JP2006169378A - Cleaning fluid - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a new liquid agent for cleaning, requiring entirely no operation for washing away, and thereby suitable for an operation for removing secretion product of a pet, and an operation for removing a dead body of an insect, excrements of a bird, etc., attached to a car body or the like. <P>SOLUTION: The liquid agent for cleaning contains an ionized alkaline water having pH≥8.0 and ≤13.0, containing silicon, and formed at the cathode side when a raw water containing the silicon-containing material dissolved therein is subjected to electrolysis. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

  The present invention relates to a wiping solution used for removing pet secretions or removing dead carcasses or bird droppings adhered to a vehicle body or a window glass of a house.

  For example, Patent Documents 1 to 4 are conventional examples of this type of wiping liquid. The wiping solution according to Patent Document 1 is composed of an amphoteric surfactant and a tea leaf extract. The wiping solution according to Patent Document 2 is obtained by blending collagen and chitosan with a surfactant. The wiping solution according to Patent Document 3 is obtained by blending a cereal hot water extract with a cationic surfactant, an amphoteric surfactant, and a nonionic surfactant. The wiping solution according to Patent Document 4 contains silicone oil in an amphoteric surfactant and a nonionic surfactant. By using the wiping solution described in each of these patent documents, various secretions from pets, carcasses of insects adhering to the vehicle body, bird droppings, etc. are removed well by the proteolytic action derived from the surfactant. It is expected to be possible.

Japanese Patent Laid-Open No. 4-17857 JP-A-8-99865 JP-A-8-175905 JP 2002-47105 A

  Since the problem with the wiping solution described in each of Patent Documents 1 to 4 described above is that the surfactant is an essential constituent, the surfactant using water or the like after the removal operation using the wiping solution. Therefore, it is indispensable to carry out the washing-off work, which is troublesome and has poor practical convenience. That is, after the removal work for the adhering secretions on the pet's oral cavity, nostril, ear (especially the inner ear) and the anus, etc., the detergent is washed off with water or the like. It was very cumbersome and difficult to do. In addition, although it is a pet, it is a safety problem to leave the surfactant attached to the oral cavity or the like as it is. Furthermore, it can be said that this is very useful in terms of practical convenience if the wiping work for dead insects or bird droppings attached to the vehicle body or the like can be carried out without requiring washing work.

  The present invention has been made in order to solve the above-described problems, and its purpose is to eliminate the need for a washing-off operation. Therefore, the removal work of pet secretions or the dead carcasses adhering to the vehicle body etc. Another object of the present invention is to provide a novel wiping solution that is suitable for use in the removal work of birds and bird droppings.

  The present invention is a wiping solution used for removing pet secretions or removing dead carcasses, bird droppings, etc. adhering to a vehicle body or a window glass of a house. The wiping solution is produced on the cathode side when the raw material water in which the silicon-containing material is dissolved is generated on the cathode side, and contains a silicon body having a pH of 8.0 or more and 13.0 or less. It is characterized by containing alkali ion water.

  The term “pet secretion” as used herein means various waste products such as sweat, cortex, earwax, eye grease, manure, and dandruff produced by pets such as dogs and cats. “Car body and the like” particularly mean a car windshield, a bonnet, and the like. However, it is needless to say that the wiping target of the wiping liquid according to the present invention is not limited to the vehicle body or the window glass of the house. It depends.

  Examples of the raw water in the present invention include mineral water and mineral water. In addition to purified water, distilled water and tap water, ordinary water of the Japanese Pharmacy Law may be used. An auxiliary electrolyte such as sodium chloride or natural sea salt can be added to these raw waters for the purpose of improving conductivity. When natural sea salt is added, the improvement of the mineral characteristics derived from the mineral content contained therein can be expected. Various plant extracts such as assembly extract, chili pepper tincture, ginger tincture, cephalanthin, glandic acid, carrot extract, and cashew extract may be added to the raw water.

  The electrolysis treatment method in the present invention can be carried out, for example, using a household alkaline ion water conditioner or a general industrial electrolyzed water production machine approved in 1965. It does not matter whether the method of this electrolysis treatment is a batch type or a continuous type. Various electrolytic treatment conditions such as an electrolytic voltage value are not limited. However, alkaline ionized water exhibiting strong alkalinity can be obtained by repeating the electrolysis treatment a plurality of times.

Examples of the silicon-containing material herein include so-called clay minerals such as talc, mica, and kaolin, and natural substances derived from living organisms such as coral and shells. The composition of talc is represented by hydrous magnesium silicate (Mg ₃ Si ₄ O ₁₀ (OH) ₂ ), and usually forms a dense lump of fine crystals or an aggregate lump of leafy coarse crystals. Mica is muscovite that belongs to potash mica, which has many types of components, and its chemical formula is generally expressed as KAl ₂ (Si ₃ Al) O ₁₀ (OH) ₂ . Kaolin is a contained aluminum silicate (Al ₂ SiO ₅ (OH) ₄ ), and those with high crystallinity show regular hexagonal shapes, while those with low crystallinity have fine irregular plate shapes. Since shellfish, shells, and the like also contain silicon, they can be applied as the silicon-containing material in the present invention, and these are finely pulverized and then dissolved in raw water.

  When the raw material water in which the silicon-containing material is dissolved is subjected to an electrolysis treatment while separating the cathode and the anode with a porous film, hydroxide ions and hydrogen are formed on the cathode side by the water reduction reaction. appear. Mineral components (cations) contained in water are attracted to the cathode side. Part of the silicon body-containing material becomes ionic silica and is drawn to the cathode side. When a plant extract is blended, the cation component is attracted to the cathode side. The supernatant obtained by static precipitation of the liquid component on the cathode side is the silicon body-containing alkaline ionized water in the present invention.

  Alkaline ion water obtained by the above electrolysis treatment has a pH value of about 9 to 11 although there is a difference depending on electrolysis conditions. In addition, by repeating the electrolysis treatment a plurality of times, strongly alkaline ionic water having a pH value of 11 or more can be obtained.

  The total amount of silicon contained in the alkaline ionized water obtained as described above is about 300 mg / L when the pH value is 13. Here, the total amount of silicon body means a value measured according to the column of total silica of JIS K 0101. Specifically, after all silica in water is changed to ionic form, molybdenum yellow absorptiometry, molybdenum Measured by blue absorptiometry or gravimetric method. In addition, the total amount of silicon body may be obtained by adding the total amount of dissolved and colloidal silica and the total amount of ionic silica. Here, dissolved and colloidal silica refers to silica contained in the filtrate when the sample is filtered, and the total amount is obtained after filtering the sample, adding sodium hydrogen carbonate, and boiling to make the silica ionic. It can be determined quantitatively by molybdenum yellow absorptiometry or molybdenum blue absorptiometry.

  Ionic silica refers to silica that reacts with hexaammonium heptamolybdate to produce a heteropoly compound yellow, and the total amount can be determined from the yellow absorbance of the heteropoly compound. In the alkaline ionized water in the present invention, when the pH value is about 13, ionic silica of about 100 mg / L is present.

  These wiping solutions can contain a moisturizing agent in addition to the alkali ion water. The moisturizing agent is particularly suitable for blending in a wiping solution for removing pet secretions. Specific examples of such a humectant include, for example, polyethylene glycol, polypropylene glycol, 1,3-butylene glycol, glycerin, dipropylene glycol, carboxyl vinyl polymer, xanthan gum, glycoside trehalose, and the like, which are particularly stable in the alkaline region. Xantham gum and glycoside trehalose are preferred.

  Furthermore, alcohol can be mix | blended with the liquid for wiping which concerns on this invention. According to this, the bactericidal and disinfecting action of alcohol is exerted in the state where the cell walls of bacteria existing on the skin are dissolved by the reducing action of alkaline ionized water, so that alcohol alone cannot be killed until now. There is also an advantage that a good sterilizing action can be obtained against spores. A refreshing feeling can also be improved. The said effect is exhibited well, when the said liquid agent is applied as a wiping liquid agent for the removal work of a pet secretion. In addition, the present inventors have confirmed through experiments that the deterioration of the pH value over time can be well suppressed by blending alcohol.

  The wiping solution according to the present invention can be sold and used in a form impregnated with gauze, absorbent cotton, nonwoven fabric or the like. That is, it can be offered for sale in the form of a wet tissue. In addition, when the wiping solution according to the present invention is used as a cleaner for removing dead carcasses or bird droppings attached to a vehicle body or the like, the solution can be stored in a plastic container or a glass container. . You may store in a spray can.

  The wiping solution mainly composed of silicon-containing alkaline ionized water according to the present invention has excellent safety without damaging the skin of users and pets, and is excellent for secretions, carcasses of insects, etc. Demonstrates cleaning action. More specifically, such alkaline ionized water has no effect on the skin cells of the pet or the user's hand, and various secretions produced by the pet (sweat, cortex, ear wax, eye grease, manure, dandruff, etc. It has an excellent cleaning action that satisfactorily reacts and dissolves only oxidatively altered protein components and oxidatively altered fats and oils components such as waste products of In addition, it has an excellent cleaning action that does not affect the skin cells of the user's hand, etc., the car body or the window glass, and reacts and dissolves only the oxidized and denatured protein components such as dead insects and bird droppings. ing. Above all, the wiping solution according to the present invention does not contain any surfactant and is mainly composed of “water”, and is therefore practical in that it does not require the washing off of the surfactant after the removing operation. Excellent for convenience. Moreover, this alkaline ionized water is excellent in that the pH value hardly deteriorates with time and exhibits a stable effect over a long period of time. Thus, the silicon body-containing alkaline ionized water according to the present invention is used for removing pet secretions, or for removing insect carcasses and bird droppings adhered to the vehicle body, window glass, etc. It can be suitably used as a liquid preparation.

  The reason why the silicon-containing alkaline ionized water of the present invention exhibits such excellent cleaning action is not clear. As the inference of the present inventor, a large amount of hydroxide ions contained in alkaline ionized water reacts with dirt composed of oxidatively altered protein components such as secretions and carcasses of insects, and oxidatively altered oil and fat components. Think of it as being able to float dirt.

It is considered that the pH value is stable over a long period of time for the following reason. That is, H ⁺ ions generated around the cathode attach to the outer shell of oxygen molecules of water molecules (H ₂ O) to form stable hydronium ions (H ₃ O ⁺ ), which are strong against silicic acid. by being held in the coexistence to that OH ^- ions are stabilized, resulting considered it is due to be difficult deteriorated even at very high pH values.

  In the present invention, it is preferable that the pH value of silicon-containing alkaline ionized water is in the range of 8.0 or more and 13.0 or less. In order to obtain an alkaline ionized water that exceeds pH 13 because it becomes extremely poor and cannot be used as a wiping solution, electrolysis must be repeated many times, resulting in an increase in the manufacturing cost of the wiping solution. Is to invite. In view of the degradation action on proteins and the like, a more suitable pH value is preferably in the range of 10 or more (13 or less), more preferably in the range of 11 or more (13 or less).

  When moisturizing agent is added to the wiping liquid, it can give a moist feeling to the wiped area, so it is suitable when the liquid is applied as a wiping liquid for removing pet secretions. It is.

(Eye irritation test: safety confirmation test)
First, in order to confirm the safety of alkaline ionized water constituting the wiping solution according to the present invention, the following eye irritation test was performed. The test was conducted by requesting the Japan Food Analysis Center.

  In addition to the clay mineral as a silicon body-containing material, natural sea salt was dissolved in mineral water and subjected to electrolysis multiple times to obtain a silicon body-containing alkaline ionized water having a pH of 12.5. Using such alkaline ionized water, an eye irritation test (based on OECD Guidelines for the Testing of Chemicals 405) was performed on rabbits.

  Specifically, 0.1 ml of silicon body-containing alkaline ionized water was instilled into one eye of a rabbit, and the cornea, iris, conjunctiva, etc. were observed after 1, 24, 48, and 72 hours after instillation. As a result, no abnormality was observed in the eyes of the rabbit, and therefore it was confirmed that the alkaline ionized water had no safety problem.

Example 1
In Example 1, the wiping solution of the present invention is applied to the ear wiping solution for removing the ear wax adhering to the pet's ear. First, in addition to clay mineral as a silicon body-containing material, natural sea salt was dissolved in mineral water, and subjected to electrolysis multiple times to obtain a silicon body-containing alkaline ionized water having a pH of 8.0. . Next, ethanol is blended into the silicon-containing alkaline ionized water at a ratio of 90.0% by weight (alkaline ionized water): 10% by weight (ethanol), and this is used as an ear wiping solution (pH 8.0). did.

  Using the gauze impregnated with the ear wiping solution, the ear wax removal work (wiping work) of the rabbit was performed. As a result, it was confirmed that the earwax was successfully removed and that no abnormality was observed in the rabbit ears. It was also confirmed that no abnormalities were found in the human fingers that had been removed.

(Example 2)
In Example 2, the wiping solution of the present invention is applied to a tear-burning wiping solution for removing the tear burn that has adhered to the eyes of the pet. The term “tears burnt” as used herein means a product in which eye grease is hardened.

  First, in addition to clay mineral as a silicon body-containing material, natural sea salt is dissolved in mineral water and subjected to electrolysis multiple times to obtain a silicon body-containing alkaline ionized water having a pH of 12.5. This was used as a tear burner wiping solution (pH 12.5).

  Using the gauze impregnated with the tear-burning wiping solution, a removal work (wiping work) against the tear-burn adhering around the eyes of the rabbit was performed. As a result, it was confirmed that tear burn could be removed satisfactorily and that no abnormality was seen in the rabbit eye and the surrounding skin. It was also confirmed that no abnormalities were found in the human fingers that had been removed.

(Example 3)
In this Example 3, the wiping liquid of the present invention is applied to a wiping wiping liquid for removing feces and urine adhering to the vicinity of the anus of the pet. First, in addition to clay mineral as a silicon body-containing material, natural sea salt was dissolved in mineral water, and subjected to electrolysis multiple times to obtain a silicon body-containing alkaline ionized water having a pH of 12.5. . Subsequently, purified water is blended in such a silicon body-containing alkaline ionized water at a ratio of 90.0% by weight (alkaline ionized water): 10% by weight (purified water), and the resulting solution is then wiped with a wiping solution (pH 11.1). ).

  Using the gauze impregnated with the wiping solution, the removal work (wiping work) of feces and urine adhering to the vicinity of the anus of the rabbit was performed. As a result, it was confirmed that feces and urine could be removed satisfactorily and that no abnormality was observed near the anus of the rabbit. It was also confirmed that no abnormalities were found in the human fingers that had been removed.

Example 4
In Example 4, the wiping solution according to the present invention is applied to a wiping solution for removing feces and urine adhering to the vicinity of the pet's anus. In addition to the clay mineral as a silicon body-containing material, natural sea salt was dissolved in mineral water and subjected to electrolysis multiple times to obtain a silicon body-containing alkaline ionized water having a pH of 12.5. Subsequently, a moisturizing agent (xantham gum) and purified water are added to the silicon-containing alkaline ionized water at 50.0% by weight (alkaline ionized water): 0.2% by weight (humectant), 49.8% by weight (purified). This was formulated as a wiping solution.

  Using the gauze impregnated with the wiping solution, the removal work (wiping work) of feces and urine adhering to the vicinity of the anus of the rabbit was performed. As a result, it was confirmed that feces and urine could be removed satisfactorily and that no abnormality was observed near the anus of the rabbit. It was also confirmed that no abnormalities were found in the human fingers that had been removed.

(Example 5)
In Example 5, the wiping solution of the present invention is applied to a cleaner for removing carcasses of insects adhering to the windshield of a car. First, in addition to clay mineral as a silicon body-containing material, natural sea salt is dissolved in mineral water and subjected to electrolysis multiple times to obtain a silicon body-containing alkaline ionized water having a pH of 12.5. This was used as a vehicle body cleaner (pH 12.5).

  Using the gauze impregnated with the cleaner, removal work (wiping work) was performed on the dead carcass adhering to the windshield of the car. As a result, it was confirmed that the dead carcasses of insects could be removed and that no abnormalities were found in the human fingers that had been removed.

(Example 6)
In Example 6, the wiping solution of the present invention is applied to a cleaner for removing carcasses of insects adhering to the windshield of a car. First, in addition to clay mineral as a silicon body-containing material, natural sea salt was dissolved in mineral water, and subjected to electrolysis multiple times to obtain silicon body-containing alkaline ionized water having a pH of 12.2. . Next, ethanol was blended into the silicon-containing alkaline ionized water at a ratio of 90.0% by weight (alkaline ionized water): 10.0% by weight (ethanol), and this was used as a cleaner (pH 12.2). .

  Using the gauze impregnated with the cleaner, removal work (wiping work) was performed on the dead carcass adhering to the windshield of the car. As a result, it was confirmed that the dead carcasses of insects could be removed and that no abnormalities were found in the human fingers that had been removed.

Claims (2)

A wiping solution used for removing pet secretions, or for removing dead carcasses or bird droppings attached to the body or window glass of a house,
Silicon body-containing alkaline ionized water having a pH of 8.0 or more and 13.0 or less, which is generated on the cathode side when the wiping liquid is subjected to electrolysis treatment on the raw material water in which the silicon-containing material is dissolved A wiping solution characterized by comprising   The wiping solution according to claim 1, wherein a humectant is blended in the alkaline ionized water.