JP2008101826A - Recycling method of electric furnace dust - Google Patents
Recycling method of electric furnace dust Download PDFInfo
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- JP2008101826A JP2008101826A JP2006284018A JP2006284018A JP2008101826A JP 2008101826 A JP2008101826 A JP 2008101826A JP 2006284018 A JP2006284018 A JP 2006284018A JP 2006284018 A JP2006284018 A JP 2006284018A JP 2008101826 A JP2008101826 A JP 2008101826A
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- 239000000428 dust Substances 0.000 title claims abstract description 122
- 238000000034 method Methods 0.000 title claims abstract description 29
- 238000004064 recycling Methods 0.000 title claims abstract description 24
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000011701 zinc Substances 0.000 claims abstract description 12
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 12
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- 229910052742 iron Inorganic materials 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 238000001914 filtration Methods 0.000 abstract description 3
- HGUFODBRKLSHSI-UHFFFAOYSA-N 2,3,7,8-tetrachloro-dibenzo-p-dioxin Chemical compound O1C2=CC(Cl)=C(Cl)C=C2OC2=C1C=C(Cl)C(Cl)=C2 HGUFODBRKLSHSI-UHFFFAOYSA-N 0.000 abstract 1
- 150000002013 dioxins Chemical class 0.000 description 7
- 238000011084 recovery Methods 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 150000002896 organic halogen compounds Chemical class 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000002906 medical waste Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Images
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/25—Process efficiency
Landscapes
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
- Furnace Details (AREA)
- Processing Of Solid Wastes (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
- Vertical, Hearth, Or Arc Furnaces (AREA)
Abstract
Description
本発明は、電気炉ダストのリサイクル方法に関し、特に、電気炉から排出される排ガスを集塵機で濾過し、該集塵機から排出されるダストを分級器によって酸化鉄等を含む高密度のダストと亜鉛等を含む低密度のダストとに分級して、前記酸化鉄等を含む高密度のダストを電気炉に戻す電気炉ダストのリサイクル方法の改良に関するものである。 The present invention relates to a method for recycling electric furnace dust, and in particular, exhaust gas discharged from the electric furnace is filtered by a dust collector, and the dust discharged from the dust collector is collected with high-density dust including iron oxide and the like by a classifier. It is related with the improvement of the recycling method of the electric furnace dust which classify | categorizes into the low density dust containing and returns the high density dust containing the said iron oxide etc. to an electric furnace.
従来、電気炉から排出される排ガスに含まれる電気炉ダストのリサイクル方法として、例えば、図3に示すフローによる方法が採用されている。
この従来の電気炉ダストのリサイクル方法は、電気炉Xから排出されるダストを含む排ガスを吸引ファンFによって、ガスクーラ(図示省略)を介して集塵機S(例えば、バグ式集塵機等)に導入し、集塵機Sから排出されるダストを分級器Bに搬送し、分級器Bによって酸化鉄等を含む高密度のダストと亜鉛等を含む低密度のダストとに分級し、酸化鉄等を含む高密度のダストを、造粒機Pでペレット化し、適宜手段、例えば、コンベアによって電気炉Xに戻すようにしている。
Conventionally, as a method for recycling electric furnace dust contained in exhaust gas discharged from an electric furnace, for example, a method based on the flow shown in FIG. 3 has been adopted.
In this conventional electric furnace dust recycling method, exhaust gas containing dust discharged from the electric furnace X is introduced into a dust collector S (for example, a bag type dust collector) by a suction fan F via a gas cooler (not shown), The dust discharged from the dust collector S is transported to the classifier B, and is classified into a high density dust containing iron oxide and the like and a low density dust containing zinc etc. by the classifier B, and a high density containing iron oxide and the like. The dust is pelletized by the granulator P and returned to the electric furnace X by an appropriate means such as a conveyor.
一方、亜鉛等を含む低密度のダストは、サイロCに送られ、必要に応じて造粒機(図示省略)によって造粒された後、廃棄されたり、回収業者に引き渡され亜鉛の回収がなされている(例えば、特許文献1参照)。 On the other hand, low density dust containing zinc or the like is sent to silo C, and is granulated by a granulator (not shown) as needed, and then discarded or handed over to a recovery company to collect zinc. (For example, refer to Patent Document 1).
ところで、電気炉への挿入物であるAプレス(廃自動車の二次解体後のガラ)、廃自動車のシュレッダダスト、医療廃棄物等には、ポリ塩化ビニル等の塩素を含有する樹脂類が含まれている場合が多く、これらの樹脂類から発生するダイオキシン類が集塵機Sから排出されるダストに含有されている。
そして、このようなダイオキシン類を含有しているダストを、そのまま廃棄したり、回収業者に引き渡すことは、環境に対しても、また、衛生上も好ましくない。
また、集塵機Sから排出されるダストは、含水率が高く、分級器に付着しやすく、分級を効率よく行うことができないという問題があった。
And it is not preferable from the viewpoint of the environment and hygiene that the dust containing such dioxins is discarded as it is or is handed over to a recovery company.
Moreover, the dust discharged | emitted from the dust collector S had the problem that moisture content was high, and it was easy to adhere to a classifier, and classification could not be performed efficiently.
本発明は、上記従来の電気炉ダストのリサイクル方法の有する問題点に鑑み、電気炉から排出される排ガスを集塵機で濾過した際に生じるダストに含まれるダイオキシン類を無害化するとともに、分級器による分級を効率よく行うことができるようにした電気炉ダストのリサイクル方法を提供することを目的とする。 In view of the problems of the conventional electric furnace dust recycling method, the present invention renders the dioxins contained in the dust generated when the exhaust gas discharged from the electric furnace is filtered by a dust collector, and uses a classifier. An object of the present invention is to provide a method of recycling electric furnace dust that enables efficient classification.
上記目的を達成するため、本発明の電気炉ダストのリサイクル方法は、電気炉から排出される排ガスを集塵機で濾過し、該集塵機から排出されるダストを分級器によって酸化鉄等を含む高密度のダストと亜鉛等を含む低密度のダストとに分級して、前記酸化鉄等を含む高密度のダストを電気炉に戻す電気炉ダストのリサイクル方法であって、前記集塵機から排出されるダストをマイクロ波処理装置によって加熱処理し、その後、分級器に送ることを特徴とする。 In order to achieve the above object, the method for recycling electric furnace dust according to the present invention is a method of filtering exhaust gas discharged from an electric furnace with a dust collector, and separating the dust discharged from the dust collector with iron oxide or the like with a classifier. An electric furnace dust recycling method for classifying dust into low-density dust containing zinc and the like and returning the high-density dust containing iron oxide and the like to the electric furnace, wherein the dust discharged from the dust collector is micro It heat-processes with a wave processing apparatus, It sends to a classifier after that, It is characterized by the above-mentioned.
本発明の電気炉ダストのリサイクル方法によれば、集塵機から排出されるダストをマイクロ波処理装置によって加熱処理し、その後、分級器に送るようにすることにより、分級器に送る前にマイクロ波によってダストを加熱し、ダイオキシン類を無害化することができるとともに、ダストを乾燥させることができ、ダストの分級器への付着をできるだけ少なくして、無害化されたダストを分級器で効率よく分級することができる。 According to the electric furnace dust recycling method of the present invention, the dust discharged from the dust collector is heated by the microwave processing device and then sent to the classifier, so that the dust is sent to the microwave before being sent to the classifier. The dust can be heated to detoxify the dioxins, the dust can be dried, and the dust can be attached to the classifier as much as possible, and the detoxified dust is efficiently classified by the classifier. be able to.
以下、本発明の電気炉ダストのリサイクル方法の実施の形態を、図面に基づいて説明する。 Embodiments of an electric furnace dust recycling method of the present invention will be described below with reference to the drawings.
図1に、本発明の電気炉ダストのリサイクル方法の一実施例を示す。
この電気炉ダストのリサイクル方法は、電気炉Xから排出されるダストを含む排ガスを、吸引ファンFによって、集塵機S(例えば、バグ式集塵機等)に導入し、集塵機Sから排出されるダストをマイクロ波処理装置1に搬送し、マイクロ波処理装置1内でダストを加熱処理した後、分級器Bに搬送し、分級器によって酸化鉄等を含む高密度のダストと亜鉛等を含む低密度のダストとに分級して、酸化鉄等を含む高密度のダストを、適宜手段、例えば、空気輸送装置Aによって電気炉Xに戻すようにしている。
FIG. 1 shows an embodiment of the electric furnace dust recycling method of the present invention.
In this electric furnace dust recycling method, exhaust gas containing dust discharged from the electric furnace X is introduced into the dust collector S (for example, a bag-type dust collector) by the suction fan F, and the dust discharged from the dust collector S is micronized. After being transported to the wave treatment device 1 and heated in the microwave treatment device 1, the dust is transported to the classifier B, and the classifier uses a high density dust containing iron oxide and the like and a low density dust containing zinc etc. The high-density dust containing iron oxide or the like is returned to the electric furnace X by appropriate means, for example, the air transport device A.
この電気炉ダストのリサイクル方法に使用するマイクロ波処理装置は、本出願人が先に特願2005−353936号で提案した有機ハロゲン化合物等の有害物質を含有する固体の処理装置に使用しているマイクロ波処理装置を利用することができる。 The microwave processing apparatus used in this electric furnace dust recycling method is used in a solid processing apparatus containing harmful substances such as organic halogen compounds previously proposed by the present applicant in Japanese Patent Application No. 2005-353936. A microwave processing device can be used.
このマイクロ波処理装置1は、有機ハロゲン化合物等の有害物質を含有するダストを導入する筐体2と、該筐体2内に導入したダストにマイクロ波を照射するマイクロ波照射機構3とを備えるようにしている。
集塵機から排出されるダストは、搬送装置(図示省略)によって、筐体2上部に配設した導入口2aを介し、筐体2内に搬送される。
そして、筐体2の適所に配設したマイクロ波照射機構3(図例では上面1箇所に配設した例を示すが、上面及び側面に複数箇所配設するようにすることもできる。)からマイクロ波を照射し、ダストに含有しているダイオキシン類等の有害物質の分解処理を行う。
その後、筐体2の下部に配設した排出口2bを介し、搬送装置(図示省略)によって分級器Bに搬送するようにしている。
The microwave processing apparatus 1 includes a
The dust discharged from the dust collector is transported into the
And from the microwave irradiation mechanism 3 (in the example shown in the figure, an example where it is disposed at one place on the upper surface is shown), a plurality of places can be disposed on the upper surface and the side surface. Irradiate microwaves to decompose harmful substances such as dioxins contained in dust.
Then, it conveys to the classifier B by the conveying apparatus (illustration omitted) through the
分級器Bは、ダストを、酸化鉄等を含む高密度のダストと亜鉛等を含む低密度のダストとに分級できるものであれば、方式や機構は限定されるものではないが、例えば、公知のサイクロン式分離装置を好適に用いることができる。 As long as the classifier B can classify the dust into a high-density dust containing iron oxide or the like and a low-density dust containing zinc or the like, the method and mechanism are not limited. The cyclone type separation device can be suitably used.
この電気炉ダストのリサイクル方法は、分級器Bに送る前工程で、集塵機Sから排出されるダストがマイクロ波処理装置1によって加熱されるが、ダストは水分を含んでいるからマイクロ波の照射による加熱効果が高く、また、加熱によって水分が蒸発し、ダストは加熱による無害化及び乾燥処理がなされる。 In this electric furnace dust recycling method, the dust discharged from the dust collector S is heated by the microwave processing device 1 in the previous process to be sent to the classifier B. However, since the dust contains moisture, the dust is irradiated by microwave irradiation. Heating effect is high, moisture is evaporated by heating, and dust is detoxified and dried by heating.
そして、無害化と乾燥処理がなされたダストは、分級器Bに送られて酸化鉄等を含む高密度のダストと亜鉛等を含む低密度のダストとに効率よく分級される。 The detoxified and dried dust is sent to the classifier B and efficiently classified into a high density dust containing iron oxide and the like and a low density dust containing zinc and the like.
その後、酸化鉄等を含む高密度のダストは、適宜手段、例えば、空気輸送装置A、コンベア(図示省略)等の搬送装置によって電気炉Xに戻され、溶融処理がなされる。 Thereafter, the high-density dust containing iron oxide or the like is returned to the electric furnace X by an appropriate means, for example, a conveying device such as an air transport device A or a conveyor (not shown), and is melted.
一方、亜鉛等を含む低密度のダストは、サイロCに送られ、必要に応じて造粒機Pによって造粒された後、廃棄されたり、回収業者に引き渡され亜鉛の回収がなされる。
そして、この亜鉛等を含む低密度のダストは、ダイオキシン類を含有していないため、そのまま廃棄したり、回収業者に引き渡しても、環境に対しても、また、衛生上も問題はない。
On the other hand, low-density dust containing zinc or the like is sent to silo C, granulated by a granulator P as necessary, and then discarded or handed over to a recovery company for recovery of zinc.
And since the low density dust containing this zinc etc. does not contain dioxins, even if it is discarded as it is, or it is handed over to a recovery company, there is no problem in terms of the environment and hygiene.
なお、本実施例でリサイクルされるダストには、集塵機Sから排出されるダストにとどまらず、電気炉Xから集塵機Sまでの経路から排出されるダスト、例えば、ダクト内に堆積し、ダクトを清掃した際に発生するダスト、ガスクーラ内に堆積し、その下方に配設したフラップダンパ等を介して排出されるダスト等も含まれ、集塵機Sから排出されるダストと同様に処理がなされる。 The dust recycled in the present embodiment is not limited to dust discharged from the dust collector S, but dust discharged from the path from the electric furnace X to the dust collector S, for example, accumulated in the duct and cleaning the duct. The dust generated at the time, the dust accumulated in the gas cooler and discharged through a flap damper or the like disposed below the dust is included, and the same processing as the dust discharged from the dust collector S is performed.
以上、本発明の電気炉ダストのリサイクル方法について、その実施例に基づいて説明したが、本発明は上記実施例に記載した構成に限定されるものではなく、その趣旨を逸脱しない範囲において適宜その構成を変更することができるものである。 As mentioned above, although the recycling method of the electric furnace dust of this invention was demonstrated based on the Example, this invention is not limited to the structure described in the said Example, In the range which does not deviate from the meaning, that The configuration can be changed.
本発明の電気炉ダストのリサイクル方法は、電気炉から排出される排ガスを集塵機で濾過した際に生じるダストに含まれるダイオキシン類を無害化するとともに、分級器による分級を効率よく行うことができることから、一般の電気炉設備におけるダストのリサイクル方法に好適に用いることができる。 The method for recycling electric furnace dust according to the present invention is capable of detoxifying dioxins contained in dust generated when the exhaust gas discharged from the electric furnace is filtered by a dust collector, and can be efficiently classified by a classifier. It can be suitably used for a dust recycling method in general electric furnace equipment.
1 マイクロ波処理装置
B 分級器
P 造粒機
S 集塵機
X 電気炉
1 Microwave treatment equipment B Classifier P Granulator S Dust collector X Electric furnace
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010168627A (en) * | 2009-01-23 | 2010-08-05 | Nippon Yakin Kogyo Co Ltd | Method for dehydrating hydrous valuable metal-containing substance using microwave |
| WO2012035611A1 (en) * | 2010-09-14 | 2012-03-22 | スチールプランテック株式会社 | Method and apparatus for recovering metal from electric furnace dust |
| US8377175B2 (en) | 2010-02-26 | 2013-02-19 | Arcelormittal Investigacion Y Desarrollo, S.L. | Apparatus and method for treating exhaust gas |
-
2006
- 2006-10-18 JP JP2006284018A patent/JP2008101826A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010168627A (en) * | 2009-01-23 | 2010-08-05 | Nippon Yakin Kogyo Co Ltd | Method for dehydrating hydrous valuable metal-containing substance using microwave |
| US8377175B2 (en) | 2010-02-26 | 2013-02-19 | Arcelormittal Investigacion Y Desarrollo, S.L. | Apparatus and method for treating exhaust gas |
| US8657929B2 (en) | 2010-02-26 | 2014-02-25 | Arcelormittal Investigacion Y Desarrollo | Method for treating exhaust gas |
| US9375667B2 (en) | 2010-02-26 | 2016-06-28 | Arcelormittal Investigacion Y Desarrollo, S.L. | Apparatus and method for treating exhaust gas |
| WO2012035611A1 (en) * | 2010-09-14 | 2012-03-22 | スチールプランテック株式会社 | Method and apparatus for recovering metal from electric furnace dust |
| JP5541736B2 (en) * | 2010-09-14 | 2014-07-09 | スチールプランテック株式会社 | Method and apparatus for recovering metal from furnace dust |
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Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20091014 |