JP2006505688A - 金属射出成形材料及び金属射出成形方法 - Google Patents
金属射出成形材料及び金属射出成形方法 Download PDFInfo
- Publication number
- JP2006505688A JP2006505688A JP2004547537A JP2004547537A JP2006505688A JP 2006505688 A JP2006505688 A JP 2006505688A JP 2004547537 A JP2004547537 A JP 2004547537A JP 2004547537 A JP2004547537 A JP 2004547537A JP 2006505688 A JP2006505688 A JP 2006505688A
- Authority
- JP
- Japan
- Prior art keywords
- injection molding
- powder
- metal
- iron
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000001746 injection moulding Methods 0.000 title claims abstract description 70
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 68
- 239000002184 metal Substances 0.000 title claims abstract description 68
- 239000012778 molding material Substances 0.000 title claims abstract description 38
- 239000000843 powder Substances 0.000 claims abstract description 91
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 80
- 239000011230 binding agent Substances 0.000 claims abstract description 44
- 229910052742 iron Inorganic materials 0.000 claims abstract description 40
- 239000002245 particle Substances 0.000 claims abstract description 15
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 15
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 15
- 239000002270 dispersing agent Substances 0.000 claims abstract description 8
- 238000005245 sintering Methods 0.000 claims description 33
- 239000000203 mixture Substances 0.000 claims description 21
- -1 polyoxymethylene Polymers 0.000 claims description 7
- 229930040373 Paraformaldehyde Natural products 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- 229920006324 polyoxymethylene Polymers 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims 2
- 239000012752 auxiliary agent Substances 0.000 claims 1
- 239000007924 injection Substances 0.000 abstract description 4
- 238000002347 injection Methods 0.000 abstract description 4
- 229910000831 Steel Inorganic materials 0.000 description 14
- 239000010959 steel Substances 0.000 description 14
- 238000004663 powder metallurgy Methods 0.000 description 13
- 238000010438 heat treatment Methods 0.000 description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 11
- 238000000034 method Methods 0.000 description 11
- 229910045601 alloy Inorganic materials 0.000 description 10
- 239000000956 alloy Substances 0.000 description 10
- 229910052799 carbon Inorganic materials 0.000 description 10
- 238000000465 moulding Methods 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 238000001816 cooling Methods 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 238000003825 pressing Methods 0.000 description 6
- 238000011282 treatment Methods 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 229910000851 Alloy steel Inorganic materials 0.000 description 4
- 239000012298 atmosphere Substances 0.000 description 4
- 239000002923 metal particle Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 229910001111 Fine metal Inorganic materials 0.000 description 3
- 229910002065 alloy metal Inorganic materials 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 229920012196 Polyoxymethylene Copolymer Polymers 0.000 description 2
- 229920009382 Polyoxymethylene Homopolymer Polymers 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000005256 carbonitriding Methods 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 150000002505 iron Chemical class 0.000 description 2
- 229940087654 iron carbonyl Drugs 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 238000005121 nitriding Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000000197 pyrolysis Methods 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000012815 thermoplastic material Substances 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910018106 Ni—C Inorganic materials 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 238000003421 catalytic decomposition reaction Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000009770 conventional sintering Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 238000003921 particle size analysis Methods 0.000 description 1
- 229910001562 pearlite Inorganic materials 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/22—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces for producing castings from a slip
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/22—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces for producing castings from a slip
- B22F3/225—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces for producing castings from a slip by injection molding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/10—Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Powder Metallurgy (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10250526 | 2002-10-29 | ||
| PCT/EP2003/011624 WO2004039522A1 (de) | 2002-10-29 | 2003-10-21 | Metallpulverspritzgussmasse und verfahren zum metallpulverspritzguss |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2006505688A true JP2006505688A (ja) | 2006-02-16 |
Family
ID=32185285
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004547537A Withdrawn JP2006505688A (ja) | 2002-10-29 | 2003-10-21 | 金属射出成形材料及び金属射出成形方法 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20060099103A1 (de) |
| EP (1) | EP1558417A1 (de) |
| JP (1) | JP2006505688A (de) |
| KR (1) | KR20050059280A (de) |
| CN (1) | CN1708372A (de) |
| AU (1) | AU2003278115A1 (de) |
| CA (1) | CA2503834A1 (de) |
| MX (1) | MXPA05003960A (de) |
| RU (1) | RU2005116300A (de) |
| WO (1) | WO2004039522A1 (de) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014503061A (ja) * | 2010-10-07 | 2014-02-06 | プランゼー エスエー | X線、ガンマ線又は粒子線のためのコリメータ |
| WO2017175471A1 (ja) | 2016-04-05 | 2017-10-12 | 三菱重工航空エンジン株式会社 | 焼結体及び焼結体の製造方法、並びに燃焼器パネル及び燃焼器パネルの製造方法 |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102005031669A1 (de) * | 2005-07-05 | 2007-01-18 | Basf Ag | Polyoxymethylene mit Eisenpulver |
| KR100707855B1 (ko) * | 2005-07-05 | 2007-04-17 | 주식회사 엔씨메탈 | 분말사출성형용 금속 미세입자 피드스톡의 제조방법 |
| CN100434473C (zh) * | 2006-02-27 | 2008-11-19 | 南京工业大学 | 一种纳米真空修复剂及其制备和应用 |
| JP4420003B2 (ja) * | 2006-09-22 | 2010-02-24 | セイコーエプソン株式会社 | 成形体形成用組成物 |
| KR20080027171A (ko) * | 2006-09-22 | 2008-03-26 | 세이코 엡슨 가부시키가이샤 | 소결체의 제조방법 및 소결체 |
| JP4483880B2 (ja) * | 2007-03-15 | 2010-06-16 | セイコーエプソン株式会社 | 成形体形成用組成物、脱脂体および焼結体 |
| US20100007169A1 (en) * | 2008-07-11 | 2010-01-14 | Trinh Anh Hieu Nguyen | Vehicle protection assembly |
| DE102008059191A1 (de) * | 2008-11-27 | 2010-06-02 | Schaeffler Kg | Spanneinheit für eine Zugmittelspannvorrichtung |
| BRPI0805606A2 (pt) * | 2008-12-15 | 2010-09-14 | Whirlpool S.A | composição de materiais particulados para formação de produtos autolubrificantes em aço sinterizado, produto em aço sinterizado autolubrificante e processo de obtenção de produtos autolubrificantes em aço sinterizado |
| US20100178194A1 (en) * | 2009-01-12 | 2010-07-15 | Accellent, Inc. | Powder extrusion of shaped sections |
| CN102387882A (zh) * | 2009-04-09 | 2012-03-21 | 巴斯夫欧洲公司 | 生产废气汽轮增压器用汽轮的方法 |
| US9162927B2 (en) * | 2011-03-16 | 2015-10-20 | Basf Se | Process for producing metallic or ceramic shaped bodies |
| WO2013035059A1 (de) * | 2011-09-07 | 2013-03-14 | Basf Se | Bindemittel und verfahren zur herstellung von metallischen oder keramischen formkörpern im pulverspritzguss |
| TWI572842B (zh) * | 2012-03-16 | 2017-03-01 | 鴻準精密工業股份有限公司 | 熱管製造方法及熱管 |
| EP2925473B1 (de) * | 2012-11-30 | 2018-02-21 | NV Bekaert SA | Hülse für eine sägeleiste, die durch metallspritzguss erhalten wird |
| CN103042219A (zh) * | 2012-12-27 | 2013-04-17 | 华侨大学 | 一种钛金属眼镜框的成型方法 |
| HRP20240523T1 (hr) * | 2014-06-02 | 2024-07-05 | Basf Se | Postupak za proizvodnju sinteriranih kalupa |
| CN103981436B (zh) * | 2014-06-06 | 2015-11-04 | 海安县鹰球粉末冶金有限公司 | 金属粉末注射成形高强度马氏体时效钢的制造方法 |
| DE102018121902A1 (de) * | 2018-09-07 | 2020-03-12 | Isabellenhütte Heusler Gmbh & Co. Kg | Herstellungsverfahren für ein elektrisches Widerstandselement und entsprechendes Widerstandselement |
| CN109986075A (zh) * | 2019-04-02 | 2019-07-09 | 合肥核舟电子科技有限公司 | 一种金属粉末注射成型磁性喂料及其制备方法 |
| KR102405771B1 (ko) | 2021-06-10 | 2022-06-07 | 한국피아이엠(주) | 휴대폰금속테두리 기초제품 및 그 제조 방법 |
| KR102392104B1 (ko) | 2021-06-10 | 2022-04-29 | 한국피아이엠(주) | 휴대폰금속테두리 기초제품 및 그 제조 방법 |
| KR102834117B1 (ko) | 2022-04-25 | 2025-07-15 | 한국피아이엠(주) | 금속테두리 기초제품의 제조를 위한 금속분말 사출성형품 및 그 제조 방법 |
| KR102810968B1 (ko) | 2022-04-25 | 2025-05-22 | 한국피아이엠(주) | 금속테두리 기초제품의 제조를 위한 금속분말 사출성형품 시스템 및 이를 이용한 금속테두리 기초제품 제조 방법 |
| KR102834118B1 (ko) | 2022-04-25 | 2025-07-15 | 한국피아이엠(주) | 금속테두리 기초제품의 제조를 위한 금속분말 사출성형품 시스템 및 이를 이용한 금속테두리 기초제품 제조 방법 |
| CN114378293B (zh) * | 2021-09-15 | 2024-05-24 | 东莞市环力智能科技有限公司 | 一种奥氏体不锈钢搅拌头的烧结工艺及不锈钢搅拌头 |
| CN115338405B (zh) * | 2022-08-31 | 2024-06-04 | 中南大学 | 一种微注射成形铁基小模数齿轮的制备方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4007345A1 (de) * | 1990-03-08 | 1991-09-12 | Basf Ag | Thermoplastische massen fuer die herstellung metallischer formkoerper |
| DE4021739A1 (de) * | 1990-07-07 | 1992-01-09 | Basf Ag | Thermoplastische massen fuer die herstellung metallischer formkoerper |
| DE4225619A1 (de) * | 1992-08-03 | 1994-02-10 | Basf Ag | Alkoxylierungsprodukte |
| DE4314694C1 (de) * | 1993-05-04 | 1994-05-11 | Basf Ag | Verfahren zur Herstellung von Sinterformteilen |
| DE4435904A1 (de) * | 1994-10-07 | 1996-04-11 | Basf Ag | Verfahren und Spritzgußmasse für die Herstellung metallischer Formkörper |
| JP2955754B1 (ja) * | 1998-06-01 | 1999-10-04 | 有限会社モールドリサーチ | 金属粉末の射出成形用組成物と、その組成物を用いた射出成形及び焼結法 |
| DE10019447A1 (de) * | 2000-04-19 | 2001-10-25 | Basf Ag | Bindemittel für anorganische Materialpulver zur Herstellung metallischer und keramischer Formkörper |
-
2003
- 2003-10-21 WO PCT/EP2003/011624 patent/WO2004039522A1/de not_active Ceased
- 2003-10-21 AU AU2003278115A patent/AU2003278115A1/en not_active Abandoned
- 2003-10-21 CN CNA2003801024499A patent/CN1708372A/zh active Pending
- 2003-10-21 CA CA002503834A patent/CA2503834A1/en not_active Abandoned
- 2003-10-21 KR KR1020057006819A patent/KR20050059280A/ko not_active Withdrawn
- 2003-10-21 JP JP2004547537A patent/JP2006505688A/ja not_active Withdrawn
- 2003-10-21 MX MXPA05003960A patent/MXPA05003960A/es unknown
- 2003-10-21 RU RU2005116300/02A patent/RU2005116300A/ru not_active Application Discontinuation
- 2003-10-21 EP EP03769426A patent/EP1558417A1/de not_active Ceased
- 2003-10-21 US US10/533,315 patent/US20060099103A1/en not_active Abandoned
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014503061A (ja) * | 2010-10-07 | 2014-02-06 | プランゼー エスエー | X線、ガンマ線又は粒子線のためのコリメータ |
| US9721693B2 (en) | 2010-10-07 | 2017-08-01 | Plansee Se | Collimator for x-ray, gamma, or particle radiation |
| WO2017175471A1 (ja) | 2016-04-05 | 2017-10-12 | 三菱重工航空エンジン株式会社 | 焼結体及び焼結体の製造方法、並びに燃焼器パネル及び燃焼器パネルの製造方法 |
| US11511339B2 (en) | 2016-04-05 | 2022-11-29 | Mitsubishi Heavy Industries Aero Engines, Ltd. | Sintered body, method of manufacturing sintered body, combustor panel, and method of manufacturing combustor panel |
| US11666967B2 (en) | 2016-04-05 | 2023-06-06 | Mitsubishi Heavy Industries Aero Engines, Ltd. | Sintered body, method of manufacturing sintered body, combustor panel, and method of manufacturing combustor panel |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20050059280A (ko) | 2005-06-17 |
| US20060099103A1 (en) | 2006-05-11 |
| RU2005116300A (ru) | 2006-02-10 |
| WO2004039522A1 (de) | 2004-05-13 |
| AU2003278115A1 (en) | 2004-05-25 |
| MXPA05003960A (es) | 2005-06-22 |
| CN1708372A (zh) | 2005-12-14 |
| EP1558417A1 (de) | 2005-08-03 |
| CA2503834A1 (en) | 2004-05-13 |
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