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JP2007119899A - 490 MPa class low yield ratio cold-formed steel pipe excellent in weldability and manufacturing method thereof - Google Patents

490 MPa class low yield ratio cold-formed steel pipe excellent in weldability and manufacturing method thereof Download PDF

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JP2007119899A
JP2007119899A JP2006046739A JP2006046739A JP2007119899A JP 2007119899 A JP2007119899 A JP 2007119899A JP 2006046739 A JP2006046739 A JP 2006046739A JP 2006046739 A JP2006046739 A JP 2006046739A JP 2007119899 A JP2007119899 A JP 2007119899A
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Mitsuaki Shibata
光明 柴田
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Kobe Steel Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/10Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of tubular bodies
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/50Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium

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Abstract

【課題】SR処理を施すことなく、引張強さが490MPa以上で低降伏比の冷間成形鋼管、およびこうした冷間成形鋼管を製造するための有用な方法を提供する。
【解決手段】所定の化学成分組成を有し、鋼板のミクロ組織が、4〜70面積%のポリゴナルフェライト相、0〜20面積%の擬ポリゴナルフェライト相、および0〜5面積%で、アスペクト比(長径/短径)が4.0以下のマルテンサイト相、残部がベイナイト相から構成され、板厚をt(mm)、外側冷間曲げ直径をd(mm)としたときにt/dが10%以下である冷間成形部位を有するものである。
【選択図】なし
A cold-formed steel pipe having a tensile strength of 490 MPa or more and a low yield ratio without performing SR treatment, and a useful method for producing such a cold-formed steel pipe.
The steel sheet has a predetermined chemical composition, and the microstructure of the steel sheet is 4 to 70 area% of a polygonal ferrite phase, 0 to 20 area% of a pseudopolygonal ferrite phase, and 0 to 5 area%. When the aspect ratio (major axis / minor axis) is composed of a martensite phase of 4.0 or less and the balance is composed of a bainite phase, the thickness is t (mm) and the outer cold bending diameter is d (mm). It has a cold-formed part whose d is 10% or less.
[Selection figure] None

Description

本発明は、溶接性に優れ低降伏比で引張強さが490MPa級の冷間成形鋼管、およびその製造方法に関するものであり、特に耐震性に優れたCFT(Concrete-Filled Tube)構造の建築物に好適に用いることのできる490MPa級の冷間成形鋼管、およびこうした冷間成形鋼管を製造するための有用な方法に関するものである。   The present invention relates to a cold-formed steel pipe excellent in weldability and having a low yield ratio and a tensile strength of 490 MPa, and a method for producing the same, and particularly a building having a CFT (Concrete-Filled Tube) structure excellent in earthquake resistance. The present invention relates to a 490 MPa grade cold-formed steel pipe that can be suitably used for the present invention, and a useful method for producing such a cold-formed steel pipe.

建築構造物には、優れた耐震性や耐火性が要求されており、特に耐震性に優れた上記CFT構造の建築物を構築するには、高強度、低降伏比で優れた溶接性を発揮する冷間成型鋼管が必要になる。   Building structures are required to have excellent seismic resistance and fire resistance. To build buildings with the above-mentioned CFT structure, which are particularly excellent in earthquake resistance, they exhibit excellent weldability with high strength and low yield ratio. Cold forming steel pipe is required.

こうした要求特性を満足する冷間成形用鋼管に関する技術として、これまで様々なものが提案されている。例えば、特許文献1には、600MPa級および800MPa級の低降伏比鋼管を対象として、熱間圧延後、空冷或いは水冷した鋼板を、t/D(t:板厚、D:鋼管外径)≦10%の範囲で冷間成形により鋼管を製作し、降伏比(YR)≦80−0.8×t/Dに制御した鋼板を、その後750〜850℃の温度範囲で焼ならしをする技術について開示されている。   Various techniques for cold forming steel pipes that satisfy these required characteristics have been proposed so far. For example, in Patent Document 1, steel plates that have been subjected to hot rolling and then air-cooled or water-cooled for 600 MPa class and 800 MPa class low yield ratio steel pipes are expressed as t / D (t: plate thickness, D: steel pipe outer diameter) ≦ Technology to manufacture steel pipes by cold forming in the range of 10% and normalize the steel sheet controlled to the yield ratio (YR) ≦ 80−0.8 × t / D in the temperature range of 750 to 850 ° C. Is disclosed.

また特許文献2には、590MPa級の低降伏比の鋼管を対象として、圧延仕上げ温度:(Ar−20℃)〜(Ar+120℃)となるように圧延を行った後、鋼板を(Ar−100℃)〜(Ar−120℃)まで空冷し、引き続きこの温度から直ちに常温まで焼入れし、更にAc点以下の温度範囲まで焼き戻し処理を行い、上記t/D≦10%の範囲で管状に冷間成形し、その後500〜600℃の温度範囲で焼鈍することについて開示されている。 Further, in Patent Document 2, a steel pipe having a low yield ratio of 590 MPa class is subjected to rolling so that the rolling finish temperature is (Ar 3 −20 ° C.) to (Ar 3 + 120 ° C.), and then the steel plate ( Ar 3 −100 ° C.) to (Ar 3 −120 ° C.), followed by quenching immediately from this temperature to room temperature, and further tempering to a temperature range of Ac 1 point or less, and the above t / D ≦ 10% Is cold formed into a tube in the range of, and then annealed in a temperature range of 500 to 600 ° C.

更に、特許文献3には、590MPa級の低降伏比鋼管を対象として、Ac点以上の温度に再加熱して焼入れ或いは焼入れ・焼き戻しを行い、上記t/D≦10%の範囲で冷間成形を施して鋼管を製作し、その後650〜750℃の温度範囲に再加熱して焼きならしすることについて開示されている。 Furthermore, in Patent Document 3, for a 590 MPa class low yield ratio steel pipe, it is reheated to a temperature of Ac 3 point or higher and quenched or tempered and tempered, and cooled in the above range of t / D ≦ 10%. It is disclosed that a steel pipe is manufactured by performing inter-forming and then reheated to a temperature range of 650 to 750 ° C. to normalize.

上記各技術は、いずれも590MPa級の低降伏比の冷間成形鋼管を対象とするものであるが、このうち特許文献1では、冷間成形後、焼ならしをするものである。特許文献2では、圧延ライン上で二相域まで空冷するものであるので、圧延における生産性低下を招くことになり、経済的な観点から好ましくない。   Each of the above technologies is directed to a cold-formed steel pipe having a low yield ratio of 590 MPa, and among them, Patent Document 1 performs normalization after cold forming. In patent document 2, since it cools to a two-phase area | region on a rolling line, it will cause the productivity fall in rolling and is not preferable from an economical viewpoint.

上記特許文献3の技術では、鋼素材にCu,Ni等の元素を必須成分として含有するものであるので、素材コストが高くなるという問題がある。また、この技術ではCu添加による析出強化によって鋼管の強度向上を図っているが、熱処理工程において外面側と内面側の温度が不均一になり、Cuの析出にむらを生じるので、材質のバラツキが発生するということが十分予想される。   In the technique of the above-mentioned patent document 3, since the steel material contains elements such as Cu and Ni as essential components, there is a problem that the material cost is increased. In this technique, the strength of the steel pipe is improved by precipitation strengthening due to the addition of Cu, but the temperature on the outer surface side and the inner surface side becomes uneven in the heat treatment process, causing unevenness in the precipitation of Cu. It is expected that it will occur.

上記いずれの技術においても、冷間成形後には、降伏比の低減を目的として、熱処理を施す必要があり、コスト面および生産性の点で問題がある。また、上記特許文献2の所謂Delay DQ法を適用すると、Ar点以上の温度からの直接焼入れ(DQ)に比べて焼入れままの強度が低くなるので、それを補填するために合金元素を増量する必要があり、その結果溶接性が劣化することになる。 In any of the above techniques, after cold forming, it is necessary to perform heat treatment for the purpose of reducing the yield ratio, and there are problems in terms of cost and productivity. In addition, when the so-called Delay DQ method of Patent Document 2 is applied, the strength as quenched is lower than direct quenching (DQ) from a temperature of three or more points of Ar, so the alloy element is increased to compensate for it. As a result, weldability deteriorates.

こうしたことから、冷間成形後に熱処理を施さない方法として、特許文献4のような技術も提案されている、この技術では、熱間圧延後にAc〜1000℃に再加熱して焼入れし、引き続き700〜850℃の温度に再加熱して焼入れし、Ac点以下で焼戻し処理を行い、且つYR(%)≦80−0.8×t/Dに制御する鋼板を用いて、t/D≦10%の範囲で冷間成形によって鋼管を製作するものであり、これによって板厚:100mm以下、管軸方向のYRが80%以下である建築用低降伏比600MPa級鋼管を得るものである。 Therefore, as a method of not performing heat treatment after cold forming, a technique such as Patent Document 4 has also been proposed. In this technique, after hot rolling, it is reheated to Ac 3 to 1000 ° C. and quenched. Using a steel plate that is reheated to 700 to 850 ° C. and quenched, tempered at Ac 1 point or less, and controlled to YR (%) ≦ 80−0.8 × t / D, t / D A steel pipe is manufactured by cold forming in a range of ≦ 10%, thereby obtaining a low yield ratio 600 MPa class steel pipe for construction having a sheet thickness of 100 mm or less and a YR in the pipe axis direction of 80% or less. .

この技術は、600MPa級の低降伏比鋼管を対象とするものであり、圧延後に組織をベイナイト化するための再加熱焼入れ、鋼管の靭性改善と、溶接、応力除去処理等による軟化を防止するための焼戻しを必須工程とするものであり、生産性やコストの点からして若干の問題が残っている。しかも、この技術では、強度確保という観点から、合金元素の増量が必要であり、溶接性の点で依然として問題がある。   This technology is intended for 600MPa class low-yield ratio steel pipes to prevent softening due to reheating and quenching, steel pipe toughness improvement, welding, stress relief treatment, etc. Is an essential process, and some problems remain in terms of productivity and cost. Moreover, this technique requires an increase in the amount of alloy elements from the viewpoint of securing strength, and still has a problem in terms of weldability.

一方、490MPa級の低降伏比高張力鋼板の製造方法として、例えば特許文献5のような技術も提案されている。この技術では、900℃以下における累積圧下率が50%以上となるように圧延し、且つAr点以上で圧延を終了し、Ac点以下に冷却した後、730〜850℃以下の範囲に再加熱し、空冷するものである。 On the other hand, for example, a technique as disclosed in Patent Document 5 has been proposed as a method for producing a 490 MPa class low yield ratio high tensile steel sheet. In this technique, rolling is performed so that the cumulative rolling reduction at 900 ° C. or less is 50% or more, and rolling is finished at Ar 3 points or more, cooling to Ac 1 point or less, and then within a range of 730 to 850 ° C. or less. It is reheated and air cooled.

この技術では、二相域温度(Ac点超え、Ac点未満)からの焼入れ(Q’)処理したものに比べて、強度が低いものとなるので、炭素当量Ceq(JIS)が0.40%以下で溶接性が良好なものは、32mm程度までの板厚に適用できるが(例えば、表1の鋼No.1,2,4〜6)、冷間成形用の厚物鋼管に適用しようとすれば炭素当量Ceqを大幅に上げる必要があり(例えば表1のNo.3)、それに伴って溶接性が劣化し、予熱が必要になる。しかも、オーステナイト未再結晶域(約900〜Ar点)での圧下率を大きくするため、建築用鋼に要求される音響異方性が小さいという要件を満足しないものとなる。
特開平6−128641号公報 特許請求の範囲等 特許第2529042号公報 特許請求の範囲等 特開平7−233416号公報 特許請求の範囲等 特開平7−109521号公報 特許請求の範囲等 特開昭55−115921号公報 特許請求の範囲、表1等
In this technique, since the strength is lower than that obtained by quenching (Q ′) treatment from a two-phase region temperature (Ac 1 point and less than Ac 3 point), the carbon equivalent Ceq (JIS) is 0.00. Those with good weldability at 40% or less can be applied to plate thicknesses up to about 32 mm (for example, steel Nos. 1, 2, 4 to 6 in Table 1), but are applied to thick steel pipes for cold forming. If it is going to be, it is necessary to raise carbon equivalent Ceq significantly (for example, No. 3 of Table 1), weldability deteriorates in connection with it, and preheating is needed. Moreover, in order to increase the rolling reduction in the austenite non-recrystallized region (about 900 to Ar 3 points), the requirement that the acoustic anisotropy required for the steel for construction is small is not satisfied.
Japanese Patent Application Laid-Open No. 6-128641 Japanese Patent No. 2529042 Patent Claim etc. JP, 7-233416, A Claims etc. Japanese Patent Laid-Open No. 7-109521 Japanese Patent Laid-Open No. 55-115921 Claims, Table 1, etc.

ところで、新耐震設計法の改正(1981年)によって、建築分野では大地震時に鋼材の塑性変形を許容し、地震のエネルギーを吸収して構造物の倒壊を防止するという設計概念が高層建築物を中心に取り入れられるようになり、そのために鋼材に必要な特性として低降伏比が求められるようになってきた。   By the way, with the revision of the new seismic design method (1981), the design concept of allowing the plastic deformation of steel materials in the case of a large earthquake and absorbing the energy of the earthquake to prevent the collapse of the structure in the building field As a result, a low yield ratio has been required as a necessary characteristic for steel materials.

コンクリート充填鋼管柱に適用される冷間成形鋼管では、t/D:5〜10%という厳しい冷間曲げが加わった場合、t/4部で約2.5〜5%相当の歪み(ε)が付与されることになるので、降伏応力が上昇し、引張強さが490MPa級の鋼材であっても目標降伏比(降伏点/引張強さ)である85%以下を確保することができない。こうした場合には、冷間成形後に残留応力の除去を目的とした焼鈍(Stress Relieving:SR処理)を施さざるを得ず、高コスト化、工期の長期化および生産性の低下を招いていた。   In cold-formed steel pipes applied to concrete-filled steel pipe columns, when severe cold bending of t / D: 5 to 10% is applied, a strain (ε) equivalent to about 2.5 to 5% at t / 4 part Therefore, even if it is a steel material having a tensile strength of 490 MPa class, the target yield ratio (yield point / tensile strength) of 85% or less cannot be ensured. In such a case, annealing (Stress Relieving: SR treatment) for the purpose of removing residual stress after cold forming is unavoidable, resulting in higher costs, longer construction periods, and lower productivity.

本発明は、こうした状況の下でなされたものであって、その目的は、SR処理を施すことなく、引張強さが490MPa以上で低降伏比の冷間成形鋼管、およびこうした冷間成形鋼管を製造するための有用な方法を提供することにある。   The present invention has been made under such circumstances, and an object of the present invention is to provide a cold-formed steel pipe having a tensile strength of 490 MPa or more and a low yield ratio without performing SR treatment, and such a cold-formed steel pipe. It is to provide a useful method for manufacturing.

上記目的を達成し得た本発明の490MPa級低降伏比冷間成形鋼管とは、C:0.07〜0.18%(質量%の意味、以下同じ)、Si:0.05〜1.0%、Mn:0.7〜1.7%(但し、Mn含有量[Mn]とC含有量[C]の比[Mn]/[C]≦15)、Ti:0.002〜0.025%、sol.Al:0.005〜0.1%およびN:0.001〜0.008%を夫々含有する他、Cr:0.6%以下(0%を含む)、Mo:0.5%以下(0%を含む)およびV:0.08%以下(0%を含む)よりなる群から選ばれる1種または2種以上を含み、下記(1)式で示される炭素当量Ceq値が0.34〜0.42%の範囲内にあると共に、下記(2)式で示されるA値が1.1〜2.6を満足し、残部がFeおよび不可避的不純物からなる化学成分組成を有する鋼板からなり、且つ当該鋼板のミクロ組織が、4〜70面積%のポリゴナルフェライト相、0〜20面積%の擬ポリゴナルフェライト相、および0〜5面積%で、アスペクト比(長径/短径)が4.0以下の島状マルテンサイト相、残部がベイナイト相から構成され、板厚をt(mm)、外側冷間曲げ直径をd(mm)としたときにt/dが10%以下である冷間成形部位を有するものである点に要旨を有するものである。
Ceq=[C]+[Si]/24+[Mn]/6+[Ni]/40+[Cr]/5
+[Mo]/4+[V])/15 …(1)
但し、[C],[Si],[Mn],[Ni],[Cr],[Mo]および[V]は、夫々C,Si,Mn,Ni,Cr,MoおよびVの含有量(質量%)を示す。
A=(2.16{Cr}+1)×(3.0{Mo}+1)×(1.75{V}+1) …(2)
但し、{Cr},{Mo}および{V}は、夫々Cr,MoおよびVにおける鋼板中の固溶量(質量%)を示す。
The 490 MPa class low yield ratio cold-formed steel pipe of the present invention capable of achieving the above object is C: 0.07 to 0.18% (meaning of mass%, the same shall apply hereinafter), Si: 0.05 to 1. 0%, Mn: 0.7 to 1.7% (provided that the ratio of Mn content [Mn] to C content [C] [Mn] / [C] ≦ 15), Ti: 0.002 to 0.8%. 025%, sol. In addition to containing Al: 0.005 to 0.1% and N: 0.001 to 0.008%, Cr: 0.6% or less (including 0%), Mo: 0.5% or less (0 %) And V: 0.08% or less (including 0%), including one or more selected from the group consisting of carbon equivalent Ceq values of 0.34 to It is within the range of 0.42%, and the A value shown by the following formula (2) satisfies 1.1 to 2.6, and the balance is made of a steel plate having a chemical composition composed of Fe and inevitable impurities. And the microstructure of the steel sheet is 4 to 70 area% of polygonal ferrite phase, 0 to 20 area% of pseudopolygonal ferrite phase, and 0 to 5 area%, and the aspect ratio (major axis / minor axis) is 4. 0.0 or less island martensite phase, the balance is composed of bainite phase, It has a gist in that it has a cold forming portion where t / d is 10% or less when t (mm) and the outer cold bending diameter is d (mm).
Ceq = [C] + [Si] / 24 + [Mn] / 6 + [Ni] / 40 + [Cr] / 5
+ [Mo] / 4 + [V]) / 15 (1)
However, [C], [Si], [Mn], [Ni], [Cr], [Mo] and [V] are the contents (mass of C, Si, Mn, Ni, Cr, Mo and V, respectively). %).
A = (2.16 {Cr} +1) × (3.0 {Mo} +1) × (1.75 {V} +1) (2)
However, {Cr}, {Mo} and {V} indicate the amount of solid solution (mass%) in the steel sheet in Cr, Mo and V, respectively.

本発明の冷間成形鋼管には、必要によって、更に(a)Cu:0.5%以下(0%を含まない)および/またはNi:3.0%以下(0%を含まない)、(b)Nb:0.015%以下(0%を含まない)、(c)Ca:0.003%以下(0%を含まない)、(d)希土類元素:0.02%以下(0%を含まない)、等を含有することも有効であり、これら含有される成分に応じて鋼管の特性を更に向上させることができる。   In the cold-formed steel pipe of the present invention, if necessary, (a) Cu: 0.5% or less (not including 0%) and / or Ni: 3.0% or less (not including 0%), ( b) Nb: 0.015% or less (not including 0%), (c) Ca: 0.003% or less (not including 0%), (d) Rare earth element: 0.02% or less (0% It is also effective to contain (not contained), etc., and the characteristics of the steel pipe can be further improved according to these contained components.

上記のような冷間成形鋼管を製造するに当っては、本発明で規定する化学成分組成を有する鋼片を950〜1250℃の温度範囲に加熱し、下記(3)式で示されるオーステナイト未再結晶化温度Aγ(℃)以下での累積圧下率を60%以下(0%を含む)として圧延を終了して鋼板とした後、Ar変態点以上の温度から450℃以下まで4〜100℃/秒の冷却速度で加速冷却し、次いで730〜830℃の温度範囲に再加熱してから焼入れし、引き続き前記載t/dが10%以下の範囲で冷間成形するようにすれば良い。
γ(℃)=887+467[C]+(6445[Nb]−644√[Nb])+
(732[V]−230√[V])+890[Ti]+363[Al]−357[Si]
…(3)
但し、[C],[Nb],[V],[Ti],[Al]および[Si]は、夫々C,Nb,V,Ti,AlおよびSiの含有量(質量%)を示す。
In producing the cold-formed steel pipe as described above, a steel piece having a chemical composition defined in the present invention is heated to a temperature range of 950 to 1250 ° C., and austenite-free steel represented by the following formula (3) is used. After the rolling was finished by setting the cumulative reduction ratio below the recrystallization temperature A γ (° C.) to 60% or less (including 0%) to form a steel plate, the temperature from the Ar 3 transformation point or higher to 450 ° C. or lower was 4 to 4 ° C. Accelerated cooling at a cooling rate of 100 ° C./second, then reheating to a temperature range of 730 to 830 ° C., followed by quenching, followed by cold forming with a t / d of 10% or less. good.
A γ (° C.) = 887 + 467 [C] + (6445 [Nb] −644√ [Nb]) +
(732 [V] -230√ [V]) + 890 [Ti] +363 [Al] -357 [Si]
... (3)
However, [C], [Nb], [V], [Ti], [Al], and [Si] indicate the contents (mass%) of C, Nb, V, Ti, Al, and Si, respectively.

この製造方法においては、(1)730〜830℃の温度範囲に再加熱してから焼入れした後、前記鋼板を500℃以下で焼戻しを施す、(2)前記圧延を終了した後、加速冷却するに先立ち、オンラインレベラ矯正を行う、(3)鋼板温度を400℃以下として冷間成形する、等の条件を付加することが好ましい。   In this manufacturing method, (1) after reheating to a temperature range of 730 to 830 ° C. and quenching, the steel sheet is tempered at 500 ° C. or less. (2) After the rolling is finished, accelerated cooling is performed. Prior to, it is preferable to add conditions such as performing online leveler correction, (3) cold forming with a steel plate temperature of 400 ° C. or lower.

本発明によれば、鋼板の化学成分組成を適正に調整すると共に、ミクロ組織中の各相の体積分率を適切に制御することによって、SR処理を施さずとも、低降伏比で490MPa級の冷間成形鋼管を得ることができ、こうした冷間成形鋼管は製造条件を適切に制御することによって得られるものであり、得られた鋼管は、CFT構造の建築物に好適に用いることができる。   According to the present invention, by appropriately adjusting the chemical composition of the steel sheet and appropriately controlling the volume fraction of each phase in the microstructure, the 490 MPa class with a low yield ratio can be obtained without performing SR treatment. A cold-formed steel pipe can be obtained, and such a cold-formed steel pipe is obtained by appropriately controlling manufacturing conditions, and the obtained steel pipe can be suitably used for a building having a CFT structure.

本発明者らは、板厚をt(mm)、外側冷間曲げ直径をd(mm)としたときにt/dが10%以下である冷間成形部位を有し、引張強さが490MPa以上の鋼管において、溶接性に優れ、且つ降伏比を目標値である85%以下を達成するために、化学成分組成やミクロ組織について、詳細に検討した。   The present inventors have a cold-formed portion where t / d is 10% or less when the plate thickness is t (mm) and the outer cold bending diameter is d (mm), and the tensile strength is 490 MPa. In the above steel pipe, in order to achieve excellent weldability and to achieve a yield ratio of 85% or less, which is a target value, the chemical composition and the microstructure were examined in detail.

その結果、鋼管における降伏比を低減させるためには、鋼板段階での降伏比を予め鋼管での上昇分以上下げておくこと、および一様伸びδ(最大荷重までの塑性伸び)を増大させることが重要であるとの知見が得られた。 As a result, in order to reduce the yield ratio in the steel pipe, the yield ratio at the steel plate stage is lowered in advance by an amount higher than the increase in the steel pipe, and the uniform elongation δ u (plastic elongation up to the maximum load) is increased. It was found that this is important.

そして、鋼板段階で低降伏比と引張強さを両立させるためには、ミクロ組織を、硬質相となるベイナイト相(B)と、軟質相となるポリゴナル化したフェライト相(ポリゴナルフェライト相:α)を共存させ、そのポリゴナルフェライト相(α)の面積分率を40〜70%に制御することが有効であることが判明した。また一様伸びδは、フェライト相をポリゴナル化させることによって増大させることができることが分かった。 In order to achieve both a low yield ratio and tensile strength at the steel plate stage, the microstructure is divided into a bainite phase (B) that becomes a hard phase and a polygonalized ferrite phase that becomes a soft phase (polygonal ferrite phase: α It was proved effective to coexist P 2 ) and control the area fraction of the polygonal ferrite phase (α P ) to 40 to 70%. It was also found that the uniform elongation δ u can be increased by polygonalizing the ferrite phase.

鋼板段階(冷間成形前)において、マルテンサイトが島状に形成される場合には、降伏点を低減し、冷間曲げ後の降伏比を更に低位にする作用を発揮する。島状マルテンサイトは、マルテンサイト相とオーステナイト相(残留オーステナイト相)が混合する相からなるものであるが(Martensite-Austenite constitute: M−A相)、島状マルテンサイト中に存在する残留オーステナイト相γは冷間曲げにより加工誘起マルテンサイトに変態することによって一様伸びδを更に増大させることができる。尚、こうした組織に冷間曲げを施して冷間成形鋼管とした場合には、組織中の残留オーステナイト相はなくなり、変態したマルテンサイト相として存在することになる。 In the steel plate stage (before cold forming), when martensite is formed in an island shape, the yield point is reduced and the yield ratio after cold bending is further lowered. Island-like martensite consists of a mixture of martensite and austenite phases (residual austenite phase) (Martensite-Austenite constitute: MA phase), but the retained austenite phase present in island-like martensite. gamma R can further increase the uniform elongation [delta] u by transformation to deformation-induced martensite by cold bending. When such a structure is cold-bent to form a cold-formed steel pipe, the retained austenite phase in the structure disappears and exists as a transformed martensite phase.

本発明の冷間成形鋼管においては、上記観点からミクロ組織を適切に制御する必要があるが、この組織中における各相の範囲(面積分率)限定理由は下記の通りである。   In the cold-formed steel pipe of the present invention, it is necessary to appropriately control the microstructure from the above viewpoint, and the reasons for limiting the range (area fraction) of each phase in this structure are as follows.

[ポリゴナルフェライト相α:40〜70面積%]
降伏比を低位にするためには、変態後のミクロ組織に転位密度の小さいポリゴナル化したフェライト(α)を生成させることが有効であり、降伏比を鋼板段階で予め下げておくには、その面積分率を40〜70%の範囲に制御する必要がある。ポリゴナルフェライト相(α)の面積分率が70%を超えると、厚肉材において目標強度の確保が困難となる。一方、ポリゴナルフェライト相(α)の面積分率が40%未満となると、降伏比が目標値(85%)を超えてしまうことになる。
[Polygonal ferrite phase α P : 40 to 70 area%]
In order to reduce the yield ratio, it is effective to generate polygonalized ferrite (α P ) having a low dislocation density in the microstructure after transformation, and in order to lower the yield ratio in advance in the steel plate stage, It is necessary to control the area fraction within a range of 40 to 70%. When the area fraction of the polygonal ferrite phase (α P ) exceeds 70%, it becomes difficult to secure the target strength in the thick material. On the other hand, when the area fraction of the polygonal ferrite phase (α P ) is less than 40%, the yield ratio exceeds the target value (85%).

[擬ポリゴナルフェライト相α:0〜20面積%]
転位密度の高い擬ポリゴナルフェライト相(α)は、強度を上昇させる一方で、可動転位の移動を妨げて降伏比を上昇させるので、できるだけ少ない程よく、面積分率で0〜20%程度とする必要がある。好ましくは0〜15%程度とするのが良い。
[Pseudopolygonal ferrite phase α q : 0 to 20 area%]
The pseudopolygonal ferrite phase (α q ) having a high dislocation density increases the strength, while preventing the movement of movable dislocations and increasing the yield ratio. Therefore, it is better as little as possible, and the area fraction is about 0 to 20%. There is a need to. Preferably, the content is about 0 to 15%.

[島状マルテンサイト相M−A:0〜5面積%]
鋼板段階におけるマルテンサイト相(M)若しくはマルテンサイト−オーステナイト混合相(M−A相)は、未変態オーステナイトにおけるC,合金元素の偏析の大きい部分がベイナイト変態をせずに、局所的に島状にマルテンサイト相(M)や残留オーステナイト相(γ)となったものである。このうち、マルテンサイト相(M)は引張強さの上昇、降伏比の低減に有効に作用する。また残留オーステナイト(γ)は、外部からの加工歪みによって加工誘起変態を発現させるために、一様伸びδの増大に有効に作用する。従って、冷間成形鋼管には、降伏比の較低減および一様伸びδの増大をより促進するために、島状マルテンサイト相(M−A:残留オーステナイトからの変態後のマルテンサイト相Mも含む)を生成させる。島状マルテンサイト相(M−A)の面積分率は、0〜5%程度とするのが良い。島状マルテンサイト相(M−A)の面積分率が5%を超えると、靭性が劣化することになる。この面積分率は、好ましくは0〜4%程度とするのが良い。
[Islandic martensite phase MA: 0 to 5 area%]
The martensite phase (M) or martensite-austenite mixed phase (MA phase) in the steel plate stage is locally island-like without bainite transformation in the part where C and alloy elements are largely segregated in untransformed austenite. In the martensite phase (M) and the retained austenite phase (γ R ). Of these, the martensite phase (M) effectively acts to increase the tensile strength and reduce the yield ratio. Residual austenite (γ R ) effectively works to increase the uniform elongation δ u in order to develop a processing-induced transformation due to external processing strain. Therefore, in cold-formed steel pipe, in order to further promote the reduction in yield ratio and the increase in uniform elongation δ u , the island-like martensite phase (MA: martensite phase M after transformation from retained austenite M Including). The area fraction of the island martensite phase (MA) is preferably about 0 to 5%. If the area fraction of the island martensite phase (MA) exceeds 5%, the toughness will deteriorate. This area fraction is preferably about 0 to 4%.

[島状マルテンサイト相(M−A)のアスペクト比:4.0以下]
島状マルテンサイト相(M−A)の面積分率が5%以下であっても、その形状でアスペクト比(長径/短径)が4.0を超えると、一様伸びδが増大せず、靭性も劣化することになる。またM−A相は、旧オーステナイト粒界に形成されることから、そのアスペクト比を4.0以下に制御することは、旧オーステナイト粒の展伸度が小さいことの帰結であり、圧延集合組織の形成も微小となることから、鋼管のシーム溶接部(端曲げの無加工部に相当)の音響異方性を小さくすることができる。
[Aspect ratio of island martensite phase (MA): 4.0 or less]
Even if the area fraction of the island martensite phase (MA) is 5% or less, if the aspect ratio (major axis / minor axis) exceeds 4.0 in the shape, the uniform elongation δ u increases. The toughness is also deteriorated. Further, since the MA phase is formed at the prior austenite grain boundaries, controlling the aspect ratio to 4.0 or less is a consequence of the low degree of expansion of the prior austenite grains, and the rolling texture Therefore, the acoustic anisotropy of the seam welded portion of the steel pipe (corresponding to a non-machined portion of the end bend) can be reduced.

本発明の冷間成形鋼管では、板厚をt(mm)、外側冷間曲げ直径をd(mm)としたときにt/dが10%以下である冷間成形部位を有するものであるが、このt/dが10%を超えるような冷間加工では、引張り変形側の降伏比が加工後において85%を超えてしまうので、降伏比の上昇を抑えるために、熱間、温間での成形、或は成形後の応力除去焼鈍処理(前記SR処理)が必要となる。そのために、前記t/dは10%以下とする必要がある。このt/dは好ましくは7.5%以下とするのが良い。このt/dを達成するための加工方法については、プレス曲げ成形に限定されるものでなく、例えばローラ曲げ、圧縮プレス、スピニング等の適用も可能である。また曲げ温度は、常温のみならず、本発明の鋼板の材質を損なわない程度(400℃程度)の温度まで許容できる。尚、本発明の冷間成形鋼管は、その断面形状が円形、角形のいずれも含まれるものである。また、前記外側冷間曲げ直径dは冷間成形(曲げ加工)された部位における曲率直径を意味し、鋼管の断面形状が円形のときは、外側冷間曲げ直径dは鋼管外径Dと一致することになる。   The cold-formed steel pipe of the present invention has a cold-formed portion where t / d is 10% or less when the plate thickness is t (mm) and the outer cold bend diameter is d (mm). In cold working such that t / d exceeds 10%, the yield ratio on the tensile deformation side exceeds 85% after working. Therefore, in order to suppress the increase in yield ratio, Or a stress-relieving annealing process (the SR process) after the molding is required. Therefore, the t / d needs to be 10% or less. This t / d is preferably 7.5% or less. The processing method for achieving this t / d is not limited to press bending, and for example, roller bending, compression pressing, spinning, and the like can be applied. The bending temperature is acceptable not only at room temperature but also up to a temperature that does not impair the material of the steel sheet of the present invention (about 400 ° C.). The cold-formed steel pipe of the present invention includes both circular and square cross-sectional shapes. The outer cold bend diameter d means a curvature diameter at a cold-formed (bent) portion. When the cross-sectional shape of the steel pipe is circular, the outer cold bend diameter d matches the outer diameter D of the steel pipe. Will do.

本発明の冷間成形鋼管において、ミクロ組織におけるフェライト(α)の量的割合を上記のように制御するには(面積分率で40〜70%)、変態曲線のフェライトノーズを短時間側に移行させること、具体的には、Mn含有量[Mn]とC含有量[C]との比([Mn]/[C])を15以下にして、二相域(α+γ領域)温度保持におけるCの二相分離化を容易にすることが有効である。また、こうした効果を発揮させるためには、二相域焼入れ温度としては730〜830℃程度とすることが有効である(この条件については後述する)。 In the cold-formed steel pipe of the present invention, in order to control the quantitative ratio of ferrite (α p ) in the microstructure as described above (area fraction: 40 to 70%), the ferrite nose of the transformation curve is set to the short time side. Specifically, the ratio of the Mn content [Mn] to the C content [C] ([Mn] / [C]) is set to 15 or less, and the temperature in the two-phase region (α + γ region) is maintained. It is effective to facilitate the two-phase separation of C. In order to exert such effects, it is effective to set the two-phase region quenching temperature to about 730 to 830 ° C. (this condition will be described later).

フェライトの軟質化、およびセメンタイトの硬質化は、フェライトにとって負の偏析元素を添加し、二相域温度保持において存在するオーステナイトとフェライトの共存状態において、フェライトにとって負の偏析元素を未変態オーステナイトに拡散させ、その後ベイナイト変態をさせて、ベイナイト変態過程においてその吐き出された合金元素をセメンタイト中に濃化させることが有効であると考えられた。   The softening of ferrite and the hardening of cementite add a negative segregation element for ferrite and diffuse the negative segregation element for ferrite into untransformed austenite in the coexistence state of austenite and ferrite existing in two-phase temperature holding. Then, it was considered effective to cause bainite transformation and to concentrate the exhaled alloy elements in cementite during the bainite transformation process.

フェライトにとって負の偏析元素としては、Cr,MoおよびVの作用が大きいことに着目し、これらの固溶量として、前記(2)式で規定される量を1.1〜2.6に制御することで、合金元素を二相分離化できる。尚、前記(2)式で規定される量を1.1〜2.6に制御するためには、鋼片を950〜1250℃の温度範囲に加熱することと、圧延終了後にAr変態点以上の温度からの急冷によって、上記各元素の窒化物析出温度域での析出の回避を図りつつ、Cr,MoおよびVを固溶状態とした後、二相域焼入れすることが有効である(この条件については後述する)。 Focusing on the fact that Cr, Mo, and V have large effects as negative segregation elements for ferrite, the amount defined by equation (2) is controlled to 1.1 to 2.6 as the amount of these solid solutions. By doing so, the alloy element can be separated into two phases. Incidentally, the (2) in order to control the 1.1 to 2.6 the amount defined by the equation, and heating the billet to a temperature range of: 950 ° C., Ar 3 transformation point after the end of rolling It is effective to quench Cr, Mo and V in a solid solution state and then quench in a two-phase region while avoiding precipitation in the nitride precipitation temperature region of each element by rapid cooling from the above temperature ( This condition will be described later).

降伏点を下げること、および一様伸びδを増大させることについては、フェライト変態後、無加工で粒成長させてポリゴナル化させることによって、フェライトの転位密度を低位なものにすることが有効である。 For lowering the yield point and increasing the uniform elongation δ u , it is effective to lower the dislocation density of the ferrite by grain growth without ferrite after the ferrite transformation and making it polygonal. is there.

冷間成形鋼管の降伏比を低減し、且つ靭性も確保するには、より等方的なマルテンサイト相を形成させる必要があるが、こうした観点から前記アスペクト比は4.0以下とする必要がある。またアスペクト比を低位にすることによって、圧延集合組織も少なくなるため、鋼管のシーム溶接部(端曲げの無加工部に相当)での音響異方性の低減にも有効である。   In order to reduce the yield ratio of the cold-formed steel pipe and to secure toughness, it is necessary to form a more isotropic martensite phase. From this viewpoint, the aspect ratio must be 4.0 or less. is there. In addition, since the rolling texture is reduced by reducing the aspect ratio, it is effective in reducing the acoustic anisotropy at the seam welded portion of the steel pipe (corresponding to the unmachined portion of the end bend).

鋼板段階でのマルテンサイト相或はオーステナイトとの混合層の扁平化を抑制する手段としては、前記(3)式で示されるオーステナイト未再結晶化温度Aγ以下での累積圧下率を60%以下として圧延を終了することが、旧オーステナイト粒および粒界析出するマルテンサイト相或はオーステナイトとの混合相の扁平化の抑制には有効である。また、このときの圧延終了温度は、旧オーステナイト粒の扁平化の抑制という観点から、オーステナイト未再結晶化温度Aγ以上であることが好ましい。更に、マルテンサイトの組織分率を上記のように制御するためには、炭素当量式でのCを本発明に示す合金元素(特に、Cr、Mo,V等)で置き換えることが必要となる。 As a means for suppressing the flattening of the martensite phase or the mixed layer with austenite at the steel plate stage, the cumulative rolling reduction at the austenite non-recrystallization temperature A γ or less represented by the above formula (3) is 60% or less. Ending the rolling as described above is effective in suppressing flattening of the prior austenite grains and the martensite phase or grain mixed with the austenite. In addition, the rolling end temperature at this time is preferably equal to or higher than the austenite non-recrystallization temperature Aγ from the viewpoint of suppressing flattening of the prior austenite grains. Furthermore, in order to control the martensite structure fraction as described above, it is necessary to replace C in the carbon equivalent formula with an alloy element (particularly, Cr, Mo, V, etc.) shown in the present invention.

本発明の冷間成形鋼管において、そのミクロ組織は、上記以外(残部)は、基本的にベイナイトからなるものであるが、そのためには本発明範囲のポリゴナルフェライトαを析出させた後、パーライト変態させないように、直ちに加速冷却すれば良い。 In cold-formed steel pipe of the present invention, the microstructure, other than the above (balance), after it is made of essentially bainite, is obtained by precipitation of polygonal ferrite alpha P of the present invention ranges Therefore, Immediate acceleration cooling may be performed so as not to cause pearlite transformation.

ところで、本発明の冷間成形鋼管では、溶接性が良好であることも必要であるが、そのためには、Bを無添加とすることによって溶接熱影響部(HAZ)におけるマルテンサイト化、或はベイナイト化を抑制でき、耐割れ性とHAZ靭性を向上させることができる。また、Tiの添加によって、TiNを生成させ、母材およびHAZにおける旧オーステナイト粒の微細化作用を発揮させることによって、靭性が向上することになる。   By the way, in the cold-formed steel pipe of the present invention, it is necessary that the weldability is good. To that end, by adding B to the martensite in the weld heat affected zone (HAZ), or Bainite can be suppressed and crack resistance and HAZ toughness can be improved. Further, by adding Ti, TiN is generated, and the toughness is improved by exerting the effect of refining the prior austenite grains in the base material and HAZ.

次に、本発明の冷間成形鋼管における化学成分組成の限定理由について説明する。まず本発明では、上記のようにC:0.07〜0.18%、Si:0.05〜1.0%、Mn:0.7〜1.7%(但し、Mn含有量[Mn]とC含有量[C]の比[Mn]/[C]≦15)、Ti:0.002〜0.025%、sol.Al:0.005〜0.1%およびN:0.001〜0.008%を含有する他、Cr:0.6%以下(0%を含む)、Mo:0.5%以下(0%を含む)およびV:0.08%以下(0%を含む)よりなる群から選ばれる1種または2種以上を含有すると共に、前記(1)式および(2)式で規定する値を適正な範囲に制御する必要があるが、これら元素の範囲限定理由は、次の通りである。   Next, the reason for limiting the chemical component composition in the cold-formed steel pipe of the present invention will be described. First, in the present invention, as described above, C: 0.07 to 0.18%, Si: 0.05 to 1.0%, Mn: 0.7 to 1.7% (provided that Mn content [Mn] And C content [C] ratio [Mn] / [C] ≦ 15), Ti: 0.002 to 0.025%, sol. Al: 0.005 to 0.1% and N: 0.001 to 0.008%, Cr: 0.6% or less (including 0%), Mo: 0.5% or less (0%) And V: 0.08% or less (including 0%), and one or more selected from the group consisting of 0 and 8%, and appropriate values defined by the above formulas (1) and (2) Although it is necessary to control within such a range, the reasons for limiting the ranges of these elements are as follows.

[C:0.07〜0.18%]
Cは最も安価な元素で強度上昇に有効な元素であるが、過剰に含有されると溶接性が著しく低下するため、含有量の上限を0.18%とする。しかしながら、C含有量が0.07%未満になると、強度不足が生じ、それを補うためには、合金元素の添加が必要になるが、これらの合金元素の添加を過多に行うと、降伏比の増加を招くことになるので、好ましくない。この降伏比の増加を抑えつつ目標の強度(引張強さで490MPa以上)を確保するためには、Cは少なくとも0.07%以上含有させる必要がある。尚、母材強度と溶接HAZ靭性の両立の観点から、C含有量の好ましい下限は0.08%であり、好ましい上限は0.16%である。
[C: 0.07 to 0.18%]
C is the cheapest element and is effective for increasing the strength. However, if excessively contained, the weldability is remarkably lowered, so the upper limit of the content is 0.18%. However, when the C content is less than 0.07%, the strength is insufficient, and in order to make up for it, addition of alloy elements is required. However, if these alloy elements are added excessively, the yield ratio is increased. Increase, which is not preferable. In order to secure the target strength (tensile strength of 490 MPa or more) while suppressing the increase in yield ratio, C needs to be contained at least 0.07% or more. In addition, from a viewpoint of coexistence of base material strength and welded HAZ toughness, a preferable lower limit of the C content is 0.08%, and a preferable upper limit is 0.16%.

[Si:0.05〜1.0%]
Siは脱酸のために0.05%以上含有させることが必要であるが、1.0%を超えて過剰に含有させると溶接性並びにHAZ靭性を低下させる。こうしたことから、Si含有量は0.05〜1.0%とする必要がある。尚、Si含有量の好ましい下限は0.10%であり、好ましい上限は0.9%である。
[Si: 0.05-1.0%]
Si needs to be contained in an amount of 0.05% or more for deoxidation. However, if it exceeds 1.0%, the weldability and the HAZ toughness are deteriorated. For these reasons, the Si content needs to be 0.05 to 1.0%. In addition, the minimum with preferable Si content is 0.10%, and a preferable upper limit is 0.9%.

[Mn:0.7〜1.7%(但し、Mn含有量[Mn]とC含有量[C]の比[Mn]/[C]≦15)]
Mnは強度と靭性を共に高める元素として有効である。こうした効果を発揮させるためには、Mnは0.7%以上含有させる必要がある。しかしながらMnを過剰に含有させると、溶接性およびHAZ靭性が著しく劣化するので、上限を1.7%とする。尚、Mn含有量の好ましい下限は1.0%であり、好ましい上限は1.6%である。
[Mn: 0.7 to 1.7% (provided that the ratio of Mn content [Mn] to C content [C] [Mn] / [C] ≦ 15)]
Mn is effective as an element that increases both strength and toughness. In order to exhibit such an effect, it is necessary to contain 0.7% or more of Mn. However, if Mn is contained excessively, the weldability and the HAZ toughness deteriorate significantly, so the upper limit is made 1.7%. In addition, the minimum with preferable Mn content is 1.0%, and a preferable upper limit is 1.6%.

また、Mn含有量はC含有量との関係で適切な範囲に調整する必要がある。Mn含有量[Mn]とC含有量[C]との比[Mn]/[C]は、連続冷却変態曲線(CCT曲線)および等温変態曲線(TTT曲線)でのフェライト変態曲線の張り出し(ノーズ)の程度を成分的に制御する因子となるものであり、上記比[Mn]/[C]が15を超えると、フェライトノーズが長時間側に後退するので、二相域熱処理(Q’)で平衡状態の二相組織(α+γ)にするための保持時間が長くなり、生産上での制約を受けて非効率となる。そのため、上記比[Mn]/[C]は15以下とする必要がある。   Further, the Mn content needs to be adjusted to an appropriate range in relation to the C content. The ratio [Mn] / [C] between the Mn content [Mn] and the C content [C] is the overhang of the ferrite transformation curve (nose) in the continuous cooling transformation curve (CCT curve) and isothermal transformation curve (TTT curve). ) Is a factor that controls the degree of component), and when the ratio [Mn] / [C] exceeds 15, the ferrite nose retreats to the long time side, so that the two-phase region heat treatment (Q ′) Thus, the holding time for obtaining an equilibrium two-phase structure (α + γ) becomes long, and it becomes inefficient due to restrictions on production. Therefore, the ratio [Mn] / [C] needs to be 15 or less.

[Ti:0.002〜0.025%]
Tiは、スラブ加熱時に鋼中で微細なTiNとして存在し、加熱オーステナイト粒の粗大化を防止する効果がある。適正なオーステナイト(γ)再結晶温度域圧延、引き続くγ未再結晶温度Aγ域圧延、および微細なTiN生成との複合効果により、良好な靭性と超音波音響異方性を確保することが可能である。またTiは、直接焼入れ後のQ’処理においても逆変態オーステナイトからTiNをフェライト変態核として、ポリゴナルフェライトの析出を促進させて、降伏比低減、一様神びδの増大に有効である。こうした効果を発揮させるためには、Ti含有量は0.002%以上とする必要がある。しかしながら、Tiを過剰に含有させてもその効果が飽和するので、その上限を0.025%とする。尚、Ti含有量の好ましい下限は0.008%であり、好ましい上限は0.015%である。
[Ti: 0.002 to 0.025%]
Ti exists as fine TiN in the steel during slab heating, and has the effect of preventing coarsening of the heated austenite grains. Combined with proper austenite (γ) recrystallization temperature rolling, subsequent γ non-recrystallization temperature A γ region rolling, and fine TiN formation, it is possible to ensure good toughness and ultrasonic acoustic anisotropy. It is. The Ti is a TiN as ferrite transformation nuclei from reverse transformed austenite in the Q 'treatment after direct quenching, by promoting the precipitation of polygonal ferrite, it is effective to yield ratio reduction, increase of uniform god beauty [delta] u . In order to exert such effects, the Ti content needs to be 0.002% or more. However, even if Ti is contained excessively, the effect is saturated, so the upper limit is made 0.025%. In addition, the minimum with preferable Ti content is 0.008%, and a preferable upper limit is 0.015%.

[sol.Al:0.005〜0.1%]
Alは脱酸のために、少なくとも0.005%含有させる必要があるが、過剰に含有させると、非金属介在物が増加して靭性が低下するので、0.1%以下とする必要がある。尚、Al含有量の好ましい下限は0.01%であり、好ましい上限は0.06%である。
[Sol. Al: 0.005 to 0.1%]
Al needs to be contained at least 0.005% for deoxidation, but if it is contained excessively, nonmetallic inclusions increase and toughness decreases, so it is necessary to make it 0.1% or less. . In addition, the minimum with preferable Al content is 0.01%, and a preferable upper limit is 0.06%.

[N:0.001〜0.008%]
NはTiと反応してTiNを生成し、加熱時のオーステナイトの粗大化の防止に有効な元素である。こうした効果を発揮させるためには、少なくとも0.001%以上含有させる必要があるが、過剰に含有させると溶接継手部の靭性が劣化するので、0.008%以下とする必要がある。尚、N含有量の好ましい下限は0.002%であり、好ましい上限は0.006%である。
[N: 0.001 to 0.008%]
N reacts with Ti to produce TiN, and is an element effective in preventing austenite coarsening during heating. In order to exert such an effect, it is necessary to contain at least 0.001% or more, but if contained excessively, the toughness of the welded joint portion deteriorates, so it is necessary to make it 0.008% or less. In addition, the minimum with preferable N content is 0.002%, and a preferable upper limit is 0.006%.

[Cr:0.6%以下(0%を含む)、Mo:0.5%以下(0%を含む)およびV:0.08%以下(0%を含む)よりなる群から選ばれる1種または2種以上[且つ、固溶量が前記(2)式を満足する量]
Cr,MoおよびVは、強度を向上させる元素であるが、化合物として析出する場合、析出強化によって降伏比を上昇させ、一方靭性を劣化させることになる。降伏比を低位に保ったまま高強度と高靭性を確保するためには、固溶状態でセメンタイトに正偏析、フェライトに負偏析させることが有効である。こうしたことから、Cr,MoおよびVの含有量を夫々0.6%以下、0.5%以下、0.08%以下とし(いずれも0%を含む)、その固溶量を前記(2)式で規定されるA値で1.1〜2.6の範囲内に制御する必要がある。この成分元素量およびA値が上限を超えると、溶接性を阻害することになる。また、A値が1.1未満になると、鋼管成形後の降伏比が目標値を満足できなくなる。尚、各元素は好ましくはCr:0.3%以下、Mo:0.3%以下、V:0.06%以下とするのが良い。また、A値の好ましい範囲は、1.05〜2.0程度である。
[Cr: 0.6% or less (including 0%), Mo: 0.5% or less (including 0%) and V: 0.08% or less (including 0%) Or two or more kinds [and the amount of solid solution satisfying the formula (2)]
Cr, Mo, and V are elements that improve the strength. However, when precipitated as a compound, the yield ratio is increased by precipitation strengthening, while the toughness is deteriorated. In order to ensure high strength and high toughness while keeping the yield ratio low, it is effective to cause segregation to be positive segregation to cementite and negative segregation to ferrite in a solid solution state. Therefore, the contents of Cr, Mo and V are 0.6% or less, 0.5% or less and 0.08% or less (all include 0%), respectively. It is necessary to control within the range of 1.1 to 2.6 with the A value defined by the equation. When the amount of component elements and the A value exceed the upper limit, weldability is hindered. On the other hand, if the A value is less than 1.1, the yield ratio after forming the steel pipe cannot satisfy the target value. Each element is preferably Cr: 0.3% or less, Mo: 0.3% or less, and V: 0.06% or less. Moreover, the preferable range of A value is about 1.05-2.0.

[Ceq:0.34〜0.42%]
前記(1)式で表わされる炭素当量Ceqは、HAZの硬化性を表す指標であり(例えば、JIS G 3106)、溶接割れ感受性を低減し、y形溶接割れ試験での割れ防止予熱温度を25℃以下とするためには、Ceq値を0.42%以下とする必要がある。一方、引張り強さ490MPa以上を確保するためには、Ceq値は0.34%以上とする必要がある。Ceq値の好ましい下限は0.36%であり、好ましい上限は0.40%である。尚、上記(1)式には、基本成分であるC,Si,Mn,Cr,Mo,V等の他に、必要によって含有される成分(Ni)も式中の項目として含むものであるが、これらの成分は含有されるときにはその含有量も考慮して(1)式の値として計算すればよく、含まれないときにはこれらの含有量を考慮せずに計算すれば良い。
[Ceq: 0.34 to 0.42%]
The carbon equivalent Ceq represented by the formula (1) is an index representing the curability of the HAZ (for example, JIS G 3106), reduces the weld crack sensitivity, and reduces the crack prevention preheating temperature in the y-type weld crack test to 25. In order to set the temperature at or below ° C, the Ceq value needs to be set to 0.42% or less. On the other hand, in order to ensure a tensile strength of 490 MPa or more, the Ceq value needs to be 0.34% or more. The preferable lower limit of the Ceq value is 0.36%, and the preferable upper limit is 0.40%. In addition to the basic components C, Si, Mn, Cr, Mo, V, etc., the above formula (1) includes the component (Ni) contained as necessary in the formula. When the component is contained, it may be calculated as the value of the formula (1) in consideration of the content, and when not contained, it may be calculated without considering these contents.

本発明の冷間成形鋼管において、上記成分の他は、Feおよび不可避的不純物からなるものであるが、溶製上不可避的に混入する微量成分(許容成分)も含み得るものであり(例えば、P,S,O,B≦0.0005%等)、こうした鋼スラブも本発明の範囲に含まれるものである。また、本発明の冷間成形鋼管には、必要によって、更に(a)Cu:0.5%以下(0%を含まない)および/またはNi:3.0%以下(0%を含まない)、(b)Nb:0.015%(0%を含まない)、(c)Ca:0.003%以下(0%を含まない)、(d)希土類元素:0.02%以下(0%を含まない)、等を含有することも有効であるが、これらの成分を含有させるときの範囲限定理由は、次の通りである。   In the cold-formed steel pipe of the present invention, in addition to the above components, it is composed of Fe and unavoidable impurities, but may contain a trace component (acceptable component) inevitably mixed for melting (for example, P, S, O, B ≦ 0.0005%, etc.), such steel slabs are also included in the scope of the present invention. The cold-formed steel pipe of the present invention may further include (a) Cu: 0.5% or less (not including 0%) and / or Ni: 3.0% or less (not including 0%) as necessary. (B) Nb: 0.015% (not including 0%), (c) Ca: 0.003% or less (not including 0%), (d) Rare earth element: 0.02% or less (0%) It is also effective to contain these components, etc., but the reason for limiting the range when these components are contained is as follows.

[Cu:0.5%以下(0%を含まない)および/またはNi:3.0%以下(0%を含まない)]
これらの元素は、高価であり、しかも降伏比を上昇させるため、その添加はできるだけ避けることが好ましい。しかし、厚肉鋼板で板厚中心部の強度低下を抑制する作用があるので、微量添加する場合がある。これらの元素を添加する場合には、Cuは0.5%、Niは3.0%を上限として含有させる必要がある。Cu含有量のより好ましい上限は0.3%であり、Niのより好ましい上限は1.5%である。
[Cu: 0.5% or less (not including 0%) and / or Ni: 3.0% or less (not including 0%)]
Since these elements are expensive and increase the yield ratio, addition of these elements is preferably avoided as much as possible. However, since a thick steel plate has an effect of suppressing the strength reduction in the central portion of the plate thickness, a small amount may be added. When these elements are added, it is necessary to contain Cu up to 0.5% and Ni up to 3.0%. A more preferable upper limit of the Cu content is 0.3%, and a more preferable upper limit of Ni is 1.5%.

[Nb:0.015%(0%を含まない)]
Nbは強度、靭性を共に向上させる元素として知られているが、熱間圧延後、加速冷却を行った場合、焼入れ性向上元素であるNbを含有させた鋼では、第2相組織のベイナイト量が増加し、しかも軟質のフェライトが生成し難くなる。その結果、降伏比が上昇することになる。こうしたことから、Nbを含有させる場合には、0.015%程度までとすることが好ましい。Nb含有量のより好ましい上限は0.010%程度である。
[Nb: 0.015% (excluding 0%)]
Nb is known as an element that improves both strength and toughness. However, when accelerated cooling is performed after hot rolling, the amount of bainite in the second phase structure is obtained in steel containing Nb, which is a hardenability improving element. Increases, and it becomes difficult to produce soft ferrite. As a result, the yield ratio increases. For these reasons, when Nb is contained, the content is preferably up to about 0.015%. The upper limit with more preferable Nb content is about 0.010%.

[Ca:0.005%以下(0%を含まない)]
Caは、非金属介在物の球状化作用を有し、異方性の低減に有効であるが、0.005%を超えて含有させると、介在物の増加によって靭性が劣化することになる。従って、Caを含有させるときには、0.005%以下とすることが好ましい。Ca含有量の好ましい下限は0.0005%であり、より好ましい上限は0.003%である。
[Ca: 0.005% or less (excluding 0%)]
Ca has a spheroidizing effect of nonmetallic inclusions and is effective in reducing anisotropy. However, when Ca is contained in an amount exceeding 0.005%, the toughness deteriorates due to an increase in inclusions. Therefore, when Ca is contained, the content is preferably 0.005% or less. The preferable lower limit of the Ca content is 0.0005%, and the more preferable upper limit is 0.003%.

[希土類元素:0.02%以下(0%を含まない)]
希土類元素(以下、「REM」と略記する)は、そのオキシサルファイドとしてTiN共存下でオーステナイト異常成長を抑制してHAZの靭性を向上させる元素であるが、0.02%を超えて過剰に含有されると鋼の清浄度を悪くして内部欠陥を発生させる。REMによる効果を発揮させるためには0.002%以上含有させることが好ましく、より好ましい上限は0.01%である。尚、REMとは、周期律表第3属に属するスカンジウム(Sc)、イットリウム(Y)およびランタノイド系列希土類元素のいずれも使用できる。
[Rare earth elements: 0.02% or less (excluding 0%)]
A rare earth element (hereinafter abbreviated as “REM”) is an element that suppresses abnormal austenite growth in the presence of TiN as oxysulfide and improves the toughness of HAZ, but exceeds 0.02% in excess. If done, the cleanliness of the steel is deteriorated and internal defects are generated. In order to exhibit the effect by REM, it is preferable to contain 0.002% or more, and a more preferable upper limit is 0.01%. As REM, any of scandium (Sc), yttrium (Y) and lanthanoid series rare earth elements belonging to Group 3 of the periodic table can be used.

本発明の冷間成形鋼管を製造するには、基本的には連鋳法あるいは造塊法により作製されたスラブからの鋼片を用いて、加熱−熱間圧延−冷却−熱処理等の工程、或は熱間圧延後の制御冷却(加速冷却や直接焼入れも含む)等の工程を経ることによって、上記のような化学成分組成および組織を有する鋼管を製造すれば良く、そのための製造方法については特に限定するものではないが(後記実施例の実験No.42〜46)、本発明方法に従って製造することが好ましい。次に本発明の製造方法で規定する各要件について説明する。   In order to produce the cold-formed steel pipe of the present invention, basically, using a steel piece from a slab produced by a continuous casting method or an ingot-making method, a process such as heating-hot rolling-cooling-heat treatment, Alternatively, a steel pipe having the above chemical composition and structure may be manufactured through a process such as controlled cooling after hot rolling (including accelerated cooling and direct quenching). Although it does not specifically limit (Experiment No. 42-46 of an after-mentioned Example), manufacturing according to this invention method is preferable. Next, each requirement prescribed | regulated with the manufacturing method of this invention is demonstrated.

[鋼片の加熱温度:950〜1250℃]
鋼片の加熱温度を1250℃を超える温度とすると、鋼片のオーステナイト粒が急激に粒成長を起こして、変態後の組織が粗大なベイナイト組織となり、鋼板の靭性が著しく低位となる。一方、加熱温度が950℃未満となると、(γ未再結晶化温度Aγ−50℃)未満での累積圧下率が大きくなり、旧オーステナイト粒の過大な細粒化が起こり、降伏点YP、0.2%耐力σ0.2および降伏比YRが大幅に上昇することになる。こうしたことから、鋼片の加熱温度は、950〜1250℃の範囲とする必要がある。この加熱温度は、好ましくは1000℃以上、1150℃以下とするのが良い。
[Heating temperature of steel slab: 950 to 1250 ° C.]
When the heating temperature of the steel slab exceeds 1250 ° C., the austenite grains of the steel slab undergo rapid grain growth, the transformed structure becomes a coarse bainite structure, and the toughness of the steel sheet becomes extremely low. On the other hand, when the heating temperature is less than 950 ° C., the cumulative reduction ratio below (γ non-recrystallization temperature Aγ−50 ° C.) increases, and excessive austenite grain refinement occurs, yield point YP, 0 The 2% yield strength σ 0.2 and the yield ratio YR will be significantly increased. For these reasons, the heating temperature of the steel slab needs to be in the range of 950 to 1250 ° C. The heating temperature is preferably 1000 ° C. or higher and 1150 ° C. or lower.

[γ未再結晶化温度Aγ以下での累積圧下率が60%以下]
前述の如く、鋼板段階でのマルテンサイト相或はオーステナイトとの混合相の扁平化を抑制するために、γ未再結晶化温度Aγ以下での累積圧下率が60%以下とする必要がある。またこの累積圧下率が60%を超えると、旧オーステナイト粒の過大な細粒化が起こり、降伏比が上昇することになる。尚、上記「圧下率」とは、圧延前・後の鋼板の厚さを夫々t(mm)およびt(mm)としたとき、{(t−t)/t}×100(%)で示されるものである。
[Cumulative rolling reduction at γ non-recrystallization temperature A γ or less is 60% or less]
As described above, in order to suppress the flattening of the mixed phase with the martensite phase or austenite at the steel plate stage, the cumulative rolling reduction at the γ non-recrystallization temperature A γ or less needs to be 60% or less. . On the other hand, when the cumulative rolling reduction exceeds 60%, excessive austenite grain refinement occurs and the yield ratio increases. The “rolling ratio” is {(t 1 −t 2 ) / t 1 } × 100 when the thicknesses of the steel sheet before and after rolling are t 1 (mm) and t 2 (mm), respectively. (%).

[圧延終了後、Ar変態点以上から450℃以下まで4〜100℃/秒の冷却速度で冷却する]
鋼板のミクロ組織におけるCの均一分散、およびCr,Mo,Vの固溶を図ることと強度を確保することを目的として、圧延後にAr変態点以上から450℃以下までを加速冷却する必要がある。冷却開始温度がAr変態点よりも低くなったり、冷却停止温度が450℃よりも高くなったり、冷却速度が4℃/秒未満であったりすれば、変態強化不十分となると共に、Cr,MoおよびVの全固溶が達成されなくなる。このときの冷却速度の上限については、冷却媒体の冷却能の限界という観点から、100℃/秒以下とする必要がある。尚、本発明におけるAr変態点とは、下記(4)式によって計算される値を採用したものである。
Ar変態点=910−310[C]−80[Mn]−20[Cu]−15[Cr]−
55[Ni]−80[Mo]+0.35(t−8) …(4)
但し、t:板厚
[After the rolling is completed, cooling is performed at a cooling rate of 4 to 100 ° C./second from the Ar 3 transformation point to 450 ° C.]
For the purpose of ensuring uniform dispersion of C in the microstructure of the steel sheet and solid solution of Cr, Mo, V and ensuring the strength, it is necessary to accelerate cooling from the Ar 3 transformation point to 450 ° C. after rolling. is there. If the cooling start temperature is lower than the Ar 3 transformation point, the cooling stop temperature is higher than 450 ° C., or the cooling rate is less than 4 ° C./second, transformation strengthening is insufficient, Cr, The total solid solution of Mo and V is not achieved. The upper limit of the cooling rate at this time needs to be 100 ° C./second or less from the viewpoint of the limit of the cooling capacity of the cooling medium. In the present invention, the Ar 3 transformation point is a value calculated by the following equation (4).
Ar 3 transformation point = 910-310 [C] -80 [Mn] -20 [Cu] -15 [Cr]-
55 [Ni] -80 [Mo] +0.35 (t-8) (4)
Where t: thickness

[730〜830℃の温度範囲に再加熱してから焼入れ]
加速冷却した鋼板を、二相域(α+γ)温度に保持することによって、一旦分散したCがフェライトと逆変態オーステナイトに二相分離されて、フェライトにおけるCの負偏析、オーステナイトにおける正偏析を生起させる。また、加速冷却によって、一旦固溶させたCr,MoおよびVの各元素についても、この二相域保持において、フェライトへの負偏析、オーステナイトへの正偏析を生起させ、降伏比の低減と高強度の確保という相反する課題を解決することができる。二相域での保持温度が730℃未満の場合、および830℃超える場合には、夫々逆変態オーステナイト量、フェライト量が少な過ぎる為に、鋼板段階での降伏比が高くなり、冷間成形鋼管後の降伏比が目標降伏比を満足できなくなる。また二相域温度に保持した後焼入れするのは、逆変態オーステナイトから焼入れにより主相のベイナイト組織と島状マルテンサイト相を析出させるためである。
[Quenching after reheating to 730-830 ° C temperature range]
By maintaining the accelerated cooled steel sheet at a two-phase region (α + γ) temperature, once dispersed C is two-phase separated into ferrite and reverse-transformed austenite, causing negative segregation of C in ferrite and positive segregation in austenite. . In addition, the Cr, Mo and V elements once dissolved by accelerated cooling also cause negative segregation to ferrite and positive segregation to austenite in this two-phase region retention, thereby reducing the yield ratio. The conflicting problem of ensuring strength can be solved. When the holding temperature in the two-phase region is lower than 730 ° C and higher than 830 ° C, the amount of reverse transformed austenite and ferrite is too small, and the yield ratio at the steel plate stage becomes high, and cold formed steel pipe The later yield ratio cannot satisfy the target yield ratio. The reason for quenching after maintaining the temperature in the two-phase region is to precipitate the bainite structure of the main phase and the island martensite phase by quenching from the reverse transformed austenite.

[板厚をt(mm)、外側冷間曲げ直径をd(mm)としたときにt/dが10%以下の範囲で冷間成形する]
本発明の冷間成形鋼管では、引張り変形側の降伏比が加工後において85%以下とするために、t/dが10%以下である冷間成形部位を有するものであるが、こうした部位を形成するために、t/dが10%以下の範囲で冷間成形するものである。
[Cold forming is performed in a range where t / d is 10% or less when the plate thickness is t (mm) and the outer cold bending diameter is d (mm)]
In the cold-formed steel pipe of the present invention, since the yield ratio on the tensile deformation side is 85% or less after processing, it has a cold-formed part where t / d is 10% or less. In order to form, cold forming is performed in a range where t / d is 10% or less.

本発明の製造方法においては、必要によって、(1)730〜830℃の温度範囲に再加熱してから焼入れした後、前記鋼板を500℃以下で焼き戻しを施す、(2)前記圧延を終了した後、加速冷却するに先立ち、オンラインレベラ矯正を行う、(3)鋼板温度を400℃以下として冷間成形する、等の条件を付加することが好ましいが、これらの要件を規定する理由は次の通りである。   In the production method of the present invention, if necessary, (1) after reheating to a temperature range of 730 to 830 ° C. and then quenching, the steel sheet is tempered at 500 ° C. or less, and (2) the rolling is finished. Then, prior to accelerated cooling, it is preferable to add conditions such as online leveler correction, (3) cold forming at a steel plate temperature of 400 ° C. or lower. The reason for defining these requirements is as follows: It is as follows.

[730〜830℃の温度範囲に再加熱してから焼入れした後、前記鋼板を500℃以下で焼戻しを施す]
二相域焼入れした鋼板の残留応力をなくす為に、選択的に500℃以下で焼戻しを施すことも有効である。このときの焼戻し温度が500℃を超えると、焼入れままで生成されたベイナイト組織中のCが拡散・凝集してパーライトを生成させるために、強度が低下することになる。こうしたことから、焼戻し温度は500℃以下とするが、好ましくは480℃以下とするのが良い。
[After reheating to a temperature range of 730 to 830 ° C. and quenching, the steel sheet is tempered at 500 ° C. or lower]
It is also effective to selectively temper at 500 ° C. or less in order to eliminate the residual stress of the steel sheet subjected to the two-phase region quenching. When the tempering temperature at this time exceeds 500 ° C., C in the bainite structure generated as it is quenched is diffused and aggregated to generate pearlite, resulting in a decrease in strength. For these reasons, the tempering temperature is set to 500 ° C. or lower, preferably 480 ° C. or lower.

[前記圧延を終了した後、加速冷却するに先立ち、オンラインレベラ矯正を行う]
圧延終了後、圧延済鋼板の先後端に平坦不良を生じた場合においても、直接焼入れ前の熱間矯正によって平坦度が良好となるため、先後端部に対する均一冷却が可能となり、機械的性質が安定し、歩留まりが向上する。こうしたことから、圧延終了後で直接焼入れ前においてオンラインレベラ矯正を行うことが有効である。
[Online leveler correction is performed prior to accelerated cooling after the rolling is completed]
Even after the end of rolling, even when a flat defect occurs at the front and rear ends of the rolled steel plate, the flatness is improved by hot straightening before direct quenching, so uniform cooling can be performed on the front and rear ends, and mechanical properties are improved. Stable and improved yield. For these reasons, it is effective to perform online leveler correction after the completion of rolling and before direct quenching.

[鋼板温度を400℃以下として冷間成形する]
曲げ温度(成形温度)は、常温のみならず、本発明の鋼板の材質を損なわない程度(400℃程度)の温度まで許容できることは上述した通りであるが、冷間成形時のスプリングバック等の成形阻害要因を軽減するために、ミクロ組成が変化せず、転位密度が低減できる400℃以下で選択的に成形(温間成形)することも有効である。このときの成形温度が400℃を超えると、Cが拡散して主相のベイナイトの一部がパーライトに変化し始めるため、強度低下を招くことになる。この形成温度の好ましい温度は300℃以下である。
[Cold forming at a steel plate temperature of 400 ° C. or lower]
As described above, the bending temperature (forming temperature) is acceptable not only at room temperature but also up to a temperature that does not impair the material of the steel sheet of the present invention (about 400 ° C.). In order to reduce the molding inhibition factor, it is also effective to perform selective molding (warm molding) at 400 ° C. or less at which the micro composition does not change and the dislocation density can be reduced. If the molding temperature at this time exceeds 400 ° C., C diffuses and a part of the bainite of the main phase starts to change to pearlite, resulting in a decrease in strength. A preferable temperature for this formation temperature is 300 ° C. or less.

以下、実施例によって本発明をより具体的に説明するが、本発明はもとより下記実施例によって制限を受けるものではなく、前・後記の趣旨に適合し得る範囲で変更を加えて実施することは勿論可能であり、それらはいずれも本発明の技術的範囲に包含される。   Hereinafter, the present invention will be described in more detail by way of examples.However, the present invention is not limited by the following examples as a matter of course, and may be implemented with modifications within a range that can meet the gist of the preceding and following descriptions. Of course, they are all possible and are included in the technical scope of the present invention.

下記表1、2に示す化学成分組成の鋼を通常の溶製方法によって溶製し、下記に示すいずれかの処理を行い(タイプ1〜3)、鋼板を製造した。尚、表1、2には、前記(1)式で規定される炭素当量Ceqの値、[Mn]/[C]の値およびγ未再結晶化温度についても示した。   Steels having the chemical composition shown in Tables 1 and 2 were melted by a normal melting method, and any one of the following treatments was performed (types 1 to 3) to produce steel plates. Tables 1 and 2 also show the value of carbon equivalent Ceq, the value of [Mn] / [C] and the γ non-recrystallization temperature defined by the above formula (1).

[処理手順]
タイプ1:通常の加熱、熱間圧延を行った後、直接焼入れ(DQ)を行い、その後二相域温度(Ac1点以上、Ac3点未満)で熱処理保持後に焼入れ(Q’)または500℃以下まで加速冷却を行った。
[Processing procedure]
Type 1: After performing normal heating and hot rolling, direct quenching (DQ) is performed, and then quenching (Q ′) or 500 after two-phase region temperature (Ac 1 point or more, less than Ac 3 point) is maintained. Accelerated cooling was performed to below ℃.

タイプ2:圧延終了後、Ar3点未満まで空冷程度の緩冷却した後、二相域温度(Ar1点超え、Ar3点未満)から加速冷却あるいは直接焼入れ(DQ’)を行った。 Type 2: After completion of rolling, after slow cooling of about air cooled Ar less than 3 points, were performed two-phase region temperature accelerated cooling or direct quenching from (Ar 1 Tenkoe, Ar less than 3 points) (DQ ').

タイプ3:熱間圧延後、加速冷却して二相域温度に保持後、再び加速冷却あるいは直接焼入れ(DQ)を行った。   Type 3: After hot rolling, accelerated cooling and holding at a two-phase temperature were followed by accelerated cooling or direct quenching (DQ) again.

その後、一部のものについては、Ac点未満の温度での焼戻し(T)無しに加えて、焼戻し有りのものも実施した。このときの製造条件を、前記(2)式の値およびAr変態点等と共に、下記表3〜5に示す。 After that, some samples were tempered in addition to no tempering (T) at a temperature of less than 1 Ac. The production conditions at this time are shown in Tables 3 to 5 below together with the value of the formula (2), the Ar 3 transformation point, and the like.

Figure 2007119899
Figure 2007119899

Figure 2007119899
Figure 2007119899

Figure 2007119899
Figure 2007119899

Figure 2007119899
Figure 2007119899

Figure 2007119899
Figure 2007119899

得られた各鋼板について、t/dを変化させて、冷間プレス成形を行い、鋼管を作製した。鋼板の機械的特性(降伏点YP、引張強さTS、一様伸びδ)およびミクロ組織の種類を測定すると共に、鋼管の管軸方向(L方向)の機械的特性(降伏点、引張強さTS、降伏比YRおよび靭性)およびCr,Mo,Vの固溶量、ミクロ組織を測定し、下記の基準で材質を評価した。 About each obtained steel plate, t / d was changed and cold press molding was performed and the steel pipe was produced. While measuring the mechanical properties (yield point YP, tensile strength TS, uniform elongation δ u ) of steel sheet and the type of microstructure, mechanical properties (yield point, tensile strength) in the tube axis direction (L direction) of the steel pipe TS, yield ratio YR and toughness), the amount of Cr, Mo, and V, and the microstructure were measured, and the materials were evaluated according to the following criteria.

[Cr,Mo,Vの固溶量]
鋼管のCr,MoおよびVの固溶量については、各元素の添加量−析出物として析出した各元素量として算定した。析出物として析出したCr、Mo、Vの元素量については、鋼管の外側t/4部の表面に平行な断面において、電解抽出残渣法により、析出元素量を測定した。
[Solution amount of Cr, Mo, V]
About the solid solution amount of Cr, Mo, and V of a steel pipe, it calculated as the amount of each element deposited as the added amount of each element-precipitate. Regarding the element amounts of Cr, Mo, and V deposited as precipitates, the amount of precipitated elements was measured by an electrolytic extraction residue method in a cross section parallel to the surface of the outer t / 4 part of the steel pipe.

[材質評価基準]
材質評価基準としては、鋼管の管軸方向での引張強さTS:490MPa以上、降伏比YR:85%以下、破面遷移温度(vTrs):−20℃以下を目標に設定した。
[Material Evaluation Criteria]
As the material evaluation criteria, the tensile strength TS in the tube axis direction of the steel pipe was set to 490 MPa or more, the yield ratio YR: 85% or less, and the fracture surface transition temperature (vTrs): −20 ° C. or less.

機械的特性(鋼板および鋼管)の評価方法、鋼管の靭性評価方法、並びにミクロ組織測定方法は下記の通りである。   The evaluation method of mechanical properties (steel plate and steel pipe), the toughness evaluation method of steel pipe, and the microstructure measurement method are as follows.

[機械的特性の評価方法]
鋼板のt/4部(tは板厚)からL方向(圧延方向)、および鋼管の外側t/4部の管軸に平行方向(鋼板の主圧延方向に相当)に、JIS Z 2201 4号試験片を採取してJIS Z 2241の要領で引張試験を行ない、鋼板の機械的特性(降伏点YP、引張り強さTS、一様伸びδ)、鋼管の機械的特性(降伏点YP、引張強さTS、降伏比(降伏点/引張強度×100%:YR)を測定した。
[Mechanical property evaluation method]
JIS Z 2201 No. 4 from t / 4 part (t is the plate thickness) of the steel plate to the L direction (rolling direction) and parallel to the tube axis of the outer t / 4 part of the steel pipe (corresponding to the main rolling direction of the steel plate) A specimen is taken and subjected to a tensile test according to JIS Z 2241. The mechanical properties of the steel sheet (yield point YP, tensile strength TS, uniform elongation δ u ), and the mechanical properties of the steel pipe (yield point YP, tensile). The strength TS and the yield ratio (yield point / tensile strength × 100%: YR) were measured.

[靭性評価方法]
鋼管の外側t/4部から管軸に平行方向(鋼板の主圧延方向)に、JIS Z 2202 4号試験片を採取してJIS Z 2242に準拠してシャルピー衝撃試験を行ない、破面遷移温度(vTrs)を測定した。
[Toughness evaluation method]
A specimen of JIS Z 2202 No. 4 was taken from the outer t / 4 part of the steel pipe in the direction parallel to the pipe axis (main rolling direction of the steel sheet), and Charpy impact test was conducted in accordance with JIS Z 2242. (VTrs) was measured.

[ミクロ組織測定方法]
鋼板段階では、鋼板の主圧延方向のt/4部のミクロ組織を光学顕微鏡で観察し、存在する残留オーステナイトγについては、50〜100μmに電解研磨した鋼板t/4部のX線回折を行い、α−Fe(200)面とγ―Fe(200)面のピーク強度比から残留オーステナイトγの存在を確認した。鋼管の管軸に平行方向(鋼板の主圧延方向に相当)の外側t/4部、および鋼板の主圧延方向のt/4部を、ナイタールエッチングしたミクロ組織の写真を画像解析して、フェライトの形態、面積分率、ベイナイトの面積分率等を測定した。島状マルテンサイト相は、圧延方向板厚面の1/4部をレペラ試薬でエッチングしたミクロ組織の写真を画像解析して、面積分率とアスペクト比を測定した。
[Microstructure measurement method]
At the steel sheet stage, the microstructure of the t / 4 part in the main rolling direction of the steel sheet is observed with an optical microscope, and the residual austenite γ R present is subjected to X-ray diffraction of the steel sheet t / 4 part electropolished to 50 to 100 μm. The presence of residual austenite γ R was confirmed from the peak intensity ratio between the α-Fe (200) plane and the γ-Fe (200) plane. Image analysis of the microstructure of the nital etched outer t / 4 part in the direction parallel to the pipe axis of the steel pipe (corresponding to the main rolling direction of the steel sheet) and t / 4 part in the main rolling direction of the steel sheet, Ferrite morphology, area fraction, bainite area fraction, and the like were measured. The island-like martensite phase was subjected to image analysis of a photograph of a microstructure obtained by etching 1/4 part of the plate thickness surface in the rolling direction with a repeller reagent, and the area fraction and the aspect ratio were measured.

上記の材質基準を満足する鋼管について、溶接性(耐溶接割れ性およびHAZ靭性)を下記の方法によって評価した。   The steel pipes that satisfy the above-mentioned material standards were evaluated for weldability (weld crack resistance and HAZ toughness) by the following methods.

[耐溶接割れ性]
JIS Z 3158に規定されたy形溶接割れ試験法に従い、入熱量:1.7KJ/mmで炭酸ガス溶接を行ない、ルート割れ防止予熱温度を測定した。25℃以下を合格とした。
[Weld crack resistance]
In accordance with the y-type weld crack test method defined in JIS Z 3158, carbon dioxide gas welding was performed at a heat input of 1.7 KJ / mm, and the root crack prevention preheating temperature was measured. 25 degrees C or less was set as the pass.

[HAZ靭性]
入熱量7KJ/mmの両面サブマージアーク溶接(SAW)のシーム溶接を行い(X開先)、外側t/4部から管軸と直角方向にシャルピー衝撃試験片(JIS Z 2204 4号)を採取し、0℃における平均衝撃吸収エネルギーvEを求めた(3回試験の平均値)。平均vEが47J以上を合格とした。
[HAZ toughness]
Double-sided submerged arc welding (SAW) seam welding with 7KJ / mm heat input (X groove) was performed, and Charpy impact test piece (JIS Z 2204 No. 4) was taken from the outer t / 4 part in the direction perpendicular to the tube axis. The average impact absorption energy vE 0 at 0 ° C. was determined (average value of three tests). The average vE 0 was 47 J or more.

溶接性試験結果を、機械的特性(鋼板と鋼管)およびミクロ組織等と共に、下記表6〜8に示すが、これらの結果から、次のように考察できる。まず、実験No.1は、V単独添加鋼の制御圧延まま材であり、Ceqが本発明で規定する範囲を超えているため、耐溶接れ防止予熱温度が50℃と高く、HAZ靭性も低位である。   The weldability test results are shown in the following Tables 6 to 8 together with mechanical properties (steel plate and steel pipe), microstructure and the like. From these results, it can be considered as follows. First, Experiment No. No. 1 is a control-rolled steel of V-added steel, and since Ceq exceeds the range specified in the present invention, the preheating temperature for preventing welding is as high as 50 ° C., and the HAZ toughness is also low.

実験No.2は、Nb単独添加鋼の加速冷却450℃停止材であり、ミクロ組織にポリゴナルフェライトが生成していないので、冷間曲げ後に降伏比YRが目標値の85%以下を満足しないものとなっている。   Experiment No. No. 2 is an accelerated cooling 450 ° C. stop material of Nb single added steel, and since polygonal ferrite is not generated in the microstructure, the yield ratio YR does not satisfy 85% or less of the target value after cold bending. ing.

実験No.3のものは、Nb単独添加鋼の加速冷却450℃停止後に、二相域温度焼入れ(Q’)したものであり、ポリゴナルフェライト相の面積分率が本発明で規定する範囲よりも少なくなっているので、冷間曲げ後の降伏比YRが目標値の85%以下を満足しないものとなっている。   Experiment No. No. 3 is a steel obtained by quenching 450 ° C. of accelerated cooling of Nb-only added steel, followed by two-phase region temperature quenching (Q ′), and the area fraction of the polygonal ferrite phase is less than the range specified in the present invention. Therefore, the yield ratio YR after cold bending does not satisfy 85% or less of the target value.

実験No.14のものは、前記(2)式の値(A値)が本発明で規定する範囲内にあるものの、C含有量が本発明で規定する範囲よりも多くなっており、母材およびHAZの靭性が低位である。   Experiment No. In the case of No. 14, although the value (A value) of the formula (2) is within the range specified by the present invention, the C content is larger than the range specified by the present invention. The toughness is low.

実験No.15は、Mn含有量が本発明で規定する範囲よりも多くなっており、冷間曲げ後の降伏比YRが目標値の85%以下を満足しないものとなっている。   Experiment No. No. 15, the Mn content is larger than the range defined in the present invention, and the yield ratio YR after cold bending does not satisfy 85% or less of the target value.

実験No.18は、C含有量およびMn含有量が本発明で規定する範囲よりも少なくなっており、冷間曲げ後の引張強さTSが目標値の490MPa以上を満足しないものとなっている。   Experiment No. In No. 18, the C content and the Mn content are less than the ranges defined in the present invention, and the tensile strength TS after cold bending does not satisfy the target value of 490 MPa or more.

実験No.22は、Ti含有量が本発明で規定する範囲よりも多くなっており、冷間曲げ後の降伏比YRが目標値の85%以下を満足しないものとなっている。   Experiment No. In No. 22, the Ti content is larger than the range defined in the present invention, and the yield ratio YR after cold bending does not satisfy 85% or less of the target value.

実験No.24は、Mo含有量が本発明で規定する範囲よりも多くなっており、HAZ靭性が目標値の47J以上を満足しないものとなっている。   Experiment No. In No. 24, the Mo content is larger than the range specified in the present invention, and the HAZ toughness does not satisfy the target value of 47 J or more.

実験No.29は、Si含有量が本発明で規定する範囲よりも多くなっており、鋼管の島状マルテンサイト分率が本発明で規定する範囲よりも多くなっており、冷間曲げ後の降伏比YRが目標値の85%以下を満足しないものとなっている。   Experiment No. No. 29, the Si content is higher than the range specified in the present invention, the island martensite fraction of the steel pipe is higher than the range specified in the present invention, the yield ratio YR after cold bending However, it does not satisfy 85% or less of the target value.

実験No.32は、Cu含有量が本発明で規定する範囲よりも多くなっており、耐溶接れ防止予熱温度が目標の25℃以下を満足しないものとなっている。また破面遷移温度vTrsが−20℃以下、およびHAZ靭性は47J以上の目標値を満足しないものとなっている。   Experiment No. In No. 32, the Cu content is larger than the range defined in the present invention, and the preheating temperature for preventing welding is not satisfying the target of 25 ° C. or less. Further, the fracture surface transition temperature vTrs is −20 ° C. or lower, and the HAZ toughness does not satisfy the target value of 47 J or higher.

実験No.35は、Nb含有量が本発明で規定する範囲よりも多くなっており、冷間曲げ後の降伏比YRが目標値の85%以下を満足しないものとなっている。   Experiment No. In No. 35, the Nb content is larger than the range specified in the present invention, and the yield ratio YR after cold bending does not satisfy 85% or less of the target value.

実験No.38は、CaやREMの含有量が本発明で規定する範囲よりも多くなっており、冷間曲げ後の破面遷移温度vTrsが−20℃以下を満足しないものとなっている。   Experiment No. In No. 38, the content of Ca or REM is larger than the range specified in the present invention, and the fracture surface transition temperature vTrs after cold bending does not satisfy −20 ° C. or less.

実験No.51は、加熱温度が1300℃となっており、冷間曲げ後の破面遷移温度vTrsが−20℃以下を満足しないものとなっている。   Experiment No. No. 51 has a heating temperature of 1300 ° C., and the fracture surface transition temperature vTrs after cold bending does not satisfy −20 ° C. or less.

実験No.54は、加熱温度が900℃となっており、また累積圧下率が100%となってあり、冷間曲げ後の降伏比YRが目標値の85%以下を満足しないものとなっている。また実験No.55は、累積圧下率が80%となってあり、冷間曲げ後の降伏比YRが目標値の85%以下を満足しないものとなっている。   Experiment No. In No. 54, the heating temperature is 900 ° C., the cumulative rolling reduction is 100%, and the yield ratio YR after cold bending does not satisfy 85% or less of the target value. In addition, Experiment No. 55, the cumulative rolling reduction is 80%, and the yield ratio YR after cold bending does not satisfy 85% or less of the target value.

実験No.58は、圧延後の加速冷却開始温度が760℃となっており、ポリゴナルフェライト分率が80面積%となっており、引張強度TSが低下している。   Experiment No. In No. 58, the accelerated cooling start temperature after rolling is 760 ° C., the polygonal ferrite fraction is 80 area%, and the tensile strength TS is reduced.

実験No.60は、圧延後の加速冷却停止温度が580℃となっており、引張強度TSが低下している。   Experiment No. In No. 60, the accelerated cooling stop temperature after rolling is 580 ° C., and the tensile strength TS is reduced.

実験No.61は、圧延後の加速冷却速度が1.5℃/秒となっており、引張強度TSが低下している。   Experiment No. No. 61 has an accelerated cooling rate after rolling of 1.5 ° C./second, and the tensile strength TS is reduced.

実験No.63は、焼入れ前の再加熱温度が850℃となっており、ポリゴナルフェライト分率が35面積%となっており、冷間曲げ後の降伏比YRが目標値の85%以下を満足しないものとなっている。   Experiment No. No. 63 has a reheating temperature before quenching of 850 ° C., a polygonal ferrite fraction of 35 area%, and the yield ratio YR after cold bending does not satisfy the target value of 85% or less. It has become.

実験No.66は、焼入れ前の再加熱温度が700℃となっており、引張強度TSが低下している。   Experiment No. In No. 66, the reheating temperature before quenching is 700 ° C., and the tensile strength TS is lowered.

実験No.68は、焼戻し温度が600℃となっており、ポリゴナルフェライト分率が80面積%となっており、引張強度TSが低下すると共に、冷間曲げ後の降伏比YRが目標値の85%以下を満足しないものとなっている。   Experiment No. In No. 68, the tempering temperature is 600 ° C., the polygonal ferrite fraction is 80 area%, the tensile strength TS is lowered, and the yield ratio YR after cold bending is 85% or less of the target value. Is not satisfied.

実験No.70は、冷間成形時のt/dが15%となっており、冷間曲げ後の降伏比YRが目標値の85%以下を満足しないものとなっている。   Experiment No. No. 70 has a t / d of 15% during cold forming, and the yield ratio YR after cold bending does not satisfy 85% or less of the target value.

これに対して、本発明で規定する要件のいずれも満足するもの(実験No.4〜13,16,17,19〜21,23,25〜28,30,31,34,36,37、39〜50、52,53,56,57,59,62,64,65,67,69,71)では、全ての特性において目標値を満足するものとなっている。   On the other hand, all of the requirements specified in the present invention are satisfied (Experiment Nos. 4 to 13, 16, 17, 19 to 21, 23, 25 to 28, 30, 31, 34, 36, 37, 39). ˜50, 52, 53, 56, 57, 59, 62, 64, 65, 67, 69, 71) all satisfy the target values.

尚、実験No.4〜71のおける製造上のポイントは次の通りである。即ち、実験No.4〜38は、前記表1、2に示した化学成分組成の鋼材を圧延終了後に二相域温度焼入れ(Q’)したもの、実験No.39は更に焼戻し処理(T)を施したものである。   Experiment No. The production points in 4 to 71 are as follows. That is, Experiment No. Nos. 4 to 38 are steels having the chemical composition shown in Tables 1 and 2 that were subjected to two-phase temperature quenching (Q ') after the end of rolling. No. 39 is further tempered (T).

実験No.40は、圧延終了後、加速冷却450℃で停止したものであり、実験No.41は、更に焼戻し処理(T)を施したものである。   Experiment No. No. 40 was stopped at 450 ° C. after the end of rolling at the accelerated cooling. No. 41 is further tempered (T).

実験No.42は、圧延終了後、緩冷(空冷)し、二相域温度から直接焼入れ(DQ’)したもの、実験No.43は更に焼戻し処理(T)を施したものである。   Experiment No. No. 42 is a product which is slowly cooled (air-cooled) after the rolling, and directly quenched (DQ ') from the two-phase region temperature. No. 43 is further tempered (T).

実験No.44は、圧延終了後、Ar点超え、Ar点未満まで加速冷却し、その後空冷で60秒保持して、ポリゴナルフェライトαを生成させ、引き続き直接焼入れしたものである。 Experiment No. 44, after the end of rolling, Ar 1 Tenkoe, accelerated cooling to less than Ar 3 point, and then held for 60 seconds in air, to produce a polygonal ferrite alpha P, it is obtained by subsequently direct quenching.

実験No.45は、圧延終了後、Ar点超え、Ar点未満まで加速冷却し、その後オンライン保持炉にて二相域温度に保持して、ポリゴナルフェライトαを生成させ、引き続き焼入れしたものであり、実験No.46は、更に焼戻し処理(T)を施したものである。 Experiment No. 45, after the end of rolling, accelerated cooling to over Ar 1 point and below Ar 3 point, and then kept at the two-phase region temperature in an on-line holding furnace to generate polygonal ferrite α P , and subsequently quenched. Yes, Experiment No. No. 46 is further tempered (T).

実験No.47,48は、本発明で規定する範囲内でt/dを7.5,5(%)と変化させたものである。実験No.49は、板厚が40mmのものの結果である。実験No.50は、400℃昇温後プレス曲げしたものである。   Experiment No. 47 and 48 are obtained by changing t / d to 7.5, 5 (%) within the range defined by the present invention. Experiment No. 49 is a result of a plate thickness of 40 mm. Experiment No. 50 is press-bended after heating at 400 ° C.

実験No.51〜54は、本発明で規定する化学成分で加熱温度を900〜1300℃の範囲で変化させたものである。実験No.55〜58は、本発明で規定する化学成分で、圧延後の加速冷却開始温度を変化させたものである。   Experiment No. 51 to 54 are chemical components specified in the present invention and the heating temperature is changed in the range of 900 to 1300 ° C. Experiment No. 55 to 58 are chemical components defined in the present invention, and are obtained by changing the accelerated cooling start temperature after rolling.

実験No.59,60は、本発明で規定する化学成分で、加速冷却停止温度を変化させたものである。実験No.60〜62は、本発明で規定する化学成分で、圧延後の加速冷却速度を変化させたものである。   Experiment No. 59 and 60 are chemical components defined in the present invention, and the accelerated cooling stop temperature is changed. Experiment No. Reference numerals 60 to 62 are chemical components defined in the present invention, and change the accelerated cooling rate after rolling.

実験No.63〜66は、本発明で規定する化学成分で、焼入れ時の加熱温度(Q’)を変化させたものである。実験No.67,68は、本発明で規定する化学成分で、焼戻し温度(T)を変化させたものである。   Experiment No. 63 to 66 are chemical components defined in the present invention, and the heating temperature (Q ') during quenching is changed. Experiment No. 67 and 68 are chemical components specified in the present invention, and the tempering temperature (T) is changed.

実験No.69は、本発明で規定する化学成分で、加速冷却前にオンラインレベラ矯正を行ったものである。実験No.70は、本発明で規定する化学成分で、冷間曲げのt/dを本発明で規定する範囲外としたものである。実験No.71は、本発明で規定する成分で、曲げ成形温度を400℃としたものである。   Experiment No. 69 is a chemical component specified in the present invention, and is obtained by performing on-line leveler correction before accelerated cooling. Experiment No. 70 is a chemical component defined in the present invention, and the cold bending t / d is outside the range defined in the present invention. Experiment No. 71 is a component specified in the present invention, and has a bending temperature of 400 ° C.

Figure 2007119899
Figure 2007119899

Figure 2007119899
Figure 2007119899

Figure 2007119899
Figure 2007119899

Claims (9)

C:0.07〜0.18%(質量%の意味、以下同じ)、Si:0.05〜1.0%、Mn:0.7〜1.7%(但し、Mn含有量[Mn]とC含有量[C]の比[Mn]/[C]≦15)、Ti:0.002〜0.025%、sol.Al:0.005〜0.1%およびN:0.001〜0.008%を夫々含有する他、Cr:0.6%以下(0%を含む)、Mo:0.5%以下(0%を含む)およびV:0.08%以下(0%を含む)よりなる群から選ばれる1種または2種以上を含み、下記(1)式で示される炭素当量Ceq値が0.34〜0.42%の範囲内にあると共に、下記(2)式で示されるA値が1.1〜2.6を満足し、残部がFeおよび不可避的不純物からなる化学成分組成を有する鋼板からなり、且つ当該鋼板のミクロ組織が、40〜70面積%のポリゴナルフェライト相、0〜20面積%の擬ポリゴナルフェライト相、および0〜5面積%で、アスペクト比(長径/短径)が4.0以下の島状マルテンサイト相、残部がベイナイト相から構成され、板厚をt(mm)、外側冷間曲げ直径をd(mm)としたときにt/dが10%以下である冷間成形部位を有するものであることを特徴とする溶接性に優れた490MPa級低降伏比冷間成形鋼管。
Ceq=[C]+[Si]/24+[Mn]/6+[Ni]/40+[Cr]/5
+[Mo]/4+[V])/15 …(1)
但し、[C],[Si],[Mn],[Ni],[Cr],[Mo]および[V]は、夫々C,Si,Mn,Ni,Cr,MoおよびVの含有量(質量%)を示す。
A=(2.16{Cr}+1)×(3.0{Mo}+1)×(1.75{V}+1) …(2)
但し、{Cr},{Mo}および{V}は、夫々Cr,MoおよびVにおける鋼板中の固溶量(質量%)を示す。
C: 0.07 to 0.18% (meaning of mass%, hereinafter the same), Si: 0.05 to 1.0%, Mn: 0.7 to 1.7% (however, Mn content [Mn] And C content [C] ratio [Mn] / [C] ≦ 15), Ti: 0.002 to 0.025%, sol. In addition to containing Al: 0.005 to 0.1% and N: 0.001 to 0.008%, Cr: 0.6% or less (including 0%), Mo: 0.5% or less (0 %) And V: 0.08% or less (including 0%), including one or more selected from the group consisting of carbon equivalent Ceq values of 0.34 to It is within the range of 0.42%, and the A value shown by the following formula (2) satisfies 1.1 to 2.6, and the balance is made of a steel plate having a chemical composition composed of Fe and inevitable impurities. And the microstructure of the said steel plate is 40-70 area% polygonal ferrite phase, 0-20 area% pseudopolygonal ferrite phase, and 0-5 area%, and the aspect ratio (major axis / minor axis) is 4. 0.0 or less island martensite phase, balance is composed of bainite phase, 490 MPa class excellent in weldability, characterized in that it has a cold forming portion where t / d is 10% or less, where t is the t (mm) and the outer cold bending diameter is d (mm). Low yield ratio cold formed steel pipe.
Ceq = [C] + [Si] / 24 + [Mn] / 6 + [Ni] / 40 + [Cr] / 5
+ [Mo] / 4 + [V]) / 15 (1)
However, [C], [Si], [Mn], [Ni], [Cr], [Mo] and [V] are the contents (mass of C, Si, Mn, Ni, Cr, Mo and V, respectively). %).
A = (2.16 {Cr} +1) × (3.0 {Mo} +1) × (1.75 {V} +1) (2)
However, {Cr}, {Mo} and {V} indicate the amount of solid solution (mass%) in the steel sheet in Cr, Mo and V, respectively.
更に、Cu:0.5%以下(0%を含まない)および/またはNi:3.0%以下(0%を含まない)を含有するものである請求項1に記載の490MPa級低降伏比冷間成形鋼管。   The 490 MPa class low yield ratio according to claim 1, further comprising Cu: 0.5% or less (not including 0%) and / or Ni: 3.0% or less (not including 0%). Cold formed steel pipe. 更に、Nb:0.015%以下(0%を含まない)を含有するものである請求項1または2に記載の490MPa級低降伏比冷間成形鋼管。   The 490 MPa class low yield ratio cold formed steel pipe according to claim 1 or 2, further comprising Nb: 0.015% or less (not including 0%). 更に、Ca:0.005%以下(0%を含まない)を含有するものである請求項1〜3のいずれかに記載の490MPa級低降伏比冷間成形鋼管。   The 490 MPa class low yield ratio cold formed steel pipe according to any one of claims 1 to 3, further comprising Ca: 0.005% or less (not including 0%). 更に、希土類元素:0.02%以下(0%を含まない)を含有するものである請求項1〜4のいずれかに記載の490MPa級低降伏比冷間成形鋼管。   The 490 MPa class low yield ratio cold-formed steel pipe according to any one of claims 1 to 4, further comprising rare earth element: 0.02% or less (not including 0%). 請求項1〜5のいずれかに記載の冷間成形鋼管を製造するに当り、鋼片を950〜1250℃の温度範囲に加熱し、下記(3)式で示されるオーステナイト未再結晶化温度Aγ(℃)以下での累積圧下率を60%以下(0%を含む)として圧延を終了して鋼板とした後、Ar変態点以上の温度から450℃以下まで4〜100℃/秒の冷却速度で加速冷却し、次いで730〜830℃の温度範囲に再加熱してから焼入れし、引き続き前記載t/dが10%以下の範囲で冷間成形することを特徴とする溶接性に優れた490MPa級低降伏比冷間成形鋼管の製造方法。
γ(℃)=887+467[C]+(6445[Nb]−644√[Nb])+
(732[V]−230√[V])+890[Ti]+363[Al]−357[Si]
…(3)
但し、[C],[Nb],[V],[Ti],[Al]および[Si]は、夫々C,Nb,V,Ti,AlおよびSiの含有量(質量%)を示す。
In producing the cold-formed steel pipe according to any one of claims 1 to 5, the slab is heated to a temperature range of 950 to 1250 ° C, and the austenite non-recrystallization temperature A represented by the following formula (3): After rolling to a steel plate by setting the cumulative reduction rate at γ (° C.) or less to 60% or less (including 0%) to 4 ° C./second from the temperature above the Ar 3 transformation point to 450 ° C. or less. Excellent weldability, characterized by accelerated cooling at a cooling rate, followed by reheating to a temperature range of 730 to 830 ° C. and quenching, followed by cold forming with a t / d of 10% or less. 490 MPa class low yield ratio cold-formed steel pipe manufacturing method.
A γ (° C.) = 887 + 467 [C] + (6445 [Nb] −644√ [Nb]) +
(732 [V] -230√ [V]) + 890 [Ti] +363 [Al] -357 [Si]
... (3)
However, [C], [Nb], [V], [Ti], [Al], and [Si] indicate the contents (mass%) of C, Nb, V, Ti, Al, and Si, respectively.
730〜830℃の温度範囲に再加熱してから焼入れした後、前記鋼板を500℃以下で焼戻しを施す請求項6に記載の製造方法。   The manufacturing method according to claim 6, wherein the steel sheet is tempered at 500 ° C. or lower after being reheated to a temperature range of 730 to 830 ° C. and then quenched. 前記圧延を終了した後、加速冷却するに先立ち、オンラインレベラ矯正を行う請求項6または7に記載の製造方法。   The manufacturing method according to claim 6 or 7, wherein after the rolling is finished, online leveler correction is performed prior to accelerated cooling. 鋼板温度を400℃以下として冷間成形する請求項6〜8のいずれかに記載の製造方法。   The manufacturing method according to any one of claims 6 to 8, wherein cold forming is performed at a steel plate temperature of 400 ° C or lower.
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009019503A (en) * 2007-07-10 2009-01-29 Usui Kokusai Sangyo Kaisha Ltd Steel pipe for fuel injection pipe and manufacturing method thereof
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Families Citing this family (3)

* Cited by examiner, † Cited by third party
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KR101120351B1 (en) * 2008-09-04 2012-03-13 가부시키가이샤 고베 세이코쇼 Steel plate
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JP5480215B2 (en) * 2011-09-08 2014-04-23 株式会社神戸製鋼所 Steel plate for low yield ratio thick circular steel pipe having a tensile strength of 780 MPa or more, manufacturing method thereof, and low yield ratio thick circular steel pipe having a tensile strength of 780 MPa or more

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06264143A (en) * 1993-03-12 1994-09-20 Nippon Steel Corp Production of steel tube with low yield ratio for construction use by cold forming
JPH06264144A (en) * 1993-03-16 1994-09-20 Nippon Steel Corp Production of steel tube with low yield ratio for construction use by cold forming
JP2000178689A (en) * 1998-12-18 2000-06-27 Nkk Corp Steel pipe excellent in buckling resistance and method of manufacturing the same
JP2002220634A (en) * 2001-01-29 2002-08-09 Sumitomo Metal Ind Ltd High-strength steel excellent in strain aging resistance and its manufacturing method
JP2005048289A (en) * 2003-07-16 2005-02-24 Jfe Steel Kk Low yield ratio high strength high toughness steel sheet and method for producing the same
JP2005125351A (en) * 2003-10-22 2005-05-19 Sumitomo Metal Ind Ltd Steel plate production line and steel plate production method

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07109521A (en) * 1993-10-12 1995-04-25 Nippon Steel Corp Manufacturing method of low yield ratio 600N / mm2 class steel pipe for building by cold forming

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06264143A (en) * 1993-03-12 1994-09-20 Nippon Steel Corp Production of steel tube with low yield ratio for construction use by cold forming
JPH06264144A (en) * 1993-03-16 1994-09-20 Nippon Steel Corp Production of steel tube with low yield ratio for construction use by cold forming
JP2000178689A (en) * 1998-12-18 2000-06-27 Nkk Corp Steel pipe excellent in buckling resistance and method of manufacturing the same
JP2002220634A (en) * 2001-01-29 2002-08-09 Sumitomo Metal Ind Ltd High-strength steel excellent in strain aging resistance and its manufacturing method
JP2005048289A (en) * 2003-07-16 2005-02-24 Jfe Steel Kk Low yield ratio high strength high toughness steel sheet and method for producing the same
JP2005125351A (en) * 2003-10-22 2005-05-19 Sumitomo Metal Ind Ltd Steel plate production line and steel plate production method

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US20150361518A1 (en) * 2013-01-24 2015-12-17 Baoshan Iron & Steel Co., Ltd. 500 MPa GRADE LONGITUDINALLY WELDED STEEL PIPE WITH LOW YIELD RATIO AND MANUFACTURING METHOD THEREFOR
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