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JP2008152027A - Optical component and manufacturing method thereof - Google Patents

Optical component and manufacturing method thereof Download PDF

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JP2008152027A
JP2008152027A JP2006340047A JP2006340047A JP2008152027A JP 2008152027 A JP2008152027 A JP 2008152027A JP 2006340047 A JP2006340047 A JP 2006340047A JP 2006340047 A JP2006340047 A JP 2006340047A JP 2008152027 A JP2008152027 A JP 2008152027A
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optical component
film
filter
deposited
antireflection film
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Manabu Otake
学 大竹
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Topcon Corp
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Topcon Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide an optical component which can make the manufacturing time an ordinary time and can suppress a product cost. <P>SOLUTION: On one side surface of the optical component, chemical reinforcement treatment is performed and, thereafter, an antireflection film is deposited. On the other side surface of the optical component, an antireflection film on which a filter film is deposited has a multilayer structure of the order of three layers. The filter film has a multilayer structure of the order of 30 layers. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、CD・DVD・Blue−Ray等のレコーダー用光ピックアップ、プロジェクタ、露光装置、半導体検査装置などに用いられる波長板、偏光板、ビームスプリッタ、ミラー等の光学部品及びその製造方法に関する。   The present invention relates to an optical component such as a wavelength plate, a polarizing plate, a beam splitter, and a mirror used in an optical pickup for a recorder such as a CD / DVD / Blue-Ray, a projector, an exposure apparatus, and a semiconductor inspection apparatus, and a manufacturing method thereof.

従来から、例えば特許文献1の段落0026と図2に示すように、ガラス基板の裏面に成膜する光学薄膜としてARコートの熱膨張係数とほぼ等しいアルミナ膜を用いて、表面側に圧縮応力により反りが発生していたガラス基板の裏面側に引張り応力Fbを働かせ、前記ARコートと前記アルミナ膜とにより生じる夫々の応力(Fa、Fb)を相殺させることにより、ガラス基板の反りを解消することが知られている。   Conventionally, for example, as shown in paragraph 0026 of FIG. 1 and FIG. 2, an alumina film that is almost equal to the thermal expansion coefficient of the AR coat is used as the optical thin film to be formed on the back surface of the glass substrate, and the surface side is subjected to compressive stress. By applying a tensile stress Fb to the back side of the glass substrate where the warpage has occurred and canceling out the respective stresses (Fa, Fb) caused by the AR coat and the alumina film, the warp of the glass substrate is eliminated. It has been known.

また、特許文献1の段落0030と図4には、薄肉の樹脂製波長板に一方の面にARコートを成膜した薄肉の樹脂製偏光板を積層し、ARコートとアルミナ膜とを夫々の主表面に形成したガラス基板を、前記薄肉の樹脂製偏向板が積層された主表面とは反対側の樹脂製波長板の主表面に貼り合わせた積層光学部品が記載されている。   Further, in paragraph 0030 and FIG. 4 of Patent Document 1, a thin resin polarizing plate having an AR coat formed on one surface is laminated on a thin resin wave plate, and the AR coat and the alumina film are respectively laminated. There is described a laminated optical component in which a glass substrate formed on a main surface is bonded to the main surface of a resin wave plate opposite to the main surface on which the thin resin deflecting plate is laminated.

また、例えば特許文献2の特許請求の範囲に示されているように、化学強化によってガラス基板の表面及び裏面に各々形成された圧縮歪み層の各々の深さの差を、再化学強化することにより減少させる記録媒体用ガラス基板の製造方法が記載されている。
特開2004−258377号公報 特許第2998952号公報
Further, for example, as shown in the claims of Patent Document 2, re-chemical strengthening is performed on the difference in depth of each of the compression strain layers formed on the front surface and the back surface of the glass substrate by chemical strengthening. Describes a method for producing a glass substrate for a recording medium which is reduced by the above.
JP 2004-258377 A Japanese Patent No. 2998952

上述した従来の光学部品などをDVD、CD用の光ピックアップ関連の立ち上げミラー、ビームスプリッタなどに適用する場合、その要求面精度が厳しく、また光学特性の耐環境性も厳しい。特許文献1のアルミナ膜を用いて、温度試験や振動試験などの環境試験を行ったところ、ガラス基板との間に剥離が生じてしまった。   When the above-described conventional optical components are applied to DVD, CD optical pickup-related startup mirrors, beam splitters, etc., the required surface accuracy is severe and the optical properties are also environmentally resistant. When an environmental test such as a temperature test and a vibration test was performed using the alumina film of Patent Document 1, peeling occurred between the glass substrate and the glass substrate.

そのため、通常の光学部品へ蒸着方法を適用する場合、波長シフトの問題があり、製造困難である。そのため、イオンプロセスを用いた蒸着(IAD、RF−イオンスパッタリング)やスパッタリングなどの成膜方法が用いられている。しかし、上記の成膜方法を用いると、膜自体の内部応力(圧縮)が強くなり、多層膜を数十層重ねた場合、0.2〜0.3GPaの圧縮応力になってしまう。   Therefore, when applying a vapor deposition method to a normal optical component, there exists a problem of a wavelength shift and it is difficult to manufacture. Therefore, film forming methods such as vapor deposition (IAD, RF-ion sputtering) and sputtering using an ion process are used. However, when the film forming method described above is used, the internal stress (compression) of the film itself becomes strong, and when several tens of multilayer films are stacked, the compressive stress becomes 0.2 to 0.3 GPa.

図2(A)に示すように、例えば波長板1の一方の面にフィルター膜2を30層程度成膜すると、膜自体の内部応力で撓みが発生してしまう。   As shown in FIG. 2A, for example, when about 30 layers of the filter film 2 are formed on one surface of the wave plate 1, bending occurs due to internal stress of the film itself.

これを緩和するには、図2(B)に示すように、波長板1の反対面(裏面)にストレス緩和層3(応力緩和層)をフィルター2と同厚程度の厚さを成膜しなければならず、製造時間は通常の反射防止膜の2〜3倍程度掛かってしまう。   In order to alleviate this, as shown in FIG. 2B, a stress relaxation layer 3 (stress relaxation layer) is formed on the opposite surface (back surface) of the wave plate 1 to a thickness approximately equal to that of the filter 2. The manufacturing time is about 2 to 3 times that of a normal antireflection film.

その結果、フィルター2と同程度の膜厚をつけるために、製品コストが倍になってしまう。   As a result, the product cost is doubled because the film thickness is about the same as that of the filter 2.

そこで、本発明は、製造時間を通常通りの時間とすることが可能で、製品コストを抑えることができる光学部品及びその製造方法を提供することを目的とする。   In view of the above, an object of the present invention is to provide an optical component and a method for manufacturing the same that can reduce the manufacturing cost by making the manufacturing time as normal.

本発明の解決手段を例示すると、次のとおりである。   Examples of the solving means of the present invention are as follows.

(1)一方の面には、化学強化処理をした後に反射防止膜が蒸着されており、他方の面には、フィルター膜が蒸着されていることを特徴とする光学部品。   (1) An optical component in which an antireflection film is deposited on one surface after a chemical strengthening treatment, and a filter film is deposited on the other surface.

(2)前述の光学部品において、前記反射防止膜は多層構造を有し、前記フィルター膜は多層構造を有することを特徴とする光学部品。   (2) In the optical component described above, the antireflection film has a multilayer structure, and the filter film has a multilayer structure.

(3)前述の光学部品において、前記反射防止膜は3層程度の構造を有し、前記フィルター膜は30層程度の構造を有することを特徴とする光学部品。   (3) In the optical component described above, the antireflection film has a structure of about three layers, and the filter film has a structure of about 30 layers.

(4)一方の面には、化学強化処理をした後に反射防止膜を蒸着し、他方の面には、フィルター膜を蒸着することを特徴とする光学部品の製造方法。   (4) A method for producing an optical component, characterized in that an antireflection film is deposited on one surface after a chemical strengthening treatment, and a filter film is deposited on the other surface.

なお、本発明において、「3層程度の構造」と「30層程度の構造」とは、それぞれ厳密に3層と30層に画成される多層構造の態様に限定されず、3層と30層に近い多層構造を含む。   In the present invention, the “about three-layer structure” and the “about thirty-layer structure” are not limited to a multilayer structure that is strictly defined by three and thirty layers, respectively. Includes a multilayer structure close to the layer.

本発明によれば、化学強化処理をした後に反射防止膜を蒸着するので、イオンプロセスを用いた蒸着(IAD、RF−イオンスパッタリング)やスパッタリングなどの成膜方法を用いて成膜しても、光学部品のゆがみをなくすことができる。しかも、ストレス緩和層(応力緩和層)をフィルターと同じ厚さ程度成膜する必要がなく、製造時間も通常通りの時間とすることが可能であり、製品コストを抑えることができる。   According to the present invention, since the antireflection film is deposited after the chemical strengthening treatment, the film may be deposited using a deposition method using an ion process (IAD, RF-ion sputtering) or sputtering. The distortion of the optical component can be eliminated. In addition, it is not necessary to form a stress relieving layer (stress relieving layer) to the same thickness as the filter, and the manufacturing time can be made as usual, thereby reducing the product cost.

本発明では、光学部品の一方の面に化学強化処理をした後に反射防止膜を蒸着し、他方の面にフィルター膜を蒸着する。そのため、イオンプロセスを用いた蒸着(IAD、RF−イオンスパッタリング)やスパッタリングなどの成膜方法を用いて成膜しても、光学部品のゆがみをなくすことができる。さらに、ストレス緩和層(応力緩和層)をフィルターと同じ厚さ程度成膜する必要がない。しかも、製造時間を通常通りの時間とすることができる。   In the present invention, an antireflection film is deposited after chemical strengthening treatment on one surface of the optical component, and a filter film is deposited on the other surface. Therefore, even if a film is formed using a film forming method such as vapor deposition (IAD, RF-ion sputtering) or sputtering using an ion process, the distortion of the optical component can be eliminated. Furthermore, it is not necessary to form a stress relaxation layer (stress relaxation layer) to the same thickness as the filter. In addition, the production time can be set as usual.

本発明は、光学部品の片面のみを化学強化処理する実施形態のみに限定されない。例えば、光学部品の両面を化学強化処理したあと、一方の片面を研磨して他方の片面のみにストレス(応力)を残すようにしてもよい。   The present invention is not limited only to the embodiment in which only one side of the optical component is chemically strengthened. For example, after both surfaces of the optical component are chemically strengthened, one side may be polished to leave stress only on the other side.

図1(A)(B)を参照しつつ、本発明に係る光学部品を説明する。   The optical component according to the present invention will be described with reference to FIGS.

図1(A)に示すように、例えばミラー10の一方の面10aに化学強化処理を行う。その後、他方の面10bにフィルター層11を30層程度コートし、30層程度の多層構造とする。化学強化処理した一方の面10aにも反射防止膜12をコートする。このようにすると、その化学強化処理した一方の面10aに設ける反射防止膜12は、3層程度の多層構造とするだけでも、十分にゆがみがなくなる。従来のようにストレス緩和層(応力緩和層)を特別に設けてフィルターと同じ程度の厚さに成膜する必要がない。その結果、製造時間が通常通りの時間でよく、製品コストを抑えることができる。   As shown in FIG. 1A, for example, a chemical strengthening process is performed on one surface 10a of the mirror 10. Thereafter, about 30 layers of the filter layer 11 are coated on the other surface 10b to obtain a multilayer structure of about 30 layers. The antireflection film 12 is also coated on the one surface 10a subjected to the chemical strengthening treatment. In this case, even if the antireflection film 12 provided on the one surface 10a subjected to the chemical strengthening treatment has only a multi-layer structure of about three layers, there is no sufficient distortion. There is no need to specially provide a stress relaxation layer (stress relaxation layer) as in the prior art to form a film with the same thickness as the filter. As a result, the manufacturing time may be a normal time, and the product cost can be suppressed.

本実施例では、光学部品としてミラーを例にとって説明したが、本発明は、これに限定されず、例えば波長板、偏光板、ビームスプリッタなどの光学部品であってもよい。   In this embodiment, a mirror is used as an example of an optical component. However, the present invention is not limited to this, and may be an optical component such as a wave plate, a polarizing plate, or a beam splitter.

ガラスの化学強化方法には、風冷強化と化学強化があるが、ガラスの強化はガラス表面に圧縮応力を発生させることによって、引張に弱いガラスの性質を改善するのが好ましい。例えば特許文献2の段落0028〜004に記載の方法を参照。   The glass chemical strengthening methods include air cooling strengthening and chemical strengthening. It is preferable that glass strengthening improves the properties of glass that is weak against tension by generating a compressive stress on the glass surface. For example, see the method described in paragraphs 0028 to 004 of Patent Document 2.

化学強化について述べると、ガラスを硝酸カリウム(KNO)中に浸漬して、ガラス表面層のイオン半径の小さいNaを、よりイオン半径の大きいKに置換して、ガラス20の表面に圧縮応力を発生させる。 Regarding chemical strengthening, glass is immersed in potassium nitrate (KNO 3 ) to replace Na + having a small ionic radius in the glass surface layer with K + having a larger ionic radius, and compressive stress is applied to the surface of the glass 20. Is generated.

化学強化ガラスの特徴としては、ガラスの厚みが薄くても強化可能であること、強化による変形が殆ど無いこと、異形や曲げガラスでも強化できることが挙げられる。   The characteristics of chemically tempered glass include that it can be tempered even when the glass is thin, that there is almost no deformation due to tempering, and that it can be tempered even with deformed or bent glass.

化学強化ガラスは、耐熱性、ガラス表面応力、静圧加重強度、落球試験強度の諸特性が優れている。   Chemically tempered glass has excellent properties such as heat resistance, glass surface stress, static pressure load strength, and falling ball test strength.

本発明の1つの実施例による光学部品の製造方法を示す説明図。Explanatory drawing which shows the manufacturing method of the optical component by one Example of this invention. 従来の波長板への成膜法を示す。A film forming method on a conventional wave plate will be described.

符号の説明Explanation of symbols

1 波長板
2 フィルター
3 ストレス緩和層(応力緩和層)
10 ミラー
10a ミラーの一方の面
10b ミラーの他方の面
11 フィルター層
12 反射防止膜
1 Wave plate 2 Filter 3 Stress relaxation layer (stress relaxation layer)
DESCRIPTION OF SYMBOLS 10 Mirror 10a Mirror one surface 10b Mirror other surface 11 Filter layer 12 Antireflection film

Claims (4)

一方の面には、化学強化処理をした後に反射防止膜が蒸着されており、他方の面には、フィルター膜が蒸着されていることを特徴とする光学部品。   An optical component, wherein an antireflection film is deposited on one surface after a chemical strengthening treatment, and a filter film is deposited on the other surface. 請求項1に記載の光学部品において、
前記反射防止膜は多層構造を有し、前記フィルター膜は多層構造を有することを特徴とする光学部品。
The optical component according to claim 1,
The optical component, wherein the antireflection film has a multilayer structure, and the filter film has a multilayer structure.
請求項1に記載の光学部品において、
前記反射防止膜は3層程度の構造を有し、前記フィルター膜は30層程度の構造を有することを特徴とする光学部品。
The optical component according to claim 1,
The optical component, wherein the antireflection film has a structure of about 3 layers, and the filter film has a structure of about 30 layers.
一方の面には、化学強化処理をした後に反射防止膜を蒸着し、他方の面には、フィルター膜を蒸着することを特徴とする光学部品の製造方法。   A method of manufacturing an optical component, comprising: depositing an antireflection film on one surface after chemical strengthening treatment and depositing a filter film on the other surface.
JP2006340047A 2006-12-18 2006-12-18 Optical component and manufacturing method thereof Pending JP2008152027A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
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JP2015143824A (en) * 2013-12-27 2015-08-06 日本電気硝子株式会社 Fluorescent wheel for projector, manufacturing method of the same, and light-emitting device for projector
WO2015137183A1 (en) * 2014-03-12 2015-09-17 コニカミノルタ株式会社 Optical filter and imaging device
WO2016158623A1 (en) * 2015-03-31 2016-10-06 旭硝子株式会社 Glass plate

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015143824A (en) * 2013-12-27 2015-08-06 日本電気硝子株式会社 Fluorescent wheel for projector, manufacturing method of the same, and light-emitting device for projector
US10338458B2 (en) 2013-12-27 2019-07-02 Nippon Electric Glass Co., Ltd. Projector-use luminescent wheel and manufacturing method therefor, and projector-use light emitting device
WO2015137183A1 (en) * 2014-03-12 2015-09-17 コニカミノルタ株式会社 Optical filter and imaging device
US20170017025A1 (en) * 2014-03-12 2017-01-19 Konica Minolta, Inc. Optical Filter And Imaging Device
JPWO2015137183A1 (en) * 2014-03-12 2017-04-06 コニカミノルタ株式会社 Optical filter and imaging device
US10274657B2 (en) 2014-03-12 2019-04-30 Konica Minolta, Inc. Optical filter and imaging device
WO2016158623A1 (en) * 2015-03-31 2016-10-06 旭硝子株式会社 Glass plate
JPWO2016158623A1 (en) * 2015-03-31 2018-01-25 旭硝子株式会社 Glass plate

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