JP2005325091A - External preparation composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To obtain an external preparation composition containing an oily component having excellent oxidation stability. <P>SOLUTION: (1) This external preparation composition comprises an oily component obtained from the seed of moringa. (2) The external preparation composition comprises 0.001-100 wt.% of the oily component obtained from the seed of moringa. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

  The present invention relates to an external composition containing an oily component obtained from Moringa seeds. Here, the external preparation composition includes detergents such as shampoos, rinses and facial cleansing foams, basic cosmetics, makeup cosmetics, hair cosmetics, aromatic cosmetics, cosmetics such as body cosmetics, quasi drugs and pharmaceuticals.

  Oily ingredients are blended in external preparation compositions such as cleaning agents, cosmetics, and pharmaceuticals for various purposes such as suppressing the transpiration of moisture from the skin, setting the hair, and improving the feeling of use. These oily components include animal and vegetable oils and fats, waxes, hydrocarbons, higher fatty acids, higher alcohols, esters, silicone oils, and the like, which are properly used depending on the characteristics such as chemical and physical properties and feeling of use.

  Of these, olive oil, soybean oil, camellia oil, sunflower oil, macadamia nut oil and the like have been used as vegetable oils in rinses, emulsions, creams, lipsticks, hairdressing agents, body cosmetics, and the like. However, none of them are satisfactory in terms of oxidation stability, especially at high temperatures and long-term stability, and the formula is assembled by constantly reducing the compounding amount and adding a large amount of antioxidant. Was the current situation.

  This invention is made | formed under the above situations, and makes it a subject to provide the external preparation composition containing the oil-based component excellent in oxidation stability.

The present invention
1. An external preparation composition comprising an oily component obtained from moringa seeds.
2. The external preparation composition according to claim 1, wherein the oily component obtained from the seeds of Moringa is 0.001 to 100% by weight.
The above-mentioned problem is solved by means comprising the above.

  Experiments on the oxidative stability of oily components obtained from moringa seeds used in the present invention (also referred to as “WASABINOKI SEED OIL” as the corresponding INCI name, or “moringa oil” as common name; hereinafter referred to as “MORINGA OIL”) The data is shown in FIG. According to FIG. 1, it can be seen that the stability of moringa oil is higher than any of the other vegetable oils conventionally used. Therefore, the external preparation composition of the present invention has excellent oxidation stability, and a large amount of moringa oil can be added to the external preparation composition, and it is not necessary to add a large amount of antioxidant.

Hereinafter, the configuration of the present invention will be described in detail.
The moringa oil of the present invention is obtained from Moringa oleifera seeds. The production method is not particularly limited, but it is general to use crude oil obtained by squeezing seeds after purification such as clay treatment or heat treatment.

  Further, one or more stabilizers such as tocopherol, malic acid, kojic acid and ascorbic acid may be added. The blending amount is preferably 0.005 to 5% by weight (hereinafter simply referred to as%) of Moringa oil.

  In the external preparation composition of the present invention, the preferred blending amount of Moringa oil is 0.001 to 100% in the external preparation composition, although it depends on the dosage form and function. If it is less than 0.001%, it is insufficient to exhibit the function as an oil component. Depending on the function of the preparation, 100% is blended.

  The external preparation composition of this invention can mix | blend the other component normally used for an external preparation composition according to the objective other than said moringa oil. Examples of such other components include the following components, and one or more of these components are blended and manufactured according to a conventional method.

  The following can be mentioned as an oil-based component. Olive oil, camellia oil, macadamia nut oil, castor oil, avocado oil, wheat germ oil, safflower oil, cottonseed oil, soybean oil, tea seed oil, sunflower oil, evening primrose oil, coconut oil, palm oil, palm kernel oil, beef tallow, horse Fats and oils such as cacao butter and owl, carnauba wax, candelilla wax, jojoba oil, beeswax, lanolin and other waxes, liquid paraffin, paraffin, petrolatum, ceresin, microcrystalline wax, squalane hydrocarbons, lauric acid, Higher fatty acids such as myristic acid, palmitic acid, stearic acid, isostearic acid, behenic acid, oleic acid, linoleic acid, linolenic acid, cetyl alcohol, stearyl alcohol, isostearyl alcohol, 2-octyldodecanol, batyl alcohol, lanolin alcohol, Cholesterol, fi Higher alcohols such as sterol, isopropyl myristate, 2-octyldodecyl myristate, cetyl octanoate, cetyl 2-ethylhexanoate, pentaerythritol tetraester, diisostearyl malate, triethyl citrate, cholesteryl stearate, phytoisostearate Stearyl, ethoxydiglycol pehenate, esters such as ethoxydiglycol oleate, methylpolysiloxane, methylphenylpolysiloxane, cyclic dimethylsilicone oil, alkyl-modified silicone, amino-modified silicone, three-dimensional network silicone, silicone rubber, etc. Silicone.

  The following can be mentioned as a polyhydric alcohol. Glycerin, diglycerin, propylene glycol, dipropylene glycol, 1,3-butylene glycol, diethylene glycol, polyethylene glycol, ethoxydiglycol, heptanediol, octanediol and the like.

  The following can be mentioned as saccharides. Sorbitol, mannitol, sucrose, lactose, xylitol, maltitol, trehalose, etc.

  Examples of the polymer compound include the following. Natural polymers such as guar gum, quince seed, pectin, mannan, agar, carrageenan, xanthan gum, curdlan, gelatin, casein, collagen, semi-synthetic high such as methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, carboxymethylcellulose, alginate Molecules, polyvinyl alcohol, polyvinylpyrrolidone, carboxyvinyl polymer, polyacrylic acid soda, synthetic polymers such as POE / POP copolymer, inorganic polymers such as bentonite and laponite, amphoteric methacrylate copolymer, cationized cellulose , Polydimethylpiperidinium chloride, Polyvinyl acetate, Polyacrylate copolymer, Polyvinyl acetate, Nitrocellulose, High molecular silicone, Silicone Film-forming polymer resin, and the like.

  The following can be mentioned as surfactant. Higher fatty acid soap, alkylbenzene sulfonate, alkyl sulfate, POE alkyl ether sulfate, acyl N-methyl taurate, alkyl ether phosphate, N-acyl amino acid salt, α-olefin sulfonate, POE alkyl ether Anionic surfactants such as carboxylates, cationic surfactants such as alkyltrimethylammonium chloride, dialkyldimethylammonium chloride, benzalkonium chloride, alkyldimethylaminoacetic acid betaines, alkylamidopropyl dimethylaminoacetic acid betaines, 2- Amphoteric surfactants such as alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, glyceryl monofatty acid ester, sorbitol monofatty acid ester, sorbitan monofatty acid ester Sugar fatty acid esters, POE alkyl ethers, POE alkyl phenyl ethers, alkanolamides, ethylene oxide-propylene oxide block copolymer, POE hardened castor oil derivatives, nonionic surfactants such as alkyl amine oxides.

  Examples of the powder and colorant include the following. Inorganic powders such as talc, kaolin, mica, magnesium aluminum silicate, silicic anhydride, titanium oxide, mica titanium, zinc white, zeolite, organic powders such as nylon powder, polyethylene powder, cellulose powder, silk powder, metal soap , Inorganic pigments, pearl pigments, organic pigments, tar dyes, natural dyes, etc.

  The following can be mentioned as animal and plant extracts. Mucopolysaccharides such as sodium hyaluronate and sodium chondroitin sulfate, animal extracts such as chitin / chitosan, collagen, elastin, peptides, aloe extract, prunus extract, nettle extract, chamomile extract, licorice extract, walnut seed extract, shikon extract, birch Extract, Achillea millefolium extract, Pepper extract, Tea extract, Toki extract, Garlic extract, Carrot extract, Hamamelis extract, Hinokithiol, Loquat leaf extract, Beech tree seedling extract, Loofah extract, Safflower extract, Willow extract, Peach leaf Plant extracts such as extracts, eucalyptus extracts, and rose water.

  Examples of the bactericidal / preservative include the following. Benzoic acid, sodium benzoate, salicylic acid, sorbic acid, paraoxybenzoic acid ester (ethyl paraben, butyl paraben, etc.), trichlorocarbanilide, phenoxyethanol, hexachlorophene, benzalkonium chloride, chlorhexidine, zinc pyrithione, triclosan and the like.

  The following can be mentioned as antioxidant. Gallic acid ester, sodium bisulfite, etc. Examples of the antioxidant assistant include the following. Phosphoric acid, citric acid, maleic acid, malonic acid, succinic acid, fumaric acid, kephalin, phytic acid, EDTA, etc.

  Examples of the metal sequestering agent include the following. Edetate, hydroxyethanediphosphonic acid, phosphoric acid, citric acid, succinic acid, phytic acid, etc.

  The following can be mentioned as a ultraviolet absorber. Benzophenone derivatives such as 2-hydroxy-4-methoxybenzophenone and 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid, paraaminobenzoic acid derivatives such as paraaminobenzoic acid and octylparadimethylaminobenzoate, octyl paramethoxycinnamate, diparamethoxy Methoxycinnamic acid derivatives such as mono-2-ethylhexanoic acid glyceryl cinnamate, salicylic acid derivatives such as octyl salicylate, urocanic acid and the like.

  The following can be mentioned as various chemical | medical agents. Whitening agents such as arbutin, kojic acid, vitamin C, assembly extract, gamma-oryzanol, capsicum tincture, nicotinic acid benzyl ester, estradiol, ethinyl estradiol, pantothenic acid, photosensitizing agent 301 and other hair growth agents, β-glycyrrhetinic acid, Glycyrrhizic acid derivatives, allantoin, ε-aminocaproic acid, zinc oxide, aluminum sulfate, tannic acid, lactic acid, menthol, corticosteroids, antihistamines and other rough skin prevention agents, sulfur, salicylic acid, resorcin, benzalkonium chloride, halocarban, etc. Anti-acne agents, chlorohydroxyaluminum, aluminum chloride, antiperspirants such as zinc oxide, vitamin A and its derivatives, vitamin B6 hydrochloride, vitamin B6 tripalmitate, vitamin B6 dioctanoate, vitamin B2 and its derivatives, vitamin B such as vitamin B12, vitamin B15 and its derivatives, ascorbic acid, ascorbic acid phosphate ester (salt), vitamin C such as ascorbic acid dipalmitate, α-tocopherol, β-tocopherol, γ -Vitamin E such as tocopherol, vitamin E acetate, vitamin E nicotinate, vitamins such as vitamin D, vitamin H, pantothenic acid, panthetin, glycine, alanine, valine, leucine, serine, threonine, phenylalanine, tyrosine, aspartic acid Amino acids such as asparagine, glutamine, taurine, arginine, histidine and their hydrochlorides.

  The dosage form of the external preparation composition of the present invention is in the form of powder, solid, liquid, emulsion, gel, cream, spray, aerosol foam, powder dispersion, etc., shampoo, rinse, hair conditioner, soap, Body shampoo, massage oil, cleansing foam, pack mask, lotion, milky lotion, cream, gel, face powder, foundation, lipstick, eyeliner, mascara, eye shadow, nail enamel, hair restorer, hair styling agent, hair color, It can be applied to permanent wave agents, bathing agents, fragrances, sun care agents, deodorant agents and the like.

  Next, the present invention will be described more specifically with reference to examples. In addition, this invention is not limited only to these Examples. Unless otherwise specified, the blending amount is expressed in weight%.

<Shampoo>
Lauryl POE (3) sulfate ester Na salt (30% aqueous solution) 35.00
Lauryl sulfate Na salt (30% aqueous solution) 10.00
Palm fatty acid diethanolamide 3.00
Moringa oil ¹⁾ 2.00
1,3-butylene glycol 2.00
Preservative, metal sequestering agent appropriate amount
Purified water to 100
* 1) "Floralipids Moringa Oil", Floratech
This shampoo was good for fingering during rinsing and excellent in long-term storage stability.

<Rinse>
Stearyltrimethylammonium chloride 0.70
Cetyl alcohol 1.50
Stearyl alcohol 1.00
Moringa oil ¹⁾ 3.00
Methylphenylpolysiloxane 1.00
Glycerin 5.00
Preservative, metal sequestering agent appropriate amount
Purified water to 100
This rinse was a moist type and excellent in long-term storage stability.

<Body shampoo>
Lauric acid 10.00
Myristic acid 2.00
Palmitic acid 2.00
Oleic acid 6.00
Potassium hydroxide (85%) 5.18
Cocamidopropyl betaine (30% aqueous solution) 6.00
Coacamide MEA 1.50
Hydroxypropylcellulose 0.10
Moringa oil ¹ ) 1.50
α-Tocopherol 0.02
Metal sequestering agent Appropriate amount Perfume, dye Appropriate amount
Purified water to 100
This body shampoo had a smooth feeling after use and had excellent long-term storage stability.

<Massage oil>
Ethyl macadamite ²⁾ 15.00
Jojoba ester ³⁾ 15.00
Sunflower oil ⁴⁾ 15.00
Moringa oil ¹⁾ 15.00
Olive oil 20.00
Capric / Capric Triglyceride 20.00
* 2) Floratec “Floracac 10”
* 3) Floratech “Floraesters 15”
* 4) Florate “Florasun 90”
This massage oil was a light type, had an appropriate ease of sliding on the skin, and was excellent in long-term storage stability.

<Massage oil>
Moringa oil ¹⁾ 89.95
Olive oil 10.00
α-Tocopherol 0.05
This massage oil is a heavy type, has an appropriate ease of sliding on the skin, and has excellent long-term storage stability.

<Peel-off type mask>
Polyvinyl acetate emulsion 15.00
Polyvinyl alcohol 10.00
Sorbitol 4.00
PEG400 6.00
Moringa oil ¹⁾ 3.00
POE sorbitan monostearate 1.00
Titanium oxide 5.00
Talc 10.00
Ethanol 8.00
Preservative appropriate amount Fragrance proper amount
Purified water to 100
This mask was a moist type and had excellent long-term storage stability.

<Hand & body lotion>
Purified water to 100
Acrylate / C10-30 alkyl acrylate copolymer 0.25
CARBOMER 0.05
EDTA2Na 0.10
Glycerin 5.00
Hydroxyethyl cellulose 0.20
Phenoxyethanol 1.00
Moringa oil ¹⁾ 5.00
Ores-10 0.30
Tocopherol 0.01
Perfume
Hydrolyzed jojoba ester ⁵⁾ 4.00
* 5) Floratec's “Floraesters K-20W Jojoba”
This hand and body lotion was light and easy to apply, and had excellent long-term storage stability.

<Emollient cream>
Stearyl alcohol 4.00
Cetyl alcohol 2.00
Stearic acid 2.00
Hydrogenated lanolin 4.00
Liquid paraffin 3.00
Moringa oil ¹⁾ 5.00
Octyldodecanol 10.00
1,3-butylene glycol 6.00
PEG1500 4.00
POE (25) cetyl alcohol ether 3.00
Glycerol monostearate 2.00
α-Tocopherol 0.01
Preservative appropriate amount Fragrance proper amount
Purified water to 100
This emollient cream was a moist type and excellent in long-term storage stability.

<Liquid type foundation>
Stearic acid 2.00
Isohexadecyl alcohol 6.00
Glycerol monostearate 2.00
Moringa oil ¹⁾ 2.00
Liquid paraffin 5.00
Talc 3.00
Titanium dioxide 5.00
Bengala 0.50
Yellow iron oxide 1.20
Black iron oxide 0.10
Bentonite 0.50
Polyoxyethylene sorbitan monostearate 0.90
Triethanolamine 1.00
Propylene glycol 8.00
Preservative appropriate amount Fragrance proper amount
Purified water to 100
The foundation had smooth usability and excellent long-term storage stability.

<Lipstick>
Solid paraffin 9.00
Candelilla Row 8.00
Beeslow 6.00
Carana Barrow 4.00
Castor oil 15.18
Lanolin 12.00
Moringa oil ¹⁾ 10.00
Cetyl 2-ethylhexanoate 20.00
Isopropyl myristate 10.00
α-Tocopherol 0.02
Titanium dioxide 4.00
Red 201 No. 0.60
Red No. 202 1.00
Red 223 0.20
Perfume Appropriate amount This lipstick is smooth and glossy and has excellent long-term storage stability.

<Hair wax>
White petrolatum 36.50
Beeslow 6.00
Cyclomethicone, quartz-18 hectorite,
SD alcohol 40 4.00
Moringa oil ¹⁾ 7.00
Talc 2.00
Carana Barrow 6.00
Purified water to 100
Jojoba wax PEG-120 ester ⁶⁾ 10.00
Preservative appropriate amount Fragrance proper amount
Tocopherol 0.01
* 6) Floratech "Florasolves PEG-120 Joba"
This hair wax provided a conditioning effect and gloss, and was excellent in long-term storage stability.

<Hair oil>
Liquid paraffin 89.98
Moringa oil ¹⁾ 10.00
Perfume
Tocopherol 0.02
This hair oil gives smoothness and gloss, and has excellent long-term storage stability.

<Sant Angel>
Liquid paraffin 70.95
Moringa oil ¹⁾ 12.00
Olive oil 10.00
Organically modified montmorillonite 5.00
Octyl paramethoxycinnamate 2.00
BHT 0.05
Fragrance, pigment Appropriate amount This santangel was a smooth gel and had excellent long-term storage stability.

<Emulsion bath>
Liquid paraffin 60.99
Squalane 10.00
Moringa oil ¹ ) 5.00
Olive oil 5.00
Sorbitan oleate 5.00
POE oleyl ether 10.00
BHT 0.01
Purified water 1.00
Fragrance 3.00
This bath agent has a smooth skin feel and is excellent in long-term storage stability.

Experimental data on the oxidative stability of moringa oil is shown in comparison with conventionally used vegetable oils. The vertical axis represents the oxidation stability index, and the larger the value, the higher the oxidation stability. In this figure, it can be seen that the stability of the moringa oil used in the present invention is higher than that of any other vegetable oil conventionally used.

Claims (2)

An external preparation composition comprising an oily component obtained from moringa seeds. The external preparation composition according to claim 1, wherein the oily component obtained from the seeds of Moringa is 0.001 to 100% by weight.

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