[go: up one dir, main page]

JP2006110982A - Foam molded sound absorber and method for producing the same - Google Patents

Foam molded sound absorber and method for producing the same Download PDF

Info

Publication number
JP2006110982A
JP2006110982A JP2005037960A JP2005037960A JP2006110982A JP 2006110982 A JP2006110982 A JP 2006110982A JP 2005037960 A JP2005037960 A JP 2005037960A JP 2005037960 A JP2005037960 A JP 2005037960A JP 2006110982 A JP2006110982 A JP 2006110982A
Authority
JP
Japan
Prior art keywords
foam
sound absorber
molded
molded sound
heating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2005037960A
Other languages
Japanese (ja)
Inventor
Akemasa Shimazaki
明正 島崎
Shigeki Yoshimura
茂樹 吉村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Daisen Industry Co Ltd
Original Assignee
Daisen Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Daisen Industry Co Ltd filed Critical Daisen Industry Co Ltd
Priority to JP2005037960A priority Critical patent/JP2006110982A/en
Publication of JP2006110982A publication Critical patent/JP2006110982A/en
Pending legal-status Critical Current

Links

Images

Landscapes

  • Soundproofing, Sound Blocking, And Sound Damping (AREA)
  • Building Environments (AREA)
  • Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

【課題】接着用樹脂を使用することなく、吸音体に好ましい細孔構造と構造強度の両立を図る。
【解決手段】本発明の発泡成形吸音体を構成する発泡成形体1は、所定の形状に構成された型内に充填した発泡性樹脂粒子を加熱発泡して得られる無数の発泡セル11、11、・・で構成される発泡成形体であって、隣接する発泡セル11、11、・・が接触面11a、11a、においてそれ自体が軟化溶融して結合している。この発泡成形体1は、少なくとも3個の発泡セル11に囲まれる空間12(図1では、5個の発泡セル11に囲まれる空間12が例示してある)が連なって形成される連通気孔からなる3次元細気孔を備え、この3次元細気孔は、全体の容積に対する細気孔の全容積比である容積気孔率が10〜40%であって、かつ少なくとも0.16MPaの引裂き強度を有する。
【選択図】 図1
[PROBLEMS] To achieve both a preferable pore structure and structural strength for a sound absorber without using an adhesive resin.
A foam molded body 1 constituting the foam molded sound absorbing body of the present invention has a myriad of foam cells 11 and 11 obtained by heating and foaming foamable resin particles filled in a mold having a predetermined shape. ,..., Wherein the adjacent foam cells 11, 11,... Are softened and melted together at the contact surfaces 11a, 11a. The foamed molded body 1 includes a continuous air hole formed by connecting a space 12 surrounded by at least three foamed cells 11 (in FIG. 1, a space 12 surrounded by five foamed cells 11 is illustrated). The three-dimensional fine pores have a volume porosity of 10 to 40%, which is the total volume ratio of the fine pores to the entire volume, and have a tear strength of at least 0.16 MPa.
[Selection] Figure 1

Description

本発明は、型内に充填した発泡性樹脂粒子を加熱発泡して得られる発泡成形吸音体およびその製造方法の改良に関する。   The present invention relates to a foam molded sound absorber obtained by heating and foaming expandable resin particles filled in a mold, and an improvement of a method for producing the same.

従来から発泡ポリスチレン樹脂や発泡ポリオレフィン樹脂は多孔質吸音材料として期待され、その開発が要望されていた。ところが、この種の発泡樹脂成形体は、用途が「魚箱」のような生鮮食品保管・搬送BOXに代表されるように断熱保冷性が重視された結果、実質的に無通気性の材料に仕上げられていて、吸音材料に適した細孔構造を持っていなかった。   Conventionally, expanded polystyrene resin and expanded polyolefin resin are expected as porous sound-absorbing materials, and their development has been demanded. However, this type of foamed resin molded product has become a substantially non-breathable material as a result of the emphasis on heat insulation and cold preservation, as represented by the fresh food storage and transport BOX such as “fish box”. It was finished and did not have a pore structure suitable for sound-absorbing materials.

そこで、発泡樹脂成形体の適当な細孔構造を付与する研究が行なわれたが、好ましい細孔気孔率を実現するには、加熱温度条件を下げる必要があり、その結果、発泡セルの結合強度が低下し、成形体として実用的な構造強度が得られず、実用化に成功していなかった。このような点を改善するものとして、特許文献1にあるような「吸音体」が提案されている。   Therefore, research has been conducted to give an appropriate pore structure of the foamed resin molded body. However, in order to achieve a favorable pore porosity, it is necessary to lower the heating temperature condition, and as a result, the bond strength of the foamed cell As a result, the structural strength practical for the molded body could not be obtained, and the practical application was not successful. In order to improve such a point, a “sound absorber” as disclosed in Patent Document 1 has been proposed.

特許第3268094号公報(特開平7−168577号公報):特許請求に範囲、段落〔0017〕〔0018〕など。Japanese Patent No. 3268094 (Japanese Patent Laid-Open No. 7-168577): claims, paragraphs [0017] [0018] and the like.

この特許文献1の吸音体では、原料である発泡性樹脂粒子の表面にその粒子の軟化発泡温度よりも低い温度で熱接着しうる接着用樹脂を付着しておき、成形時に、発泡量を調節して細孔構造を残してながら、この接着用樹脂でもって発泡セル同士を接着接合するものであって、従来実現できなかった、吸音体に好ましい細孔構造と構造強度の両立を意図したものである。   In the sound absorber of Patent Document 1, an adhesive resin that can be thermally bonded at a temperature lower than the softening foaming temperature of the particles is attached to the surface of the foamable resin particles that are raw materials, and the amount of foaming is adjusted during molding. The foamed cells are bonded and bonded together with this adhesive resin while leaving the pore structure, and this is intended to achieve both the preferred pore structure and structural strength for sound absorbers that could not be realized in the past. It is.

ところが、この吸音体は、接着用樹脂を用いることから以下のような解決課題があって、実用上の問題となった。
1)接着用樹脂が付加されるため、材料費や加工費がコストアップとなる。
2)接着用樹脂のため発泡性樹脂粒子の流動性が低下し、充填装置が目詰まりしたり、型内の充填度に不均一になりやすいなど操作性に劣る。
3)接着用樹脂の低温軟化特性が原因となり吸音材の耐熱性や長期耐久性が大幅に低下する。
However, since this sound absorber uses an adhesive resin, it has the following problems to be solved and has become a practical problem.
1) Since an adhesive resin is added, material costs and processing costs are increased.
2) Due to the adhesive resin, the fluidity of the expandable resin particles decreases, the filling device is clogged, and the operability is inferior, for example, the degree of filling in the mold tends to be uneven.
3) Due to the low temperature softening properties of the adhesive resin, the heat resistance and long-term durability of the sound absorbing material are greatly reduced.

本発明は、上記の問題点を解決するためになされたものであり、接着用樹脂を使用することなく、吸音体に好ましい細孔構造と構造強度の両立を図るもので、接着用樹脂に起因するコストアップ、操作性あるいは耐熱性や長期耐久性の低下を防止できる発泡成形吸音体およびその製造方法を提供する。   The present invention has been made in order to solve the above-described problems, and is intended to achieve both a preferable pore structure and structural strength for a sound absorber without using an adhesive resin. The present invention provides a foam molded sound absorber that can prevent cost increase, operability, heat resistance, and long-term durability, and a method for producing the same.

本発明は、発泡性樹脂粒子を用いた発泡成形において、発泡性樹脂粒子を融着温度条件下で膨張量を制御することによって、粒子間に間隙を設けながら粒子相互が軟化融着して強固に結合するという本件発明者が見出した知見に基づくものである。   In the foam molding using foamable resin particles, the present invention controls the expansion amount of the foamable resin particles under the fusion temperature condition so that the particles soften and fuse with each other while providing a gap between the particles. This is based on the knowledge found by the present inventors that it binds to.

(発泡成形吸音体の発明)
上記の課題は、物の発明であるところの、型内に充填した発泡性樹脂粒子を加熱発泡して得られる無数の発泡セルで構成される発泡成形体であって、隣接する発泡セルが接触面においてそれ自体が軟化溶融して結合されるとともに、少なくとも3個の発泡セルに囲まれる空間が連なって形成される連通気孔からなり、容積気孔率が10〜40%である3次元細気孔を備え、かつ少なくとも0.16MPaの引裂き強度を有する発泡成形体からなることを特徴とする本発明の発泡成形吸音体によって、解決することができる。
(Invention of foam molded sound absorber)
The above-mentioned problem is a foamed molded article composed of an infinite number of foamed cells obtained by heating and foaming foamable resin particles filled in a mold, which is an invention of a product, and adjacent foamed cells are in contact with each other A three-dimensional fine pore having a volume porosity of 10 to 40%, which is composed of continuous air holes formed by being connected with a space surrounded by at least three foamed cells while being softened and melted on the surface. It can be solved by the foam molded sound absorbing body of the present invention, characterized in that it comprises a foam molded body having a tear strength of at least 0.16 MPa.

前記このような発泡成形体は、発泡性樹脂粒子の膨張量を融着温度条件下で制御することで実現できる。その詳細については、発泡成形吸音体の製造法として追って説明する。
また本発明は、前記発泡成形体の外表面の一部または全部に、より容積気孔率の少ない表層部を付加した形態に具体化でき、この場合、前記表層部が、当該発泡成形体の発泡成形時に一体に成形されたものであるのが好ましい。
Such a foamed molded product can be realized by controlling the expansion amount of the expandable resin particles under the fusion temperature condition. Details thereof will be described later as a method of manufacturing a foam molded sound absorber.
Further, the present invention can be embodied in a form in which a surface layer portion having a smaller volume porosity is added to a part or all of the outer surface of the foam molded body. In this case, the surface layer portion is foamed of the foam molded body. It is preferable that they are integrally molded at the time of molding.

さらに、本発明は、前記した発泡成形体の一部に、より強度の大なる増強発泡体を付加した形態に好ましく具体化できる。この場合、前記増強発泡体が、当該発泡成形体の発泡成形時に一体に成形されたものであるのが好ましい。   Furthermore, the present invention can be preferably embodied in a form in which an enhanced foam having higher strength is added to a part of the above-described foamed molded article. In this case, it is preferable that the reinforcing foam is integrally formed at the time of foam molding of the foam molded body.

また、本発明は、このような構成を有するとともに、前記表層部の厚さが発泡成形吸音体の全体の厚さの10〜45%であり、自動車用内装部材として用いられる発泡成形吸音体として具体化される。また、前記表層部を車室側に向けて設置し、この発泡成形吸音体によって車体フロア面の凹凸をフラットにする車両用フロアフラット材として用いられる発泡成形吸音体としても具体化される。この場合、前記表層部の厚さが5〜40mmであるのが好ましい。   Further, the present invention has such a configuration, and the thickness of the surface layer portion is 10 to 45% of the total thickness of the foam molded sound absorber, and the foam molded sound absorber used as an automobile interior member Embodied. Further, the present invention may be embodied as a foam molded sound absorber used as a vehicle floor flat material in which the surface layer portion is installed facing the vehicle compartment and the unevenness of the vehicle body floor surface is flattened by the foam molded sound absorber. In this case, the thickness of the surface layer portion is preferably 5 to 40 mm.

さらに、本発明は、同様に、前記表層部の厚さが発泡成形吸音体の全体の厚さの10〜45%であり、建築用吸音部材、道路・鉄道騒音防止部材、住宅用吸音部材または産業機器用吸音部材として用いられる発泡成形吸音体として具体化される。また、この場合、前記表層部の厚さが5〜40mmであるのが好ましい。   Further, in the present invention, similarly, the thickness of the surface layer portion is 10 to 45% of the total thickness of the foam molded sound absorbing body, and the sound absorbing member for building, the road / railway noise preventing member, the sound absorbing member for housing, It is embodied as a foam molded sound absorber used as a sound absorbing member for industrial equipment. In this case, the thickness of the surface layer part is preferably 5 to 40 mm.

(発泡成形吸音体の製造方法の発明)
さらに、上記の問題は、型内に充填した発泡性樹脂粒子を加熱発泡して得られる発泡成形体で構成される発泡成形吸音体の製造方法であって、発泡性樹脂粒子を加熱水蒸気の存在下で、その発泡性樹脂粒子の融着温度に加熱した後、発泡量を制御しながら発泡セルを融着させるとともに冷却して、前記した物の発明で規定した発泡成形体を得ることを特徴とする本発明の発泡成形吸音体に製造方法によって解決することができる。
(Invention of production method of foam molded sound absorber)
Furthermore, the above problem is a method for producing a foam molded sound absorber composed of a foam molded article obtained by heating and foaming foamable resin particles filled in a mold, wherein the foamable resin particles are present in the presence of heated steam. Under the above, after heating to the fusing temperature of the expandable resin particles, the foamed cell is fused and cooled while controlling the amount of foaming, to obtain a foamed molded article as defined in the invention of the above-mentioned product The foam molded sound absorber of the present invention can be solved by the production method.

本発明では、前記発泡量の制御を、発泡性樹脂粒子に対する圧力を制御することにより行なう形態に具体化できる。この場合、圧力制御を前記発泡性樹脂粒子の融着完了温度まで行なうのが好ましい。   In the present invention, the foaming amount can be controlled by controlling the pressure on the foamable resin particles. In this case, it is preferable to perform pressure control up to the fusion completion temperature of the expandable resin particles.

さらに、本発明は、前記融着温度に加熱した後、圧力制御しつつ冷却するに当たり、予め型内の加熱水蒸気を空気で置換する形態、または型内の加熱水蒸気を空気で置換しながら行なうのが好適である。   Further, in the present invention, after heating to the above-mentioned fusion temperature, when cooling while controlling the pressure, the heating steam in the mold is replaced with air in advance, or the heating steam in the mold is replaced with air. Is preferred.

本発明の発泡成形吸音体によれば、接着用樹脂を使用することなく、吸音体に好ましい10〜40%の容積気孔率を有する細孔構造と、取扱い、搬送に耐え、かつ構造体として実用的構造強度として、0.16MPaの引裂き強度を有する発泡成形体から構成されるので、接着用樹脂に起因するコストアップは抑制され、また発泡性樹脂粒子の有する本来の特性が活かすことができ、操作性あるいは耐熱性や長期耐久性の問題も解消できる利点が得られる。   According to the foam-molded sound absorber of the present invention, a pore structure having a volume porosity of 10 to 40% that is preferable for a sound absorber without using an adhesive resin, withstands handling and conveyance, and is practical as a structure. As a structural strength, it is composed of a foamed molded article having a tear strength of 0.16 MPa, so the cost increase caused by the adhesive resin can be suppressed, and the original properties of the expandable resin particles can be utilized. There is an advantage that problems of operability, heat resistance and long-term durability can be solved.

また、前記の発泡成形体の外表面に、より容積気孔率の少ない表層部を付加したものは、その表層部が保護層として機能する他、吸音体としては遮音層または反射層として機能して吸音効果を高める利点が得られる。さらに、発泡成形体の一部に、より構造強度の大なる増強発泡体を付加したものは、単なる吸音材としての役割に止まらず、強度を負担する構造部材を兼ねる用途にも適用できるという利点が得られるのである。   In addition, a surface layer portion having a lower volume porosity is added to the outer surface of the foamed molded body, the surface layer portion functions as a protective layer, and the sound absorber functions as a sound insulating layer or a reflective layer. The advantage of enhancing the sound absorption effect is obtained. Furthermore, the addition of an enhanced foam having a higher structural strength to a part of the foamed molded product is not limited to a simple sound absorbing material, and can be applied to applications that also serve as a structural member that bears strength. Is obtained.

また、本発明の発泡成形吸音体の製造方法によれば、発泡性樹脂粒子の発泡・融着工程に新規な操作を行なうことにより、接着用樹脂を使用することなく、前記した発泡成形吸音体を製造することができる。また、前記発泡量を発泡性樹脂粒子に対する圧力によって制御する場合は、発泡性樹脂粒子の発泡時の内圧と外圧とのバランスをとり発泡量を調節して、好ましい容積気孔率を実現できるので、従来の発泡樹脂原料資材をそのまま利用できる利点があり、その減圧速度を制御しつつ冷却するに当たり、型内の加熱水蒸気を空気で置換するようにすれば、加熱水蒸気の潜熱による温度条件の変動要因が排除できるから、発泡・融着工程条件が安定する利点が得られる。   Further, according to the method for producing a foam-molded sound absorber of the present invention, the above-described foam-molded sound-absorber can be used without using an adhesive resin by performing a new operation in the foaming / fusion process of the foamable resin particles. Can be manufactured. Moreover, when controlling the foaming amount by the pressure on the foamable resin particles, it is possible to achieve a preferable volume porosity by adjusting the foaming amount by balancing the internal pressure and the external pressure at the time of foaming of the foamable resin particles. There is an advantage that conventional foamed resin raw materials can be used as they are, and when cooling while controlling the pressure reduction speed, if the heated steam in the mold is replaced with air, it will cause fluctuations in temperature conditions due to the latent heat of the heated steam Therefore, there is an advantage that the foaming / fusion process conditions are stabilized.

かくして、本発明の発泡成形吸音体およびその製造方法は、このように、接着用樹脂を使用することなく、吸音体に好ましい細孔構造と構造強度を得るという従来困難であった問題を解決して、接着用樹脂に起因するコストアップ、操作性あるいは耐熱性や長期耐久性の低下を防止できるという優れた効果がある。よって本発明は、従来の問題点を解消した発泡成形吸音体およびその製造方法として、工業的価値はきわめて大なるものがある。   Thus, the foam-molded sound absorber of the present invention and the method for producing the same solve the problem that has heretofore been difficult to obtain a preferable pore structure and structural strength for the sound absorber without using an adhesive resin. Thus, there are excellent effects that the increase in cost, operability, heat resistance and long-term durability caused by the adhesive resin can be prevented. Therefore, the present invention has an extremely great industrial value as a foam molded sound absorber and a method for producing the same which have solved the conventional problems.

次に、本発明の発泡成形吸音体およびその製造方法に係る実施形態について、図1〜4を参照しながら説明する。
(発泡成形吸音体)
本発明の発泡成形吸音体は、先ず、図1に例示する次に述べる発泡成形体1からなる点に特徴がある。その発泡成形体1は、所定の形状に構成された型内に充填した発泡性樹脂粒子を加熱発泡して得られる無数の発泡セル11、11、・・で構成される発泡成形体であって、隣接する発泡セル11、11、・・が接触面11a、11a、においてそれ自体が軟化溶融して結合しているものである。すなわち、その融着結合部は、文字通り発泡樹脂素材が融合しているのであるから、発泡樹脂素材と全く同一の物性を持つのである。
Next, an embodiment according to the foam molded sound absorbing body and the manufacturing method thereof of the present invention will be described with reference to FIGS.
(Foam molded sound absorber)
The foam molded sound absorbing body of the present invention is characterized in that it is first composed of the foam molded body 1 described below illustrated in FIG. The foam molded body 1 is a foam molded body composed of a myriad of foam cells 11, 11,... Obtained by heating and foaming expandable resin particles filled in a mold configured in a predetermined shape. , Adjacent foam cells 11, 11,... Are bonded to each other at the contact surfaces 11a, 11a by softening and melting. That is, the fusion bonded portion literally has the same resin properties as the foamed resin material because the foamed resin material is fused.

次に、この発泡成形体1は、少なくとも3個の発泡セル11に囲まれる空間12(図1では、5個の発泡セル11に囲まれる空間12が例示してある)が連なって形成される連通気孔からなる3次元細気孔を備えていて、少なくとも次の物性を有するものである。   Next, the foam molded body 1 is formed by connecting a space 12 surrounded by at least three foam cells 11 (in FIG. 1, a space 12 surrounded by five foam cells 11 is illustrated). It has three-dimensional fine pores composed of continuous ventilation holes and has at least the following physical properties.

すなわち、この3次元細気孔は、全体の容積に対する細気孔の全容積比である容積気孔率が10〜40%であって、かつ少なくとも0.16MPaの引裂き強度を有するのである。
なお、この3次元細気孔は、多数の枝分かれしてジグザグ、曲がりくねり、その内径は拡大・縮小の変化を不規則に繰り返すという複雑な空間経路を持っているので、進入した音波に対し、反射、干渉、共振などの減衰効果が作用するという吸音基本機能を発揮するのである。
That is, the three-dimensional fine pores have a volume porosity of 10 to 40%, which is the total volume ratio of the fine pores to the entire volume, and have a tear strength of at least 0.16 MPa.
The three-dimensional pores have a complicated spatial path in which a large number of branches, zigzags, and windings, and the inner diameter of the three-dimensional fine pores irregularly repeats expansion and contraction. It exhibits the basic sound absorbing function of attenuating effects such as interference and resonance.

この容積気孔率が10%を下回る場合は、高強度を得るには好都合であるが、吸音効果が不足するので吸音体としては好ましくない。また、40%を超える場合は、吸音効果が低下する傾向を示すうえ、機械的強度が得られ難いという構造上の理由から好ましくない。また、本発明の吸音体の強度としてはは、ハンドリングに耐える形状保持強度が最低、必要であり、好ましくは構造体としての機械的強度を持つことが好ましい。この点から、機械的強度を代表する尺度として、引裂き強度で評価するのが適当であり、かつ少なくとも0.16MPa、好ましくは0.22MPa以上であるのが好ましい。   When this volume porosity is less than 10%, it is convenient to obtain high strength, but it is not preferable as a sound absorber because the sound absorbing effect is insufficient. On the other hand, if it exceeds 40%, the sound absorption effect tends to decrease, and the mechanical strength is difficult to obtain, which is not preferable. In addition, as the strength of the sound absorber of the present invention, it is necessary to have a shape retention strength that can withstand handling at a minimum, and it is preferable to have a mechanical strength as a structure. From this point, it is appropriate to evaluate the tear strength as a measure representative of mechanical strength, and it is preferably at least 0.16 MPa, preferably 0.22 MPa or more.

本発明の発泡成形体を構成する発泡セルの形状にも以下のような特徴がある。すなわち、その発泡セルのカット断面は、略円形ないし長円形断面を持つ粒体であって、その大きさは長径基準で1.5〜5.5mmのものが好ましい。この範囲外の場合は、吸音作用に必要な細気孔容積が得られ難いからである。
また、個々の発泡セルは、その長径/短径の範囲が3.0までの略長円形断面粒体であるのが、吸音作用に必要な細気孔容積が得られ易いので好ましい。
The shape of the foam cell constituting the foam molded article of the present invention also has the following characteristics. That is, the cut cross section of the foam cell is a granule having a substantially circular or oval cross section, and the size thereof is preferably 1.5 to 5.5 mm on the basis of the major axis. If it is outside this range, it is difficult to obtain a fine pore volume necessary for the sound absorbing action.
In addition, it is preferable that each foam cell has a substantially oval cross-sectional particle having a major axis / minor axis range of up to 3.0, because a fine pore volume necessary for sound absorption is easily obtained.

また、本発明は、図2に示すように、前記発泡成形体1の片面により容積気孔率の少ない表層部2を一体に設けるのが好ましい。この表層部2は、発泡成形体1の保護層として機能する他、吸音体としては遮音層または反射層として機能して吸音効果を高めるものであるから、発泡成形体1より容積気孔率の少ないことが必要であり、目的よっては、無通気性の強固な樹脂層であってもよい。   Further, in the present invention, as shown in FIG. 2, it is preferable to integrally provide a surface layer portion 2 having a small volume porosity on one side of the foam molded body 1. In addition to functioning as a protective layer for the foam molded body 1, the surface layer portion 2 functions as a sound insulating layer or a reflective layer as a sound absorbing body to enhance the sound absorbing effect, and therefore has a lower volume porosity than the foam molded body 1. Depending on the purpose, it may be a non-breathable strong resin layer.

なお、この表層部2は、図2のような片面の他、片面の一部、両面の一部または全部のように目的に応じて配置できる。また、前記表層部2は、発泡成形体1に別途、貼付したものでもよいが、その発泡成形体の発泡成形時に一体に成形されたものが、製造コスト面から好ましい。なお、このような構造の発泡成形吸音体を製造するには、表層部2に相当する部位の加熱条件を調整することで可能である。   In addition, this surface layer part 2 can be arrange | positioned according to the objective like one part of one side like FIG. Further, the surface layer portion 2 may be affixed separately to the foam molded body 1, but is preferably integrally molded at the time of foam molding of the foam molded body from the viewpoint of manufacturing cost. In addition, in order to manufacture the foam-molded sound absorber having such a structure, it is possible to adjust the heating conditions of the portion corresponding to the surface layer portion 2.

さらに、本発明は、図3に示すように、発泡成形体1の一部に、より引裂き強度の大なる増強発泡体3を設けたものとして具体化すれば、単に吸音材としてのみならず、強度を負担する構造部材を兼ねる用途にも応用範囲が広がり、好ましいものとなる。
なお、図3の事例では、屈曲角を有する発泡成形体1の角部分に増強発泡体3を配し、さらに表層部2をも併せて備えた構造を示すが、増強発泡体3としては前記表層部2と同様に容積気孔率を少なく設定して強度を向上させたものが適用できる。この場合も、この増強発泡体3を発泡成形体1の発泡成形時に加熱条件を調整して一体に成形するようにしたものが製造コストの面から好適である。
Furthermore, as shown in FIG. 3, the present invention, when embodied as a part of the foam molded body 1 provided with the enhanced foam 3 having a higher tear strength, is not only a sound absorbing material, The range of application is also widened for applications that also serve as a structural member that bears strength, which is preferable.
In the example of FIG. 3, the reinforcing foam 3 is arranged at the corner portion of the foam molded body 1 having a bending angle, and the surface layer portion 2 is also provided. As in the case of the surface layer portion 2, a material having a reduced volume porosity and improved strength can be applied. Also in this case, it is preferable from the viewpoint of manufacturing cost that the reinforcing foam 3 is integrally formed by adjusting the heating conditions at the time of foam molding of the foam molded body 1.

次に、本発明をその用途面から補足する。本発明は、吸音材としてのみならず、強度を負担する構造部材を兼ねる材料であるから、適度な吸音性と強度を要求される自動車用内装部材に好適である。図5に示すようにダッシュボード51、車室内壁52、フロア53などに用いられ得るが、この場合、前記表層部2の厚さを発泡成形吸音体の全体の厚さの10〜45%、発泡成形体1部分の厚さを残部(90〜55%)とするのが適当である。特に、フロア53に用いられる場合には、図6に略示するように、前記表層部2を車室側に向けて設置し、車体フロアとの間に発泡成形体1を介在させて、この発泡成形吸音体によって車体フロア53a面の凹凸をフラットにする車両用フロアフラット材として好ましく用いられる。この場合、前記表層部の厚さが5〜40mmであるのが好ましい。   Next, the present invention will be supplemented from the application aspect. The present invention is suitable not only as a sound-absorbing material but also as a structural member that bears strength, and is therefore suitable for automobile interior members that require moderate sound-absorbing properties and strength. As shown in FIG. 5, it can be used for the dashboard 51, the vehicle interior wall 52, the floor 53, etc. In this case, the thickness of the surface layer portion 2 is 10 to 45% of the total thickness of the foam molded sound absorber, It is appropriate that the thickness of one part of the foamed molded product is the remainder (90 to 55%). In particular, when used for the floor 53, as schematically shown in FIG. 6, the surface layer portion 2 is installed toward the vehicle compartment side, and the foam molded body 1 is interposed between the vehicle body floor and the It is preferably used as a vehicle floor flat material for flattening the unevenness of the surface of the vehicle body floor 53a by the foam molded sound absorber. In this case, the thickness of the surface layer portion is preferably 5 to 40 mm.

さらに、本発明は、建築物の壁用、天井用など吸音内装部材の他、道路・鉄道騒音防止部材、住宅用吸音部材または産業機器用吸音部材として広く用いられ得るのはいうまでもないが、この場合、前記表層部2は強度を有する化粧面を構成するのであるが、その厚さを発泡成形吸音体の全体の厚さの10〜45%とするのが好ましく、より具体的には、前記表層部2の厚さが5〜40mmであるのが好ましい。   Furthermore, it goes without saying that the present invention can be widely used as a sound absorbing interior member such as a building wall or a ceiling, a road / railway noise preventing member, a residential sound absorbing member, or an industrial equipment sound absorbing member. In this case, the surface layer portion 2 constitutes a decorative face having strength, but the thickness is preferably 10 to 45% of the total thickness of the foam molded sound absorbing body, more specifically. The surface layer 2 preferably has a thickness of 5 to 40 mm.

(発泡成形吸音体の製造方法)
本発明の発泡成形吸音体の製造方法について、図4(A)(B)を参照して説明する
図4は、発泡成形方法における重要な操作条件である、発泡性樹脂粒子が充填されるキャビティ内の圧力(圧力曲線4,5)と温度(温度曲線4a,5a)を縦軸に、時間経過を横軸にして、その挙動を模式的にやや誇張して示したグラフであり、図4(A)は従来の無通気性の発泡成形方法の場合、図4(B)は本発明の方法の場合である。
(Method for producing foam molded sound absorber)
The method for producing a foam molded sound absorber of the present invention will be described with reference to FIGS. 4A and 4B. FIG. 4 shows a cavity filled with expandable resin particles, which is an important operating condition in the foam molding method. FIG. 4 is a graph schematically showing the behavior slightly exaggerated, with the pressure (pressure curves 4 and 5) and the temperature (temperature curves 4a and 5a) in the vertical axis and the passage of time as the horizontal axis. (A) is the case of the conventional air-impermeable foam molding method, and FIG. 4 (B) is the case of the method of the present invention.

本発明の方法も、所定の型内に充填した発泡性樹脂粒子を加熱発泡して発泡成形体を製作する点を要点としていることは、従来の基本的手法と変わるところはない。
先ず、従来から製造されている、本発明のような気孔構造を持たない無通気性の発泡成形体の製造工程を、本件発明者の知見に基づいて、図4(A)を参照して解説すると、以下のA1)昇温工程、A2)融着温度加熱工程、A3)発泡融着工程、A4)冷却・取出し工程に大別される。
The method of the present invention is not different from the conventional basic method in that the foamed resin particles filled in a predetermined mold are heated and foamed to produce a foamed molded article.
First, the production process of a non-breathable foamed molded article having no pore structure as in the present invention, which has been conventionally produced, will be described with reference to FIG. 4 (A) based on the knowledge of the present inventors. Then, it is roughly divided into the following A1) temperature raising step, A2) fusion temperature heating step, A3) foam fusion step, and A4) cooling / removal step.

(対比する従来方法)
A1)昇温工程:キャビティ内を加熱昇温する工程で、発泡樹脂粒子の充填に続いて、チャンバ内排気、キャビティ内の加熱蒸気による一方向排気、同じく逆方向排気などにより、内部を水蒸気で昇温するとともに水蒸気で充満させる。圧力曲線4、温度曲線4aは実際はジグザグに上昇するが、温度曲線4aは遅れて圧力曲線4を追う形になる。
(Contrast conventional method)
A1) Temperature raising step: In the step of heating and raising the temperature inside the cavity, following filling of the foamed resin particles, the inside is made of water vapor by exhausting in the chamber, one-way exhausting by the heating steam in the cavity, or reverse exhausting in the same way. Heat up and fill with steam. The pressure curve 4 and the temperature curve 4a actually increase in a zigzag manner, but the temperature curve 4a is delayed and follows the pressure curve 4.

A2)融着温度加熱工程:発泡樹脂粒子を発泡(膨張)させ、かつ融着させて、キャビティ形状に沿った所定の形状に成形するために、加熱水蒸気により全体を加熱してむら無く融着温度に加熱する工程。なお、この工程では、発泡樹脂粒子は融着温度に相当する蒸気圧で加圧され圧縮された粒径形状となって、キャビティ内を自由に流動可能な状態に保たれている。   A2) Fusion temperature heating step: In order to foam (expand) and fuse the foamed resin particles into a predetermined shape along the cavity shape, the whole is heated with heated steam to fuse evenly. Heating to temperature. In this step, the foamed resin particles are pressed and compressed with a vapor pressure corresponding to the fusing temperature, and are kept in a freely flowable state in the cavity.

A3)発泡融着工程:均一に融着温度に加熱されたa点において、蒸気の供給を止め、排気弁を開いて圧力を開放する工程。この場合、圧縮された発泡樹脂粒子は融着温度のまま、急激な減圧にさらされるので、内圧によって急激に発泡(膨張)して相互間の空隙を押し潰しさらに相互に押圧して境界面が融着することになる。ここでは、圧力は圧力曲線4が示すように、急激に低下するものの、キャビティ内の温度は、膨張した発泡樹脂粒子(発泡セル)は断熱性なので追随することなく、温度曲線4aのように、融着完了温度:b点まで遅れて低下する。ここで、融着完了温度は前記融着現象が進行しなくなる温度をいう。   A3) Foam fusion process: A process of stopping the supply of steam and opening the exhaust valve to release the pressure at point a heated to the fusion temperature uniformly. In this case, since the compressed foamed resin particles are exposed to a rapid decompression at the fusion temperature, the foam is expanded (expanded) suddenly by the internal pressure to crush the gaps between them and further press each other to form a boundary surface. It will be fused. Here, although the pressure rapidly decreases as shown by the pressure curve 4, the temperature in the cavity does not follow the expanded foamed resin particle (foamed cell) because it is adiabatic, as in the temperature curve 4a. Fusion completion temperature: Decreases with delay until point b. Here, the fusion completion temperature is a temperature at which the fusion phenomenon does not proceed.

A4)冷却・取出し工程:型内を冷水などで冷却し、所定形状に発泡成形された成形物を取り出す工程。温度は急激に低下する。
かくして、隣接する発泡セルが全面的に融着して、実質的に無通気性の発泡成形方体が得られるのである。
A4) Cooling / removing step: A step of cooling the inside of the mold with cold water or the like and taking out a molded product foam-molded into a predetermined shape. The temperature drops rapidly.
Thus, the adjacent foam cells are fused together to obtain a substantially air-impermeable foam molding.

(本発明の方法)
次に、本発明の発泡成形吸音体の製造方法を図4(B)を参照して説明する。
本発明の要点である発泡成形体は、大別してB1)昇温工程、B2)融着温度加熱工程、B3)発泡融着工程、B4)冷却・取出し工程によって得られる。ここで、B1)昇温工程、B2)融着温度加熱工程は、発泡性樹脂粒子を加熱水蒸気の存在下で、その発泡性樹脂粒子の融着温度に均一に加熱する工程であって、先に解説したA1工程、A2工程と同様である。
(Method of the present invention)
Next, a method for producing the foam molded sound absorbing body of the present invention will be described with reference to FIG.
The foamed molded product, which is the main point of the present invention, can be roughly divided into B1) a temperature raising step, B2) a fusion temperature heating step, B3) a foam fusion step, and B4) a cooling / removal step. Here, B1) temperature raising step and B2) fusing temperature heating step are steps in which the expandable resin particles are uniformly heated to the fusing temperature of the expandable resin particles in the presence of heated steam. It is the same as A1 process and A2 process which were explained in 1.

B3)発泡融着工程:本発明の特徴とする工程であり、B2工程に続いて、発泡性樹脂粒子の発泡(膨張)量を制御しながら発泡セルを融着させる工程である。具体的には、先のA3工程のように急激に減圧させるのではなく、蒸気の供給と排気を調節して、圧力曲線5が図4(B)に示すa点からc点に変化するように、ある圧力経路に沿って圧力を制御しながら、最終的に減圧する点が重要である。   B3) Foam fusion process: This is a process characterized by the present invention, and is a process of fusing foam cells while controlling the amount of foaming (expansion) of the expandable resin particles following the process B2. Specifically, the pressure curve 5 changes from the point a to the point c shown in FIG. 4B by adjusting the supply and exhaust of steam instead of reducing the pressure rapidly as in the previous step A3. In addition, it is important to finally reduce the pressure while controlling the pressure along a certain pressure path.

図4(B)の事例では、キャビティ内が均一な設定融着温度になったa点から、温度が融着完了温度であるb点にいたる間を、キャビティ内圧力を制御終了圧力:c点まで制御しながら減圧している。この圧力制御の目的は、融着温度域にある発泡性樹脂粒子を、粒子の内圧(粒子内圧)と外圧(キャビティ内圧力)とをバランスさせながら発泡(膨張)させる、すなわち、減圧制御してこの発泡(膨張)量を調節して、発泡性樹脂粒子の相互間に空間(容積気孔率)を残しつつ、かつ押し圧させ接触面では融着させようとする点にある。かくして、本発明の発泡成形吸音体の実質的構成材料である、前記した所定の容積気孔率を持つ3次元細気孔を備えながら所定の引裂き強度で代表される強度に融着結合した発泡セルからなる発泡成形体が得られるのである。   In the case of FIG. 4 (B), the pressure in the cavity is controlled to the end point of control: point c from the point a where the inside of the cavity has a uniform set fusion temperature to the point b where the temperature is the fusion completion temperature. The pressure is reduced while controlling. The purpose of this pressure control is to expand (expand) foamable resin particles in the fusion temperature range while balancing the internal pressure (particle internal pressure) and external pressure (cavity internal pressure) of the particles. The amount of foaming (expansion) is adjusted to leave the space (volume porosity) between the foamable resin particles, and to press and press the contact surface to be fused. Thus, from the foam cell which is a substantial constituent material of the foam-molded sound absorber of the present invention and has the above-mentioned three-dimensional fine pores having a predetermined volume porosity and fusion-bonded to a strength represented by a predetermined tear strength. Thus, a foamed molded product is obtained.

また、一般的に、減圧速度を大とすれば膨張が促進され容積気孔率は低下し、減圧速度を小とすれば膨張が抑制され容積気孔率は増大することになるが、発泡性樹脂粒子の発泡特性は、樹脂種類や予備発泡処理によって変化するので、減圧速度の程度、減圧曲線、および制御終了圧力cの値は予めに使用する発泡性樹脂粒子に基づいて予備テストを行い定めるものとする。   In general, if the decompression speed is increased, the expansion is promoted and the volume porosity is decreased, and if the decompression speed is decreased, the expansion is suppressed and the volume porosity is increased. Since the foaming characteristics of the resin vary depending on the type of resin and the prefoaming treatment, the degree of decompression speed, the decompression curve, and the value of the control end pressure c are determined by conducting a preliminary test based on the foamable resin particles used in advance. To do.

また、この圧力制御は、使用する発泡性樹脂粒子の融着完了温度のb点に至るまで行なうのが適当である。この融着完了温度は、発泡セルの融着が進行しなくなる温度であるから、この温度以下にまで圧力制御しても目的とする効果が期待できない。
なお、本発明における融着温度や、この融着完了温度は、使用する発泡性樹脂粒子の主に樹脂種類によって定まる値であり、例えば、ポリオレフィン樹脂の場合は、下限融着温度は130〜135℃であり、上限は160℃までが好ましい。また、融着完了温度は125〜129℃である。したがって、a点における設定融着温度は、この下限融着温度を基準にして上限までの間に設定するものである。
Further, it is appropriate to perform this pressure control until reaching the point b of the fusion completion temperature of the expandable resin particles to be used. Since the fusion completion temperature is a temperature at which the fusion of the foamed cells does not proceed, the desired effect cannot be expected even if the pressure is controlled below this temperature.
The fusing temperature and the fusing temperature in the present invention are values determined mainly by the resin type of the expandable resin particles to be used. For example, in the case of polyolefin resin, the lower fusing temperature is 130 to 135. The upper limit is preferably up to 160 ° C. The fusion completion temperature is 125 to 129 ° C. Accordingly, the set fusion temperature at point a is set between the upper limit and the lower limit fusion temperature.

以上説明した発泡成形方法融着工程の後、B4)冷却・取出し工程となるが、この工程は従前のA4工程と同様である。
かくして、本発明の発泡成形吸音体を構成するところの、隣接する発泡セルそれ自体が軟化溶融して結合しており、容積気孔率が10〜40%である3次元細気孔と少なくとも0.16MPaの引裂き強度を有する発泡成形体が得られる。
After the foam molding method fusion process described above, B4) a cooling / removal process is performed, which is the same as the previous A4 process.
Thus, the adjacent foam cells themselves constituting the foam molded sound absorber of the present invention are softened and melted and bonded, and three-dimensional fine pores having a volume porosity of 10 to 40% and at least 0.16 MPa. A foamed molded article having a tear strength of 5% is obtained.

また、この発泡融着工程における圧力制御するに当たり、型内に充満している加熱水蒸気を予め空気で置換するか、またはその圧力制御を行いながら加熱水蒸気を空気で置換するのが好ましい。その理由は、圧力制御に際して通常、水蒸気の大部分は凝縮水に変化するのであるが、その場合、大きな容積変化を伴うとともに、液化の顕熱が発生するなどして、工程中の温度・圧力の予想外の影響を与えるおそれがあり、圧力制御の安定性を損なうおそれがあるからである。また、空気を用いる場合は、水蒸気に比較して温度の昇降制御も容易に行なえるという利点も得られる。   In controlling the pressure in the foaming and fusion process, it is preferable to replace the heated steam filled in the mold with air in advance, or replace the heated steam with air while controlling the pressure. The reason for this is that during the pressure control, most of the water vapor usually changes to condensed water. In this case, the temperature and pressure during the process are accompanied by a large volume change and sensible heat of liquefaction. This is because an unexpected influence may be exerted, and the stability of pressure control may be impaired. In addition, when air is used, there is an advantage that temperature raising and lowering control can be easily performed as compared with water vapor.

次に、本発明の製造方法の実施例およびそれに得られた発泡成形体の特性を説明する。
なお、製造条件の諸元は次の通りであった。
a)使用発泡樹脂:
種類;ポリオレフィン樹脂、粒度;2.5〜3.5mm、予備発泡処理;済み。
b)金型:
キャビティの両側にベントホールを備えた加熱水蒸気による通常の加熱タイプの開閉金型。
Next, examples of the production method of the present invention and the characteristics of the foamed molded article thus obtained will be described.
The specifications of the manufacturing conditions were as follows.
a) Used foamed resin:
Type: Polyolefin resin, particle size: 2.5-3.5 mm, pre-foaming treatment: finished.
b) Mold:
A normal heating type open / close mold using heated steam with vent holes on both sides of the cavity.

c)融着温度加熱工程までの昇温工程:
発泡樹脂粒子の充填、チャンバ内排気、キャビティ内の加熱蒸気による一方向排気、同じく逆方向排気などは従来から知られている条件で行なう。
d)融着温度加熱工程:
両側のチャンバに0.3〜0.35MPaの加熱水蒸気を20秒間導入し、キャビティ内の発泡樹脂粒子を設定融着温度(143〜149℃)にまで加熱する。
c) Temperature raising step up to the fusion temperature heating step:
The filling of the foamed resin particles, the exhaust in the chamber, the one-way exhaust by the heating steam in the cavity, and the reverse exhaust in the same manner are performed under the conditions conventionally known.
d) Fusion temperature heating process:
Heated water vapor of 0.3 to 0.35 MPa is introduced into the chambers on both sides for 20 seconds, and the foamed resin particles in the cavity are heated to the set fusion temperature (143 to 149 ° C.).

e)発泡・融着工程:
加熱終了のa点から水蒸気の供給を止め、空気を供給しつつ、排気弁を開いて、水蒸気と空気を入れ替えながら減圧速度を調節する。予め確認しておいた融着完了温度のb点(129℃)に相当する時点まで、図4(B)に示すようなa点からb点に至る圧力曲線51に沿って減圧制御を行い、圧力c点(0.18MPa)で減圧制御を終了する。なお、この圧力曲線51、使用発泡樹脂粒子、加熱条件、予定容積気孔率、予定強度などの諸元に適用するよう予め予備テストによって定めておくものとする。
e) Foaming / fusion process:
The supply of water vapor is stopped at point a after the heating is completed, the air is supplied, the exhaust valve is opened, and the pressure reduction rate is adjusted while replacing the water vapor and the air. The pressure reduction control is performed along the pressure curve 51 from the point a to the point b as shown in FIG. 4B until the point corresponding to the point b (129 ° C.) of the fusion completion temperature confirmed in advance. The pressure reduction control is terminated at the pressure point c (0.18 MPa). In addition, it shall be previously determined by a preliminary test so as to be applied to specifications such as the pressure curve 51, the foamed resin particles used, the heating conditions, the planned volume porosity, and the planned strength.

f)冷却・取出し工程:チャンバへの給気を停止し、排気弁を開いて、内部に気体を排気し、同時にチャンバ内に冷水を注水して冷却する。その後、金型を開いて成形体を取り出す。   f) Cooling / removal step: The supply of air to the chamber is stopped, the exhaust valve is opened, the gas is exhausted inside, and at the same time, cold water is poured into the chamber for cooling. Thereafter, the mold is opened and the molded body is taken out.

かくして得られた発泡成形体は、容積気孔率が20%、引裂き強度が0.22MPaの構造体であって、ハンドリングは勿論、構造部材として利用可能な強度を持つことが確認された。また、そのカット断面の観察結果、発泡セルは略円形ないし長円形断面を持つ粒体であって、それぞれ隣接する発泡セルが接触面においてそれ自体が軟化溶融して結合していることが認められた。なお、本発明における引裂き強度は、JIS−K6767規定の方法で測定したものである。   The foamed molded body thus obtained was a structure having a volume porosity of 20% and a tear strength of 0.22 MPa, and it was confirmed that the foamed molded body has a strength that can be used as a structural member as well as handling. In addition, as a result of observation of the cut cross section, it is recognized that the foam cell is a granule having a substantially circular or oval cross section, and each of the adjacent foam cells is softened and melted and bonded to each other at the contact surface. It was. The tear strength in the present invention is measured by the method defined in JIS-K6767.

また、このような発泡セルに囲まれる空間は、成形体内に網の目のように連通した気孔を構成し、全体として3次元細孔構造が作られていることも観察され、その吸音特性は、
試料厚さ15mm、100〜3000Hzの周波数領域の測定(JIS(A)1405)において、吸音率が30%以上のピークを持つ低音吸音性に優れる点が確認できた。
Moreover, it is observed that the space surrounded by such foam cells constitutes pores communicating like a mesh in the molded body, and a three-dimensional pore structure is formed as a whole, and its sound absorption characteristics are ,
In the measurement of a sample thickness of 15 mm and a frequency range of 100 to 3000 Hz (JIS (A) 1405), it was confirmed that the sound absorption coefficient was excellent in bass sound absorption with a peak of 30% or more.

かくして、本発明の発泡成形体からなる吸音体は、このような3次元細孔構造による吸音効果と、発泡樹脂が持つ本来の材料強度、耐熱性、耐久性を利用した騒音防止用吸音体、例えば、自動車用内装部材、車両用フロアフラット材、住宅壁など建築物用吸音材、産業機器用、道路の騒音防止用、工場や地下鉄などの排気消音ダクト用として広く有用なことが確認された。   Thus, the sound absorber made of the foamed molded product of the present invention has a sound absorbing effect by such a three-dimensional pore structure and a sound absorbing material for noise prevention utilizing the original material strength, heat resistance, and durability possessed by the foamed resin, For example, it has been confirmed that it is widely useful for automobile interior members, vehicle floor flat materials, sound absorbing materials for buildings such as residential walls, industrial equipment, road noise prevention, and exhaust silencers for factories and subways. .

本発明の発泡成形体の模式的断面図。The typical sectional view of the foaming fabrication object of the present invention. 本発明の発泡成形体の別形態を示す模式的断面図。The typical sectional view showing another form of the foaming fabrication object of the present invention. 本発明の発泡成形体の他の別形態を示す模式的断面図。Typical sectional drawing which shows the other another form of the foaming molding of this invention. 本発明の製造法を説明するための圧力、温度と時間の関係を示す模式的経過グラフ(B)および従来の参考グラフ(A)。The typical progress graph (B) which shows the relationship between the pressure, temperature, and time for demonstrating the manufacturing method of this invention, and the conventional reference graph (A). 自動車内装を示す断面イラスト図。The cross-sectional illustration which shows a motor vehicle interior. 本発明の自動車用内装部材の断面略図。The cross-sectional schematic of the interior member for motor vehicles of this invention.

符号の説明Explanation of symbols

1:発泡成形体、11:発泡セル、11a:接触面、12:空間 1: foamed molded body, 11: foamed cell, 11a: contact surface, 12: space

Claims (15)

型内に充填した発泡性樹脂粒子を加熱発泡して得られる無数の発泡セルで構成される発泡成形体であって、隣接する発泡セルが接触面においてそれ自体が軟化溶融して結合されるとともに、少なくとも3個の発泡セルに囲まれる空間が連なって形成される連通気孔からなり、容積気孔率が10〜40%である3次元細気孔を備え、かつ少なくとも0.16MPaの引裂き強度を有する発泡成形体からなることを特徴とする発泡成形吸音体。   A foam-molded article composed of an infinite number of foam cells obtained by heating and foaming foamable resin particles filled in a mold, and adjacent foam cells are softened and melted and bonded to each other at the contact surface. A foam having three-dimensional narrow pores having a volume porosity of 10 to 40% and having a tear strength of at least 0.16 MPa, comprising continuous vents formed by connecting spaces surrounded by at least three foam cells. A foam molded sound absorber comprising a molded body. 請求項1に記載の発泡成形体の外表面の一部または全部に、より容積気孔率の少ない表層部を付加したことを特徴とする発泡成形吸音体。   A foam molded sound absorber, wherein a surface layer portion having a smaller volume porosity is added to a part or all of the outer surface of the foam molded body according to claim 1. 前記表層部が、当該発泡成形体の発泡成形時に一体に成形されたものである請求項2に記載の発泡成形吸音体。   The foam molded sound absorbing body according to claim 2, wherein the surface layer portion is integrally formed at the time of foam molding of the foam molded body. 請求項1、2または3に記載の発泡成形体の一部に、より強度の大なる増強発泡体を付加したことを特徴とする発泡成形吸音体。   A foam-molded sound absorber, wherein an enhanced foam having a higher strength is added to a part of the foam-molded body according to claim 1, 2 or 3. 前記増強発泡体が、当該発泡成形体の発泡成形時に一体に成形されたものである請求項4に記載の発泡成形吸音体。   The foam-molded sound absorber according to claim 4, wherein the reinforcing foam is integrally formed when the foam-molded body is foam-molded. 型内に充填した発泡性樹脂粒子を加熱発泡して得られる発泡成形体で構成される発泡成形吸音体の製造方法であって、発泡性樹脂粒子を加熱水蒸気の存在下で、その発泡性樹脂粒子の融着温度に加熱した後、発泡量を制御しながら発泡セルを融着させるとともに冷却して、請求項1に記載の発泡成形体を得ることを特徴とする発泡成形吸音体に製造方法。   A method for producing a foam-molded sound absorber comprising a foam-molded product obtained by heating and foaming foamable resin particles filled in a mold, wherein the foamable resin particles are heated in the presence of heated steam. The foam molded sound absorber according to claim 1, wherein the foam molded body according to claim 1 is obtained by heating to the fusion temperature of the particles and then fusing and cooling the foamed cells while controlling the amount of foaming. . 前記発泡量の制御を、発泡性樹脂粒子に対する圧力を制御することにより行なう請求項6に記載の発泡成形吸音体に製造方法。   The method for producing a foam-molded sound absorber according to claim 6, wherein the amount of foaming is controlled by controlling the pressure on the foamable resin particles. 前記圧力制御を前記発泡性樹脂粒子の融着完了温度まで行なうようにした請求項7に記載の発泡成形吸音体の製造方法。   The method for producing a foam molded sound absorber according to claim 7, wherein the pressure control is performed up to a fusion completion temperature of the expandable resin particles. 前記融着温度に加熱した後、圧力制御しつつ冷却するに当たり、予め型内の加熱水蒸気を空気で置換することを特徴とする請求項7または8に記載の発泡成形吸音体の製造方法。   The method for producing a foam-molded sound absorber according to claim 7 or 8, wherein the heating steam in the mold is replaced with air in advance when cooling while controlling the pressure after heating to the fusion temperature. 前記融着温度に加熱した後、圧力制御しつつ冷却するに当たり、型内の加熱水蒸気を空気で置換しながら行なうことを特徴とする請求項7または8に記載の発泡成形吸音体の製造方法。   The method for producing a foam-molded sound absorber according to claim 7 or 8, wherein the heating steam in the mold is replaced with air when cooling while controlling the pressure after heating to the fusion temperature. 請求項2、3、4、5のいずれかに記載の発泡成形吸音体であって、前記表層部の厚さが発泡成形吸音体の全体の厚さの10〜45%であり、自動車用内装部材として用いられる発泡成形吸音体。   The foam molded sound absorber according to any one of claims 2, 3, 4, and 5, wherein the thickness of the surface layer portion is 10 to 45% of the total thickness of the foam molded sound absorber. Foam molded sound absorber used as a member. 請求項2、3、4、5のいずれかに記載の発泡成形吸音体であって、前記表層部を車室側に向けて設置し、この発泡成形吸音体によって車体フロア面の凹凸をフラットにする車両用フロアフラット材として用いられる発泡成形吸音体。   The foam molded sound absorber according to any one of claims 2, 3, 4, and 5, wherein the surface layer portion is disposed toward a vehicle compartment side, and the unevenness of the vehicle body floor surface is flattened by the foam molded sound absorber. Foam molded sound absorber used as a vehicle floor flat material. 請求項12記載の発泡成形吸音体であって、前記表層部の厚さが5〜40mmである発泡成形吸音体。   The foam-molded sound absorber according to claim 12, wherein the thickness of the surface layer portion is 5 to 40 mm. 請求項2、3、4、5のいずれかに記載の発泡成形吸音体であって、前記表層部の厚さが発泡成形吸音体の全体の厚さの10〜45%であり、建築用吸音部材、道路・鉄道騒音防止部材、住宅用吸音部材または産業機器用吸音部材として用いられる発泡成形吸音体。   The foam-molded sound absorber according to any one of claims 2, 3, 4, and 5, wherein the thickness of the surface layer portion is 10 to 45% of the total thickness of the foam-molded sound absorber. A foam molded sound absorber used as a member, a road / railway noise prevention member, a residential sound absorbing member, or a sound absorbing member for industrial equipment. 請求項14記載の発泡成形吸音体であって、前記表層部の厚さが5〜40mmである発泡成形吸音体。   The foam-molded sound absorber according to claim 14, wherein the surface layer portion has a thickness of 5 to 40 mm.
JP2005037960A 2004-09-14 2005-02-15 Foam molded sound absorber and method for producing the same Pending JP2006110982A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2005037960A JP2006110982A (en) 2004-09-14 2005-02-15 Foam molded sound absorber and method for producing the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2004266853 2004-09-14
JP2005037960A JP2006110982A (en) 2004-09-14 2005-02-15 Foam molded sound absorber and method for producing the same

Publications (1)

Publication Number Publication Date
JP2006110982A true JP2006110982A (en) 2006-04-27

Family

ID=36379888

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2005037960A Pending JP2006110982A (en) 2004-09-14 2005-02-15 Foam molded sound absorber and method for producing the same

Country Status (1)

Country Link
JP (1) JP2006110982A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007106973A (en) * 2005-09-13 2007-04-26 Daisen Kogyo:Kk Foam molded body and method for producing the same
WO2007105285A1 (en) * 2006-03-13 2007-09-20 Daisen Industry Co., Ltd. Foam molding and process for producing the same
WO2008043385A1 (en) * 2006-10-13 2008-04-17 Henkel Ag & Co. Kgaa Acoustic absorbing member with different types of pores
JP2008179064A (en) * 2007-01-25 2008-08-07 Daisen Industry Co Ltd Molding machine for porous molding and method for manufacturing porous molding
JP2013035256A (en) * 2011-08-11 2013-02-21 Daisen Co Ltd Composite molded article, and method of manufacturing the same
US9976007B2 (en) 2014-03-27 2018-05-22 Sekisui Plastics Co., Ltd. Resin composite and method for producing resin composite

Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS50108365A (en) * 1974-02-02 1975-08-26
JPS5726511A (en) * 1980-07-23 1982-02-12 Iseki Agricult Mach Taking-on and feeding device for auxiliary nursery plant of rice transplanter
JPH01148533A (en) * 1987-12-07 1989-06-09 Toyo Mach & Metal Co Ltd Foam molding device
JPH0416330A (en) * 1990-05-09 1992-01-21 Mitsubishi Yuka Badische Co Ltd In-mold molding of thermoplastic resin foamable particle
JPH07308930A (en) * 1994-05-16 1995-11-28 Yuichi Nakamura Foam molded product, separation molding method of different kinds of foamable beads and molding device therefor
JPH0811148A (en) * 1994-07-01 1996-01-16 Kasahara Kogyo Kk Production of synthetic resin foamed molded object
JPH11953A (en) * 1997-06-12 1999-01-06 Mitsuboshi Belting Ltd Skin integrated bead expanded product and its manufacture
JPH11165326A (en) * 1997-12-03 1999-06-22 Asahi Chem Ind Co Ltd Manufacture of foamed particle molded product
JPH11333938A (en) * 1998-05-28 1999-12-07 Asahi Chem Ind Co Ltd Polystyrenic foamed particle molded object and production thereof
JP2001341149A (en) * 2000-05-31 2001-12-11 Kasahara Industries Co Ltd Method for molding foamed resin molded article and eject pin used for the method
JP2002036276A (en) * 2000-07-25 2002-02-05 Daisen Kogyo:Kk Apparatus and method for molding a foamed composite molded article, and a foamed composite molded article obtained by the molding method
JP2003118460A (en) * 2001-10-15 2003-04-23 Hitachi Chem Co Ltd Automobile floor spacer
JP2004202915A (en) * 2002-12-26 2004-07-22 Daisen Kogyo:Kk Porous molded article and foam molding method thereof
JP2007106973A (en) * 2005-09-13 2007-04-26 Daisen Kogyo:Kk Foam molded body and method for producing the same

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS50108365A (en) * 1974-02-02 1975-08-26
JPS5726511A (en) * 1980-07-23 1982-02-12 Iseki Agricult Mach Taking-on and feeding device for auxiliary nursery plant of rice transplanter
JPH01148533A (en) * 1987-12-07 1989-06-09 Toyo Mach & Metal Co Ltd Foam molding device
JPH0416330A (en) * 1990-05-09 1992-01-21 Mitsubishi Yuka Badische Co Ltd In-mold molding of thermoplastic resin foamable particle
JPH07308930A (en) * 1994-05-16 1995-11-28 Yuichi Nakamura Foam molded product, separation molding method of different kinds of foamable beads and molding device therefor
JPH0811148A (en) * 1994-07-01 1996-01-16 Kasahara Kogyo Kk Production of synthetic resin foamed molded object
JPH11953A (en) * 1997-06-12 1999-01-06 Mitsuboshi Belting Ltd Skin integrated bead expanded product and its manufacture
JPH11165326A (en) * 1997-12-03 1999-06-22 Asahi Chem Ind Co Ltd Manufacture of foamed particle molded product
JPH11333938A (en) * 1998-05-28 1999-12-07 Asahi Chem Ind Co Ltd Polystyrenic foamed particle molded object and production thereof
JP2001341149A (en) * 2000-05-31 2001-12-11 Kasahara Industries Co Ltd Method for molding foamed resin molded article and eject pin used for the method
JP2002036276A (en) * 2000-07-25 2002-02-05 Daisen Kogyo:Kk Apparatus and method for molding a foamed composite molded article, and a foamed composite molded article obtained by the molding method
JP2003118460A (en) * 2001-10-15 2003-04-23 Hitachi Chem Co Ltd Automobile floor spacer
JP2004202915A (en) * 2002-12-26 2004-07-22 Daisen Kogyo:Kk Porous molded article and foam molding method thereof
JP2007106973A (en) * 2005-09-13 2007-04-26 Daisen Kogyo:Kk Foam molded body and method for producing the same

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007106973A (en) * 2005-09-13 2007-04-26 Daisen Kogyo:Kk Foam molded body and method for producing the same
WO2007105285A1 (en) * 2006-03-13 2007-09-20 Daisen Industry Co., Ltd. Foam molding and process for producing the same
US8470217B2 (en) 2006-03-13 2013-06-25 Daisen Industry Co., Ltd. Foamed molding and its manufacturing method
WO2008043385A1 (en) * 2006-10-13 2008-04-17 Henkel Ag & Co. Kgaa Acoustic absorbing member with different types of pores
JP2008179064A (en) * 2007-01-25 2008-08-07 Daisen Industry Co Ltd Molding machine for porous molding and method for manufacturing porous molding
JP2013035256A (en) * 2011-08-11 2013-02-21 Daisen Co Ltd Composite molded article, and method of manufacturing the same
US9976007B2 (en) 2014-03-27 2018-05-22 Sekisui Plastics Co., Ltd. Resin composite and method for producing resin composite

Similar Documents

Publication Publication Date Title
CN101400495B (en) Foam molding and process for producing the same
EP3245461B1 (en) Vacuum insulating panel
WO2005075878A1 (en) Vacuum thermally insulating material and method for production thereof, thermally insulated equipment having the vacuum thermally insulating material, and thermally insulated board
JP2006110982A (en) Foam molded sound absorber and method for producing the same
US6165300A (en) Process for manufacturing composite bodies made of plastics
JP4566114B2 (en) Method for producing foam molded article
WO2018101198A1 (en) Foamable resin multilayer molded board and method for manufacturing same
JP3765815B2 (en) Method for manufacturing vehicle cushion material and vehicle seat cushion
JP2004202915A (en) Porous molded article and foam molding method thereof
JP3180765U (en) Porous foam molding for automobile interior materials
JP4393453B2 (en) Vehicle seat cushion
JP2011056882A (en) Method for manufacturing vacuum foam heat insulating body and core material using beads method polystyrene foam, and the vacuum foam heat insulating body by the method
KR20110000170U (en) Architectural metal panels and composite panels of aluminum and color steel
JP4336440B2 (en) Polyolefin resin composite molded body
WO2016166934A1 (en) Vacuum heat insulator, and heat-insulating container and heat-insulating wall using same
JP2008179064A (en) Molding machine for porous molding and method for manufacturing porous molding
JP2005273696A (en) Vacuum heat insulating material, heat insulation and cold insulation equipment provided with vacuum heat insulating material, and heat insulating board
KR100590224B1 (en) Method for producing polystyrene foam having excellent thermal barrier property and polystyrene foam prepared by the method
KR100818182B1 (en) Interlayer sound insulation material and manufacturing method
EP2431410A1 (en) Sunlight-resistant expanded styrene-polymerised sheets with high heat insulation value
JP5534526B2 (en) Method for producing composite molded body
JP3668871B2 (en) Tubeless tire, tubeless tire and wheel assembly, and manufacturing method thereof
JP2008033160A (en) Sound insulating material
JPH09254179A (en) Foamed synthetic resin molded object and its molding method
JPH10217413A (en) Vacuum heat insulating body, refrigerator, heat insulating panel, and manufacture of vacuum heat insulating panel

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20080208

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20100916

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20110325

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20110517

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20120106

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20120301

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20120911