JP2006008574A5 - - Google Patents

Description

One of the important factors when applying makeup such as a pack or massage is to feel warmth. This is because the effect expected in such a makeup act is a blood circulation promoting action, and by feeling a sense of warmth, the actual feeling of such an effect is realized, and as a result, the makeup act itself is greatly satisfied. This is because a feeling of warmth and a feeling of moderate warmth embody comfort in use, and this pleasant sensation adjusts the environment of a personal biological system and exhibits a favorable effect on health. Examples of methods for embodying such warming cosmetics include methods using heat generated by oxidation reaction of metal oxide with water and neutralization reaction with acid, glycerin, dipropylene glycol, liquid polyethylene glycol, etc. There is a method that utilizes the heat of hydration that occurs when solvates with water. Among these, the former is a two-component system, and there is a drawback that the heat generation cannot be controlled unless it takes the form of mixing at the time of use. In the latter, a single-agent system can be formulated, There was a drawback that the calorific value itself was small ( see, for example, Patent Document 1, Patent Document 2, Patent Document 3, and Patent Document 4) . That is, in such a one-component cosmetic, an appropriate temperature of about 50 ° C. usually lasts only about 3 to 5 minutes.

On the other hand, it is already known that foam-shaped cosmetics have a blocking effect, a heat insulating effect, and the like and are suitable for pack cosmetics. Moreover, in foam cosmetics, it is also known that polyglycerol fatty acid esters such as decaglycerol monolaurate and diglycerol monolaurate have excellent foaming properties. (For example, see Patent Document 5, Patent Document 6, Patent Document 7, and Patent Document 8) However, there is no known formulation technology for making a non-aqueous emulsion into a foam. There is no known warm foam cosmetic using heat of hydration.

Also known is a foam cosmetic comprising 1) a fatty acid ester of polyglycerol , 2) 15 to 80% by mass of a polyhydric alcohol, and 3) 15 to 80% by mass of an oily component that is liquid at 25 ° C. and 1 atm. In addition, it is not known at all that the cosmetic material having such a configuration exhibits an excellent thermal effect during use.

In view of such circumstances, the present inventors have intensively researched for a one-component foam cosmetic that has an excellent thermal effect, and 1) polyglycerin. containing 15 to 80 wt% liquid oil component in the fatty acid esters of 2) a polyhydric alcohol 15-80 wt% and 3) 25 ° C. 1 atm, foam cosmetic has a such characteristic I found out and came to complete the invention. That is, the present invention is as follows.
(1) 1), characterized in that it contains an oil component from 15 to 80 wt% of liquid fatty acid esters of polyglycerol with 2) 15 to 80 wt% polyhydric alcohol and 3) 25 ° C. 1 atm, foam Cosmetics.
(2) even without least, characterized by containing a fatty acid ester of two polyglycerin, foam cosmetic according to (1).
(3) The foam cosmetic according to (2), wherein the fatty acid ester of at least two kinds of polyglycerol contains a mono fatty acid ester of diglycerin and a mono fatty acid ester of decaglycerin.
(4) The foam cosmetic according to any one of (1) to (3), wherein 30 to 80% by mass of the oily component is a tetraglyceryl ester of diglycerin.
(5) The foam cosmetic according to any one of (1) to (4), which is substantially free of water.
(6) The foam cosmetic according to any one of (1) to (5), which is a cosmetic having a warm feeling.
(7) Further, characterized in that it contains one or more selected from alkyl glycyrrhetinate, glycyrrhizic acid, ascorbic acid, ascorbic acid derivatives, arbutin, tranexamic acid, 4-methoxysalicylic acid and salts thereof. The foam cosmetic according to any one of (1) to (6).
(8) The foam cosmetic as described in (7), which is a quasi-drug that promotes anti-inflammatory action and / or melanin production-suppressing action.
(9) The foam cosmetic according to (7) or (8), wherein the packaging form has an indication that it has an anti-inflammatory action and / or a melanin production inhibitory action.

(1) Polyglycerin fatty acid ester which is an essential component of the foam cosmetic of the present invention The foam cosmetic of the present invention is characterized by containing at least two fatty esters of polyglycerol as essential components. The fatty acid ester of polyglycerin that can be used in the foam cosmetic of the present invention can be used without particular limitation as long as it has a free hydroxyl group and has a surface-active action. It is preferable to contain a combination of two types of lipophilic polyglycerol fatty acid esters. Examples of the fatty acid ester of a hydrophilic polyglycerol, polyglycerol moiety constituting it, the degree of polymerization of glycerin is preferably one having 5 to 15, particularly preferably from 7 to 12. It is preferable that more than half of the hydroxyl groups possessed by such polyglycerin are free hydroxyl groups. Moreover, as a fatty acid residue, as long as it is generally known, it can be used without any particular limitation, for example, a linear fatty acid residue having 10 to 30 carbon atoms, a fatty acid residue having a branched chain, A fatty acid residue having a cyclic structure, a fatty acid residue having an unsaturated bond and the like can be preferably exemplified. Specifically, for example, lauric acid residue, myristic acid residue, palmitic acid residue, stearic acid residue, behen Preferred examples include acid residues, isostearic acid residues, octyldodecanoic acid residues, oleic acid residues, linoleic acid residues, linolenic acid residues and the like. More preferable examples include a lauric acid residue, a stearic acid residue, an isostearic acid residue or an oleic acid residue. As such a hydrophilic fatty acid ester of polyglycerin, a monofatty acid ester of decaglycerin can be preferably exemplified, and among them, decaglycerin monooleate is particularly preferred. In the fatty acid ester of polyglycerin as a lipophilic surfactant, the degree of polymerization of glycerin in the polyglycerin moiety is preferably 2 to 5, particularly preferably 2 to 3. In addition, the average number of fatty acid residues present per molecule is preferably 1 to 4, and more preferably 1 to 3. Examples of the fatty acid moiety are preferably linear fatty acid residues having 10 to 30 carbon atoms, fatty acid residues having a branched chain, fatty acid residues having a cyclic structure, fatty acid residues having an unsaturated bond, and the like. Specifically, for example, lauric acid residue, myristic acid residue, palmitic acid residue, stearic acid residue, behenic acid residue, isostearic acid residue, octyldodecanoic acid residue, oleic acid residue, linoleic acid residue Preferred examples include groups and linolenic acid residues. More preferable examples include lauric acid residues, stearic acid residues, isostearic acid residues, and oleic acid residues, and lauric acid residues are particularly preferable. Particularly preferred is diglycerin monolaurate. In the foam cosmetic of the present invention, such a fatty acid ester of polyglycerin is a hydrophilic surfactant and a lipophilic surfactant, but each can contain only one species. A combination of more than one species can also be included. In the foam cosmetic of the present invention, the preferable content of the fatty acid ester of polyglycerin is 1 to 20% by mass, more preferably 3 to 10% by mass, based on the total amount of the foam cosmetic. %. This is because if the amount is too small, a stable foam is not formed. Moreover, as a preferable form, it can be illustrated that the fatty acid ester of hydrophilic polyglycerol and the fatty acid ester of lipophilic polyglycerol are contained in a mass ratio of 1: 8 to 1: 1.

(2) Polyhydric alcohol which is an essential component of the foam cosmetic of the present invention The foam cosmetic of the present invention contains 15 to 80% by mass of polyhydric alcohol, more preferably 25 to 70% by mass, still more preferably. 40-50 mass% It contains as an essential component, It is characterized by the above-mentioned. The polyhydric alcohol can be used without particular limitation as long as it is usually used in cosmetics. For example, polyethylene glycol, glycerin, 1,3-butylene glycol, erythritol, sorbitol, xylitol, maltitol. And propylene glycol, dipropylene glycol, diglycerin, isoprene glycol, 1,2-pentanediol, 2,4-hexylene glycol, 1,2-hexanediol, 1,2-octanediol and the like. Such polyhydric alcohol is in the foam cosmetic composition of the present invention to it is also possible to make containing only species, it is also possible to make containing a combination of two or more thereof. As a preferred form, it is preferable to contain 70% by mass or more, more preferably 80% by mass or more, of polyhydric alcohol having fluidity at 1 atm and 25 ° C. with respect to the total amount of polyhydric alcohol. Examples of the polyhydric alcohol having fluidity at 1 atm and 25 ° C. include polyethylene glycol having an average molecular weight of 1000 or less, glycerin, propylene glycol, dipropylene glycol, diglycerin, isoprene glycol, 1,2-pentanediol, 2,4 Preferred examples include -hexylene glycol, 1,2-hexanediol, and 1,2-octanediol. Particularly preferable is a form in which glycerin is contained in an amount of 70% by mass or more, more preferably 80% by mass or more based on the total amount of polyhydric alcohol. In the foam cosmetic of the present invention, such a component, when applied on the skin, hydrates with moisture on the skin and generates heat of hydration, thereby producing a thermal effect.

(3) Oily component that is an essential component of the foam cosmetic of the present invention The foam cosmetic of the present invention has 15 to 80% by mass, more preferably 25 to 70% by mass, and still more preferably an oily component as an essential component. Is characterized by taking the form of a foam aerosol containing 40-50% by weight. The oil component is an oil-soluble component that has little or no surfactant activity, and is a component that does not emulsify itself, such as hydrocarbons, fatty acid esters, dimethicone silicones, higher alcohols, Preferred examples include glycerin tri-fatty acid ester, diglycerin tetra-fatty acid ester, triglycerin penta-fatty acid ester, fatty acid, diester of N-acyl glutamic acid, and the like. Specifically, for example, macadamia nut oil, avocado oil, corn oil, olive oil, rapeseed oil, sesame oil, castor oil, safflower oil, cottonseed oil, jojoba oil, palm oil, palm oil, liquid lanolin, hardened coconut oil, hardened oil Oil, wax, liquid paraffin, squalane, pristane, ozokerite, paraffin, ceresin, petrolatum, microcrystallin, oil, wax, liquid oil, waxy wax, liquid paraffin, squalane, pristine Hydrocarbons such as wax, higher fatty acids such as oleic acid, isostearic acid, lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, undecylenic acid, cetyl alcohol, stearyl alcohol, isostearyl alcohol, Higher alcohols such as hexyl alcohol, octyldodecanol, myristyl alcohol, cetostearyl alcohol, cetyl isooctanoate, isopropyl myristate, hexyldecyl isostearate, diisopropyl adipate, di-2-ethylhexyl sebacate, cetyl lactate, diacid malate Isostearyl, ethylene glycol di-2-ethylhexanoate, neopentyl glycol dicaprate, glycerin di-2-heptylundecanoate, glycerin tri-2-ethylhexanoate, tri-2-ethylhexanoate trimethylolpropane, triisostearin Synthetic ester oils such as acid trimethylolpropane, tetra-2-ethylhexanoic acid pentane erythritol, dimethylpolysiloxane, methylphenylpolysiloxane, di Chain polysiloxane such as phenyl polysiloxane, cyclic polysiloxane such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexanesiloxane, amino-modified polysiloxane, polyether-modified polysiloxane, alkyl-modified polysiloxane, fluorine-modified Oil agents such as silicone oil such as modified polysiloxane such as polysiloxane, N-lauroyl-L-glutamate di (phytosteryl / octyldodecyl), N-lauroyl-L-glutamate di (cholesteryl / behenyl / octyldodecyl), Preferred examples include N-acylated glutamic acid diesters such as N-lauroyl-L-glutamic acid di (phytosteryl / behenyl / octyldodecyl). Any of these can be used in the foam cosmetic of the present invention, but 30 to 80% by mass thereof is preferably diglycerin tetrafatty acid ester, and the diglycerin tetrafatty acid ester is diglycerin tetra. Olate is particularly preferred. This includes that easily form a stable foam in part, the other is the lipophilic dirt is because easily redispersed any hydrophilic stains. Further, from the same viewpoint, it is preferable to further contain a diester of N-acylglutamic acid. In this component, the acyl group constituting the diester of N-acylglutamic acid is preferably a linear aliphatic acyl group having 10 to 32 carbon atoms, for example, lauroyl group, myristoyl group, palmitoyl group, stearoyl group, behenoyl group. Etc. can be suitably exemplified. Moreover, it is preferable that the hydrocarbon group which comprises diester is aliphatic, and 10-32 are preferable and, as for carbon number, 18-30 are more preferable. The aliphatic hydrocarbon group may be linear or have a cyclic structure or a branched structure. Preferable examples include phytosteryl groups such as decyl group, dodecyl group, octyldodecyl group, cholesteryl group, campesteryl group, sitosteryl group and stigmasteryl group. These esters are preferably mixed esters derived by a reagent that induces a mixed hydrocarbon group and stochastically derived to have two or more types of hydrocarbon groups. As a combination of hydrocarbon groups constituting such a mixed ester, a mixed ester obtained by combining a hydrocarbon group having at least one cyclic structure and a hydrocarbon group having at least one branched structure is more preferable. Examples of such diesters of N-acylglutamic acid include, for example, N-lauroyl-L-glutamate di (phytosteryl / octyldodecyl), N-lauroyl-L-glutamate di (cholesteryl / benenyl / octyldodecyl), N- Preferable examples include lauroyl-L-glutamate di (phytosteryl / behenyl / octyldodecyl). For example, N-acylglutamic acid such as N-lauroylglutamic acid is condensed with halogenated hydrocarbons such as phytosteryl chloride, octyldodecyl chloride, and behenyl chloride in the presence of alkali in the presence of alkali. Can be manufactured. In addition, such diesters of N-acylated glutamic acid are already commercially available as cosmetic raw materials, and such commercial products can be purchased and used. Preferable examples of commercially available products include “El Deu PS203” (N-lauroyl-L-glutamate di (phytosteryl / octyldodecyl)) sold by Ajinomoto Co., Inc. The content of the diester of N-acylglutamic acid in the foam cosmetic of the present invention is preferably 0.01 to 1% by mass, more preferably 0.05 to 0.5% by mass. Furthermore, the foam cosmetic of the present invention preferably contains an aqueous component, and specifically contains 15 to 80% by mass of water. This is because an excellent moist feeling is exhibited after use.

(4) Foam cosmetic of the present invention The foam cosmetic of the present invention is characterized in that it contains the essential components and is in the form of a foam. The cosmetic of the present invention can contain any components that are usually used in cosmetics in addition to the essential components. Examples of such optional components include fatty acid soap (sodium laurate, sodium palmitate, etc.), anionic surfactants such as potassium lauryl sulfate, alkylsulfuric triethanolamine ether, stearyltrimethylammonium chloride, benzalkonium chloride , Cationic surfactants such as laurylamine oxide, imidazoline amphoteric surfactants (such as 2-cocoyl-2-imidazolinium hydroxide-1-carboxyethyloxy disodium salt), betaine surfactants (alkyl betaines) Amphoteric surfactants such as acylmethyl taurine, sorbitan fatty acid esters (such as sorbitan monostearate, sorbitan sesquioleate), glycerin fatty acids (monostearic acid group) Serine etc.), propylene glycol fatty acid esters (propylene glycol monostearate, etc.), hydrogenated castor oil derivative, glycerin alkyl ether, POE sorbitan fatty acid esters (POE sorbitan monooleate, polyoxyethylene sorbitan monostearate, etc.), POE Sorbit fatty acid esters (POE-sorbite monolaurate, etc.), POE glycerin fatty acid esters (POE-glycerin monoisostearate, etc.), POE fatty acid esters (polyethylene glycol monooleate, POE distearate, etc.), POE alkyl ethers ( POE2-octyldodecyl ether, etc.), POE alkylphenyl ethers (POE nonylphenyl ether, etc.), Pluronic types, POE / POP alkyl Nonionic interfaces such as ethers (POE / POP2-decyltetradecyl ether, etc.), tetronics, POE castor oil / hardened castor oil derivatives (POE castor oil, POE hardened castor oil, etc.), sucrose fatty acid esters, alkyl glucosides, etc. Active agents, moisturizing ingredients such as sodium pyrrolidone carboxylate, lactic acid, sodium lactate, guar gum, quince seed, carrageenan, galactan, gum arabic, pectin, mannan, starch, xanthan gum, curdlan, methylcellulose, hydroxyethylcellulose, carboxymethylcellulose, Methylhydroxypropylcellulose, chondroitin sulfate, dermatan sulfate, glycogen, heparan sulfate, hyaluronic acid, sodium hyaluronate, tragacanth gum, keratan sulfate, chondroitin , Mucoitin sulfate, hydroxyethyl guar gum, carboxymethyl guar gum, dextran, keratosulfate, locust bean gum, succinoglucan, caronic acid, chitin, chitosan, carboxymethyl chitin, agar, polyvinyl alcohol, polyvinyl pyrrolidone, carboxyvinyl polymer, polyacryl Thickeners such as sodium acid, polyethylene glycol, bentonite, surface may be treated, mica, talc, kaolin, synthetic mica, calcium carbonate, magnesium carbonate, anhydrous silicic acid (silica), aluminum oxide, barium sulfate, etc. Powders, the surface may be treated, bengara, yellow iron oxide, black iron oxide, cobalt oxide, ultramarine, bitumen, titanium oxide, zinc oxide inorganic pigments, the surface may be treated, Mica titanium, fish phosphorus foil Pearl agent such as bismuth oxychloride, red 202, red 228, red 226, yellow 4, blue 404, yellow 5, red 505, red 230, red 223 which may be raked No., Orange No. 201, Red No. 213, Yellow No. 204, Yellow No. 203, Blue No. 1, Green No. 201, Purple No. 201, Red No. 204 and other organic pigments, polyethylene powder, polymethyl methacrylate, nylon powder, Organic powders such as organopolysiloxane elastomers, paraaminobenzoic acid UV absorbers, anthranilic acid UV absorbers, salicylic acid UV absorbers, cinnamic acid UV absorbers, benzophenone UV absorbers, sugar UV absorbers 2- (2′-hydroxy-5′-t-octylphenyl) benzotriazole, 4-methoxy-4′-t-butyldiben UV absorbers such as ilmethane, lower alcohols such as ethanol and isopropanol, vitamin A or its derivatives, vitamin B6 hydrochloride, vitamin B6 tripalmitate, vitamin B6 dioctanoate, vitamin B2 or its derivatives, vitamin B12, vitamin B15 or Vitamin B such as its derivatives, vitamin E such as α-tocopherol, β-tocopherol, γ-tocopherol, vitamin E acetate, vitamin D, vitamin H, vitamins such as pantothenic acid, panthetin, pyrroloquinoline quinone, etc. Preferred examples can be given. In addition, in order to take the form of foam aerosol, the foam cosmetic of the present invention preferably contains a vaporizing component. Examples of the vaporizing component include halogenated hydrocarbon gas such as chlorofluorocarbon gas, carbon dioxide gas, A liquefied natural gas, dimethyl ether, etc. can be illustrated and a liquefied natural gas can be illustrated especially preferable. As a composition of liquefied natural gas, what contains isobutane as a main component is especially preferable, and it is preferable that the content is at least 80 mass% of gas whole quantity with isobutane. The preferable content of the vaporizing component is 2 to 10% by mass. The foam cosmetic of the present invention can be produced by treating such essential components, preferred components, and optional components according to a conventional method.

The foam cosmetic of the present invention can be applied without particular limitation as long as it is a formulation in which foam cosmetics are usually used. Pack cosmetics, cleansing cosmetics, nourishing cosmetics, massage cosmetics Either can be used. Among these, examples of the cosmetics that can maximize the thermal effect of the present invention include pack cosmetics and massage cosmetics, which are preferably applied to these. In such an embodiment, since the active ingredient can also be efficiently transdermally absorbed, it is preferable to contain an active ingredient, and the active ingredient contains an anti-inflammatory agent or a melanin production inhibitor. Is preferred. Preferred examples of the anti-inflammatory agent include alkyl glycyrrhetinate, glycyrrhizic acid and salts thereof, and preferred melanin production inhibitors include ascorbic acid, ascorbic acid derivatives, arbutin, tranexamic acid, 4-methoxysalicylic acid and salts thereof. Can be illustrated. Such active ingredient salts include alkali metal salts such as sodium salt and potassium salt, alkaline earth metal salts such as calcium and magnesium, organic amine salts such as ammonium salt, triethanolamine salt and triethylamine salt, lysine salt, arginine. Preferred examples include basic amino acid salts such as salts. Further, as derivatives of ascorbic acid, glycosides such as ascorbic acid-2-glucoside, and phosphate esters such as ascorbic acid diphosphate can be preferably exemplified. It Such components can also make contain only species, can also make contain two or more kinds. The preferable content of the anti-inflammatory agent or the melanin production inhibitor in the cosmetic of the present invention is 0.01 to 10% by mass, more preferably 0.03 to 5% by mass, respectively. In the case of containing these active ingredients, the foam cosmetic of the present invention is preferably a quasi-drug that appeals for each effect, and in the quasi-drug, safety and In order to embody the effectiveness more specifically, the effect of having an anti-inflammatory effect or the effect of suppressing the production of melanin, and the use mode, the location where inflammation exists or the production of melanin is enhanced or enhanced. Appropriate amount should be applied once or several times a day, and if you feel any abnormalities on your skin, stop using it immediately and indicate to your dermatologist. It is preferable to clearly inform the user.

A non-aqueous gel 2 was prepared in the same manner as in Example 1, a) and b), and this was sealed together with c) to obtain a foam aerosol cosmetic 2 which was a foam cosmetic of the present invention. This was evaluated in the same manner as in Test Example 1. The results are shown in Table 2. It can be seen that this product has the same effect as the foam aerosol cosmetic 1. It can also be seen that it is preferable to use three types of fatty acid esters of polyglycerin as the surfactant.

Claims (9)

1. Foam cosmetic comprising 1) a fatty acid ester of polyglycerin , 2) 15 to 80% by mass of a polyhydric alcohol, and 3) 15 to 80% by mass of an oily component that is liquid at 25 ° C. and 1 atm. Characterized in that it contains two types of fatty acid esters of polyglycerol even without low, foam cosmetic composition according to claim 1. The foam cosmetic according to claim 2, wherein the fatty acid ester of at least two kinds of polyglycerol contains a mono fatty acid ester of diglycerol and a mono fatty acid ester of decaglycerol. The foamed cosmetic composition according to any one of claims 1 to 3, wherein 30 to 80 mass% of the oil component is a tetra fatty acid ester of diglycerin. The foam cosmetic according to any one of claims 1 to 4, wherein the foam cosmetic is substantially free of water. The foam cosmetic according to any one of claims 1 to 5, which is a cosmetic having a warm feeling. Furthermore, it comprises one or more selected from alkyl glycyrrhetinate, glycyrrhizic acid, ascorbic acid, ascorbic acid derivatives, arbutin, tranexamic acid, 4-methoxysalicylic acid and salts thereof, Item 7. The foam cosmetic according to any one of Items 1 to 6. The foam cosmetic according to claim 7, which is a quasi-drug that promotes anti-inflammatory action and / or melanin production-suppressing action. The foam cosmetic according to claim 7 or 8, wherein the packaging form has an indication that it has an anti-inflammatory action and / or a melanin production inhibitory action.