JP2007017942A - X-ray image recording reading device, and x-ray analyzer - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide an X-ray image recording reading device where a series of treatments from X-ray exposure to a two-dimensional X-ray detector to image reading can be performed in a vacuum atmosphere. <P>SOLUTION: The X-ray image recording reading device comprises: a drum 21a in which the first end side 26a in a two-dimensional X-ray detector 13a is fixed to the outer circumferential face; and a motor 22a of rotating the drum 21a. The motor 22a rotates the drum 21a between the first angle position where the whole face of the detector 13a winds round the drum 21a, and the second angle position where the prescribed region on the side of the second edge side 26b in the detector 13a is arranged at the X-ray exposure position E. The second edge side 26b in the detector 13a wound round the drum 21a is fixed by a pawl 28. The detector 13a, the drum 21a and the pawl 28 are airtightly surrounded by an airtight chamber 34. A reading apparatus 41a is provided oppositely to a quartz glass window 37a provided at the airtight chamber 34. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

  The present invention relates to an X-ray image recording / reading apparatus which records an image by X-rays and reads the recorded image by light. The present invention also relates to an X-ray analyzer configured using the X-ray image recording / reading apparatus.

  2. Description of the Related Art Conventionally, an X-ray analyzer is known in which X-rays emitted from a sample due to diffraction, reflection, scattering, and the like are detected by a two-dimensional X-ray detector using a storage phosphor. Here, the two-dimensional X-ray detector is an X-ray detector that can receive X-rays in a plane. In addition, the stimulable phosphor can store an energy latent image in a portion that has been irradiated with X-rays, and when the portion where the latent image is stored is irradiated with light (for example, laser light), the energy latent image becomes light. It is a substance with the characteristic of being released to the outside.

  The X-ray receiving surface of a two-dimensional X-ray detector having a stimulable phosphor as an X-ray receiving surface is exposed to X-rays, an image is recorded in the X-ray receiving surface, and the recorded image is converted into light. An apparatus that uses and reads is known (for example, see Patent Document 1). In this apparatus, a series of processing from X-ray exposure to image reading for a two-dimensional X-ray detector is automatically performed using a flat support member and a cylindrical rotary drum. .

  Conventionally, an X-ray analysis is configured such that a sample is placed in a vacuum atmosphere, and an image is recorded by irradiating the X-ray light-receiving surface of the two-dimensional X-ray detector in the vacuum atmosphere. The device is known. If the X-ray receiving surface is exposed to X-rays in a vacuum atmosphere, the X-rays can be prevented from being attenuated by air scattering, so even if the X-rays emitted from the sample are weak, the weak X-rays can be suppressed. Can be captured by a two-dimensional X-ray detector. In this X-ray analysis apparatus, when reading the energy latent image accumulated in the two-dimensional X-ray detector, the two-dimensional X-ray detector is taken out from the vacuum atmosphere, and the two-dimensional X-ray detector is placed in the reading device. It is mounted at a predetermined reading position, and reading processing is performed in the mounted state.

JP-A-5-313265 (pages 2 and 3, FIG. 1)

  As described above, in a conventional X-ray analysis apparatus, X-ray recording apparatus, or X-ray reader, the process of exposing the X-ray receiving surface of the two-dimensional X-ray detection means with X-rays in a vacuum atmosphere It was already done. However, the image reading process for the two-dimensional X-ray detection means has not yet been performed in a vacuum atmosphere. This is because the conventional apparatus disclosed in Patent Document 1 uses a vacuum suction method when the two-dimensional X-ray detector is supported by a flat plate-like support member or a cylindrical rotary drum. This is because the rotating drum cannot be placed in a vacuum atmosphere.

  However, in the case of the conventional processing method in which the X-ray exposure processing for the two-dimensional X-ray detector is performed in a vacuum atmosphere, and the processed two-dimensional X-ray detector is taken out of the vacuum atmosphere and read out. It has been very difficult to automatically and continuously perform the processing from X-ray exposure to image reading for a two-dimensional X-ray detector.

  The present invention has been made in view of the above problems, and a series of processing from X-ray exposure to image reading for a two-dimensional X-ray detection means is performed in a special atmosphere different from the outside, for example, in a vacuum atmosphere. It is an object of the present invention to provide an X-ray image recording / reading apparatus which can be performed by

  An X-ray image recording / reading apparatus according to the present invention records an image by exposing an X-ray receiving surface of a two-dimensional X-ray detection means placed at an X-ray exposure position with X-rays, and further reads the image with light. An X-ray image recording / reading apparatus comprising: a detection means processing means and an airtight chamber; (a) the detection means processing means has (a) a cylindrical outer peripheral surface and the two-dimensional X-ray detection. Detecting means supporting means in which a first end of the means is fixed to the outer peripheral surface; (a) supporting means rotating means for rotating the detecting means supporting means about the central axis of the cylindrical shape; Edge fixing means for fixing the second end opposite to the first edge of the two-dimensional X-ray detection means that rotates integrally with the detection means support and is wound around the detection means support; (D) provided in the airtight chamber And (i) a reading means provided outside the hermetic chamber and facing the first light transmitting section, and (i) the support means rotating means includes the two-dimensional A first angular position where the entire surface of the X-ray detection means wraps around the detection means support means, and the second end of the two-dimensional X-ray detection means protrudes away from the detection means support means and the two-dimensional X-rays The detection means support means is rotated between a predetermined area of the X-ray light receiving surface of the detection means and a second angular position at which the predetermined area is arranged at the X-ray exposure position, and (ii) the first light transmission portion is the detection means. (B) The airtight chamber surrounds the two-dimensional X-ray detection means, the detection means support means, and the edge fixing means. .

  In this specification, the “two-dimensional X-ray detection means” can be formed by, for example, a sheet-like X-ray detection member in which an X-ray light receiving surface is planarly formed by a stimulable phosphor. The stimulable phosphor can be formed by a photosensitive member called an imaging plate (registered trademark) or the like. The “detecting means supporting means” can be formed by, for example, a cylindrical member, that is, a drum-shaped member. The “support means rotating means” is formed by a mechanism that uses a rotating machine capable of controlling the number of rotations, such as a stepping motor, a servo motor, etc., as a power source, and transmits the power to the detecting means support means via an appropriate power transmission means. it can.

  Further, the “end side fixing means” can be constituted by one or a plurality of openable and closable claw members that can rotate integrally with the detection means support means such as a rotating drum. When a plurality of claw members are used, it is desirable that the claw members are arranged side by side in parallel with the rotation axis of a rotating drum or the like. After inserting the edge of the two-dimensional X-ray detector between the claw member in the open state and the surface of the rotating drum, etc., if the claw member is closed, the two-dimensional X-ray detector is rotated. It can be pressed against the surface of a drum or the like.

  The “airtight chamber” can be formed of, for example, structural steel such as stainless steel or hard plastic. The shape of the hermetic chamber can be freely set according to the shape of the mechanical and electrical components housed therein. The “first light transmitting portion” can be formed of, for example, quartz glass fitted in a part of the hermetic chamber.

  The “reading unit” includes, for example, a unit that irradiates the X-ray receiving surface of the two-dimensional X-ray detection unit with excitation light (that is, primary light), and X-ray reception by receiving the primary light. It can be configured by an electro-optical device having photoelectric conversion means (for example, a photomultiplier) that receives light (that is, secondary light) generated from the surface and converts it into an electric signal. The “erasing light irradiating means” can be formed by, for example, a fluorescent lamp that emits white light.

  According to the X-ray image recording / reading apparatus having the above-described configuration according to the present invention, the X-ray receiving surface of the two-dimensional X-ray detection means is set to X while the two-dimensional X-ray detection means is housed in the airtight chamber. It is possible to perform image reading processing continuously without taking out the two-dimensional X-ray detection means from the hermetic chamber. That is, according to the X-ray image recording / reading apparatus of the present invention, a series of processing from X-ray exposure to image reading for the two-dimensional X-ray detection means can be performed in an atmosphere state in an airtight chamber, for example, in a vacuum atmosphere. it can. As a result, the processing from the X-ray exposure in a vacuum atmosphere to the image reading can be performed continuously in a short time and a plurality of times as necessary.

  Next, in the X-ray image recording / reading apparatus according to the present invention, the detection means processing means is provided in the airtight chamber at a position opposite to the detection means support means and at a position different from the first light transmission portion. It is desirable to have a second light transmission part and an erasing light irradiation means provided outside the hermetic chamber and facing the second light transmission part. If the two-dimensional X-ray detection means is irradiated with light by the erasing light irradiation means, the energy latent image remaining on the two-dimensional X-ray detection means is erased and the two-dimensional X-ray detection means is set to an initial reusable state. it can.

  The erasing light irradiation means can be provided inside the hermetic chamber instead of outside the hermetic chamber. However, considering the case of replacing the erasing light irradiation means, it is convenient that the erasing light irradiation means is outside the hermetic chamber.

  Next, in the X-ray image recording / reading apparatus according to the present invention, only one set of the detection means processing means may be provided on one side of the X-ray exposure position, or on both sides of the X-ray exposure position. Two sets may be provided in total, one set at a time. When the detector processing means and the like are provided on both sides of the X-ray exposure position, the support means rotating means can individually rotate the detection means support means provided on both sides of the X-ray exposure position. desirable.

  The combination of the detecting means supporting means and the supporting means rotating means is for taking out or retracting the two-dimensional X-ray detecting means toward the X-ray exposure position, but the supporting means rotating means supports the detecting means. To rotate the means individually means that the two-dimensional X-ray detection means can be taken out or retracted at a unique timing from the pair of detection means support means. According to this configuration, a series of processing from X-ray exposure processing to image reading processing for the two-dimensional X-ray detection means can be performed very efficiently by effectively using the pair of two-dimensional X-ray detection means. Can do.

  Next, it is desirable that the X-ray image recording / reading apparatus according to the present invention further includes a detection means fixing / arranging means for fixing and arranging the two-dimensional X-ray detection means protruding from the detection means supporting means at an X-ray exposure position. . In that case, it is desirable that the airtight chamber surrounds the detection means fixing and arranging means. In this case, the detection means fixing and arranging means includes, for example, a face plate arranged at the X-ray exposure position and an opening arranged on the upstream side of the face plate with respect to the X-ray traveling direction to allow X-rays to pass therethrough. It is desirable to have a clamp plate provided and a clamp moving means for moving the clamp plate in parallel toward the face plate.

  If the detection means fixing / arranging means is provided as in the aspect of the present invention, the two-dimensional X-ray detection means can be used when exposing the two-dimensional X-ray detection means protruding from the detection means support means. Since the X-ray exposure position can be firmly fixed so as not to vibrate or shift, highly reliable X-ray image data can be obtained in the two-dimensional X-ray detection means.

  Next, it is preferable that the X-ray image recording / reading apparatus according to the present invention further includes a detection unit pressing unit that presses the two-dimensional X-ray detection unit wound around the detection unit support unit against the detection unit support unit. The detection means pressing means can be constituted by, for example, a rotating roller that comes into contact with the surface of the detection means support means in an appropriate pressure state.

  In the present invention, when the image reading process is performed on the two-dimensional X-ray detection unit, the entire two-dimensional X-ray detection unit is wound around the detection unit support unit, and then the reading process is executed. At this time, if the two-dimensional X-ray detection means is simply wrapped around the detection means support means, the two-dimensional X-ray detection means may be peeled off or displaced from the detection means support means during the reading process. In this case, highly reliable X-ray image data cannot be obtained in the two-dimensional X-ray detection means. On the other hand, if the detection means pressing means is equipped on the detection means support means as in the aspect of the present invention, the two-dimensional X-ray detection means is peeled off from the detection means support means during the reading process, Misalignment can be prevented, and therefore highly reliable X-ray image data can be obtained with certainty.

  Next, an X-ray analyzer according to the present invention is for an X-ray optical system that irradiates a sample with X-rays to generate secondary X-rays from the sample, and an optical system that hermetically surrounds the X-ray optical system. An X-ray receiving surface of an airtight chamber, a decompression means for sucking air inside the airtight chamber for the optical system to decompress the inside, and an X-ray receiving surface of a two-dimensional X-ray detection means placed at an X-ray exposure position An X-ray analysis apparatus comprising: an X-ray image recording / reading apparatus that records an image by exposure with the secondary X-ray from an optical system, and further reads the image with light; (A) the X-ray image; The recording / reading apparatus has a detection means processing means and an airtight chamber. (A) The detection means processing means has (a) a cylindrical outer peripheral surface and a first end of the two-dimensional X-ray detection means. Detecting means supporting means whose side is fixed to the outer peripheral surface; and (a) the detecting means supporting means is (C) the two-dimensional X-ray detection means in a state of being rotated integrally with the detection means support means and wound around the detection means support means; An edge fixing means for fixing the second edge facing the first edge; (d) a first light transmitting portion provided in the airtight chamber; and (e) an outside of the airtight chamber, (I) the support means rotating means has a first angle at which the entire surface of the two-dimensional X-ray detection means is wound around the detection means support means. And a predetermined region of the X-ray light receiving surface of the two-dimensional X-ray detection means is arranged at the X-ray exposure position by projecting the second end side of the two-dimensional X-ray detection means away from the detection means support means Between the second angular position to be (Ii) the first light transmission portion is provided in the airtight chamber at a position facing the detection means support means, and (b) the airtight chamber includes the two-dimensional X-ray detection means, Surrounding the detection means support means and the edge fixing means, (c) the airtight chamber is hermetically connected to the optical system airtight chamber.

  According to the X-ray analysis apparatus having the above-described configuration according to the present invention, the X-ray receiving surface of the two-dimensional X-ray detection means is X-rayed while the two-dimensional X-ray detection means is housed in the airtight chamber. The exposure can be performed, and the image reading process can be continuously performed without removing the two-dimensional X-ray detection means from the hermetic chamber. That is, according to the X-ray analysis apparatus of the present invention, a series of processing from X-ray exposure to image reading for the two-dimensional X-ray detection means can be performed in an atmosphere state in an airtight chamber, for example, in a vacuum atmosphere. Thereby, it is possible to perform image reading processing from X-ray exposure in a vacuum atmosphere in a short time and continuously a plurality of times as necessary.

(First embodiment)
Hereinafter, an X-ray image recording / reading apparatus and an X-ray analysis apparatus according to the present invention will be described based on embodiments. Of course, the present invention is not limited to this embodiment.

  FIG. 1 shows an embodiment of an X-ray analyzer and an X-ray image recording / reading apparatus according to the present invention. FIG. 2 shows the internal structure of the X-ray image recording / reading apparatus, which is the main part of FIG. FIG. 3 shows a cross-sectional structure of the X-ray exposure position according to the line AA in FIG.

  In FIG. 1, an X-ray analyzer 1 according to the present embodiment includes an X-ray measuring device 2 and an X-ray image recording / reading device 3. The X-ray measuring apparatus 2 includes an X-ray optical system 4, an optical system hermetic chamber 6 surrounding the X-ray optical system 4, and a reduced pressure for reducing the inside of the optical system hermetic chamber 6 to a reduced pressure state, for example, a vacuum state. And a decompression pump 8 as means. Although only a part of the optical system hermetic chamber 6 is shown in FIG. 1, the optical system hermetic chamber 6 hermetically surrounds the entire X-ray optical system 4. The optical system hermetic chamber 6 can be formed of, for example, structural steel such as stainless steel or hard plastic.

  The X-ray optical system 4 includes an X-ray source F that generates X-rays and a sample holder 7 that supports the sample S. The X-ray source F can be configured by, for example, a filament that generates heat electrons by generating heat when energized, and a target that is disposed to face the filament. The target is formed of a metal according to demand, for example, Cu (copper). If the target is made of Cu, X-rays including CuKα rays can be generated. The sample holder 7 may support the sample S in a fixed state, or may give a predetermined movement to the sample S.

  Examples of such predetermined movement include ω rotational movement for changing the incident angle of X-rays incident on the sample S, in-plane rotational movement for rotating the sample S in a plane, A tilting movement that swings and a variety of other movements are conceivable. Note that the X-ray optical system 4 may be an optical system using radiation light as a radiation source.

  The X-ray optical system 4 irradiates the sample S with the primary X-ray R1 to generate a secondary X-ray R2, for example, a diffraction line, a reflection line, and a scattered line from the sample S. The optical system hermetic chamber 6 holds the entire X-ray optical system 4 in a reduced pressure state such as a vacuum state. The X-ray optical system 4 is maintained in a reduced pressure state in this manner because X-rays that are emitted from the X-ray source F and incident on the sample S, secondary X-rays emitted from the sample S, and the like are attenuated by air. This is to prevent it.

  The X-ray image recording / reading apparatus 3 has a housing case 11 in which the structure shown in FIG. 2 is accommodated. In FIG. 2, the detector fixed arrangement device 12 is provided at a position E where the exposure is performed by the secondary X-ray R2 (that is, an X-ray exposure position). As shown in FIG. 3, the detector fixing and arranging device 12 has a face plate 14 that supports plate detectors 13a and 13b as two-dimensional X-ray detection means exposed from secondary X-rays R2 from the back surface thereof, A clamp plate 16 disposed upstream of the face plate 14 with respect to the traveling direction of the X-ray R2, a movable plate 18 coupled to the clamp plate 16 via a space member 17, and a rotary solenoid connected to the back surface of the movable plate 18 19. The combination of the space member 17, the movable plate 18, and the rotary solenoid 19 functions as a clamp moving unit that translates the clamp plate 16 relative to the face plate 14.

  The face plate 14 is a single plate made of metal or plastic having a rectangular or square shape having a height larger than the width W0 of the plate detectors 13a and 13b. The face plate 14 is fixed so that its position does not move. As shown in FIG. 2, the clamp plate 16 is a metal or plastic frame-like member having an opening Q for exposing the X-ray light receiving surfaces of the plate detectors 13a and 13b with X-rays.

  In the present embodiment, two rotary solenoids 19 are provided corresponding to the diagonal lines of the movable plate 18. In FIG. 3, the output shaft 19 a of these rotary solenoids 19 is fixed to the back surface of the movable plate 18. As is well known, the rotary solenoid 19 is a device that has a rotor inside and converts the reciprocal rotation of the rotor in the forward and counterclockwise direction into a reciprocating linear movement of the output shaft 19a by screw fitting.

  When the output shaft 19a moves back and forth, the movable plate 18 moves in parallel, and the clamp plate 16 moves in parallel accordingly. When the output shaft 19a extends to the extended position, a large space is formed between the clamp plate 16 and the face plate 14, and the plate detectors 13a and 13b can enter the large space. When the output shaft 19a is retracted to the contracted position when the plate detectors 13a and 13b are between the clamp plate 16 and the face plate 18, the clamp plate 16 presses the plate detectors 13a and 13b against the face plate 18, Thereby, the plate-like detectors 13a and 13b are arranged in a fixed state at the X-ray exposure position E.

  In FIG. 2, detector processing units 20 a and 20 b as detection means processing means are provided on each of the left and right sides of the X-ray exposure position E. The individual detector processing units 20a and 20b include plate-like detectors 13a and 13b, drums 21a and 21b as detecting means supporting means for supporting them, motors 22a and 22b as supporting means rotating means, and end sides. It has a plurality of claw members 28 as fixing means, quartz glass windows 37a and 37b as first light transmission parts, and reading devices 41a and 41b provided facing the quartz glass windows 37a and 37b.

  The apparatus having the drums 21a and 21b, the motors 22a and 22b, and the plurality of claw members 28 feeds the plate detectors 13a and 13b to the X-ray exposure position E and winds up from the X-ray exposure position E. It is a device for. FIG. 2 shows a state in which the right detector processing unit 20a feeds the plate detector 13a to the X-ray exposure position E, and the left detector processing unit 20b winds up the plate detector 13b. Yes.

  The drums 21a and 21b are provided symmetrically with respect to the X-ray exposure position E. These drums 21a and 21b are formed in a cylindrical shape by, for example, metal or plastic. The shafts 24a and 24b extending from the drums 21a and 21b are connected to the output shafts of the motors 22a and 22b, respectively. These motors 22a and 22b rotate the output shafts 24a and 24b, respectively, at a rotation speed and a rotation angle controlled according to a command from the rotation control device 23. The rotation control device 23 individually controls the operations of the motor 22a and the motor 22b.

  The first ends 26a of the plate detectors 13a and 13b are fixed to the drum 21a and the drum 21b, respectively, by screws or other fastening elements. The second end sides 26b of the plate detectors 13a and 13b facing the first end side 26a are sides that are not fixed to the drums 21a and 21b, that is, free sides. A shaft member 27 extending in parallel to the central axis X0 of the drums 21a and 21b is provided on the outer peripheral surface in the vicinity of the portion where the plate detectors 13a and 13b are fixed in the outer peripheral surfaces of the drums 21a and 21b. Yes. These shaft members 27 are attached to the drums 21a and 21b so that each of the shaft members 27 can independently rotate about its own axis.

  A plurality of claw members 28 as end side fixing means are fixed to each shaft member 27. These claw members 28 rotate together with the shaft member 27. The shaft member 27 is biased by an elastic biasing member such as a spring or the like, and is given a rotational behavior such that the shaft member 27 rotates in a direction opposite to the first end side 26a of the plate detectors 13a and 13b. Therefore, the claw member 28 that rotates integrally with the shaft member 27 normally presses the outer peripheral surfaces of the drums 21a and 21b with elastic force.

  A claw-side engagement piece 29 is fixed to the upper portion of the shaft member 27. On the other hand, a fixed engagement piece 31 is provided on the machine frame near the upper ends of the drums 21a and 21b. The claw-side engagement piece 29 moves according to the rotation of the drums 21a and 21b. On the other hand, the fixed engagement piece 31 is always in a fixed position independently of the drums 21a and 21b. A plurality of, in the present embodiment, four pressing rollers 32 are provided as detecting means pressing means in positions near the drums 21a and 21b and at a predetermined distance from the X-ray exposure position E.

  These presser rollers 32 are rotatably provided on a roller shaft 33, respectively. These presser rollers 32 are connected to the drums 21a. The outer peripheral surface of 21b is contacted with an appropriate pressure. When the drums 21a and 21b rotate, the claw member 28 also rotates integrally. These claw members 28 that rotate are passed through the place where the presser roller 32 is provided according to the rotation of the drums 21a and 21b. In order to avoid the claw member 28 that rotates from hitting the presser roller 32, the plurality of claw members 28 and the plurality of presser rollers 32 are arranged at alternate positions along the axis X <b> 0.

  In the plate-like detector 13a shown on the right side of the X-ray exposure position E in FIG. 2, the second end side 26b extends away from the drum 21a. A predetermined region of the protruding portion is fixed at the X-ray exposure position E by the detector fixing / arranging device 12. On the other hand, the left plate-shaped detector 13b is entirely wound around the outer peripheral surface of the drum 21b. The second end side 26b of the plate detector 13b is pressed against the outer peripheral surface of the drum 21b by the claw member 28.

  When the clamp of the plate detector 13a by the detector fixing arrangement device 12 is released, the right drum 21a is rotated from the illustrated state in the direction indicated by the arrow A, that is, in the direction of winding the plate detector 13a. The state detector 13a is gradually wound around the drum 21a. During the winding operation, the presser roller 32 presses the plate detector 13a against the outer peripheral surface of the drum 21a. As a result, the plate-like detector 13a is wound up in a state in which the plate-like detector 13a is in surface contact with the outer peripheral surface of the drum 21a.

  When the second end 26b of the plate-like detector 13a wound up in this way comes close to the drum 21a, the claw-side engagement piece 29 fixed to the upper end of the shaft member 27 that supports the claw member 28 is fixed to the fixed engagement piece 31. It hits. Then, the claw-side engaging piece 29 rotates with the shaft member 27, and the claw member 28 on the shaft member 27 that has been closed until then opens and rotates. The second end 26a of the plate detector 13a that has arrived at the drum 21a enters between the claw member 28 opened as described above and the outer peripheral surface of the drum 21a.

  When the drum 21a rotates to a predetermined final angle position for winding, the claw side engagement piece 29 and the fixed engagement piece 31 are disengaged, and the claw member 28 is instantaneously closed and rotated by the spring force. By the claw member 28 thus closed, the second end side 26b of the plate detector 13a is pressed against the outer peripheral surface of the drum 21a and fixed. Thereby, the plate-shaped detector 13a is supported in a state where it is not easily peeled off from the outer peripheral surface of the drum 1a. As described above, in the present embodiment, the plate-shaped detector 13a can be wound around the drum 21a in close contact with the cooperation of the claw member 28 and the pressing roller 32.

  The plate-like detector 13b located on the left side of the X-ray exposure position E in FIG. 2 shows a state in which the entire surface is wound around the outer peripheral surface of the drum 21b as described above. When the drum 21b rotates from this state in the direction of the arrow B, the claw-side engagement piece 29 immediately hits the fixed engagement piece 31 and opens and rotates. The two end sides 26b are opened. The opened second end side 26b is separated from the drum 21b, and further protrudes in the tangential direction of the outer peripheral surface of the drum 21b as the drum 21b rotates in the arrow B direction.

  The second end side 26 b of the plate-like detector 13 b that moves overhangs into the gap between the clamp plate 16 and the face plate 14. Thereafter, when the drum 21b rotates to a predetermined final angular position for unwinding, a predetermined region on the second end side 26b side of the plate detector 13b is exposed to the outside from the opening Q of the clamp plate 16. In this state, when the clamp plate 16 is pulled by the solenoid 19 in FIG. 3, the plate detector 13 b is pressed against the face plate 14 by the clamp plate 16 and fixed.

  The plate-like detectors 13a and 13b are rectangular and plate-like elements, and are formed by laminating a stimulable phosphor having a uniform thickness over the entire surface of a rectangular substrate. The layer of the stimulable phosphor constitutes the X-ray light receiving surface. In FIG. 3, the surface irradiated with X-rays R2 is the surface of the stimulable phosphor layer, that is, the X-ray light receiving surface. The stimulable phosphor is a well-known optical material, for example, an element having the following characteristics.

  That is, when the storable phosphor is exposed to synchrotron radiation or X-rays, an energy latent image is accumulated in the contacted phosphor. Then, when primary light (for example, laser light) is irradiated to the portion where the latent image is accumulated in this manner, the latent image is converted into light and emitted to the outside as secondary light. A plate-like detector having such a storage phosphor as an X-ray light receiving surface is known as an imaging plate (registered trademark), for example.

  In FIG. 2, the structure for unwinding and winding the plate detectors 13a and 13b, that is, the structure including the drums 21a and 21b, the pressing roller 32, the claw member 28, and the like, and the detector fixing and arranging device 12 Is covered by an airtight chamber 34. An opening 36 for capturing X-rays is formed in one of a plurality of surfaces forming the airtight chamber 34. The airtight chamber 34 is airtightly covered with a portion other than the opening 36. The hermetic chamber 34 is formed of, for example, structural steel such as stainless steel, plastic, or the like. The above-described motors 22a and 22b for rotationally driving the drums 21a and 21b are provided outside the airtight chamber 34.

  A quartz glass window 37a serving as a first light transmission portion is provided in a portion facing the drum 21a disposed on the right side of the X-ray exposure position E in the rear side partition that forms the airtight chamber 34. In addition, a quartz glass window 37b as another first light transmission portion is provided in a portion of the rear side partition facing the drum 21b disposed on the left side of the X-ray exposure position E. Further, a quartz glass window 38a as a second light transmission portion is provided in a portion facing the drum 21a disposed on the right side of the X-ray exposure position E in the right partition that forms the hermetic chamber 34. In addition, a quartz glass window 38b as another second light transmitting portion is provided in a portion facing the drum 21b disposed on the left side of the X-ray exposure position E in the left partition wall forming the hermetic chamber 34. .

  A reading device 41a is provided at a position outside the quartz glass window 37a as the first light transmission portion, and another reading device 41b is provided at a position outside the quartz glass window 37b as the other first light transmission portion. Yes. Further, a fluorescent lamp 42a as an erasing light irradiating means is provided at a position outside the quartz glass window 38a as the second light transmitting portion, and an erasing is performed at a position outside the quartz glass window 38b as another second light transmitting portion. A fluorescent lamp 42b is provided as a light irradiation means. The fluorescent lamps 42a and 42b emit light having a wavelength that can erase the energy latent image accumulated on the X-ray receiving surfaces of the plate detectors 13a and 13b.

  The quartz glass forming the quartz glass windows 37a, 37b, 38a, 38b is subjected to a treatment for suppressing light reflection, for example, a coating treatment. This coating process is a process of laminating material layers on one or both front and back surfaces such as quartz glass, but the function of suppressing reflection may be realized by the characteristics of the material itself that constitutes the material layer. The function may be realized depending on how. Further, the present invention is not limited to the coating process, and if the reflection suppressing function can be realized by processing the surface of quartz glass or other window forming material, such processing may be added to quartz glass or the like. In this embodiment, the reflectance of the quartz glass windows 37a, 37b, 38a, and 38b is set to 2.2% by coating a single layer of a material capable of suppressing reflection on both the front and back surfaces of the quartz glass with a thickness of 650 nm. did.

  FIG. 4 shows the structure of the readers 41a and 41b when the readers 41a and 41b are viewed from the direction of arrow C in FIG. In FIG. 4, the reading devices 41 a and 41 b include a feed screw shaft 43 extending in parallel with the center axis X 0 of the drums 21 a and 21 b and a scanning moving body 44 that is screwed to the feed screw shaft 43. In the scanning moving body 44, a laser light generating device 46 as primary light generating means for generating laser light L1 as primary light, a prism 47 for reflecting laser light, and a lens 48 for refracting light. , A blue filter 49 that suppresses the passage of the laser light L1, and a photomultiplier as photoelectric conversion means that receives the secondary light L2 generated by the plate detectors 13a and 13b and condensed by the lens 48 (ie, Photomultiplier tube) 51 is provided. An X-ray intensity calculation circuit 58 is electrically connected to the output terminal of the photomultiplier 51. The surface of the lens 48 is subjected to a coating process for suppressing light reflection in the same manner as the quartz glass windows 37a, 37b, 38a, and 38b.

  The blue filter 49 has a property of suppressing the passage of the laser light L1 and allowing the passage of the secondary light L2 generated by the plate detectors 13a and 13b. Further, as shown in FIG. 5A, a region 53 for allowing the laser light L1 to pass therethrough is provided in a portion of the blue filter 49 through which the laser light L1 that has passed through the lens 48 passes. The laser beam passage region 53 can be formed by, for example, making a through hole in the blue filter 49. Further, when the blue filter 49 is formed by coating a blue filter material on a transparent base material, the laser light passage region 53 can be formed by not coating the portion with the blue filter material. Note that the front and back surfaces of the blue filter 49 are subjected to the same light reflection suppressing coating treatment as that applied to the quartz glass windows 37a, 37b, 38a, and 38b.

  The laser beam passage region 53 is formed in a circular shape when viewed from the direction of the arrow D. This circular diameter is desirably as small as possible within a range in which the laser beam L1 can pass. In the present embodiment, the diameter of the laser beam passage region 53 is 2 mm in diameter. An opening member 54 is provided in front of the laser beam passage region 53. The opening member 54 is formed by providing a circular through hole in the center of a disk or square plate as viewed from the direction of the arrow D made of metal or plastic. The through hole is formed with a diameter of 0.8 mm, for example. An opening member 56 is also provided at a position in front of the laser beam exit of the laser generator 46. The opening member 56 is formed, for example, by providing a circular through hole in the center of a metal or plastic disk or square plate. The through hole is formed with a diameter of 1.5 mm, for example.

  In FIG. 4, the drums 21a and 21b are driven by the motors 2a and 22b and rotate around their own central axis X0. At this time, the plate detectors 13a and 13b wound on the outer peripheral surfaces of the drums 21a and 21b also rotate together. At this time, if the laser beam L1 is irradiated from the scanning moving body 44 to the plate detectors 13a and 13b, the laser beam L1 passes through the plate detectors 13a and 13b in the lateral direction (that is, the direction perpendicular to the paper surface of FIG. 4). Scan to. Such scanning of the laser beam L1 in the horizontal direction with respect to the plate detectors 13a and 13b is main scanning.

  Next, the feed screw shaft 43 is connected to an output shaft of a motor 52 (for example, a pulse motor, a servo motor, etc.) capable of controlling the rotation speed. For example, when the motor 52 rotates the output shaft in the clockwise direction, the feed screw shaft 43 rotates about its own axis in the same direction, and the scanning moving body 44 fitted with the screw moves parallel to the arrow Z direction. To do. On the other hand, when the motor 52 rotates its output shaft in the counterclockwise direction, the scanning moving body 44 translates in the Z ′ direction, which is the opposite direction.

  When the scanning moving body 44 moves in the Z direction, the laser light L1 emitted from the scanning moving body 44 scans the plate detectors 13a and 13b in the vertical direction (that is, the vertical direction in FIG. 4). Such vertical scanning of the laser beam L1 with respect to the plate detectors 13a and 13b is sub-scanning. The movement of the scanning moving body 44 in the Z ′ direction is a movement for returning to the home position. As described above, the laser beam L1 scans the plate-like detectors 13a and 13b in the main scanning and sub-scanning so that the entire X-ray light receiving surface of the plate-like detectors 13a and 13b can be scanned with the laser beam L1.

  In FIG. 5A, the laser light L 1 emitted from the laser light generator 46 is reflected by the prism 47 through the opening of the opening member 56 and enters the lens 48. The incident point A of the laser beam L1 to the lens 48 is deviated from the central axis of the lens 48, that is, the optical axis X1 of the lens 48, as shown in FIG. Specifically, the laser beam L1 is shifted with respect to both the main scanning direction and the sub-scanning direction with respect to the plate detectors 13a and 13b. More specifically, the incident point A is shifted to the front side (that is, the downstream side) in the main scanning direction with respect to the lens optical axis X1, and is shifted to the front side (that is, the downstream side) in the sub-scanning direction. More specifically, the incident point A is set at a position of an angle θ0 = 45 ° with respect to the main scanning direction and an angle θ1 = 45 ° with respect to the sub-scanning direction.

The operation of the X-ray analyzer having the above configuration will be described below.
In FIG. 1, the tip of the optical system hermetic chamber 6 constituting the X-ray measuring apparatus 2 and the opening 36 (see FIG. 2) provided in the hermetic chamber 34 in the X-ray image recording / reading apparatus 3 are coupled. The device 57 is connected in an airtight manner. As a result, the entire X-ray measuring device 2 and the X-ray image recording / reading device 3 are completely sealed from the outside. The housing case 11 does not need to cover the airtight chamber 34 in an airtight manner.

  Next, the pressure reducing pump 8 attached to the X-ray measuring apparatus 2 is operated to evacuate or close to the optical system hermetic chamber 6 of the X-ray measuring apparatus 2 (hereinafter, these states are simply referred to as a vacuum state). ). At this time, the inside of the hermetic chamber 34 in the X-ray image recording / reading apparatus 3 is also evacuated through the opening 36 and set to a vacuum or a reduced pressure state close thereto.

  Next, in the airtight chamber 34 in the X-ray image recording / reading apparatus 3, as shown in FIG. 2, the right detector processing unit 20a including the drum 21a and the plate-like detector 13a, or the drum 21b and the plate-like shape. The plate-like detector 13a or 13b is projected from any one of the left detector processing units 20b including the detector 13b, and the plate-like detector 13a or 13b is placed at the X-ray exposure position E. The detector 13 a or 13 b is fixed by the detector fixing / arranging device 12. In the following description, it is assumed that the plate detector 13a on the right side protrudes to the X-ray exposure position E as shown in FIG.

  Thereafter, in FIG. 1, X-rays are emitted from the X-ray source F and are incident on the sample S. When a predetermined diffraction condition is satisfied between the X-ray incident on the sample S and the crystal in the sample S, a diffraction line as a secondary X-ray R2 is emitted from the sample S. Further, depending on the type of measurement, scattered rays and fluorescent X-rays are emitted as secondary X-rays R2. The secondary X-ray R2 exposes the X-ray receiving surface of the plate detector 13a placed at the X-ray exposure position E in FIG. By this X-ray exposure, an energy latent image is formed and stored where the X-ray of the plate-like detector 13a hits. Since both the airtight chamber 6 for the optical system and the airtight chamber 34 in FIG. 1 are in a vacuum state, the X-rays that exit the X-ray source F and reach the X-ray exposure position E are attenuated by air scattering. Therefore, even when the intensity of the secondary X-ray R2 emitted from the sample S is weak, a clear energy latent image can be formed on the plate detector 13a.

  As described above, an energy latent image corresponding to the secondary X-ray R2 generated corresponding to the crystal structure inside the sample S is accumulated in the plate detector 13a. Then, the latent image is read as follows. That is, in FIG. 2, the drum 21a in the right detector processing unit 20a is driven by the motor 22a to rotate in the arrow A direction. Then, the plate detector 13a is wound around the drum 21a according to the rotation of the drum 21a. At this time, the plate detector 13a is pressed against the outer peripheral surface of the drum 21a by the pressing roller 32, so that the plate detector 13a is in close contact with the outer peripheral surface of the drum 21a.

  When the drum 21a is rotated almost once, the second end 26b of the plate detector 13a approaches the outer peripheral surface of the drum 21a, and the claw-side engagement fixed to the upper end of the shaft member 27 to which the claw member 28 is fixed. The combined piece 29 approaches the fixed engagement piece 31. As the drum 21a continues to rotate, the claw-side engagement piece 29 hits the fixed engagement piece 31, the claw-side engagement piece 29 opens and moves, and the claw member 28 resists the elastic force of an elastic member such as a spring. Open away from the outer peripheral surface of the drum 21a. Then, the second end piece 26b of the plate-like detector 13a enters between the opened claw member 28 and the outer peripheral surface of the drum 21a.

  When the drum 21a continues to rotate, the claw-side engagement piece 29 is disengaged from the fixed engagement piece 31, and the claw member 28 moves back onto the outer peripheral surface of the drum 21a by the elastic force of an elastic member such as a spring. Thus, the second end piece 26b of the plate detector 13a is pressed against the outer peripheral surface of the drum 21a, and the entire surface of the plate detector 13a is held in close contact with the outer peripheral surface of the drum 21a. FIG. 4 shows a state where the entire surface of the plate detector 13a is held on the outer peripheral surface of the drum 21a.

  Thereafter, processing for reading the energy latent image accumulated in the X-ray light receiving surface of the X-ray detector 13a is performed. In the reading process, the scanning moving body 44 of FIG. 4 is initially placed at the home position, which is a position corresponding to the upper end of the plate-like detector 13a. When the reading process is started, the drum 21a is driven by the motor 22a and rotates at a predetermined rotation speed. At the same time, the scanning moving body 44 is driven by the motor 52 and the feed screw shaft 43 to translate in the arrow Z direction at a predetermined speed.

  At the same time, the laser beam L1 is emitted from the laser beam generator 46, the laser beam L1 is reflected by the prism 47 and incident on the lens 48, and after the laser beam L1 is refracted by the lens 48, the blue filter 49 and The light passes through the quartz glass window 37a and is irradiated to the plate detector 13a on the drum 21a. In this embodiment, since the plate-shaped detector 13a is irradiated with the laser beam L1 through the quartz glass window 37a as a partition wall, the laser beam L1 is left in a state where the plate-shaped detector 13a is placed in a vacuum atmosphere. Can be irradiated to the plate detector 13a.

  The laser beam L1 irradiating the plate detector 13a performs main scanning on the plate detector 13a according to the rotation of the drum 21a, and further sub-scans the plate detector 13a according to parallel movement in the Z direction of the scanning moving body 44. To do. By these main scanning and sub scanning, the laser beam L1 scans the entire surface of the X-ray receiving surface of the plate detector 13a. While this scanning is being performed, when the laser beam L1 is irradiated on the portion inside the X-ray light receiving surface of the plate-like detector 13a and holding the energy latent image, it is shown in FIG. As described above, light is excited from the energy latent image and emitted as secondary light L2.

  The emitted secondary light L2 passes through the quartz glass window 37a and the blue filter 49, and is refracted by the lens 48 and directed to the photomultiplier 51. The photomultiplier 51 outputs a signal corresponding to the amount of the received secondary light L2, and this output signal is transmitted to the X-ray intensity calculation circuit 58 of FIG. The X-ray intensity calculation circuit 58 calculates the X-ray intensity by calculation based on the received signal.

  When the X-ray light receiving surface of the plate detector 13a is viewed in plan, the position where the secondary light L2 is emitted can be specified by the position in the main scanning direction and the position in the sub scanning direction. The position in the X-ray light receiving surface specified in this way corresponds to the X-ray diffraction angle diffracted by the sample S in FIG. Specifically, the origin that intersects the X-ray optical axis X2 is the position at the diffraction angle 2θ = 0 °, and the diffraction angle 2θ increases as the distance from the origin increases. A point on one circle centered on the origin is It represents that they are at the same diffraction angle. When a plurality of energy latent images are recorded on one circle centered on the origin, the X-ray intensity calculation circuit 58 in FIG. 4 integrates signals resulting from these latent images to obtain one diffraction angle 2θ. Calculated as X-ray intensity. In this way, the diffraction angle 2θ of the secondary X-ray emitted from the sample S and the intensity I of the secondary X-ray are obtained and stored as (2θ, I) data in an appropriate storage medium. The stored measurement data is displayed as an image on the screen of the image display device as needed, or printed on paper by a printer.

  When the image reading process for the plate detector 13a is completed as described above, the energy remaining on the X-ray receiving surface of the plate detector 13a is erased and the energy state is set to a uniform initial state in the plane. Is called. Specifically, in FIG. 2, the fluorescent lamp 42a is turned on while the drum 21a is rotated at high speed by the motor 22a while the plate detector 13a is wound around the outer peripheral surface of the drum 21a. The light emitted from the fluorescent lamp 42a passes through the quartz glass window 38a and is applied to the plate detector 13a that rotates at high speed. Thereby, unnecessary energy in the X-ray light receiving surface of the plate detector 13a is erased, and the plate detector 13a is set in a state where it can be used again. Since this X-ray erasing process is also performed from the outside of the hermetic chamber 34 through the quartz glass window 38a, the plate detector 13a is performed in a state of being placed in a vacuum atmosphere in the hermetic chamber 34.

  When the X-ray erasing process on the plate detector 13a is completed as described above, the entire surface of the plate detector 13a is wound around the drum 21a. This state is the same as the plate detector 13b drawn on the left side of the X-ray exposure position E. When the plate-like detector 13a is projected again to the X-ray exposure position E to be used for X-ray image recording, the drum 21a is driven by the motor 22a and rotated in the arrow B direction. Then, at the beginning of rotation, the claw-side engaging piece 29 hits the fixed engaging piece 31 and opens, and the second end piece 26b of the plate-like detector 13a is released from being fixed.

  When the drum 21a continues to rotate, the plate detector 13a is fed out in the tangential direction of the outer peripheral surface of the drum 21a. At this time, as shown in FIG. 3, the plate detector 13a enters the space between the clamp plate 16 and the face plate 14 of the detector fixing / arrangement device 12 and protrudes to the X-ray exposure position E in FIG. When a predetermined area of the X-ray receiving surface of the plate detector 13a projects to the X-ray exposure position E, the rotation of the drum 21a stops. In this state, the plate detector 13a is set in a state where it can receive another X-ray exposure process.

  As is apparent from the above description, according to the present embodiment, a series of processes of X-ray exposure processing, image reading processing, and image erasing processing for the plate-shaped detector 13a is performed. It can be performed automatically repeatedly and continuously without being taken out of the chamber 34, that is, with the plate detector 13a left in a vacuum atmosphere.

  In addition, the above-described operation is mainly related to the drum 21a and the plate detector 13a disposed on the right side of the X-ray exposure position E, but the drum disposed on the left side of the X-ray exposure position E. The detector processing unit 20b including 21b and the plate detector 13b can perform the same operation. Therefore, the X-ray exposure processing, the image reading processing, and the image erasing processing are performed using both the detector processing unit 20b placed on the left side of the X-ray exposure position E and the detector processing unit 20a placed on the right side thereof. If a series of processing is performed, highly efficient measurement can be performed.

  More specifically, in FIG. 2, while the plate detector 13a is fed out from the detector processing unit 20a on the right side of the X-ray exposure position E and the X-ray exposure processing is performed, the detector processing on the left side is performed. It is efficient to perform image reading processing using the reading device 41b and image erasing processing using the fluorescent lamp 42b on the plate-like detector 13b in the unit 20b. Further, while the plate detector 13b is fed out from the detector processing unit 20b on the left side of the X-ray exposure position E and the X-ray exposure processing is performed, the plate detector 13a in the detector processing unit 20a on the right side On the other hand, it is efficient to perform image reading processing using the reading device 41a and image erasing processing using the fluorescent lamp 42a. In this manner, the detector processing units 20a and 20b provided on both sides of the X-ray exposure position E can be used alternately without repeating the vacuum state in the airtight chamber 34 according to this embodiment. Can be performed continuously.

  As described above, according to the present embodiment, the plate detectors 13a and 13b are stored in the airtight chamber 34, and the X-ray light receiving surfaces of the plate detectors 13a and 13b are X-rays. Further, the image reading process can be continuously performed without taking out the plate detectors 13a and 13b from the airtight chamber 34. That is, according to the present embodiment, a series of processing from X-ray exposure to image reading for the plate detectors 13a and 13b can be performed in a vacuum atmosphere in the airtight chamber 34. Thereby, it is possible to perform image reading processing from X-ray exposure in a vacuum atmosphere in a short time and continuously a plurality of times as necessary.

  Further, according to the present embodiment, when the plate detectors 13a and 13b protruding from the drums 21a and 21b are exposed by X-rays, the plate detectors 13a and 13b are X-ray exposed by the detector fixing / arranging device 12. The position E can be firmly fixed so as not to vibrate or shift. Therefore, highly reliable X-ray image data can be obtained in the X-ray receiving surfaces of the plate detectors 13a and 13b.

  In this embodiment, the plate detectors 13a and 13b wound around the outer peripheral surfaces of the drums 21a and 21b are arranged on the outer peripheral surfaces of the drums 21a and 21b by a plurality of press rollers 32 arranged in the axial direction of the drums 21a and 21b. The plate detectors 13a and 13b can be brought into close contact with the outer peripheral surfaces of the drums 21a and 21b, and plate detection is performed during the image reading process using the reading devices 41a and 41b. The containers 13a and 13b can be prevented from being peeled off or displaced from the drums 21a and 21b. As a result, the measurement data of (2θ, I) can be measured accurately.

(Resolve look-ahead and look-ahead)
In this embodiment, in FIGS. 5A and 5B, (1) a blue filter 49 is provided between the quartz glass windows 37 a and 37 b and the lens 48. (2) The incident point A of the laser light L1 incident on the lens 48 is set at a position shifted from the central optical axis X1 of the lens 48. Further, (3) an opening member 56 is provided in the vicinity of the laser beam L1 emission port in the laser beam generator 46. Further, (4) an opening member 54 is provided in the vicinity of the incident point of the laser light L1 to the blue filter 49. The above-described configurations (1) to (4) are the so-called pre-reading phenomenon and post-reading phenomenon that are considered to occur when these configurations are not used in the reading system shown in FIGS. 5 (a) and 5 (b). This is a configuration adopted to eliminate the problem. Hereinafter, the pre-reading phenomenon, the post-reading phenomenon, and the relationship between these phenomena and the above configurations (1) to (4) will be described.

  5A and FIG. 5B, (A) the blue filter 49 is removed, and (B) the incident point A of the laser light incident on the lens 48 is set as the center light of the lens 48. (C) the opening member 56 is removed from the vicinity of the exit of the laser light L1 in the laser light generator 46, and (D) the opening member 54 from the vicinity of the incident point of the laser light L1 to the blue filter 49. Let us consider a reading system having a configuration in which is removed. This reading system has, for example, the configuration shown in FIG.

  Then, the true image 61 formed on the plate detectors 13a and 13b shown in FIG. 7 is read using this reading system shown in FIG. A main scanning direction indicated by an arrow in FIG. 7 indicates a direction in which the laser light moves relatively in the lateral direction of the plate detectors 13a and 13b with respect to the rotation of the plate detectors 13a and 13b. Further, the sub-scanning direction indicated by the arrow indicates a direction in which the laser light relatively moves in the vertical direction of the plate detectors 13a and 13b when the scanning moving body 44 in FIG. 4 moves in parallel in the Z direction. .

  The reading system shown in FIG. 6 is supposed to read only the true image 61 in FIG. 7, but actually reads that there is an image at the positions indicated by reference numerals 62A, 62B, 62C, and 62D. End up. The image 62A and the image 62C appear as shadows of the true image 61. That is, it appeared as an image thinner than the true image 61. Further, the image 62B appeared in the form of spots. The image 62D appeared in a hat shape covering the true image 61.

  In FIG. 6, the image 62 </ b> A is considered to be caused by the fact that the laser beam L <b> 1 is reflected between the plate-like detectors 13 a and 13 b and the lens 48, resulting in the prefetching phenomenon. . Further, the image 62B and the image 62C are caused by the fact that the pre-reading phenomenon and the post-reading phenomenon occur due to the reflection from the lens 48 in FIG. 6 being further reflected by the quartz glass windows 37a and 37b. It is thought to have occurred.

  Here, pre-reading and post-reading will be described with reference to FIG. In FIG. 8, when the laser beam L3 passes through the lens 48 and irradiates the plate detectors 13a and 13b, the laser beam L3 is reflected by the plate detectors 13a and 13b. Some of the reflected laser beams L30 travels ahead of the reading point B, and some laser light L31 travels behind the reading point B. The pre-reading phenomenon is that the laser beam L30 reflected backward reads the true image 61 in FIG. 7, and the post-reading phenomenon is that the laser light reflected backward reads the true image 61.

  The image 62D in FIG. 7 is considered to be caused not by the reflection of the laser light from the lens 48 shown in FIG. 8, but by the reflection at the quartz glass windows 37a and 37b in FIG. In this case, since the intensity of the laser light before reading is stronger than the intensity after reading, it seems that the influence of the pre-reading phenomenon is stronger. Further, it seems that the cause is that the image is blurred and read out due to the spread of the bottom of the laser beam and the blurring of the detectors 13a and 13b at the reading point B.

  With respect to the unnecessary read images 62A, 62B, 62C, and 62D as described above, as shown in FIG. 5A, a blue filter 49 having a laser beam passage region 53 is connected between the quartz glass windows 7a and 37b and the lens 48. If they are arranged between them, reading of these unnecessary images 62A, 62B, 62C, and 62D can be suppressed to the extent that there is no practical problem. This is considered because the reflection of the laser light L1 generated between the lens 48, the quartz glass windows 37a and 37b, and the plate detectors 13a and 13b can be suppressed by the blue filter 49.

  Further, as shown in FIG. 5B, the incident point A of the laser beam to the lens 48 is set downstream of the lens optical axis X1 in the main scanning direction, and the incident point A is set to the lens optical axis. When either one or both of the X1 and the downstream are set in the sub-scanning direction, reading of unnecessary images 62A, 62B, 62C, and 62D can be further suppressed. This is thought to be due to the following reason.

  That is, the laser light incident on a point other than the optical axis X 1 of the lens 48 is generally refracted toward the optical axis X 1 on the downstream side of the lens 48. Accordingly, if the incident point A of the laser beam on the lens 48 is shifted downstream in the scanning direction from the optical axis X1, the laser beam is refracted by the lens 48 and upstream in the scanning direction (that is, backward in the scanning direction). Refract. That is, the laser light travels toward the rear of the lens 48. In this way, if the laser light is regulated so as to travel toward the rear of the lens 48, the occurrence of the prefetching phenomenon can be suppressed. The unnecessary read images 62A, 62B, 62C, and 62D shown in FIG. 7 have a higher rate of occurrence due to the pre-reading phenomenon than the post-reading phenomenon, so that the occurrence of the pre-reading phenomenon is suppressed as described above. Thus, it seems that the generation of these unnecessary images can be effectively suppressed.

  In FIG. 5B, the laser beam incident point A to the lens 48 may be set to be shifted downstream in the scanning direction in either the main scanning direction or the sub-scanning direction. Or both of them. However, it is more effective to suppress reading of an unnecessary image when the laser beam irradiation point A is shifted in both directions than when the laser beam irradiation point A is shifted only in either the main scanning direction or the sub-scanning direction. Met.

  Shifting the incident point A of the laser beam to the lens 48 from the lens optical axis in both the main scanning direction and the sub-scanning direction means that the incident point A of the laser beam to the lens 48 is as shown in FIG. This can be realized by shifting the angle by 45 ° with respect to the main scanning direction axis or the sub-scanning direction axis. In this case, the incident point A is deviated from the lens optical axis by an equal distance in the main scanning direction and the sub scanning direction.

  Further, regarding shifting the incident point A of the laser beam to the lens 48 from the lens optical axis, as shown in FIG. 9, instead of shifting by 45 ° with respect to the main scanning direction axis or the sub scanning direction axis. Alternatively, the angle θ0 with respect to the main scanning direction axis may be increased, and the angle θ1 with respect to the sub scanning direction axis may be decreased. In general, the pre-reading phenomenon and the post-reading phenomenon have a greater effect on the sub-scanning direction than on the main scanning direction. This is because unnecessary image reading can be suppressed more effectively. In FIG. 9, in order to increase the distance shift amount in the sub-scanning direction, the angle θ0 with respect to the main scanning direction axis is 60 °, and the angle θ1 with respect to the sub-scanning direction axis is 30 °.

  Also, as shown in FIG. 5A, an opening member 54 is provided in front of the laser beam passage region 53 of the blue filter 49, or an opening member 56 is provided in front of the laser emission port of the laser beam generator 46. Alternatively, by providing both the opening member 54 and the opening member 56, reading of an unnecessary image can be suppressed. This is considered to be because by providing the opening elements 54 and 56, the peripheral portion of the spot of the laser beam L1 that irradiates the X-ray light receiving surfaces of the plate detectors 13a and 134b can be prevented from being blurred. It is also considered that the laser beam can be prevented from traveling in an unnecessary direction inside the reading optical system and performing unnecessary reading.

  In the present embodiment, the surface of the quartz glass forming the quartz glass windows 37a, 37b, 38a, and 38b in FIG. 2 and the surface of the lens 48 in FIG. Treated. Thereby, it was possible to suppress reading of an unnecessary image at the time of reading. This seems to be because the laser beam could be prevented from being reflected by the quartz glass window or the lens.

(Second Embodiment)
10 and 11 show another embodiment of the X-ray analyzer and the X-ray image recording / reading apparatus according to the present invention. In the embodiment described above, the detector processing units 20a and 20b are provided on both sides of the X-ray exposure position E as shown in FIGS. On the other hand, in the present embodiment shown in FIGS. 10 and 11, one detector processing unit 20 a is provided only on one side of the X-ray exposure position E. In particular, in FIGS. 10 and 11, the detector processing unit 20 a is provided on the right side of the X-ray exposure position E. The detector processing unit 20a is not limited to the right side of the X-ray exposure position E but can be provided on any one of the left side, the upper side, and the lower side.

  Also in this embodiment, as in the case of the previous embodiment shown in FIG. 2, the plate detector 13a is housed in the hermetic chamber 34, and the X-ray light received by the plate detector 13a. The surface can be exposed with X-rays, and the image reading process can be continuously performed without removing the plate-like detector 13a from the airtight chamber 34. That is, also in the present embodiment, a series of processing from X-ray exposure to image reading on the plate detector 13a can be performed in an atmosphere state in the hermetic chamber 34, for example, in a vacuum atmosphere. As a result, the processing from the X-ray exposure in a vacuum atmosphere to the image reading can be performed continuously in a short time and a plurality of times as necessary.

(Other embodiments)
The present invention has been described with reference to the preferred embodiments. However, the present invention is not limited to the embodiments, and various modifications can be made within the scope of the invention described in the claims.

  For example, in the embodiment shown in FIG. 2, a pair of units of a detector processing unit 20a including a drum 21a and a plate detector 13a and a detector processing unit 20b including a drum 21b and a plate detector 13b are arranged as X. The detector processing units 20a and 20b may be provided on both the upper and lower sides of the X-ray exposure position E instead of this configuration.

  In the embodiment of FIG. 2, the fluorescent lamps 42 a and 42 b are provided outside the airtight chamber 34, but they may be provided inside the airtight chamber 34.

  Further, if the plate-like detectors 13a and 13b protruding from the drums 21a and 21b can be stationary in a stable state at the X-ray exposure position E in a natural state, the detector fixing / arranging device 12 is not necessarily provided. Moreover, it can also be set as the structure which provides only the face plate 14 of FIG. Further, a guide plate for guiding the plate detectors 13a and 13b from the drums 21a and 21b to the X-ray exposure position E may be provided.

  In the embodiment shown in FIG. 1, the measurement is performed using the X-rays emitted from the X-ray source F composed of the filament and the target. The present invention can also be applied to line measurements. Since synchrotron radiation is generally weak in intensity, it is very effective if the X-ray analyzer of the present invention, which can perform all processing in a vacuum atmosphere, is applied when using synchrotron radiation.

1 is a perspective view showing an embodiment of an X-ray analysis apparatus according to the present invention. It is a perspective view which shows the internal structure of the X-ray image recording / reading apparatus which is the principal part of the X-ray analyzer shown in FIG. It is sectional drawing which shows the cross-section of an X-ray exposure position according to the AA line of FIG. It is sectional drawing which shows the structure of the reader which is a principal part of the X-ray image recording / reading apparatus shown in FIG. (A) is a figure which expands and shows the principal part of the reader shown in FIG. 4, (b) is a front view of the lens according to the arrow D of (a). FIG. 6 is a diagram showing a reading system in a state where main optical elements are removed from the configuration of FIG. 5 for comparison. It is a figure which shows reading failure concretely. It is a figure for demonstrating the pre-reading phenomenon and the post-reading phenomenon which are one of the causes of the reading failure of FIG. It is a figure which shows the principal part of other embodiment of the X-ray image recording / reading apparatus which concerns on this invention. It is a perspective view which shows other embodiment of the X-ray analyzer which concerns on this invention. It is a perspective view which shows the internal structure of the X-ray image recording / reading apparatus which is the principal part of the X-ray analyzer shown in FIG.

Explanation of symbols

1. 1. X-ray analyzer, 2. X-ray measuring device; X-ray image recording / reading device,
4). X-ray optical system, 6. 6. airtight chamber for optical system; Sample holder,
11. Housing case, 12. Detector fixed arrangement device,
13a, 13b. Plate detector (two-dimensional X-ray detection means), 14. Face plate,
16. Clamp plate, 17. Space member, 18. Movable plate,
19. Rotary solenoid, 21. Drum (detection means support means),
20a, 20b. Detector processing unit (detection means processing means),
22a, 22b. Motor (support means rotating means), 24a, 24b. axis,
26a. First end, 26b. Second edge, 27. Shaft member,
28. Claw member (edge fixing means), 29. Claw side engaging piece, 31. Fixed engagement piece,
32. 33. Presser roller (detection means pressing means) Roller shaft, 34. Airtight chamber,
36. Openings 37a, 37b. Quartz glass window (first light transmission part),
38a, 38b. Quartz glass window (second light transmission part), 41a, 41b. Reader,
42a, 42b. Fluorescent lamp (erasing light irradiation means), 43. Feed screw shaft,
44. Scanning moving body, 46. Laser light generator (primary light generator), 47. prism,
48. Lens, 9. Blue filter,
51. 52. Photomultiplier (photoelectric conversion means) motor,
53. Racer light passage region, 54. Opening member, 56. Opening member,
57. Coupling device, 61. True image,
62A, 62B, 62C, 62D. Image of poor reading, A. Laser beam incident point,
B. Reading point, E.E. X-ray exposure position; X-ray source, L1. Laser light (primary light),
L2.2 order light, L3, L30, L31. Laser light, Q. Aperture, R1.1 order X-ray,
R2, secondary X-ray; Sample, width of W0.2 dimensional X-ray detector,
X0. Drum center axis, X1. Lens optical axis, X2. X-ray optical axis

Claims (8)

An X-ray image recording / reading apparatus for recording an image by exposing an X-ray receiving surface of a two-dimensional X-ray detection means placed at an X-ray exposure position with X-rays, and further reading the image with light. Having processing means and an airtight chamber;
(A) The detection means processing means includes:
(A) a detecting means supporting means having a cylindrical outer peripheral surface and having a first end of the two-dimensional X-ray detecting means fixed to the outer peripheral face;
(A) support means rotation means for rotating the detection means support means about the cylindrical central axis;
(C) An end for fixing the second end side facing the first end side of the two-dimensional X-ray detection unit that rotates together with the detection unit support unit and is wound around the detection unit support unit Edge fixing means;
(D) a first light transmission part provided in the airtight chamber;
(E) having reading means provided outside the hermetic chamber and facing the first light transmission portion;
(I) The supporting means rotating means includes a first angular position where the entire surface of the two-dimensional X-ray detecting means is wound around the detecting means supporting means, and the second end side of the two-dimensional X-ray detecting means is the detection. Rotating the detection means support means between a second angular position projecting away from the means support means and disposing a predetermined region of the X-ray light receiving surface of the two-dimensional X-ray detection means at the X-ray exposure position;
(Ii) the first light transmission portion is provided in the hermetic chamber at a position facing the detection means support means;
(B) The X-ray image recording / reading apparatus characterized in that the airtight chamber surrounds the two-dimensional X-ray detection means, the detection means support means, and the edge fixing means. The X-ray image recording / reading apparatus according to claim 1, wherein the detection unit processing unit includes:
A second light transmission part provided in the airtight chamber at a position opposite to the detection means support means and at a position different from the first light transmission part;
An erasing light irradiation means provided outside the hermetic chamber and facing the second light transmission portion;
An X-ray image recording / reading apparatus comprising: The X-ray image recording / reading apparatus according to claim 1 or 2,
Detecting means fixing and arranging means for fixing and arranging the two-dimensional X-ray detecting means protruding from the detecting means supporting means at the X-ray exposure position;
The X-ray image recording / reading apparatus according to claim 1, wherein the hermetic chamber hermetically surrounds the detection means fixing / arranging means. The X-ray image recording / reading apparatus according to claim 3.
The detection means fixing arrangement means is
A face plate disposed at the X-ray exposure position;
A clamp plate disposed upstream of the face plate with respect to the X-ray traveling direction and having an opening for allowing X-rays to pass through;
An X-ray image recording / reading apparatus comprising: a clamp moving unit that translates the clamp plate toward the face plate. The X-ray image recording / reading apparatus according to any one of claims 1 to 4,
An X-ray image recording / reading apparatus comprising: detection means pressing means for pressing the two-dimensional X-ray detection means wound around the detection means support means against the detection means support means.   6. The X-ray image recording / reading apparatus according to claim 1, wherein the detection means processing means is arranged on both sides of the X-ray exposure position. Record reader.   7. The X-ray image recording / reading apparatus according to claim 6, wherein detection means processing means arranged on both sides of the X-ray exposure position alternately project the two-dimensional X-ray detection means to the X-ray exposure position. An X-ray image recording / reading apparatus. An X-ray optical system for irradiating the sample with X-rays to generate secondary X-rays from the sample;
An optical hermetic chamber for hermetically surrounding the X-ray optical system;
Decompression means for sucking air inside the airtight chamber for the optical system and decompressing the inside;
X-ray which exposes the X-ray light receiving surface of the two-dimensional X-ray detection means placed at the X-ray exposure position with the secondary X-ray from the X-ray optical system, records an image, and further reads the image with light An image recording and reading device;
An X-ray analyzer having
(A) The X-ray image recording / reading apparatus has a detection means processing means and an airtight chamber,
(A) The detection means processing means includes:
(A) a detecting means supporting means having a cylindrical outer peripheral surface and having a first end of the two-dimensional X-ray detecting means fixed to the outer peripheral face;
(A) support means rotation means for rotating the detection means support means about the cylindrical central axis;
(C) An end for fixing a second end side facing the first end side of the two-dimensional X-ray detection unit that rotates together with the detection unit support unit and is wound around the detection unit support unit. Edge fixing means;
(D) a first light transmission part provided in the airtight chamber;
(E) having reading means provided outside the hermetic chamber and facing the first light transmission portion;
(I) The support means rotating means has a first angular position where the entire surface of the two-dimensional X-ray detection means is wound around the detection means support means, and the second end side of the two-dimensional X-ray detection means is the detection Rotating the detection means support means between a second angular position projecting away from the means support means and disposing a predetermined region of the X-ray light receiving surface of the two-dimensional X-ray detection means at the X-ray exposure position;
(Ii) the first light transmission portion is provided in the hermetic chamber at a position facing the detection means support means;
(B) the airtight chamber surrounds the two-dimensional X-ray detection means, the detection means support means, and the edge fixing means;
(C) The X-ray analysis apparatus characterized in that the airtight chamber is airtightly connected to the optical system airtight chamber.

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