JP2006198601A - Method for recycling apricot vinegar liquid and oyster shell as highly functional resource - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To recycle Japanese apricot (ume) vinegar liquid and oyster shell, which although respectively having useful substances, are serious and heavy loads on environments as they are, as highly functional resources. <P>SOLUTION: The ume vinegar liquid is an extract obtained by biochemical reaction of ume fruit and salt and on the other hand, the oyster shell is an organic compound enriched with structure water around Ca in which seawater mineral is accumulated while enclosing and growing oyster therein. Both are enriched with particular inherent components. The oyster shell is calcined at a high temperature in dry distillation manner to obtain a fine powder of quick lime. Both resources are separately jetted and mixed in a highly functional reaction tower having a long cylindrical shape and complete fusion reaction is induced in the environments of high temperature due to simultaneous exothermal chemical reactions; that is, hydroxylation reaction and acid-neutralization reaction. The reaction agent obtained thereby is separated into solid matter analogous to gypsum and a liquid agent. The solid matter is added to, for example, a raw material for marine base construction and used for contribution to oyster culture industry by seaweed propagation. Being mixed with special humus extract liquid, the liquid agent is aged and used as an acidic mineral for soil amendment. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

  The present invention relates to a method for collecting and utilizing health functional components that ume vinegar and oyster shells, which have been turned into industrial resources, are born and used to regenerate them as functional resources.

Plum is widely produced worldwide and has been used habitually as a health food deeply related to human life. In particular, processing technology is advancing as a premise for utilization suitable for Japanese food.
Healthy food: Ume-Noriko Nakagawa (Agricultural Bunko 1986)

The oyster shells of marine organisms have long been prized for their environmental functionality that emits far-infrared rays by using the calcined ash as an additive material. It is assumed that the composition is very complicated and contains carion, karionite, halloysite, datekite, hydrated halosite, nacrite, etc. common to white porcelain (carion ceramics) raw material clay.

Oyster shells fired at a high temperature (1,200 ° C) become quick lime CaO qualities, and a compound obtained by adding water to a plurality of extenders and plum vinegar react to react with each other to undergo hydroxylation reaction and acid neutralization reaction for ionization. The structure (gypsum analogue) that promotes and promotes the hydration reaction to enhance environmental functionality.
Manufacture of environmental functional regeneration structure-Japanese Patent Application No. 2004-163851

Quick lime crystals that have been used for a long time can be obtained by baking limestone at 1,000 ° C. Oyster shell quicklime does not crystallize even if it is said to have been fired at 1,200 ° C. and has a low hygroscopic property.
It can be said that the use example in the previous section is also easy to use, and the reaction power is felt weak at 1,000 ° C. baking. Considering that the oyster shell is an organic substance, I think that it is due to the large dissociation energy. The combustion heat per mol of sucrose (solid) C ₁₂ H ₂₂ O ₁₁ is 1,351.29 kilocalories, Compared to 9,406 kilocalories per mole of other carbon (graphite, solid) C and 530.58 kilocalories per mole of C ₃ H ₈ of propane (gas) (Why chemical reactions occur) -I was able to advance to new thinking because I was taught that the dissociation energy was correspondingly large by the teaching of Kagehei Ueno (1993).
Carbonization of wood, which is a complex organism, overcomes the dissociative energy endotherm that presupposes it. Carbonization by dry distillation gasification is far easier than conventional carbonization by pyrolysis. There is also an experience of an event that facilitates the gasification of organisms due to the synergistic effect of the action and the self-medium action of the superheated steam atmosphere, so it is certain that quick calcification of oyster shells will reduce time and cost by applying the principle I can do it. For that purpose, the heat generated by dry gas combustion is also an essential factor, so the basic technology is also presented.
High efficiency heat exchange combustion system-Japanese Patent Application No. 3030321 Self-burning plant material far-infrared carbonization device-Japanese Patent Application No. 2004-90516

Organic substances have become strong crystals as a result of complex biosynthesis, and a large amount of dissociation energy is required to solve them. However, there are methods such as catalysis, fermentation, and heating. If you borrow the power of heat rays such as far-infrared rays, radiant heat rays, and negative ions that react with heat, heat waves, and light waves, the efficiency will be greatly improved. High-performance ceramics and furnace walls that respond to heat are required and used. As an example
Method for producing functional ceramics-Japanese Patent Application 2005-

Plum pickles have excellent food functionality and are distributed in large quantities, and a large amount of liquid remains in their processing. They have a high salt content, high acidity, and strong pigments. On the other hand, oyster shells are a hard substance several times as large as the contents, and a burden is required for disposal. However, as in the background art, the potential value of using any of them is certainly high. It is all about the construction of technology that makes it possible to extract it, how much it can be processed in large quantities, low in cost, and can be converted into resources with high added value.
The present inventors aim to achieve this by combining multiple technologies for the theme of converting to low-cost, high-value-added materials by utilizing the technologies accumulated up to now. It is a combination of the basic characteristics possessed and technology that utilizes the meaning of chemical reactions taught by natural phenomena.

The present inventors focused on which of the chemical reactions taught by the natural phenomenon that can be used under the above-mentioned goals.
The center of the method of the present invention is a hydroxylation reaction in which quick lime CaO reacts with water and a neutralization reaction with acid, and the speed of the reaction is instantaneous and accompanied by explosive heat generation.
Plum vinegar is a product of a slow reaction between plum fruit and a plurality of organic acids with salt as the core, and its composition is complex, requiring large dissociation energy to separate them.
Oyster shells are organically grown layers with physical properties that do not crystallize even when fired at 1,200 ° C., but organic matter containing structural water centered on strong crystalline CaCO ₃ enriched in sea minerals Thus, in order to separate CO ₂ or the like, there is an endothermic reaction that requires a large dissociation energy to become quick lime CaO, and when it reacts with water, it becomes CaO + 2H ₂ OCA (OH) _2, and there is an energy cycle accompanied by intense heat generation.
Based on the above, we start with quick calcification of oyster shells.

In the carbonization of organic matter (wood), the present inventors tried a dry distillation method instead of the conventional thermal decomposition (Patent Document 2), far infrared irradiation, nitrogen gas (oxygen-free) atmosphere and superheated steam atmosphere catalytic, There is an event in which a self-mechanistic synergistic environment is similar to pure carbon (94 to 98% of the pure carbon ratio in the calorific value measurement) and charcoal is obtained by greatly reducing temperature and time compared to pyrolysis.
Oyster shells are a combination of Ca, the main component, with many organic substances, and the odor of the structural water contained in them is accompanied by an event that plagues the site. According to the above, high-quality oyster shell quicklime is obtained at low cost with the device means shown in the examples.

  The reaction tower that mixes and reacts plum vinegar and oyster shell quicklime is a long cylindrical shape with a significant diameter and length, and the inner surface is equipped with a high-functional ceramics furnace wall, the bottom is a reservoir for the reactants, and the upper is weak. Equipped with a negative pressure suction vapor vent. The liquid and quicklime are based on precise analysis considerations, and the reaction equilibrium amount is set together with actual measurements, sent in separate transport pipes while being heated at a high temperature in the reactor reservoir and in the furnace, and jetted separately at the top to mix and react. Then, the reaction proceeds efficiently in a high temperature atmosphere where high heat is generated and far infrared rays are reflected from the furnace wall, the reactant falls, and water vapor is dissipated outside the furnace. The reactant stored in the bottom is taken out and separated into solid and liquid.

  To the liquid that has been separated into solid and liquid, 3% of special humic substance extract is added to increase the cleanliness by electrolysis in a multistage circulation in which a plurality of electrodes are combined. The electrode is arranged in accordance with the upper, lower and flow devices, and the (+) pole is arranged at the upstream, the (+) pole is arranged at the upstream, and the (-) pole is arranged at the downstream position. Activates the movement of electrons in a miniaturized environment.

  Gypsum-quality solids and electrolyzed cleaning fluids are each examined for the components they contain, and the solids meet demand for functional structures by dry sintering or the like. Purified liquid preparations meet demand for mineral materials.

一方のカキ殻も食品機能性の秀れたカキを包み育てた殻なので、それを生石灰化したものと梅酢酸との化学反応生成物は本来の特性を失っていないと確信される。最終的浄化液も添加した特殊腐植物質の抽出液（フルボ酸類）の機能も加わった酸性ミネラル液に進化すること信じられるが故に、廃棄物処理の発想はなく、あくまで機能性資源として再生するための化学反応を利用し、その面を強化する方策を極める。In general, plum vinegar is an extract of typical food functionality that contains citric acid and picric acid, which are the elements of sourness, and has the effect of suppressing the production of lactic acid in the body by citric acid (crepes) cycle function and picric acid. It works in a variety of ways to recover fatigue, such as enhancing liver function. The figure below shows how food is digested in the body, which teaches the grounds that umeboshi helps to relieve fatigue.

On the other hand, oyster shells are shells that wrap and grow oysters with excellent food functionality, so it is believed that the chemical reaction product of lime acetic acid and ume acetic acid has not lost its original characteristics. Because it is believed that it evolves into an acidic mineral liquid that also has the function of a special humic substance extract (fulvic acid) with the addition of a final purification solution, there is no idea of waste treatment, and it is to be regenerated as a functional resource only Measures to strengthen the aspect of the chemical reaction.

  As stated in the previous section, the technical concept of this application that approaches the target through chemical reaction is a reasonable consequence from the dimension of trying to make the best use of the characteristics produced by these materials as both industrial waste. By-product resources that have become environmental burdens in the production areas of plums and oysters nationwide are literally treasures according to the present invention. It is also one accumulation of resource utilization accumulated by teaching the natural phenomenon at the production site of the present inventor. The effect is not small.

Best Mode for Carrying Out the Invention

  The approach dimension of the present invention lies in the recognition that ingredients that have been superior in food functionality of plum fruit and oysters are inherited by processing reaction liquids and shells. Plum seeds have cyanide (amygdalin) as a self-defense function at the top of growth, but there is a biochemical reaction that evolves into a component called functionality in fermentation mediated by salt, and the oyster shell protects the soft body This is a product as a ca-centered biochemical reaction that grows in layers. Oyster shells are dissociated with high heat and become unstable lime, while the organic oxidization mixture centering on sodium chloride, a strong conjugate, is too stable. It is the reaction tower that gives a place where the material of the extremely distant nature has a catalytic function such as far-infrared rays and generates high heat to become a self-supporting environment. The ending of the drama that both substances unfold in the reaction tower cannot be affirmed unless they are scrutinized, but it will be an event that provides brightness to the current environmentally polluted society. For this purpose, organic compatibility cooperation between the two production areas that are in a remote relationship is required.

  This will be described below with reference to the drawings.

FIG.

Longitudinal view of equipment for firing oyster shells at high temperature, including waste heat treatment equipment

FIG.

1 is a cross-sectional view of the firing furnace of the apparatus.

FIG.

It is a longitudinal section of the mixing reaction tower of ume acetic acid and oyster shell quicklime

FIG.

It is a longitudinal bird's-eye view of an electrolysis device

  1 is a firing furnace, 2- is a hearth thereof, and 3- is a ceiling wall. 4- is a raw material supply apparatus, 5- is a fired material carrying-out screw, 7- is a gas burner. 8- is a heat exchange device for exhaust gas, which is connected by an exhaust pipe 6-. Reference numeral 9 denotes an exhaust gas passage pipe, which is sucked into the 10-chimney. Reference numeral 11 denotes a heat exchange water tank. Water is supplied from a 12-caskate pump, and steam is ejected from a steam port 11'-. The 13-reaction tower has 14 furnace walls and a 13'-reactant outlet. 17- is a supply device of ume acetic acid, 18- is a oyster shell quicklime powder supply device, and is ejected at 17'- and 18'-. Reference numeral 13 'denotes a reactant outlet, which is taken out and separated into individual pieces, and is processed by changing a plurality of electrodes in a plurality of 19 electrolysis tanks.

An operation based on the above configuration will be described.
The stored oyster shell material that has been appropriately crushed and purged of air with nitrogen gas is supplied from 4-. When the 7-gas burner is ignited, the material is dry-distilled, and the combustible portion of the dry-distilled gas is also counter-flow burned, and the upper part of the ceiling becomes a gas layer and is sucked downward to a progressively high temperature. Far infrared rays are radiated from the furnace wall in response to heat, oxygen free, superheated steam catalyst, autogenous functional atmosphere is maintained, and the material flowing through the hearth layer is efficiently dry-distilled into cao and sintered The finished product is taken out with a 5-screen.

6- Combustion gas that has passed through the exhaust pipe is heated by a honeycomb (combustion gas reburning device-Honda Motor Co., Ltd.) at the outlet, passes through 9-smoke tube of 8 heat exchange device, and 12-caskate pump 11 tank water supplied with water is heated. Aquarium water becomes steam and spouts from 11 '.
The steam pressure ejected from 11 'depends on the scale of the 1-firing furnace, but if it becomes large, the amount of heat increases, and the use is expanded to power generation by another Japanese Patent Application No. 2004-209241.
Since the oyster shell material contains salt, it is heated at high temperature and dioxins may be generated. Therefore, the formation temperature (800 ° C) is avoided by the high temperature by the honeycomb, and the final exhaust is absorbed by the venturi scrubber mechanism by water. Take measures to cool rapidly and prevent recrystallization.

  The sintered quicklime is pulverized and supplied from the reaction tower 18 and ejected from 18 '. On the other hand, ume acetic acid is pumped by 17 supply devices, ejected from 17 ', mixed with quick lime, and efficiently produces a high heat by simultaneously proceeding hydroxylation reaction and acid neutralization reaction. Since the reaction tower is equipped with a high-functional ceramics furnace wall on the inner wall, a high-heat atmosphere to which far-infrared radiation is also applied is maintained, the reaction is completely completed, and it is taken out from 13 'and separated into solid and liquid.

  The separated liquid agent is electrolyzed in a multistage water tank. The electrode moves up, down, or flows, and at the downstream position, a (+) electrode is installed at the lower stage or upstream, and a (-) electrode is installed at the upper stage or downstream. For the electrode in the first stage water tank, copper having high conductivity is used for (+), and a carbon rod having low conductivity is used for the (−) electrode. The (−) electrodes in the second and lower stages are significantly replaced, and finally titanium oxide is used. Needless to say, the relative amperage and voltage need to be carefully adjusted.

Plum processing residue and oyster shells are becoming more difficult waste than ever before, and the social monitoring of the processing is severe and the economic burden is being imposed.
However, both plum vinegar and oyster shells are excellent food functional ingredients, and plum vinegar is a fermented extract of plum fruit, while one oyster shell wraps oysters grown with marine minerals and grows a layer of calcium accumulated biochemical compounds. It is.
The inventors of the present application are enthusiastic about the origin characteristics of both substances and believe that they are still in use, and look at the characteristics of oyster shell quicklime, which is one of the means. Aiming at regeneration by a high-performance reaction tower utilizing the exothermic phenomenon of hydroxylation reaction and acid neutralization reaction woven with fermented extract.
We knew the function held by both in the utilization process in (0004) and the like, and came to the idea of the present application by knowing the actual state of the extraordinary chemical reaction of carbonization of biomass in (0005).

The reaction product is no longer an industrial waste resource but a treasure resource. The gypsum-based solidified material becomes a part of the material for the foundation of seagrass, which is a nutrient source for oysters, for example, and contributes to the fishery industry by purifying and hatching the seawater environment through the growth of seagrass. The separated liquid becomes an acidic mineral by adding and ripening 3% of the Marinex extract, for example, and can be a savior that saves soil deterioration caused by Mampa disease, which is one of the causes of deterioration of the vigor in the cultivation field of plums. Both are the regeneration of valuable resources that hold special functions.
It becomes a way to return to society the accumulation of technology supported by the teaching of natural phenomena of the inventors, etc., and environmental load resources scattered throughout the country are regenerated into special functional resources by cooperation of each production area. A recycling industry that contributes to the promotion of the industry by returning to the place of origin is established.

Exhaust heat treatment is included in a longitudinal view of an apparatus for firing oyster shells at high temperature. Fig. 1 Cross section of firing furnace Longitudinal view of the mixing reactor of plum vinegar and oyster shell quicklime Electrolytic device longitudinal view

Explanation of symbols

1-firing furnace, 2-furnace floor, 3-ceiling wall, 4-material supply device, 5-fired material take-out screw, 6-exhaust pipe, 7-gas burner, 8-exhaust heat exchanger, 9-exhaust passage Tube, 10-chimney, 11-heat exchange water tank, 11'-steam port, 12-cascade pump, 13-reaction tower, 13'-reactant outlet, 14-furnace wall, 17-plum vinegar supply device, 17 ' -Injection port, 18-Oyster shell green compact powder supply device, 18 '-Injection port, 19-Electrolysis tank

Claims (5)

  Plum pickled processing residue (hereinafter referred to as plum vinegar) and marine organism oyster shell (hereinafter referred to as oyster shell), which is calcined at high temperature, are jetted and mixed in a high-performance reaction tower to produce hydroxylation reaction and organic acid neutralization reaction. In the course of the chemical reaction, the organic solids are separated by agglomeration and precipitation and acid neutralization, and purified by an electrolysis apparatus with a new mechanism while circulating the supernatant liquid in multiple stages. Plum vinegar is an extract produced by fermentation, which is a biochemical reaction in which a specific component of plum is salted, and oyster shell retains significant results grown in the sea by mineral-enriched bionutrition. Therefore, in the reaction tower, the catalytic function in the reaction tower due to the exothermic heat of both reactions is increased to lower the activation energy hills of both objects, and dissociation energy is added to provide new functionality by biochemical fusion reaction. A method for regenerating ume vinegar and oyster shells into highly functional resources, characterized in that the structure of the mechanism evolves into a substance having the same.   The apparatus for firing the oyster shell at high temperature according to claim 1 is a slanting furnace comprising a flat hearth and a near semicircular ceiling wall, and having a significant angle and length through which the material naturally flows down. And provide a strong suction function port at the lower ceiling wall edge. A material supply port is provided at the top, and a plurality of gas burner heat source ports are provided at the top of the ceiling wall. The combustion flame directed upwards is sucked downward to cause a counter-flow combustion reaction so that the material and the combustion gas flow are parallel. The gas flow flame that flows through the upper ceiling of the combustion furnace with the combustible part of the combustion chamber is heated from the heated furnace wall by a mechanism that becomes a self-supporting environment of progressively hot oxygen-free and superheated steam atmosphere as it goes down. The far-infrared radiant heat rays that are set are radiated and reflected, and the material flowing down the furnace hearth layer is heated by radiation from the ceiling wall, gas flow heat, and conduction heat from the hearth. The method for regenerating ume vinegar and oyster shells into high-functional resources according to claim 1, characterized in that the functional structure is obtained by calcining in a dry state and releasing carbon dioxide or the like to lead to quick calcification. The reaction tower of claim 1 has a long cylindrical shape with a significant diameter and length, is equipped with a highly functional ceramic furnace wall on the inner wall, a weak negative pressure suction vapor diffusion port is provided at the top, and a reactant is provided at the bottom. A take-out device is provided, and solid-liquid separation is carried out after take-out.
Plum vinegar and oyster shell quicklime are heated by the temperature of the reactor as well as the reactants, each of which contains scientifically measured and measured equilibrium amounts, which are set to high temperatures in separate transport pipes from the bottom. The method for regenerating ume vinegar and oyster shells into highly functional resources according to claim 1, wherein the functional structure is such that it is mixed in a jet diffusion state at the upper position and undergoes a fusion reaction.   In the electrolysis apparatus according to claim 1, the combination order of two or more types of electrodes arranged in the vertical or liquid flow is (+) → (−), and a special humic substance extract equivalent to 3% is added to the liquid. The method for regenerating ume vinegar and oyster shells into high-functional resources according to claim 1, wherein the function of fulvic acid is enhanced to activate electronic activity.   The reaction product of claim 1 is subjected to solid-liquid separation. The stock solution is a further fermented product of plum fruit that is well-established for its biosynthesized food functionality, while the other is a by-product of primary marine products. The method for regenerating ume vinegar and oyster shells into functional resources according to claim 1, wherein the mechanism is a means for stacking means for collecting the causative substance as health functionality after the means of the previous item.

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