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JP2006288270A - Method for packaging 'ampo' persimmon - Google Patents

Method for packaging 'ampo' persimmon Download PDF

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JP2006288270A
JP2006288270A JP2005113046A JP2005113046A JP2006288270A JP 2006288270 A JP2006288270 A JP 2006288270A JP 2005113046 A JP2005113046 A JP 2005113046A JP 2005113046 A JP2005113046 A JP 2005113046A JP 2006288270 A JP2006288270 A JP 2006288270A
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persimmons
packaging
oxygen
bag
ampo
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Takamasa Tachibana
孝全 立花
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Tachibana Paper Wear KK
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for packaging 'Ampo' persimmons (a kind of dried persimmons) by which fully ripened, sterilized and wrapped 'Ampo' persimmons get free from fear of browning during storage so as to keep the taste of the 'Ampo' persimmons favorable. <P>SOLUTION: The method for packaging 'Ampo' persimmons comprises the following process: naturally afterripening fresh persimmons, peeling the persimmons, putting the peeled persimmons in lines and hanging them on a drying shelf followed by drying/rapening them, housing the 'Ampo' persimmons 11 and a first organic deoxydizer 12 in a low oxygen-permeable packaging small bag 10 and sealing the bag; housing the packaging small bag 10 in a low oxygen-permeable packaging large bag 14 together with a second organic deoxidizer 15 and sealing the bag so as to be doubly packaged. An amount of oxygen inhalation of the deoxidizer 15 encapsulated in the large bag 14 is twice that of the deoxidizer 12 encapsulated in the small bag 10. Such a packaging process enables long storage of the 'Ampo' persimmons for 1 year or more in a condition where the freshness and also the taste of the 'Ampo' persimmons are kept favorable. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、充分熟成されたあんぽ柿の包装方法に関する。   The present invention relates to a packaging method for well-ripened red bean paste.

干し柿は、生柿の皮をむき、漂白、殺菌、殺虫の目的で15〜30分イオウ蒸を行って天日乾燥をするか、40℃前後、湿度60〜70%で徐々に火力乾燥し、途中で温度を下げて水分の均一化をはかり、再び乾燥を続け約1週間で乾燥を終了する。火力乾燥の代わりに、イオウ燻蒸ののち遠赤外線照射して加工日数を早めることが行われている。いずれの場合も製品1Kgあたり亜硫酸としての残留量が0.03g以下に抑えることが必要とされている。イオウ燻蒸すると、イオウ煙霧の排出や漏れ出しに伴う臭気と酸性空気により環境を汚染することが多い。また、無公害、無農薬の食品の摂取が健康保持の上で有効であることが、消費者の間でとみに関心が高まってきている中で、亜硫酸としての残留量が無視できない製品の加工方法を改善することが望まれている。
一方、干し柿の日持ちをよくするため、真空包装、チッソガス充填包装が僅かながら行われてきた。しかし、干し柿の単価が安い割りに、大掛かりの設備をしなければならず、その費用も大きかった。また、干し柿の鮮度保持のため、鉄系脱酸素剤とエタノール製剤、乾燥剤が多用されるようになった。
Dried persimmon is, peeled raw persimmon skin, bleaching, sterilization, or the sun drying is performed 15 to 30 minutes sulfur smoke steam for the purpose of insecticides, around 40 ℃, then gradually flame-dried at 60-70% humidity Then, the temperature is lowered in the middle to make the water uniform, and the drying is continued again in about one week. Instead of thermal drying, sulfur fumigation is followed by far-infrared irradiation to shorten the processing days. In any case, it is necessary to suppress the residual amount as sulfurous acid to 0.03 g or less per 1 kg of the product. Sulfur fumigation often pollutes the environment with odors and acid air associated with the emission and leakage of sulfur fumes. In addition, there is a growing interest among consumers that the consumption of pollution-free and pesticide-free foods is effective in maintaining health. It is desired to improve.
On the other hand, in order to improve the shelf life of dried persimmons, vacuum packaging and nitrogen gas filling packaging have been carried out slightly. However, despite the low unit price of dried persimmons, large-scale facilities had to be installed, and the cost was high. In addition, iron-based oxygen scavengers, ethanol preparations, and desiccants have been frequently used to maintain the freshness of dried persimmons.

脱酸素剤は、主として化学反応によって包装袋内の酸素を除去し、食品の品質保持に用いるもので、鉄粉、アスコルビン酸、活性炭などを紙またはプラスチックをベースとした通気性の良い小袋に充填したものが一般的である。脱酸素剤は、鉄又は鉄化合物の酸化反応を利用した鉄系(無機系)と、アスコルビン酸のようなレダクトン類の酸化反応や活性炭の吸着能を利用した有機系のものとがある。無機系の脱酸素剤は安全で取扱いが容易で、安価であるが、有機系のものは金属探知機にかからないという特徴がある。
また、脱酸素剤は、酸素との反応に必要な水分が予め含まれていて酸素に触れると同時に酸素を吸収し始めるタイプの自力反応型と、空気にさらすと同時に酸素の吸収をはじめる乾燥した大気下では酸素を吸収せず、高湿度の空気に触れて後、酸素を吸収するタイプの水分依存型に分類されている。鉄系脱酸素剤は、脱酸素剤の酸素吸収能と包装材料のガスバリヤー性が適切であれば、0.1%以下の低酸素濃度の雰囲気を維持することが可能であり、真空包装やガス置換包装に要求されるハイバリヤー性の包装材料を必要とされない。
脱酸素剤のメーカーも多く、主としてエージレス(三菱ガス化学(株)の登録商標)と凸版印刷(株)の鮮度保持剤等が多用されている。エージレスは、包装形態としとて水分依存型と自力反応型があるが、干し柿の鮮度保持は、劣化防止、カビ防止、変色防止などが主目的であるため、干し柿一個包装の場合は水分依存型(例えばエージレスFタイプ、凸版FTタイプ)を使用し、干し柿をひとつのトレーに数個入れて包装する場合は自力反応型(例:エージレスZタイプ、凸版Cタイプ)を使用する。
Oxygen scavengers are mainly used to remove oxygen in packaging bags by chemical reaction and maintain the quality of foods. Filling air-permeable bags with iron powder, ascorbic acid, activated carbon, etc. based on paper or plastic. It is common. As the oxygen scavenger, there are an iron type (inorganic type) using an oxidation reaction of iron or an iron compound and an organic type using an oxidation reaction of reductones such as ascorbic acid and an adsorption ability of activated carbon. Inorganic oxygen scavengers are safe, easy to handle, and inexpensive, but organic ones are not affected by metal detectors.
In addition, the oxygen scavenger contains the moisture necessary for the reaction with oxygen in advance and is a self-reactive type that begins to absorb oxygen as soon as it comes into contact with oxygen, and a dry that begins to absorb oxygen upon exposure to air. It is classified as a moisture-dependent type that does not absorb oxygen in the atmosphere and absorbs oxygen after contact with high-humidity air. An iron-based oxygen absorber can maintain an atmosphere having a low oxygen concentration of 0.1% or less if the oxygen absorbing capacity of the oxygen absorber and the gas barrier property of the packaging material are appropriate. There is no need for high barrier packaging materials required for gas replacement packaging.
There are many manufacturers of oxygen scavengers, and AGELESS (registered trademark of Mitsubishi Gas Chemical Co., Ltd.) and Toppan Printing Co., Ltd. freshness-keeping agents are mainly used. AGELESS has a moisture-dependent type and a self-reactive type as a packaging form, but the main purpose of keeping freshness of dried persimmon is to prevent deterioration, mold prevention, discoloration, etc. When using (for example, Ageless F type, letterpress FT type) and packaging several raisins in one tray, use a self-reactive type (eg, Ageless Z type, Letterpress C type).

問題点:ごく最近食品の安全確保の点から干し柿も、従来より厳しい条件が要求されるようになってきた。
1.従来の脱酸素剤は内容が鉄が主成分であるため、金属探知機に感知される。そのため、干し柿の中に金属片(針、カッター刃)が残留しているのではないかとの疑念がもたれ、出荷上不都合であった。
2.鉄が主成分である脱酸素剤の中にはマンガン等の成分も含まれている。干し柿(あんぽ柿)は水分が40〜50%と多いため、暖かい室内などでは包装袋の中で醗酵してエチレン等の有害ガスを発生する。マンガンとエチレンガスが反応すると発ガン物質を発生する、といわれている。この疑いにより、鉄系の脱酸素剤は使用すべきではない。
3.水分反応型の鉄系脱酸素剤では、脱酸素日数が25℃室内で0.5〜1日であれば鮮度保持には好都合であるが、自力反応型の有機物が主成分である脱酸素剤では同一条件下で、脱酸素日数が3〜4日も要するので、鮮度保持上好ましくない。
Problem: Very recently, harsh conditions have been demanded for dried straw from the viewpoint of ensuring food safety.
1. Since conventional oxygen scavengers are mainly composed of iron, they are detected by metal detectors. For this reason, there was a suspicion that metal pieces (needle, cutter blade) remained in the drying basket, which was inconvenient in shipment.
2. In the oxygen scavenger whose main component is iron, components such as manganese are also included. Dried persimmons (anpo persimmons) have a high moisture content of 40 to 50%, so they are fermented in packaging bags and generate harmful gases such as ethylene in warm rooms. It is said that carcinogens are generated when manganese and ethylene gas react. Because of this suspicion, iron-based oxygen scavengers should not be used.
3. The moisture-reactive iron-based oxygen scavenger is convenient for maintaining freshness if the oxygen scavenging period is 0.5 to 1 day in a room at 25 ° C., but the oxygen scavenger is mainly composed of a self-reactive organic substance. Then, since it takes 3 to 4 days for deoxygenation under the same conditions, it is not preferable for maintaining freshness.

干し柿のうち、特に水分の多いあんぽ柿(40〜50%)を脱酸素剤を使用して1年以上長期保存するのは不可能であった。第1には色が変退色し、第2には炭酸ガスとエチレンガスが発生し、第3には食味が悪くなることである。あんぽ柿を入れた袋の中に酸素吸入量を超える脱酸素剤を入れれば、早急にあんぽ柿の果肉が老化して弾力性のないものとなり、色も褐変し生気のないあんぽ柿になってしまう。   It was impossible to store anchovy (40-50%) with a particularly high moisture content for a year or more using a deoxidizer. The first is that the color changes, the second is that carbon dioxide and ethylene gas are generated, and the third is that the taste is poor. If you put an oxygen scavenger that exceeds the oxygen inhalation amount in the bag containing the anpo porridge, the flesh of the anpo porridge will quickly become unresilient, the color will also turn brown, and there will be no vitality Become.

あんぽ柿を春から夏にかけて販売することが流通業者、販売業者の望みである。しかし、4月に入ると、冷蔵庫に入れておいても、酸素が低酸素透過性袋の中に入り込むため、あんぽ柿は発酵して変退色、ガス発生、食味不良となる。冷凍したあんぽ柿を解凍して食べる時、果肉がベタつき、食味しにくい。
本発明は、十分熟成されたあんぽ柿を食味の劣化なしに長期保存できる包装方法を提供することを目的とする。
Distributors and distributors are hoping to sell anpochi from spring to summer. However, in April, even if put in the refrigerator, oxygen enters the low-oxygen permeable bag, so that the anpochi ferments and becomes discolored, generates gas, and tastes bad. When thawing frozen anpo rice cake, the flesh is sticky and difficult to eat.
An object of this invention is to provide the packaging method which can preserve | save the fully-ripened red bean paste for a long term, without deterioration of a taste.

上記目的を達成するため、本発明の請求項1は、水分含有率40〜50%のあんぽ柿と脱酸素剤とを低酸素透過性の包装袋または包装容器に収納し密封して長期保存に適するようにしたことを特徴とするあんぽ柿の包装方法である。請求項2は、水分含有率40〜50%のあんぽ柿と第1の脱酸素剤とを小形の低酸素透過性の包装袋に収納して密封し、さらに前記密封包装袋と第2の脱酸素剤とを前記小形の低酸素透過性包装袋より大形の包装袋または包装容器に収納し密封して長期保存に適するようにしたことを特徴とする。
請求項3は、低酸素透過性包装袋のうち、大形袋の脱酸素剤の酸素吸入量は、小形袋のそれの2倍以上の容量であることを特徴とする。
In order to achieve the above object, claim 1 of the present invention is to store an anchovy cake having a water content of 40 to 50% and an oxygen scavenger in a low oxygen permeable packaging bag or container and sealed for a long period of time. It is a packaging method of anpo rice cake characterized by being adapted to. According to a second aspect of the present invention, an anchovy cake having a moisture content of 40 to 50% and the first oxygen scavenger are housed and sealed in a small low oxygen permeable packaging bag, and the sealed packaging bag and the second oxygen scavenger are sealed. The oxygen scavenger is accommodated in a larger packaging bag or packaging container than the small low oxygen permeable packaging bag and sealed to be suitable for long-term storage.
The third aspect of the present invention is characterized in that, among the low oxygen permeable packaging bags, the oxygen suction amount of the oxygen scavenger of the large bag is more than twice that of the small bag.

上記のように、本発明は、乾燥あんぽ柿と脱酸素剤とを低酸素透過性の包装小袋に収容して密封したので、変退色するおそれなく、長期保存することができる。   As described above, the present invention can be stored for a long period of time without fear of discoloration because the dried bean paste and the oxygen scavenger are housed and sealed in a low oxygen permeable packaging pouch.

図1は水分含有率40〜50%のあんぽ柿11と脱酸素剤12とを低酸素透過性の包装袋10に収納し熱シール部13で密封した状態を示す。この場合に、包装袋10の代わりに低酸素透過性の包装容器(図示省略)に収容して密封してもよい。
図2は、同前あんぽ柿11と第1の脱酸素剤12とを小形の低酸素透過性の包装袋10に収納し熱シール部13で密封し、さらに密封すみの包装袋10と第2の脱酸素剤15とを小形の低酸素透過性包装袋10より大形の包装袋14または包装容器に収納し熱シール部16で密封した場合を示す。低酸素透過性包装袋のうち、大形の包装袋14の脱酸素剤の酸素吸入量は、小形袋10のそれの2倍以上の容量であることが好ましい。
FIG. 1 shows a state in which an anchovy 11 having a moisture content of 40 to 50% and an oxygen scavenger 12 are housed in a low oxygen permeable packaging bag 10 and sealed by a heat seal part 13. In this case, instead of the packaging bag 10, it may be housed and sealed in a low oxygen permeable packaging container (not shown).
FIG. 2 shows that the anpox 11 and the first oxygen scavenger 12 are housed in a small, low oxygen permeable packaging bag 10 and sealed with a heat-sealing portion 13, and further the sealed packaging bag 10 and 2 shows a case where two oxygen scavengers 15 are accommodated in a larger packaging bag 14 or a packaging container than the small low-oxygen permeable packaging bag 10 and sealed with a heat seal portion 16. Of the low oxygen permeable packaging bags, the oxygen absorbing amount of the oxygen absorber in the large packaging bag 14 is preferably at least twice that of the small bag 10.

低酸素透過性包装袋に脱酸素剤を封入したり、包装袋内の空気を抽気にしたりする場合に、微量の酸素が袋内に侵入するため、袋内の酸素濃度は徐々に高くなる。袋中のあんぽ柿は発酵をはじめるから変退色現象が起き、ガスも発生する。その結果として、あんぽ柿の食味は次第に悪くなる。この問題を解決する方法は、包装袋内に酸素が入り込まないようにすることである。低酸素透過性包装袋を二重にし、内袋となる小形袋にも、外袋となる大形袋にも各々立つ酸素剤を収納し密封する。大形袋の脱酸素剤は、小形袋のそれよりも2倍以上の酸素吸入量であることが望ましい。また、保存温度は1℃〜5℃の間に設定する。大形袋内は長期にわたって無酸素状態であり、小形袋に脱酸素剤と共に収納されているあんぽ柿も無酸素状態の中にいる。このように、二重の無酸素状態の袋に収納されているあんぽ柿は変退色もなく、ガス発生もなく、食味も悪くならない。この状態は1℃〜5℃の暗所で1年以上も持続する。   When an oxygen scavenger is enclosed in a low oxygen permeable packaging bag or when air in the packaging bag is extracted, a small amount of oxygen enters the bag, so that the oxygen concentration in the bag gradually increases. The anpochi in the bag begins to ferment, causing discoloration and gas. As a result, the taste of the anpo rice cake becomes progressively worse. A method for solving this problem is to prevent oxygen from entering the packaging bag. Double the low oxygen permeable packaging bags and store and seal the oxygen agent standing in both the small bag as the inner bag and the large bag as the outer bag. It is desirable that the oxygen absorber of the large bag has an oxygen inhalation amount twice or more that of the small bag. The storage temperature is set between 1 ° C and 5 ° C. The inside of the large bag is in an oxygen-free state for a long time, and the anpochi stored in the small bag together with the oxygen scavenger is also in an oxygen-free state. As described above, the anpochi stored in the double oxygen-free bag has no discoloration, no gas generation, and no bad taste. This state persists for more than a year in the dark at 1 ° C to 5 ° C.

次に、低酸素透過性一重袋による包装と本発明の2重包装との比較試験を下記のように行い、その結果を表1に示す。   Next, a comparative test between the packaging using the low oxygen permeability single bag and the double packaging of the present invention was performed as follows, and the results are shown in Table 1.

〔比較試験〕
a.実施場所:タチバナペーパーウエアー株式会社福島事業所
b.実施期間:平成15年11月10日〜平成17年1月10日
c.原料干柿:蜂屋柿 1個約120g 乾燥率40%
d.脱酸素剤:日本曹達製セキュールSW−150(有機系)。
セキュールBP−500(鉄系)。
e.包装袋 :OPP(延伸ポリプロピレン)/エバール(ポバール系)/PE
20/17/40(各層厚みミクロン)
酸素透過度 0.3〜4cc/m/20〜25℃
f.冷蔵庫 :三洋電機製SRR−UV1881C2
容積 1,550リットル。温度設定範囲:冷蔵庫 −6℃〜12℃
g.食味表示:5段階
秀 :とても美味。
優 :美味だが果肉がボサボサする。
良 :がまんすれば食べられる。
可 :まずい。舌先にピリっと感じる。
不可:食べられない。腐敗臭がする。
h.資料干柿:一重袋25個。二重袋25個
(食味用各15個)
i.庫内温度:5℃
[Comparative test]
a. Location: Tachibana Paperware Co., Ltd. Fukushima Office b. Implementation period: November 10, 2003 to January 10, 2005 c. Raw material dried rice cake: bee rice cake about 120g 1 piece drying rate 40%
d. Oxygen scavenger: Secur SW-150 (organic) manufactured by Nippon Soda.
Secur BP-500 (iron-based).
e. Packaging bag: OPP (stretched polypropylene) / Eval (Poval) / PE
20/17/40 (thickness of each layer is micron)
Oxygen permeability 0.3~4cc / m 2 / 20~25 ℃
f. Refrigerator: Sanyo Electric SRR-UV1881C2
Volume 1,550 liters. Temperature setting range: refrigerator −6 ° C. to 12 ° C.
g. Taste display: 5 stages Hide: Very delicious.
Yu: Delicious but fluffy.
Ryo: You can eat if you do it.
OK: Bad. Feels tangled on the tip of the tongue.
Impossible: Cannot eat. It smells rotten.
h. Material drought: 25 single bags. 25 double bags
(15 for each taste)
i. Chamber temperature: 5 ℃

Figure 2006288270
Figure 2006288270

本発明による包装品の平面図。The top view of the packaged goods by this invention. 本発明による二重包装品の平面図。The top view of the double package by this invention.

符号の説明Explanation of symbols

10 低酸素透過性の包装小袋
11 あんぽ柿
12、15 脱酸素剤
13、16 熱シール部
14 低酸素透過性の包装大袋
10 Low oxygen permeable packaging sachet 11 Anpo porcelain 12, 15 Oxygen absorber 13, 16 Heat seal part 14 Low oxygen permeable packaging sachet

Claims (3)

水分含有率40〜50%のあんぽ柿と脱酸素剤とを低酸素透過性の包装袋または包装容器に収納し密封して長期保存に適するようにしたことを特徴とするあんぽ柿の包装方法。   Anpo-pocket packaging, characterized in that an anchovy with a moisture content of 40-50% and an oxygen scavenger are housed in a low-oxygen-permeable packaging bag or container and sealed to be suitable for long-term storage. Method. 水分含有率40〜50%のあんぽ柿と第1の脱酸素剤とを小形の低酸素透過性包装袋に収納して密封し、さらに前記密封包装袋と第2の脱酸素剤とを前記小形の低酸素透過性包装袋より大形の低酸素透過性包装袋または包装容器に収納し密封して長期保存に適するようにしたことを特徴とするあんぽ柿の包装方法。   An anchovy with a moisture content of 40 to 50% and the first oxygen scavenger are housed in a small low oxygen permeable packaging bag and sealed, and the sealed packaging bag and the second oxygen scavenger are further sealed. A method for packaging an anchovy, which is suitable for long-term storage by storing in a large low oxygen-permeable packaging bag or packaging container rather than a small low-oxygen-permeable packaging bag. 低酸素透過性包装袋のうち、大形袋の脱酸素剤の酸素吸入量は、小形袋のそれの2倍以上の容量であることを特徴とする請求項2に記載のあんぽ柿の包装方法。   3. The packaging of red bean paste according to claim 2, wherein the oxygen absorption amount of the oxygen scavenger in the large bag among the low oxygen permeable packaging bags is more than twice that of the small bag. Method.
JP2005113046A 2005-04-11 2005-04-11 Method for packaging 'ampo' persimmon Pending JP2006288270A (en)

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CN101543237B (en) * 2009-04-28 2011-09-14 陕西科技大学 Method for prolonging shelf life of dried persimmon
CN104192431A (en) * 2014-08-29 2014-12-10 成都大学 Natural oxygen consumption modified atmosphere packaging technology
CN109094858A (en) * 2017-06-21 2018-12-28 旭化成株式会社 Package body, save set and the store method of fruits and vegetables
TWI885946B (en) * 2024-06-13 2025-06-01 孕龍科技股份有限公司 Deoxygenation storage device

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JP2000037162A (en) * 1998-07-24 2000-02-08 Nippon Soda Co Ltd Storage of 'anpokaki'
JP2002335854A (en) * 2001-05-23 2002-11-26 Hoshizaki Electric Co Ltd Method for dried (anpo) persimmon preservation

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101543237B (en) * 2009-04-28 2011-09-14 陕西科技大学 Method for prolonging shelf life of dried persimmon
CN104192431A (en) * 2014-08-29 2014-12-10 成都大学 Natural oxygen consumption modified atmosphere packaging technology
CN104192431B (en) * 2014-08-29 2016-04-13 成都大学 A kind of natural oxygen consumption controlled atmospheric packing technology
CN109094858A (en) * 2017-06-21 2018-12-28 旭化成株式会社 Package body, save set and the store method of fruits and vegetables
KR20200034687A (en) * 2017-06-21 2020-03-31 아사히 가세이 가부시키가이샤 Packaging, preservation apparatus and preservation method for fruit and vegetable
CN109094858B (en) * 2017-06-21 2021-08-27 旭化成株式会社 Fruit and vegetable package, storage device and storage method
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TWI885946B (en) * 2024-06-13 2025-06-01 孕龍科技股份有限公司 Deoxygenation storage device

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