JP2006160708A - Multilayer-type hair cosmetic - Google Patents
Multilayer-type hair cosmetic Download PDFInfo
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- JP2006160708A JP2006160708A JP2004358261A JP2004358261A JP2006160708A JP 2006160708 A JP2006160708 A JP 2006160708A JP 2004358261 A JP2004358261 A JP 2004358261A JP 2004358261 A JP2004358261 A JP 2004358261A JP 2006160708 A JP2006160708 A JP 2006160708A
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- 210000004209 hair Anatomy 0.000 title claims abstract description 53
- 239000002537 cosmetic Substances 0.000 title claims abstract description 38
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 22
- 150000001413 amino acids Chemical class 0.000 claims abstract description 16
- 239000004475 Arginine Substances 0.000 claims abstract description 8
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- 239000000203 mixture Substances 0.000 claims description 24
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- BTFJIXJJCSYFAL-UHFFFAOYSA-N arachidyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 description 1
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- Cosmetics (AREA)
Abstract
Description
本発明は、毛髪化粧料に関する。詳しくは特定のアミノ変性シリコーンと塩基性アミノ酸を含有し、多層に分離した多層型毛髪化粧料であって、毛髪に塗布した際に毛髪に十分な補修効果を付与することができ、さらに多層分離性・透明性に優れた毛髪化粧料に関する。 The present invention relates to a hair cosmetic. Specifically, it is a multi-layered hair cosmetic containing a specific amino-modified silicone and a basic amino acid and separated into multiple layers, which can give a sufficient repair effect to the hair when applied to the hair, and further separate into multiple layers. The present invention relates to a hair cosmetic composition excellent in properties and transparency.
多層型毛髪化粧料としては水層―油層からなる液―液系の２層型毛髪化粧料（例えば、特許文献１）、エタノール、炭化水素油、ジメチルポリシロキサンをそれぞれ特定量含有することを特徴とする多層型毛髪化粧料（例えば、特許文献２）などが知られている。
毛髪を乾燥や摩擦から守る毛髪保護成分としては高分子のジメチコンが汎用されており、現在では毛髪への吸着率が高いアミノ変性シリコーンがダメージ毛の補修成分として使われている。しかしアミノ変性シリコーンを多層型化粧料に配合すると、油でありながら極性基を持つアミノ変性シリコーンの作用で多層分離性が悪化し、分離後の透明性も悪くなることが問題となっていった。
High molecular weight dimethicone is widely used as a hair protecting component that protects hair from drying and friction. At present, amino-modified silicone, which has a high adsorption rate to hair, is used as a repairing component for damaged hair. However, when amino-modified silicones are blended into multilayer cosmetics, the problem is that multilayer separability deteriorates due to the action of amino-modified silicones that are oil but have polar groups, and the transparency after separation also deteriorates. .
本発明は前記事情に鑑みてなされたもので、特定のアミノ変性シリコーンと塩基性アミノ酸を含有する毛髪化粧料であって、毛髪に塗布した際、毛髪に十分な補修効果を与えることが出来、さらに振とう後の静置状態での多層分離性、各層の透明性が良好である多層型毛髪化粧料を提供することを技術的課題とする。 The present invention has been made in view of the above circumstances, is a hair cosmetic containing a specific amino-modified silicone and a basic amino acid, and when applied to the hair, can give a sufficient repair effect to the hair, Furthermore, it is a technical problem to provide a multilayer hair cosmetic composition that has a multilayer separation property in a stationary state after shaking and a transparency of each layer.
本発明者等は、前記課題を達成するために、鋭意研究を重ねた結果、（ａ）特定のアミノ変性シリコーンと、（ｂ）塩基性アミノ酸とを組み合わせて配合することにより、毛髪に十分な補修効果を与えることが出来、さらに振とう後、静置状態での多層分離性、各層の透明性が良好である多層型毛髪化粧料を提供できることを見出し、本発明を完成するに至った。 As a result of intensive research to achieve the above-mentioned problems, the present inventors have found that (a) a specific amino-modified silicone and (b) a basic amino acid are combined in combination, and the hair is sufficient for hair. The inventors have found that it is possible to provide a repairing effect, and it is possible to provide a multi-layered hair cosmetic composition having a good multi-layer separation property in a stationary state and good transparency of each layer after shaking, and the present invention has been completed.
すなわち、本発明は、（ａ）下記一般式（１）−１及び／又は（１）−２で表されるアミノ性シリコーンと、（ｂ）塩基性アミノ酸とを含有する多層型毛髪化粧料である。
（１）−２：（式（１）中、ｍ及びｎはそれぞれ正の整数で、ｍ＋ｎの平均値は４０００〜６０００であり、ｎ／ｍの平均値は０．００２〜０．０３である。）
That is, the present invention is a multilayer hair cosmetic containing (a) an amino silicone represented by the following general formula (1) -1 and / or (1) -2, and (b) a basic amino acid. is there.
(1) -2: (In formula (1), m and n are each a positive integer, the average value of m + n is 4000 to 6000, and the average value of n / m is 0.002 to 0.03. .)
また、本発明は、前記（ａ）アミノ変性シリコーンが、下記一般式（１）−２で表されるアミノプロピルジメチコンである前記多層型毛髪化粧料である。
また、本発明は、前記（ｂ）塩基性アミノ酸が、アルギニン、リジン、ヒスチジンから選ばれる１種又は２種以上である前記毛髪化粧料である。 Moreover, this invention is the said hair cosmetics whose said (b) basic amino acid is 1 type (s) or 2 or more types chosen from arginine, a lysine, and histidine.
また、本発明は、油層−水層の２層型及び／または油層−乳化層−水層からなる３層型の多層型毛髪化粧料である。 In addition, the present invention is a multi-layered hair cosmetic composition comprising an oil layer-water layer two-layer type and / or an oil layer-emulsified layer-water layer.
以下、本発明の構成について詳述する。 Hereinafter, the configuration of the present invention will be described in detail.
本発明に用いる成分（ａ）のアミノ変性シリコーンは、下記一般式（１）−１及び／又は（１）−２で表されるものを使用することができる。
（１）−２：（式（１）中、ｍ及びｎはそれぞれ正の整数で、ｍ＋ｎの平均値は４０００〜６０００であり、ｎ／ｍの平均値は０．００２〜０．０３である。）
上記アミノ変性シリコーンを配合することにより、毛髪に十分な補修効果を与えることが出来る。
As the amino-modified silicone of component (a) used in the present invention, those represented by the following general formula (1) -1 and / or (1) -2 can be used.
(1) -2: (In formula (1), m and n are each a positive integer, the average value of m + n is 4000 to 6000, and the average value of n / m is 0.002 to 0.03. .)
By blending the amino-modified silicone, a sufficient repair effect can be given to the hair.
中でも、後者の一般式（１）−２で表される（式（１）中、ｍ及びｎはそれぞれ正の整数で、ｍ＋ｎの平均値は４０００〜６０００であり、ｎ／ｍの平均値は０．００２〜０．０３である。）であるアミノ変性率の高いアミノプロピルジメチコンを配合することによって、より毛髪への吸着度が高まり、高い毛髪補修効果を得る事が出来る。 Especially, it is represented by the latter general formula (1) -2 (in formula (1), m and n are each a positive integer, the average value of m + n is 4000 to 6000, and the average value of n / m is By blending aminopropyl dimethicone having a high amino modification rate, which is 0.002 to 0.03), the degree of adsorption to hair is further increased, and a high hair repair effect can be obtained.
本発明に用いる前記成分（ａ）の市販品としては、ＡＰＳ−１０−ＤＭＳ、ＡＰＳ−２０−ＤＭＳ（信越化学工業社製）等が上げられる。特にこのましいアミノ変性率の高いアミノプロピルジメチコンとしては、前記一般式（１）において、ｍ＋ｎの平均値が約５０００であり、ｎ／ｍの平均値が約０．００５であるもの等が挙げられる。 As a commercial item of the said component (a) used for this invention, APS-10-DMS, APS-20-DMS (made by Shin-Etsu Chemical Co., Ltd.), etc. are raised. Particularly preferable aminopropyl dimethicone having a high amino modification rate includes those having an average value of m + n of about 5000 and an average value of n / m of about 0.005 in the general formula (1). It is done.
本発明の毛髪化粧料において、前記成分（ａ）は、該化粧料全量に対して０．０００１〜５．０質量％配合することが好ましく、より好ましくは０．００１〜１．０質量％である。０．０００１質量％以下では毛髪に充分な補修効果が得られず、また、５．０質量％を超えて配合すると、外観の分離性および各層の透明性が塩基性アミノ酸でも改善しにくくなる等の点で好ましくない。 In the hair cosmetic composition of the present invention, the component (a) is preferably added in an amount of 0.0001 to 5.0 mass%, more preferably 0.001 to 1.0 mass%, based on the total amount of the cosmetic composition. is there. If it is 0.0001% by mass or less, a sufficient repair effect cannot be obtained on the hair, and if it exceeds 5.0% by mass, the separation of appearance and the transparency of each layer are difficult to improve even with basic amino acids. This is not preferable.
本発明に用いる成分（ｂ）の塩基性アミノ酸としては特に限定されないが、アルギニン、リジン、ヒスチジン等が挙げられ、それらを単独、または２種類以上を任意に選択して使用することができる。中でもアルギニンが、本発明で用いるアミノ変性シリコーンを含む多層型毛髪化粧料の層分離する効果が高く、また各層の透明性も良好な為これを用いることが好ましい。 Although it does not specifically limit as a basic amino acid of the component (b) used for this invention, Arginine, a lysine, histidine, etc. are mentioned, These can be used individually or in combination of 2 or more types. Among them, it is preferable to use arginine because the layer separating effect of the multilayer hair cosmetic containing the amino-modified silicone used in the present invention is high and the transparency of each layer is also good.
前記成分（ｂ）の市販品としては、Ｌ−アルギニン（味の素社製、協和発酵社製、田辺製薬株式会社製）、Ｌ−リジン（ＳＩＧＭＡ ＣＨＥＭＩＣＡＬ ＣＯＭＰＡＮＹ社製）、Ｌ−ヒスチジン（ＳＩＧＭＡ ＣＨＥＭＩＣＡＬ ＣＯＭＰＡＮＹ社製）が挙げられる。 Commercially available components (b) include L-arginine (manufactured by Ajinomoto Co., Kyowa Hakko, Tanabe Seiyaku Co., Ltd.), L-lysine (manufactured by SIGMA CHEMICAL COMPANY), L-histidine (SIGMA CHEMICAL COMPANY). Manufactured).
本発明の毛髪化粧料において、前記成分（ｂ）は、該化粧料全量に対して０．０１〜５質量％配合することが好ましく、より好ましくは０．０５〜１質量％である。０．０１質量％以下では、アミノ変性シリコーンによる分離性の悪さ・外観透明性の悪さを改善することが難しく、また、５質量％を超えて配合すると、使用性上のべたつき・重さ等の点で好ましくない。 In the hair cosmetic composition of the present invention, the component (b) is preferably blended in an amount of 0.01 to 5 mass%, more preferably 0.05 to 1 mass%, based on the total amount of the cosmetic composition. If it is 0.01% by mass or less, it is difficult to improve the poor separation property and transparency of the appearance due to the amino-modified silicone, and if it exceeds 5% by mass, stickiness / weight, etc. in terms of usability It is not preferable in terms.
本発明の毛髪化粧料の剤型は多層型の液状である。中でも、外観の透明性・分離性により、透明・又は半透明の油層−水層からなる２層型液状組成物か、油層−乳化層−水層からなる３層型液状組成物であることが特に好ましい。
また、毛髪とは体毛と頭髪の総称であり、本発明の毛髪化粧料は、頭髪用化粧料、睫毛用化粧料等、毛髪化粧料であれば特に限定されない。
The dosage form of the hair cosmetic of the present invention is a multilayer liquid. Among them, it may be a two-layer liquid composition composed of a transparent or translucent oil layer-water layer or a three-layer liquid composition composed of an oil layer-emulsification layer-water layer depending on the transparency / separability of the appearance. Particularly preferred.
Hair is a general term for body hair and hair, and the hair cosmetic composition of the present invention is not particularly limited as long as it is a hair cosmetic composition such as a cosmetic for hair and a cosmetic for eyelashes.
本発明において、上記成分以外に、（ｃ）精製水、エタノールの他グリセリン、ジグリセリン、プロピレングリコール、ジプロピレングリコール、ソルビトール、キシリトール、ポリエチレングリコール等の保湿成分、キサンタンガム、アラビアゴム、カルボキシビニルポリマー、ヒドロキシプロピルセルロース、ヒドロキシエチルセルロース、高重合ポリエチレングリコール、デキストリン、グアーガム等の水溶性高分子を配合することが好ましい。
本発明の毛髪化粧料において、前記成分（ｃ）は、該化粧料全量に対して５〜９５質量％配合することが好ましく、より好ましくは１０〜９０質量％である。５質量％以下、また、９５質量％を超えて配合すると、油層の割合が少なくなり、外観上の多層構造が分かりにくくなるという点で好ましくない。
In the present invention, in addition to the above components, (c) moisturizing ingredients such as purified water, ethanol, glycerin, diglycerin, propylene glycol, dipropylene glycol, sorbitol, xylitol, polyethylene glycol, xanthan gum, gum arabic, carboxyvinyl polymer, It is preferable to blend a water-soluble polymer such as hydroxypropyl cellulose, hydroxyethyl cellulose, highly polymerized polyethylene glycol, dextrin, guar gum and the like.
In the hair cosmetic composition of the present invention, the component (c) is preferably blended in an amount of 5 to 95 mass%, more preferably 10 to 90 mass%, based on the total amount of the cosmetic composition. If it is blended in an amount of 5% by mass or less and more than 95% by mass, the ratio of the oil layer is decreased, and it is not preferable in that the multilayer structure on the appearance becomes difficult to understand.
本発明において、上記成分以外に、（ｄ）ミネラルオイル、２−エチルヘキサン酸セチル、揮発性イソパラフィン、軽質イソパラフィン、重質流動イソパラフィン、植物性スクワラン、オクチルドデカノール、パルミチン酸イソステアリル、ポリオキシプロピレン（４０）ブチルエーテル、ジメチコン、メチルフェニルポリシロキサン、コハク酸ジ２−エチルヘキシル、ポリオキシエチレン（１４）ポリオキシプロピレン（７）ジメチルエーテル、ポリオキシエチレン（９）ポリオキシプロピレン（２）ジメチルエーテル、オリーブ油、ゴマ油、マカデミアナッツ油、ホホバ油、トウモロコシ油、ツバキ油を配合することが好ましい。
本発明の毛髪化粧料において、前記成分（ｄ）は、該化粧料全量に対して５〜９５質量％配合することが好ましく、より好ましくは１０〜９０質量％である。５質量％以下、また、９５質量％を超えて配合すると、外観上の多層構造が分かりにくくなるという点で好ましくない。
In the present invention, in addition to the above components, (d) mineral oil, cetyl 2-ethylhexanoate, volatile isoparaffin, light isoparaffin, heavy liquid isoparaffin, vegetable squalane, octyldodecanol, isostearyl palmitate, polyoxypropylene (40) Butyl ether, dimethicone, methylphenyl polysiloxane, di-2-ethylhexyl succinate, polyoxyethylene (14) polyoxypropylene (7) dimethyl ether, polyoxyethylene (9) polyoxypropylene (2) dimethyl ether, olive oil, sesame oil Macadamia nut oil, jojoba oil, corn oil and camellia oil are preferably blended.
In the hair cosmetic composition of the present invention, the component (d) is preferably blended in an amount of 5 to 95 mass%, more preferably 10 to 90 mass%, based on the total amount of the cosmetic composition. When the blending amount is 5% by mass or less and more than 95% by mass, it is not preferable in that the multilayer structure on the appearance becomes difficult to understand.
本発明において、上記成分以外に（ｅ）塩化ナトリウム、塩化カリウム、硫酸ナトリウム、硫酸マグネシウム、硫酸カリウム、クエン酸ナトリウム、乳酸ナトリウム、炭酸カルシウムなどの水溶性塩類を配合することが好ましい。
本発明の毛髪化粧料において、前記成分（ｅ）は該化粧料全量に対して０．０１〜３質量％配合することが好ましく、より好ましくは０．１〜１質量％である。０．０１質量％以下だと塩析効果が弱まり多層の分離性が弱くなり、また、３質量％を超えて配合すると、べたつきなど使用性上の問題が出る点で好ましくない。
In the present invention, in addition to the above components, (e) water-soluble salts such as sodium chloride, potassium chloride, sodium sulfate, magnesium sulfate, potassium sulfate, sodium citrate, sodium lactate and calcium carbonate are preferably blended.
In the hair cosmetic composition of the present invention, the component (e) is preferably blended in an amount of 0.01 to 3 mass%, more preferably 0.1 to 1 mass%, based on the total amount of the cosmetic composition. If it is 0.01% by mass or less, the salting-out effect is weakened and the separability of the multilayer is weakened, and if it exceeds 3% by mass, it is not preferable in terms of stickiness and other usability problems.
本発明によれば、特定のアミノ変性シリコーンと塩基性アミノ酸を配合する多層型毛髪化粧料であって、毛髪に塗布した際、毛髪に十分な補修効果を付与することができ、さらに振とう後の静置状態での各層の分離性・透明性が良好な毛髪化粧料が得られる。 According to the present invention, a multi-layered hair cosmetic comprising a specific amino-modified silicone and a basic amino acid, which can impart a sufficient repair effect to hair when applied to hair, and further after shaking A hair cosmetic composition in which the separation and transparency of each layer in the stationary state is good can be obtained.
本発明の代表的な実施の形態は次の通りである。なお、配合量の単位は質量％である。 A typical embodiment of the present invention is as follows. In addition, the unit of a compounding quantity is the mass%.
水層に水、アルコール、食塩、塩基性アミノ酸を溶解させ、また油層に水添ポリイソブテンとアミノ変性シリコーンを溶解して２層を混合・攪拌して得た試験品について、後述の試験法により、振とう後、８時間静置した状態での分離性と透明性を確認した。結果を表１に示す。 About a test product obtained by dissolving water, alcohol, sodium chloride, basic amino acid in the aqueous layer, and mixing and stirring the two layers by dissolving hydrogenated polyisobutene and amino-modified silicone in the oil layer, After shaking, separation and transparency in a state of standing for 8 hours were confirmed. The results are shown in Table 1.
＜振盪後の分離性と透明性確認＞
各試験品を５０ｇガラス管に入れ、３０回振盪した後、水平に８時間放置すると試験品は２層分離した。その後経時での各層の分離性・透明性を確認した。
<Separation and transparency after shaking>
Each test product was placed in a 50 g glass tube, shaken 30 times, and allowed to stand horizontally for 8 hours. The test product was separated into two layers. Thereafter, the separation and transparency of each layer over time was confirmed.
次に、後述の製造方法によって、表２に示す配合処方の毛髪化粧料を調製した。得られた各毛髪化粧料を用い、前記実施の形態と同一方法の振とう後振とう後、８時間静置した状態での分離性と透明性確認を行った。結果を表２に示す。なお、配合量の単位は質量％である。 Next, hair cosmetics having the formulation shown in Table 2 were prepared by the production method described below. Using each hair cosmetic obtained, after separation after shaking in the same manner as in the above embodiment, separation and transparency were confirmed after standing for 8 hours. The results are shown in Table 2. In addition, the unit of a compounding quantity is the mass%.
＜製造方法＞
水に食塩、アルコール、塩基性アミノ酸を溶解させ、水添ポリイソブテン、アミノ変性シリコーンからなる油層パーツを添加・攪拌融解して試験品を得、容器に充填した。
<Manufacturing method>
Salt, alcohol, and basic amino acid were dissolved in water, and oil layer parts composed of hydrogenated polyisobutene and amino-modified silicone were added, stirred and melted to obtain a test product, which was filled in a container.
（＊３）ＡＰＳ−１０−ＤＭＳ（信越化学工業社製）
(* 3) APS-10-DMS (manufactured by Shin-Etsu Chemical Co., Ltd.)
実施例１、比較例２・３は、２層に、実施例２，３は３層に分離した。表２に示すとおり、前記成分（ｂ）として塩基性アミノ酸であるアルギニン・リジン・ヒスチジンを配合した毛髪化粧料において、塩基性アミノ酸無配合の比較例２と比べて各層の透明性・分離性が向上している。また前記成分（ａ）アミノ変性シリコーン無配合の比較例２と同程度の透明性・分離性を示し、かつ良好な毛髪補修効果を有する。比較例３に見られるように、アミノプロピルジメチコン（＊３）はアミノ変性率が低いため、より少量のアルギニンで透明性と分離性を改善することが出来るが、毛髪補修効果はアミノプロピルジメチコン（＊２）に比べて低い。 Example 1 and Comparative Examples 2 and 3 were separated into two layers, and Examples 2 and 3 were separated into three layers. As shown in Table 2, in the hair cosmetic containing arginine, lysine and histidine which are basic amino acids as the component (b), the transparency / separability of each layer is higher than that of Comparative Example 2 containing no basic amino acid. It has improved. Moreover, the said component (a) shows transparency and separation properties comparable to those of Comparative Example 2 containing no amino-modified silicone, and has a good hair repair effect. As seen in Comparative Example 3, since aminopropyl dimethicone (* 3) has a low amino modification rate, transparency and separability can be improved with a smaller amount of arginine, but the effect of repairing hair is aminopropyl dimethicone ( * 2) Low compared to
実施例４は、２層分離した。表３に示すとおり、さらに他のアミノ酸としてＬ−グルタミン、アミノ酸塩としてグルタミン酸ナトリウム、タンパク質分解物として加水分解コムギタンパクを配合した比較例３・４・５は、成分（ｂ）がアルギニンである実施例４と比べて、外観の透明性・分離性が悪い。 In Example 4, two layers were separated. As shown in Table 3, Comparative Examples 3, 4, and 5 in which L-glutamine as another amino acid, sodium glutamate as an amino acid salt, and hydrolyzed wheat protein as a proteolysate were blended were those in which component (b) was arginine. Compared to Example 4, the transparency and separation of the appearance are poor.
以下に、本発明のその他の実施例を示す。なお、配合量の単位は質量％である。なお、アミノプロピルジメチコン（＊５）については、（化１）他の一般式において、ｍ＋ｎの平均値＝５０００、ｎ／ｍの平均値＝０．００５であるものを用いた Other examples of the present invention will be shown below. In addition, the unit of a compounding quantity is the mass%. In addition, about aminopropyl dimethicone (* 5), (chemical formula 1) In other general formula, the average value of m + n = 5000, the average value of n / m = 0.005 was used.
実施例５：ヘアトリートメント（２層分離）
エタノール ４０
グリセリン ２
食塩 ０．３
揮発性イソパラフィン ２０
メチルポリシロキサン ２
アミノプロピルジメチコン（＊５） １
Ｌ−アルギニン ０．３
香料 ０．１
精製水 残余
Example 5: Hair treatment (two-layer separation)
Ethanol 40
Glycerin 2
Salt 0.3
Volatile isoparaffin 20
Methyl polysiloxane 2
Aminopropyl dimethicone (* 5) 1
L-Arginine 0.3
Fragrance 0.1
Purified water residue
＜製造方法＞
水に食塩、アルコール、グリセリン、Ｌ−アルギニンを溶解させ、水添ポリイソブテン、メチルポリシロキサン、アミノプロピルジメチコンからなる油層パーツを添加・攪拌融解し、容器に充填した。
<Manufacturing method>
Salt, alcohol, glycerin and L-arginine were dissolved in water, and oil layer parts composed of hydrogenated polyisobutene, methylpolysiloxane and aminopropyldimethicone were added, stirred and melted, and filled into a container.
実施例６：セットローション（３層分離）
（メタクリロイルオキシエチルカルボキシベタイン／メタクリル酸アルキル）コポリマー １
アミノプロピルジメチコン（＊５） １
Ｌ−リジン １
エタノール ２０
ソルビトール ５
キサンタンガム ０．１
ミネラルオイル ８
香料 ０．１
食塩 ０．３
精製水 残余
Example 6: Set lotion (3 layer separation)
(Methacryloyloxyethylcarboxybetaine / alkyl methacrylate) copolymer 1
Aminopropyl dimethicone (* 5) 1
L-lysine 1
Ethanol 20
Sorbitol 5
Xanthan gum 0.1
Mineral oil 8
Fragrance 0.1
Salt 0.3
Purified water residue
＜製造方法＞
水に食塩、アルコール、グリセリン、Ｌ−リジン、キサンタンガム、（メタクリロイルオキシエチルカルボキシベタイン／メタクリル酸アルキル）コポリマーを溶解させ、水添ポリイソブテン、アミノプロピルジメチコンからなる油層パーツを添加・攪拌融解し、容器に充填した。
<Manufacturing method>
Salt, alcohol, glycerin, L-lysine, xanthan gum, (methacryloyloxyethylcarboxybetaine / alkyl methacrylate) copolymer are dissolved in water, and oil layer parts consisting of hydrogenated polyisobutene and aminopropyl dimethicone are added, stirred and melted into a container. Filled.
実施例７：スカルプローション ３層のものを記載して下さい。
ポリグリセリン（８）ドデシルフェニルエーテル ０．５％
塩化ナトリウム ０．７
ジメチコン ３
アミノプロピルジメチコン（＊５）
Ｌ−ヒスチジン
エタノール ３０
ｌ−メントール ０．１
ビタミンＥ誘導体 ０．５
ジプロピレングリコール ７
精製水 残余
Example 7: Skull Propation Please describe the 3 layers.
Polyglycerin (8) dodecyl phenyl ether 0.5%
Sodium chloride 0.7
Dimethicone 3
Aminopropyl dimethicone (* 5)
L-histidine ethanol 30
l-Menthol 0.1
Vitamin E derivative 0.5
Dipropylene glycol 7
Purified water residue
＜製造方法＞
水に塩化ナトリウム、ジプロピレングリコール、Ｌ−ヒスチジン、ポリグリセリン（８）ドデシルフェニルエーテルを溶解させ、ビタミンＥ誘導体とｌ−メントールを溶解したアルコールを添加した。そこにアミノプロピルジメチコン（＊５）とジメチコンからなる油層パーツを添加・攪拌融解し、容器に充填した。
<Manufacturing method>
Sodium chloride, dipropylene glycol, L-histidine, polyglycerin (8) dodecylphenyl ether were dissolved in water, and an alcohol in which vitamin E derivative and l-menthol were dissolved was added. The oil layer part which consists of aminopropyl dimethicone (* 5) and dimethicone was added there, and it stirred and thawed, and filled the container.
Claims (4)
（１）−２：（式（１）中、ｍ及びｎはそれぞれ正の整数で、ｍ＋ｎの平均値は４０００〜６０００であり、ｎ／ｍの平均値は０．００２〜０．０３である。） (A) A multilayer hair cosmetic comprising an amino silicone represented by the following general formula (1) -1 and / or (1) -2, and (b) a basic amino acid.
(1) -2: (In formula (1), m and n are each a positive integer, the average value of m + n is 4000 to 6000, and the average value of n / m is 0.002 to 0.03. .)
The multilayer hair cosmetic according to any one of claims 1 to 3, which is a two-layer type comprising an oil layer-an aqueous layer and / or a three-layer type comprising an oil layer-an emulsified layer-an aqueous layer.
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| JP2004358261A JP2006160708A (en) | 2004-12-10 | 2004-12-10 | Multilayer-type hair cosmetic |
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| JP2004358261A JP2006160708A (en) | 2004-12-10 | 2004-12-10 | Multilayer-type hair cosmetic |
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Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008132816A1 (en) * | 2007-04-17 | 2008-11-06 | Kao Corporation | Hair cosmetic |
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| US9011886B2 (en) | 2007-04-17 | 2015-04-21 | Kao Corporation | Hair cosmetic composition |
| JP2009161508A (en) * | 2007-04-17 | 2009-07-23 | Kao Corp | Hair cosmetics |
| WO2008132816A1 (en) * | 2007-04-17 | 2008-11-06 | Kao Corporation | Hair cosmetic |
| JP2010059157A (en) * | 2008-08-08 | 2010-03-18 | Shiseido Co Ltd | Hair styling agent |
| WO2010146784A1 (en) * | 2009-06-19 | 2010-12-23 | 花王株式会社 | Separated two-layer hair cosmetic |
| CN102458345B (en) * | 2009-06-19 | 2014-07-16 | 花王株式会社 | Separated two-layer hair cosmetic |
| CN102458345A (en) * | 2009-06-19 | 2012-05-16 | 花王株式会社 | Double layer separation type hair cosmetics |
| US9132289B2 (en) | 2009-06-19 | 2015-09-15 | Kao Corporation | Two-layer separate type hair cosmetic composition |
| US9586063B2 (en) | 2014-04-25 | 2017-03-07 | The Procter & Gamble Company | Method of inhibiting copper deposition on hair |
| US9642788B2 (en) | 2014-04-25 | 2017-05-09 | The Procter & Gamble Company | Shampoo composition comprising gel matrix and histidine |
| US9642787B2 (en) | 2014-04-25 | 2017-05-09 | The Procter & Gamble Company | Method of inhibiting copper deposition on hair |
| US10835469B2 (en) | 2014-04-25 | 2020-11-17 | The Procter And Gamble Company | Method of inhibiting copper deposition on hair |
| JP2016064994A (en) * | 2014-09-24 | 2016-04-28 | 川研ファインケミカル株式会社 | Cosmetic composition containing arginine derivative |
| US11246816B2 (en) | 2016-06-30 | 2022-02-15 | The Procter And Gamble Company | Shampoo compositions comprising a chelant |
| US10973744B2 (en) | 2016-06-30 | 2021-04-13 | The Procter And Gamble Company | Conditioner composition comprising a chelant |
| US11166894B2 (en) | 2016-06-30 | 2021-11-09 | The Procter And Gamble Company | Shampoo compositions comprising a chelant |
| US11458085B2 (en) | 2016-06-30 | 2022-10-04 | The Procter And Gamble Company | Hair care compositions for calcium chelation |
| US11786447B2 (en) | 2016-06-30 | 2023-10-17 | The Procter & Gamble Company | Conditioner composition comprising a chelant |
| CN108653018B (en) * | 2018-07-11 | 2021-03-09 | 孔令超 | Scalp skin-cleaning cream and preparation and use methods thereof |
| CN108653018A (en) * | 2018-07-11 | 2018-10-16 | 孔令超 | The net skin breast of scalp and its preparation, application method |
| US12180437B2 (en) | 2018-08-24 | 2024-12-31 | The Procter & Gamble Company | Treatment compositions comprising a surfactant system and an oligoamine |
| US12195702B2 (en) | 2018-08-24 | 2025-01-14 | The Procter & Gamble Company | Treatment compositions comprising low levels of an oligoamine |
| JP2021024807A (en) * | 2019-08-05 | 2021-02-22 | 日本精化株式会社 | Hair cavity repairing agent and hair cavity repair method using the same |
| JP7731654B2 (en) | 2019-08-05 | 2025-09-01 | 日本精化株式会社 | Hair cavity repair agent and hair cavity repair method using the same |
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