORIDAE, Maekiawafuki (Aphrophora costalis), Matsuawafuki (Aphrophora flavipes), Budouawafuki (Aphrophora intermedia), Princess lid ten Naga Awa butterbur (Clovia punctata), Hosoawafuki (Philaenus spumarius), etc.,
As TETIGELLIDAE, the bluefin leafhopper (Bothrogonia japonica), the leafhopper (Cicellaella viridis), etc.
As CICADELLIDAE, Aguriana ferracea (Aguriahanaquarcus), Arneidia alnesida (Anetodiarias), Aphedonia ferrigeniae, Arboridia aeridis, and Arberidia aeridis. , Empoasca abietis, Empoasca onukii, Tia subrufa, Zyginella citri, etc.
As DELTOCEPHALIDAE, lid Ten leafhopper (Macrosteles fascifrons), green rice leafhopper (Nephotettix cincticeps), cross di leafhopper (Nephotettix nigropictus), Taiwan green rice leafhopper (Nephotettix virescens), apple spotted leafhopper (Orientus ishidai), Inazuma leafhopper (Recilia dorsalis), Mugiyokobai (Sorhoanus tritici), Hannonagayokobai (Speusotettix subfusculus), etc.,
As DELPHACIDAE, small brown planthopper (Laodelphax striatellus), brown planthopper (Nilaparvata lugens), sugar Roh Humpback planthopper (Numata muiri), corn planthopper (Peregrinus maidis), Crofts Roh planthoppers (Perkinsiella saccharicida), Sejirounka (Sogatella furcifera), Hieunka (Sogatella panicicola) etc,
As PSYLLIDAE, Kuwakijirami (Anomomeura mori), Seguro Hime pheasant Rami (Calophya nigridorsalis), Diaphorina citri (Diaphorina citri), Yamaasakijirami (Mesohomotoma camphorae), Todokijirami (Psylla abieti), Han'nokijirami (Psylla alni), Yamatokijirami (Psylla jamatonica), apple Whale (Psylla mary), Black apple killer whale (Psylla maryvorella), Psylla pyrisuga, Psylla tobirae (Psylla tobirae), Trichoa cricket a quercicola), etc.,
As ALEYRODIDAE, citrus whitefly (Aleurocanthus spiniferus), grape whitefly (Aleurobus taurabia), tobacco whitefly (Bemisia tabaci), citrus whitefly (Dialeurodosa radica)
As PHYLOXERIDAE, grape aphids (Viteus vitifolii), etc., as PEMPHIGIDAE, apple aphids (Aphidonugalis mary), apple beetles (Eriosoma lanigerum), sugar beetle (Geioglu, etc.)
Pea aphid as APHIDIDAE (Acyrthosiphon pisum), Spiraea aphid (Aphis citricola), bean aphid (Aphis craccivora), willow aphid (Aphis farinose yanagicola), cotton aphid (Aphis gossypii), potato aphid (Aulacorthum solani), wheat straw chrysanthemum Omar aphids (Brachycadus helichrysi), radish aphids (Brevicoryne brassicae), tulip aphids (Dysaphis tulipae), eucaphipsis puntipennis, Moko butterbur aphid (Hyalopterus pruni), fake radish aphid (Lipaphis erysimi), chrysanthemum Princess aphid (Macrosiphoniella sanborni), tulip aphid (Macrosiphum euphorbiae), broad bean aphid (Megoura crassicauda), without Coffs key aphid (Melanaphis siphonella), Ringokobu Aphids (Myzus malisuctus), Japanese aphids (Myzusumecocola), peach aphids (Myzus persicae), Nephipodera (Neotoxoptera formosana), Omidori aramushi (Ovatu) malicolens), lotus constricted aphids (Rhopalosophum nymphaeae), wheat constricted aphid (Rhopalosophum padi), Oka Bono aphid (Rhopalosophum rufiabdominalis), no circle aphid (Sappaphis piri), pear aphid (Schizaphis piricola), wheat aphid (Sitobion akebiae) , Sitbion ibarae, Toxoptera aurantii, Toxoptera citricidus, Plumbing aphid (Tuberocephalus momonis) Aphid (Uroeucon formosanum), etc.,
As MARGARODIDAE, the scale insect (Doshicha corporenta), the scale insect (Icerya purchasi), etc.,
As PSEUDOCOCCIDAE, Matsumoto mealybugs (Crisicoccus matsumotoi), pine mealybug (Crisicoccus pini), without mealybugs (Dysmicoccus wistariae), mandarin orange mealybug (Planococcus citri), mealybug (Planococcus kranuhiae), mandarin orange Hime mealybugs (Pseudococcus citriculus ), Pseudococcus comstock, etc.,
As COCCIDAE, Tsunoroumushi (Ceroplastes ceriferus), Rubiroumushi (Ceroplastes rubens), mandarin orange Hirata scale insects (Coccus discrepans), Hirata Kata scale insects (Coccus hesperidum), citrus Kata scale insects (Coccus pseudomagnoliarum), Ibotaroumushi (Ericerus pela), Mizuki Kata scale insects (Lecanium corni), Lecanium persicae, citrus scales (Pulvinaria aurantii), citrus scales (Pulvinaria citricola), scallop scales (Pulvin) aria kuwacola) etc.
As DIASPIDIDAE, citrus scale insects (Andaspis kashicola), Acamar scale insects (Aonidiella aurantii), Kimaru scale insects (Aonidiella citrina), Humpback Mar scale insects (Aspidiotus destructor), white circle scale insects (Aspidiotus hederae), red-spotted Marukai rise insects (Chrysomphalus ficus), pear Buprestidae (Santhoze scales: Comstockcaspis perniciosa), Duplaspidiotus claviger, Lepidosaphes beckii, Apple oyster scale (Lepidosaphes ulmi), pear beetle scale (Lephoreucaspis japonica), papilla scale (Parlatoreopsis pylori), camellia scale beetle (Parlatoropesis pteridae) Pinnaspisaspidistrae, Citrus scalea (Pseudaonidia duplex), Pseudoonidae paeoniae, Pseudaulaspaistenti, Pseudaulaspaspenti Ramushi (Pseudaulacaspis prunicola), Yano yanonensis (Unaspis yanonensis), etc.,
Lepidoptera (LEPIDOPTERA): Koumoriga (Endoclyta excrecens), macular bats (Endoclytasinensis), white Ten bats (Palpifer sexnotata), Barahamaki (Acleris comariana), apple Coca summer fruit tortrix (Adoxophyes orana fasciata), smaller tea tortrix (Adoxophyes sp. ), Apples brevipicanus, Midekakumonmonaki (Archips fuscocuppreanus), Kakimon oyster (Archips xylostaneus), Bakutra furfuranane, Asakua Chiro reipalpana), Kurimiga (Cydia kurokoi), chestnut green sink bur (Eucoenogenes aestuosa), oriental fruit moth (Grapholita molesta), Chahamaki (Homona magnanima), apple fruit moth (Hoshimoa adumbratana), soybean pod borer, Leguminivora glycinivorella (Leguminivora glycinivorella), Azukisayamushiga (Matsumuraeses azukivora), Soybean mushroom (Matsumuraeses falcana), bean mushroom mushroom (Matsumuraeses phaseoli), apple spider leaflet (Spilonota lechriaspis), apple spruce leaf spider (Spirono) a ocellana), grapes bombardier moth (Eupoecillia ambiguella), Kuwaihosohamaki (Phalonidia mesotypa), mugwort giant bombardier moth (Phtheochroides clandestina), Minoga (Bambalina sp.), Oominoga (Eumeta japonica), Chaminoga (Eumeta minuscule), carvings (Nemapogon granellus ), Iga (Tinea translucens), prickly moth (Bucculatrix pyricorella), peach leaf moth (Lyonetia clarkerella), lingon leaf moth (Lyonetia prunifoiliella), lobster moth la), Chanohosoga (Caloptilia theivora), Ringohosoga (Caloptilia zachrysa), Kakihosoga (Cuphodes diospyrosella), the apple leaf miner (Phyllonorycter ringoniella), Nashihosoga (Spulerina astaurota), mandarin orange leafminer (Phyllocnistis citrella), grape leafminer (Phyllocnistis toparcha), Negikoga (Acrolepiopsis sapporensis), yamanoimokoga (Acroleopsis suzukiella), black moth (Plutella xylostella), apple corn cinchui (Argyresthia conjugel) la), grapes Sukashiba (Paranthrene regalis), Kosukashiba (Synanthedon hector), Kakinohetamushiga (Stathmopoda masinissa), Imokibaga (Brachmia triannulella), peach fruit moth (Carposina niponensis), apple moth black bar (Illiberis pruni), Kuroshitaaoiraga (Lotoia sinica), monema flavescens ( Monema flavescens, Nashiiraga (Nanosidedeus flavidosalis), Auraira (Parasa consocia), Siperodes consturacus, Chilo supresnosco Moth (Cnaphalocroscis medinalis), peach monopoda teltibell (Diaphania indica), papaver moth (Etamyelois pyridae) Black-backed shore moth (Euzophera batogensis), Glyphodes pylorialis, Hellulla undalis, Marasmia exigua, Maru mulberry, Moth (Notarcha derogate), the European corn borer (Ostrinia furnacalis), Azukinomeiga (Ostrinia scapulalis), Fukinomeiga (Ostrinia zaguliaevi), Shibatsutoga (Parapediasia teterrella), Ukon'nomeiga (Pleuroptya ruralis), Sankameiga (Scirpophaga incertulas), parnara guttata (Parnara guttata), Papilio Helenus, Papilio machaon hipporates, Papilio xutus, Monk butterfly (Colias erate polygraphus), Monshirocho (Pieris rapae crucivora), lampides boeticus (Lampides boeticus), Plum Eda Shakti (Angerona prunaria), mugwort Eda Shakti (Ascotis selenaria), Tobi Mont giant Eda Shakti (Biston robustum), Umeedashaku (Cystidia couaggaria), pine moth (Dendrolimus spectabilis), lackey moth ( Malacosoma neutria testacea, apple calcare (Odonestis pruni japonensis), hawk moth (Cephonodes hylas), grape sparrow (Acosmerix castanea) choreta), kelp killer whale pike (Clostera anastomosis), Mont black killer whale pike (Phalera flavescens), giant Tobi Mont killer whale pike (Phalerodonta manleyi), killer whale pike moth (Stauropus fagi persimilis), Arna Pseudoconspersa (Euproctis pseudoconspersa), Monshirodokuga (Euproctis similes), tussock (Euproctis subflava), Mymantia dispar, Orgyia thyella, Hyphantria cunea, Spirosoma imparilis, Spirosoma imparilis (Acanthoplusia agnata), Nakajiroshitaba (Aedia leucomelas), black cutworm (Agrotis ipsilon), Kaburayaga (Agrotis segetum), Akakiriba (Anomis mesogona), Tamanagin'uwaba (Autographa nigrisigna), Trichoplusia ni (Trichoplusia ni), cotton bollworm (Helicoverpa armigera), tobacco budworm (Helicoverpa assulta), crested saga (Heliothis maritime), mushroom (Mamestra brassicae), pterodactyl (Nangaga aenescens), Ayuyoto (Pseudaletia sepata) C (Sesamia inferens), Sujikiriyotou (Spodoptera depravata), beet armyworm (Spodoptera exigua), common cutworm (Spodoptera litura), Ringokenmon (Trianea intermedia), Nashikenmon (Viminia rumicis), Shiromon'yaga (Xestia c-nigrum) and the like,
Coleoptera (COLEOPTERA): Chairokogane (Adoretus tenuimaculatus), cupreous chafer (Anomala cuprea), rufocuprea (Anomala rufocuprea), flower chafer (Eucetonia pilifera), Blue flower chafer (Eucetonia roelofsi), Nagachakogane (Heptophylla picea), Kofukikogane (Melolontha japonica), Scarab beetles (Mimela splendens), core red clover (Oxycetonia jucunda), bean scallops (Popilia japonica), beetle beetle (Anthrenus verbasci), beetle worm beetle (Atun tussage nus) color japonicus), cigarette beetle (Lasioderma serricorne), Hirata beetle (Lyctus brunneus), Guy My Deo kiss Lee (Carpophilus dimidiatus), clear Keshikisui (Carpophilus hemipterus), giant beetle, Epilachna vigintioctopunctata (Epilachna vigintioctomaculata), the beetle, Epilachna vigintioctopunctata (Epilachna vintignoctopuncta), Japanese red beetle (Alphitobius laevigatas), Japanese red beetle (Neatus picipes), Japanese red beetle (Palorus ratzeburgii), Japanese red beetle subdepressus), Chai loco agate molitor (Tenebrio molitor), red flour beetle (Tribolium castaneum), Hirata red flour beetle (Tribolium confusum), beans Beetle (Epicauta gorhami), key sawyer (Aeolesthes chrysothrix), Gomadarakamikiri (Anoplophora malasiaca), Matsunomadara Japanese beetle (Monochamus alternatus), Japanese beetle (Psacothea hilaris), Grape tiger beetle (Xylotrechus pyrrhoderus), Ayojikamikiri (Xytrocena globosa), Azuki beetle bruchus chinensis), cucurbit leaf beetle (Aulacophara femoralis), Tenebrio monkey beetle (Basilepta balyi), Kamenokohamushi (Cassida nebulosa), Ten site bi potato beetle (Chaetocnema concinna), Imosaruhamushi Colasposoma dauricum), A person who spotted neck Naga leaf beetle (Crioceris quatuordecimpunctata),
Inenekuihamushi (Donacia provosti), Rurihamushi (Linaeidea aenea), Kiashinomihamushi (Luperomorpha tunebrosa), lid streaks Anthrenus Beetle (Medythia nigrobilineata), Inedorooimushi (Oulema oryzae), Anthrenus key spring monkey Beetle (Pagria signata), daikon leaf beetle (Phaedon brassicae) , Phyllotreta striolata, Umechokuri weevil (Involvulus cupreus), Peach weevil (Rhynchites heros), Aryomo weevil (Cylas formmicarius) morum), die consulting weevil (Ceuthorhynchidius albosuturalis), chestnut weevil (Curculio sikkimenesis), rice weevil (Echinocnemus squameus), Imozoumushi (Euscepes postfasciatus), clover weevil (Hypera nigrirostris), alfalfa weevil (Hypera postica), rice water weevil (Lissorhoptrus oryzophilus ), Yasuki weevil (Listroderes costirostris), apple beetle weevil (Phyllobius armatus), chibi beetle weevil (Sitona japiconicus), coconut beetle Musi (Sitophilus oryzae), maize weevil (Sitophilus zeamais), such as grass reed weevil (Sphenophrus venatus vestitus),
Hymenoptera: Japanese bee wasp (Athalia japonica), bee (Athalia rosae tuficornis), apple bee (Arge mali), Arge pagaura (Arge pagaura), D
Diptera: Tipula aino, Bradysia agrestis, Asphondylia sp., Ac (Dacus cucurbitae), D Cherry Leaf Spot fruit fly (Rhacochlaena japonica), Inemigiwabae (Hydrellia griseola), rice click Kimi Giwa fly (Hydrellia sasakii), cherry fruit fly (Drosophila suzukii), Inekimoguribae Chlorops oryzae), Mugikimoguribae (Meromuza nigriventr s), rice leafminer (Agromyza oryzae), the pea (Chromatomyia horticola), eggplant leafminer (Liriomyza bryoniae), green onion leafminer (Liriomyza chinensis), legume leafminer (Liriomyza trifolii), tomato leafminer (Liriomyza sativae), reed Gros leafminer (Liriomyza huidobrensis ), Onion fly (Delia antiqua), fly fly (Delia platera), sugar beet fly (Pegomya cunicularia), house fly (Musca domestica), black fly (Phomia cue fly) ex pipiens pallens Coquillett), Culex pipiens (Culex pipiens molestus Forskal), Anopheles sinensis (Anopheles (Anopheles) sinensis Wiedemann), Aedes albopictus (Aedes albopictus (Skuse)) and others as mentioned, but not limited thereto.

  In addition, as other stored grain pests, Necrobia rubipes, Callilospbruchuus analis, Necrobia ruficulis, Unerophermus humulis, gularis), common beetle (Acanthoscelides obectus), pea weevil (Bruchus pisorum), Australian leopard beetle (Ptinus tectus), white-footed beetle (Prostephanus truncates), white-horned beetle Key (Gnathocerus cornutus), multiview saw-tooth grain beetle (Oryzaephirus mercator), Casino Shima moth (Pyralis farinalis), Kashmir red flour beetle (Tribolium freemani), Kado Cobb bombardier grain beetle (Ahasvers advena), Guy My mealworm (Alphitobius diaperinus), Gaimaitsudzuriga (Corcyla cephalonica), Nippus holoeucus, Granaria weevil (Sitophilus granaries), Tribolium maedens, Tribulus trodurum tructor), carvings (Nemapogon grannella), maize weevil (Sitophilus zeamais), receptacle of void beetle (Caulophilus oryzae), red flour (Tenebrioides manuritanicus), Kokumaruhakibaga (Martyringa xeraula), small basket mealworm (Latheticus oryzae), tips Roh red flour beetle (Gnathocerus maxillosus), Konanagashinkui (Rhizopertha dominica), Aridius nodifer, Carpophilus pilosellus, Tenebrio obscurus , Agrossa dimidiata, Cryptoles ferruguneus, icinus siamus, Utah siamus, Utah Mussels (Typhaea stercore), Tsukihimememushi (Holoparamecus signatus), Corn beetle (Pagiocerus frontalis), Nesekuri keshikisui (Carpophilus derkeskampi), Nisebum um aequinoctialle), saw-tooth grain beetle (Oryzaephilus surinamensis), Indian meal Madara My moth (Plodia interpunctella), Hara Giro carpet beetle (Dermestes maculates), Gray bean weevil (Callosobruchus phaseori), Howe Kaku breast grain beetle (Cryptolestes pusilloides), malt (Sitotroga cerealella) , Trogoderma granarias, Pinus clavipes, Trogoderma Inclusum, Bruchus les tis), twins bean weevil (Callosobruchus subinnotatus), Brazil bean weevil (Zabrotes subfasciatus), vetch bean weevil (Bruchus brachialis), bombardier Chibi red flour (Lophocaterus pusillus), beam Navi Russia Hime Hamakimushi (Dienerella costulata), Mexican grain beetle (Pharaxonota kirschi), Carabidon weevil (Caryedon serratus), tsutsutome weevil (Callosobruchus maculatus), Ruriboshi viramaceae, Rhodesia beetle (Callosobrucchurus) Esianus), but boll Acyrthosiphon weevil (Araecerus fasciculatus), and the like, but is not limited thereto.

  Wood pests include Nehyrrhynchus niisimai, Coffee chrysanthemum (X, cylocium), Southern cocoa beetle (Xe cyloctus), Xenopsis bicolor), Xylosandrus cincisus, Xylosandrus glabratus, Xylosandrus insectus, Xylosandrus mussels , Fir but giant beetle (Xylosandrus validus), and the like, but is not limited thereto.

  Plant seeds refer to those that store nutrients for germination of young plants and are used for agricultural reproduction. For example, seeds such as corn, soybean, cotton, rice, sugar beet, wheat, barley, sunflower, tomato, cucumber, eggplant, spinach, green pea, pumpkin, sugar cane, tobacco, pepper, rape, oats, taro, Examples include seed potatoes such as potatoes, sweet potatoes, and konjac, edible lilies, bulbs such as tulips, and seed balls such as sea urchins. Moreover, the pest damage control by the plant seeds provided here extends not only to seeds, seed pods, seed balls, etc., but also to harvested products such as stems, leaves, and fruits of grown plants.

  These are transformed plant seeds, cereals, beans, vegetables, florets, that is, plants produced by artificially manipulating genes and the like, and may not originally exist in nature. Examples thereof include corn, cotton, potato and the like that have been provided with the ability to produce insecticides, such as soybean, corn, and cotton that have been given herbicide resistance, and rice and tobacco that have been adapted to cold regions.

  Stored cereals, stored beans, stored fruits, and stored vegetables refer to cereals, beans, fruits, and vegetables that are stored and preserved for domestic distribution and import / export, and are mainly used for food and processing. Rice, barley, wheat, corn, rye, oats, peas, green beans, pigtails, sultani beans, saltapia beans, butter beans, peggia beans, white beans, lima beans, broad beans, soybeans, azuki beans, apricots, ume, outo, Plum, Nectarine, Thigh, Orange, Grapefruit, Natsumikan, Lime, Lemon, Biwa, Quince, Apple, Avocado, Kiwi, Guava, Natsuya, Pineapple, Passionfruit, Banana, Papaya, Mango, Strawberry, Cranberry, Huckleberry, Blackberry, Blueberry, Oyster, Watermelon, Grape, Rolled melon, Melon, Turnip, Cauliflower, Cabbage, Watercress, Kale, Horseradish, Radish, Broccoli, Kansai, Konjac potato, Sweet potato, Potato, Pumpkin, Cucumber Salmon, artichoke, endive, burdock, salsify, chicory, lettuce, shiitake, mushroom, celery, carrot, parsnip, tomato, eggplant, pepper, asparagus, onion, garlic, green onion, parsley, edamame, okra, sugarcane , Ginger, sugar beet, spinach, immature beans, immature peas, oil seeds (sesame seeds, rapeseed, sunflower, safflower, cottonseed, etc.), nuts (almonds, beans, chestnuts, walnuts, pecans, etc.) , Cocoa beans, coffee beans, tea, hops and the like.

  Stored feed refers to feed that is stored and preserved for domestic distribution and import / export, and is mainly used for raising livestock. Examples include cereals and beans.

  Stored florets refer to fresh flowers such as potted plants, cut flowers, bulbs, seeds, etc. that are stored and preserved for domestic distribution and import / export, and are mainly used for ornamental and cultivation purposes. Examples include orchid, rumora, chrysanthemum, xerophim, hisakaki, lily, freesia, nadesico, rose, anthurium, orchid, carnation, and tulip.

  Import / export wood refers to logs or lumber materials that are stored and preserved for the purpose of import / export, and are generally used for processing, construction, and the like. Hemlock, Douglas fir, spruce, spruce, todomatsu, larch, lawan and the like.

  Pyrethroids useful in the compositions of the present invention include pyrethrins and synthetic pyrethroids. Preferred pyrethrins for use in the process of the present invention include 2,2-dimethyl-3- (2-methylpropenyl) -cyclopropanecarboxylic acid 2-allyl-4-hydroxy-3-methyl-2-cyclopentene- 1-one esters and / or (2-methyl-1-propenyl) -2-methoxy-4-oxo-3- (2-propenyl) -2-cyclopenten-1-yl esters and their cis and trans isomers Mixture (Chemical Abstracts Service Registration Number (“CAS RN”) 8003-34-7).

  Preferred synthetic pyrethroids for use in the present invention include (S) -cyano (3-phenoxyphenyl) methyl 4-chloroalpha (1-methylethyl) benzeneacetate (fenvalerate; CASRN51630-58-1); ) -Cyano (3-phenoxyphenyl) methyl (S) -4-chloro-alpha- (1-methylethyl) benzeneacetate (esfenvalerate; CASRN 66230-04-4); (3-phenoxyphenyl) -methyl (+ ) Cis-trans-3- (2,2-dichloroethenyl) -2,2-dimethylcyclopropanecarboxylate (permethrin; CASRN 52645-53-1); (±) alpha-cyano- (3-phenoxyphenyl) methyl ( +)-Cis, trans-3- (2,2-dichroic) Ethenyl) -2,2-dimethyl-cyclopropanecarboxylate (cypermethrin; CAS RN52315-07-8); (beta-cypermethrin; CAS RN65731-84-2); (theta-cypermethrin; CAS RN71697-59- 1); S-cyano (3-phenoxyphenyl) methyl (±) cis / trans 3- (2,2-dichloroethenyl) 2,2-dimethylcyclopropanecarboxylate (zeta-cypermethrin; CAS RN52315-07-8 ); (S) -alpha-cyano-3-phenoxybenzyl (1R, 3R) -3- (2,2-dibromovinyl) -2,2-dimethylcyclopropanecarboxylate (deltamethrin; CAS RN52918-63-5) Alpha-cyano-3-phenoxybenz 2,2,3,3-tetramethylcyclopropanecarboxylate (phenpropatoline; CAS RN64257-84-7); (RS) -alpha-cyano-3-phenoxybenzyl (R) -2- [2-chloro -4- (trifluoromethyl) anilino] -3-methylbutanoate (tau-fulvalinate; CAS RN102851-06-9); (2,3,5,6-tetrafluoro-4-methylphenyl) -methyl -(1alpha, 3alpha)-(Z)-(±) -3- (2-chloro-3,3,3-trifluoro-1-propenyl) -2,2-dimethylcyclopropanecarboxylate (tefluthrin; CASSN 79538-32-2); (±) -cyano (3-phenoxyphenyl) methyl (±) -4- (difluoromethoxy) -alph -(1-methylethyl) benzeneacetate (flucitrinate; CAS RN 70124-77-5); cyano (4-fluoro-3-phenoxyphenyl) methyl 3- [2-chloro-2- (4-chlorophenyl) ethenyl] -2,2-dimethylcyclopropanecarboxylate (flumethrin; CAS RN69770-45-2); cyano (4-fluoro-3-phenoxyphenyl) methyl 3- (2,2-dichloroethenyl) -2,2-dimethylcyclo Propanecarboxylate (cyfluthrin; CAS RN68359-37-5); (beta cyfluthrin; CAS RN68359-37-5); (2,3,5,6-tetrafluorophenyl) methyl (1R-trans) -3- ( 2,2-dichloroethenyl) -2,2-dimethylcyclop Pancarboxylate (transfluthrin; CAS RN118712-89-3); (S) -alpha-cyano-3-phenoxybenzyl (Z)-(1R-cis) -2,2-dimethyl-3- [2- ( 2,2,2-trifluoro-trifluoromethyl-ethoxycarbonyl) vinyl] cyclopropanecarboxylate (acrinathrin; CAS RN101007-07-1); alpha-cyano-3-phenoxybenzyl-3- (2,2 dichlorovinyl ) -2,2-dimethylcyclopropanecarboxylate (1R cis) S and (1S cis) R enantiomeric isomer pairs (alpha-cypermethrin; CAS RN67375-30-8); [1R, 3S] 3 (1 ′ RS) (1 ′, 2 ′, 2 ′, 2′-tetrabromoethyl)]-2,2-dimethyl Tylcyclopropanecarboxylic acid (S) -alpha-cyano-3-phenoxybenzyl ester (tralomethrin; CAS RN66884-25-6); cyano- (3-phenoxyphenyl) methyl 2,2-dichloro-1- (4-ethoxy Phenyl) cyclopropanecarboxylate (cycloproton; CASRN 63935-38-6); [1α, 3α (Z)]-(±) -cyano- (3-phenoxyphenyl) methyl 3- (2-chloro-3,3 , 3-trifluoro-1-propenyl) -2,2-dimethylcyclopropanecarboxylate (cyhalothrin; CAS RN68085-85-8); [1alpha (S), 3alpha (Z)]-cyano (3-phenoxy Phenyl) methyl-3- (2-chloro-3,3,3-trifluoro-1-pro Nyl) -2,2-dimethylcyclopropanecarboxylate (lambda dahalothrin; CAS RN91465-08-6); (2-methyl [1,1′-biphenyl] -3-yl) methyl 3- (2-chloro) -3,3,3-trifluoro-1-propenyl) -2,2-dimethylcyclopropanecarboxylate (bifenthrin; CAS RN 82657-04-3); 5-1-benzyl-3-furylmethyl-d-cis ( 1R, 3S, E) 2,2-Dimethyl-3- (2-oxo, -2,2,4,5-tetrahydrothiophenylidenemethyl) cyclopropanecarboxylate (cadetrin, RU15525; CAS RN 58769-20-3) [5- (phenylmethyl) -3-furanyl] -3-furanyl 2,2-dimethyl-3- (2-methyl-1- (Propenyl) cyclopropanecarboxylate (resmethrin; CAS RN10453-86-8); (1R-trans)-[5- (phenylmethyl) -3-furanyl] methyl 2,2-dimethyl-3- (2-methyl-1 -Propenyl) cyclopropanecarboxylate (violesmethrin; CAS RN28434-01-7); 3,4,5,6-tetrahydro-phthalimidomethyl- (1RS) -cis-trans-chrysanthelate (tetramethrin; CAS RN7696-12 0); 3-phenoxybenzyl-d, l-cis, trans 2,2-dimethyl-3- (2-methyl-1-propenyl) cyclopropanecarboxylate (phenothrin; CAS RN 26002-80-2); (1R) -Cis-trans-1-ethynyl-2-methyl- 2-pentenyl-2,2-dimethyl-3- (2-methyl-1-propenyl) cyclopropanecarboxylate (empentrin; CASRN 54406-48-3); 2,2-dimethyl-3- (2-methyl-1- Propenyl) cyclopropanecarboxylic acid cyano (3-phenoxyphenyl) methyl ester (cyphenothrin; CASRN39515-40-7); 2,2-dimethyl-3- (2-methyl-1-propenyl) cyclopropanecarboxylic acid 2 -Methyl-4-oxo-3- (2-propynyl) -2-cyclopenten-1-yl ester (praretrin; CASRN23031-36-9); [2,5-dioxo-3- (2-propynyl) -1- Imidazolidinyl] methyl (1R) -2,2-dimethyl-3- (2 Methyl-1-propenyl) cyclopropanecarboxylate (2- (imiprothrin; CASRN 72963-72-5); (RS) -3-allyl-2-methyl-4-oxcyclopent-2-enyl- (1A, 3R; 1R, 3S) -2,2-dimethyl-3- (2-methylprop-1-enyl) cyclopropanecarboxylate (alletrin; CAS RN584-79-2); (bioalletrin; CAS RN584-79-2); (4-Ethoxyphenyl) -2-methylpropyl-3-phenoxybenzyl-ether (ethofenprox; CAS RN80844-07-1); 4-ethoxyphenyl [3- (4-fluoro-3-phenoxyphenyl) propyl] Dimethylsilane (silafluophene; CAS RN1050024 6-6) are included. One or a mixture of two or more of the above synthetic pyrethroids can also be used in the present invention.

  In the embodiments of the present invention, more preferred pyrethroids include lambda-cyhalothrin, teflutrin, tau-fulvalinate, flumethrin, transcifluthrin, cadetrin, violesmethrin, tetramethrin, phenothrin, empentrin, cyphenothrin, praretrin, imiprotolin, alletrin. , Bioalletrin, esfenvalerate, permethrin, cypermethrin, beta-cypermethrin, zeta-cypermethrin, deltamethrin, beta-cyfluthrin, alpha-cypermethrin, and bifenthrin.

  Formula 1 used in the present invention

[Wherein X represents CH or N;
Y represents a nitro group or a cyano group;
R ¹ represents a 2-chloro-5-pyridyl group, a 2-chloro-5-thiazolyl group;
R ² is hydrogen, methyl group, ethyl group;
R ³ represents a methyl group or a group represented by NHR ⁴ or SR ⁵ (where R ⁴ represents hydrogen, a methyl group or an ethyl group, and R ⁵ represents a methyl group or an ethyl group);
Or R ² and R ⁴ together represent an ethylene group, a trimethylene group, a group represented by CH ₂ OCH ₂ , or a group represented by CH ₂ N (R ⁶ ) CH ₂ (where R ⁶ represents C _{1 -6 represents} an alkyl group);
Or R ² and R ⁵ together represent an ethylene group]
Among the compounds [I] represented by the formula, chloronicotinyl compounds such as imidacloprid, thiacloprid, clothianidin, thiamethoxam, nitenpyram, acetamiprid and the like can be exemplified.

  The composition used in the present invention is usually used by mixing with a carrier, and if necessary, for preparations such as surfactants, wetting agents, fixing agents, thickeners, preservatives, colorants, stabilizers and the like. Adjuvants are added and used in a timely formulation by generally known methods such as wettable powder, flowable powder, granular wettable powder, powder, and emulsion. The content of at least one chloronicotinyl compound and at least one pyrethrin or synthetic pyrethroid as active ingredients in these preparations is usually 0.005 to 99% by weight, preferably 0.01 to The range is 50%, more preferably 0.05 to 20%.

  The carrier used in the above preparation can be either solid or liquid as long as it is usually used in agricultural chemical preparations, and is not particularly limited. For example, as a solid carrier, bentonite, montmorillonite, kaolinite, diatomaceous earth, white clay, talc, clay, vermiculite, gypsum, calcium carbonate, silica gel, ammonium sulfate, etc., soybean powder, sawdust, wheat flour, lactose, sucrose, glucose And vegetable organic substances such as urea and urea. Examples of the liquid carrier include aromatic hydrocarbons such as toluene, xylene, cumene and naphthenes, n-paraffin, iso-paraffin, liquid paraffin, kerosene, mineral oil, polybutene and other paraffinic hydrocarbons, acetone, methyl ethyl ketone, etc. Ketones, ethers such as dioxane and diethylene glycol dimethyl ether, alcohols such as ethanol, propanol and ethylene glycol, carbonates such as ethylene carbonate, propylene carbonate and butylene carbonate, aprotic solvents such as dimethylformamide and dimethyl sulfoxide, and water Is mentioned. Furthermore, in order to enhance the efficacy of the compound of the present invention, the following adjuvants can be used alone or in combination depending on the purpose in consideration of the dosage form of the preparation, the treatment method and the like. As surfactants usually used for the purpose of emulsifying, dispersing, spreading and wetting in agricultural chemical formulations, sorbitan fatty acid esters, polyoxyethylene sorbitan fatty acid esters, sucrose fatty acid esters, polyoxyethylene fatty acid esters, Polyoxyethylene resin acid ester, polyoxyethylene fatty acid diester, polyoxyethylene castor oil, polyoxyethylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene dialkyl phenyl ether, formalin condensate of polyoxyethylene alkyl phenyl ether, Polyoxyethylene polyoxypropylene block polymer, alkyl polyoxyethylene polyoxypropylene block polymer ether, alkylphenyl polyoxyethylene polymer Oxypropylene block polymer ether, polyoxyethylene alkylamine, polyoxyethylene fatty acid amide, polyoxyethylene bisphenyl ether, polyoxyalkylene benzyl phenyl ether, polyoxyalkylene styryl phenyl ether, polyoxyalkylene adduct of higher alcohol and polyoxy Nonionic surfactants such as ethylene ether and ester-type silicon and fluorine surfactants, alkyl sulfates, polyoxyethylene alkyl ether sulfates, polyoxyethylene alkyl phenyl ether sulfates, polyoxyethylene benzyl phenyl ether sulfates, polyoxy Ethylene styryl phenyl ether sulfate, polyoxyethylene polyoxypropylene Block polymer sulfate, paraffin sulfonate, alkane sulfonate, AOS, dialkyl sulfosuccinate, alkyl benzene sulfonate, naphthalene sulfonate, dialkyl naphthalene sulfonate, formalin condensate of naphthalene sulfonate, alkyl diphenyl ether disulfonate, lignin sulfonate, polyoxyethylene alkyl phenyl ether sulfonate , Polyoxyethylene alkyl ether sulfosuccinic acid half ester, fatty acid salt, N-methyl-fatty acid sarcosinate, resin acid salt, polyoxyethylene alkyl ether phosphate, polyoxyethylene phenyl ether phosphate, polyoxyethylene dialkyl phenyl ether phosphate, polyoxyethylene Benzylation Phenyl ether phosphate, polyoxyethylene benzylated phenyl phenyl ether phosphate, polyoxyethylene styrylated phenyl ether phosphate, polyoxyethylene styrylated phenyl phenyl ether phosphate, polyoxyethylene polyoxypropylene block polymer phosphate, phosphatidylcholine, phosphatidylethanolimine, alkyl Anionic surfactants such as phosphate, sodium tripolyphosphate, polyanionic polymer surfactants derived from acrylic acid and acrylonitrile, acrylamidomethylpropane sulfonic acid, alkyltrimethylammonium chloride, methylpolyoxyethylenealkylammonium chloride, alkyl N- Methylpyridinium bromide, Cationic surfactants such as nomethylated ammonium chloride, dialkylmethylated ammonium chloride, alkylpentamethylpropyleneamine dichloride, alkyldimethylbenzalkonium chloride, and benzethonium chloride; amphoteric surfactants such as dialkyldiaminoethylbenthine and alkyldimethylbenzylbentain However, it is not limited to these. Examples of the binder include sodium alginate, polyvinyl alcohol, gum arabic, CMC sodium, bentonite and the like. Examples of the disintegrant include CMC sodium and croscarmellose sodium, and examples of the stabilizer include hindered phenol-based antioxidants, benzotriazole-based and hindered amine-based ultraviolet absorbers, and the like. Use phosphoric acid, acetic acid, sodium hydroxide as a pH adjuster, or add industrial disinfectants such as 1,2-benzisothiazolin-3-one, antibacterial and antifungal agents, etc. You can also. As a thickener, xanthan gum, guar gum, CMC sodium, gum arabic, polyvinyl alcohol, montmorillonite and the like can also be used. A silicone compound as an antifoaming agent and propylene glycol, ethylene glycol or the like as an antifreezing agent may be used as necessary.

  Usually, the seed coating agent contains one or more binders. Binders useful in the present invention include adhesive polymers that may be natural or synthetic and have no phytotoxic effects on the seed to be coated. This binder is composed of polyvinyl acetate; polyvinyl acetate copolymer; polyvinyl alcohol; polyvinyl alcohol copolymer; cellulose including ethyl cellulose, methyl cellulose, hydroxymethyl cellulose, hydroxypropyl cellulose and carboxymethyl cellulose; polyvinyl pyrrolidone; starch, modified starch, dextrin, maltodextrin, Polysaccharides including alginate and chitosan; fat; oil; protein including gelatin and zein; gum arabic; shellac; vinylidene chloride and vinylidene chloride copolymer; calcium lignosulfonate; acrylic copolymer; polyvinyl acrylate; polyethylene oxide; Polyhydroxyethyl acrylate, methacrylic It can be selected from Domonoma and polychloroprene. The amount of binder in the coating can vary, but is in the range of about 0.01% to about 25% of the seed weight, more preferably about 0.05% to about 15%, and even more preferably about 0. .1% to about 10%.

  When the composition is applied to the plant seed according to the present invention, the plant seed may be immersed in the composition as it is. After the composition is diluted to an appropriate concentration in an appropriate carrier, the plant seed is immersed, powdered and sprayed. It can also be used after being smeared. In addition, when applied to stored cereals, stored beans, stored fruits, stored vegetables, stored feed, stored florets, and imported / exported wood, it may be immersed in the composition as it is, and the composition used is suitable for an appropriate carrier. After diluting to a suitable concentration, it can be used by dipping, powder coating, spraying, smearing, coating, fumigation / smoke treatment, or pressure injection.

  Suitable carriers are liquid carriers of organic solvents such as water or ethanol, bentonite, montmorillonite, kaolinite, diatomaceous earth, white clay, talc, clay, vermiculite, gypsum, calcium carbonate, silica gel, ammonium sulfate and other inorganic substances, soy flour, Sawdust, wheat flour, lactose, sucrose, plant organic substances such as glucose, and solid carriers such as urea are exemplified, but not limited thereto. The amount used in the case of dressing, spraying and smearing is usually about 0.005 to 50% of the dry plant seed weight, but such amount is not limited to these ranges. However, it may vary depending on the form of the preparation and the types of plant seeds, cereals, beans, fruits, vegetables, feed and wood to be treated.

The following examples and test examples illustrate the invention in detail.
Example 1 (Dust)
5 parts of imidacloprid, 0.5 part of permethrin and 94 parts of clay and 0.5 part of Doreless B (Sankyo Co., Ltd.) were mixed and ground uniformly to obtain a mixed powder containing 5% imidacloprid and 0.5% permethrin.

Example 2 (wettable powder)
60 parts of imidocloprid, 6 parts of permethrin, 1 part of sodium lignin sulfonate, 5 parts of white carbon and 28 parts of diatomaceous earth were mixed and pulverized to obtain a mixed wettable powder containing 60% imidacloprid and 6% permethrin.

Example 3 (wettable powder)
60 parts of thiamethoxam, 6 parts of permethrin, 1 part of sodium lignin sulfonate, 5 parts of white carbon and 28 parts of diatomaceous earth were mixed and ground to obtain a mixed wettable powder containing 60% thiamethoxam and 6% permethrin.

Example 4 (wettable powder)
60 parts of clothianidin, 6 parts of permethrin, 1 part of sodium lignin sulfonate, 5 parts of white carbon and 28 parts of diatomaceous earth were mixed and ground to obtain a mixed wettable powder containing 60% clothianidin and 6% permethrin.

Example 5 (emulsion)
10 parts of imidacloprid, 5 parts of permethrin, 10 parts of cyclohexane, 55 parts of xylene, and 20 parts of Solpol (surfactant manufactured by Toho Chemical Co., Ltd.) were uniformly dissolved and mixed to obtain a mixed emulsion containing 10% imidacloprid and 5% permethrin. .

Example 6 (wettable powder)
30 parts of imidacloprid, 30 parts of tefluthrin, 1 part of sodium lignin sulfonate, 5 parts of white carbon and 34 parts of diatomaceous earth were mixed and pulverized to obtain a mixed wettable powder containing 30% imidacloprid and 30% tefluthrin.

Example 7 (wettable powder)
30 parts of clothianidin, 30 parts of teflutrin, 1 part of sodium lignin sulfonate, 5 parts of white carbon and 34 parts of diatomaceous earth were mixed and ground to obtain a mixed wettable powder containing clothianidin 30% and teflutrin 30%.

Example 8 (wettable powder)
30 parts of thiamethoxam, 30 parts of tefluthrin, 1 part of sodium lignin sulfonate, 5 parts of white carbon and 34 parts of diatomaceous earth were mixed and ground to obtain a mixed wettable powder containing thiamethoxam 30% and tefluthrin 30%.

Example 9 (wettable powder)
20 parts of thiacloprid, 20 parts of tau-fulvalinate, 1 part of sodium lignin sulfonate, 5 parts of white carbon and 54 parts of diatomaceous earth are mixed and ground to obtain a mixed wettable powder containing 20% thiacloprid and 20% tau-fulvalinate. Obtained.

Example 10 (wettable powder)
20 parts of acetamiprid, 20 parts of bifenthrin, 1 part of sodium lignin sulfonate, 5 parts of white carbon and 54 parts of diatomaceous earth are mixed and ground to obtain a mixed wettable powder containing 20% of the active ingredient of acetamiprid and 20% of the active ingredient of bifenthrin. Obtained.

Example 11 (wettable powder)
20 parts of clothianidin, 20 parts of bifenthrin, 1 part of sodium lignin sulfonate, 5 parts of white carbon and 54 parts of diatomaceous earth were mixed and pulverized to obtain a mixed wettable powder containing 20% clothianidin and 20% bifenthrin.

Example 12 (wettable powder)
20 parts of thiamethoxam, 20 parts of esfenvalerate, 1 part of sodium lignin sulfonate, 5 parts of white carbon and 54 parts of diatomaceous earth were mixed and ground to obtain a mixed wettable powder containing 20% thiamethoxam and 20% esfenvalerate. .

Example 13 (wettable powder)
20 parts of nitenpyram, 20 parts of cypermethrin, 1 part of sodium lignin sulfonate, 5 parts of white carbon and 54 parts of diatomaceous earth were mixed and ground to obtain a mixed wettable powder containing 20% nitenpyram and 20% cypermethrin.

Example 14 (wettable powder)
20 parts of imidacloprid, 20 parts of beta-cypermethrin, 1 part of sodium lignin sulfonate, 5 parts of white carbon and 54 parts of diatomaceous earth are mixed and ground to obtain a mixed wettable powder containing 20% imidacloprid and 20% beta-cypermethrin. Obtained.

Example 15 (wettable powder)
20 parts of thiacloprid, 20 parts of zeta-cypermethrin, 1 part of sodium lignin sulfonate, 5 parts of white carbon and 54 parts of diatomaceous earth are mixed and ground to obtain a mixed wettable powder containing 20% thiacloprid and 20% zeta-cypermethrin. Obtained.

Example 16 (wettable powder)
20 parts of thiamethoxam, 20 parts of beta cyfluthrin, 1 part of sodium lignin sulfonate, 5 parts of white carbon and 54 parts of diatomaceous earth were mixed and ground to obtain a mixed wettable powder containing 20% thiamethoxam and 20% beta cyfluthrin. .

Example 17 (wettable powder)
20 parts of nitenpyram, 20 parts of alpha-cypermethrin, 1 part of sodium lignin sulfonate, 5 parts of white carbon and 54 parts of diatomaceous earth are mixed and ground to obtain a mixed wettable powder containing 20% nitenpyram and 20% alpha-cypermethrin. Obtained.

Example 18 (wettable powder)
20 parts of acetamiprid, 20 parts of lambda cihalothrin, 1 part of sodium lignin sulfonate, 5 parts of white carbon and 54 parts of diatomaceous earth are mixed and pulverized, and mixed water containing 20% aceta microprid and 20% lambda cihalothrin. A balm was obtained.

Test Example 1 1) Maize: Effect of controlling against crickets Using the wettable powder prepared in Examples 2 and 4, the seed dressing machine (chemical injection in a rotating drum) was used.
Example 2, 3 and 4 wettable powder 25, 50 g / 4000 seeds of corn seed 50, 100 g of wettable powder of Examples 6, 7 and 8/4000 seeds of corn seed 1.0 m ² (1.0 × 1) 0.0 m) The ward was surrounded by a surf sheet, and 15 larvae of 3 to 4 instar moths that were subcultured in-house on the day before sowing were released for each ward. 40 seeds were sown per section. The number of buddings 21 days after sowing was investigated, and the budding rate was determined with respect to the number of buddings in the unreleased area. (3 iterations)
The results are shown in Tables 1 to 3.
2) Chemical damage test: 1 section 1.0m ² (1.0 × 1.0m) The section was surrounded by a surf sheet, and 40 seeds were seeded per section. The number of budding 21 days after sowing was investigated, and the budding rate was determined with respect to the number of budding in the untreated group. (Three iterations) Tables 4 to 6 show the results.

薬害試験

Phytotoxicity test

Test Example 2 Control effect against Azuki beetle
The mixed wettable powder prepared in Examples 2, 3, and 4 was smeared with 5, 10, and 20 g of 1 kg of azuki seeds. After air drying, a part was transferred to a 9 cm waist high petri dish and left in a constant temperature room at 25 ° C. After 2 and 3 months of treatment, 10 male weevil males and females were released per waist-high petri dish (5-regulation). Two days after release, the number of dead insects and the number of eggs laid on azuki bean were examined.
The results are shown in Table 7 to Table 9.

Claims (8)

Formula 1

[Wherein X represents CH or N;
Y represents a nitro group or a cyano group;
R ¹ represents a 2-chloro-5-pyridyl group, a 2-chloro-5-thiazolyl group;
R ² is hydrogen, methyl group, ethyl group;
R ³ represents a methyl group or a group represented by NHR ⁴ or SR ⁵ (where R ⁴ represents hydrogen, a methyl group or an ethyl group, and R ⁵ represents a methyl group or an ethyl group);
Or R ² and R ⁴ together represent an ethylene group, a trimethylene group, a group represented by CH ₂ OCH ₂ , or a group represented by CH ₂ N (R ⁶ ) CH ₂ (where R ⁶ represents C _{1 -6 represents} an alkyl group);
Or R ² and R ⁵ together represent an ethylene group]
2-allyl-4-hydroxy of 2,2-dimethyl-3- (2-methylpropenyl) -cyclopropanecarboxylic acid comprising at least one compound selected from the group consisting of compound [I] -3-Methyl-2-cyclopenten-1-one ester, 2,2-dimethyl-3- (2-methylpropenyl) -cyclopropanecarboxylic acid (2-methyl-1-propenyl) -2-methoxy-4- Oxo-3- (2propenyl) -2-cyclopenten-1-yl ester, fenvalerate, esfenvalerate, permethrin, cypermethrin, beta-cypermethrin, thetacypermethrin, zeta-cypermethrin, deltamethrin, fenpropatoline, Tau-fulvalinate, tefluthrin, flucitrinate, flumethrin, Flutrin, betacyfluthrin, transfluthrin, acrinatrin, alpha-cypermethrin, tralomethrin, cycloprotorin, cyhalothrin, lambda cihalothrin, bifenthrin, cadetrin, resmethrin, violesmethrin, tetramethrin, phenothrin, empentrin, pratrithrin, proretrin Seed, stored cereals, stored beans, stored fruit, storage, containing at least one pyrethrin or synthetic pyrethroid selected from the group consisting of alletrin, bioalletrin, etofenprox, silafluophene and mixtures thereof as an active ingredient A method for preventing pest damage characterized by being applied to vegetables, stored feed, stored flower buds, and imported / exported wood.   The method according to claim 1, wherein the compound [I] represented by the formula 1 is one or more chloronicotinyl compounds selected from the group consisting of imidacloprid, thiacloprid, clothianidin, thiamethoxam, nitenpyram, and acetamiprid.   The synthetic pyrethroid consists of esfenvalerate, permethrin, cypermethrin, beta-cypermethrin, zeta-cypermethrin, deltamethrin, tau-fulvalinate, tefluthrin, betacyfluthrin, alpha-cypermethrin, lambda cihalothrin, and bifenthrin. 3. A method according to claim 1 or 2 selected from the group.   Plant seeds, stored cereals, stored beans, stored berries, stored vegetables, stored feed, stored florets are corn, soybean, cotton, rice, sugar beet, wheat, barley, sunflower, tomato, cucumber, eggplant, spinach, green pea, The method according to any one of claims 1 to 3, which is pumpkin, sugarcane, tobacco, pepper, rape, rye, oat seed, taro, potato, sweet potato, konjac seed, edible lily, and tulip bulb.   Application methods for stored cereals, stored beans, stored fruits, stored vegetables, stored feed, stored flower buds, and imported / exported wood are spraying, smearing, coating, dipping, dressing, fumigation, fumigation The method according to any one of claims 1 to 3, which is smoke treatment and pressure injection.   The method according to any one of claims 1 to 4, wherein a pest damage to a plant seed or a plant grown from the plant seed is prevented.   Plant seeds, stored cereals, stored beans, stored fruits, stored vegetables, stored feed, stored flower buds, and import / export wood applied with the method according to any one of claims 1 to 4.   The plant seeds, stored cereals, stored beans, stored fruits, stored vegetables, stored feeds according to claim 7, which are transformed plant seeds, stored cereals, stored beans, stored berries, stored vegetables, stored feed, stored florets Storage flower buds.