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JP2007073124A - Method and device for manufacturing optical recording medium - Google Patents

Method and device for manufacturing optical recording medium Download PDF

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JP2007073124A
JP2007073124A JP2005258338A JP2005258338A JP2007073124A JP 2007073124 A JP2007073124 A JP 2007073124A JP 2005258338 A JP2005258338 A JP 2005258338A JP 2005258338 A JP2005258338 A JP 2005258338A JP 2007073124 A JP2007073124 A JP 2007073124A
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covering member
resin material
circular covering
substrate
circular
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Yuzo Sato
裕三 佐藤
Tsutomu Kozu
力 神津
Mitsuyoshi Harano
光祥 原野
Mamoru Usami
守 宇佐美
Tomoki Ushita
智樹 丑田
Hiroaki Takahata
広彰 高畑
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TDK Corp
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TDK Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method and a device for manufacturing an optical recording medium capable of forming a cover layer with a uniform thickness so as to prevent the generation of burrs or peeling. <P>SOLUTION: A radiation curable resin material 18 is supplied annularly around a center hole 12 on a substrate 14 in a flowing state, a translucent circular covering member 20 having a center hole 22A, formed into a circular plate shape, and having an outer diameter smaller than the inner diameter of a recording area Ar is moved and mounted onto the resin material 18, the substrate 14 and the circular covering member 20 are rotated to make the resin material 18 flow outside in the radial direction by a centrifugal force to spread on the substrate 14, and a radiation ray is irradiated to the substrate 14 to harden the resin material 18, and then the circular covering member 20 is peeled off. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、基板の上に基板よりも薄いカバー層が形成され、且つ、中心孔が形成された光記録媒体の製造方法及び製造装置に関する。   The present invention relates to a method and an apparatus for manufacturing an optical recording medium in which a cover layer thinner than a substrate is formed on a substrate and a center hole is formed.

情報記録媒体としてCD(Compact Disc)、DVD(Digital Versatile Disc)等の光記録媒体が急速に普及している。光記録媒体は一般的に外径が120mm、厚さが1.2mmに統一されているが、DVDは照射光としてCDよりも波長が短いレーザ光を用いると共に、照射光のレンズの開口数をCDよりも大きくすることでCDよりも高密度で大容量の情報を記録・再生できるようになっている。   As information recording media, optical recording media such as CD (Compact Disc) and DVD (Digital Versatile Disc) are rapidly spreading. An optical recording medium is generally standardized to have an outer diameter of 120 mm and a thickness of 1.2 mm. However, DVD uses laser light having a shorter wavelength than CD as irradiation light, and also sets the numerical aperture of the lens of irradiation light. By making it larger than a CD, it is possible to record / reproduce information having a higher density and a higher capacity than a CD.

尚、照射光の波長が短く、レンズの開口数が大きいほどディスクの傾き、反りにより情報の記録・再生精度が低下しやすい傾向があるため、DVDはカバー層の厚さをCDの半分の0.6mmとすることで、ディスクの傾き、反りに対するマージンを確保し、情報の記録・再生精度を維持している。   Note that the shorter the wavelength of the irradiating light and the larger the numerical aperture of the lens, the more likely the information recording / reproducing accuracy tends to decrease due to the tilt and warp of the disc. By setting the thickness to .6 mm, a margin for tilting and warping of the disk is ensured, and information recording / reproducing accuracy is maintained.

更に近年、一層高密度で大容量の情報の記録を実現すべく、更に照射光の波長を短かくすると共にレンズの開口数を大きくし、これに対応して一層薄いカバー層を形成した光記録媒体が普及しつつある。   In recent years, in order to realize higher density and higher capacity information recording, optical recording with a shorter cover wavelength and a correspondingly thinner lens is provided. The media is spreading.

尚、仕様を統一すべく、照射光として波長が約405nmの青紫色のレーザ光を用いると共に開口数を0.85とし、カバー層の厚さを約100μmとした光記録媒体が普及しつつある。   In order to unify the specifications, an optical recording medium using a blue-violet laser beam having a wavelength of about 405 nm as an irradiation light, a numerical aperture of 0.85, and a cover layer thickness of about 100 μm is becoming widespread. .

この光記録媒体のうち片面単層記録式のものは、全体の厚さが1.2mmとなるように、基板の厚さが1.1mmとなっている。基板は、一般的に量産性に優れた射出成形により成形される。具体的には、ポリカーボネート等の樹脂が一対の型の間に射出されて所定の温度に冷却、保温され、円板形状に成形される。射出成形後、中心部が打ち抜かれて、例えば直径が15mmの中心孔が形成される。   Among these optical recording media, the single-sided single-layer recording type has a substrate thickness of 1.1 mm so that the overall thickness is 1.2 mm. The substrate is generally formed by injection molding excellent in mass productivity. Specifically, a resin such as polycarbonate is injected between a pair of molds, cooled and kept at a predetermined temperature, and formed into a disk shape. After the injection molding, the central portion is punched to form a central hole having a diameter of 15 mm, for example.

カバー層は、基板の上にスピンコート法等により形成される。具体的には、まず、透光性を有し紫外線硬化性や電子線硬化性等の放射線が照射されることで硬化する性質を有する放射線硬化性の樹脂材料を流動状態で基板の中心孔の周りに環状に供給する。又、基板の中心孔をキャップ等で閉塞し、このキャップ等の上に樹脂材料を供給する技術も知られている(例えば、特許文献1、2、3、4参照)。又、中心孔がない円板形状に基板を成形し、この基板の中心近傍に樹脂材料を供給する技術も知られている。   The cover layer is formed on the substrate by a spin coat method or the like. Specifically, first, a radiation curable resin material that has transparency and is cured by being irradiated with radiation such as ultraviolet curable and electron beam curable, in a fluidized state. Feed around the ring. There is also known a technique in which a central hole of a substrate is closed with a cap or the like and a resin material is supplied onto the cap or the like (see, for example, Patent Documents 1, 2, 3, and 4). A technique is also known in which a substrate is formed into a disk shape without a central hole, and a resin material is supplied near the center of the substrate.

次に、基板を回転させて、供給した樹脂材料を遠心力で径方向外側に流動させることにより基板の全面に展延する。展延後、紫外線、電子線等の放射線を基板に照射し、樹脂材料を硬化させる。これによりカバー層が形成され光記録媒体が完成する。両面単層記録式の場合は、基板の厚さを1.0mmとし、基板の両面それぞれに100μmのカバー層を形成すればよい。又、2層以上の記録層が片面又は両面に設けられる場合、100μmよりも薄いカバー層が形成される。尚、中心孔がない基板上にカバー層を形成する場合、カバー層の形成後に基板及びカバー層の中心部を打ち抜いて中心孔を形成する。   Next, the substrate is rotated, and the supplied resin material is caused to flow radially outward by a centrifugal force so as to spread over the entire surface of the substrate. After spreading, the substrate is irradiated with radiation such as ultraviolet rays or electron beams to cure the resin material. Thereby, a cover layer is formed and the optical recording medium is completed. In the case of double-sided single-layer recording, the thickness of the substrate is 1.0 mm, and a cover layer of 100 μm may be formed on each side of the substrate. When two or more recording layers are provided on one side or both sides, a cover layer thinner than 100 μm is formed. In the case where the cover layer is formed on the substrate having no central hole, the central hole is formed by punching the central portion of the substrate and the cover layer after the cover layer is formed.

特開平11―195250号公報Japanese Patent Laid-Open No. 11-195250 特開平11―195251号公報JP-A-11-195251 特開平11―213459号公報Japanese Patent Laid-Open No. 11-213459 特開平11―66647号公報Japanese Patent Application Laid-Open No. 11-66647

しかしながら、基板の中心孔の周りに樹脂材料を環状に供給し、基板を回転させると、展延した樹脂の厚さが不均一となりやすく、高密度な情報の記録、再生が困難となることがある。具体的には、展延した樹脂は径方向の外側ほど厚くなりやすい。   However, if the resin material is supplied in an annular shape around the center hole of the substrate and the substrate is rotated, the thickness of the spread resin is likely to be non-uniform, making it difficult to record and reproduce high-density information. is there. Specifically, the spread resin tends to be thicker toward the outer side in the radial direction.

厚さが不均一になる理由は必ずしも明らかではないが、概ね次のように考えられている。樹脂材料を中心孔の周辺に供給すると基板の回転により樹脂材料に直ちに遠心力が作用し、径方向外側に流動する。径方向の外側ほど遠心力が強いため、樹脂材料の流動量が径方向にばらつきやすい。又、全周に同時、且つ、均一に樹脂材料を供給することは困難であるため、樹脂材料の流動量が周方向にもばらつくことがある。一方、流動量がばらついても、流動量を制御することは困難である。このように流動量がばらついた状態で樹脂材料が展延されるためカバー層の厚さが不均一になると考えられる。   The reason why the thickness is not uniform is not necessarily clear, but it is generally considered as follows. When the resin material is supplied to the periphery of the central hole, a centrifugal force immediately acts on the resin material due to the rotation of the substrate and flows outward in the radial direction. Since the centrifugal force is stronger toward the outside in the radial direction, the flow rate of the resin material tends to vary in the radial direction. In addition, since it is difficult to supply the resin material uniformly and uniformly around the entire circumference, the flow amount of the resin material may vary in the circumferential direction. On the other hand, even if the flow amount varies, it is difficult to control the flow amount. Thus, it is considered that the thickness of the cover layer becomes non-uniform because the resin material is spread with the flow amount varied.

これに対し、基板の中心孔をキャップ等で閉塞し、このキャップ等の上に樹脂材料を供給すれば、樹脂材料を基板の中心部に供給することができ、供給した樹脂材料に直ちに遠心力が作用することを回避できる。この場合、基板の中心部が樹脂材料の貯留部のような役割を果たし、基板上における樹脂材料の流動量を緩衝して安定させるため、樹脂材料を均一な厚さで展延することが可能であるが、樹脂材料が付着したキャップ等を毎回洗浄する必要があり、洗浄設備のために生産設備が複雑となると共に生産効率が低いという問題がある。   On the other hand, if the center hole of the substrate is closed with a cap or the like and a resin material is supplied onto the cap or the like, the resin material can be supplied to the central portion of the substrate, and a centrifugal force is immediately applied to the supplied resin material. Can be avoided. In this case, the central part of the substrate acts as a reservoir for the resin material, and the flow rate of the resin material on the substrate is buffered and stabilized, so the resin material can be spread with a uniform thickness. However, it is necessary to wash the cap or the like to which the resin material is adhered every time, and there is a problem that the production equipment becomes complicated due to the washing equipment and the production efficiency is low.

又、中心孔がない基板の中心近傍に樹脂材料を供給する場合は、展延した樹脂を硬化させてから、カバー層及び基板を円形工具等で打ち抜いて中心孔を形成することになるが、カバー層は厚さが100μm以下の極めて薄い層であるため、円形工具等で打ち抜く際、カバー層の内周部にバリが発生したり、カバー層の内周部が剥離することがある。   In addition, when supplying the resin material near the center of the substrate without the center hole, the spread resin is cured, and then the cover layer and the substrate are punched out with a circular tool or the like to form the center hole. Since the cover layer is an extremely thin layer having a thickness of 100 μm or less, when punching with a circular tool or the like, burrs may occur on the inner peripheral portion of the cover layer, or the inner peripheral portion of the cover layer may peel off.

又、光記録媒体は中心孔において記録/再生装置等に保持されるため、記録/再生装置に繰り返し脱着されることで、カバー層の内周部が剥離することもある。   Further, since the optical recording medium is held by the recording / reproducing apparatus or the like in the central hole, the inner peripheral portion of the cover layer may be peeled off by being repeatedly detached from the recording / reproducing apparatus.

本発明は、以上の問題点に鑑みてなされたものであって、バリや剥離が発生しないようにカバー層を均一な厚さで形成できる光記録媒体の製造方法及び製造装置を提供することを目的とする。   The present invention has been made in view of the above problems, and provides an optical recording medium manufacturing method and manufacturing apparatus capable of forming a cover layer with a uniform thickness so that burrs and peeling do not occur. Objective.

本発明は、基板の上に放射線硬化性の樹脂材料を流動状態で中心孔の周りに環状に供給し、中心孔を有する円板形状で外径が記録エリアの内径よりも小さい透光性を有する円形被覆部材を環状の樹脂材料の上に移載し、基板及び円形被覆部材を回転させて樹脂材料を遠心力により径方向外側に流動させて基板上に展延し、基板に放射線を照射して樹脂材料を硬化させ、円形被覆部材を剥離することにより上記目的を達成するものである。   The present invention supplies a radiation curable resin material on a substrate in an annular shape around a central hole in a flowing state, and has a disc shape having a central hole and has a translucency with an outer diameter smaller than the inner diameter of a recording area. The circular covering member is transferred onto the annular resin material, the substrate and the circular covering member are rotated, the resin material is caused to flow radially outward by centrifugal force and spread on the substrate, and the substrate is irradiated with radiation. Then, the above-mentioned object is achieved by curing the resin material and peeling off the circular covering member.

このように、円形被覆部材を環状の樹脂材料の上に移載してから基板を回転させることで、樹脂材料を基板の中心孔の周りに環状に供給しても樹脂材料の流動を円形被覆部材で制御できるので、樹脂材料を基板の全面に均一な厚さで展延できる。   In this way, by rotating the substrate after transferring the circular covering member onto the annular resin material, the flow of the resin material is circularly coated even if the resin material is annularly supplied around the central hole of the substrate. Since it can be controlled by the member, the resin material can be spread over the entire surface of the substrate with a uniform thickness.

即ち、以下の発明により上記目的を達成できる。   That is, the above object can be achieved by the following invention.

(1)中心孔を有する円板形状で略水平に設置された基板の上に透光性を有する放射線硬化性の樹脂材料を流動状態で前記中心孔の周りに環状に供給する樹脂材料供給工程と、中心孔を有する円板形状で外径が記録エリアの内径よりも小さい透光性を有する円形被覆部材を前記環状の樹脂材料の上に移載する円形被覆部材移載工程と、前記基板及び前記円形被覆部材を回転させて前記樹脂材料を遠心力により径方向外側に流動させて前記基板上に展延する樹脂材料展延工程と、前記基板に放射線を照射して前記樹脂材料を硬化させる放射線照射工程と、前記円形被覆部材を前記樹脂材料から剥離する円形被覆部材剥離工程と、を含むことを特徴とする光記録媒体の製造方法。   (1) A resin material supply step of supplying a radiation curable resin material having translucency on a substrate having a disc shape having a center hole and disposed substantially horizontally in a ring shape around the center hole in a fluid state A circular covering member transfer step of transferring a circular covering member having a disc shape having a central hole and having a light transmitting property whose outer diameter is smaller than the inner diameter of the recording area onto the annular resin material, and the substrate And rotating the circular covering member to cause the resin material to flow radially outward by centrifugal force and spreading the resin material on the substrate, and curing the resin material by irradiating the substrate with radiation. A method for producing an optical recording medium, comprising: a radiation irradiation step for causing a circular covering member to peel off the circular covering member from the resin material.

(2) (1)において、前記円形被覆部材移載工程及び前記展延工程の少なくとも一方において前記円形被覆部材を前記基板側に加圧することを特徴とする光記録媒体の製造方法。   (2) The method of manufacturing an optical recording medium according to (1), wherein the circular covering member is pressed toward the substrate in at least one of the circular covering member transfer step and the spreading step.

(3) (1)又は(2)において、前記放射線照射工程において、前記基板を回転させつつ前記円形被覆部材の外周近傍に放射線を照射することを特徴とする光記録媒体の製造方法。   (3) The method of manufacturing an optical recording medium according to (1) or (2), wherein, in the radiation irradiating step, radiation is applied to the vicinity of the outer periphery of the circular covering member while rotating the substrate.

(4) (1)乃至(3)のいずれかにおいて、前記円形被覆部材として少なくとも前記樹脂材料との接触面が撥水性を有する円形被覆部材を用いることを特徴とする光記録媒体の製造方法。   (4) The method for producing an optical recording medium according to any one of (1) to (3), wherein a circular covering member having at least a contact surface with the resin material is water-repellent as the circular covering member.

(5) (1)乃至(4)のいずれかにおいて、前記円形被覆部材として外周側面がテーパ形状である円形被覆部材を用い、前記円形被覆部材移載工程において前記基板から離間する方向に前記外周側面が拡径する姿勢で前記円形被覆部材を前記樹脂材料の上に移載することを特徴とする光記録媒体の製造方法。   (5) In any one of (1) to (4), a circular covering member having a tapered outer peripheral side surface is used as the circular covering member, and the outer periphery is moved away from the substrate in the circular covering member transfer step. A method of manufacturing an optical recording medium, wherein the circular covering member is transferred onto the resin material in a posture in which a side surface has a diameter expanded.

(6) (1)乃至(5)のいずれかにおいて、前記円形被覆部材剥離工程の後に、前記樹脂材料における前記円形被覆部材の外周に相当する段部を厚さ方向に加圧する段部加圧工程が設けられたことを特徴とする光記録媒体の製造方法。   (6) In any one of (1) to (5), after the circular covering member peeling step, the step portion pressurizing the step portion corresponding to the outer periphery of the circular covering member in the resin material in the thickness direction. A method of manufacturing an optical recording medium, comprising a step.

(7) (1)乃至(5)のいずれかにおいて、前記円形被覆部材剥離工程の後に、前記樹脂材料における前記円形被覆部材の外周に相当する段部を除去する段部除去工程が設けられたことを特徴とする光記録媒体の製造方法。   (7) In any one of (1) to (5), a step removing step for removing a step corresponding to the outer periphery of the circular covering member in the resin material is provided after the circular covering member peeling step. A method of manufacturing an optical recording medium.

(8)中心孔を有する円板形状の基板を略水平に設置するための回転テーブルと、前記基板の上に透光性を有する放射線硬化性の樹脂材料を流動状態で前記中心孔の周りに環状に供給するための樹脂材料供給装置と、中心孔を有する円板形状で外径が記録エリアの内径よりも小さい透光性を有する円形被覆部材を前記環状の樹脂材料の上に移載するための円形被覆部材移載装置と、前記基板に放射線を照射して該基板上に展延された前記樹脂材料を硬化させるための放射線照射装置と、前記円形被覆部材を前記樹脂材料から剥離するための円形被覆部材剥離装置と、を含むことを特徴とする光記録媒体の製造装置。   (8) A rotary table for installing a disk-shaped substrate having a center hole substantially horizontally, and a radiation curable resin material having translucency on the substrate in a fluid state around the center hole. A resin material supply device for supplying an annular shape and a circular covering member having a disc shape having a central hole and having an outer diameter smaller than the inner diameter of the recording area are transferred onto the annular resin material. A circular covering member transfer device for irradiating the substrate with radiation and curing the resin material spread on the substrate, and peeling the circular covering member from the resin material An apparatus for manufacturing an optical recording medium, comprising:

(9) (8)において、前記円形被覆部材移載装置は、前記円形被覆部材を前記基板側に加圧可能であることを特徴とする光記録媒体の製造装置。   (9) In (8), the circular covering member transfer device can pressurize the circular covering member to the substrate side.

(10) (8)又は(9)において、前記回転テーブルは、前記基板の中心孔及び前記円形被覆部材の中心孔に嵌入してこれら基板及び円形被覆部材を位置決めするためのガイドを備えることを特徴とする光記録媒体の製造装置。   (10) In (8) or (9), the turntable includes a guide for positioning the substrate and the circular covering member by fitting into the central hole of the substrate and the central hole of the circular covering member. An optical recording medium manufacturing apparatus.

(11) (10)において、前記ガイドは、上下動自在で上昇しつつ前記円形被覆部材を前記樹脂材料から剥離可能であり、前記円形被覆部材剥離装置を兼ねることを特徴とする光記録媒体の製造装置。   (11) In the optical recording medium according to (10), the guide is capable of moving up and down and detaching the circular covering member from the resin material, and also serves as the circular covering member peeling device. Manufacturing equipment.

(12) (8)乃至(11)のいずれかにおいて、前記円形被覆部材移載装置は、前記円形被覆部材を保持して上昇することにより該円形被覆部材を前記樹脂材料から剥離可能であり、前記円形被覆部材剥離装置を兼ねることを特徴とする光記録媒体の製造装置。   (12) In any one of (8) to (11), the circular covering member transfer device is capable of peeling the circular covering member from the resin material by holding and lifting the circular covering member. An apparatus for manufacturing an optical recording medium, which also serves as the circular covering member peeling apparatus.

(13) (8)乃至(12)のいずれかにおいて、前記樹脂材料における前記円形被覆部材の外周に相当する段部を厚さ方向に加圧するための段部加圧装置が備えられたことを特徴とする光記録媒体の製造装置。   (13) In any one of (8) to (12), there is provided a step pressurizing device for pressing in a thickness direction a step corresponding to the outer periphery of the circular covering member in the resin material. An optical recording medium manufacturing apparatus.

(14) (8)乃至(12)のいずれかにおいて、前記樹脂材料における前記円形被覆部材の外周に相当する段部を除去するための段部除去装置が備えられたことを特徴とする光記録媒体の製造装置。   (14) The optical recording according to any one of (8) to (12), further comprising a step removing device for removing a step corresponding to the outer periphery of the circular covering member in the resin material. Medium production equipment.

尚、本出願において「放射線」という用語は、流動状態の特定の樹脂材料を硬化させる性質を有する、例えば紫外線等の電磁波、電子線等の粒子線の総称という意義で用いることとする。   In the present application, the term “radiation” is used in the meaning of a generic name for electromagnetic waves such as ultraviolet rays and particle beams such as electron beams, which have the property of curing a specific resin material in a fluid state.

本発明によれば、バリや剥離が発生しないようにカバー層を均一な厚さで形成できる。   According to the present invention, the cover layer can be formed with a uniform thickness so that burrs and peeling do not occur.

以下、本発明を実施するための好ましい形態について図面を参照して詳細に説明する。   Hereinafter, preferred embodiments for carrying out the present invention will be described in detail with reference to the drawings.

本発明の第1実施形態に係る光記録媒体の製造装置10は、図1に示されるように、中心孔12Aを有する円板形状の基板12を略水平に設置するための回転テーブル14と、基板12の上に透光性を有する放射線硬化性の樹脂材料16を流動状態で中心孔12Aの周りに環状に供給するための樹脂材料供給装置18と、中心孔20Aを有する円板形状で外径が記録エリアArの内径よりも小さい透光性を有する円形被覆部材20を環状の樹脂材料16の上に移載するための円形被覆部材移載装置22と、基板12に放射線を照射して基板12上に展延された樹脂材料16を硬化させるための放射線照射装置24(図6参照)と、基板12上に展延された樹脂材料16における円形被覆部材20の外周20Bに相当する段部16Bを厚さ方向に加圧するための段部加圧装置26(図8参照)と、を備えている。   As shown in FIG. 1, the optical recording medium manufacturing apparatus 10 according to the first embodiment of the present invention includes a turntable 14 for installing a disc-shaped substrate 12 having a center hole 12A substantially horizontally, A resin material supply device 18 for annularly supplying a radiation curable resin material 16 having translucency on the substrate 12 around the center hole 12A in a fluidized state, and a disk shape having a center hole 20A. A circular covering member transfer device 22 for transferring a circular covering member 20 having a light transmissivity smaller in diameter than the inner diameter of the recording area Ar onto the annular resin material 16, and irradiating the substrate 12 with radiation. A radiation irradiation device 24 (see FIG. 6) for curing the resin material 16 spread on the substrate 12, and a step corresponding to the outer periphery 20B of the circular covering member 20 in the resin material 16 spread on the substrate 12. Section 16B in thickness direction Includes a stepped portion pressurizing device 26 for pressurizing (see FIG. 8), the.

基板12は、外径が約120mm、厚さが約1.1mmで、中心孔12Aの直径は約15mmである。基板12の材料としては、例えばポリカーボネート、アクリル、エポキシ等の樹脂等を用いることができる。   The substrate 12 has an outer diameter of about 120 mm, a thickness of about 1.1 mm, and the center hole 12A has a diameter of about 15 mm. As a material of the substrate 12, for example, a resin such as polycarbonate, acrylic, epoxy, or the like can be used.

又、基板12におけるピット、グルーブが形成された面の上には図示しない情報層が形成されている。情報層は、用途に応じて一又は複数の機能層で構成される。例えば、光記録媒体がROM(Read Only Memory)タイプの場合、情報層は材料がAl、Ag、Au等の反射層で構成される。又、RW(Re−Writable)タイプの場合は、反射層に加え、相変化材料層、光磁気材料層、誘電体材料層等の層で構成される。又、R(Recordable)タイプの場合は、反射層に加え、相変化材料層、有機色素層や無機材料層の記録層、誘電体材料層等の層で構成される。   An information layer (not shown) is formed on the surface of the substrate 12 on which pits and grooves are formed. The information layer is composed of one or more functional layers depending on the application. For example, when the optical recording medium is a ROM (Read Only Memory) type, the information layer is made of a reflective layer made of Al, Ag, Au, or the like. In the case of the RW (Re-Writable) type, in addition to the reflective layer, it is composed of layers such as a phase change material layer, a magneto-optical material layer, and a dielectric material layer. In the case of the R (Recordable) type, in addition to the reflective layer, it is composed of layers such as a phase change material layer, a recording layer of an organic dye layer or an inorganic material layer, and a dielectric material layer.

記録エリアArは、例えばφ48mm〜φ116mmの範囲に設定される。又、基板12を記録/再生装置にクランプするためのクランプエリアは、例えばφ23mm〜φ33mmの範囲である。   The recording area Ar is set, for example, in a range of φ48 mm to φ116 mm. The clamping area for clamping the substrate 12 to the recording / reproducing apparatus is, for example, in the range of φ23 mm to φ33 mm.

回転テーブル14は、略水平に配置された円板形状のテーブル部14Aから軸部14Bが下方に突出した構造である。又、回転テーブル14は、基板12の中心孔12A及び円形被覆部材20の中心孔20Aに嵌入してこれら基板12及び円形被覆部材20を位置決めするためのガイド14Cを備えている。尚、テーブル部14Aは図示しない負圧機構により基板12を吸着するようになっている。   The turntable 14 has a structure in which a shaft portion 14B protrudes downward from a disk-shaped table portion 14A arranged substantially horizontally. The turntable 14 includes a guide 14 </ b> C for fitting into the center hole 12 </ b> A of the substrate 12 and the center hole 20 </ b> A of the circular covering member 20 to position the substrate 12 and the circular covering member 20. The table portion 14A sucks the substrate 12 by a negative pressure mechanism (not shown).

ガイド14Cは上端部がこれよりも下の主部よりも細い段付の丸棒状体でテーブル部14A及び軸部14Bの中央部を上下方向に貫通し、テーブル部14Aの上面よりも上方に突出している。ガイド14Cの上端部は下方に拡径するテーパ形状であり根元部分の外径が円形被覆部材20の中心孔20Aの直径よりも若干小さい。又、ガイド14Cの主部の外径は基板12の中心孔12Aの直径よりも若干小さい。又、ガイド14Cは、図示しない駆動機構により上下動自在であり上昇しつつ円形被覆部材20を樹脂材料16から剥離可能とされている。即ち、ガイド14Cは円形被覆部材剥離装置を兼ねている。尚、ガイド14Cは軸部14Bにも係合されており(図示省略)、軸部14Bと共に一体で回転するようになっている。   The guide 14C is a stepped round bar-like body whose upper end is thinner than the main part below the guide 14C, penetrates the center of the table portion 14A and the shaft portion 14B in the vertical direction, and projects upward from the upper surface of the table portion 14A. ing. The upper end of the guide 14 </ b> C has a tapered shape that expands downward, and the outer diameter of the base portion is slightly smaller than the diameter of the center hole 20 </ b> A of the circular covering member 20. Further, the outer diameter of the main part of the guide 14C is slightly smaller than the diameter of the center hole 12A of the substrate 12. The guide 14 </ b> C can be moved up and down by a drive mechanism (not shown) so that the circular covering member 20 can be peeled from the resin material 16 while rising. That is, the guide 14C also serves as a circular covering member peeling device. The guide 14C is also engaged with the shaft portion 14B (not shown), and rotates together with the shaft portion 14B.

樹脂材料16は、具体的には、例えば紫外線や電子線等の放射線が照射されることにより硬化する性質を有する透光性のアクリル系やエポキシ系の樹脂である。ここで透光性とは、透明であるという意味に限定されず、例えば紫外光や青紫色の光線が透過できれば着色されていてもよい。   Specifically, the resin material 16 is a light-transmitting acrylic or epoxy resin having a property of being cured when irradiated with radiation such as ultraviolet rays or electron beams. Here, translucency is not limited to the meaning of being transparent, and may be colored as long as it can transmit ultraviolet light or blue-violet light, for example.

樹脂材料供給装置18は、樹脂材料16を基板12上に吐出するためのノズル18Aを備えている。ノズル18Aは可動であり、基板12の中心孔12Aの近傍に接近/離間自在とされている。   The resin material supply device 18 includes a nozzle 18 </ b> A for discharging the resin material 16 onto the substrate 12. The nozzle 18 </ b> A is movable and can approach / separate in the vicinity of the center hole 12 </ b> A of the substrate 12.

円形被覆部材20は、中心孔20Aの直径が0.1mm以上、15mm未満であり基板12の中心孔12Aの直径よりも小さい。円形被覆部材20の材料としては、例えばポリエチレンテレフタレート、ポリエチレンナフタレート、ポリカーボネート等のフィルム状の材料を用いることができる。尚、円形被覆部材20についても、透光性とは透明であるという意味に限定されず、紫外光や電子線等の放射線が透過できれば、円形被覆部材20の材料として例えばポリイミド、ポリアミド、アラミド等の着色された材料を用いてもよい。   In the circular covering member 20, the diameter of the center hole 20 </ b> A is not less than 0.1 mm and less than 15 mm, and is smaller than the diameter of the center hole 12 </ b> A of the substrate 12. As a material of the circular covering member 20, for example, a film-like material such as polyethylene terephthalate, polyethylene naphthalate, or polycarbonate can be used. In addition, the circular covering member 20 is not limited to the meaning of being transparent, and the material of the circular covering member 20 may be, for example, polyimide, polyamide, aramid, etc. as long as it can transmit radiation such as ultraviolet light and electron beam. Colored materials may be used.

又、円形被覆部材20は、少なくとも樹脂材料16との接触面が撥水性を有していることが好ましい。このような材料の具体例としては、例えば、ポリエチレンテレフタレートのフィルムの片面にシリコンを塗布した材料を挙げることができる。   The circular covering member 20 preferably has water repellency at least on the contact surface with the resin material 16. Specific examples of such a material include a material in which silicon is applied to one side of a polyethylene terephthalate film.

円形被覆部材移載装置22は、下端近傍が円筒形で下端において円形被覆部材20を保持するように構成された保持部22Aを備えている。保持部22Aの円筒形の部分には下端に連通する図示しない通気孔が形成されている。この通気孔には図示しない負圧供給装置が連結されており、保持部22Aは円形被覆部材20を負圧により吸着して保持するようになっている。尚、保持部22Aは、例えば静電気により円形被覆部材20を吸着して保持する構成としてもよい。   The circular covering member transfer device 22 includes a holding portion 22A configured so that the vicinity of the lower end is cylindrical and the circular covering member 20 is held at the lower end. An air hole (not shown) communicating with the lower end is formed in the cylindrical portion of the holding portion 22A. A negative pressure supply device (not shown) is connected to the vent hole, and the holding portion 22A is configured to adsorb and hold the circular covering member 20 with a negative pressure. The holding portion 22A may be configured to adsorb and hold the circular covering member 20 by, for example, static electricity.

又、円形被覆部材移載装置22は、保持部22Aを移送するための図示しない移送装置を備えており、円形被覆部材20を基板12側に加圧可能とされている。これにより、これら円形被覆部材20及び基板12の間の樹脂材料16の厚さを調整可能とされている。   The circular covering member transfer device 22 includes a transfer device (not shown) for transferring the holding portion 22A, and the circular covering member 20 can be pressurized toward the substrate 12 side. Thereby, the thickness of the resin material 16 between the circular covering member 20 and the substrate 12 can be adjusted.

又、円形被覆部材移載装置22は、回転テーブル14のガイド14Cが上昇して円形被覆部材20を樹脂材料16から剥離させる際、ガイド14Cと共に保持部22Aが円形被覆部材20を挟み込んだ状態で上昇し、剥離された円形被覆部材20を保持部22Aで保持して搬出するように構成されている。   In addition, when the guide 14C of the rotary table 14 is raised and the circular covering member 20 is peeled from the resin material 16, the circular covering member transfer device 22 is in a state where the holding portion 22A sandwiches the circular covering member 20 together with the guide 14C. The circular covering member 20 that has been lifted and separated is held by the holding portion 22A and carried out.

放射線照射装置24は、基板12に対して紫外線、電子線等の放射線を上方から照射して、基板12の上に展延された樹脂材料16を硬化させるように構成されている。   The radiation irradiation device 24 is configured to cure the resin material 16 spread on the substrate 12 by irradiating the substrate 12 with radiation such as ultraviolet rays and electron beams from above.

段部加圧装置26は、下端近傍が円筒形で下端において基板12上に展延された樹脂材料16における円形被覆部材20の外周20Bに相当する段部16Bに上方から当接して段部16Bを厚さ方向に加圧するための加圧部26Aを備えている。加圧部26Aは、図示しないヒータによる加熱や超音波の発振等により、段部16Bを軟化させるように構成されている。又、段部加圧装置26は、加圧部26Aを移送するための図示しない移送装置を備えており、加圧部26Aを基板12側に付勢して段部16Bを加圧可能とされている。尚、段部16Bは放射線の照射による硬化度をコントロールすることで、加熱や超音波の発振等により軟化可能であり、段部16Bを加圧して均した後に、再度放射線を照射することで、均された部分を完全に硬化させることができる。   The step pressurizing device 26 comes into contact with the step 16B corresponding to the outer periphery 20B of the circular covering member 20 in the resin material 16 extended on the substrate 12 at the lower end in the vicinity of the lower end, and contacts the step 16B from above. Is provided with a pressing portion 26A for pressing in the thickness direction. The pressurizing unit 26A is configured to soften the stepped portion 16B by heating with a heater (not shown), ultrasonic oscillation, or the like. Further, the step portion pressurizing device 26 includes a transfer device (not shown) for transferring the pressurizing portion 26A, and the step portion 16B can be pressurized by urging the pressurizing portion 26A toward the substrate 12 side. ing. The step 16B can be softened by controlling the degree of curing by irradiation with radiation, by heating, oscillating ultrasonic waves, etc., and by pressing and leveling the step 16B, irradiating again with radiation, The leveled portion can be completely cured.

次に、図2のフローチャートに沿って、光記録媒体の製造装置10を用いた光記録媒体の製造方法について説明する。   Next, an optical recording medium manufacturing method using the optical recording medium manufacturing apparatus 10 will be described with reference to the flowchart of FIG.

まず、情報層が形成された面が上向きになるように基板12を回転テーブル14に略水平に装着する。   First, the substrate 12 is mounted on the turntable 14 substantially horizontally so that the surface on which the information layer is formed faces upward.

次に、図1に示されるように、樹脂材料供給装置18のノズル18Aの下端を基板12の表面近傍、且つ、中心孔12Aよりも若干径方向外側の位置に配置し、回転テーブル14を回転させつつノズル18Aの下端から所定量の樹脂材料16を基板12上に供給する(S102)。これにより樹脂材料16は、基板12の中心孔12Aの周りに環状に供給される。   Next, as shown in FIG. 1, the lower end of the nozzle 18A of the resin material supply device 18 is arranged near the surface of the substrate 12 and slightly outside the center hole 12A, and the turntable 14 is rotated. Then, a predetermined amount of the resin material 16 is supplied onto the substrate 12 from the lower end of the nozzle 18A (S102). As a result, the resin material 16 is annularly supplied around the center hole 12 </ b> A of the substrate 12.

次に、円形被覆部材移載装置22の保持部22Aで円形被覆部材20を保持し、円形被覆部材20の中心と回転テーブル14の中心とが一致する位置まで円形被覆部材20を移送してから下降させ、図3に示されるように、中心孔20Aに回転テーブル14のガイド14Cの上端部が嵌入するように円形被覆部材20を環状の樹脂材料16の上に移載する(S104)。この際、円形被覆部材20を基板12側に加圧してこれら円形被覆部材20及び基板12の間の樹脂材料16の厚さを所定の厚さに調整する。   Next, the circular covering member 20 is held by the holding portion 22A of the circular covering member transfer device 22, and the circular covering member 20 is transferred to a position where the center of the circular covering member 20 coincides with the center of the rotary table 14. As shown in FIG. 3, the circular covering member 20 is transferred onto the annular resin material 16 so that the upper end portion of the guide 14C of the turntable 14 is fitted into the center hole 20A (S104). At this time, the circular covering member 20 is pressed toward the substrate 12 to adjust the thickness of the resin material 16 between the circular covering member 20 and the substrate 12 to a predetermined thickness.

次に、図4に示されるように、保持部22Aを上昇させてから、回転テーブル14を回転させて樹脂材料16を遠心力により径方向外側に流動させる(S106)。この際、円形被覆部材20と基板12との間に挟まれた樹脂材料16は、両者との摩擦力により流動が抑制される。言い換えれば、円形被覆部材20と基板12との間の部分が樹脂材料16の貯留部のような役割を果たし、基板12上における樹脂材料16の流動量を緩衝して安定させる。これにより、樹脂材料16は、基板12上に均一な厚さで展延される。尚、回転テーブル14を回転させつつ、保持部22Aで円形被覆部材20を基板12側に加圧して、樹脂材料16の流動量を増加させることも可能である。更に、樹脂材料16が径方向外側に流動し、図5に示されるように、樹脂材料16が基板12の全面に展延されて厚さが約100μmとなったところで、回転テーブル14の回転を停止させる。尚、円形被覆部材20の外周20Bには樹脂材料16が盛り上がるように付着して段部16Bが形成される。又、基板12の外周近傍においても樹脂材料16は若干盛り上がった形状に成形されて段部16Cが形成されるが、この段部16Cは記録エリアArの外側であるので実用上問題はない。   Next, as shown in FIG. 4, after raising the holding portion 22A, the turntable 14 is rotated to cause the resin material 16 to flow radially outward by centrifugal force (S106). At this time, the flow of the resin material 16 sandwiched between the circular covering member 20 and the substrate 12 is suppressed by the frictional force between them. In other words, the portion between the circular covering member 20 and the substrate 12 serves as a reservoir for the resin material 16, and the flow amount of the resin material 16 on the substrate 12 is buffered and stabilized. As a result, the resin material 16 is spread on the substrate 12 with a uniform thickness. It is also possible to increase the flow amount of the resin material 16 by pressing the circular covering member 20 toward the substrate 12 with the holding portion 22A while rotating the turntable 14. Furthermore, when the resin material 16 flows radially outward and the resin material 16 is spread over the entire surface of the substrate 12 to a thickness of about 100 μm, as shown in FIG. Stop. A step 16B is formed on the outer periphery 20B of the circular covering member 20 by adhering the resin material 16 so as to rise. Also, the resin material 16 is formed in a slightly raised shape near the outer periphery of the substrate 12 to form a stepped portion 16C, but this stepped portion 16C is outside the recording area Ar, so there is no practical problem.

次に、図6に示されるように、放射線照射装置24から基板12に放射線を照射して樹脂材料16を硬化させる(S108)。この工程では、少なくとも円形被覆部材20の外周20B近傍に放射線を照射する際、基板12を回転させながら放射線を照射することが好ましい。このようにすることで円形被覆部材20の外周20Bに沿って形成される樹脂材料16の段部16Bの突出量を抑制した形状で樹脂材料16を硬化させることができる。又、この工程では、少なくとも円形被覆部材20の外周20B近傍に放射線を照射する際、段部16Bがヒータによる加熱や超音波の発振等により軟化可能である程度の硬化度で硬化するように、放射線の照射量を制限する。尚、円形被覆部材20が透光性を有しているので、円形被覆部材20の下の樹脂材料16も円形被覆部材20を介して放射線が照射されて硬化する。   Next, as shown in FIG. 6, the resin material 16 is cured by irradiating the substrate 12 with radiation from the radiation irradiating device 24 (S108). In this step, it is preferable to irradiate radiation while rotating the substrate 12 when irradiating at least the vicinity of the outer periphery 20B of the circular covering member 20. By doing in this way, the resin material 16 can be hardened with the shape which suppressed the protrusion amount of the step part 16B of the resin material 16 formed along the outer periphery 20B of the circular coating | coated member 20. FIG. Also, in this process, when irradiating at least the vicinity of the outer periphery 20B of the circular covering member 20, the radiation of the stepped portion 16B can be softened by heating with a heater, oscillation of ultrasonic waves, etc. and cured with a certain degree of curing. Limit the amount of irradiation. In addition, since the circular covering member 20 has translucency, the resin material 16 under the circular covering member 20 is irradiated with radiation through the circular covering member 20 and is cured.

次に、図7に示されるように、円形被覆部材移載装置22の保持部22A及び回転テーブル14のガイド14Cで円形被覆部材20を挟み込み、これらガイド14C及び保持部22Aを上昇させて、樹脂材料16から円形被覆部材20を剥離する(S110)。剥離した円形被覆部材20は、保持部22Aで保持して搬出する。   Next, as shown in FIG. 7, the circular covering member 20 is sandwiched between the holding portion 22A of the circular covering member transfer device 22 and the guide 14C of the rotary table 14, and the guide 14C and the holding portion 22A are lifted to form a resin. The circular covering member 20 is peeled from the material 16 (S110). The peeled circular covering member 20 is held and carried out by the holding portion 22A.

次に、図8に示されるように、段部加圧装置26の加圧部26Aを樹脂材料16の段部16Bに当接させてヒータによる加熱や超音波の発振等により段部16Bを軟化させる共に加圧部26Aを厚さ方向に付勢して段部16Bを加圧する(S112)。これにより、樹脂材料16の表面が均される。尚、均された部分を含む、樹脂材料16においてヒータによる加熱や超音波の発振等により軟化可能である程度に硬化した部分には再度放射線を照射して完全に硬化させる(S114)。これにより、図9に示されるような(記録エリアArの外側の部分を除いて)厚さが均一なカバー層28が形成され、光記録媒体30が完成する。   Next, as shown in FIG. 8, the pressurizing portion 26A of the stepped portion pressurizing device 26 is brought into contact with the stepped portion 16B of the resin material 16, and the stepped portion 16B is softened by heating with a heater, oscillation of ultrasonic waves, or the like. At the same time, the pressing portion 26A is urged in the thickness direction to pressurize the stepped portion 16B (S112). Thereby, the surface of the resin material 16 is leveled. In addition, the resin material 16 including the smoothed portion is completely cured by irradiating the portion of the resin material 16 that has been softened to some extent by heating with a heater or oscillating ultrasonic waves (S114). As a result, a cover layer 28 having a uniform thickness as shown in FIG. 9 (excluding the portion outside the recording area Ar) is formed, and the optical recording medium 30 is completed.

このように、基板12の中心孔12Aの周囲に樹脂材料16を供給するので、基板の中心部に樹脂材料を供給する場合よりも樹脂材料が流動する距離が短い。従って、樹脂材料16の展延に要する時間がそれだけ短く生産効率がよい。   Thus, since the resin material 16 is supplied around the center hole 12A of the substrate 12, the distance that the resin material flows is shorter than when the resin material is supplied to the central portion of the substrate. Therefore, the time required for spreading the resin material 16 is so short that the production efficiency is good.

又、基板12の中心孔12Aの周囲に樹脂材料16を供給しても円形被覆部材20で樹脂材料16の流動を制御することができ、カバー層28を均一な厚さで形成できる。   Even if the resin material 16 is supplied around the center hole 12A of the substrate 12, the flow of the resin material 16 can be controlled by the circular covering member 20, and the cover layer 28 can be formed with a uniform thickness.

次に、本発明の第2実施形態について説明する。   Next, a second embodiment of the present invention will be described.

本第2実施形態は、前記第1実施形態に対し、段部加圧装置26に代えて図10に示されるような段部削除装置50が備えられ、図11のフローチャートに示されるように、段部加圧工程(S112)に代えて、段部削除工程(S200)が設けられたことを特徴としている。尚、放射線照射工程(S108)では、段部16Bを含む樹脂材料16全体を完全に硬化させ、放射線再照射工程(S114)は行わない。他の工程については前記第1実施形態と同様であるので図1〜図9と同一符号を用いることとして説明を適宜省略する。   Compared to the first embodiment, the second embodiment is provided with a step portion deleting device 50 as shown in FIG. 10 instead of the step portion pressurizing device 26, and as shown in the flowchart of FIG. Instead of the step pressurizing step (S112), a step deleting step (S200) is provided. In the radiation irradiation step (S108), the entire resin material 16 including the step portion 16B is completely cured, and the radiation re-irradiation step (S114) is not performed. Since other steps are the same as those in the first embodiment, the same reference numerals as those in FIGS.

段部削除装置50は、下端近傍が円筒形状で下端面に刃が形成された円形工具52を有し、該円形工具52を回転させつつ樹脂材料16の段部16Bに当接させることにより段部16Bを削除するようになっている。尚、円形工具52を回転させずに回転テーブル14を回転させて段部16Bを削除してもよい。又、円形工具52及び回転テーブル14両方を逆方向に回転させて段部16Bを削除してもよい。   The step portion deleting device 50 has a circular tool 52 having a cylindrical shape near the lower end and a blade formed on the lower end surface, and the stepped portion is brought into contact with the step portion 16B of the resin material 16 while rotating the circular tool 52. The part 16B is deleted. Note that the step portion 16B may be deleted by rotating the rotary table 14 without rotating the circular tool 52. Alternatively, the step 16B may be deleted by rotating both the circular tool 52 and the rotary table 14 in the reverse direction.

これにより、前記第1実施形態と同様に図9に示されるような(記録エリアArの外側の部分を除いて)厚さが均一なカバー層28が形成され、光記録媒体30が完成する。   As a result, as in the first embodiment, the cover layer 28 having a uniform thickness as shown in FIG. 9 (excluding the portion outside the recording area Ar) is formed, and the optical recording medium 30 is completed.

尚、円形工具52に代えて例えばエンドミルを回転させながら環状の段部16Bに沿って円周軌道で移動させて段部16Bを削除してもよい。   Instead of the circular tool 52, for example, the step 16B may be deleted by moving along an annular step 16B along a circular path while rotating the end mill.

次に、本発明の第3実施形態について説明する。   Next, a third embodiment of the present invention will be described.

本第3実施形態は、前記第1実施形態に対し、図12のフローチャートに示されるように、放射線照射工程(S108)と円形被覆部材剥離工程(S110)との間に、円形被覆部材20の外周20Bに沿って樹脂材料20に円形の切り込みを形成する切り込み形成工程(S300)が設けられ、段部加圧工程(S112)が省略されたことを特徴としている。又、上記第2実施形態と同様に放射線照射工程(S108)では、段部16Bを含む樹脂材料16全体を完全に硬化させ、放射線再照射工程(S114)は行わない。他の工程については前記第1実施形態と同様であるので図1〜図9と同一符号を用いることとして説明を適宜省略する。   The third embodiment is different from the first embodiment in that the circular covering member 20 is disposed between the radiation irradiation step (S108) and the circular covering member peeling step (S110) as shown in the flowchart of FIG. A notch forming step (S300) for forming a circular notch in the resin material 20 along the outer periphery 20B is provided, and the step pressurizing step (S112) is omitted. In the radiation irradiation step (S108) as in the second embodiment, the entire resin material 16 including the stepped portion 16B is completely cured, and the radiation re-irradiation step (S114) is not performed. Since other steps are the same as those in the first embodiment, the same reference numerals as those in FIGS.

図13に示されるように、切り込み形成工程(S300)では、下端が尖鋭な円筒形状である円形工具32を樹脂材料20に加圧することにより、段部16Bよりも径方向の外側において円形被覆部材20の外周20Bに沿って樹脂材料20に円形の切り込みを形成する。尚、円周方向の一部だけにカッタのような工具を当接させて基板12を回転させることにより、樹脂材料20に円形の切り込みを形成してもよい。   As shown in FIG. 13, in the notch forming step (S300), the circular covering member is pressed on the outer side in the radial direction from the step portion 16B by pressing the circular tool 32 having a sharp cylindrical shape at the lower end against the resin material 20. A circular cut is formed in the resin material 20 along the outer periphery 20 </ b> B of 20. Note that a circular cut may be formed in the resin material 20 by rotating the substrate 12 by bringing a tool such as a cutter into contact with only a part in the circumferential direction.

次に、図14に示されるように、円形被覆部材移載装置22の保持部22A及び回転テーブル14のガイド14Cで円形被覆部材20を挟み込み、これらガイド14C及び保持部22Aを保持して上昇させ、樹脂材料16から円形被覆部材20を剥離する(S110)。これにより、円形被覆部材20と共に段部16Bを含む円形被覆部材20の周囲の樹脂材料16も除去される。これにより、(記録エリアArの外側の部分を除いて)表面が平坦なカバー層28が形成されて光記録媒体が完成する。この光記録媒体は、クランプエリアの樹脂材料16が除去されており、記録/再生装置に装着された場合にクランプ機構がカバー層28の内周部に接触しないので、カバー層28が剥離しにくい。   Next, as shown in FIG. 14, the circular covering member 20 is sandwiched between the holding portion 22A of the circular covering member transfer device 22 and the guide 14C of the rotary table 14, and the guide 14C and the holding portion 22A are held and raised. Then, the circular covering member 20 is peeled from the resin material 16 (S110). Thereby, the resin material 16 around the circular covering member 20 including the step portion 16 </ b> B is also removed together with the circular covering member 20. Thereby, the cover layer 28 having a flat surface is formed (excluding the portion outside the recording area Ar), and the optical recording medium is completed. In this optical recording medium, the resin material 16 in the clamp area is removed, and the clamp mechanism does not come into contact with the inner peripheral portion of the cover layer 28 when mounted on a recording / reproducing apparatus. .

次に、本発明の第4実施形態について説明する。   Next, a fourth embodiment of the present invention will be described.

前記第1実施形態に係る円形被覆部材20は外周側面の外径が一定であるのに対し、本第4実施形態は、図15に示されるように、外周側面がテーパ形状の円形被覆部材60を用い、基板12から離間する方向に外周側面が拡径する姿勢で円形被覆部材60を樹脂材料16の上に移載することを特徴としている。他の工程については前記第1実施形態と同様であるので図1〜図9と同一符号を用いることとして説明を適宜省略する。このように外周側面がテーパ形状の円形被覆部材60を用いることで、樹脂材料16の段部16Bの成長を抑制できると共に円形被覆部材60をカバー層28から剥離しやすくする効果が得られる。尚、段部16Bは、上記第1〜第3実施形態と同様に加圧や削除により均すことができる。   The circular covering member 20 according to the first embodiment has a constant outer diameter on the outer peripheral side surface, whereas in the fourth embodiment, as shown in FIG. 15, the circular covering member 60 whose outer peripheral side surface is tapered. The circular covering member 60 is transferred onto the resin material 16 in such a posture that the outer peripheral side surface is expanded in the direction away from the substrate 12. Since other steps are the same as those in the first embodiment, the same reference numerals as those in FIGS. Thus, by using the circular covering member 60 whose outer peripheral side surface is tapered, the growth of the stepped portion 16B of the resin material 16 can be suppressed and the effect of easily peeling the circular covering member 60 from the cover layer 28 can be obtained. In addition, the step part 16B can be leveled by pressurization or deletion similarly to the first to third embodiments.

尚、前記第1〜第4実施形態において、円形被覆部材移載装置22の保持部22A及び回転テーブル14のガイド14Cで円形被覆部材20を挟み込み、これらガイド14C及び保持部22Aを保持して上昇させて、樹脂材料16から円形被覆部材20を剥離しているが、円形被覆部材移載装置22の保持部22Aを円形被覆部材20から離間させた状態でガイド14Cを保持して上昇させて、樹脂材料16から円形被覆部材20を剥離した後、保持部22Aで円形被覆部材20を保持して搬出してもよい。   In the first to fourth embodiments, the circular covering member 20 is sandwiched between the holding portion 22A of the circular covering member transfer device 22 and the guide 14C of the rotary table 14, and the guide 14C and the holding portion 22A are held and lifted. The circular covering member 20 is peeled from the resin material 16, but the guide 14C is held and raised in a state where the holding portion 22A of the circular covering member transfer device 22 is separated from the circular covering member 20, After peeling off the circular covering member 20 from the resin material 16, the circular covering member 20 may be held and carried out by the holding portion 22A.

又、前記第1〜第4実施形態において、ガイド14Cを上昇させて、樹脂材料16から円形被覆部材20を剥離しているが、ガイド14Cを上昇させることなく円形被覆部材移載装置22の保持部22Aで円形被覆部材20を吸着して保持部22Aを上昇させることにより、樹脂材料16から円形被覆部材20を剥離してもよい。即ち、円形被覆部材移載装置22が円形被覆部材剥離装置を兼ねる構成としてもよい。尚、この場合、ガイド14Cは、段付形状である必要はない。   In the first to fourth embodiments, the guide 14C is raised to peel the circular covering member 20 from the resin material 16, but the circular covering member transfer device 22 is held without raising the guide 14C. The circular covering member 20 may be peeled from the resin material 16 by adsorbing the circular covering member 20 by the portion 22A and raising the holding portion 22A. In other words, the circular covering member transfer device 22 may also serve as the circular covering member peeling device. In this case, the guide 14C does not need to have a stepped shape.

又、前記第1〜第4実施形態において、円形被覆部材20の中心孔20Aの直径は0.1mm以上、15mm未満で基板12の中心孔12Aの直径よりも小さいが、樹脂材料16を均一な厚さで展延でき、又、円形被覆部材20を樹脂材料16から確実に剥離できれば、基板12の中心孔12Aの直径よりも中心孔の直径が大きい円形被覆部材を用いてもよい。例えば、中心孔の直径が15mm以上、20mm以下程度の円形被覆部材を用いてもよい。   In the first to fourth embodiments, the diameter of the center hole 20A of the circular covering member 20 is 0.1 mm or more and less than 15 mm and smaller than the diameter of the center hole 12A of the substrate 12, but the resin material 16 is made uniform. A circular covering member having a diameter of the central hole larger than the diameter of the central hole 12 </ b> A of the substrate 12 may be used as long as it can be spread with a thickness and the circular covering member 20 can be reliably peeled from the resin material 16. For example, a circular covering member having a center hole diameter of about 15 mm or more and 20 mm or less may be used.

又、前記第1〜第4実施形態において、段部16Bを加圧や削除により均しているが、実用上問題がなければ段部16Bを残存させてもよい。   Moreover, in the said 1st-4th embodiment, although the step part 16B is equalized by pressurization or deletion, if there is no problem practically, you may leave the step part 16B.

又、前記第1〜第4実施形態において、カバー層の厚さは約100μmであるが、カバー層の厚さは情報層の積層数等に応じて適宜設定すればよい。例えば、情報層を2層形成する場合は、カバー層の厚さを75μmとしてもよい。   In the first to fourth embodiments, the thickness of the cover layer is about 100 μm, but the thickness of the cover layer may be appropriately set according to the number of information layers stacked. For example, when two information layers are formed, the cover layer may have a thickness of 75 μm.

又、前記第1〜第4実施形態において、カバー層は基板の片面だけに形成されているが、情報層が基板の両面に形成される両面記録式の光記録媒体についても本発明は適用可能である。この場合、前記第1〜第4実施形態のような手法でカバー層も両面に形成すればよい。尚、前記第1〜第4実施形態において、基板の厚さは約1.1mmであるが、両面記録式の場合は、例えば、基板の厚さを1.0mmとすればよい。   In the first to fourth embodiments, the cover layer is formed only on one side of the substrate. However, the present invention can also be applied to a double-sided recording type optical recording medium in which the information layer is formed on both sides of the substrate. It is. In this case, the cover layer may be formed on both sides by the method as in the first to fourth embodiments. In the first to fourth embodiments, the thickness of the substrate is about 1.1 mm. In the case of the double-side recording type, for example, the thickness of the substrate may be 1.0 mm.

表1に示されるような、外径及び厚さが異なるA〜Hの8種類の円形被覆部材20を用意し、これら8種類の円形被覆部材20を用いて前記第1実施形態のとおり8種類の光記録媒体30を作製した。主な製造条件を以下に示す。   As shown in Table 1, eight types of circular covering members 20 of A to H having different outer diameters and thicknesses are prepared, and these eight types of circular covering members 20 are used as in the first embodiment. An optical recording medium 30 was prepared. The main production conditions are shown below.

Figure 2007073124
Figure 2007073124

樹脂材料供給工程(S102)では、樹脂材料16として、粘度が約2000cpの紫外線硬化性樹脂を用いた。又、回転テーブル14の回転速度を約15rpmに設定し、上記の樹脂材料16を約3g、基板12上における中心から11〜25mmの範囲に供給した。樹脂材料16は、径方向の幅が約14mm、高さが約2mmの環状となった。   In the resin material supply step (S102), an ultraviolet curable resin having a viscosity of about 2000 cp was used as the resin material 16. Moreover, the rotation speed of the turntable 14 was set to about 15 rpm, and about 3 g of the resin material 16 was supplied in a range of 11 to 25 mm from the center on the substrate 12. The resin material 16 has an annular shape having a radial width of about 14 mm and a height of about 2 mm.

円形被覆部材移載工程(S106)では、外径及び厚さが上記表1に示される値であり、材料がポリエチレンテレフタレートで中心孔20Aの直径が約15mmの円形被覆部材20を環状の樹脂材料16の上に移載し、円形被覆部材20を略水平に保持しつつ基板12側に加圧して約1mm押し込み、円形被覆部材20と基板12との間の樹脂材料16の厚さを約1mmに調整した。   In the circular covering member transfer step (S106), the outer diameter and thickness are the values shown in Table 1 above, the material is polyethylene terephthalate, and the diameter of the central hole 20A is about 15 mm. 16, and while pressing the circular covering member 20 substantially horizontally, pressurizing it toward the substrate 12 and pushing it in for about 1 mm, the thickness of the resin material 16 between the circular covering member 20 and the substrate 12 is about 1 mm. Adjusted.

樹脂材料展延工程(S106)では、回転テーブル14の回転速度をまず約300rpmまで増加させて一定時間この回転速度を保持した後、1300rpmまで回転速度を増加させた。   In the resin material spreading step (S106), the rotation speed of the turntable 14 was first increased to about 300 rpm, and this rotation speed was maintained for a certain period of time, and then the rotation speed was increased to 1300 rpm.

以上の製造条件の下で製造された光記録媒体30のカバー層28の厚さを複数の部位で測定した。測定結果を図16及び図17に示す。尚、図16及び図17の横軸は、光記録媒体の中心から測定部位までの径方向の距離を示す。又、図16及び図17中の符号A〜Hは、これらが付された曲線が、それぞれA〜Hの円形被覆部材20を用いて製造された光記録媒体30のデータであることを示す。   The thickness of the cover layer 28 of the optical recording medium 30 manufactured under the above manufacturing conditions was measured at a plurality of sites. The measurement results are shown in FIGS. 16 and 17 indicate the radial distance from the center of the optical recording medium to the measurement site. In addition, reference signs A to H in FIGS. 16 and 17 indicate that the curves with these marks are data of the optical recording medium 30 manufactured using the circular covering members 20 of A to H, respectively.

[比較例]
上記実施例に対し、円形被覆部材20を用いないで1種類の光記録媒体を作製した。尚、他の製造条件は実施例と同様とした。
[Comparative example]
In contrast to the above example, one type of optical recording medium was manufactured without using the circular covering member 20. Other manufacturing conditions were the same as in the examples.

この光記録媒体のカバー層の厚さを複数の部位で測定した。測定結果を図16及び図17双方に示す。図16及び図17中において符号Xが付された曲線が、円形被覆部材20を用いないで製造された比較例に係る光記録媒体のデータである。   The thickness of the cover layer of this optical recording medium was measured at a plurality of sites. The measurement results are shown in both FIG. 16 and FIG. 16 and 17 are data of an optical recording medium according to a comparative example manufactured without using the circular covering member 20.

図16及び17に示されるように、A〜Hの円形被覆部材20を用いて製造された光記録媒体30はいずれも、円形被覆部材20を用いないで製造された比較例に係る光記録媒体よりもカバー層の厚さのばらつきが小さく抑制されていることが確認された。   As shown in FIGS. 16 and 17, the optical recording medium 30 manufactured using the circular covering members 20 of A to H is an optical recording medium according to a comparative example manufactured without using the circular covering member 20. It was confirmed that the variation in the thickness of the cover layer was suppressed to a smaller level.

本発明は、基板の上に基板よりも薄いカバー層が形成され、且つ、中心孔が形成された光記録媒体に利用することができる。   The present invention can be used for an optical recording medium in which a cover layer thinner than a substrate is formed on a substrate and a central hole is formed.

本発明の第1実施形態に係る光記録媒体の製造装置の主要部の構造を模式的に示す側断面図1 is a side sectional view schematically showing the structure of a main part of an optical recording medium manufacturing apparatus according to a first embodiment of the present invention. 同光記録媒体の製造装置を用いた光記録媒体の製造工程の概要を示すフローチャートThe flowchart which shows the outline | summary of the manufacturing process of the optical recording medium using the manufacturing apparatus of the optical recording medium 同製造装置により環状の樹脂材料上に円形被覆部材を移載する工程を模式的に示す側断面図Side sectional view which shows typically the process of transferring a circular coating | coated member on the cyclic | annular resin material with the manufacturing apparatus. 同樹脂材料が前記基板上の一部に展延された状態を模式的に示す側断面図Side sectional view schematically showing a state in which the resin material is spread on a part of the substrate 同樹脂材料が前記基板上の全面に展延された状態を模式的に示す側断面図Side sectional view schematically showing a state in which the resin material is spread over the entire surface of the substrate. 同基板に放射線を照射する工程を模式的に示す側断面図Side sectional view schematically showing the process of irradiating the substrate with radiation 同樹脂材料から前記円形被覆部材を剥離する工程を模式的に示す側断面図Side sectional view which shows typically the process of peeling the said circular coating | coated member from the resin material 同樹脂材料の段部を加圧する工程を模式的に示す側断面図Side sectional view schematically showing the process of pressurizing the step of the resin material 同光記録媒体の製造装置により製造された光記録媒体の構造を模式的に示す側断面図Side sectional view schematically showing the structure of an optical recording medium manufactured by the optical recording medium manufacturing apparatus 本発明の第2実施形態に係る光記録媒体の製造装置の段部削除装置の構造を模式的に示す側断面図Sectional drawing which shows typically the structure of the step part deletion apparatus of the manufacturing apparatus of the optical recording medium based on 2nd Embodiment of this invention 同第2実施形態に係る光記録媒体の製造工程の概要を示すフローチャートThe flowchart which shows the outline | summary of the manufacturing process of the optical recording medium based on the said 2nd Embodiment. 本発明の第3実施形態に係る光記録媒体の製造工程の概要を示すフローチャートFlowchart showing an outline of the manufacturing process of the optical recording medium according to the third embodiment of the present invention. 同第3実施形態においてカバー層に切り込みを形成する工程を模式的に示す側断面図Side sectional view which shows typically the process of forming a notch in a cover layer in the same 3rd embodiment 第3実施形態において樹脂材料を剥離する工程を模式的に示す側断面図Side sectional view which shows typically the process of peeling resin material in 3rd Embodiment 本発明の第4実施形態に係る円形被覆部材を拡大して示す側断面図Side sectional view which expands and shows the circular coating | coated member which concerns on 4th Embodiment of this invention. 本発明の実施例及び比較例に係る光記録媒体のカバー層の厚さのばらつきを対比して示すグラフThe graph which compares and compares the dispersion | variation in the thickness of the cover layer of the optical recording medium which concerns on the Example and comparative example of this invention 本発明の他の実施例及び同比較例に係る光記録媒体のカバー層の厚さのばらつきを対比して示すグラフThe graph which compares and compares the dispersion | variation in the thickness of the cover layer of the optical recording medium based on the other Example of this invention, and the comparative example

符号の説明Explanation of symbols

10…光記録媒体の製造装置
12…基板
12A…中心孔
14…回転テーブル
16…樹脂材料
18…樹脂材料供給装置
20、60…円形被覆部材
20A…中心孔
20B…外周
22…円形被覆部材移載装置
24…放射線照射装置
26…段部加圧装置
28…カバー層
30、40…光記録媒体
32、52…円形工具
50…段部削除装置
Ar…記録エリア
S102…樹脂材料供給工程
S104…円形被覆部材移載工程
S106…樹脂材料展延工程
S108…放射線照射工程
S110…円形被覆部材剥離工程
S112…段部加圧工程
S114…放射線再照射工程
S200…段部削除工程
S300…切り込み形成工程
DESCRIPTION OF SYMBOLS 10 ... Manufacturing apparatus of optical recording medium 12 ... Board | substrate 12A ... Center hole 14 ... Rotary table 16 ... Resin material 18 ... Resin material supply apparatus 20, 60 ... Circular covering member 20A ... Center hole 20B ... Outer periphery 22 ... Circular covering member transfer Device 24 ... Radiation irradiation device 26 ... Step part pressurization device 28 ... Cover layer 30, 40 ... Optical recording medium 32, 52 ... Circular tool 50 ... Step part deletion device Ar ... Recording area S102 ... Resin material supply step S104 ... Circular coating Member transfer step S106 ... Resin material spreading step S108 ... Radiation irradiation step S110 ... Circular covering member peeling step S112 ... Step portion pressurization step S114 ... Radiation re-irradiation step S200 ... Step portion deletion step S300 ... Cut formation step

Claims (14)

中心孔を有する円板形状で略水平に設置された基板の上に透光性を有する放射線硬化性の樹脂材料を流動状態で前記中心孔の周りに環状に供給する樹脂材料供給工程と、中心孔を有する円板形状で外径が記録エリアの内径よりも小さい透光性を有する円形被覆部材を前記環状の樹脂材料の上に移載する円形被覆部材移載工程と、前記基板及び前記円形被覆部材を回転させて前記樹脂材料を遠心力により径方向外側に流動させて前記基板上に展延する樹脂材料展延工程と、前記基板に放射線を照射して前記樹脂材料を硬化させる放射線照射工程と、前記円形被覆部材を前記樹脂材料から剥離する円形被覆部材剥離工程と、を含むことを特徴とする光記録媒体の製造方法。   A resin material supplying step for supplying a radiation curable resin material having translucency onto a substrate having a disk shape and having a central hole in an annular shape around the central hole in a fluid state; A circular covering member transfer step of transferring a circular covering member having a disc shape having a hole and having a translucency whose outer diameter is smaller than the inner diameter of the recording area onto the annular resin material; and the substrate and the circular shape A resin material spreading step of rotating the coating member to flow the resin material radially outward by centrifugal force and spreading it on the substrate, and radiation irradiation for irradiating the substrate with radiation to cure the resin material And a circular covering member peeling step of peeling the circular covering member from the resin material. 請求項1において、
前記円形被覆部材移載工程及び前記展延工程の少なくとも一方において前記円形被覆部材を前記基板側に加圧することを特徴とする光記録媒体の製造方法。
In claim 1,
A method for manufacturing an optical recording medium, wherein the circular covering member is pressed toward the substrate in at least one of the circular covering member transfer step and the spreading step.
請求項1又は2において、
前記放射線照射工程において、前記基板を回転させつつ前記円形被覆部材の外周近傍に放射線を照射することを特徴とする光記録媒体の製造方法。
In claim 1 or 2,
In the radiation irradiating step, radiation is applied to the vicinity of the outer periphery of the circular covering member while rotating the substrate.
請求項1乃至3のいずれかにおいて、
前記円形被覆部材として少なくとも前記樹脂材料との接触面が撥水性を有する円形被覆部材を用いることを特徴とする光記録媒体の製造方法。
In any one of Claims 1 thru | or 3,
A method of manufacturing an optical recording medium, wherein a circular covering member having at least a contact surface with the resin material having water repellency is used as the circular covering member.
請求項1乃至4のいずれかにおいて、
前記円形被覆部材として外周側面がテーパ形状である円形被覆部材を用い、前記円形被覆部材移載工程において前記基板から離間する方向に前記外周側面が拡径する姿勢で前記円形被覆部材を前記樹脂材料の上に移載することを特徴とする光記録媒体の製造方法。
In any one of Claims 1 thru | or 4,
As the circular covering member, a circular covering member having a tapered outer peripheral side surface is used, and in the circular covering member transfer step, the circular covering member is placed in the posture in which the outer peripheral side surface expands in a direction away from the substrate. A method for producing an optical recording medium, wherein the method is transferred onto a recording medium.
請求項1乃至5のいずれかにおいて、
前記円形被覆部材剥離工程の後に、前記樹脂材料における前記円形被覆部材の外周に相当する段部を厚さ方向に加圧する段部加圧工程が設けられたことを特徴とする光記録媒体の製造方法。
In any one of Claims 1 thru | or 5,
A step of pressing a step corresponding to the outer periphery of the circular covering member in the resin material in the thickness direction is provided after the step of peeling the circular covering member. Method.
請求項1乃至5のいずれかにおいて、
前記円形被覆部材剥離工程の後に、前記樹脂材料における前記円形被覆部材の外周に相当する段部を除去する段部除去工程が設けられたことを特徴とする光記録媒体の製造方法。
In any one of Claims 1 thru | or 5,
A method of manufacturing an optical recording medium, comprising: a step removing step for removing a step corresponding to an outer periphery of the circular covering member in the resin material after the circular covering member peeling step.
中心孔を有する円板形状の基板を略水平に設置するための回転テーブルと、前記基板の上に透光性を有する放射線硬化性の樹脂材料を流動状態で前記中心孔の周りに環状に供給するための樹脂材料供給装置と、中心孔を有する円板形状で外径が記録エリアの内径よりも小さい透光性を有する円形被覆部材を前記環状の樹脂材料の上に移載するための円形被覆部材移載装置と、前記基板に放射線を照射して該基板上に展延された前記樹脂材料を硬化させるための放射線照射装置と、前記円形被覆部材を前記樹脂材料から剥離するための円形被覆部材剥離装置と、を含むことを特徴とする光記録媒体の製造装置。   A rotary table for installing a disk-shaped substrate having a center hole substantially horizontally, and a radiation-curable resin material having translucency on the substrate are supplied in an annular shape around the center hole in a fluid state. And a circular material for transferring a circular covering member having a disc shape having a central hole and a translucency whose outer diameter is smaller than the inner diameter of the recording area onto the annular resin material. A covering member transfer device, a radiation irradiation device for irradiating the substrate with radiation and curing the resin material spread on the substrate, and a circle for peeling the circular covering member from the resin material An apparatus for producing an optical recording medium, comprising: a covering member peeling device. 請求項8において、
前記円形被覆部材移載装置は、前記円形被覆部材を前記基板側に加圧可能であることを特徴とする光記録媒体の製造装置。
In claim 8,
The apparatus for manufacturing an optical recording medium, wherein the circular covering member transfer device can pressurize the circular covering member toward the substrate.
請求項8又は9において、
前記回転テーブルは、前記基板の中心孔及び前記円形被覆部材の中心孔に嵌入してこれら基板及び円形被覆部材を位置決めするためのガイドを備えることを特徴とする光記録媒体の製造装置。
In claim 8 or 9,
An apparatus for manufacturing an optical recording medium, wherein the turntable includes a guide for positioning the substrate and the circular covering member by fitting into the central hole of the substrate and the central hole of the circular covering member.
請求項10において、
前記ガイドは、上下動自在で上昇しつつ前記円形被覆部材を前記樹脂材料から剥離可能であり、前記円形被覆部材剥離装置を兼ねることを特徴とする光記録媒体の製造装置。
In claim 10,
2. The optical recording medium manufacturing apparatus according to claim 1, wherein the guide is movable up and down and can be lifted to peel the circular covering member from the resin material, and also serves as the circular covering member peeling device.
請求項8乃至11のいずれかにおいて、
前記円形被覆部材移載装置は、前記円形被覆部材を保持して上昇することにより該円形被覆部材を前記樹脂材料から剥離可能であり、前記円形被覆部材剥離装置を兼ねることを特徴とする光記録媒体の製造装置。
In any of claims 8 to 11,
The circular covering member transfer device is capable of peeling the circular covering member from the resin material by holding and lifting the circular covering member, and also serves as the circular covering member peeling device. Medium production equipment.
請求項8乃至12のいずれかにおいて、
前記樹脂材料における前記円形被覆部材の外周に相当する段部を厚さ方向に加圧するための段部加圧装置が備えられたことを特徴とする光記録媒体の製造装置。
In any one of Claims 8 thru | or 12.
An apparatus for manufacturing an optical recording medium, comprising: a step pressurizing device for pressing in a thickness direction a step corresponding to the outer periphery of the circular covering member in the resin material.
請求項8乃至12のいずれかにおいて、
前記樹脂材料における前記円形被覆部材の外周に相当する段部を除去するための段部除去装置が備えられたことを特徴とする光記録媒体の製造装置。
In any one of Claims 8 thru | or 12.
An apparatus for producing an optical recording medium, comprising: a step removing device for removing a step corresponding to the outer periphery of the circular covering member in the resin material.
JP2005258338A 2005-09-06 2005-09-06 Method and device for manufacturing optical recording medium Pending JP2007073124A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09245384A (en) * 1996-03-07 1997-09-19 Kitano Eng Kk Treatment of flash of memory disk and device therefor
JP2004134050A (en) * 2002-08-14 2004-04-30 Fuji Photo Film Co Ltd Method for forming cover layer of optical disk

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09245384A (en) * 1996-03-07 1997-09-19 Kitano Eng Kk Treatment of flash of memory disk and device therefor
JP2004134050A (en) * 2002-08-14 2004-04-30 Fuji Photo Film Co Ltd Method for forming cover layer of optical disk

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