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JP2008102037A - Charged particle amount evaluation system - Google Patents

Charged particle amount evaluation system Download PDF

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JP2008102037A
JP2008102037A JP2006285360A JP2006285360A JP2008102037A JP 2008102037 A JP2008102037 A JP 2008102037A JP 2006285360 A JP2006285360 A JP 2006285360A JP 2006285360 A JP2006285360 A JP 2006285360A JP 2008102037 A JP2008102037 A JP 2008102037A
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voltage
dew condensation
particle size
cylindrical electrode
charged particle
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Masato Yamana
正人 山名
Yoshio Mitsutake
義雄 光武
Junichi Watanabe
純一 渡邉
Yukiyasu Asano
幸康 浅野
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Panasonic Electric Works Co Ltd
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Matsushita Electric Works Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a charged particle amount evaluation system capable of evaluating the amount of charged particles with high precision even under an environment easy to dew-condensate. <P>SOLUTION: The charged particle amount evaluation system 1 is equipped with a concentric cylindrical electrode 2 constituted so that a columnar inside conductor 2a and a cylindrical outside conductor 2b having a diameter larger than that of the columnar inside conductor 2a are concentrically arranged, a suction fan 3 for producing a laminar flow in the space between both conductors 2a and 2b along the axial direction of the concentric cylindrical electrode 2, a voltage source 5 for applying voltage across both conductors 2a and 2b, an ammeter 4 for measuring the current flowing across both conductors 2a and 2b, a current value acquiring part 12 for acquiring the measuring value of the ammeter 4, a dewing detection part 16 for detecting the presence of the dewing occurring on both conductors 2a and 2b which form the wall surface of the flow channel of the laminar flow and a particle size calculation part 15 for evaluating the amount of the charged particles on the basis of the shape and dimension of the concentric cylindrical electrode 2, the flow rate of the laminar flow due to the suction fan 3, the applied voltage of the voltage source 5 and the current value acquired by the current value acquiring part 12 in a case that no dewing is detected by the dewing detection part 16. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、大気中に浮遊する微粒子の粒径や粒子数などを評価する帯電粒子量評価装置に関するものである。   The present invention relates to a charged particle amount evaluation apparatus for evaluating the particle size, the number of particles, and the like of fine particles floating in the atmosphere.

この種の帯電粒子量評価装置としては、帯電した微粒子の電場中における移動速度(電気移動度)の違いを利用して、微粒子の粒径を測定する微分型電気移動度測定器(DMA:Differential Mobility Analyzer)が従来より提供されている(例えば特許文献1参照)。   This kind of charged particle quantity evaluation apparatus is a differential type electric mobility measuring device (DMA: Differential) that measures the particle size of fine particles by utilizing the difference in the moving speed (electric mobility) of charged fine particles in an electric field. Mobility Analyzer) has been conventionally provided (see, for example, Patent Document 1).

しかしながら、DMAを用いた帯電粒子量評価装置は大型のため、ゲルディエンコンデンサと呼ばれる二重同心円筒を用いた帯電粒子量評価装置が従来より提供されている(例えば非特許文献1参照)。図5はゲルディエンコンデンサを用いた帯電粒子量評価装置1の概略構成図であり、この帯電粒子量評価装置1は、同心円筒状電極2と、吸気ファン3と、電流計4と、電圧源5とを主要な構成として備えている。   However, since the charged particle amount evaluation apparatus using DMA is large, a charged particle amount evaluation apparatus using a double concentric cylinder called a Gel Dien capacitor has been conventionally provided (for example, see Non-Patent Document 1). FIG. 5 is a schematic configuration diagram of a charged particle amount evaluation apparatus 1 using a gel diene capacitor. The charged particle amount evaluation apparatus 1 includes a concentric cylindrical electrode 2, an intake fan 3, an ammeter 4, a voltage source. 5 as a main configuration.

同心円筒状電極2は、互いに半径の異なる円筒状の内側導体2aおよび外側導体2bを同心に配して構成される。二重同心円筒の内、外側導体2bには電圧源5により直流電圧が印加され、内側導体2aは接地されている。なお電圧源5は図示しない電圧制御部によって電源電圧を変化させることができる。   The concentric cylindrical electrode 2 is configured by concentrically arranging cylindrical inner conductors 2a and outer conductors 2b having different radii. In the double concentric cylinder, a DC voltage is applied to the outer conductor 2b by the voltage source 5, and the inner conductor 2a is grounded. The voltage source 5 can change the power supply voltage by a voltage control unit (not shown).

吸気ファン3は、内側導体2aと外側導体2bとの間の空間を通して空気を吸引することによって、内側導体2aと外側導体2bの間の空間に矢印Aの方向に空気を流し、この空間に空気の流れる方向と速度が均一な層流を生成する。   The intake fan 3 sucks air through the space between the inner conductor 2a and the outer conductor 2b, thereby causing air to flow in the direction of the arrow A through the space between the inner conductor 2a and the outer conductor 2b. A laminar flow with uniform flow direction and velocity is generated.

電流計4は内側導体2aと外側導体2bとの間に流れる電流を測定するものであり、その電流値から帯電粒子の個数を算出することができる。   The ammeter 4 measures the current flowing between the inner conductor 2a and the outer conductor 2b, and the number of charged particles can be calculated from the current value.

本装置では吸気ファン3により空気を吸引している状態で、内側導体2aを接地するとともに、電圧源5により外側導体2bに電圧Vを印加して、内外の導体間に電位差を与えると、両導体間に吸引された空気中の帯電粒子が、両導体間に発生する電界によって内側導体2aに引き寄せられる。そして、帯電粒子が内側導体2aに流れ込むと、両導体間に電流が発生するので、電流計4の測定値をもとに帯電粒子の粒子数を測定することができる。なお、電圧源5による印加電圧Vの極性と、電流計4の測定値の極性とを考慮すれば正負何れの極性の帯電粒子でも測定することができる。   In this apparatus, when air is sucked by the intake fan 3, the inner conductor 2a is grounded, and a voltage V is applied to the outer conductor 2b by the voltage source 5 to give a potential difference between the inner and outer conductors. Charged particles in the air sucked between the conductors are attracted to the inner conductor 2a by an electric field generated between the two conductors. When the charged particles flow into the inner conductor 2a, a current is generated between the two conductors, so that the number of charged particles can be measured based on the measured value of the ammeter 4. In addition, if the polarity of the voltage V applied by the voltage source 5 and the polarity of the measured value of the ammeter 4 are taken into account, charged particles having either positive or negative polarity can be measured.

ここで、帯電粒子の粒径はその移動度に依存し、その移動度は二重円筒(内側導体2aおよび外側導体2b)の寸法と空気の流量とを一定にすると、電圧源5の印加電圧Vによって定まる。したがって電圧源5の印加電圧を変化させ、その時の電流値を電流計4で測定することによって、所定の粒径の帯電粒子の数を求めることができる。但し、ゲルディエンコンデンサと呼ばれる二重同心円筒を用いた図5の測定装置では、電圧源5の印加電圧により定めた移動度以上(粒径以下)の帯電粒子を全て取り込み、その全数を評価している。
特開平10−288600号公報 北川信一郎編著、「大気電気学」、東海大学出版会、1996年6月10日、47−49頁
Here, the particle size of the charged particles depends on the mobility, and the mobility is determined by making the size of the double cylinder (inner conductor 2a and outer conductor 2b) and the air flow rate constant, the applied voltage of the voltage source 5. Determined by V. Therefore, by changing the applied voltage of the voltage source 5 and measuring the current value with the ammeter 4, the number of charged particles having a predetermined particle diameter can be obtained. However, in the measuring apparatus of FIG. 5 using a double concentric cylinder called a gel diene capacitor, all charged particles having a mobility equal to or higher than the mobility determined by the applied voltage of the voltage source 5 (particle size or less) are taken and the total number is evaluated. ing.
Japanese Patent Laid-Open No. 10-288600 Edited by Shinichiro Kitagawa, “Atmospheric Electricals”, Tokai University Press, June 10, 1996, pp. 47-49

上述の帯電粒子量評価装置1では、移動度の変化をもとに帯電粒子の粒子量を所定の粒径範囲で測定することによって粒子数の分布を求めているが、層流の流路の壁面をなす内側導体2aと外側導体2bとに結露が発生すると、測定結果に誤差が生じるという問題があった。   In the charged particle amount evaluation apparatus 1 described above, the distribution of the number of particles is obtained by measuring the particle amount of the charged particles in a predetermined particle size range based on the change in mobility. When dew condensation occurs between the inner conductor 2a and the outer conductor 2b forming the wall surface, there is a problem that an error occurs in the measurement result.

本発明は上記問題点に鑑みて為されたものであり、その目的とするところは、結露が発生しやすい環境下でも精度の高い帯電粒子量の評価が行える帯電粒子量評価装置を提供することにある。   The present invention has been made in view of the above problems, and an object of the present invention is to provide a charged particle amount evaluation apparatus that can accurately evaluate the amount of charged particles even in an environment where condensation is likely to occur. It is in.

上記目的を達成するために、請求項1の発明は、円柱状の内側導体および内側導体よりも径の大きい円筒状の外側導体を同心に配置して構成された同心円筒状電極と、内側導体と外側導体との間の空間に同心円筒状電極の軸方向に層流を発生させる気流発生手段と、内側導体と外側導体との間に電圧を印加する電圧印加手段と、内側導体と外側導体との間に流れる電流を測定する電流測定手段と、層流の流路の壁面をなす内側導体および外側導体に発生する結露の有無を検出する結露検出手段と、当該結露検出手段により結露無しと検出された場合に、同心円筒状電極の形状および寸法と気流発生手段による層流の流量と電圧印加手段による印加電圧と電流測定手段の測定結果とに基づいて帯電粒子量を評価する帯電粒子量評価手段とを具備したことを特徴とする。   In order to achieve the above object, a first aspect of the present invention provides a concentric cylindrical electrode configured by concentrically arranging a cylindrical inner conductor and a cylindrical outer conductor having a diameter larger than that of the inner conductor, and an inner conductor. An air flow generating means for generating a laminar flow in the axial direction of the concentric cylindrical electrode in a space between the inner conductor and the outer conductor, a voltage applying means for applying a voltage between the inner conductor and the outer conductor, and the inner conductor and the outer conductor A current measuring means for measuring the current flowing between the inner conductor and the outer conductor, a dew condensation detecting means for detecting the presence or absence of dew condensation occurring on the inner and outer conductors forming the wall surface of the laminar flow path, and no dew condensation by the dew condensation detecting means. When detected, the charged particle amount is evaluated based on the shape and size of the concentric cylindrical electrode, the laminar flow rate by the air flow generating unit, the applied voltage by the voltage applying unit, and the measurement result of the current measuring unit. With evaluation means Characterized in that was.

請求項2の発明は、請求項1の発明において、層流の流路の途中であって帯電粒子量の評価時の気流発生方向において同心円筒状電極よりも下流側に配置されて空気を加熱するヒータと、気流発生手段による気流発生方向の正逆を切り換える送風方向切換手段と、結露検出手段が結露を検出した場合に、ヒータで空気を加熱させるとともに送風方向切換手段を用いて気流発生手段による気流発生方向を帯電粒子量の評価時と反対方向に切り換える暖気運転を行う暖気運転制御手段とを設けたことを特徴とする。   According to a second aspect of the present invention, in the first aspect of the present invention, the air is heated in the middle of the laminar flow path and downstream of the concentric cylindrical electrode in the air flow generation direction when evaluating the charged particle amount. A heater for heating, air blowing direction switching means for switching the direction of air flow generation by the air flow generating means, and when the condensation detection means detects condensation, the heater is used to heat the air and the air flow generation means using the air blowing direction switching means There is provided a warming-up operation control means for performing a warming-up operation for switching the airflow generation direction by the direction opposite to that at the time of evaluation of the charged particle amount.

請求項3の発明は、請求項2の発明において、暖気運転制御手段は、結露検出手段により結露無しと検出されるまで暖気運転を継続することを特徴とする。   According to a third aspect of the present invention, in the second aspect of the present invention, the warm-up operation control means continues the warm-up operation until the condensation detection means detects no condensation.

請求項4の発明は、請求項2又は3の発明において、気流発生手段の送風量を変化させる気流制御手段を設け、暖気運転制御手段は、暖気運転中に所定時間だけ、気流制御手段を用いて気流発生手段の送風量を帯電粒子量の評価時の送風量よりも大きい所定流量に増加させることを特徴とする。   According to a fourth aspect of the present invention, in the second or third aspect of the present invention, there is provided an air flow control means for changing the air flow rate of the air flow generating means, and the warm air operation control means uses the air flow control means for a predetermined time during the warm air operation. The air flow generation means is configured to increase the air flow rate to a predetermined flow rate larger than the air flow rate at the time of evaluating the charged particle amount.

請求項5の発明は、請求項1乃至4の何れか1つの発明において、結露検出手段は、電流測定手段の測定結果より求めた同心円筒状電極に蓄えられる電荷量および電圧印加手段による印加電圧から求めた静電容量と、同心円筒状電極の形状および寸法から求めた静電容量とを比較し、両者の差の絶対値が所定のしきい値を超えることから結露の発生を検出することを特徴とする。   According to a fifth aspect of the present invention, in the invention according to any one of the first to fourth aspects, the dew condensation detection means is the amount of charge stored in the concentric cylindrical electrode obtained from the measurement result of the current measurement means and the voltage applied by the voltage application means. Capacitance obtained from the above and the capacitance obtained from the shape and dimensions of concentric cylindrical electrodes are compared, and the occurrence of condensation is detected because the absolute value of the difference between the two exceeds a predetermined threshold. It is characterized by.

請求項1の発明によれば、帯電粒子量評価手段は、結露検出手段により結露無しと検出された場合に、帯電粒子量の評価を行っており、誤差が発生しやすい結露環境下では帯電粒子量の評価を行っていないので、精度の高い帯電粒子量の評価を行えるという効果がある。   According to the first aspect of the present invention, the charged particle amount evaluating means evaluates the charged particle amount when the condensation detecting means detects that there is no condensation, and in a condensation environment where errors are likely to occur, the charged particles Since the amount is not evaluated, there is an effect that the charged particle amount can be evaluated with high accuracy.

請求項2の発明によれば、結露検出手段により結露ありと検出された場合には、暖気運転制御手段が、ヒータにより空気を加熱させるとともに、気流発生手段の送風方向を帯電粒子量の評価時と反対方向に切り換えており、ヒータの加熱で暖められた空気が内側導体と外側導体との間の空間に送風されるので、層流の流路の壁面をなす内側導体および外側導体の結露を取り除くことができる。また、暖気運転の結果、結露が検出されなくなると、帯電粒子量評価手段により帯電粒子量の評価が行われるので、より高い精度で帯電粒子量を評価することができる。   According to the second aspect of the present invention, when the dew condensation detecting means detects that there is dew condensation, the warm-up operation control means heats the air with the heater, and the air flow generating means determines the blowing direction when the charged particle amount is evaluated. Since the air heated by the heater is blown into the space between the inner conductor and the outer conductor, the condensation of the inner and outer conductors forming the wall surface of the laminar flow path is prevented. Can be removed. Further, when condensation is no longer detected as a result of the warm-up operation, the charged particle amount is evaluated by the charged particle amount evaluating means, so that the charged particle amount can be evaluated with higher accuracy.

請求項3の発明によれば、結露検出手段により結露無しと検出されるまで、暖気運転制御手段が暖気運転を継続しているので、結露を取り除くのに必要な最短時間で暖気運転を終了して、帯電粒子量の評価を行える状態に復帰させることができる。   According to the invention of claim 3, since the warm-up operation control means continues the warm-up operation until the condensation detection means detects no condensation, the warm-up operation is completed in the shortest time necessary to remove the condensation. Thus, it is possible to return to a state where the charged particle amount can be evaluated.

請求項4の発明によれば、暖気運転制御手段が、暖気運転中に所定時間だけ、気流発生手段の送風量を帯電粒子量の評価時の送風量よりも大きい所定流量に増加させているので、結露を取り除くとともに内側導体や外側導体に付着した塵や埃を吹き飛ばすことができ、より精度の高い帯電粒子量の評価が行える。   According to the invention of claim 4, since the warm-up operation control means increases the air flow rate of the air flow generating means to a predetermined flow rate larger than the air flow rate at the time of evaluating the charged particle amount for a predetermined time during the warm-up operation. In addition to removing condensation, it is possible to blow off dust and dirt adhering to the inner conductor and the outer conductor, and the charged particle amount can be evaluated with higher accuracy.

請求項5の発明によれば、結露検出手段は、電流測定手段の測定結果より求めた同心円筒状電極に蓄えられる電荷量および電圧印加手段による印加電圧から求めた静電容量と、同心円筒状電極の形状および寸法から求めた静電容量との差の絶対値が所定のしきい値を超えることから、結露の発生を検出しているので、結露検出用のセンサを別途設ける必要が無く、結露の有無を安価に検出できるという効果がある。   According to the fifth aspect of the present invention, the dew condensation detection means includes a capacitance obtained from the amount of charge stored in the concentric cylindrical electrode obtained from the measurement result of the current measurement means and a voltage applied by the voltage application means, and a concentric cylindrical shape. Since the absolute value of the difference from the capacitance determined from the electrode shape and dimensions exceeds a predetermined threshold, the occurrence of condensation is detected, so there is no need to provide a separate sensor for detecting condensation. There is an effect that the presence or absence of condensation can be detected at low cost.

以下に本発明の実施の形態を図面に基づいて説明する。   Embodiments of the present invention will be described below with reference to the drawings.

(実施形態1)
本発明の実施形態1を図1及び図2に基づいて説明する。本実施形態の帯電粒子量評価装置1は、図1に示すように、同心円筒状電極2と、気流発生手段たる吸気ファン3と、電流測定手段たる電流計4と、電圧印加手段たる電圧源5と、コントローラ10とを主要な構成として備えている。
(Embodiment 1)
A first embodiment of the present invention will be described with reference to FIGS. 1 and 2. As shown in FIG. 1, a charged particle amount evaluation apparatus 1 according to the present embodiment includes a concentric cylindrical electrode 2, an intake fan 3 serving as an air flow generating unit, an ammeter 4 serving as a current measuring unit, and a voltage source serving as a voltage applying unit. 5 and the controller 10 are provided as main components.

同心円筒状電極2は、円柱状の内側導体2aおよび内側導体2aよりも径の大きい円筒状の外側導体2bを同心に配して構成される。内側導体2aおよび外側導体2bは帯電粒子を引き寄せやすく、且つ、両導体間に流れる電流を測定しやすいように導電率の高い材料で形成するのが好ましく、例えば真鍮の表面にクロムめっきを施して形成される。   The concentric cylindrical electrode 2 is configured by concentrically arranging a columnar inner conductor 2a and a cylindrical outer conductor 2b having a diameter larger than that of the inner conductor 2a. The inner conductor 2a and the outer conductor 2b are preferably formed of a material having high conductivity so that the charged particles can be easily attracted and the current flowing between the two conductors can be easily measured. It is formed.

内側導体2aは中空ではなく、周面に接地端子21と電流測定端子22とを備え、接地端子21に接続された接地線25を介してグランドに接地される。この内側導体2aは、帯電して電流が流れることによって誤差が生じるのを防止するために、高い絶縁性を有する保持部材(図示せず)を介して外側導体2b内に保持されており、保持部材の材料としては、例えば高絶縁性の三フッ化塩化エチレン樹脂を用いるのが好ましい。   The inner conductor 2 a is not hollow, and has a ground terminal 21 and a current measurement terminal 22 on the peripheral surface, and is grounded to the ground via a ground line 25 connected to the ground terminal 21. The inner conductor 2a is held in the outer conductor 2b via a holding member (not shown) having a high insulating property in order to prevent an error from occurring due to charging and current flowing. As a material for the member, it is preferable to use, for example, a highly insulating ethylene trifluoride chloride resin.

外側導体2bは中空円筒状であって、電源接続端子23と電流測定端子24とを備え、電源接続端子23を介して電圧源5の直流電圧が印加される。また内側導体2aの電流測定端子22と外側導体2bの電流測定端子24との間には電流計4が接続されている。ここに、内側導体2aの接地端子21と外側導体2bの電源接続端子23とで電圧印加端子が構成され、両導体2a,2b間に電圧源5の直流電圧が印加されようになっている。   The outer conductor 2 b has a hollow cylindrical shape and includes a power connection terminal 23 and a current measurement terminal 24, and a DC voltage from the voltage source 5 is applied through the power connection terminal 23. An ammeter 4 is connected between the current measurement terminal 22 of the inner conductor 2a and the current measurement terminal 24 of the outer conductor 2b. Here, the ground terminal 21 of the inner conductor 2a and the power connection terminal 23 of the outer conductor 2b constitute a voltage application terminal, and the DC voltage of the voltage source 5 is applied between the two conductors 2a and 2b.

ここで、帯電粒子の粒径および移動度と、外側導体2bおよび内側導体2aの間に印加した印加電圧と、同心円筒状電極2の形状および寸法の関係を図5に基づいて説明する。   Here, the relationship between the particle size and mobility of the charged particles, the applied voltage applied between the outer conductor 2b and the inner conductor 2a, and the shape and dimensions of the concentric cylindrical electrode 2 will be described with reference to FIG.

空気中の帯電粒子が等しい移動度を持っていると仮定し、同心円筒状電極2の吸気側において外側導体2bの縁の点Pから流入した帯電粒子が、導体2a,2b間の電界を受けて点Sで捕捉されたものとすると、同心円筒状電極2の筒内に流入してくる帯電粒子は全て内側導体2aに捕捉されることになる。なお帯電粒子が捕捉される点Sの位置は外側導体2bへの印加電圧や気流の流量を調整することで変化する。   Assuming that the charged particles in the air have the same mobility, the charged particles flowing from the point P at the edge of the outer conductor 2b on the intake side of the concentric cylindrical electrode 2 receive the electric field between the conductors 2a and 2b. Assuming that the particles are captured at the point S, all the charged particles flowing into the cylinder of the concentric cylindrical electrode 2 are captured by the inner conductor 2a. The position of the point S where the charged particles are captured changes by adjusting the voltage applied to the outer conductor 2b and the flow rate of the airflow.

ところで、実際の空気中には様々な移動度を持った帯電粒子が存在しており、ある印加電圧および流量の条件下で点Pから流入し、内側導体2aにおいて出口側の縁の点Tで捕捉される帯電粒子の移動度を臨界移動度と呼ぶ。この臨界移動度は、内側導体2aで捕捉可能な帯電粒子と、内側導体2aで捕捉できない帯電粒子の境界を示し、臨界移動度よりも移動度の大きな帯電粒子は内側導体2aで全て捕捉されるが、臨界移動度よりも移動度の小さい帯電粒子は一部が捕捉されずに、同心円筒状電極2の出口から外部へ流出することになる。   By the way, charged particles having various mobilities exist in the actual air, and flow from the point P under a certain applied voltage and flow rate, and at the edge T on the outlet side of the inner conductor 2a. The mobility of charged particles to be trapped is called critical mobility. This critical mobility indicates a boundary between charged particles that can be captured by the inner conductor 2a and charged particles that cannot be captured by the inner conductor 2a, and all charged particles having a mobility higher than the critical mobility are captured by the inner conductor 2a. However, a part of the charged particles whose mobility is lower than the critical mobility is not captured and flows out from the outlet of the concentric cylindrical electrode 2 to the outside.

例えば図5中の点Rから流入した帯電粒子が点Tで捕捉されたものとすると、移動度が同じ帯電粒子で、点Rを通る同心円C1と外側導体2bとの間の領域から流入する帯電粒子は同心円筒状電極2の出口から流出することになり、同心円C1と内側導体2aの間の領域(図中の斜線部)から流入した帯電粒子のみが内側導体2aで捕捉されることになる。   For example, if the charged particles flowing from the point R in FIG. 5 are captured at the point T, the charged particles having the same mobility and charged from the region between the concentric circle C1 passing through the point R and the outer conductor 2b. The particles flow out from the outlet of the concentric cylindrical electrode 2, and only the charged particles flowing in from the region between the concentric circle C1 and the inner conductor 2a (the hatched portion in the figure) are captured by the inner conductor 2a. .

ここで、帯電粒子の臨界移動度kcは、外側導体2bへの印加電圧がV、内側導体2aと外側導体2bとの間に流れる層流の流量がφ、外側導体2bの半径がr0、内側導体2aの半径がr1、同心円筒状電極2の軸方向の全長がLの場合に、以下の式(1)を用いて表される。   Here, the critical mobility kc of the charged particles is such that the applied voltage to the outer conductor 2b is V, the laminar flow rate between the inner conductor 2a and the outer conductor 2b is φ, the radius of the outer conductor 2b is r0, the inner When the radius of the conductor 2a is r1 and the total length in the axial direction of the concentric cylindrical electrode 2 is L, the following expression (1) is used.

Figure 2008102037
Figure 2008102037

また、移動度kcと帯電粒子の粒径Dpとの関係は、帯電粒子の荷電数をnp、電気素量をe、カニンガム補正係数をCc、空気の粘性係数をμとした時に以下の式(2)で表される。   Further, the relationship between the mobility kc and the particle size Dp of the charged particles is expressed by the following formula when the charged number of the charged particles is np, the elementary charge is e, the Cunningham correction coefficient is Cc, and the viscosity coefficient of air is μ: 2).

Figure 2008102037
Figure 2008102037

ここで、カニンガム補正係数Ccは粒径Dpの関数であり、臨界移動度kcと粒径Dp及び印加電圧Vは上記の式(1)と式(2)を連立して求めることができる。なお、粒径Dpと印加電圧Vとの関係を求める際には、カニンガム補正係数Ccが粒径Dpにより変化するため、式(1)と式(2)を連立して臨界移動度kcを消去した式から数値的に算出する。   Here, the Cunningham correction coefficient Cc is a function of the particle diameter Dp, and the critical mobility kc, the particle diameter Dp, and the applied voltage V can be obtained by simultaneous equations (1) and (2). When determining the relationship between the particle size Dp and the applied voltage V, the Cunningham correction coefficient Cc varies depending on the particle size Dp, and therefore, the critical mobility kc is eliminated by simultaneous equations (1) and (2). Calculate numerically from the formula.

ところで、本実施形態では粒径の測定範囲を例えば0.6〜28nmとして以下の説明を行う。ここで、帯電粒子の荷電数npを1と仮定すると、式(2)より電気移動度は5.49〜0.00274cm/V・sとなる。また、層流の流量φを0.05m/min(50L/min)、内側導体2aの半径r1を4.5cm、外側導体2bの半径r0を4.8cmとし、同心円筒状電極2の全長を52cmと固定した場合、印加電圧Vは0〜60Vとなる。 By the way, in the present embodiment, the following description will be made assuming that the measurement range of the particle size is, for example, 0.6 to 28 nm. Here, assuming that the charged particle number np is 1, the electric mobility is 5.49 to 0.00274 cm 2 / V · s from the equation (2). The laminar flow rate φ is 0.05 m 3 / min (50 L / min), the radius r 1 of the inner conductor 2 a is 4.5 cm, the radius r 0 of the outer conductor 2 b is 4.8 cm, and the total length of the concentric cylindrical electrode 2 Is fixed at 52 cm, the applied voltage V is 0 to 60V.

また、吸気ファン3は、帯電粒子量の評価時の気流発生方向において同心円筒状電極2に対し気流の出口側(図1中の右側)に配置され、内側導体2aと外側導体2bの間の環状空間2cの空気を吸引することによって、この環状空間2c内に同心円筒状電極2の軸方向に沿って流れる気流を生成している。吸気ファン3の回転数は一定に保たれ、気流の流量を一定にしている。また、両導体2a,2b間の空間(環状空間2c)内に層流を生成するために、吸気ファン3の備える回転羽根(図示せず)の径が外側導体2bの径よりも大きく形成されており、回転羽根の回転面が同心円筒状電極2の中心軸方向と直交し、且つ、回転羽根の回転軸と同心円筒状電極2の中心軸とが同一直線上に存在するように吸気ファン3が配置され、同心円筒状電極2と吸気ファン3との間に気流の流れを乱す凹凸が出来ないように接続されている。なお両導体2a,2bの間の空間に層流を生成するのは、同心円筒状電極2の入口側(図1中の左側)から両導体2a,2bの間の空間に流入した帯電粒子を同心円筒状電極2の軸方向と平行に進ませることによって、帯電粒子を一定速度で移動する状態にして電界を作用させるためである。   Further, the intake fan 3 is disposed on the air flow outlet side (right side in FIG. 1) with respect to the concentric cylindrical electrode 2 in the air flow generation direction at the time of evaluation of the charged particle amount, and between the inner conductor 2a and the outer conductor 2b. By sucking the air in the annular space 2c, an airflow flowing along the axial direction of the concentric cylindrical electrode 2 is generated in the annular space 2c. The rotational speed of the intake fan 3 is kept constant, and the flow rate of the airflow is kept constant. Further, in order to generate a laminar flow in the space between the two conductors 2a and 2b (annular space 2c), the diameter of the rotary blade (not shown) provided in the intake fan 3 is formed larger than the diameter of the outer conductor 2b. The rotary fan has a rotation surface orthogonal to the direction of the central axis of the concentric cylindrical electrode 2, and the intake fan so that the rotation axis of the rotary blade and the central axis of the concentric cylindrical electrode 2 exist on the same straight line. 3 is arranged and connected between the concentric cylindrical electrode 2 and the intake fan 3 so as not to have irregularities that disturb the flow of airflow. The laminar flow is generated in the space between the two conductors 2a and 2b because the charged particles flowing into the space between the two conductors 2a and 2b from the inlet side (left side in FIG. 1) of the concentric cylindrical electrode 2 are generated. This is because the electric field is applied by moving the charged particles at a constant speed by advancing parallel to the axial direction of the concentric cylindrical electrode 2.

電流計4は、内側導体2aの電流測定端子22と外側導体2bの電流測定端子24との間に接続されるデジタル式の電流計であり、電流の測定値は後述の電流値取得部12によって自動的に取得される。なお内側導体2aと外側導体2bとの間に流れる電流から帯電粒子の粒子数を求めることができ、両導体2a,2b間に流れる電流をisとすると、帯電粒子の荷電数npを1と仮定しているので、帯電粒子の個数nsは以下の式(3)で表される。なお、荷電数npが1でないときには、式(3)の電気素量eに荷電数npを乗じることにより算出できる。但し、eは電気素量、φは気流の流量である。   The ammeter 4 is a digital ammeter connected between the current measurement terminal 22 of the inner conductor 2a and the current measurement terminal 24 of the outer conductor 2b. The measured value of the current is measured by a current value acquisition unit 12 described later. Obtained automatically. The number of charged particles can be obtained from the current flowing between the inner conductor 2a and the outer conductor 2b. If the current flowing between the two conductors 2a and 2b is is assumed, the charged number np of the charged particles is assumed to be 1. Therefore, the number ns of charged particles is expressed by the following formula (3). When the charge number np is not 1, it can be calculated by multiplying the electric quantity e in the equation (3) by the charge number np. Here, e is the elementary electric charge, and φ is the airflow rate.

Figure 2008102037
Figure 2008102037

また、電圧源5は、電源接続端子23を介して外側導体2bに直流電圧を印加する可変電源であり、自動制御で測定が行えるように後述の電圧制御部11によって印加電圧が自動的に制御される。なお、電圧源5による印加電圧の極性は正又は負に切り替えることが可能であり、電圧源5による印加電圧が正の電圧であれば正の帯電粒子を計測でき、印加電圧が負の電圧であれば負の帯電粒子を計測することができる。   The voltage source 5 is a variable power source that applies a DC voltage to the outer conductor 2b via the power connection terminal 23, and the applied voltage is automatically controlled by a voltage control unit 11 described later so that measurement can be performed by automatic control. Is done. The polarity of the voltage applied by the voltage source 5 can be switched between positive and negative. If the voltage applied by the voltage source 5 is positive, positive charged particles can be measured, and the applied voltage is negative. If so, negatively charged particles can be measured.

次にコントローラ10の構成について説明する。コントローラ10は電圧制御部11と電流値取得部12と入力部13と演算処理部14を主要な構成として備える。   Next, the configuration of the controller 10 will be described. The controller 10 includes a voltage control unit 11, a current value acquisition unit 12, an input unit 13, and an arithmetic processing unit 14 as main components.

電圧制御部11は、後述の粒径算出部15から入力された印加電圧の電圧値および極性に基づいて電圧源5の印加電圧を自動的に制御する。   The voltage controller 11 automatically controls the applied voltage of the voltage source 5 based on the voltage value and polarity of the applied voltage input from the particle size calculator 15 described later.

電流値取得部12は、電流計4から電流の測定値を自動的に取得し、取得した電流値を粒径算出部15と後述の結露検出部16(結露検出手段)とに出力する。   The current value acquisition unit 12 automatically acquires a current measurement value from the ammeter 4 and outputs the acquired current value to a particle size calculation unit 15 and a dew condensation detection unit 16 (condensation detection unit) described later.

入力部13は、測定しようとする帯電粒子の測定範囲、極性及び粒径のスイープ幅、流量及び同心円筒状電極2の寸法などの測定条件をユーザが入力するためのものであり、入力された測定条件は演算処理部14の粒径算出部15と結露検出部16とに出力される。   The input unit 13 is for the user to input measurement conditions such as the measurement range of the charged particles to be measured, the sweep width of the polarity and the particle size, the flow rate, and the dimensions of the concentric cylindrical electrode 2. The measurement conditions are output to the particle size calculation unit 15 and the dew condensation detection unit 16 of the arithmetic processing unit 14.

演算処理部14は、粒径算出部15(帯電粒子量評価手段)と結露検出部16とを備え、電圧制御部11を用いて電圧源5の印加電圧を設定したり、電流値取得部12から得られた電流値をもとに帯電粒子の粒径分布を求めたり、結露検出部16により内側電極2a又は外側電極2bの結露が検出されると粒径算出部15に結露の検出信号を出力する機能を有している。尚、演算処理部14は例えばマイクロコンピュータを用いて構成され、粒径算出部15および結露検出部16はマイクロコンピュータの演算機能によって実現される。   The arithmetic processing unit 14 includes a particle size calculation unit 15 (charged particle amount evaluation unit) and a dew condensation detection unit 16, and sets an applied voltage of the voltage source 5 using the voltage control unit 11 or a current value acquisition unit 12. The particle size distribution of the charged particles is obtained based on the current value obtained from the above, or when the dew condensation detection unit 16 detects dew condensation on the inner electrode 2a or the outer electrode 2b, a dew condensation detection signal is sent to the particle size calculation unit 15. It has a function to output. The arithmetic processing unit 14 is configured using, for example, a microcomputer, and the particle size calculation unit 15 and the dew condensation detection unit 16 are realized by a calculation function of the microcomputer.

粒径算出部15は、入力部13から入力された測定条件に従い、測定対象の帯電粒子の粒径と移動度の関係から、外側導体2bに印加する電圧を算出して算出結果を電圧制御部11と結露検出部16に出力するとともに、電流値取得部12から取得した電流値をもとに、電圧源5の印加電圧により設定される粒径以下の帯電粒子の個数を算出する。粒径算出部15では、電圧制御部11を用いて電圧源5の印加電圧をスイープさせることで、測定対象の粒径を所定のスイープ幅ずつ変化させており、測定対象の粒径をスイープ幅だけ変化させる毎に粒子数を測定することによって、帯電粒子の粒子数の粒径分布を求めることができる。さらに、粒径算出部15は計測したい帯電粒子の極性を電圧制御部11に出力する。また、粒径算出部15は、計測した粒径分布を電子データとして記憶部(図示せず)に記憶させるとともに、図示しない出力装置(プリンタやモニタ装置など)に粒径分布を出力する。また、粒径算出部15は、後述の結露検出部16から結露の検出信号が入力されると、検出信号が入力される間は帯電粒子量の評価を停止する機能を有している。   The particle size calculation unit 15 calculates the voltage applied to the outer conductor 2b from the relationship between the particle size of the charged particles to be measured and the mobility in accordance with the measurement conditions input from the input unit 13, and calculates the calculation result as a voltage control unit. 11 and the condensation detection unit 16, and the number of charged particles having a particle size equal to or smaller than the particle size set by the applied voltage of the voltage source 5 is calculated based on the current value acquired from the current value acquisition unit 12. In the particle size calculation unit 15, the voltage applied by the voltage source 5 is swept using the voltage control unit 11 to change the particle size of the measurement target by a predetermined sweep width, and the particle size of the measurement target is changed to the sweep width. By measuring the number of particles every time it is changed, the particle size distribution of the number of charged particles can be obtained. Further, the particle size calculator 15 outputs the polarity of the charged particles to be measured to the voltage controller 11. The particle size calculator 15 stores the measured particle size distribution as electronic data in a storage unit (not shown) and outputs the particle size distribution to an output device (printer, monitor device, etc.) not shown. Further, the particle size calculation unit 15 has a function of stopping the evaluation of the charged particle amount while a detection signal is input when a detection signal of condensation is input from the condensation detection unit 16 described later.

結露検出部16は、同心円筒状電極2の形状および寸法から求めた静電容量C1と、電流値取得部12が取得した電流値より求めた同心円筒状電極2に蓄えられる電荷量および電圧源5の印加電圧から求めた静電容量C2とを比較することによって、結露の発生を検出する。すなわち、結露検出部16は、入力部13から入力された測定条件(同心円筒状電極2の寸法)をもとに、以下の式(4)を用いて同心円筒状電極2の静電容量C1を求める。但し、εは空気の誘電率である。   The dew condensation detection unit 16 includes a capacitance C1 obtained from the shape and dimensions of the concentric cylindrical electrode 2 and a charge amount and voltage source stored in the concentric cylindrical electrode 2 obtained from the current value obtained by the current value obtaining unit 12. The occurrence of condensation is detected by comparing the capacitance C2 obtained from the applied voltage 5. That is, the dew condensation detection unit 16 uses the following equation (4) based on the measurement conditions (dimensions of the concentric cylindrical electrode 2) input from the input unit 13, and the electrostatic capacitance C1 of the concentric cylindrical electrode 2: Ask for. Where ε is the dielectric constant of air.

Figure 2008102037
Figure 2008102037

この静電容量C1は、同心円筒状電極2の形状および寸法で決まる固有の値である。   This capacitance C1 is a unique value determined by the shape and dimensions of the concentric cylindrical electrode 2.

一方、結露検出部16は、電流値取得部12から入力された電流値isとその時間tと印加電圧Vから、以下の式(5)を用いて静電容量C2を求める。   On the other hand, the dew condensation detection unit 16 obtains the capacitance C2 from the current value is input from the current value acquisition unit 12, the time t, and the applied voltage V using the following equation (5).

Figure 2008102037
Figure 2008102037

そして、結露検出部16は、同心円筒状電極2の形状および寸法で決まる同心円筒状電極2に固有の静電容量C1と、電流値isと印加電圧Vとから求めた実際の静電容量C2とを比較し、両者が異なる値になると(すなわち静電容量C1,C2の差の絶対値が所定のしきい値を超えると)、結露の発生を示す結露検出信号を粒径算出部15に出力するのである。   The dew condensation detection unit 16 then determines the actual capacitance C2 obtained from the capacitance C1 inherent to the concentric cylindrical electrode 2 determined by the shape and dimensions of the concentric cylindrical electrode 2, the current value is, and the applied voltage V. If the two values are different (that is, if the absolute value of the difference between the capacitances C1 and C2 exceeds a predetermined threshold value), a dew condensation detection signal indicating the occurrence of dew condensation is sent to the particle size calculation unit 15 It outputs.

次に本実施形態の帯電粒子量評価装置1の動作を図2のフロー図に従って説明する。   Next, the operation of the charged particle amount evaluation apparatus 1 of the present embodiment will be described with reference to the flowchart of FIG.

先ずコントローラ10の電源を投入する。コントローラ10に電力が供給されて、コントローラ10が動作を開始すると、測定担当者が入力部13を用いて帯電粒子の粒径の測定範囲および極性と、粒径のスイープ幅と、同心円筒状電極2の寸法などの測定条件を入力する(ステップS1)。   First, the controller 10 is turned on. When power is supplied to the controller 10 and the controller 10 starts to operate, the person in charge of measurement uses the input unit 13 to measure the range and polarity of the particle size of the charged particles, the sweep width of the particle size, and the concentric cylindrical electrode. Measurement conditions such as the dimension 2 are input (step S1).

次に電圧源5の電源を投入する。但し電源投入時には電圧源5の電圧はゼロに設定されている。尚、コントローラ10の電源と連動して、電圧源5の電源を投入させても良い。   Next, the power source of the voltage source 5 is turned on. However, when the power is turned on, the voltage of the voltage source 5 is set to zero. The power source of the voltage source 5 may be turned on in conjunction with the power source of the controller 10.

電圧源5の電源が投入されると、粒径算出部15は、入力部13を用いて入力された帯電粒子の粒径の測定範囲および極性と、帯電粒子の流量と、同心円筒状電極2の寸法などの測定条件をもとに、前述の粒径、臨界移動度および印加電圧の関係式(1)(2)を連立して解くことにより、測定対象の粒径範囲に対応する印加電圧の変動範囲と、粒径のスイープ幅に対応した印加電圧のスイープ幅を算出しており、粒径を最小値から最大値まで所定のスイープ幅で変化させる際に各々の粒径に対応した印加電圧を求めている(ステップS2)。   When the power source of the voltage source 5 is turned on, the particle size calculation unit 15 detects the particle size measurement range and polarity of the charged particles input using the input unit 13, the flow rate of the charged particles, and the concentric cylindrical electrode 2. The applied voltage corresponding to the particle size range to be measured can be solved by simultaneously solving the relational expressions (1) and (2) of the particle size, critical mobility and applied voltage based on the measurement conditions such as the dimensions of The range of fluctuations and the sweep width of the applied voltage corresponding to the sweep width of the particle size are calculated, and when changing the particle size from the minimum value to the maximum value with a predetermined sweep width, the application corresponding to each particle size The voltage is obtained (step S2).

次に粒径算出部15は、粒径の最小値に対応した印加電圧の電圧値及び極性を電圧制御部11と結露検出部16とに出力する(ステップS3)。今回の測定条件では粒径の最小値は0.6nmである。このとき、電圧制御部11が電圧源5の印加電圧を設定して、粒径の最小値に対応した印加電圧が外側導体2bに印加される(ステップS4)。なお外側導体2bに印加される電圧の極性は測定対象の帯電粒子の極性と同極性であり、負の帯電粒子を測定したい場合は外側導体2bに印加する電圧の極性を負極性とする。これによって、内側導体2aから外側導体2bに電界が発生し、この電界により負の帯電粒子はグランドに接地された内側導体2aに引き寄せられる。そして、電圧源5の印加電圧で設定された粒径以下の帯電粒子は内側導体2aに取り込まれて、内側導体2aと外側導体2bとの間に電流が流れるのである(ステップS5)。   Next, the particle size calculation unit 15 outputs the voltage value and polarity of the applied voltage corresponding to the minimum value of the particle size to the voltage control unit 11 and the dew condensation detection unit 16 (step S3). Under the current measurement conditions, the minimum value of the particle size is 0.6 nm. At this time, the voltage control unit 11 sets the applied voltage of the voltage source 5, and the applied voltage corresponding to the minimum value of the particle size is applied to the outer conductor 2b (step S4). Note that the polarity of the voltage applied to the outer conductor 2b is the same as the polarity of the charged particles to be measured. When negatively charged particles are to be measured, the polarity of the voltage applied to the outer conductor 2b is negative. As a result, an electric field is generated from the inner conductor 2a to the outer conductor 2b, and negatively charged particles are attracted to the inner conductor 2a grounded to the ground by the electric field. Then, charged particles having a particle size equal to or smaller than the particle size set by the voltage applied by the voltage source 5 are taken into the inner conductor 2a, and a current flows between the inner conductor 2a and the outer conductor 2b (step S5).

内側導体2aに取り込まれた帯電粒子によって電流が流れると、その電流値は電流計4によって測定される。電流計4の測定値は電流値取得部12によって自動的に取得され、電流値取得部12は取得した電流値を粒径算出部15及び結露検出部16に出力する(ステップS6)。   When a current flows through the charged particles taken into the inner conductor 2a, the current value is measured by the ammeter 4. The measurement value of the ammeter 4 is automatically acquired by the current value acquisition unit 12, and the current value acquisition unit 12 outputs the acquired current value to the particle size calculation unit 15 and the dew condensation detection unit 16 (step S6).

結露検出部16は、入力部13を用いて入力された測定条件から式(4)を用いて同心円筒状電極2に固有の静電容量C1を算出して、図示しない記憶部に記憶させる(ステップS7)。なお、静電容量C1を算出するステップS7の処理は、入力部13を用いて測定条件が入力される毎に1回だけ行えば良く、以後は記憶部から静電容量C1の値を読み込めば良い。   The dew condensation detection unit 16 calculates the capacitance C1 inherent to the concentric cylindrical electrode 2 from the measurement conditions input using the input unit 13 using the equation (4), and stores it in a storage unit (not shown) ( Step S7). The process of step S7 for calculating the capacitance C1 need only be performed once every time measurement conditions are input using the input unit 13, and thereafter, the value of the capacitance C1 is read from the storage unit. good.

また結露検出部16は、粒径算出部15から入力された印加電圧Vと、電流値取得部12から取得した電流値isと、取得した時間tとから、上述の式(5)を用いて実際の静電容量C2を算出して、記憶部に記憶させ(ステップS8)、ステップS7で求めた固有の静電容量C1との比較により結露の有無を判断する(ステップS9)。つまり結露検出部16は、同心円筒状電極2の形状および寸法から求めた固有の静電容量C1と、実際の静電容量C2とが一致しているか否かを判断し、一致していなければ(つまり静電容量C1,C2の差の絶対値が所定のしきい値を超えると)、結露が発生したと判断して、結露検出信号を粒径算出部15に出力し(ステップS10)、その後結露が検出されなくなるまで結露検出信号を粒径算出部15に出力し続ける。   Also, the dew condensation detection unit 16 uses the above equation (5) from the applied voltage V input from the particle size calculation unit 15, the current value is acquired from the current value acquisition unit 12, and the acquired time t. The actual capacitance C2 is calculated and stored in the storage unit (step S8), and the presence or absence of condensation is determined by comparison with the specific capacitance C1 obtained in step S7 (step S9). That is, the dew condensation detection unit 16 determines whether or not the intrinsic capacitance C1 obtained from the shape and size of the concentric cylindrical electrode 2 and the actual capacitance C2 match, and if they do not match. (In other words, when the absolute value of the difference between the capacitances C1 and C2 exceeds a predetermined threshold value), it is determined that condensation has occurred, and a condensation detection signal is output to the particle size calculator 15 (step S10). Thereafter, the dew condensation detection signal is continuously output to the particle size calculator 15 until dew condensation is no longer detected.

ここで、粒径算出部15は、結露検出部16から結露検出信号が入力されると、直ちに帯電粒子量の評価を停止し(ステップS11)、結露検出信号が入力されなくなるまで上述のステップS6〜S9の処理を繰り返し実行する。一方、粒径算出部15は、結露検出部16から結露検出信号が入力されなくなると、電流値取得部12から入力された電流値isから、上述の式(3)を用いて最小粒径以下の帯電粒子の数を算出し、測定対象の帯電粒子の粒径および個数を記憶部に記憶させる(ステップS12)。   Here, when the dew condensation detection signal is input from the dew condensation detection unit 16, the particle size calculation unit 15 immediately stops the evaluation of the charged particle amount (step S11), and the above-described step S6 until the dew condensation detection signal is not input. The process of S9 is repeatedly executed. On the other hand, when the dew condensation detection signal is not input from the dew condensation detection unit 16, the particle size calculation unit 15 uses the current value is input from the current value acquisition unit 12 and uses the above equation (3) to obtain the minimum particle size or less. The number of charged particles is calculated, and the particle size and number of charged particles to be measured are stored in the storage unit (step S12).

測定対象の帯電粒子の粒径と個数とを記憶部に記憶させると、粒径算出部15では全ての測定範囲について測定を終了したか否かを判断し(ステップS13)、測定が終わっていなければ、粒径を所定のスイープ幅だけ増加させた場合の印加電圧の電圧値及び極性を電圧制御部11および結露検出部16に出力した後(ステップS14)、上述のステップS4〜S12の処理を繰り返す。尚、本実施形態では0.6〜2nmの粒径範囲ではスイープ幅を0.2nm、2〜28nmの粒径範囲ではスイープ幅を2nmとしているので、最小粒径(0.6nm)の次は粒径が0.8nmの時の印加電圧の電圧値を出力する。   When the particle size and number of charged particles to be measured are stored in the storage unit, the particle size calculation unit 15 determines whether or not the measurement has been completed for all measurement ranges (step S13), and the measurement must be completed. For example, after outputting the voltage value and polarity of the applied voltage when the particle size is increased by a predetermined sweep width to the voltage control unit 11 and the dew condensation detection unit 16 (step S14), the processing of the above steps S4 to S12 is performed. repeat. In the present embodiment, the sweep width is 0.2 nm in the particle size range of 0.6 to 2 nm, and the sweep width is 2 nm in the particle size range of 2 to 28 nm. The voltage value of the applied voltage when the particle size is 0.8 nm is output.

本装置では上述の処理を行い、粒径を0.6nmから28nmまで所定のスイープ幅ずつスイープさせる毎に、各々の粒径の設定値で上記の処理S4〜S13を繰り返すことによって粒子数を算出して、粒径分布(粒径に対する個数の分布)を求めており、ステップS13において、粒径算出部15が、全ての測定範囲で測定を終了したと判断すると、粒径分布の算出結果を記憶部に記憶させるとともに、出力装置に測定結果を出力する(ステップS15)。   In this device, the number of particles is calculated by repeating the above-described processing S4 to S13 at each particle size setting value every time the particle size is swept by a predetermined sweep width from 0.6 nm to 28 nm. Then, the particle size distribution (number distribution with respect to the particle size) is obtained, and in step S13, when the particle size calculation unit 15 determines that the measurement has been completed in the entire measurement range, the calculation result of the particle size distribution is obtained. While memorize | storing in a memory | storage part, a measurement result is output to an output device (step S15).

以上説明したように本実施形態の帯電粒子量評価装置1では、同心円筒状電極2において層流の流路の壁面をなす内側導体2aおよび外側導体2bの結露の有無を検出する結露検出部16を設け、結露検出部16により結露が無いと判断された場合に粒径算出部15が帯電粒子量の評価を行っており、測定の誤差が発生しやすい結露環境下では帯電粒子量の評価を行わないので、精度の高い帯電粒子量の評価を行うことができる。   As described above, in the charged particle amount evaluation apparatus 1 of the present embodiment, the dew condensation detection unit 16 that detects the presence or absence of dew condensation on the inner conductor 2a and the outer conductor 2b forming the wall surface of the laminar flow channel in the concentric cylindrical electrode 2. The particle size calculation unit 15 evaluates the charged particle amount when the condensation detection unit 16 determines that there is no condensation, and the charged particle amount is evaluated in a condensation environment where measurement errors are likely to occur. Since it is not performed, the charged particle amount can be evaluated with high accuracy.

また結露検出部16では、同心円筒状電極2の形状および寸法から求めた静電容量C1と、電流値取得部12の取得した電流値より求めた同心円筒状電極2に蓄えられる電荷量および電圧源5の印加電圧から求めた静電容量C2とを比較し、静電容量C1、C2の差の絶対値が所定のしきい値を超えることから、結露が発生したと判断しているので、結露検出用のセンサを別途設ける必要が無く、結露の有無を安価に検出することができる。   Further, in the dew condensation detection unit 16, the charge amount and voltage stored in the concentric cylindrical electrode 2 obtained from the electrostatic capacity C <b> 1 obtained from the shape and size of the concentric cylindrical electrode 2 and the current value obtained by the current value obtaining unit 12. Compared with the capacitance C2 obtained from the applied voltage of the source 5, and since the absolute value of the difference between the capacitances C1 and C2 exceeds a predetermined threshold value, it is determined that condensation has occurred. There is no need to separately provide a sensor for detecting condensation, and the presence or absence of condensation can be detected at low cost.

(実施形態2)
本発明の実施形態2を図3及び図4に基づいて説明する。
(Embodiment 2)
A second embodiment of the present invention will be described with reference to FIGS.

本実施形態では、実施形態1で説明した帯電粒子量評価装置1において、吸気ファン3に電源を供給する電圧源6と、吸気ファン3により発生される層流の流路の途中であって帯電粒子量の評価時の気流発生方向において同心円筒状電極2よりも下流側に配置されて空気を加熱するヒータ7と、電圧源6による印加電圧の極性を反転させることで吸気ファン3の気流発生方向の正逆を切り換える気流制御部17(送風方向切換手段)と、結露検出部16が結露の発生を検出すると、ヒータ7により吸気ファン3の近傍の空気を加熱させるとともに、気流制御部17を用いて吸気ファン3による気流発生方向を帯電粒子量の評価時と反対方向に切り換える暖気運転を行わせる暖気運転制御部18とを設けている。尚、電圧源6、ヒータ7、気流制御部17および暖気運転制御部18以外の構成は実施形態1と同様であるので、共通する構成要素には同一の符号を付して、その説明は省略する。   In the present embodiment, in the charged particle amount evaluation apparatus 1 described in the first embodiment, the charging is performed in the middle of the voltage source 6 for supplying power to the intake fan 3 and the laminar flow path generated by the intake fan 3. Airflow generation of the intake fan 3 by reversing the polarity of the voltage applied by the heater 7 which is arranged downstream of the concentric cylindrical electrode 2 in the airflow generation direction at the time of particle amount evaluation and heats the air and the voltage source 6 When the airflow control unit 17 (air blowing direction switching unit) that switches the direction and the dew condensation detection unit 16 detects the occurrence of dew condensation, the heater 7 heats the air in the vicinity of the intake fan 3 and the air flow control unit 17 There is provided a warming-up operation control unit 18 that performs a warming-up operation that switches the direction of airflow generation by the intake fan 3 to the direction opposite to that during the evaluation of the charged particle amount. The configuration other than the voltage source 6, the heater 7, the airflow control unit 17, and the warming-up operation control unit 18 is the same as that in the first embodiment, and therefore, common constituent elements are denoted by the same reference numerals and description thereof is omitted. To do.

電圧源6は、電圧端子31を介して吸気ファン3に直流電圧を印加する可変電源であり、気流制御部17により印加電圧の極性が正又は負に切り換えられるようになっている。例えば気流制御部17が電圧源6による印加電圧の極性を正の電圧とすると、吸気ファン3は同心円筒状電極2側から空気を吸気し、ヒータ7を介して図3中の右側に空気を送風しており、気流発生方向は矢印Aの方向となる。一方、気流制御部17が電圧源6による印加電圧の極性を負の電圧とすると、吸気ファン3はヒータ7側から空気を吸気し、同心円筒状電極2を介して図3中の左側に空気を送風しており、気流発生方向は矢印Bの方向となる。   The voltage source 6 is a variable power source that applies a DC voltage to the intake fan 3 via a voltage terminal 31, and the polarity of the applied voltage is switched between positive and negative by the airflow control unit 17. For example, when the airflow control unit 17 sets the polarity of the voltage applied by the voltage source 6 to a positive voltage, the intake fan 3 sucks air from the concentric cylindrical electrode 2 side, and the air flows to the right side in FIG. Air is blown, and the direction of airflow generation is the direction of arrow A. On the other hand, when the airflow control unit 17 sets the polarity of the voltage applied by the voltage source 6 to a negative voltage, the intake fan 3 draws air from the heater 7 side, and the air flows to the left side in FIG. 3 via the concentric cylindrical electrode 2. The air flow generation direction is the direction of arrow B.

ヒータ7は、吸気ファン3の近傍(本実施形態では帯電粒子量評価時の気流発生方向の排気側)の空気を加熱するものであり、暖気運転制御部18からの電源投入信号が接続端子71に入力されると、内蔵するスイッチが導通して、図示しない電圧源から電源が供給され、発熱するようになっている。   The heater 7 heats the air in the vicinity of the intake fan 3 (in this embodiment, the exhaust side in the direction of airflow generation when the charged particle amount is evaluated), and a power-on signal from the warm-up operation control unit 18 is connected to the connection terminal 71. When the signal is input to the switch, the built-in switch is turned on, and power is supplied from a voltage source (not shown) to generate heat.

入力部13は、実施形態1で説明した測定条件に加えて暖気運転時間を入力するためのものであり、入力された暖気運転時間を暖気運転制御部18に出力する機能を有している。   The input unit 13 is for inputting the warm-up operation time in addition to the measurement conditions described in the first embodiment, and has a function of outputting the input warm-up operation time to the warm-up operation control unit 18.

粒径算出部15は、実施形態1で説明した機能に加えて、結露検出部16から結露の検出信号が入力された後に結露の検出信号が入力されなくなると、帯電粒子量の測定を開始する機能を備えている。   In addition to the function described in the first embodiment, the particle size calculation unit 15 starts measuring the amount of charged particles when the dew condensation detection signal is not input after the dew condensation detection signal is input from the dew condensation detection unit 16. It has a function.

結露検出部16は実施形態1で説明したものと同様であり、結露の発生を検出すると結露の検出信号を粒径算出部15と暖気運転制御部18とに出力する。また実施形態1では、結露検出部16は、結露の発生を検出している間だけ結露の検出信号を出力しているのに対して、本実施形態では、結露検出部16が、結露の発生を検出して結露検出信号を出力すると、暖気運転制御部18から暖気運転の終了を示す暖気終了信号が入力されるまで結露の検出信号を出力し続けており、暖気終了信号が入力された時点で再度結露が検出されなければ、結露検出信号の出力を停止する。   The dew condensation detection unit 16 is the same as that described in the first embodiment. When the dew condensation is detected, a dew condensation detection signal is output to the particle size calculation unit 15 and the warm-up operation control unit 18. In the first embodiment, the dew condensation detection unit 16 outputs a dew condensation detection signal only while detecting the occurrence of dew condensation. In the present embodiment, the dew condensation detection unit 16 generates the dew condensation. Is detected and the dew condensation detection signal is output, the dew condensation detection signal continues to be output until the warm air end signal indicating the end of the warm air operation is input from the warm air operation control unit 18, and when the warm air end signal is input. If dew condensation is not detected again, the dew condensation detection signal output is stopped.

気流制御部17は、暖気運転制御部18から入力される極性切換信号の極性に応じて電圧源6の印加電圧の極性を切り換え、吸気ファン3による気流発生方向の正逆を反転させるようになっている。   The airflow control unit 17 switches the polarity of the voltage applied to the voltage source 6 in accordance with the polarity of the polarity switching signal input from the warm-up operation control unit 18, and reverses the forward / reverse direction of the airflow generation direction by the intake fan 3. ing.

暖気運転制御部18は、結露検出部16から結露の検出信号が入力されると、暖気運転を開始するために、気流制御部17に極性切換信号を出力して、吸気ファン3による気流発生方向を帯電粒子量の評価時と反対方向に切り換えるとともに、ヒータ7に電源投入信号を出力する機能を有している。暖気運転時にはヒータ7による加熱で乾燥させた空気が吸気ファン3に吸気されて、同心円筒状電極2の環状空間2c内へ送風されるので、内側導体2aや外側導体2bを暖めて、結露を取り除くことができる。また、暖気運転制御部18は、入力部13を用いて入力された暖気運転時間を図示しない記憶手段に保持させており、結露検出信号が入力されてから上記暖気運転時間が継続するまでの間暖気運転を行い、暖気運転時間が経過した時点で気流制御部17に極性切換信号を出力して気流発生方向を帯電粒子量の評価時の方向に反転させるとともに、ヒータ7の接続端子71に電源停止信号を出力して、ヒータ7への電源供給を停止させた後、結露検出部16に暖気終了信号を出力する。ここに、暖気運転時間は、内側導体2aおよび外側導体2bの結露を取り除くのに必要な時間よりもやや長い時間に設定されており、暖気運転を暖気運転時間だけ継続することで、内側導体2aおよび外側導体2bの結露を確実に無くすことができるようになっている。   When the dew condensation detection signal is input from the dew condensation detection unit 16, the warm air operation control unit 18 outputs a polarity switching signal to the air flow control unit 17 to start the warm air operation, and the direction of air flow generation by the intake fan 3. Is switched to the opposite direction to that during the evaluation of the charged particle amount, and a function for outputting a power-on signal to the heater 7 is provided. During the warming-up operation, air dried by heating by the heater 7 is sucked into the intake fan 3 and blown into the annular space 2c of the concentric cylindrical electrode 2, so that the inner conductor 2a and the outer conductor 2b are warmed to cause dew condensation. Can be removed. The warming-up operation control unit 18 holds the warming-up operation time input using the input unit 13 in a storage unit (not shown), and after the dew condensation detection signal is input until the warming-up operation time continues. When the warm-up operation is performed and the warm-up operation time elapses, a polarity switching signal is output to the air flow control unit 17 to reverse the air flow generation direction to the direction when the charged particle amount is evaluated, and the power supply is supplied to the connection terminal 71 of the heater 7. After stopping the power supply to the heater 7 by outputting a stop signal, a warm-up end signal is output to the dew condensation detection unit 16. Here, the warm-up operation time is set to a time slightly longer than the time required to remove the condensation of the inner conductor 2a and the outer conductor 2b, and the warm-up operation is continued for the warm-up operation time, whereby the inner conductor 2a. And the dew condensation of the outer conductor 2b can be reliably eliminated.

次に本実施形態の帯電粒子量評価装置1の動作を図4のフロー図に従って説明する。   Next, the operation of the charged particle amount evaluation apparatus 1 of this embodiment will be described with reference to the flowchart of FIG.

先ずコントローラ10の電源を投入する。コントローラ10に電力が供給されて、コントローラ10が動作を開始すると、測定担当者が入力部13を用いて帯電粒子の粒径の測定範囲および極性、粒径のスイープ幅および同心円筒状電極2の寸法などの測定条件と、暖気運転時間を入力する(ステップS1)。   First, the controller 10 is turned on. When electric power is supplied to the controller 10 and the controller 10 starts operating, the person in charge of measurement uses the input unit 13 to measure the particle diameter measurement range and polarity, the sweep width of the particle diameter, and the concentric cylindrical electrode 2. Measurement conditions such as dimensions and warm-up operation time are input (step S1).

次に、電圧源6の電源を投入する。但し電源投入時の電圧源6の電圧値は予め設定された値となっており、既知の流量の層流が吸気ファン3により発生される。尚、コントローラ10の電源と連動して、電圧源6の電源を投入させても良い。   Next, the power source of the voltage source 6 is turned on. However, the voltage value of the voltage source 6 when the power is turned on is a preset value, and a laminar flow having a known flow rate is generated by the intake fan 3. The power source of the voltage source 6 may be turned on in conjunction with the power source of the controller 10.

その後、電圧源5の電源を投入する。但し電源投入時には電圧源5の電圧はゼロに設定されている。尚、コントローラ10の電源と連動して、電圧源5の電源を投入させても良い。   Thereafter, the power source of the voltage source 5 is turned on. However, when the power is turned on, the voltage of the voltage source 5 is set to zero. The power source of the voltage source 5 may be turned on in conjunction with the power source of the controller 10.

電圧源5の電源が投入されると、粒径算出部15は、入力部13を用いて入力された帯電粒子の粒径の測定範囲および極性と、帯電粒子の流量と、同心円筒状電極2の寸法などの測定条件をもとに、前述の粒径、臨界移動度および印加電圧の関係式(1)(2)を連立して解くことにより、測定対象の粒径範囲に対応する印加電圧の変動範囲と、粒径のスイープ幅に対応した印加電圧のスイープ幅を算出しており、粒径を最小値から最大値まで所定のスイープ幅で変化させる際に各々の粒径に対応した印加電圧を求めている(ステップS2)。   When the power source of the voltage source 5 is turned on, the particle size calculation unit 15 detects the particle size measurement range and polarity of the charged particles input using the input unit 13, the flow rate of the charged particles, and the concentric cylindrical electrode 2. The applied voltage corresponding to the particle size range to be measured can be solved by simultaneously solving the relational expressions (1) and (2) of the particle size, critical mobility and applied voltage based on the measurement conditions such as the dimensions of The range of fluctuations and the sweep width of the applied voltage corresponding to the sweep width of the particle size are calculated, and when changing the particle size from the minimum value to the maximum value with a predetermined sweep width, the application corresponding to each particle size The voltage is obtained (step S2).

次に粒径算出部15は、粒径の最小値に対応した印加電圧の電圧値及び極性を電圧制御部11と結露検出部16とに出力する(ステップS3)。今回の測定条件では粒径の最小値は0.6nmである。このとき、電圧制御部11が電圧源5の印加電圧を設定して、粒径の最小値に対応した印加電圧が外側導体2bに印加される(ステップS4)。なお外側導体2bに印加される電圧の極性は測定対象の帯電粒子の極性と同極性であり、負の帯電粒子を測定したい場合は外側導体2bに印加する電圧の極性を負極性とする。これによって、内側導体2aから外側導体2bに電界が発生し、この電界により負の帯電粒子はグランドに接地された内側導体2aに引き寄せられる。そして、電圧源5の印加電圧で設定された粒径以下の帯電粒子は内側導体2aに取り込まれて、内側導体2aと外側導体2bとの間に電流が流れるのである(ステップS5)。   Next, the particle size calculation unit 15 outputs the voltage value and polarity of the applied voltage corresponding to the minimum value of the particle size to the voltage control unit 11 and the dew condensation detection unit 16 (step S3). Under the current measurement conditions, the minimum value of the particle size is 0.6 nm. At this time, the voltage control unit 11 sets the applied voltage of the voltage source 5, and the applied voltage corresponding to the minimum value of the particle size is applied to the outer conductor 2b (step S4). Note that the polarity of the voltage applied to the outer conductor 2b is the same as the polarity of the charged particles to be measured. When negatively charged particles are to be measured, the polarity of the voltage applied to the outer conductor 2b is negative. As a result, an electric field is generated from the inner conductor 2a to the outer conductor 2b, and negatively charged particles are attracted to the inner conductor 2a grounded to the ground by the electric field. Then, charged particles having a particle size equal to or smaller than the particle size set by the voltage applied by the voltage source 5 are taken into the inner conductor 2a, and a current flows between the inner conductor 2a and the outer conductor 2b (step S5).

内側導体2aに取り込まれた帯電粒子によって電流が流れると、その電流値は電流計4によって測定される。電流計4の測定値は電流値取得部12によって自動的に取得され、電流値取得部12は取得した電流値を粒径算出部15及び結露検出部16に出力する(ステップS6)。   When a current flows through the charged particles taken into the inner conductor 2a, the current value is measured by the ammeter 4. The measurement value of the ammeter 4 is automatically acquired by the current value acquisition unit 12, and the current value acquisition unit 12 outputs the acquired current value to the particle size calculation unit 15 and the dew condensation detection unit 16 (step S6).

結露検出部16は、入力部13を用いて入力された測定条件から式(4)を用いて同心円筒状電極2に固有の静電容量C1を算出して、図示しない記憶部に記憶させる(ステップS7)。なお、静電容量C1を算出するステップS7の処理は、入力部13を用いて測定条件が入力される毎に1回だけ行えば良く、以後は記憶部から静電容量C1の値を読み込めば良い。   The dew condensation detection unit 16 calculates the capacitance C1 inherent to the concentric cylindrical electrode 2 from the measurement conditions input using the input unit 13 using the equation (4), and stores it in a storage unit (not shown) ( Step S7). The process of step S7 for calculating the capacitance C1 need only be performed once every time measurement conditions are input using the input unit 13, and thereafter, the value of the capacitance C1 is read from the storage unit. good.

また結露検出部16は、粒径算出部15から入力された印加電圧Vと、電流値取得部12から取得した電流値isと、取得した時間tとから、上述の式(5)を用いて実際の静電容量C2を算出して、記憶部に記憶させ(ステップS8)、ステップS7で求めた固有の静電容量C1との比較により結露の有無を判断する(ステップS9)。つまり結露検出部16は、同心円筒状電極2の形状および寸法から求めた固有の静電容量C1と、実際の静電容量C2とが一致しているか否かを判断し、一致していなければ(つまり静電容量C1,C2の差の絶対値が所定のしきい値を超えると)、結露の発生を示す結露検出信号を粒径算出部15および暖気運転制御部18に出力する(ステップS10)。   Also, the dew condensation detection unit 16 uses the above equation (5) from the applied voltage V input from the particle size calculation unit 15, the current value is acquired from the current value acquisition unit 12, and the acquired time t. The actual capacitance C2 is calculated and stored in the storage unit (step S8), and the presence or absence of condensation is determined by comparison with the specific capacitance C1 obtained in step S7 (step S9). That is, the dew condensation detection unit 16 determines whether or not the intrinsic capacitance C1 obtained from the shape and size of the concentric cylindrical electrode 2 and the actual capacitance C2 match, and if they do not match. (In other words, when the absolute value of the difference between capacitances C1 and C2 exceeds a predetermined threshold value), a dew condensation detection signal indicating the occurrence of dew condensation is output to particle size calculation unit 15 and warm-up operation control unit 18 (step S10). ).

ここで、粒径算出部15は、結露検出部16から結露検出信号が入力されると、直ちに帯電粒子量の評価を停止し、電圧制御部11により電圧源5の電圧をゼロにするとともに(ステップS15)、図示しない記憶部に評価停止直前の印加電圧を記憶させる。   Here, when the condensation detection signal is input from the condensation detection unit 16, the particle size calculation unit 15 immediately stops the evaluation of the charged particle amount, and the voltage control unit 11 sets the voltage of the voltage source 5 to zero ( Step S15), the applied voltage immediately before the stop of the evaluation is stored in a storage unit (not shown).

また、暖気運転制御部18は、結露検出部16から結露検出信号が入力されると、暖気運転を開始するために、気流制御部17に極性切換信号を出力するとともに、ヒータ7に電源投入信号を出力する(ステップS16)。このとき、気流制御部17では、暖気運転制御部18から入力された極性切換信号に応じて、電圧源6の極性を正から負に切り換え、吸気ファン3による気流発生方向を、帯電粒子量の評価時の気流発生方向と反対方向(つまり吸気ファン3から同心円筒状電極2側へと向かう方向)に切り換える(ステップS17)。また、ヒータ7では、暖気運転制御部18から電源投入信号が入力されると、電源が投入されて発熱し、周囲の空気を暖める(ステップS18)。而して、ヒータ7により吸気ファン3の吸気側の空気が暖められるとともに、ヒータ7で暖められた空気が吸気ファン3に吸気されて、同心円筒状電極2の環状空間2c内に送風されるので、同心円筒状電極2の内側導体2aと外側導体2bとが暖められる(ステップS19)。   When the dew condensation detection signal is input from the dew condensation detection unit 16, the warm air operation control unit 18 outputs a polarity switching signal to the air flow control unit 17 and starts a power on signal to the heater 7 in order to start the warm air operation. Is output (step S16). At this time, the airflow control unit 17 switches the polarity of the voltage source 6 from positive to negative in accordance with the polarity switching signal input from the warming-up operation control unit 18, and changes the direction of airflow generation by the intake fan 3 to the charged particle amount. The direction is switched to the direction opposite to the airflow generation direction at the time of evaluation (that is, the direction from the intake fan 3 toward the concentric cylindrical electrode 2) (step S17). In the heater 7, when a power-on signal is input from the warm-up operation control unit 18, the power is turned on to generate heat and warm the surrounding air (step S18). Thus, the air on the intake side of the intake fan 3 is warmed by the heater 7, and the air heated by the heater 7 is sucked into the intake fan 3 and blown into the annular space 2 c of the concentric cylindrical electrode 2. Therefore, the inner conductor 2a and the outer conductor 2b of the concentric cylindrical electrode 2 are warmed (step S19).

その後、暖気運転の開始時から入力部13で入力された暖気運転時間が経過すると、暖気運転制御部18は暖気運転を停止するために、気流制御部17に極性切換信号を出力するとともに、ヒータ7に電源停止信号を出力し、さらに結露検出部16に暖気終了信号を出力する(ステップS20)。このとき、気流制御部17では、暖気運転制御部18から入力された極性切換信号に応じて、電圧源6の極性を負から正に切り換え、吸気ファン3による気流発生方向を、吸気ファン3より同心円筒状電極2側へ向かう方向から、帯電粒子量の評価時の気流発生方向に切り換える(ステップS21)。また、ヒータ7では、暖気運転制御部18から電源停止信号が入力されると、電源供給が停止され、空気の加熱を終了する(ステップS22)。さらに、結露検出部16は、暖気運転制御部18から暖気終了信号が入力されると、結露検出信号の出力を停止し(ステップS23)、図示しない記憶部に記憶されている評価停止直前の印加電圧を電圧制御部11に出力し(ステップS24)、上述のステップS4〜S9の処理に戻って結露の有無を再度検出する。この時、結露検出部16が再び結露を検出して、結露検出信号を粒径算出部15および暖気運転制御部18に出力すると、暖気運転制御部18により再度ステップS10〜S23の暖気運転の処理が行われる。   Thereafter, when the warm-up operation time input from the input unit 13 has elapsed since the start of the warm-up operation, the warm-up operation control unit 18 outputs a polarity switching signal to the air flow control unit 17 and stops the heater operation in order to stop the warm-up operation. 7 outputs a power stop signal, and further outputs a warm-up end signal to the dew condensation detection unit 16 (step S20). At this time, the airflow control unit 17 switches the polarity of the voltage source 6 from negative to positive according to the polarity switching signal input from the warm-up operation control unit 18, and changes the direction of airflow generation by the intake fan 3 from the intake fan 3. The direction is changed from the direction toward the concentric cylindrical electrode 2 to the direction of air flow generation when the charged particle amount is evaluated (step S21). Further, in the heater 7, when the power supply stop signal is input from the warm-up operation control unit 18, the power supply is stopped and the heating of the air is finished (step S22). Furthermore, when the warming-up end signal is input from the warming-up operation control unit 18, the dew condensation detection unit 16 stops outputting the dew condensation detection signal (step S23), and the application immediately before the evaluation stop stored in the storage unit (not shown). The voltage is output to the voltage controller 11 (step S24), and the process returns to the above-described steps S4 to S9 to detect the presence or absence of condensation again. At this time, when the dew condensation detection unit 16 detects dew condensation again and outputs a dew condensation detection signal to the particle size calculation unit 15 and the warm air operation control unit 18, the warm air operation control unit 18 again performs the process of the warm air operation in steps S10 to S23. Is done.

一方、ステップS9の判定で結露検出部16が結露無しと判断し、結露の検出信号が粒径算出部15に入力されなくなると、粒径算出部15は、電流値取得部12から入力された電流値isから、上述の式(3)を用いて最小粒径以下の帯電粒子の数を算出し、測定対象の帯電粒子の粒径および個数を記憶部(図示せず)に記憶させる(ステップS11)。このとき、粒径算出部15では測定対象の帯電粒子の粒径および個数を記憶部に記憶させるとともに、プリンタなどの出力装置(図示せず)に出力させても良い。   On the other hand, when the condensation detection unit 16 determines that there is no condensation in the determination of step S9, and the condensation detection signal is not input to the particle size calculation unit 15, the particle size calculation unit 15 is input from the current value acquisition unit 12. From the current value is, the number of charged particles having a particle size equal to or smaller than the minimum particle size is calculated using the above-described equation (3), and the particle size and the number of charged particles to be measured are stored in a storage unit (not shown) (step) S11). At this time, the particle size calculation unit 15 may store the particle size and the number of charged particles to be measured in a storage unit, and may output them to an output device (not shown) such as a printer.

測定対象の帯電粒子の粒径と個数とを記憶部に記憶させると、粒径算出部15では全ての測定範囲について測定を終了したか否かを判断し(ステップS12)、測定が終わっていなければ、粒径を所定のスイープ幅だけ増加させた場合の印加電圧の電圧値及び極性を電圧制御部11および結露検出部16に出力した後(ステップS13)、上述のステップS4〜S11の処理を繰り返す。尚、0.6〜2nmの粒径範囲ではスイープ幅を0.2nmとしているので、最小粒径(0.6nm)の次は粒径が0.8nmの時の印加電圧の電圧値を出力する。   When the particle size and the number of charged particles to be measured are stored in the storage unit, the particle size calculation unit 15 determines whether or not the measurement has been completed for all measurement ranges (step S12), and the measurement must be completed. For example, after outputting the voltage value and polarity of the applied voltage when the particle size is increased by a predetermined sweep width to the voltage control unit 11 and the dew condensation detection unit 16 (step S13), the processing of the above steps S4 to S11 is performed. repeat. Since the sweep width is 0.2 nm in the particle size range of 0.6 to 2 nm, the voltage value of the applied voltage when the particle size is 0.8 nm is output next to the minimum particle size (0.6 nm). .

本装置では上述の処理を行い、粒径を0.6nmから28nmまで所定のスイープ幅ずつスイープさせる毎に、各々の粒径の設定値で上記の処理S4〜S13を繰り返すことによって粒子数を算出して、粒径分布(粒径に対する個数の分布)を求めており、ステップS12において全ての測定範囲で測定を終了したと判断されると、粒径算出部15は粒径分布の算出結果を記憶部に記憶させるとともに、出力装置に測定結果を出力する(ステップS14)。   In this device, the number of particles is calculated by repeating the above-described processing S4 to S13 at each particle size setting value every time the particle size is swept by a predetermined sweep width from 0.6 nm to 28 nm. Then, the particle size distribution (the distribution of the number with respect to the particle size) is obtained, and if it is determined in step S12 that the measurement has been completed in the entire measurement range, the particle size calculation unit 15 obtains the calculation result of the particle size distribution. While memorize | storing in a memory | storage part, a measurement result is output to an output device (step S14).

以上説明したように本実施形態の帯電粒子量評価装置1では、結露検出部16が内側導体2aおよび外側導体2bの結露を検出すると、暖気運転制御部18が暖気運転を行い、ヒータ7で暖めた空気を吸気ファン3により吸気して、同心円筒状電極2の環状空間2c内に送風することで、内側導体2aおよび外側導体2bの結露を取り除いており、暖気運転の結果、結露が検出されなくなると、粒径算出部15により帯電粒子量の評価を行わせているので、より高い精度で帯電粒子量の評価を行うことができる。また結露検出部16で結露が検出されなくなるまで、暖気運転制御部18が暖気運転時間だけ暖気運転を行う動作を繰り返しているので、できるだけ短い時間で暖気運転から復帰して、帯電粒子量の評価を行えるようになっている。   As described above, in the charged particle amount evaluation apparatus 1 according to the present embodiment, when the dew condensation detection unit 16 detects dew condensation on the inner conductor 2a and the outer conductor 2b, the warming operation control unit 18 performs the warming operation and warms the heater 7. The intake air is sucked by the intake fan 3 and blown into the annular space 2c of the concentric cylindrical electrode 2 to remove condensation on the inner conductor 2a and the outer conductor 2b. As a result of the warm-up operation, condensation is detected. When it disappears, the charged particle amount is evaluated by the particle size calculation unit 15, so that the charged particle amount can be evaluated with higher accuracy. Further, until the dew condensation detection unit 16 detects no dew condensation, the warm-up operation control unit 18 repeats the operation of performing the warm-up operation for the warm-up operation time. Therefore, the warm-up operation is resumed in as short a time as possible to evaluate the charged particle amount. Can be done.

(実施形態3)
本発明の実施形態3について以下に説明する。実施形態2で説明した帯電粒子量評価装置1では、吸気ファン3の風量を一定風量としているが、本実施形態では、気流制御部17に吸気ファン3の風量を変化させる機能を持たせ、暖気運転制御部18が、暖気運転中に所定時間だけ、気流制御部17を用いて吸気ファン3の送風量を帯電粒子量の評価時の送風量よりも大きい所定流量に増加させている。尚、帯電粒子量評価装置1の構成は実施形態2と同様であるので、共通する構成要素には同一の符号を付して、その説明は省略する。
(Embodiment 3)
Embodiment 3 of the present invention will be described below. In the charged particle amount evaluation apparatus 1 described in the second embodiment, the air volume of the intake fan 3 is set to a constant air volume. However, in this embodiment, the air flow control unit 17 is provided with a function of changing the air volume of the intake fan 3 so that warm air is supplied. The operation control unit 18 uses the airflow control unit 17 to increase the air flow rate of the intake fan 3 to a predetermined flow rate larger than the air flow rate at the time of evaluating the charged particle amount for a predetermined time during the warm-up operation. In addition, since the structure of the charged particle amount evaluation apparatus 1 is the same as that of Embodiment 2, the same code | symbol is attached | subjected to a common component and the description is abbreviate | omitted.

気流制御部17では、暖気運転制御部18からの入力信号の極性および電圧値に応じて、電圧源6の極性および電圧値を変化させることによって、吸気ファン3による気流発生方向や送風量を変化させている。   In the airflow control unit 17, the airflow generation direction and the amount of air blown by the intake fan 3 are changed by changing the polarity and voltage value of the voltage source 6 according to the polarity and voltage value of the input signal from the warm-up operation control unit 18. I am letting.

また暖気運転制御部18は、実施形態2で説明した機能に加えて、暖気運転中に所定時間だけ、吸気ファン3の送風量を帯電粒子量の評価時の送風量よりも大きい所定流量に増加させる信号を気流制御部17に出力する機能を有している。   In addition to the function described in the second embodiment, the warm-up operation control unit 18 increases the air flow rate of the intake fan 3 to a predetermined flow rate larger than the air flow rate at the time of evaluating the charged particle amount for a predetermined time during the warm-up operation. The function to output the signal to be sent to the airflow control unit 17 is provided.

この帯電粒子量評価装置1の動作は、暖気運転時以外は実施形態2と同様であるので、その説明は省略し、暖気運転時の動作について図4を参照して以下に説明する。   Since the operation of the charged particle amount evaluation apparatus 1 is the same as that of the second embodiment except during the warming-up operation, the description thereof will be omitted, and the operation during the warming-up operation will be described below with reference to FIG.

結露検出部16が、ステップS9の判定の結果結露ありと判断すると、結露の発生を示す結露検出信号を粒径算出部15および暖気運転制御部18に出力する(ステップS10)。   When the dew condensation detection unit 16 determines that there is dew condensation as a result of the determination in step S9, a dew condensation detection signal indicating the occurrence of dew condensation is output to the particle size calculation unit 15 and the warm-up operation control unit 18 (step S10).

ここで、粒径算出部15は、結露検出部16から結露検出信号が入力されると、直ちに帯電粒子量の評価を停止し、電圧制御部11により電圧源5の電圧をゼロにするとともに(ステップS15)、図示しない記憶部に評価停止直前の印加電圧を記憶させる。   Here, when the condensation detection signal is input from the condensation detection unit 16, the particle size calculation unit 15 immediately stops the evaluation of the charged particle amount, and the voltage control unit 11 sets the voltage of the voltage source 5 to zero ( Step S15), the applied voltage immediately before the stop of the evaluation is stored in a storage unit (not shown).

また、暖気運転制御部18は、結露検出部16から結露検出信号が入力されると、暖気運転を開始するために、気流制御部17に極性切換信号を出力するとともに、ヒータ7に電源投入信号を出力する(ステップS16)。このとき、気流制御部17では、暖気運転制御部18から入力された極性切換信号に応じて、電圧源6の極性を正から負に切り換え、吸気ファン3による気流発生方向を、帯電粒子量の評価時の気流発生方向と反対方向に切り換える(ステップS17)。また、ヒータ7では、暖気運転制御部18から電源投入信号が入力されると、電源が投入されて発熱し、周囲の空気を暖める(ステップS18)。而して、ヒータ7により吸気ファン3の吸気側の空気が暖められるとともに、ヒータ7で暖められた空気が吸気ファン3に吸気されて、同心円筒状電極2の環状空間2c内に送風されるので、同心円筒状電極2の内側導体2aと外側導体2bとが暖められる(ステップS19)。   When the dew condensation detection signal is input from the dew condensation detection unit 16, the warm air operation control unit 18 outputs a polarity switching signal to the air flow control unit 17 and starts a power on signal to the heater 7 in order to start the warm air operation. Is output (step S16). At this time, the airflow control unit 17 switches the polarity of the voltage source 6 from positive to negative in accordance with the polarity switching signal input from the warming-up operation control unit 18, and changes the direction of airflow generation by the intake fan 3 to the charged particle amount. It switches to the direction opposite to the airflow generation direction at the time of evaluation (step S17). In the heater 7, when a power-on signal is input from the warm-up operation control unit 18, the power is turned on to generate heat and warm the surrounding air (step S18). Thus, the air on the intake side of the intake fan 3 is warmed by the heater 7, and the air heated by the heater 7 is sucked into the intake fan 3 and blown into the annular space 2 c of the concentric cylindrical electrode 2. Therefore, the inner conductor 2a and the outer conductor 2b of the concentric cylindrical electrode 2 are warmed (step S19).

ここで、暖気運転制御部18は、入力部13により入力された暖気運転時間のうち所定時間(例えば暖気運転時間の20%の時間)だけ、吸気ファン3の送風量(流量)を帯電粒子量評価時の送風量よりも大きい所定流量(例えば帯電粒子量評価時の50%増の流量)に増加させる制御信号を気流制御部17に出力する。そして気流制御部17では、暖気運転制御部18から入力された制御信号に応じて、所定時間だけ吸気ファン3の流量を所定流量に増加させるように電圧源6の印加電圧を制御する。そして、吸気ファン3は電圧源6の印加電圧に応じて流量を変化させており、暖気運転中に所定時間だけ送風量を所定流量に増加させ、所定時間の経過後は帯電粒子量評価時の流量に戻している。   Here, the warming-up operation control unit 18 sets the air flow rate (flow rate) of the intake fan 3 for the predetermined amount of time (for example, 20% of the warming-up operation time) in the warming-up operation time input by the input unit 13. A control signal for increasing the flow rate to a predetermined flow rate (for example, a flow rate increased by 50% at the time of charged particle amount evaluation) larger than the air flow rate at the time of evaluation is output to the airflow control unit 17. The airflow control unit 17 controls the applied voltage of the voltage source 6 so as to increase the flow rate of the intake fan 3 to a predetermined flow rate for a predetermined time according to the control signal input from the warm-up operation control unit 18. The intake fan 3 changes the flow rate according to the applied voltage of the voltage source 6 and increases the air flow rate to a predetermined flow rate for a predetermined time during the warming-up operation. Return to flow rate.

その後、暖気運転の開始時から入力部13で入力された暖気運転時間が経過すると、暖気運転制御部18は暖気運転を停止するために、気流制御部17に極性切換信号を出力するとともに、ヒータ7に電源停止信号を出力し、さらに結露検出部16に暖気終了信号を出力する(ステップS20)。このとき、気流制御部17では、暖気運転制御部18から入力された極性切換信号に応じて、電圧源6の極性を負から正に切り換え、吸気ファン3による気流発生方向を、吸気ファン3より同心円筒状電極2側へ向かう方向から、帯電粒子量の評価時の気流発生方向に切り換える(ステップS21)。また、ヒータ7では、暖気運転制御部18から電源停止信号が入力されると、電源供給が停止され、空気の加熱を終了する(ステップS22)。さらに、結露検出部16は、暖気運転制御部18から暖気終了信号が入力されると、結露検出信号の出力を停止し(ステップS23)、図示しない記憶部に記憶されている評価停止直前の印加電圧を電圧制御部11に出力し(ステップS24)、上述のステップS4〜S9の処理に戻って結露の有無を再度検出する。この時、結露検出部16が再び結露を検出して、結露検出信号を粒径算出部15および暖気運転制御部18に出力すると、暖気運転制御部18により再度ステップS10〜S23の暖気運転の処理が行われる。   Thereafter, when the warm-up operation time input from the input unit 13 has elapsed since the start of the warm-up operation, the warm-up operation control unit 18 outputs a polarity switching signal to the air flow control unit 17 and stops the heater operation in order to stop the warm-up operation. 7 outputs a power stop signal, and further outputs a warm-up end signal to the dew condensation detection unit 16 (step S20). At this time, the airflow control unit 17 switches the polarity of the voltage source 6 from negative to positive according to the polarity switching signal input from the warm-up operation control unit 18, and changes the direction of airflow generation by the intake fan 3 from the intake fan 3. The direction is changed from the direction toward the concentric cylindrical electrode 2 to the direction of air flow generation when the charged particle amount is evaluated (step S21). Further, in the heater 7, when the power supply stop signal is input from the warm-up operation control unit 18, the power supply is stopped and the heating of the air is finished (step S22). Furthermore, when the warming-up end signal is input from the warming-up operation control unit 18, the dew condensation detection unit 16 stops outputting the dew condensation detection signal (step S23), and the application immediately before the evaluation stop stored in the storage unit (not shown). The voltage is output to the voltage controller 11 (step S24), and the process returns to the above-described steps S4 to S9 to detect the presence or absence of condensation again. At this time, when the dew condensation detection unit 16 detects dew condensation again and outputs a dew condensation detection signal to the particle size calculation unit 15 and the warm air operation control unit 18, the warm air operation control unit 18 again performs the process of the warm air operation in steps S10 to S23. Is done.

このように本実施形態では、気流制御部17に、吸気ファン3の送風量を変化させる機能を追加し、暖気運転制御部18が、暖気運転中に所定時間だけ、気流制御部17を用いて吸気ファン3の送風量を帯電粒子量の評価時の送風量よりも大きい所定流量に増加させているので、温風を送風することで結露を取り除くとともに、帯電粒子量の評価時よりも流量の大きい層流を送風することで、内側導体2aおよび外側導体2bに付着した塵や埃を吹き飛ばすことができ、より高い精度で帯電粒子量の評価を行うことができる。   As described above, in the present embodiment, a function of changing the air flow rate of the intake fan 3 is added to the air flow control unit 17, and the warm air operation control unit 18 uses the air flow control unit 17 for a predetermined time during the warm air operation. Since the air blowing amount of the intake fan 3 is increased to a predetermined flow rate larger than the air blowing amount at the time of evaluating the charged particle amount, dew condensation is removed by blowing hot air, and the flow rate is higher than at the time of evaluating the charged particle amount. By blowing a large laminar flow, dust and dirt attached to the inner conductor 2a and the outer conductor 2b can be blown off, and the amount of charged particles can be evaluated with higher accuracy.

なお、本発明の精神と範囲に反することなしに、広範に異なる実施形態を構成することができることは明白なので、この発明は、特定の実施形態に制約されるものではない。   It should be noted that a wide variety of different embodiments can be configured without departing from the spirit and scope of the present invention, and the present invention is not limited to a specific embodiment.

実施形態1の帯電粒子量評価装置の概略構成図である。1 is a schematic configuration diagram of a charged particle amount evaluation apparatus according to Embodiment 1. FIG. 同上の動作を説明するフロー図である。It is a flowchart explaining operation | movement same as the above. 実施形態2の帯電粒子量評価装置の概略構成図である。6 is a schematic configuration diagram of a charged particle amount evaluation apparatus according to Embodiment 2. FIG. 同上の動作を説明するフロー図である。It is a flowchart explaining operation | movement same as the above. 従来の帯電粒子量評価装置の概略構成図である。It is a schematic block diagram of the conventional charged particle amount evaluation apparatus.

符号の説明Explanation of symbols

1 帯電粒子量評価装置
2 同心円筒状電極
2a 内側導体
2b 外側導体
3 吸気ファン(気流発生手段)
4 電流計(電流測定手段)
5 電圧源(電圧印加手段)
10 コントローラ
14 演算処理部
15 粒径算出部(帯電粒子量評価手段)
16 結露検出部(結露検出手段)
DESCRIPTION OF SYMBOLS 1 Charged particle amount evaluation apparatus 2 Concentric cylindrical electrode 2a Inner conductor 2b Outer conductor 3 Intake fan (air flow generation means)
4 Ammeter (Current measurement means)
5 Voltage source (voltage application means)
10 controller 14 arithmetic processing unit 15 particle size calculation unit (charged particle amount evaluation means)
16 Condensation detection unit (condensation detection means)

Claims (5)

円柱状の内側導体および内側導体よりも径の大きい円筒状の外側導体を同心に配置して構成された同心円筒状電極と、内側導体と外側導体との間の空間に同心円筒状電極の軸方向に層流を発生させる気流発生手段と、内側導体と外側導体との間に電圧を印加する電圧印加手段と、内側導体と外側導体との間に流れる電流を測定する電流測定手段と、層流の流路の壁面をなす内側導体および外側導体に発生する結露の有無を検出する結露検出手段と、当該結露検出手段により結露無しと検出された場合に、同心円筒状電極の形状および寸法と気流発生手段による層流の流量と電圧印加手段による印加電圧と電流測定手段の測定結果とに基づいて帯電粒子量を評価する帯電粒子量評価手段とを具備したことを特徴とする帯電粒子量評価装置。   A concentric cylindrical electrode configured by concentrically arranging a cylindrical inner conductor and a cylindrical outer conductor having a diameter larger than that of the inner conductor, and an axis of the concentric cylindrical electrode in a space between the inner conductor and the outer conductor. An airflow generating means for generating a laminar flow in the direction, a voltage applying means for applying a voltage between the inner conductor and the outer conductor, a current measuring means for measuring a current flowing between the inner conductor and the outer conductor, and a layer Condensation detection means for detecting the presence or absence of condensation occurring on the inner conductor and outer conductor forming the wall of the flow path, and the shape and dimensions of the concentric cylindrical electrode when no condensation is detected by the condensation detection means. Charged particle amount evaluation means comprising charged particle amount evaluation means for evaluating the amount of charged particles based on the flow rate of laminar flow by the airflow generation means, the applied voltage by the voltage application means, and the measurement result of the current measurement means apparatus. 前記層流の流路の途中であって帯電粒子量の評価時の気流発生方向において前記同心円筒状電極よりも下流側に配置されて空気を加熱するヒータと、前記気流発生手段による気流発生方向の正逆を切り換える送風方向切換手段と、前記結露検出手段が結露を検出した場合に、ヒータで空気を加熱させるとともに送風方向切換手段を用いて気流発生手段による気流発生方向を帯電粒子量の評価時と反対方向に切り換える暖気運転を行う暖気運転制御手段とを設けたことを特徴とする請求項1記載の帯電粒子量評価装置。   A heater arranged in the middle of the laminar flow path and downstream of the concentric cylindrical electrode in the air flow generation direction when evaluating the amount of charged particles, and the air flow generation direction by the air flow generation means When the dew condensation detection means detects dew condensation, and when the dew condensation detection means detects dew condensation, the air is heated by a heater and the air flow generation direction by the air flow generation means is evaluated by using the air flow direction switching means. 2. The charged particle amount evaluation apparatus according to claim 1, further comprising a warming-up operation control unit that performs a warming-up operation that switches in a direction opposite to the time. 前記暖気運転制御手段は、前記結露検出手段により結露無しと検出されるまで暖気運転を継続することを特徴とする請求項2記載の帯電粒子量評価装置。   3. The charged particle amount evaluation apparatus according to claim 2, wherein the warm-up operation control unit continues the warm-up operation until the dew condensation detection unit detects that there is no dew condensation. 前記気流発生手段の送風量を変化させる気流制御手段を設け、前記暖気運転制御手段は、暖気運転中に所定時間だけ、気流制御手段を用いて気流発生手段の送風量を帯電粒子量の評価時の送風量よりも大きい所定流量に増加させることを特徴とする請求項2又は3記載の帯電粒子量評価装置。   Airflow control means for changing the air flow rate of the airflow generation means is provided, and the warm-up operation control means uses the airflow control means for a predetermined time during the warm-up operation to evaluate the air flow rate of the airflow generation means when evaluating the charged particle amount. The charged particle amount evaluation apparatus according to claim 2, wherein the flow rate is increased to a predetermined flow rate larger than the air flow rate. 前記結露検出手段は、前記電流測定手段の測定結果より求めた前記同心円筒状電極に蓄えられる電荷量および前記電圧印加手段による印加電圧から求めた静電容量と、前記同心円筒状電極の形状および寸法から求めた静電容量とを比較し、両者の差の絶対値が所定のしきい値を超えることから結露の発生を検出することを特徴とする請求項1乃至4の何れか1つに記載の帯電粒子量評価装置。   The dew condensation detection means includes an amount of charge stored in the concentric cylindrical electrode obtained from the measurement result of the current measurement means and a capacitance obtained from an applied voltage by the voltage application means, a shape of the concentric cylindrical electrode, and The occurrence of dew condensation is detected because the absolute value of the difference between the two is compared with a capacitance obtained from the dimensions and exceeds a predetermined threshold value. The charged particle amount evaluation apparatus described.
JP2006285360A 2006-10-19 2006-10-19 Charged particle amount evaluation system Withdrawn JP2008102037A (en)

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Cited By (2)

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WO2013183652A1 (en) * 2012-06-06 2013-12-12 株式会社島津製作所 Fine particle classification measurement device, sample creation device with uniform particle concentration, and nanoparticle film forming device
WO2019039072A1 (en) * 2017-08-22 2019-02-28 日本碍子株式会社 Microparticle count detector

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013183652A1 (en) * 2012-06-06 2013-12-12 株式会社島津製作所 Fine particle classification measurement device, sample creation device with uniform particle concentration, and nanoparticle film forming device
CN104380078A (en) * 2012-06-06 2015-02-25 株式会社岛津制作所 Particle classification measurement device, sample preparation device with uniform particle concentration distribution, and nanoparticle film formation device
JPWO2013183652A1 (en) * 2012-06-06 2016-02-01 株式会社島津製作所 Fine particle classification measurement device, sample preparation device with uniform particle concentration distribution, and nanoparticle film formation device
WO2019039072A1 (en) * 2017-08-22 2019-02-28 日本碍子株式会社 Microparticle count detector
CN111033217A (en) * 2017-08-22 2020-04-17 日本碍子株式会社 Particle number detector

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