JP2006069974A - Face lotion or cosmetic produced by using weakly acidic concentrated mineral liquid as stock water - Google Patents
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Abstract
Description
本発明は、紫外線によるダメージや、加齢等によって弱った肌細胞に活力を与えることのできる、バーミキュライトから硫酸水溶液により抽出された強酸性のミネラル濃縮液を、低い酸化還元電位を持つ酸性の還元水を用いて希釈して、弱酸性のミネラル濃縮液とし、これを原料水として用いた化粧水または化粧品に関するものである。 The present invention provides a highly acidic mineral concentrate extracted from vermiculite with an aqueous sulfuric acid solution that can give vitality to skin cells that have been damaged by ultraviolet rays, aging, etc., and has an acidic reduction with a low redox potential. The present invention relates to a skin lotion or a cosmetic product that is diluted with water to form a weakly acidic mineral concentrate, which is used as raw material water.
紫外線は、波長の長さによって長い順にUV−A、UV−BおよびUV−Cの3種類に分けられる。このうち、UV−Cは大気のオゾン層に吸収され、地表にはほとんど届かず、肌に影響を与えることはないが、UV−Bは、日やけの原因となり、大量に浴びると炎症を伴う日やけとなる。更に、UV−Bはそのほとんどが表皮内で散乱、吸収され、真皮に届くのは10%程度であるが、表皮の基底層にある色素細胞(メラノサイト)を活性化し、メラニン色素を多く作り出し、染み、そばかす、くすみや、かさつき等の肌のトラブル原因となる。 Ultraviolet rays are classified into three types, UV-A, UV-B, and UV-C, in order of increasing wavelength. Among these, UV-C is absorbed by the ozone layer in the atmosphere, hardly reaches the surface of the earth, and does not affect the skin. However, UV-B causes sunburn, and it causes inflammation when exposed in large quantities. Sunburn. Furthermore, most of UV-B is scattered and absorbed in the epidermis, and only about 10% reaches the dermis, but it activates pigment cells (melanocytes) in the basal layer of the epidermis, producing a lot of melanin pigments, It causes skin problems such as stains, freckles, dullness, and roughness.
一方、UV−Aは表皮を透過して真皮にまで達する。そして、酸素を真皮層内で老化の原因といわれる活性酸素に変えて、コラーゲン繊維層を切断し、肌にたるみや、しわを生じさせ、老化を早める原因となる。 On the other hand, UV-A penetrates the epidermis and reaches the dermis. Then, oxygen is changed to active oxygen, which is said to cause aging in the dermis layer, and the collagen fiber layer is cut to cause sagging and wrinkles on the skin, thereby causing aging earlier.
従来、前記のような紫外線に基因する染み、そばかす、くすみや、かさつき等の肌のトラブル、および、たるみや、しわ等の肌の老化を防止、または回復を図るため、種々の化粧品や薬剤が使用されているが、本出願人の特許出願に係る特開2002−348208号公報に開示された「還元水を用いた化粧水または化粧品」も、その中の1つである。 Conventionally, various cosmetics and medicines have been used to prevent or restore skin troubles such as stains, freckles, dullness, and roughness due to ultraviolet rays as described above, and skin aging such as sagging and wrinkles. However, “a lotion or cosmetic using reduced water” disclosed in Japanese Patent Application Laid-Open No. 2002-348208 related to the applicant's patent application is one of them.
一方、雲母系鉱物が風化したバーミキュライトを無機酸水溶液に溶解させて、ミネラル濃縮液を製造し、且つ該ミネラル濃縮液を主成分として含有する酸性添加剤を、水処理用析出凝集剤とすることが、特公平1−44363号公報に開示されている。
しかしながら、前記従来の化粧品や薬剤では、紫外線に基因する染み、そばかす、あるいは、くすみや、かさつき等の肌のトラブル、および、たるみや、しわ等の肌の老化を充分に解決できないという問題があった。 However, the conventional cosmetics and medicines have a problem in that they cannot sufficiently solve skin troubles such as stains, freckles, dullness, and roughness due to ultraviolet rays, and skin aging such as sagging and wrinkles. there were.
前記特許文献1に記載された化粧水または化粧品の原料となる還元水は、pHが強アルカリ性である。この強アルカリ性の還元水は、優れた柔軟性や還元性を持っているが、アトピー等の皮膚疾患には、アルカリ性の化粧水、または化粧品は合わないので、配合する製品に制約があるという問題があった。
The lotion described in
一方、前記特許文献2に開示された方法により製造されたミネラル濃縮液を化粧品の原料水として使用することは現在なされておらず、またその発想すらなかった。
On the other hand, the mineral concentrate produced by the method disclosed in
そして、皮膚の老化について、活性酸素が大きく関わっているということはTVや雑誌の記事等で広く取り上げられ、一般の人にも知られている事実である。人には本来、身体を錆びつかせる(老化させる)原因である、活性酸素を分解する作用のある、SOD酵素を生成する機能を持っている。このSOD酵素は、生体内で合成され、過剰の活性酸素を分解し、DNA、たんぱく質、炭水化物、膜脂質の酸化的損傷を抑制する働きがある。しかし、人体にとって有益なこのSOD酵素も、年齢とともに生成能が減少して行くという問題があった。 The fact that active oxygen is greatly involved in aging of the skin is a fact that is widely taken up in TV and magazine articles and is also known to the general public. Humans originally have the function of generating SOD enzymes that have the effect of decomposing active oxygen, which is the cause of rusting (aging) the body. This SOD enzyme is synthesized in vivo, has a function of decomposing excess active oxygen and suppressing oxidative damage of DNA, protein, carbohydrate, and membrane lipid. However, this SOD enzyme, which is beneficial to the human body, also has a problem that its production ability decreases with age.
前記のように減少したSOD酵素を補うために、従来の化粧品には、SOD様作用のある様々な薬草エキス等を配合する例が見られた。しかしながら、前記SOD様作用のある様々な薬草エキス等では、作用が緩和で期待した効果が得られないという問題があった。 In order to compensate for the decreased SOD enzyme as described above, examples of blending various herbal extracts having an SOD-like action with conventional cosmetics were found. However, the various herbal extracts having the SOD-like action have a problem that the expected effect cannot be obtained due to the relaxed action.
本発明は前記観点より発明がなされたものであり、雲母系鉱物が風化したバーミキュライトから強酸である硫酸水溶液によって抽出されたミネラル濃縮液を、低い酸化還元電位を持つ酸性の還元水を用いて希釈して、弱酸性のミネラル濃縮液とし、これを化粧品の原料水として使用することにより、豊富に含んだミネラルが肌細胞に栄養を与えると同時に、金属含有酵素であるSOD酵素を活性化させ、肌本来の機能を正常な状態に戻して、たるみや、しわ等の肌の老化を予防し、なお且つ染み、そばかす、あるいは、くすみや、かさつき等の肌のトラブルを改善・防止できる優れた機能を持つ化粧水または化粧品を提供しようとするものである。 The present invention has been invented from the above viewpoint, and dilutes a mineral concentrate extracted from vermiculite whose mica-based mineral is weathered with an aqueous sulfuric acid solution that is a strong acid, using acidic reduced water having a low redox potential. By using this as a weakly acidic mineral concentrate and using it as a cosmetic raw material water, the rich minerals nourish the skin cells and at the same time activate the SOD enzyme, which is a metal-containing enzyme, Excellent skin function such as sagging and wrinkles can be restored to normal skin function, and skin troubles such as stains, freckles, dullness, and roughness can be improved and prevented. It is intended to provide a functioning lotion or cosmetic.
本発明は、原材料であるバーミキュライトに対して、25%硫酸水溶液を、4:3〜4の重量比で加え、時々攪拌しながら2〜4日間程度放置するか、あるいは100℃に加温しながら攪拌しつつ1〜4時間経過させることにより、前記バーミキュライト中の、Fe、Al、Mg、Si、K、Na等の元素や酸化物が、前記硫酸水溶液中に溶出して得られた強酸性のミネラル濃縮液を、低い酸化還元電位を持つ酸性の還元水を用いて希釈し、希釈後のミネラル濃縮液のpHを4.5〜5.5の弱酸性として、該弱酸性のミネラル濃縮液を化粧水または化粧品の原料水とすることを主要な特徴としている。 In the present invention, a 25% aqueous sulfuric acid solution is added at a weight ratio of 4: 3-4 to vermiculite, which is a raw material, and the mixture is allowed to stand for 2-4 days with occasional stirring, or heated to 100 ° C. By allowing 1-4 hours to elapse while stirring, the elements and oxides such as Fe, Al, Mg, Si, K, and Na in the vermiculite are obtained by eluting into the sulfuric acid aqueous solution. The mineral concentrate is diluted with acidic reduced water having a low oxidation-reduction potential, and the pH of the diluted mineral concentrate is made weakly acidic from 4.5 to 5.5. The main feature is that it is a lotion or a raw material water for cosmetics.
本発明化粧水または化粧品を肌に使用すると、紫外線により酸化された状態の肌に還元水中の電子が供給されて前記酸化された肌が元の状態に戻り、更に前記ミネラル濃縮液に含まれるミネラルが肌細胞に栄養を与え、肌細胞の活力を取り戻し、ターンオーバー(肌細胞の生まれ変わり)を促進し、更に、前記ミネラル濃縮液には、ミネラル分が豊富に含まれているため、活性酸素を分解する作用のあるSOD酵素が活性化され、過剰の活性酸素が発生しても、また過剰の活性酸素が残っても、前記SOD酵素の作用によりこれらが分解され、紫外線に基因する染み、そばかす、くすみや、かさつき等の肌のトラブル、および、たるみや、しわ等の肌の老化の防止、または回復を図ることができる。また、本発明の化粧水または化粧品の原料水として使用するミネラル濃縮液は、弱酸性であるため、アトピー等の皮膚疾患に適用できる化粧水または化粧品を得ることができる。 When the skin lotion or cosmetic of the present invention is used on the skin, electrons in the reduced water are supplied to the skin oxidized by ultraviolet rays so that the oxidized skin returns to the original state, and further the mineral contained in the mineral concentrate Nourishes skin cells, restores vitality of skin cells, promotes turnover (reincarnation of skin cells), and the mineral concentrate contains abundant minerals. Even if the SOD enzyme having an action of decomposing is activated and excessive active oxygen is generated or excessive active oxygen remains, these are decomposed by the action of the SOD enzyme, stains caused by ultraviolet rays, freckles It is possible to prevent or restore skin troubles such as dullness and roughness, and skin aging such as sagging and wrinkles. Moreover, since the mineral concentrate used as the skin lotion or cosmetic raw water of the present invention is weakly acidic, a skin lotion or cosmetic that can be applied to skin diseases such as atopy can be obtained.
本発明者は、前記特許文献2に開示された方法により製造されたミネラル濃縮液を、1000倍に希釈して農業用の水として植物に使用したところ、多くの有用性が確認できた。本来植物は、土というミネラルそのものを母体基盤として、光合成して成長するが、この光合成における触媒が、ミネラル群である。多くのミネラルを含有する前記ミネラル濃縮液は、当然の如く植物の成長に多大な影響を与えることになる。このことは植物の発芽、発根の促進、葉・茎・枝の伸長、果実の熟成と糖度増進等において顕著な効果をあらわしている。
When this inventor diluted the mineral concentrate manufactured by the method disclosed by the said
前記のような植物細胞に与える効果から、ヒト腺維芽細胞への賦活効果も、同様に期待できると考えられ、然も含有成分として、Fe、Al、Mgを特に多く含むので、皮膚細胞の収斂効果があることがわかる。また、ミネラルを含むミネラル濃縮液を配合した化粧品は、金属含有酵素であるSOD酵素に働きかけ、その活性酸素分解作用を促進して、肌老化防止効果も期待できると考えられる。 From the effects given to plant cells as described above, the activation effect on human glandular fibroblasts is also expected to be expected, and since it contains a particularly large amount of Fe, Al and Mg as contained components, It turns out that there is a convergence effect. Moreover, it is thought that the cosmetics which mix | blended the mineral concentrate containing a mineral work on the SOD enzyme which is a metal containing enzyme, promote the active oxygen decomposition | disassembly effect | action, and can anticipate the skin aging prevention effect.
本発明者は、原材料であるバーミキュライトに対して、25%硫酸水溶液を、4:3〜4の重量比で加え、時々攪拌しながら2〜4日間程度放置するか、あるいは100℃に加温しながら攪拌しつつ、1〜4時間経過させることにより、前記バーミキュライト中の、Fe、Al、Mg、Si、K、Na等の元素や酸化物を、硫酸水溶液中に溶出させて、強酸性のミネラル濃縮液を生成した。 The present inventor added a 25% sulfuric acid aqueous solution at a weight ratio of 4: 3-4 to vermiculite, which is a raw material, and left it for about 2-4 days with occasional stirring, or heated to 100 ° C. By stirring for 1 to 4 hours while stirring, elements and oxides such as Fe, Al, Mg, Si, K, and Na in the vermiculite are eluted in a sulfuric acid aqueous solution, and a strongly acidic mineral A concentrate was produced.
本発明で使用するミネラル濃縮液は、雲母系鉱物が風化したバーミキュライト(Vermicurite)(日本名 蛭石)と呼ばれる天然の粘土鉱物から抽出したものであり、抽出の際に使用される薬剤も、無機物のみを使用しているので、生成後のミネラル濃縮液への有機物の含有は皆無である。 The mineral concentrate used in the present invention is extracted from a natural clay mineral called vermiculite (Japanese name: meteorite) in which mica-based minerals are weathered. No organic substances are contained in the mineral concentrate after production.
含有ミネラル豊富な前記ミネラル濃縮液の組成としては、Fe、Al、Mgが特に多く、その他にも、K、Ti、Ca、P、Mn等20種類以上のミネラルが分析上確認された。なお、As、Pb、Cd、Hg、Cr等の有害重金属は検出されなかった。そして、前記ミネラル濃縮液は、淡黄色で、その比重は1.1〜1.2、pH0.5〜1.0という強酸性を示すが、通常の水を添加し希釈して使用する場合、そのpHはほぼ弱酸性〜中性になるので、化粧品の原料として使用することにはなんら問題はない。 As the composition of the mineral concentrate rich in contained minerals, Fe, Al, and Mg are particularly abundant, and in addition, 20 or more kinds of minerals such as K, Ti, Ca, P, and Mn were analytically confirmed. In addition, no harmful heavy metals such as As, Pb, Cd, Hg, and Cr were detected. And, the mineral concentrate is light yellow, its specific gravity is 1.1-1.2, and shows strong acidity of pH 0.5-1.0, but when adding normal water and diluting it, Since its pH is almost weakly acidic to neutral, there is no problem in using it as a raw material for cosmetics.
本発明者は、本発明で使用するミネラル濃縮液の有効性、安全性を充分に確認した上で、該ミネラル濃縮液を配合した化粧品を試作した。本来、強酸性のミネラル濃縮液の原液は、水で希釈してpHを中性付近に調節するが、化粧品に配合する場合は、肌への作用を考慮して、希釈する水に電気分解によって水を活性化して分子を微細化(マイクロクラスタ)し、低い酸化還元電位を持つ酸性の還元水を使用した。 The present inventor made a trial manufacture of a cosmetic containing the mineral concentrate after sufficiently confirming the effectiveness and safety of the mineral concentrate used in the present invention. Originally, the stock solution of strongly acidic mineral concentrate is diluted with water to adjust the pH to near neutrality. However, when blended into cosmetics, taking into account its effect on the skin, electrolyze the diluted water by electrolysis. Water was activated to refine the molecules (microclusters), and acidic reduced water having a low redox potential was used.
前記本発明に使用する酸性の還元水は、図1に示す3室型電解槽Aを用いて生成された還元水を使用する。すなわち、図1に示す電解槽は、カソード室1とアノード室2との間に、間隔を有して隔膜3・4を配設して中間室5を設け、且つ前記カソード室1とアノード室2の中に、それぞれカソード極6とアノード極7を配設して形成されている。そして、カソード室1とアノード室2に純水を入れると共に、中間室5にクエン酸を入れて電気分解すると、カソード室1内においては還元水が生成され、一方アノード室2内においては酸性水が生成される。
The acidic reduced water used in the present invention uses reduced water produced using the three-chamber electrolytic cell A shown in FIG. That is, the electrolytic cell shown in FIG. 1 is provided with an
通常、強アルカリイオン水を生成するときは、中間室5内に食塩を入れるが、本発明に使用する還元水においては、中間室5内にクエン酸を入れることによって、カソード室1内で酸性の還元水を生成することに成功した。また、前記中間室5内に入れる酸は、前記クエン酸以外のアスコルビン酸や、その他の有機酸でも、酸性の還元水を生成することは可能である。
Usually, when producing strong alkaline ionized water, sodium chloride is put in the
本発明においては、カソード室1内において生成された酸性の還元水を使用する。そして、前記生成された還元水の生成時におけるpHと酸化還元電位(ORP)を測定すると、pHは3.5〜5.0、ORPが−200〜−550mV程度であって、マイナスの酸化還元電位をもちながら、pHが中酸性の還元水であることが判った。一般に、pHが中酸性である場合の酸化還元電位は、プラスの数値を示すが、本発明で採用される還元水は、前記したように、マイナスの酸化還元電位をもつ特殊な水ということができる。
In the present invention, acidic reduced water generated in the
前記酸性の還元水で、希釈されたミネラル濃縮液のpHは4.5〜5.5の皮膚とほぼ同じ弱酸性に保たれ、殺菌・抗菌作用を持つことにより、アトピー肌にも効果が期待できる。 The pH of the diluted mineral concentrate diluted with the acidic reducing water is kept at about the same weak acidity as that of skin of 4.5 to 5.5. it can.
そして、本発明によって得られた酸性の還元水で希釈されたミネラル濃縮液のpHを5の弱酸性として、該弱酸性のミネラル濃縮液100%をそのまま(香料等の成分を全く添加していない状態)、20歳の女性の手に塗布してテストした。そして、その経過を株式会社アイ・ティ・オー製の商品名「ビューティースコープEX−400」(最新型小型高性能ビデオルーペ40倍率レンズ)で、シミ・シワなどの変化と持続性につき調査したところ、図2〜図4の写真に示すような結果が得られた。すなわち、図2の写真は、前記ミネラル濃縮液を塗布する前の状態を示すもので、皮膚がウロコ(白い部分)のようにめくれてカサついて(乾燥)おり、更にくすみも見られる。図3の写真は、前記ミネラル濃縮液を毎日塗布して3日後の写真で、全体的にカサつき(乾燥)は改善されているが、くすみが取れていない。また、図4の写真は、前記ミネラル濃縮液を毎日塗布して10日後の写真で、カサつき部分がなくなり、更にキメが細かくなると共に、くすみもなくなっているのが確認できた。 And the pH of the mineral concentrate diluted with the acidic reduced water obtained by the present invention is set to 5 weak acidity, and the weakly acidic mineral concentrate 100% is left as it is (no components such as fragrance are added) Condition), applied to the hand of a 20-year-old woman and tested. And the progress was investigated for changes and sustainability of stains and wrinkles with the brand name "Beauty Scope EX-400" (the latest compact high-performance video loupe 40 magnification lens) manufactured by IT Corporation. The results as shown in the photographs of FIGS. 2 to 4 were obtained. That is, the photograph of FIG. 2 shows a state before the mineral concentrate is applied, and the skin is turned up like a scale (white part) and is dry (dry), and further dullness is seen. The photograph of FIG. 3 is a photograph three days after the mineral concentrate was applied every day, and the overall dryness was improved, but the dullness was not removed. Moreover, the photograph of FIG. 4 is the photograph 10 days after apply | coating the said mineral concentrate every day, and it has confirmed that the part with a rust disappeared, the texture became finer, and the dullness disappeared.
以上のテストにより、酸性の還元水で希釈されたミネラル濃縮液はカサつき、シミ・シワ等をなおすだけでなく、皮膚の状態を変えながら治す力を持っていることが判った。また、1度カサつきをなくすことで、皮膚の持つ本来の質を保持する効果があるので、一度還元した皮膚は再度皮膚表面がカサつくことがなく、皮膚が再度カサつきにくい皮膚質に変えていくということが判った。 From the above tests, it was found that the mineral concentrate diluted with acidic reducing water has the power to heal not only to fix blemishes, wrinkles, etc., but also to change the skin condition. In addition, eliminating the stuffiness once has the effect of preserving the original quality of the skin, so once the skin has been reduced, the skin surface will not become stuffy again, and the skin will be changed to a stuffy material that is less stuffy. I found out that
以上のことより、本発明に使用される前記ミネラル濃縮液は持続性および免疫力があるという確証が得られた。なお、前記テストは前記ミネラル濃縮液をそのまま化粧水として使用した場合のものであるが、前記ミネラル濃縮液をクリーム等の化粧品の原料水と使用しても、同様の効果が得られると考えられる。 From the above, confirmation that the mineral concentrate used in the present invention has durability and immunity was obtained. In addition, although the said test is a thing at the time of using the said mineral concentrate as a lotion as it is, even if it uses the said mineral concentrate with raw material water of cosmetics, such as cream, it is thought that the same effect is acquired. .
そして、前記ミネラル濃縮液を前記酸性の還元水で、10000倍に希釈し、これを原料水としてローションとクリームを試作し、数人のモニターに使用してもらった。
以下は使用してみた感想の一部である。
・ 26歳(女性)肌のくすみがなくなり、化粧ののりも良くなったような気がする。
・ 29歳(女性)肌荒れがなくなり、肌が滑らかによりすべすべになった。
・ 28歳(女性)染みが薄くなったような気がする。
Then, the mineral concentrate was diluted 10,000 times with the acidic reducing water, and a lotion and a cream were made as a trial using this as raw material water, and used by several monitors.
Here are some of the thoughts I've used:
・ 26 years old (female) I feel that my skin has been dull and my makeup has improved.
・ 29 years old (female) No rough skin, smoother and smoother skin.
・ 28 years old (female) I feel like the stain has faded.
モニターの感じた肌のくすみや、染みの改善については、ミネラル濃縮液に含まれるミネラルが肌細胞に栄養を与えることによる細胞賦活効果が、弱っていた細胞の活力を取り戻し、ターンオーバーを促進し、表皮内の古い細胞やメラニンを体外に排泄した結果だと推測される。更に、前記ミネラルが過剰の活性酸素を分解する作用のあるSOD酵素を活性化させ、肌の老化の原因である過剰の活性酸素が分解された結果であるとも推測される。 As for skin dullness and stain improvement felt by the monitor, the cell activation effect by the minerals contained in the mineral concentrate nourishing the skin cells restores the vitality of the weakened cells and promotes turnover. It is speculated that this is the result of excreting old cells and melanin in the epidermis. Furthermore, it is speculated that this is the result of the minerals activating the SOD enzyme that has the action of decomposing excess active oxygen, and the decomposition of excess active oxygen that causes skin aging.
また、肌荒れの改善や肌の滑らかさについては、pHを弱酸性の調整することで殺菌・抗菌効果を持たせて皮膚上の雑菌等の繁殖を防ぎ、ミネラル濃縮液に含まれるMgやAlによる収斂作用が肌のキメを整える効果によるものと思われる。 In addition, with regard to the improvement of rough skin and the smoothness of the skin, the pH is adjusted to be weakly acidic to provide a bactericidal and antibacterial effect to prevent the growth of germs on the skin, and Mg and Al contained in the mineral concentrate It seems that the astringent action is due to the effect of adjusting the texture of the skin.
A 3室型電解槽
1 カソード室
2 アノード室
3・4 隔膜
5 中間室
6 カソード極
7 アノード極
A Three-chamber
Claims (1)
A 25% sulfuric acid aqueous solution is added to the raw material vermiculite in a weight ratio of 4: 3 to 4, and left for about 2 to 4 days with occasional stirring, or 1 while stirring at 100 ° C while heating. A strong acid mineral concentrate obtained by elution of elements and oxides such as Fe, Al, Mg, Si, K, Na, etc. in the vermiculite into the sulfuric acid aqueous solution by allowing -4 hours to pass. It is diluted with acidic reduced water having a low redox potential obtained by electrolyzing pure water using a three-chamber electrolytic cell, and the pH of the diluted mineral concentrate is 4.5 to 5. No. 5 weakly acidic lotion or cosmetic using the weakly acidic mineral concentrate as raw water.
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| JP2004256441A JP2006069974A (en) | 2004-09-03 | 2004-09-03 | Face lotion or cosmetic produced by using weakly acidic concentrated mineral liquid as stock water |
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| JP2004256441A JP2006069974A (en) | 2004-09-03 | 2004-09-03 | Face lotion or cosmetic produced by using weakly acidic concentrated mineral liquid as stock water |
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|---|---|---|---|---|
| FR2891138A1 (en) * | 2005-09-23 | 2007-03-30 | Gattefosse Sas Soc Par Actions | Use of iron as skin fibroblast collagen synthesis stimulant in anti-aging, care or cleaning products, skin make-up product, solar or capillary protection product and to treat skin aging |
| FR2911495A1 (en) * | 2007-01-23 | 2008-07-25 | Oreal | COSMETIC USE OF IRON ASSOCIATIONS FOR SKIN CARE. |
| JPWO2010073667A1 (en) * | 2008-12-24 | 2012-06-07 | 国立大学法人 千葉大学 | UV protection |
| JP2013212498A (en) * | 2012-03-07 | 2013-10-17 | Tatehiko Ogawa | Reduction powder, and method of producing the same |
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| JPH08113524A (en) * | 1994-10-13 | 1996-05-07 | Tatsuo Okazaki | Toilet water containing mineral |
| JP2000079391A (en) * | 1998-09-07 | 2000-03-21 | Mizu Kk | Production of reducing electrolytic water |
| JP2002145737A (en) * | 2000-11-10 | 2002-05-22 | Yashiro Kogyo Kk | Cosmetics containing ancient salt water. |
| JP2003306407A (en) * | 2002-04-18 | 2003-10-28 | Hiromaito Co Ltd | Reductive aqueous composition, cosmetic and use of the same |
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| JPS6122010A (en) * | 1984-07-06 | 1986-01-30 | Kurotai Shigeo | Water quality improver for bath water |
| JPH08113524A (en) * | 1994-10-13 | 1996-05-07 | Tatsuo Okazaki | Toilet water containing mineral |
| JP2000079391A (en) * | 1998-09-07 | 2000-03-21 | Mizu Kk | Production of reducing electrolytic water |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2891138A1 (en) * | 2005-09-23 | 2007-03-30 | Gattefosse Sas Soc Par Actions | Use of iron as skin fibroblast collagen synthesis stimulant in anti-aging, care or cleaning products, skin make-up product, solar or capillary protection product and to treat skin aging |
| WO2007036667A1 (en) * | 2005-09-23 | 2007-04-05 | Gattefosse S.A.S. | Use of iron in the form of a stone extract as stimulus of the synthesis of collagen by skin fibroblasts |
| FR2911495A1 (en) * | 2007-01-23 | 2008-07-25 | Oreal | COSMETIC USE OF IRON ASSOCIATIONS FOR SKIN CARE. |
| WO2008090489A3 (en) * | 2007-01-23 | 2009-05-22 | Oreal | Cosmetic skincare use of iron gluconate combinations |
| JPWO2010073667A1 (en) * | 2008-12-24 | 2012-06-07 | 国立大学法人 千葉大学 | UV protection |
| JP2013212498A (en) * | 2012-03-07 | 2013-10-17 | Tatehiko Ogawa | Reduction powder, and method of producing the same |
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