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JP2007266358A - Light emitting device and lighting device - Google Patents

Light emitting device and lighting device Download PDF

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Publication number
JP2007266358A
JP2007266358A JP2006090194A JP2006090194A JP2007266358A JP 2007266358 A JP2007266358 A JP 2007266358A JP 2006090194 A JP2006090194 A JP 2006090194A JP 2006090194 A JP2006090194 A JP 2006090194A JP 2007266358 A JP2007266358 A JP 2007266358A
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light
light emitting
emitting device
emitting element
oxide coating
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Tomoya Tabuchi
智也 田淵
Kosuke Katabe
浩介 形部
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Kyocera Corp
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Kyocera Corp
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Abstract

【課題】反射部材の内周面における反射率の変動を抑制しつつ、良好な発光性能を有するとともに長期信頼性に優れた発光装置を提供すること。
【解決手段】発光装置は、上面に発光素子2の搭載部1aを有する基体1と、基体1上面に、搭載部1aを取り囲むように設けられた反射部材4と、搭載部1aに搭載された発光素子2とを具備し、反射部材4はアルミニウムから成るとともに、内周面1aに陽極酸化被膜4bが形成されている。陽極酸化被膜4bによって良好な反射性能を得ることができるとともに、陽極酸化被膜4bは化学的に安定なことから、長期信頼性に優れた発光装置とできる。
【選択図】 図1
To provide a light-emitting device that has good light-emitting performance and excellent long-term reliability while suppressing fluctuation in reflectance on the inner peripheral surface of a reflecting member.
A light-emitting device is mounted on a base 1 having a mounting portion 1a for a light-emitting element 2 on an upper surface, a reflection member 4 provided on the upper surface of the base 1 so as to surround the mounting portion 1a, and the mounting portion 1a. The reflecting member 4 is made of aluminum, and an anodized film 4b is formed on the inner peripheral surface 1a. A good reflection performance can be obtained by the anodic oxide coating 4b, and since the anodic oxide coating 4b is chemically stable, a light emitting device with excellent long-term reliability can be obtained.
[Selection] Figure 1

Description

本発明は、発光素子が発する光を外部に効率よく放射する発光装置に関する。   The present invention relates to a light emitting device that efficiently radiates light emitted from a light emitting element to the outside.

従来の発光ダイオード(LED)等の発光素子から発光される近紫外光や、青色,赤色,緑色,青色,黄色等の可視領域波長の光を発光する発光装置を図9に示す。図9において、11は基体、12は発光素子を示す。   FIG. 9 shows a light-emitting device that emits near-ultraviolet light emitted from a light-emitting element such as a conventional light-emitting diode (LED) and light in the visible region wavelength such as blue, red, green, blue, and yellow. In FIG. 9, 11 is a base | substrate and 12 shows a light emitting element.

従来の発光装置は、上面に発光素子12を搭載するための搭載部11aを有し、搭載部11aまたはその周辺から発光装置の内外を電気的に導通接続する配線導体11bが形成された絶縁体からなる基体11と、搭載部11aに配線導体11bと導電性部材15を介してフリップチップ実装され電気的に接続固定された発光素子12と、基体11上面に発光素子12を取り囲むように配置された反射部材14から主に構成される。   The conventional light emitting device has a mounting portion 11a for mounting the light emitting element 12 on the upper surface, and an insulator in which a wiring conductor 11b is formed to electrically connect the inside and outside of the light emitting device from the mounting portion 11a or its periphery. And a light emitting element 12 that is flip-chip mounted and electrically connected and fixed to the mounting portion 11a via the wiring conductor 11b and the conductive member 15, and is disposed on the upper surface of the base 11 so as to surround the light emitting element 12. The reflecting member 14 is mainly composed.

反射部材14は、アルミニウム(Al),銀(Ag),ロジウム(Rh)またはクロム(Cr)等の紫外光から可視光領域において良好な反射率を有する金属材やこれら金属材を反射部材14の発光素子12に対向する内周面14aにコーティングした金属、樹脂等によって構成されていた。   The reflecting member 14 is made of a metal material having a good reflectivity in the ultraviolet to visible light region such as aluminum (Al), silver (Ag), rhodium (Rh), or chromium (Cr), and these metal materials. The inner peripheral surface 14a facing the light emitting element 12 is made of a metal, resin, or the like coated on the inner peripheral surface 14a.

この発光装置は、発光装置駆動回路基板(図示せず)から供給される駆動電流により、発光素子12を発光させ、発光素子12から光を放射することができる発光装置である。近年、この様な発光装置は、照明用光源として利用され始めており、特に発光装置の発光効率や環境性、長期信頼性に対する要求が高まってきている。
特開2003−110146号公報
This light-emitting device is a light-emitting device that can cause the light-emitting element 12 to emit light and emit light from the light-emitting element 12 by a drive current supplied from a light-emitting device drive circuit board (not shown). In recent years, such light-emitting devices have begun to be used as illumination light sources, and in particular, there are increasing demands for light-emitting efficiency, environmental performance, and long-term reliability of light-emitting devices.
JP 2003-110146 A

しかしながら、上記従来の発光装置において、反射部材14の内周面14aに用いられている金属は、一般的に容易に酸化反応を起こし、その表面に酸化膜が形成される傾向を有している。このため、反射部材14の内周面14aにおける発光素子12からの光に対する反射率が低下して、発光装置の光出力の低下が起きるとともに発光特性が変動するという問題点を有していた。   However, in the conventional light emitting device, the metal used for the inner peripheral surface 14a of the reflecting member 14 generally tends to easily undergo an oxidation reaction, and an oxide film tends to be formed on the surface thereof. . For this reason, the reflectance with respect to the light from the light emitting element 12 on the inner peripheral surface 14a of the reflecting member 14 is lowered, and there is a problem that the light output of the light emitting device is lowered and the light emission characteristics are changed.

したがって、本発明は上記問題点に鑑み完成されたものであり、その目的は、反射部材の内周面における反射率の変動を抑制しつつ、良好な発光性能を有するとともに長期信頼性に優れた発光装置を提供することにある。   Therefore, the present invention has been completed in view of the above problems, and its purpose is to suppress the fluctuation of the reflectance on the inner peripheral surface of the reflecting member and to have good light emitting performance and excellent long-term reliability. The object is to provide a light emitting device.

本発明の発光装置は、上面に発光素子の搭載部を有する基体と、該基体の上面に、前記搭載部を取り囲むように設けられた反射部材と、前記搭載部に搭載された発光素子とを具備している発光装置において、前記反射部材はアルミニウムから成り、内周面に陽極酸化被膜が形成されていることを特徴とする。   The light emitting device of the present invention includes a base having a light emitting element mounting portion on an upper surface, a reflecting member provided on the upper surface of the base so as to surround the mounting portion, and a light emitting element mounted on the mounting portion. In the light emitting device provided, the reflecting member is made of aluminum, and an anodized film is formed on an inner peripheral surface.

本発明の発光装置において好ましくは、前記発光素子は、紫外領域から青色領域に含まれる光を発する発光素子であり、該発光素子の発する光を波長変換する蛍光体が含まれた波長変換部材が前記発光素子の上に配置されていることを特徴とする。   In the light emitting device of the present invention, preferably, the light emitting element is a light emitting element that emits light included in an ultraviolet region to a blue region, and a wavelength conversion member including a phosphor that converts the wavelength of light emitted from the light emitting element. It is arranged on the light emitting element.

本発明の照明装置は、上記本発明の発光装置と、前記発光装置が搭載され、前記発光装置を駆動する電気配線を有する駆動部と、前記発光装置から出射される光を反射する光反射手段とを含むことを特徴とする。   The illuminating device of the present invention includes the light emitting device of the present invention, a drive unit on which the light emitting device is mounted and having an electrical wiring for driving the light emitting device, and light reflecting means for reflecting light emitted from the light emitting device. It is characterized by including.

本発明の発光装置は、反射部材の内周面にアルミニウムの陽極酸化被膜が形成されていることにより、内周面に多数の微細な穴から成る多孔質の表面が形成され、これら多孔質の表面によって内周面の表面積が大きくなる。さらに、反射部材の内周面には、陽極酸化被膜から成る強固な反射面が形成される。その結果、拡散反射光を含めた反射率で比較して金属アルミニウムと同等以上の反射率を得ることができ、発光素子から出た光を効率よく外部へ取り出すことができるとともに、表面がさらに酸化されることによる反射率の低下を抑制できる。その結果、発光効率が安定して高い発光装置を得ることができる。   In the light emitting device of the present invention, a porous surface composed of a large number of fine holes is formed on the inner peripheral surface by forming an anodized aluminum film on the inner peripheral surface of the reflecting member. The surface area of the inner peripheral surface increases depending on the surface. Further, a strong reflecting surface made of an anodized film is formed on the inner peripheral surface of the reflecting member. As a result, it is possible to obtain a reflectance equal to or higher than that of metal aluminum in comparison with the reflectance including diffuse reflected light, to efficiently extract the light emitted from the light emitting element to the outside, and to further oxidize the surface. It is possible to suppress a decrease in reflectance due to being performed. As a result, a light emitting device with stable and high luminous efficiency can be obtained.

本発明の発光装置において好ましくは、発光素子が少なくとも紫外領域から青色領域に含まれる光を放射する発光素子であり、発光素子の発する光を波長変換する蛍光体が含まれた波長変換部材が発光素子の上に配置されていることにより、紫外領域から青色領域の短波長でエネルギーの高い発光素子の光は反射部材の内周面によって拡散反射され、発光素子の上に配置された波長変換部材の全体に万遍なく照射される。そして、短波長でエネルギーの高い発光素子の光は、波長変換部材によって長波長でエネルギーの低い蛍光に効率よく変換されるとともに、波長変換部材の局所に集中することなく拡散反射光が照射されることによって、波長変換効率に応じた蛍光が波長変換部材から効率よく放射される。従って、色むらや色ばらつきが少なく、発光効率の高い発光装置を得ることができる。   In the light-emitting device of the present invention, preferably, the light-emitting element is a light-emitting element that emits light included in at least the ultraviolet region to the blue region, and the wavelength conversion member that includes a phosphor that converts the wavelength of light emitted from the light-emitting element emits light. By being disposed on the element, the light of the light emitting element having a short wavelength from the ultraviolet region to the blue region and having high energy is diffusely reflected by the inner peripheral surface of the reflecting member, and the wavelength converting member disposed on the light emitting element. The whole area is irradiated uniformly. The light of the light emitting element having a short wavelength and high energy is efficiently converted into fluorescence having a long wavelength and low energy by the wavelength converting member, and the diffuse reflected light is irradiated without being concentrated locally on the wavelength converting member. Thus, fluorescence corresponding to the wavelength conversion efficiency is efficiently emitted from the wavelength conversion member. Accordingly, a light-emitting device with little color unevenness and color variation and high light emission efficiency can be obtained.

また、本発明の照明装置は、上記本発明の発光装置と、発光装置が搭載され、発光装置を駆動する電気配線を有する駆動部と、発光装置から出射される光を反射する光反射手段とを含むことから、光出力が低下したり、長期間にわたり発光特性が変化したりすることがなく、均一な照度面が得られる照明装置とすることができる。   The lighting device of the present invention includes the light emitting device of the present invention, a drive unit on which the light emitting device is mounted and having electric wiring for driving the light emitting device, and a light reflecting means for reflecting light emitted from the light emitting device. Therefore, it is possible to provide an illumination device that can obtain a uniform illuminance surface without lowering light output or changing light emission characteristics over a long period of time.

本発明の発光装置について以下に詳細に説明する。図1乃至図4はそれぞれ本発明の発光装置の各種の実施の形態の一例を示す断面図および要部拡大断面図であり、図2は図1の反射部材の内周面を拡大して示す要部拡大断面図である。また図5,図6は、本発明の発光装置の実施の形態の他の例を示す断面図である。   The light emitting device of the present invention will be described in detail below. 1 to 4 are a sectional view and an enlarged sectional view showing an example of various embodiments of the light emitting device according to the present invention, respectively. FIG. 2 is an enlarged view of the inner peripheral surface of the reflecting member in FIG. It is a principal part expanded sectional view. 5 and 6 are sectional views showing other examples of the embodiment of the light emitting device of the present invention.

それぞれの図において、1は上面に発光素子2の搭載部1aを有する基体、2は搭載部1aに搭載された発光素子、4は搭載部1aまたは発光素子2を取り囲むように設けられた反射部材であり、主としてこれらで発光装置が構成される。また、1bは基体1の搭載部1aまたはその周囲の一端から発光装置の外側へかけて形成された配線導体、5は配線導体1bの一端と発光素子2に形成された電極(図示せず)とを接続する導電性部材、3は発光装置2の発する光を波長変換する蛍光体が含まれた波長変換部材、6は反射部材4の内側開口に発光素子2を覆うように配置された透光性部材であり、必要に応じて適宜発光装置に用いられる。   In each figure, 1 is a base having a mounting portion 1a for the light emitting element 2 on the upper surface, 2 is a light emitting element mounted on the mounting portion 1a, and 4 is a reflective member provided so as to surround the mounting portion 1a or the light emitting element 2. These mainly constitute the light emitting device. Further, 1b is a wiring conductor formed from one end of the mounting portion 1a of the substrate 1 or its periphery to the outside of the light emitting device, and 5 is an electrode (not shown) formed on one end of the wiring conductor 1b and the light emitting element 2. 3 is a wavelength conversion member that includes a phosphor that converts the wavelength of light emitted from the light emitting device 2, and 6 is a transparent member that is disposed in the inner opening of the reflection member 4 so as to cover the light emitting element 2. It is a light-sensitive member and is appropriately used for a light-emitting device as necessary.

本発明の基体1は、酸化アルミニウム質焼結体,窒化アルミニウム質焼結体,ムライト質焼結体,ガラスセラミックス等のセラミックス、またはエポキシ樹脂や液晶ポリマー(LCP)等の樹脂から成る絶縁体であり、基体1上面に発光素子2が搭載されることによって、発光素子2を支持する支持部材として機能する。   The substrate 1 of the present invention is an insulator made of an aluminum oxide sintered body, an aluminum nitride sintered body, a mullite sintered body, a ceramic such as a glass ceramic, or a resin such as an epoxy resin or a liquid crystal polymer (LCP). In addition, the light emitting element 2 is mounted on the upper surface of the base body 1 and functions as a support member for supporting the light emitting element 2.

また、基体1がセラミックス等から成る場合、基体1となる複数のグリーンシートに、発光装置の内外を電気的に導通接続するために、タングステン(W),モリブデン(Mo),マンガン(Mn),銅(Cu)等の金属ペーストから成る配線導体1bを配置し、基体1を焼成すると同時に金属ペーストも焼成することにより、配線導体1bを有する基体1が形成される。このような配線導体1bは、上記周知のメタライズ法やメッキ法などを用いて形成される。   In addition, when the substrate 1 is made of ceramics or the like, tungsten (W), molybdenum (Mo), manganese (Mn), The wiring conductor 1b made of a metal paste such as copper (Cu) is disposed, and the base 1 having the wiring conductor 1b is formed by firing the base 1 and simultaneously firing the metal paste. Such a wiring conductor 1b is formed using the known metallization method, plating method or the like.

また、基体1が樹脂から成る絶縁体の場合、配線導体1bは、Cu、Ag、Al、鉄(Fe)−ニッケル(Ni)−コバルト(Co)合金またはFe−Ni合金等の金属材料から成るリード端子を基体1に埋設し、リード端子の一端を搭載部1aに導出し、他端を基体1の側面や下面に導出して露出させることによって形成される。   When the substrate 1 is an insulator made of resin, the wiring conductor 1b is made of a metal material such as Cu, Ag, Al, iron (Fe) -nickel (Ni) -cobalt (Co) alloy, or Fe—Ni alloy. The lead terminal is formed by embedding the lead terminal in the base 1, leading one end of the lead terminal to the mounting portion 1 a, and leading the other end to the side surface or the bottom surface of the base 1 and exposing it.

なお、配線導体1bは、基体1の露出する表面に厚さ0.5〜9μmのNi層や厚さ0.5〜5μmの金(Au)層等の耐食性に優れる金属層が被着されているのがよく、これにより配線導体1bが酸化腐食するのを有効に防止できるとともに、半田等の導電性部材5による発光素子2との接合を強固にすることができる。   In addition, the wiring conductor 1b is coated with a metal layer having excellent corrosion resistance such as a Ni layer having a thickness of 0.5 to 9 μm or a gold (Au) layer having a thickness of 0.5 to 5 μm on the exposed surface of the substrate 1. Thus, it is possible to effectively prevent the wiring conductor 1b from being oxidatively corroded, and to firmly join the light emitting element 2 with the conductive member 5 such as solder.

そして、発光素子2は、基体1上面の配線導体1bの一端に電気的に導電性部材5を介して接続され、基体1の側面や下面などに導出された配線導体1bの他端と発光装置駆動回路基板(図示せず)とが電気的に接続されることにより、発光装置駆動回路基板と発光素子2とが電気的に接続される。   The light emitting element 2 is electrically connected to one end of the wiring conductor 1b on the upper surface of the base body 1 via the conductive member 5, and is connected to the other end of the wiring conductor 1b led out to the side surface or the lower surface of the base body 1 and the light emitting device. By electrically connecting the drive circuit board (not shown), the light emitting device drive circuit board and the light emitting element 2 are electrically connected.

また、基体1は、その上面に発光素子2からの光透過を抑制するとともに、基体1の上側に光を効率よく反射させることを目的として、配線導体1bに対して電気的に短絡しないように、Al,Ag,Au,白金(Pt),Cu,Cr,Rh等の金属層が蒸着法やメッキ法により形成され、基体1の上方へ光を反射させる反射層が設けられていることがより好ましい。   Further, the base 1 is designed not to be electrically short-circuited to the wiring conductor 1b for the purpose of suppressing light transmission from the light emitting element 2 on the upper surface and reflecting light efficiently on the upper side of the base 1. More preferably, a metal layer such as Al, Ag, Au, platinum (Pt), Cu, Cr, Rh is formed by a vapor deposition method or a plating method, and a reflective layer for reflecting light is provided above the substrate 1. preferable.

さらに、基体1は、上面に発光素子2を取り囲むように配置された枠状の反射部材4を具備している。これにより、発光素子2から側方に放射される光は、反射部材4の内周面4aで上方に反射され、発光装置の外部に放射される。また、内周面4aが、発光素子2の光を効率よく反射する反射面とされている構成により、発光素子2から側方に発せられた光は、発光装置の上方に効率よく反射されるとともに、基体1および反射部材4による光の吸収や透過が効果的に抑制される。その結果、発光装置の光出力や発光効率は著しく向上する。さらにまた、反射部材4は、発光素子2を外部環境や発光装置を落下させた際の衝撃から保護する機能を有するとともに、図6に示すように基体1と波長変換部材3との間に配されて、波長変換部材3を保持する保持部材としての機能を有する。   Further, the base 1 includes a frame-like reflecting member 4 disposed on the upper surface so as to surround the light emitting element 2. Thereby, the light emitted from the light emitting element 2 to the side is reflected upward by the inner peripheral surface 4a of the reflecting member 4 and is emitted to the outside of the light emitting device. Further, the configuration in which the inner peripheral surface 4a is a reflecting surface that efficiently reflects the light of the light emitting element 2, the light emitted from the light emitting element 2 to the side is efficiently reflected above the light emitting device. At the same time, absorption and transmission of light by the base 1 and the reflecting member 4 are effectively suppressed. As a result, the light output and light emission efficiency of the light emitting device are significantly improved. Furthermore, the reflecting member 4 has a function of protecting the light emitting element 2 from an external environment or an impact when the light emitting device is dropped, and is disposed between the base 1 and the wavelength converting member 3 as shown in FIG. Thus, it has a function as a holding member for holding the wavelength conversion member 3.

なお、基体1は、このように配線導体1bとなる金属およびこれを絶縁する絶縁体を組み合わせて、発光素子2を搭載する機能を有しておればよく、上記構成はその一例であって、これに限ることはない。例えば、配線導体1bは必ずしも基体1内部に配設されている必要はなく、発光装置の外部から直接発光素子2の電極に導線で接続してもよい。   In addition, the base | substrate 1 should just have the function to mount the light emitting element 2 combining the metal used as the wiring conductor 1b in this way, and the insulator which insulates this, The said structure is the example, This is not a limitation. For example, the wiring conductor 1b is not necessarily disposed inside the base 1, and may be directly connected to the electrode of the light-emitting element 2 from the outside of the light-emitting device by a conductive wire.

本発明の反射部材4は、酸化アルミニウム質焼結体,酸化ジルコニウム質焼結体,窒化アルミニウム質焼結体等のセラミックスや、エポキシ樹脂や液晶ポリマー(LCP)等の樹脂で構成され、内周面4aには、金属メッキや蒸着等によってアルミニウム膜が形成される。そして、アルミニウム膜に陽極酸化処理が施され、内周面4aにアルミニウムの陽極酸化被膜4bが形成された反射部材4を作製することができる。または、切削加工や金型成形されたアルミニウムを電解研磨や化学研磨等で所望の形状に成形した後、陽極酸化処理を施すことで内周面4aに陽極酸化被膜4bが形成された反射部材4を作製することができる。   The reflecting member 4 of the present invention is made of ceramics such as an aluminum oxide sintered body, a zirconium oxide sintered body, an aluminum nitride sintered body, or a resin such as an epoxy resin or a liquid crystal polymer (LCP). An aluminum film is formed on the surface 4a by metal plating, vapor deposition, or the like. Then, the reflecting member 4 in which the anodizing treatment is applied to the aluminum film and the aluminum anodic oxide coating 4b is formed on the inner peripheral surface 4a can be produced. Alternatively, the reflecting member 4 in which the anodized film 4b is formed on the inner peripheral surface 4a by forming an aluminum that has been cut or molded into a desired shape by electrolytic polishing or chemical polishing, and then anodizing the aluminum. Can be produced.

なお、陽極酸化処理とは、硫酸やシュウ酸、クロム酸、ホウ酸等の酸性溶液、あるいは水酸化アンモニウム(NHOH)とフッ化アンモニウム(NHF)の混合液、水酸化ナトリウム(NaOH)と過酸化水素(H)の混合液、リン酸ナトリウム(NaPO)溶液等のアルカリ性溶液等の電解液中において、AlまたはAl−Cu系、Al−Mn系、Al−Si系、Al−マグネシウム(Mg)系、Al−Mg−ケイ素(Si)系、Al−亜鉛(Zn)系等のアルミニウム合金を陽極とし、カーボンあるいは鉛を陰極として直流電圧を印加することにより、陽極に接続されるアルミニウムまたはアルミニウム合金が電解液中の活性な酸素と反応し、その表面に陽極酸化された無孔質のアルミニウム膜が形成される。 The anodizing treatment is an acidic solution such as sulfuric acid, oxalic acid, chromic acid, boric acid, or a mixed solution of ammonium hydroxide (NH 4 OH) and ammonium fluoride (NH 4 F), sodium hydroxide (NaOH). ) And hydrogen peroxide (H 2 O 2 ), in an electrolytic solution such as an alkaline solution such as a sodium phosphate (Na 3 PO 4 ) solution, Al or Al—Cu, Al—Mn, Al— By applying a DC voltage using an aluminum alloy such as Si-based, Al-magnesium (Mg) -based, Al-Mg-silicon (Si) -based, Al-zinc (Zn) -based as an anode and carbon or lead as a cathode, Aluminum or aluminum alloy connected to the anode reacts with active oxygen in the electrolytic solution, and an anodized nonporous aluminum film is formed on the surface thereof.

さらに、陽極酸化された無孔質のアルミニウム膜の酸化反応を進めることにより、無孔質のアルミニウム膜に形成された表面の凹部により高い電界が発生し、例えば硫酸溶液を用いた場合は、溶液中の硫酸イオンがその凹部に入り込み、局所的に表面が硫酸アルミニウムとなって溶出する部分ができる。その過程と酸化反応を同時に繰り返すことにより、無孔質のアルミニウム膜の表面に無数の凹部を有する表面が微細な凹凸状に多孔質の陽極酸化被膜4bが形成される。なお、陽極酸化被膜4bは、使用する材料や電解液の組成、印加電圧、印加電流密度、処理温度、処理時間等の条件を適切に選択することで、その表面を銀白色や灰白色、黄褐色、灰褐色、灰色、透明等にすることが可能であり、発光素子2から出る光の波長等を考慮し適宜決定しておけばよい。   Furthermore, by proceeding the oxidation reaction of the anodized nonporous aluminum film, a high electric field is generated in the concave portion of the surface formed in the nonporous aluminum film. For example, when using a sulfuric acid solution, The sulfate ions inside enter into the recesses, and a portion where the surface becomes aluminum sulfate and elutes locally is formed. By repeating the process and the oxidation reaction at the same time, the porous anodic oxide coating 4b is formed so that the surface having innumerable recesses on the surface of the non-porous aluminum film has fine irregularities. In addition, the surface of the anodic oxide coating 4b is silver white, grayish white, yellowish brown by appropriately selecting conditions such as the material used, the composition of the electrolytic solution, the applied voltage, the applied current density, the processing temperature, and the processing time. , Grayish brown, gray, transparent, etc., and may be appropriately determined in consideration of the wavelength of light emitted from the light emitting element 2 and the like.

このような反射部材4は、内周面4aにアルミニウムの陽極酸化被膜4bが形成されていることにより、陽極酸化被膜4bの表面が多孔質かつ、内周面4aの実効的な表面積が大きくなる。これにより、発光素子2から出た光は、陽極酸化被膜4bで反射される際に効率よく上方へ反射され、光の取り出し効率の高い発光装置とすることができる。すなわち、陽極酸化被膜4bは、無数の凹部を有する多孔質の表面であることから、陽極酸化被膜4bへ入射してきた光が拡散反射され、発光素子2からの光を上方に満遍なく放射させることができる。その結果、発光装置の強度ムラや強度バラツキは低減され、良好な発光特性を有する発光装置とすることができる。   In such a reflection member 4, the surface of the anodic oxide coating 4b is porous and the effective surface area of the inner peripheral surface 4a is increased by forming the anodic oxide coating 4b of aluminum on the inner peripheral surface 4a. . Thereby, the light emitted from the light emitting element 2 is efficiently reflected upward when reflected by the anodic oxide coating 4b, and a light emitting device with high light extraction efficiency can be obtained. That is, since the anodic oxide coating 4b is a porous surface having innumerable recesses, the light incident on the anodic oxide coating 4b is diffusely reflected, and the light from the light emitting element 2 can be evenly emitted upward. it can. As a result, intensity unevenness and intensity variation of the light-emitting device are reduced, and a light-emitting device having favorable light-emitting characteristics can be obtained.

さらに、陽極酸化被膜4bは、その表面が多孔質に形成されることにより、発光素子2から陽極酸化被膜4bに入射するとともに下地のアルミニウムで反射された光は、多孔質の表面から陽極酸化被膜4bの外部に取り出され易くなる。すなわち、反射部材4の内周面4aが平坦な陽極酸化被膜4bから成る場合、陽極酸化被膜4bと外部との屈折率差によってスネルの法則に基づいた全反射が生じ、陽極酸化被膜4bに入射し、臨界角より大きな角度で陽極酸化被膜4より出射しようとする光は、陽極酸化被膜4b内で反射を繰り返して閉じ込められる。この閉じ込められて反射を繰り返す間に、下地のアルミニウムの反射率に応じた光吸収が発生することにより、反射部材4を介して発光装置の外部に放射される光が減衰する。一方、陽極酸化被膜4bの表面に多数の微細な穴(凹部)から成る多孔質の表面が形成されていることにより、陽極酸化被膜4の表面が様々な角度で配置されたものとなり、下地のアルミニウムで反射された光が多孔質な表面を介して反射されず、陽極酸化被膜4b外部に透過され易くなる。よって、発光装置より放射される光出力および発光効率は向上する。   Further, since the surface of the anodic oxide coating 4b is made porous, the light incident on the anodic oxide coating 4b from the light emitting element 2 and reflected by the underlying aluminum is reflected from the porous surface to the anodic oxide coating 4b. It becomes easy to take out to the exterior of 4b. That is, when the inner peripheral surface 4a of the reflecting member 4 is made of a flat anodic oxide coating 4b, total reflection based on Snell's law occurs due to the refractive index difference between the anodic oxide coating 4b and the outside, and enters the anodic oxide coating 4b. However, light that is going to be emitted from the anodic oxide coating 4 at an angle larger than the critical angle is confined by repeated reflection in the anodic oxide coating 4b. While being confined and repeatedly reflected, light absorption corresponding to the reflectance of the underlying aluminum occurs, so that the light radiated to the outside of the light emitting device through the reflecting member 4 is attenuated. On the other hand, the surface of the anodic oxide coating 4b is formed with a porous surface comprising a large number of fine holes (recesses), so that the surface of the anodic oxide coating 4 is arranged at various angles. The light reflected by the aluminum is not reflected through the porous surface and is easily transmitted to the outside of the anodic oxide coating 4b. Therefore, the light output emitted from the light emitting device and the light emission efficiency are improved.

また、陽極酸化被膜4bは、化学的に安定な酸化アルミニウムで形成された酸化膜、いわゆる不動態膜であることから、紫外光から可視光領域で透過率の優れるコーティング材(例えば、低融点ガラス,ゾル−ゲルガラス、シリコーン樹脂,エポキシ樹脂,アクリル樹脂)等を用いることなく、内周面4aの耐腐食性,耐薬品性,耐候性を向上でき、より低コストで長期信頼性に優れた発光装置を作製することができる。   Further, the anodic oxide coating 4b is an oxide film formed of chemically stable aluminum oxide, so-called a passive film, so that it is a coating material (for example, low melting point glass having excellent transmittance in the ultraviolet to visible light region). , Sol-gel glass, silicone resin, epoxy resin, acrylic resin), etc., can improve the corrosion resistance, chemical resistance and weather resistance of the inner peripheral surface 4a, and can emit light with lower cost and longer-term reliability. A device can be made.

なお、陽極酸化被膜4bは、厚みが30μm以下であることが好ましい。陽極酸化被膜4bの厚みに比例して光の損失量は大きくなる一方、厚みが大きくなると表面の多孔質部の容積も大きくなり反射率は増加する。陽極酸化被膜4bの厚みが30μm以上の場合、光の損失量が拡散反射率の増加量より大きくなるため、反射率が低下し、発光装置の発光効率を低下させる。   The anodic oxide coating 4b preferably has a thickness of 30 μm or less. While the amount of light loss increases in proportion to the thickness of the anodic oxide coating 4b, the volume of the porous portion on the surface increases and the reflectance increases as the thickness increases. When the thickness of the anodic oxide coating 4b is 30 μm or more, the amount of light loss is larger than the amount of increase in the diffuse reflectance, so that the reflectance is lowered and the light emission efficiency of the light emitting device is lowered.

また、陽極酸化被膜4bは、白色系であることが好ましい。なお、白色とは、紫外領域から可視光領域の光のスペクトル帯において、連続的に高い反射率、例えば反射光に対する入射光の光強度の比において80%以上、で反射されることを意味し、発光素子2から放射される、紫外領域から可視光領域に含まれる様々な光を効率よく反射部材4を介して上方へ取り出すことができる。   The anodic oxide coating 4b is preferably white. White means that the light is continuously reflected at a high reflectance in the spectrum of light from the ultraviolet region to the visible light region, for example, 80% or more in the ratio of the light intensity of the incident light to the reflected light. Various light radiated from the light emitting element 2 and included in the visible region from the ultraviolet region can be efficiently extracted upward through the reflecting member 4.

また、陽極酸化被膜4bは、例えば、陽極側に1000系(純Al系)または7000系(Al−Zn系)合金(JIS H4100:1999 アルミニウムおよびアルミニウム合金の押出形材)で構成される反射部材4を、陰極側にカーボンやPt等を接続し、希硫酸溶液中に浸した状態で電気を導通させることで陽極側に接続された反射部材4の表面を覆うように白色系の陽極酸化被膜4bが形成される。   Moreover, the anodic oxide coating 4b is, for example, a reflective member made of a 1000 series (pure Al series) or 7000 series (Al-Zn series) alloy (JIS H4100: 1999 extruded aluminum and aluminum alloy) on the anode side. 4 is connected to the cathode side by carbon, Pt, etc., and is white so as to cover the surface of the reflecting member 4 connected to the anode side by conducting electricity while immersed in a dilute sulfuric acid solution. 4b is formed.

また、陽極酸化被膜4bは、他の合金材、例えば2000系(Al−Cu系),3000系(Al−Mn系),5000系(Al−Mg系)または6000系(Al−Mg−Si系)を利用する場合は、1000系や7000系と比較し、CuやMn、Mg、Siの割合が高いため、陽極酸化被膜4bの膜厚を薄くするように調整する必要があるものの、希硫酸溶液中で同様にして、陽極酸化被膜4bを形成することができる。   Further, the anodic oxide coating 4b is made of other alloy materials such as 2000 series (Al-Cu series), 3000 series (Al-Mn series), 5000 series (Al-Mg series) or 6000 series (Al-Mg-Si series). ) Is used, the ratio of Cu, Mn, Mg, Si is higher than that of 1000 series and 7000 series. Therefore, it is necessary to adjust the thickness of the anodic oxide coating 4b to be thin, but dilute sulfuric acid. The anodic oxide coating 4b can be formed in the same manner in the solution.

陽極あるいは陰極側には、先述と同様にして電解液をNHOHとNHFの混合溶液として電気を導通させることで陽極酸化被膜4bを透明色で形成することができ、その多孔質内部に白色の染料等を塗布することで形成してもよい。 On the anode or cathode side, the anodic oxide coating 4b can be formed in a transparent color by conducting electricity as a mixed solution of NH 4 OH and NH 4 F in the same manner as described above. You may form by apply | coating a white dye etc. to this.

なお、陽極酸化被膜4bは、白色系という記載をしているが、特に限定されるものではなく、反射部材4で反射されるべき光の波長帯において白色であればよい。また、図1乃至6において、内周面4aのみに陽極酸化被膜4bを示しているが、例えば反射部材4の表面全面に陽極酸化被膜4aが形成されていてもよいし、さらに基体1の上面に配線導体1に対して電気的に短絡しないように形成されたAl金属層表面にも陽極酸化被膜4bが形成されていても問題ないことはいうまでもない。少なくとも内周面4aに陽極酸化被膜4aが形成されておればよい。   The anodic oxide coating 4b is described as white, but is not particularly limited as long as it is white in the wavelength band of light to be reflected by the reflecting member 4. 1 to 6, the anodic oxide coating 4b is shown only on the inner peripheral surface 4a. However, for example, the anodic oxide coating 4a may be formed on the entire surface of the reflecting member 4, and the upper surface of the substrate 1 may be further formed. Needless to say, there is no problem even if the anodic oxide coating 4b is also formed on the surface of the Al metal layer formed so as not to be electrically short-circuited to the wiring conductor 1. It is only necessary that the anodic oxide coating 4a be formed on at least the inner peripheral surface 4a.

また、反射部材4は、Ag−Cu,鉛(Pb)−錫(Sn),Au−Sn,Au−ケイ素(Si),Sn−Ag−Cu等の合金ロウ材(図示せず)や、シリコーン樹脂やエポキシ樹脂、アクリル樹脂等の樹脂接合材(図示せず)により、発光素子2を取り囲むようにして基体1上面に取着されるか基体1と一体に形成される。   The reflecting member 4 is made of alloy brazing material (not shown) such as Ag-Cu, lead (Pb) -tin (Sn), Au-Sn, Au-silicon (Si), Sn-Ag-Cu, silicone, etc. It is attached to the upper surface of the substrate 1 or formed integrally with the substrate 1 so as to surround the light emitting element 2 by a resin bonding material (not shown) such as resin, epoxy resin, acrylic resin or the like.

なお、反射部材4と基体1とを接合する接合材は、基体1、反射部材4の材質や熱膨張係数等を考慮して適宜選定すればよく、特に限定されるものではない。また、基体1と反射部材4との接合に高信頼性が要求される場合、金属ロウ材や半田を用いるとよい。   The bonding material for bonding the reflecting member 4 and the substrate 1 may be appropriately selected in consideration of the material of the substrate 1 and the reflecting member 4, the thermal expansion coefficient, etc., and is not particularly limited. Further, when high reliability is required for joining the base 1 and the reflecting member 4, a metal brazing material or solder may be used.

また、反射部材4は、基体1と一体に形成されてもよく、例えば基体1および反射部材4がセラミックスからなる場合、基体1となるセラミックグリーンシートと反射部材4となるセラミックグリーンシートとを積層し、同時に焼成することにより形成できる。そして内周面4aその他所要の部位にAl金属層を形成し、陽極酸化被膜4bを形成する。   The reflecting member 4 may be formed integrally with the base 1. For example, when the base 1 and the reflecting member 4 are made of ceramics, a ceramic green sheet to be the base 1 and a ceramic green sheet to be the reflecting member 4 are laminated. And it can form by baking simultaneously. Then, an Al metal layer is formed on the inner peripheral surface 4a and other required portions to form the anodic oxide coating 4b.

また、基体1と反射部材4とが、エポキシ樹脂やLCP等の熱硬化型樹脂や熱可塑性樹脂等の樹脂から成る絶縁体から成る場合、基体1と反射部材4とが一体的に形成される成形型により、樹脂から成る絶縁体と金属リードとを一体的にモールド成形することによっても形成できる。そして内周面4aその他所要の部位にAl金属層を形成し、陽極酸化被膜4bを形成する。   When the base 1 and the reflecting member 4 are made of an insulator made of a resin such as a thermosetting resin such as an epoxy resin or LCP or a thermoplastic resin, the base 1 and the reflecting member 4 are integrally formed. It can also be formed by integrally molding an insulator made of resin and a metal lead using a molding die. Then, an Al metal layer is formed on the inner peripheral surface 4a and other required portions to form the anodic oxide coating 4b.

なお、内周面4aは、発光素子2の光を上方に効率よく反射させるために、上側に向かうに伴って外側に広がるように傾斜しているのがよい。これによって内周面4aは、発光素子2から側方に放射された光を効率よく発光装置の上方に反射することができる。   In addition, in order to reflect the light of the light emitting element 2 efficiently upwards, the inner peripheral surface 4a is preferably inclined so as to spread outward as it goes upward. As a result, the inner peripheral surface 4a can efficiently reflect the light emitted from the light emitting element 2 to the side toward the upper side of the light emitting device.

さらに、反射部材4は、開口部にガラス、サファイア、石英、またはエポキシ樹脂,シリコーン樹脂,アクリル樹脂等の透明な部材から成る蓋体(図示せず)を搭載固定しても良い。この場合、反射部材4の内側に設置された発光素子2、配線導体1b等を保護するとともに、発光装置内部を気密に封止し、発光素子2を長期に安定して動作させることができる。また、蓋体をレンズ状に形成して光学レンズの機能を付加することによって、光を集光または分散させ、所望の放射角度、強度分布で光を発光装置の外部に取りだすことができるとともに発光装置内部への耐浸水性が改善され、発光装置の長期信頼性が向上する。   Further, the reflecting member 4 may be mounted and fixed with a lid (not shown) made of a transparent member such as glass, sapphire, quartz, epoxy resin, silicone resin, acrylic resin or the like in the opening. In this case, while protecting the light emitting element 2, the wiring conductor 1b, etc. which are installed inside the reflecting member 4, the inside of the light emitting device can be hermetically sealed, and the light emitting element 2 can be stably operated for a long time. In addition, by forming the lid in the shape of a lens and adding the function of an optical lens, it is possible to collect or disperse the light, and take out the light to the outside of the light emitting device with a desired radiation angle and intensity distribution. The water resistance inside the device is improved, and the long-term reliability of the light emitting device is improved.

また、反射部材4は、その内側に発光素子2が搭載部1aに搭載されるとともに配線導体1bに導電性部材5を介して電気的に接続された後、少なくとも発光素子2表面を被覆するように透光性部材6が配置されてもよく(図3参照)、反射部材4の内側に発光素子2を被覆するように透光性部材6が注入されてもよい(図4参照)。これにより、発光素子2と透光性部材6との屈折率差が小さくなり、発光素子2の内部から放射される光が、発光素子2と透光性部材6との界面において反射され、発光素子2内に閉じ込められることなく外側へ取り出されやすくなる。その結果、発光素子2からの光は、透光性部材6を介して外部により放射されやすくなり、発光装置の光出力や発光効率は向上する。   In addition, the reflecting member 4 covers the at least the surface of the light emitting element 2 after the light emitting element 2 is mounted on the mounting portion 1a and is electrically connected to the wiring conductor 1b via the conductive member 5. The translucent member 6 may be disposed (see FIG. 3), or the translucent member 6 may be injected so as to cover the light emitting element 2 inside the reflective member 4 (see FIG. 4). Thereby, the difference in refractive index between the light emitting element 2 and the translucent member 6 is reduced, and the light emitted from the inside of the light emitting element 2 is reflected at the interface between the light emitting element 2 and the translucent member 6 to emit light. It becomes easy to take out outside without being confined in the element 2. As a result, the light from the light emitting element 2 is easily radiated from the outside through the translucent member 6, and the light output and light emission efficiency of the light emitting device are improved.

なお、透光性部材6が、発光素子2を被覆するように反射部材4の内側に注入される場合、透光性部材6が陽極酸化被膜4bに形成された多数の微細な穴に入り込む。その結果、透光性部材6と反射部材4との接着強度が向上し、経時変化によって生じる接着強度の劣化や剥がれが抑制され、発光装置の長期信頼性が向上する。   In addition, when the translucent member 6 is injected into the reflective member 4 so as to cover the light emitting element 2, the translucent member 6 enters a large number of fine holes formed in the anodic oxide coating 4b. As a result, the adhesive strength between the translucent member 6 and the reflective member 4 is improved, deterioration and peeling of the adhesive strength caused by changes over time are suppressed, and the long-term reliability of the light emitting device is improved.

透光性部材6は、例えばシリコーン樹脂,エポキシ樹脂,アクリル樹脂,フッ素系樹脂,ポリカーボネート樹脂,ポリイミド系樹脂等が挙げられるが、これに限定されるものではなく、基体1や反射部材4の材質や熱膨張係数等を考慮して適宜選定されればよい。なお、透光性部材6は透明である必要はなく、例えば、発光装置内の光が散乱される部材であってもよい、また発光装置内の光の波長帯において吸収が少ない材料であればよい。   Examples of the translucent member 6 include a silicone resin, an epoxy resin, an acrylic resin, a fluorine resin, a polycarbonate resin, and a polyimide resin, but are not limited thereto. And may be selected as appropriate in consideration of the thermal expansion coefficient and the like. The translucent member 6 does not need to be transparent. For example, the light transmissive member 6 may be a member that scatters light in the light-emitting device, or may be a material that absorbs less light in the wavelength band of light in the light-emitting device. Good.

また、透光性部材6は、未硬化の透光性部材6が少なくとも発光素子2の表面を被覆するように、または反射部材4の内側に発光素子2を被覆するようにディスペンサー等の注入器で注入される。その後、未硬化の透光性部材6は、加熱や自然放置または光照射されることによって硬化されて固化する。なお、透光性部材6の上部を透光性の蓋体で覆うことが必要にはなるが、液状の透光性部材6を用いてもよいことは言うまでもない。   Further, the translucent member 6 is an injector such as a dispenser so that the uncured translucent member 6 covers at least the surface of the light emitting element 2 or the inner surface of the reflecting member 4 covers the light emitting element 2. Injected with. Thereafter, the uncured translucent member 6 is cured and solidified by heating, natural standing or light irradiation. In addition, although it is necessary to cover the upper part of the translucent member 6 with a translucent cover body, it cannot be overemphasized that the liquid translucent member 6 may be used.

本発明の発光装置において、発光素子2は、紫外領域から青色領域に含まれる光を発する発光素子2であり、この発光素子2の発する光を波長変換する蛍光体(図示せず)が含まれた波長変換部材3が発光素子2の上に配置されていてもよい(図5,図6参照)。これにより、蛍光体によって波長変換された所望の波長スペクトルを有する光、または発光素子2からの光と蛍光体によって波長変換された光とを混合した所望の波長スペクトルを有する光を発光装置から放射できる。   In the light emitting device of the present invention, the light emitting element 2 is a light emitting element 2 that emits light included in the ultraviolet region to the blue region, and includes a phosphor (not shown) that converts the wavelength of light emitted from the light emitting element 2. The wavelength converting member 3 may be disposed on the light emitting element 2 (see FIGS. 5 and 6). Accordingly, light having a desired wavelength spectrum converted by the phosphor or light having a desired wavelength spectrum obtained by mixing the light from the light emitting element 2 and the light having the wavelength converted by the phosphor is emitted from the light emitting device. it can.

また、紫外領域から青色領域の短波長でエネルギーの高い発光素子2の光は、波長変換部材3に含有された蛍光体によって長波長でエネルギーの低い蛍光等に変換されるが、紫外領域から青色領域に含まれる光を変換する蛍光体は変換効率の高いものが多く、発光装置の光出力や発光効率が向上する。   The light of the light emitting element 2 having a short wavelength from the ultraviolet region to the blue region and having high energy is converted into fluorescence having a long wavelength and low energy by the phosphor contained in the wavelength conversion member 3. Many phosphors that convert light contained in a region have high conversion efficiency, and the light output and light emission efficiency of the light emitting device are improved.

また、波長変換部材3が発光素子2より離間させて配置されることにより、発光素子2から全方向に放射された光は、直接または反射部材4によって反射されて波長変換部材3に入射される。反射部材4の内周面4aによって反射される光は、内周面4aに陽極酸化被膜4bが形成されているので、拡散反射されて波長変換部材3に到達する。その結果、局所に集中することなく分散した光が波長変換部材3に満遍なく照射されることとなるために、波長変換部材3の各所で飽和することなく蛍光体固有の波長変換効率に応じた蛍光が放射され、波長変換部材3全体の変換効率が向上する。従って、発光装置の光出力や発光効率が向上するとともに、発光装置より放射される光の色ムラや色バラツキが抑制される。   In addition, since the wavelength conversion member 3 is disposed away from the light emitting element 2, the light emitted from the light emitting element 2 in all directions is reflected directly or by the reflecting member 4 and enters the wavelength conversion member 3. . The light reflected by the inner peripheral surface 4 a of the reflecting member 4 is diffusely reflected and reaches the wavelength conversion member 3 because the anodized film 4 b is formed on the inner peripheral surface 4 a. As a result, since the light dispersed without being concentrated locally is evenly applied to the wavelength conversion member 3, the fluorescence corresponding to the wavelength conversion efficiency specific to the phosphor without being saturated at various points of the wavelength conversion member 3. Is emitted, and the conversion efficiency of the entire wavelength conversion member 3 is improved. Therefore, the light output and light emission efficiency of the light emitting device are improved, and color unevenness and color variation of light emitted from the light emitting device are suppressed.

また、透光性部材6を用いる場合は、波長変換部材3は、図6に示すように透光性部材6に接触しないように空隙7を介して配置されることが好ましい。これによって、透光性部材6を硬化する際の収縮や環境温度による熱膨張によって発生する、透光性部材6との接着面における波長変換部材3の変形を抑制できる。さらに、波長変換部材3から発光素子2側に放射される一部の光は、波長変換部材3と透光性部材6との間に設けられた空隙7と波長変換部材3との界面で上方に全反射され易くなる。その結果、波長変換部材3の変形による色ムラや色バラツキが抑制されるとともに、発光装置の光出力や発光効率は向上する。   Moreover, when using the translucent member 6, it is preferable that the wavelength conversion member 3 is arrange | positioned through the space | gap 7 so that it may not contact the translucent member 6 as shown in FIG. Thereby, the deformation | transformation of the wavelength conversion member 3 in the adhesive surface with the translucent member 6 which generate | occur | produces by the shrinkage | contraction at the time of hardening the translucent member 6, or thermal expansion by environmental temperature can be suppressed. Further, a part of the light emitted from the wavelength conversion member 3 to the light emitting element 2 side is upward at the interface between the gap 7 and the wavelength conversion member 3 provided between the wavelength conversion member 3 and the translucent member 6. It becomes easy to be totally reflected. As a result, color unevenness and color variation due to deformation of the wavelength conversion member 3 are suppressed, and light output and light emission efficiency of the light emitting device are improved.

また、波長変換部材3は、紫外領域から可視光領域に含まれる光に対して透過率の高いシリコーン樹脂,エポキシ樹脂,ユリア樹脂,フッ素系樹脂等の透明樹脂や、低融点ガラス,ゾル−ゲルガラス等の透明ガラスから成る透明部材に、蛍光体を混合した未硬化のものを、平滑面または粗面のガラス板等から成る平板または曲面板上に塗布し、加熱や大気中に放置したり、光照射したりすることにより硬化させて形成される。そして、波長変換部材3は、発光素子2を覆うように反射部材4の開口部内側に設置される。   The wavelength conversion member 3 is made of a transparent resin such as a silicone resin, an epoxy resin, a urea resin, or a fluorine resin having a high transmittance with respect to light contained in the ultraviolet region to the visible light region, a low-melting glass, or a sol-gel glass. Apply a non-cured phosphor mixed with a transparent member made of transparent glass such as a flat plate or curved plate made of a smooth or rough glass plate, etc., and leave it in the air or in the atmosphere, It is formed by being cured by light irradiation. And the wavelength conversion member 3 is installed inside the opening part of the reflection member 4 so that the light emitting element 2 may be covered.

特に、波長変換部材3は、シリコーン樹脂から成ることがより好ましく、発光素子2から発せられる紫外光や近紫外光または青色光等の波長が短くエネルギーが高い光に対し、透過性がよく、分子結合が切断されにくいため、波長変換部材3の透過率の劣化が抑制され、封止信頼性に優れた発光装置を提供することができる。   In particular, the wavelength conversion member 3 is more preferably made of a silicone resin, and has good permeability to light having a short wavelength and high energy such as ultraviolet light, near ultraviolet light, or blue light emitted from the light emitting element 2, and molecules Since the bond is not easily broken, the deterioration of the transmittance of the wavelength conversion member 3 is suppressed, and a light emitting device having excellent sealing reliability can be provided.

なお、蛍光体は、様々な材料が用いられ、例えば赤色蛍光色を得る場合はLaS:Eu(EuドープLaS)の蛍光体やLiEuW、緑色の場合はZnS:Cu,AlやSrAl:Euの蛍光体、青色の場合は(BaMgAl)1012:EuやBaMgAl1017:Euの蛍光体等の粒子状のものが用いられる。さらに、このような蛍光体は1種類に限らず、複数のものを所要の割合で配合することにより、所望の発光スペクトルと色を有する光を出力することができる。 Various materials are used as the phosphor. For example, when a red fluorescent color is obtained, a phosphor of La 2 O 2 S: Eu (Eu-doped La 2 O 2 S), LiEuW 2 O 8 , or green is used. A phosphor in the form of ZnS: Cu, Al or SrAl 2 O 4 : Eu, or in the case of blue, particles in the form of (BaMgAl) 10 O 12 : Eu or BaMgAl 10 O 17 : Eu are used. Furthermore, such a phosphor is not limited to one type, and a light having a desired emission spectrum and color can be output by blending a plurality of phosphors at a required ratio.

また、発光素子2は、白色光や種々の色の光を発光装置から視感性よく放射させるという観点から200乃至500nmの波長範囲の紫外光から近紫外光および青色光の範囲に発光のピーク強度を有する素子であるのがよい。例えば、サファイア基板上にガリウム(Ga)−窒素(N),Al−Ga−N,インジウム(In)−GaN等から構成されるバッファ層,N型層,発光層,P型層を順次積層した窒化ガリウム系化合物半導体やシリコンカーバイド(SiC)系化合物半導体、酸化亜鉛系化合物半導体やセレン化亜鉛系化合物半導体またはダイヤモンド系化合物半導体や窒化ホウ素系化合物半導体等が用いられる。蛍光体を用いない赤色、黄色、緑色発光の発光素子2を用いる発光装置であってもよいことは言うまでもない。   In addition, the light emitting element 2 emits white light and various colors of light from the light emitting device with good visibility, and emits light with a peak intensity from ultraviolet light in the wavelength range of 200 to 500 nm to near ultraviolet light and blue light. It is preferable that the element has For example, a buffer layer composed of gallium (Ga) -nitrogen (N), Al-Ga-N, indium (In) -GaN, etc., an N-type layer, a light-emitting layer, and a P-type layer are sequentially stacked on a sapphire substrate. A gallium nitride compound semiconductor, a silicon carbide (SiC) compound semiconductor, a zinc oxide compound semiconductor, a zinc selenide compound semiconductor, a diamond compound semiconductor, a boron nitride compound semiconductor, or the like is used. It goes without saying that the light emitting device using the red, yellow, and green light emitting elements 2 that do not use a phosphor may be used.

なお、発光素子2から発生する光の紫外領域とは、可視光の短波長端360〜400nmを下限とし、上限は1nmくらいまでの波長範囲の電磁波とする(理化学事典第5版/岩波書店)。また、青色領域とは、可視光の短波長端360〜400nmを上限とし、下限は495nmくらいまでの波長範囲とする(JIS Z8701 XYZ表色系の色度座標)。   In addition, the ultraviolet region of the light generated from the light emitting element 2 is the electromagnetic wave having a wavelength range of up to about 1 nm with the short wavelength end of 360 to 400 nm of visible light as the lower limit (RIKEN KENSHU 5th edition / Iwanami Shoten) . The blue region has an upper limit of the short wavelength end of 360 to 400 nm of visible light and a lower limit of a wavelength range up to about 495 nm (chromaticity coordinates of JIS Z8701 XYZ color system).

なお、発光素子2は、その電極がAu−Sn,Sn−Ag,Sn−Ag−CuまたはSn−Pb等のロウ材や半田を用いた金属バンプ、またはAuやAg等の金属を用いた金属バンプ、エポキシ樹脂等の樹脂にAg等の金属粉末を含有して成る導電性樹脂から成る導電性部材5を介してフリップチップ実装によって配線導体1bに電気的に接続される。例えば、配線導体1b上にペースト状のAu−SnやPb−Sn等の半田材やAgペースト等からなる導電性部材5がディスペンサー等を用いて載置され、発光素子2は発光素子2の電極と導電性部材5とが接触するように搭載され、その後、全体が150℃〜350℃程度で加熱されることにより、発光素子2の電極と配線導体1bとが導電性部材5によって電気的に接続された発光装置を作製する。また、配線導体1bおよび発光素子2の電極を、例えば、ボンディングワイヤ等の導電性部材5で電気的に接続する方法を用いてもよく、フリップチップ実装しか用いることができないものではない。   The light emitting element 2 has a metal bump using a solder material such as Au-Sn, Sn-Ag, Sn-Ag-Cu, or Sn-Pb, or a metal bump, or a metal using a metal such as Au or Ag. It is electrically connected to the wiring conductor 1b by flip chip mounting through a conductive member 5 made of a conductive resin made of a resin such as a bump and an epoxy resin containing a metal powder such as Ag. For example, the conductive member 5 made of a solder material such as paste Au—Sn or Pb—Sn or Ag paste or the like is placed on the wiring conductor 1 b using a dispenser or the like, and the light emitting element 2 is an electrode of the light emitting element 2. And the conductive member 5 are brought into contact with each other, and then the whole is heated at about 150 ° C. to 350 ° C., whereby the electrode of the light emitting element 2 and the wiring conductor 1b are electrically connected by the conductive member 5. A connected light emitting device is manufactured. Further, a method of electrically connecting the wiring conductor 1b and the electrodes of the light emitting element 2 with a conductive member 5 such as a bonding wire may be used, and only flip chip mounting can be used.

また、本発明の照明装置は、上記本発明の発光装置と、発光装置が搭載され、発光装置を駆動する電気配線を有する駆動部と、発光装置から出射される光を反射する光反射手段とを含むものである。本発明の発光装置は輝度が高く、放射される光の波長等の変動および強度むらが抑制されたものであることにより、それらを集めて照明装置とした本発明の照明装置の強度むらも抑制され、輝度の高いものとなる。   The lighting device of the present invention includes the light emitting device of the present invention, a drive unit on which the light emitting device is mounted and having electric wiring for driving the light emitting device, and a light reflecting means for reflecting light emitted from the light emitting device. Is included. The light-emitting device of the present invention has high brightness, and fluctuations in the wavelength of emitted light and unevenness in intensity are suppressed, so that the unevenness in intensity of the illumination device of the present invention obtained by collecting them is also suppressed. As a result, the luminance becomes high.

本発明の照明装置において、例えば、図7,図8に示されるように、一個の発光装置101を所定の配置となるように設置したり、または、複数個の発光装置101を、例えば、格子状や千鳥状、放射状等の所定の配置となるように設置したりしてもよい。あるいは、複数の発光装置101から成る円形状や多角形状の発光装置101群を同心状に複数群形成したもの等を所定の配置となるように設置してもよい。   In the illumination device of the present invention, for example, as shown in FIGS. 7 and 8, one light emitting device 101 is installed in a predetermined arrangement, or a plurality of light emitting devices 101 are arranged in, for example, a grid. Or a predetermined arrangement such as a zigzag pattern, a zigzag pattern, or a radial pattern. Or you may install so that the circular shape which consists of the several light-emitting device 101, or the polygonal-shaped light-emitting device 101 group may form several groups concentrically, etc. may become predetermined arrangement | positioning.

図7(a)は本発明の発光装置を用いた照明装置の平面図、図7(b)は(a)の断面図を示す。複数個の発光装置101が発光装置101を駆動するための電気配線を有する駆動部102上に複数列に配置され、発光装置101の周囲に任意の形状に光学設計された光を反射する反射板等の光反射手段103が設置されてなる発光装置の場合、隣り合う発光装置101との間隔が最短にならない配置、例えば一列に配置された複数個の発光装置101の間に隣り合う列の発光装置101が配置された配置、いわゆる千鳥状の配置とすることが好ましい。即ち、発光装置101が格子状に配置される場合には、発光装置101が縦横直線状の格子に配列されることによりグレアが強くなり、このような発光装置101が人の視覚に入ってくることにより、不快感を起こしやすくなるのに対し、千鳥状とすることにより、グレアが抑制され人の眼に対する不快感を低減することができる。さらに、隣り合う発光装置101間の距離が長くなることにより、隣接する発光装置101間の熱的な干渉が有効に抑制され、発光装置101が実装された駆動部102内における熱のこもりが抑制され、発光装置101の外部に効率よく熱が放散される。その結果、人の眼に対して不快感が小さく、長期間にわたって光学特性の安定した長寿命の照明装置を作製することができる。   FIG. 7A is a plan view of a lighting device using the light-emitting device of the present invention, and FIG. 7B is a cross-sectional view of FIG. A plurality of light emitting devices 101 are arranged in a plurality of rows on a drive unit 102 having electric wiring for driving the light emitting devices 101, and a reflecting plate that reflects light optically designed in an arbitrary shape around the light emitting devices 101 In the case of the light emitting device in which the light reflecting means 103 such as the light emitting device is installed, the arrangement in which the interval between the adjacent light emitting devices 101 is not shortest, for example, the light emission in the adjacent rows between the plurality of light emitting devices 101 arranged in a row. An arrangement in which the apparatus 101 is arranged, that is, a so-called staggered arrangement is preferable. That is, when the light emitting devices 101 are arranged in a grid, glare is strengthened by arranging the light emitting devices 101 in a vertical and horizontal linear grid, and such a light emitting device 101 enters human vision. Thus, discomfort is likely to occur, but the staggered shape can suppress glare and reduce discomfort to the human eye. Further, since the distance between the adjacent light emitting devices 101 is increased, thermal interference between the adjacent light emitting devices 101 is effectively suppressed, and heat accumulation in the drive unit 102 in which the light emitting devices 101 are mounted is suppressed. Then, heat is efficiently dissipated outside the light emitting device 101. As a result, it is possible to manufacture a long-life lighting device that is less uncomfortable for human eyes and has stable optical characteristics over a long period of time.

また、図8(a)の平面図およびその断面図である図8(b)に示すように、駆動部102上に複数の発光装置101からなる円形状や多角形状の発光装置101群を、同心状に複数群形成した発光装置の場合、一つの円形状や多角形状の発光装置101群における発光装置101の配置数を発光装置の中央側より外周側ほど多くすることが好ましい。これにより、発光装置101同士の間隔を適度に保ちながら発光装置101をより多く配置することができ、発光装置の照度をより向上させることができる。また、照明装置の中央部の発光装置101の密度を低くして駆動部102の中央部における熱のこもりを抑制することができる。その結果、駆動部102内における温度分布が一様となり、照明装置を設置した外部電気回路基板やヒートシンクに効率よく熱が伝達され、発光装置101の温度上昇を抑制することができ、発光装置101は長期間にわたり安定して動作することができるとともに長寿命の照明装置を作製することができる。   Further, as shown in a plan view of FIG. 8A and a cross-sectional view of FIG. 8B, a circular or polygonal light emitting device 101 group composed of a plurality of light emitting devices 101 on a drive unit 102 is provided. In the case of light-emitting devices formed in a plurality of concentric groups, it is preferable to increase the number of light-emitting devices 101 arranged in one circular or polygonal light-emitting device 101 group from the center side to the outer peripheral side of the light-emitting device. Thereby, it is possible to arrange more light emitting devices 101 while maintaining an appropriate interval between the light emitting devices 101, and it is possible to further improve the illuminance of the light emitting devices. In addition, the density of the light emitting device 101 at the center of the lighting device can be reduced to suppress heat accumulation at the center of the drive unit 102. As a result, the temperature distribution in the drive unit 102 becomes uniform, heat is efficiently transmitted to the external electric circuit board or heat sink on which the lighting device is installed, and the temperature rise of the light emitting device 101 can be suppressed. Can operate stably over a long period of time and can produce a long-life lighting device.

このような発光装置を用いた照明装置としては、例えば、室内や室外で用いられる、一般照明用器具、シャンデリア用照明器具、住宅用照明器具、オフィス用照明器具、店装、展示用照明器具、街路灯用照明器具、誘導灯器具および信号装置、舞台およびスタジオ用の照明器具、広告灯、照明用ポール、水中照明用ライト、ストロボ用ライト、スポットライト、電柱等に埋め込む防犯用照明、非常用照明器具、懐中電灯、電光掲示板等や、調光器、自動点滅器、ディスプレイ等のバックライト、動画装置、装飾品、照光式スイッチ、光センサ、医療用ライト、車載ライト等が挙げられる。   Examples of the lighting device using such a light emitting device include, for example, general lighting fixtures, chandelier lighting fixtures, residential lighting fixtures, office lighting fixtures, store lighting, and display lighting fixtures that are used indoors and outdoors. Street lighting fixtures, guide lights and signaling devices, stage and studio lighting fixtures, advertising lights, lighting poles, underwater lighting lights, strobe lights, spotlights, security lights embedded in power poles, emergency use Examples include lighting fixtures, flashlights, electric bulletin boards, backlights such as dimmers, automatic flashers, displays, moving image devices, ornaments, illuminated switches, optical sensors, medical lights, vehicle lights, and the like.

なお、本発明は上記の実施の形態に限定されず、本発明の要旨を逸脱しない範囲内で種々の変更を行なうことは何等支障ない。例えば上記実施の形態例において、反射部材4の内周面4aが平面視において円形状である例を示して説明したが、円形状に限定されることはなく、四角形状やその他の多角形状、楕円形状、その他星型等の不定形状であってもよい。また、反射部材4および基体1の外周形状も円形状に限定されることはなく、その他の多角形状、四角形状や楕円形状、その他の不定形状であってもよい。また、反射部材4の断面形状が直角三角形状のブロック状に示したが、例えば板材等で錐台状に形成されたものでもよい。   It should be noted that the present invention is not limited to the above-described embodiment, and various modifications are not hindered without departing from the gist of the present invention. For example, in the embodiment described above, the inner peripheral surface 4a of the reflecting member 4 has been described as an example of a circular shape in plan view, but is not limited to a circular shape, and a rectangular shape or other polygonal shapes, It may be indefinite shape such as elliptical shape or other star shape. Further, the outer peripheral shape of the reflecting member 4 and the substrate 1 is not limited to a circular shape, and may be other polygonal shapes, quadrangular shapes, elliptical shapes, or other indefinite shapes. Moreover, although the cross-sectional shape of the reflecting member 4 is shown as a right triangle block, it may be formed in a frustum shape with a plate material or the like, for example.

また、上記実施の形態の説明において上下左右という用語は、単に図面上の位置関係を説明するために用いたものであり、実際の使用時における位置関係を意味するものではない。   In the description of the above embodiment, the terms “upper, lower, left and right” are merely used to describe the positional relationship in the drawings, and do not mean the positional relationship in actual use.

本発明の発光装置の実施の形態の一例を示す断面図である。It is sectional drawing which shows an example of embodiment of the light-emitting device of this invention. 図1の要部拡大断面図である。It is a principal part expanded sectional view of FIG. 本発明の発光装置の実施の形態の他の例を示す断面図である。It is sectional drawing which shows the other example of embodiment of the light-emitting device of this invention. 本発明の発光装置の実施の形態の他の例を示す断面図である。It is sectional drawing which shows the other example of embodiment of the light-emitting device of this invention. 本発明の発光装置の実施の形態の他の例を示す断面図である。It is sectional drawing which shows the other example of embodiment of the light-emitting device of this invention. 本発明の発光装置の実施の形態の他の例を示す断面図である。It is sectional drawing which shows the other example of embodiment of the light-emitting device of this invention. (a)は本発明の発光装置を用いた照明装置の一例を示す平面図であり、(b)は(a)の断面図である。(A) is a top view which shows an example of the illuminating device using the light-emitting device of this invention, (b) is sectional drawing of (a). (a)は本発明の発光装置を用いた照明装置の他の例を示す平面図であり、(b)は(a)の断面図である。(A) is a top view which shows the other example of the illuminating device using the light-emitting device of this invention, (b) is sectional drawing of (a). 従来の発光装置の一例を示す断面図である。It is sectional drawing which shows an example of the conventional light-emitting device.

符号の説明Explanation of symbols

1:基体
2:発光素子
3:波長変換部材
4:反射部材
4a:内周面
4b:陽極酸化被膜
5:導電性部材
6:透光性部材
1: Base body 2: Light emitting element 3: Wavelength conversion member 4: Reflective member 4a: Inner peripheral surface 4b: Anodized film 5: Conductive member 6: Translucent member

Claims (3)

上面に発光素子の搭載部を有する基体と、該基体の上面に、前記搭載部を取り囲むように設けられた反射部材と、前記搭載部に搭載された発光素子とを具備している発光装置において、前記反射部材はアルミニウムから成り、内周面に陽極酸化被膜が形成されていることを特徴とする発光装置。 In a light emitting device comprising: a base having a light emitting element mounting portion on an upper surface; a reflecting member provided on the upper surface of the base so as to surround the mounting portion; and a light emitting element mounted on the mounting portion. The light-emitting device is characterized in that the reflecting member is made of aluminum, and an anodized film is formed on the inner peripheral surface. 前記発光素子は、紫外領域から青色領域に含まれる光を発する発光素子であり、該発光素子の発する光を波長変換する蛍光体が含まれた波長変換部材が前記発光素子の上に配置されていることを特徴とする請求項1に記載の発光装置。 The light-emitting element is a light-emitting element that emits light included in an ultraviolet region to a blue region, and a wavelength conversion member including a phosphor that converts the wavelength of light emitted from the light-emitting element is disposed on the light-emitting element. The light-emitting device according to claim 1. 請求項1または請求項2のいずれかに記載の発光装置と、前記発光装置が搭載され、前記発光装置を駆動する電気配線を有する駆動部と、前記発光装置から出射される光を反射する光反射手段とを含む照明装置。 The light-emitting device according to claim 1, the light-emitting device mounted thereon, a drive unit having electric wiring for driving the light-emitting device, and light that reflects light emitted from the light-emitting device A lighting device including reflecting means;
JP2006090194A 2006-03-29 2006-03-29 Light emitting device and lighting device Pending JP2007266358A (en)

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