JP2005314390A - Manicure preparation - Google Patents
Manicure preparation Download PDFInfo
- Publication number
- JP2005314390A JP2005314390A JP2005098982A JP2005098982A JP2005314390A JP 2005314390 A JP2005314390 A JP 2005314390A JP 2005098982 A JP2005098982 A JP 2005098982A JP 2005098982 A JP2005098982 A JP 2005098982A JP 2005314390 A JP2005314390 A JP 2005314390A
- Authority
- JP
- Japan
- Prior art keywords
- fiber
- component
- nail
- interference
- red
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
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- 235000005985 organic acids Nutrition 0.000 description 1
- 150000001282 organosilanes Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 description 1
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- 229920000728 polyester Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
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- 229920013716 polyethylene resin Polymers 0.000 description 1
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- 229920000098 polyolefin Polymers 0.000 description 1
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- 238000001556 precipitation Methods 0.000 description 1
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- KXXXUIKPSVVSAW-UHFFFAOYSA-K pyranine Chemical compound [Na+].[Na+].[Na+].C1=C2C(O)=CC(S([O-])(=O)=O)=C(C=C3)C2=C2C3=C(S([O-])(=O)=O)C=C(S([O-])(=O)=O)C2=C1 KXXXUIKPSVVSAW-UHFFFAOYSA-K 0.000 description 1
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- 229920006395 saturated elastomer Polymers 0.000 description 1
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- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
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- AZLXCBPKSXFMET-UHFFFAOYSA-M sodium 4-[(4-sulfophenyl)diazenyl]naphthalen-1-olate Chemical compound [Na+].C12=CC=CC=C2C(O)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 AZLXCBPKSXFMET-UHFFFAOYSA-M 0.000 description 1
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Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、新規な外観及び化粧効果に優れた美爪料に関し、さらに詳細には、高彩度で光輝性に優れた外観を有し、また、塗布部位に形成される化粧膜が高彩度であり、塗布部位の質感を光学的に変化させることにより、従来にない透明感や立体感、つや感等の化粧効果をネイルに付与でき、且つ、安定性も良好な美爪料に関するものである。 The present invention relates to a beautiful nail material having a novel appearance and a cosmetic effect, and more specifically, has an appearance with high chroma and glitter, and a cosmetic film formed at the application site has high chroma, The present invention relates to a beauty nail material which can impart unprecedented cosmetic effects such as a sense of transparency, a three-dimensional effect, and a glossy feeling to the nail by optically changing the texture of the application site, and also has good stability.
美爪料は、幅広い色調を要求されるポイントメイクアップ製品の一つである。この美爪料には、従来より、有機顔料、無機顔料等の着色剤、パール剤、ラメ等の光輝性粉体が幅広く使用、配合されているが、さらに新規な発色をする色剤が開発され、化粧料に配合する技術が検討されている。例えば、表面の凹凸形状により三次元的な光沢効果が得られるホログラムラメを配合する技術(例えば特許文献1参照)や、従来にない高彩度な化粧膜を得る高彩度着色剤で着色し、且つ、表面処理された繊維を配合する技術(例えば特許文献2参照)などが知られている。一方、爪を補強する目的で短繊維を配合した美爪料の検討もされている(例えば特許文献3参照)。 Beauty nail is one of the point makeup products that require a wide range of colors. Conventionally, coloring agents such as organic pigments and inorganic pigments, and glittering powders such as pearls and lamés have been widely used and formulated in this nail polish. Therefore, techniques for blending into cosmetics are being studied. For example, coloring with a technique for blending hologram glitter that can provide a three-dimensional gloss effect due to the uneven shape of the surface (see, for example, Patent Document 1), or a high-saturation colorant that obtains an unprecedented high-saturation cosmetic film, and the surface A technique (for example, see Patent Document 2) for blending treated fibers is known. On the other hand, a beautiful nail material blended with short fibers for the purpose of reinforcing the nail has also been studied (see Patent Document 3, for example).
しかしながら、これらパール剤やラメ剤を配合した際、特有の輝きが得られるものの、静置時に色剤の沈降が見られたり、配合量を増加させることにより、透明感が失われるといった欠点があった。また、従来の繊維を用いた場合、爪補強の目的で配合した際、2枚爪を防止するといった効果は得られるものの、美観を向上させる色剤とはいえなかった。 However, when these pearls and lamés are blended, a unique brightness can be obtained, but there are drawbacks such as the precipitation of the colorant at the time of standing, and the loss of transparency by increasing the blending amount. It was. In addition, when conventional fibers are used for the purpose of reinforcing nails, an effect of preventing two nails can be obtained, but it cannot be said to be a colorant that improves the aesthetic appearance.
従って、高彩度感だけではなく、塗布部位の質感を光学的に変化させることができる新規素材を見出し、これを利用した従来にない透明感や立体感、つや感等の化粧効果を爪(ネイル)に付与できる美爪料の開発が求められており、このような美爪料を提供することが本発明の課題である。 Therefore, not only high saturation but also new materials that can optically change the texture of the application site have been found, and this has been used to create cosmetic effects such as unprecedented transparency, three-dimensionality and gloss. Development of a beautiful nail material that can be applied to the skin is required, and it is an object of the present invention to provide such a beautiful nail material.
本発明者は、上記課題を解決するために鋭意研究した結果、屈折率の異なる2種以上の高分子化合物を積層し、且つ、着色された干渉光を呈する繊維と、皮膜形成剤および非芳香族系溶剤とを用いることにより、外観は、高彩度で光輝性に優れる新規な質感が付与された外観と、使用した際は、塗布部位である爪に高い彩度を付与し、その質感を光学的に変化することができ、従来にない透明感や立体感、つや感を有する美爪料が得られること、更にこの美爪料は、新規な化粧効果を有しながら、安定性も良好であることを見出し、本発明を完成するに至った。 As a result of diligent research to solve the above-mentioned problems, the present inventors have laminated two or more kinds of polymer compounds having different refractive indexes and have colored interference light, a film-forming agent and a non-fragrance. By using a group-based solvent, the appearance is a high-saturation appearance with a new texture with excellent luster, and when used, the nail that is the application site is given high saturation and the texture is optical The beauty of the nail polish has a new cosmetic effect and has good stability. As a result, the present invention has been completed.
すなわち本発明は、次の成分(A)〜(C);
(A)着色された、屈折率の異なる2種類以上の高分子化合物を含む干渉繊維
(B)皮膜形成剤
(C)非芳香族系溶剤
を含有することを特徴とする美爪料である。
That is, the present invention includes the following components (A) to (C);
(A) Colored interference fiber containing two or more kinds of polymer compounds having different refractive indexes (B) Film-forming agent (C) A nail material characterized by containing a non-aromatic solvent.
本発明の美爪料は、使用性、使用感を損なうことなく、外観色調に高い彩度を付与する効果、(外観の高彩度感)、外観の光輝性を付与する効果(外観の光輝性)、また、塗布部位である爪に高い彩度を付与する効果(化粧膜の高彩度感)、質感を光学的に変化させ、透明感や立体感、を付与する効果(質感改良効果)を有し、更につや感、安定性に優れるものである。 The nail polish of the present invention has an effect of imparting high saturation to the appearance color tone without impairing the usability and feeling of use, (high chroma of appearance), and effect of imparting gloss of appearance (shininess of appearance) In addition, it has the effect of imparting high saturation to the nail that is the application site (high saturation feeling of the cosmetic film), and the effect of optically changing the texture to impart transparency and stereoscopic effect (texture improvement effect) Furthermore, it is excellent in glossiness and stability.
本発明の美爪料は、上記したように
(A)着色された、屈折率の異なる2種類以上の高分子化合物を含む干渉繊維
(B)皮膜形成剤
(C)非芳香族系溶剤
の三成分を含有するものである。
As described above, the beauty nail material of the present invention comprises: (A) a colored interference fiber containing two or more kinds of polymer compounds having different refractive indexes; (B) a film-forming agent; and (C) a non-aromatic solvent. Contains ingredients.
上記成分のうち、(A)成分である、着色された、屈折率の異なる2種以上の高分子化合物を含む干渉繊維(以下、「着色干渉繊維」と略す)は、少なくとも2種類以上の高分子化合物で構成される層状の断面構造(積層断面)を有する複合繊維を、着色剤で着色した繊維であり、この複合繊維は干渉色として、赤色、黄色、緑色、青色、紫色等を呈するものである。断面形状については、平行積層部を保護層でつつんだ扁平断面干渉繊維が、化粧料として爪等に付着しやすく、また一方向からの発色をより強くみせるためにも望ましい。この着色干渉繊維に使用される高分子化合物は、通常、化粧料に使用されるものであれば特に限定されないが、例えば、ナイロン、ポリエチレンテレフタレート、ポリプロピレン、ポリカーボネイト、ポリメチルメタクリレート、ポリエステル等があげられる。これらの高分子化合物のなかでも、ポリエチレンテレフタレートとナイロンの組み合わせは、干渉光を強く呈し、また繊維工程安定性も良好で、本願発明の効果がより顕著に現れるため好ましい。 Among the above components, the colored interference fibers (hereinafter referred to as “colored interference fibers”) that are two or more kinds of polymer compounds having different refractive indexes, which are the component (A), are at least two kinds of high A fiber in which a composite fiber having a layered cross-sectional structure (laminated cross section) composed of molecular compounds is colored with a colorant, and this composite fiber exhibits red, yellow, green, blue, purple, etc. as interference colors It is. As for the cross-sectional shape, the flat cross-section interference fiber in which the parallel laminated portion is sandwiched by the protective layer is preferable as it is easily attached to the nail or the like as a cosmetic and more strongly develops color from one direction. The polymer compound used in the colored interference fiber is not particularly limited as long as it is usually used in cosmetics. Examples thereof include nylon, polyethylene terephthalate, polypropylene, polycarbonate, polymethyl methacrylate, and polyester. . Among these polymer compounds, a combination of polyethylene terephthalate and nylon is preferable because it strongly exhibits interference light and has good fiber process stability, and the effects of the present invention appear more remarkably.
上記(A)成分の製造に使用される着色剤としては、通常化粧料に使用されるものであれば特に制限されず、いずれのものも使用できる。例えば、赤色2号、赤色3号、赤色102号、赤色104号(1)、赤色105号(1)、赤色106号、黄色4号、黄色5号、緑色3号、青色1号、青色2号、赤色201号、赤色213号、赤色214号、赤色215号、赤色227号、赤色230号(1)、赤色230号(2)、赤色231号、赤色232号、橙色205号、橙色207号、黄色203号、緑色201号、緑色204号、緑色205号、青色202号、青色203号、青色205号、かっ色201号、赤色401号、赤色502号、赤色503号、赤色504号、赤色506号、橙色402号、黄色402号、黄色403号(1)、黄色406号、黄色407号、緑色401号、緑色402号、紫色401号、黒色401号等の水溶性のタール系色素、赤色202号、赤色218号、赤色223号、赤色226号、赤色228号、橙色201号、黄色201号、黄色205号、青色201号、青色204号、紫色201号、赤色404号、赤色405号、橙色401号、黄色401号、黄色404号、黄色405号、青色403号、青色404号等の水不溶性のタール系色素、クチナシ色素、ベニバナ色素、ウコン色素、パプリカ色素、アナトー色素、コチニール色素等の天然色素、酸性、塩基性色素、及び分散染料等が挙げられるが、中でも水溶性のタール系色素は、着色性、安定性が高いため、顕著な化粧効果が得られ最も好ましい。また、これらの着色剤は、1種又は2種以上を使用することが可能であり、(A)成分に種々の色調を付与することができる。 As a coloring agent used for manufacture of the said (A) component, if normally used for cosmetics, it will not restrict | limit, Any thing can be used. For example, Red No. 2, Red No. 3, Red No. 102, Red No. 104 (1), Red No. 105 (1), Red No. 106, Yellow No. 4, Yellow No. 5, Green No. 3, Blue No. 1, Blue No. 2 No., Red 201, Red 213, Red 214, Red 215, Red 227, Red 230 (1), Red 230 (2), Red 231, Red 232, Orange 205, Orange 207 No., Yellow 203, Green 201, Green 204, Green 205, Blue 202, Blue 203, Blue 205, Brown 201, Red 401, Red 502, Red 503, Red 504 Red 506, orange 402, yellow 402, yellow 403 (1), yellow 406, yellow 407, green 401, green 402, purple 401, black 401, etc. Dye, red 202, Color 218, Red 223, Red 226, Red 228, Orange 201, Yellow 201, Yellow 205, Blue 201, Blue 204, Purple 201, Red 404, Red 405, Orange 401 No., yellow 401, yellow 404, yellow 405, blue 403, blue 404, etc. Examples thereof include dyes, acidic dyes, basic dyes, and disperse dyes. Among these, water-soluble tar-based dyes are most preferable because they have a high colorability and stability, and thus can provide a remarkable cosmetic effect. Moreover, these colorants can use 1 type (s) or 2 or more types, and can provide a various color tone to (A) component.
(A)成分の着色に使用される着色剤の量は、特に制限されず、目的に応じて決められるが、(A)成分全体の0.01〜30質量%(以下、単に「%」と示す)が好ましく、さらに0.01〜10%が好ましい。この範囲であれば使用部位に高彩度な化粧膜を付与するといった化粧効果が充分に得られる。また、着色剤の色は、干渉色と同系色であると、光干渉に必要な波長を積層部に達することを阻害しないため、効果的である。干渉色と反対色で着色すると、干渉効果を発現する波長を着色剤が吸収してしまう場合があり、干渉繊維の発色は減少してしまう。このため、干渉繊維の発色と同系色もしくは補色関係にない色で着色すると、干渉光を強く呈し、本願発明の効果がより顕著に現れるため、好ましい。なお、ここでいう同系色とは、P.C.C.S色彩体系の24色相環表上において、となりあう色相を意味し、例えば、干渉色が赤の場合は、赤紫〜橙を同系色とする。また、干渉色が黄色の時は、橙〜黄緑を、干渉色が緑の場合は、黄緑〜青を、干渉色が紫の場合は、青紫〜赤紫をそれぞれ同系色とする。 The amount of the colorant used for coloring the component (A) is not particularly limited and is determined according to the purpose, but is 0.01 to 30% by mass (hereinafter simply referred to as “%”) of the total component (A). Is preferable), and 0.01 to 10% is more preferable. If it is this range, the cosmetic effect of providing a highly saturated cosmetic film to the use site can be sufficiently obtained. Further, if the color of the colorant is similar to the interference color, it is effective because it does not hinder the wavelength necessary for optical interference from reaching the laminated portion. When colored with an interference color opposite to the interference color, the colorant may absorb a wavelength that exhibits an interference effect, and the color development of the interference fiber is reduced. For this reason, it is preferable to color with a color similar to the color of the interference fiber or a color that is not complementary to the color because the interference light is strongly exhibited and the effects of the present invention appear more remarkably. Here, the similar color means a hue that is adjacent on the 24-color ring table of the P.C.C.S. color system. For example, when the interference color is red, reddish purple to orange are similar. Color. Further, when the interference color is yellow, orange to yellow-green is used. When the interference color is green, yellow green to blue is used. When the interference color is purple, blue to purple is used.
本発明の(A)成分の製造方法は、特に制限されず、従来の高分子化合物から繊維を得る方法が利用できるが、好ましい方法の例としては次の方法を挙げることができる。すなわち、特開平7−34324号公報、特開平11−1829号公報あるいはWO98/46815号パンフレットに記載の方法に従って屈折率の異なる高分子化合物を積層し、干渉光を呈する繊維(干渉繊維)を製造した後、それを常法に従って染料で着色する方法や、上記記載の方法中、繊維製造時にあらかじめ着色剤を高分子化合物に分散し、これをもちいて直接着色干渉繊維を製造する方法等があげられる。 The method for producing the component (A) of the present invention is not particularly limited, and a conventional method for obtaining fibers from a polymer compound can be used. Examples of preferred methods include the following methods. That is, high-molecular compounds having different refractive indexes are laminated according to the methods described in JP-A-7-34324, JP-A-11-1829, or WO98 / 46815 to produce fibers that exhibit interference light (interference fibers). Then, a method of coloring it with a dye according to a conventional method, a method of dispersing a colorant in a polymer compound in advance at the time of fiber production, and directly producing a colored interference fiber using the method, etc. It is done.
本発明の美爪料に配合するに当たっての(A)成分の長さ及び太さは、特に制限されないが、使用部位である爪の化粧効果及び良好な使用性と均一な化粧膜の形成の面から、長さは0.01〜5mmの範囲であることが好ましく、さらに0.1〜3mmが好ましい。また、太さは、0.01〜20デニール(以下、単に「D」と示す)の範囲であることが好ましく、更に好ましくは0.1〜13Dである。また、(A)成分の断面形状は、円形であっても扁平な楕円形であっても良いが、楕円形の方がより干渉があらわれ好ましい。更に、(A)成分の効果を顕著に発現させるためには、各々の高分子化合物で構成される層が、5層ないし120層、好ましくは、30層ないし90層で交互に積層し、かつ、それぞれの層の厚みが0.02〜0.3μmの範囲にあることが好ましい。これらの繊維は、材質、太さ、長さの異なる1種又は2種以上を用いることができる。 The length and thickness of the component (A) for blending into the beauty nail material of the present invention are not particularly limited, but the cosmetic effect of the nail that is the use site, good usability, and surface formation of a uniform cosmetic film Therefore, the length is preferably in the range of 0.01 to 5 mm, more preferably 0.1 to 3 mm. The thickness is preferably in the range of 0.01 to 20 denier (hereinafter simply referred to as “D”), more preferably 0.1 to 13D. Further, the cross-sectional shape of the component (A) may be a circular shape or a flat elliptical shape, but the elliptical shape is preferable because of more interference. Furthermore, in order to remarkably express the effect of the component (A), the layers composed of the respective polymer compounds are alternately laminated in 5 to 120 layers, preferably 30 to 90 layers, and The thickness of each layer is preferably in the range of 0.02 to 0.3 μm. These fibers can be used alone or in combination of two or more materials, thicknesses, and lengths.
本発明の(A)成分は、そのまま美爪料中に配合しても良いが、表面処理することにより、美爪料中での分散性が向上し、化粧効果およびその持続性が格段に向上するので、表面処理したものを使用することがより好ましい。(A)成分の表面処理に使用する表面処理剤としては通常化粧料に使用されるものであれば特に制限されず、いずれのものも使用でき、例えば、一般油剤、シリコーン油、フッ素化合物、界面活性剤、シリカ等を挙げることができる。しかしながら、特に好ましい表面処理剤としては、シリカ及び/又はフッ素化合物を挙げることができる。 The component (A) of the present invention may be blended in the nail polish as it is, but by surface treatment, the dispersibility in the nail polish is improved, and the makeup effect and its sustainability are remarkably improved. Therefore, it is more preferable to use a surface-treated product. The surface treatment agent used for the surface treatment of component (A) is not particularly limited as long as it is usually used in cosmetics, and any one can be used, for example, general oil agent, silicone oil, fluorine compound, interface An activator, silica, etc. can be mentioned. However, particularly preferred surface treatment agents include silica and / or fluorine compounds.
上記の表面処理の方法は特に制限されないが、例えば、シリカの場合は、溶媒中に着色干渉繊維と共に入れ、これらを混合することにより被覆又は付着させる方法、シリカを着色干渉繊維に吹き付ける方法等が挙げられる。また、フッ素化合物の場合は、例えばフッ素化合物をアセトン、トルエン等の有機溶媒に加熱溶解せしめ、その中に着色干渉繊維の1種又は2種以上の混合物を加え、撹拌後溶媒を留去してこの繊維上にフッ素化合物を被覆又は付着させ、場合によってはさらに焼き付け処理をする方法がある。 The surface treatment method is not particularly limited. For example, in the case of silica, there are a method in which a colored interference fiber is placed in a solvent and mixed to coat or adhere, and a method in which silica is sprayed on the colored interference fiber. Can be mentioned. In the case of a fluorine compound, for example, the fluorine compound is dissolved by heating in an organic solvent such as acetone or toluene, and one or a mixture of two or more colored interference fibers is added thereto. After stirring, the solvent is distilled off. There is a method in which a fluorine compound is coated or adhered on the fiber, and in some cases, further baked.
表面処理剤の処理量は、特に制限されず、目的に応じて決められるが、表面処理された着色干渉繊維全体の0.01〜30%が好ましく、さらに0.1〜20%が好ましい。この範囲であれば繊維の分散性が向上し、化粧効果が顕著に現れ、その効果の持続性が充分に得られる。 The treatment amount of the surface treatment agent is not particularly limited and is determined according to the purpose, but is preferably 0.01 to 30%, more preferably 0.1 to 20% of the entire surface-treated colored interference fiber. If it is this range, the dispersibility of a fiber will improve, a cosmetic effect will appear notably, and the sustainability of the effect will fully be acquired.
成分(A)としての着色干渉繊維は、1種又は2種以上を使用することが可能である。その配合量は、特に制限されないが、美爪料組成中、0.01〜30%が好ましく、0.1〜20%がさらに好ましい。この範囲で用いれば、発明の効果が顕著に現れる。 The colored interference fiber as the component (A) can be used alone or in combination of two or more. The blending amount is not particularly limited, but is preferably 0.01 to 30% and more preferably 0.1 to 20% in the beauty nail composition. If it is used within this range, the effect of the invention will be remarkable.
一方、本発明で使用される成分(B)の皮膜形成剤は、通常の美爪料に用いられるものであれば特に限定されず、使用することができる。成分(B)の具体的な例としては、ニトロセルロース、フタル酸系アルキッド樹脂、トルエンスルホンアミド樹脂、トルエンスルホンアミドエポキシ樹脂、(メタ)アクリル酸アルキル(共)重合体、安息香酸ショ糖エステル、(メタ)アクリル酸アルキル・スチレン共重合体、(メタ)アクリル酸アルキル・アクリロニトリル・スチレン共重合体、シリコーン樹脂などが挙げられる。これらのうち、特にニトロセルロースが好ましく、その市販品としては、例えば、硝化綿H1/2、H1/4、H1/8、L1/2、L1/4(すべて旭化成工業(株)製)等が挙げられる。 On the other hand, the film-forming agent of the component (B) used in the present invention is not particularly limited as long as it is used for a normal beauty nail material, and can be used. Specific examples of the component (B) include nitrocellulose, phthalic acid alkyd resin, toluenesulfonamide resin, toluenesulfonamide epoxy resin, alkyl (meth) acrylate (co) polymer, benzoic acid sucrose ester, Examples include (meth) alkyl acrylate / styrene copolymers, alkyl (meth) acrylate / acrylonitrile / styrene copolymers, and silicone resins. Of these, nitrocellulose is particularly preferred, and examples of commercially available products thereof include nitrified cotton H1 / 2, H1 / 4, H1 / 8, L1 / 2, L1 / 4 (all manufactured by Asahi Kasei Kogyo Co., Ltd.) and the like. Can be mentioned.
さらに上記ニトロセルロースにトルエンスルホンアミドエポキシ樹脂を配合したものを成分(B)として使用するとよりつや感が向上する。この配合割合(質量比)は、ニトロセルロース/トルエンスルホンアミドエポキシ樹脂=1/0.1から1/1の範囲が好ましく、特に、ニトロセルロース/トルエンスルホンアミドエポキシ樹脂=1/0.2から1/0.7が好ましい。また、配合量も、特に限定されないが、1〜15%の範囲が好ましい。この範囲であればより優れたつや感を得ることができる。 Further, when the above nitrocellulose blended with toluenesulfonamide epoxy resin is used as the component (B), the glossiness is further improved. The blending ratio (mass ratio) is preferably in the range of nitrocellulose / toluenesulfonamide epoxy resin = 1 / 0.1 to 1/1, particularly nitrocellulose / toluenesulfonamide epoxy resin = 1 / 0.2 to 1. /0.7 is preferred. Also, the blending amount is not particularly limited, but a range of 1 to 15% is preferable. If it is this range, more excellent gloss can be obtained.
同様に、ニトロセルロース中にアクリル酸アルキル・スチレン共重合体を配合したものを成分(B)として使用した場合も、よりつや感が向上する。この場合の配合割合は、ニトロセルロース/アクリル酸アルキル・スチレン共重合体=1/0.1から1/1の範囲が好ましく、特に、ニトロセルロース/アクリル酸アルキル・スチレン共重合体=1/0.2から1/0.7が好ましい。また、配合量も、特に限定されないが、1%〜15%の範囲が好ましい。この範囲であれば、より優れたつや感が得られる。 Similarly, when a nitrocellulose blended with an alkyl acrylate / styrene copolymer is used as the component (B), the glossiness is further improved. The blending ratio in this case is preferably in the range of nitrocellulose / alkyl acrylate / styrene copolymer = 1 / 0.1 to 1/1, and in particular, nitrocellulose / alkyl acrylate / styrene copolymer = 1/0. 0.2 to 1 / 0.7 is preferred. Also, the blending amount is not particularly limited, but a range of 1% to 15% is preferable. Within this range, a better gloss feeling can be obtained.
この成分(B)の配合量は特に限定されないが、美爪料組成中、2〜35%が好ましく、特に5〜25%が好ましい。この範囲であれば化粧効果の発現がより顕著に得られる。 Although the compounding quantity of this component (B) is not specifically limited, 2-35% is preferable in a nail polish composition, and 5-25% is especially preferable. If it is this range, expression of a cosmetic effect will be obtained more notably.
本発明に使用される成分(C)の非芳香族系溶剤とは、トルエン、キシレン等の芳香族炭化水素以外の有機溶剤を広く意味するものである。具体的な成分(C)の例としては、酢酸−n−ブチル、酢酸イソブチル、酢酸エチル、メチルエチルケトン、アセトン、n−ブタノール、イソプロピルアルコール、エチルアルコール等が挙げられ、これらの1種又は2種以上用いることができる。 The non-aromatic solvent of component (C) used in the present invention broadly means organic solvents other than aromatic hydrocarbons such as toluene and xylene. Specific examples of component (C) include: n-butyl acetate, isobutyl acetate, ethyl acetate, methyl ethyl ketone, acetone, n-butanol, isopropyl alcohol, ethyl alcohol, and the like, one or more of these. Can be used.
成分(C)の配合量は、通常の溶剤系美爪料に配合されている量であれば、特に限定されないが、美爪料組成中、50%〜90%程度とすることが好ましい。この範囲であれば使用性がより優れるためである。 Although the compounding quantity of a component (C) will not be specifically limited if it is the quantity mix | blended with the normal solvent-type beautiful nail material, It is preferable to set it as about 50%-90% in a beautiful nail material composition. This is because the usability is more excellent within this range.
本発明の美爪料は、さらに必要に応じて、成分(D)としてゲル化剤を配合することができる。この成分(D)は、ゲル構造を更に安定にすることができるものであり、通常、美爪料に増粘剤として用いられる成分、例えば、有機変性粘土鉱物、無水ケイ酸等がその例としてあげられる。 The beauty nail material of the present invention may further contain a gelling agent as component (D) as necessary. This component (D) is capable of further stabilizing the gel structure. Examples of components that are usually used as thickeners in nail polishes such as organically modified clay minerals and silicic anhydride. can give.
このうち、有機変性粘土鉱物は、水膨潤性粘土鉱物をアルキル四級アンモニウム塩等のカチオン系界面活性剤でイオン交換して得られるものである。この有機変性粘土鉱物の市販品としては、例えば、ベントン27、ベントン38(ELEMENTIS社製)や有機変性合成膨潤性ケイ酸塩(特開2002−234822号公報に記載のもの)等が挙げられ、これらを使用することができる。 Among these, the organically modified clay mineral is obtained by ion exchange of a water-swellable clay mineral with a cationic surfactant such as an alkyl quaternary ammonium salt. Examples of commercially available products of this organically modified clay mineral include Benton 27, Benton 38 (manufactured by ELEMENTIS) and organically modified synthetic swellable silicates (those described in JP 2002-234822 A). These can be used.
また、無水ケイ酸としては、例えば四塩化ケイ素を水素と酸素炎中で加水分解して得られるものが挙げられ、その市販品の例としては、AEROSIL 50、AEROSIL 130、AEROSIL 200、AEROSIL 200V、AEROSIL 200CF、AEROSIL 200FAD、AEROSIL 300、AEROSIL 300CF、AEROSIL 380、AEROSIL 380S(以上、日本アエロジル社製)等や、サイリシア250、310(富士シリシア社製)等が挙げられる。また、前記無水ケイ酸を反応性オルガノシランやオルガノシラザン等で処理した疎水性無水ケイ酸でもよい。この市販品の例としては、AEROSIL R−972、AEROSIL R974、AEROSIL R976、AEROSIL RX200、AEROSIL RX300、AEROSIL R805、AEROSIL RY200、AEROSIL RY300(日本アエロジル社製)、キャボジルTS530(キャボット社製)等が挙げられる。これらの無水ケイ酸は煙霧状であることが好ましく、一次粒径は50nm以下が好ましく、20nm以下が特に好ましい。 Examples of silicic anhydride include those obtained by hydrolyzing silicon tetrachloride in hydrogen and oxygen flame. Examples of commercially available products include AEROSIL 50, AEROSIL 130, AEROSIL 200, AEROSIL 200V, AEROSIL 200CF, AEROSIL 200FAD, AEROSIL 300, AEROSIL 300CF, AEROSIL 380, AEROSIL 380S (above, manufactured by Nippon Aerosil Co., Ltd.) and the like, and Silysia 250, 310 (manufactured by Fuji Silysia Co., Ltd.) are included. Moreover, the hydrophobic silicic acid which processed the said silicic acid anhydride with reactive organosilane, organosilazane, etc. may be sufficient. Examples of this commercially available product include AEROSIL R-972, AEROSIL R974, AEROSIL R976, AEROSIL RX200, AEROSIL RX300, AEROSIL R805, AEROSIL RY200 (manufactured by Nippon Aerosil Co., Ltd.), Cabozil TS530 (manufactured by Cabot). It is done. These silicic anhydrides are preferably in the form of fumes, and the primary particle size is preferably 50 nm or less, particularly preferably 20 nm or less.
成分(D)の配合量は、特に限定されないが、美爪料組成中、0.5〜5%が好ましい。この範囲であれば使用性が良好であるとともに、安定性がより向上できるためである。 Although the compounding quantity of a component (D) is not specifically limited, 0.5 to 5% is preferable in a beauty nail composition. This is because the usability is good and the stability can be further improved within this range.
本発明の美爪料には、さらに成分(E)として水を配合することができる。この成分(E)は、ゲル補強剤として作用するもので、使用性や安定性を格段に向上させることができる。この成分(E)の配合量は、美爪料組成中、0.05〜5%が好ましい。この範囲であれば安定性が良好であるとともに、より優れた使用性が得られるためである。 The beauty nail material of the present invention may further contain water as a component (E). This component (E) acts as a gel reinforcing agent, and can greatly improve the usability and stability. The compounding amount of this component (E) is preferably 0.05 to 5% in the beauty nail composition. This is because within this range, the stability is good and more excellent usability can be obtained.
さらに、本発明の美爪料には、その効果を損なわない範囲で、上記各成分の他に、通常の美爪料に使用される可塑剤、粉体等が配合される。また、希釈剤、粘度調整剤、油剤、界面活性剤、紫外線吸収剤、褪色防止剤、酸化防止剤、消泡剤、保湿剤、薬剤、香料、無機酸、有機酸等も適量配合することができる。 Furthermore, in the beautiful nail material of the present invention, a plasticizer, a powder, and the like used for a normal beautiful nail material are blended in addition to the above-described components as long as the effect is not impaired. In addition, diluents, viscosity modifiers, oils, surfactants, UV absorbers, antifading agents, antioxidants, antifoaming agents, moisturizers, chemicals, fragrances, inorganic acids, organic acids, etc. may be blended in appropriate amounts. it can.
このうち、可塑剤としては、例えば、ジブチルフタレート、ジオクチルフタレート、クエン酸トリブチル、クエン酸アセチルトリブチル、カンフル等が挙げられる。 Among these, examples of the plasticizer include dibutyl phthalate, dioctyl phthalate, tributyl citrate, acetyl tributyl citrate, camphor, and the like.
また、粉体としては、例えば酸化チタン、酸化亜鉛、酸化セリウム、硫酸バリウム、酸化鉄、カーボンブラック、酸化クロム、水酸化クロム、紺青、群青、タルク、白雲母、金雲母、紅雲母、黒雲母、合成雲母、絹雲母(セリサイト)、合成セリサイト、カオリン、炭化珪素、酸化アルミニウム、酸化マグネシウム、酸化ジルコニウム、酸化アンチモン、珪ソウ土、ケイ酸アルミニウム、メタケイ酸アルミニウムマグネシウム、ケイ酸カルシウム、ケイ酸バリウム、ケイ酸マグネシウム、炭酸カルシウム、炭酸マグネシウム、ヒドロキシアパタイト、窒化ホウ素、二酸化チタン被覆雲母、二酸化チタン被覆オキシ塩化ビスマス、酸化鉄雲母チタン、紺青処理雲母チタン、カルミン処理雲母チタン、オキシ塩化ビスマス、魚鱗箔、ポリエチレン・テレフタレート・アルミニウム・エポキシ積層末、ポリエチレンテレフタレート・ポリオレフィン積層フィルム末、ポリアミド系樹脂、ポリエチレン系樹脂、ポリアクリル系樹脂、ポリエステル系樹脂、フッ素系樹脂、セルロース系樹脂、ポリスチレン系樹脂、スチレン−アクリル共重合樹脂等のコポリマー樹脂、ポリプロピレン系樹脂、シリコーン樹脂、ウレタン樹脂、ステアリン酸亜鉛、N−アシルリジン、澱粉、シルク粉末、セルロース粉末、赤色3号、赤色104号、赤色106号、橙色205号、黄色4号、黄色5号、緑色3号、青色1号等のジルコニウム、バリウム又はアルミニウムレーキ等の有機顔料粉体、アルミニウム粉、金粉、銀粉、微粒子酸化チタン被覆雲母チタン、微粒子酸化亜鉛被覆雲母チタン、硫酸バリウム被覆雲母チタン、酸化チタン含有二酸化珪素、酸化亜鉛含有二酸化珪素等が挙げられる。これら粉体はその1種又は2種以上を用いることができ、さらに複合化したものを用いても良い。なお、これら粉体は、フッ素系化合物、シリコーン系化合物、金属石鹸、レシチン、水素添加レシチン、コラーゲン、炭化水素、高級脂肪酸、高級アルコール、エステル、ワックス、ロウ、界面活性剤等の1種又は2種以上を用いて表面処理を施してあってもよい。 Examples of the powder include titanium oxide, zinc oxide, cerium oxide, barium sulfate, iron oxide, carbon black, chromium oxide, chromium hydroxide, bitumen, ultramarine, talc, muscovite, phlogopite, saucite, biotite. , Synthetic mica, sericite (sericite), synthetic sericite, kaolin, silicon carbide, aluminum oxide, magnesium oxide, zirconium oxide, antimony oxide, diatomaceous earth, aluminum silicate, aluminum magnesium metasilicate, calcium silicate, silica Barium acid, Magnesium silicate, Calcium carbonate, Magnesium carbonate, Hydroxyapatite, Boron nitride, Titanium dioxide coated mica, Titanium dioxide coated bismuth oxychloride, Titanium oxide mica titanium, Bituminized mica titanium, Carmine treated mica titanium, Bismuth oxychloride, Fish scale foil, polyethylene Terephthalate / aluminum / epoxy laminated powder, polyethylene terephthalate / polyolefin laminated film powder, polyamide resin, polyethylene resin, polyacrylic resin, polyester resin, fluorine resin, cellulose resin, polystyrene resin, styrene-acrylic copolymer Copolymer resin such as resin, polypropylene resin, silicone resin, urethane resin, zinc stearate, N-acyl lysine, starch, silk powder, cellulose powder, red No. 3, red No. 104, red No. 106, orange No. 205, yellow 4 No. 5, Yellow No. 5, Green No. 3 and Blue No. 1 organic pigment powder such as zirconium, barium or aluminum lake, aluminum powder, gold powder, silver powder, fine titanium oxide coated mica titanium, fine zinc oxide coated mica titanium, sulfuric acid Barium cover Titanium mica, titanium oxide-containing silicon dioxide, and zinc oxide-containing silicon dioxide and the like. These powders can be used singly or in combination of two or more types. These powders are one or two of fluorine compound, silicone compound, metal soap, lecithin, hydrogenated lecithin, collagen, hydrocarbon, higher fatty acid, higher alcohol, ester, wax, wax, surfactant and the like. Surface treatment may be performed using seeds or more.
本発明の美爪料は、常法に従い、上記した各成分を適宜配合し、例えば、ディスパーズミルやホモミキサー等の機器を用いて均一に混合、分散することによって調製することができる。 The nail polish of the present invention can be prepared by appropriately blending the above-described components according to a conventional method, and uniformly mixing and dispersing using, for example, a device such as a dispers mill or a homomixer.
以上のようにして得られた本発明の美爪料は、マニキュア、トップコート、ベースコートなどとすることができる。 The nail material of the present invention obtained as described above can be made into a nail polish, a top coat, a base coat or the like.
次に実施例を挙げ、本発明をより詳しく説明するが、本発明はこれらの実施例等により何ら制約されるものではない。 EXAMPLES Next, although an Example is given and this invention is demonstrated in detail, this invention is not restrict | limited at all by these Examples.
実 施 例 1
美 爪 料:
表1に示す処方および製法で、本発明品1〜7及び比較品1〜4の美爪料を調製し、a.美爪料の外観色調に高い彩度を付与する効果(外観の高彩度感)、b.美爪料の外観に光輝性を付与する効果(外観の光輝性)、c.使用部位に高い彩度を付与する効果(化粧膜の高彩度感)、d.使用部位に透明感、立体感を付与する(質感改良効果)、e.つや感、f.安定性について下記の方法により官能評価を行った。その結果もあわせて表1に示す。
Example 1
Beauty nail material:
With the formulation and production method shown in Table 1, the nail polishes of the present invention products 1 to 7 and comparative products 1 to 4 are prepared, and a. The effect of imparting high chroma to the appearance color tone of the nail polish (high color appearance) ), B. Effect of imparting glossiness to the appearance of the beautiful nail preparation (glossiness of appearance), c. Effect of imparting high chroma to the use site (high chroma feeling of the cosmetic film), d. Transparency to the use site Sensory evaluation was performed by the following methods for imparting a three-dimensional effect (texture improving effect), e. Glossiness, and f. Stability. The results are also shown in Table 1.
*1:硝化綿H1/4(旭化成工業(株)製)
*2:ベントン27(ELEMENTIS社製)
*3:AEROSIL 300(日本アエロジル社製)
*4:0.1%赤色202号で着色した繊維(ポリエチレンテレフタレート、ナイ
ロンを特開平11−1829号公報に従い、交互に51層積層したもの、
6D、2mm)(赤色の干渉光を呈する)
*5:0.1%赤色202号で着色した繊維(6D、2mm)(干渉光を呈しない)
*6:無着色繊維(6D、2mm)(干渉光を呈しない)
*7:四角形、1mm角、厚さ25μm
*8:TIMIRON SPLENDID RED(メルク社製)
* 1: Nitrified cotton H1 / 4 (Asahi Kasei Kogyo Co., Ltd.)
* 2: Benton 27 (manufactured by ELEMENTIS)
* 3: AEROSIL 300 (Nippon Aerosil Co., Ltd.)
* 4: Fiber colored with 0.1% red No. 202 (polyethylene terephthalate, nylon
In accordance with Japanese Patent Laid-Open No. 11-1829, Ron is alternately layered 51 layers,
6D, 2 mm) (presents red interference light)
* 5: Fiber colored with 0.1% red 202 (6D, 2 mm) (does not exhibit interference light)
* 6: Uncolored fiber (6D, 2mm) (no interference light)
* 7: Square, 1 mm square, thickness 25 μm
* 8: TIMRON SPLENDID RED (Merck)
(製 法)
A.(1)〜(12)を均一に混合し、これに成分(13)〜(19)を添加し均
一に分散する。
B.「A.」を容器に充填して、美爪料を得た。
(Production method)
A. (1) to (12) are mixed uniformly, and then components (13) to (19) are added and dispersed uniformly.
B. “A.” was filled into a container to obtain a beautiful nail material.
(評価方法および判定基準)
10名の官能検査パネルにより、各試料を下記a〜eの評価項目について、(1)絶対評価基準を用いて7段階に評価し、各試料の評点の平均値を(2)4段階判定基準を用いて判定した。
(Evaluation method and criteria)
Using 10 sensory test panels, each sample was evaluated in 7 levels using the absolute evaluation criteria for the following evaluation items a to e, and the average score of each sample was (2) 4-step criteria Was used to determine.
評価項目:
a.外観の高彩度感
b.外観の光輝性
c.化粧膜の高彩度感
d.質感改良効果
e.つや感
(1)絶対評価基準
評 点 : 評 価
6 : 非常に良い
5 : 良い
4 : やや良い
3 : 普通
2 : やや悪い
1 : 悪い
0 : 非常に悪い
(2)4段階判定基準
評点平均値 : 判 定
5点を超える : 非常に良好(◎)
3点を超えて5点以下: 良 好 (○)
2点を超えて3点以下: やや不良 (△)
2点以下 : 不 良 (×)
Evaluation item:
a. Appearance of high saturation b. Appearance glitter c. Appearance of high-saturation film d. Texture improvement effect e. Glossiness (1) Absolute evaluation criteria Rating: Evaluation 6: Very good 5: Good 4: Somewhat Good 3: Normal 2: Slightly bad 1: Bad 0: Very bad (2) Four-step criteria Criterion average value: Judgment More than 5 points: Very good (◎)
Over 3 points and below 5 points: Good (○)
Over 2 points and under 3 points: Somewhat bad (△)
2 points or less: Bad (×)
また、安定性(評価項目f)については、50℃の恒温槽に1ヶ月放置後の状況について、外観を目視にて観察し、以下の基準にて判定した。
判定基準:
判 定 : 評 価
◎ : 顔料、パール、ラメ、繊維等の色材類の沈降が全く見られない。
○ : 顔料、パール、ラメ、繊維等の色材類の沈降がわずかにあるが、
まったく支障なく使用できる。
△ : 顔料、パール、ラメ、繊維等の色材類の沈降がやや見られ、再分
散させないと使用できない。
× : 顔料、パール、ラメ、繊維等の色材類の沈降が著しい。
Moreover, about stability (evaluation item f), the external appearance was observed visually about the condition after leaving for one month in a 50 degreeC thermostat, and it determined by the following references | standards.
Judgment criteria:
Judgment: Evaluation
A: Sedimentation of coloring materials such as pigments, pearls, lamé and fibers is not observed at all.
○: There is slight sedimentation of coloring materials such as pigment, pearl, lame, fiber, etc.
Can be used without any problem.
Δ: Slight settling of coloring materials such as pigment, pearl, lame, fiber, etc.
It cannot be used unless it is scattered.
X: Sedimentation of coloring materials such as pigments, pearls, lamé, and fibers is remarkable.
評価結果:
表1の結果から明らかなように、本発明品1〜7の美爪料は、比較品1〜4の美爪料と比較し、a.外観の高彩度感、b.外観の光輝性、c.化粧膜の高彩度感、d.質感改良効果、e.つや感、f.安定性のすべての面で、はるかに優れた特性を有していることがわかる。
Evaluation results:
As is clear from the results of Table 1, the nail polishes of the present invention products 1 to 7 are a. High chroma of appearance, b. It can be seen that the film has far superior characteristics in all aspects of high-saturation feeling of the decorative film, d. Texture improvement effect, e. Glossiness, and f. Stability.
一方、質感を変化させるものとして、干渉光を呈しない着色したナイロン繊維を用いた比較品1は、外観の高彩度感や光輝性が付与できず、質感改良効果の点で満足のいくものが得られなかった。また、干渉光を呈しない着色していないナイロン繊維を用いた比較品2は、外観の高彩度感や光輝性、化粧膜の高彩度感、質感改良効果、つや感の点で満足のいくものが得られなかった。さらに、ポリエチレンテレフタレート・アルミニウム・エポキシ積層末を用いた比較品3では外観の高彩度感や光輝性、化粧膜の高彩度感において満足のいくものが得られず、雲母チタンを用いた比較品4では、外観の高彩度感、外観の光輝性、化粧膜の高彩度感、質感改良効果、つや感の点で満足のいくものが得られなかった。 On the other hand, the comparative product 1 using colored nylon fibers that do not exhibit interference light as a material that changes the texture cannot give a high-saturation appearance or glitter, and is satisfactory in terms of the texture improvement effect. I couldn't. Comparative product 2 using non-colored nylon fibers that do not exhibit interference light is satisfactory in terms of appearance of high chroma and glitter, high chroma of the decorative film, improved texture, and gloss. I couldn't. Furthermore, the comparative product 3 using the polyethylene terephthalate / aluminum / epoxy laminated powder does not give satisfactory results in the appearance of high chroma and glitter and the high chroma of the decorative film. In the comparative product 4 using titanium mica, We were unable to obtain satisfactory results in terms of high chroma of appearance, glossiness of appearance, high chroma of the cosmetic film, texture improvement effect, and gloss.
実 施 例 2
マニキュアトップコート:
(成 分) (%)
(1)トルエンスルホンアミドエポキシ樹脂 20
(2)酢酸エチル 42
(3)酢酸ブチル 残量
(4)イソプロピルアルコール 7
(5)精製水 0.1
(6)煙霧状無水ケイ酸*3 0.5
(7)クエン酸アセチルトリブチル 10
(8)着色干渉繊維*4 0.4
Example 2
Manicure top coat:
(Component) (%)
(1) Toluenesulfonamide epoxy resin 20
(2) Ethyl acetate 42
(3) Residual amount of butyl acetate (4) Isopropyl alcohol 7
(5) Purified water 0.1
(6) Haze-like silicic acid anhydride * 3 0.5
(7) Acetyltributyl citrate 10
(8) Colored interference fiber * 4 0.4
(製 法)
A.(1)〜(8)を均一に混合し、容器に充填して、マニキュアトップコートを
得た。
(Production method)
A. (1) to (8) were mixed uniformly and filled into a container to obtain a nail polish top coat.
以上のようにして得られたマニキュアトップコートは、外観の高彩度感、外観の光輝性、化粧膜の高彩度感、質感改良効果、つや感、安定性、マニキュアの仕上がりやすさの点において、優れたものであった。 The nail polish top coat obtained as described above is excellent in terms of high saturation of appearance, glossiness of appearance, high saturation of makeup film, texture improvement effect, gloss, stability, and ease of finishing of nail polish. It was a thing.
実 施 例 3
マニキュアベースコート:
(成 分) (%)
(1)ニトロセルロース 15
(2)アクリル酸アルキル・スチレン共重合体 5
(3)酢酸エチル 42
(4)酢酸ブチル 残量
(5)イソプロピルアルコール 7
(6)精製水 0.1
(7)煙霧状無水ケイ酸*3 0.5
(8)クエン酸アセチルトリブチル 10
(9)着色干渉繊維*4 0.5
(10)着色干渉繊維*9 0.5
*9:0.1%青色1号で着色した繊維(ポリエチレンテレフタレート、ナイロン
を特開平11−1829号公報に従い、交互に51層積層したもの、6D、
2mm)(青色の干渉光を呈する)
Example 3
Manicure base coat:
(Component) (%)
(1) Nitrocellulose 15
(2) Alkyl acrylate / styrene copolymer 5
(3) Ethyl acetate 42
(4) Residual amount of butyl acetate (5) Isopropyl alcohol 7
(6) Purified water 0.1
(7) Haze-like silicic acid * 3 0.5
(8) Acetyltributyl citrate 10
(9) Colored interference fiber * 4 0.5
(10) Colored interference fiber * 9 0.5
* 9: Fiber colored with 0.1% blue No. 1 (polyethylene terephthalate, nylon)
According to JP-A-11-1829, 51 layers alternately stacked, 6D,
2mm) (presents blue interference light)
(製 法)
A.(1)〜(10)を均一に混合し、容器に充填して、マニキュアベースコート
を得た。
(Production method)
A. (1) to (10) were mixed uniformly and filled into a container to obtain a nail polish base coat.
以上のようにして得られたマニキュアベースコートは、外観の高彩度感、外観の光輝性、化粧膜の高彩度感、質感改良効果、つや感、安定性、マニキュアの化粧持ちの点において、優れたものであった。 The nail polish base coat obtained as described above is excellent in terms of high saturation of appearance, glossiness of appearance, high saturation of makeup film, texture improvement effect, gloss, stability, and longevity of nail polish. there were.
実 施 例 4
マニキュア:
着色干渉繊維*4を、下記の着色干渉繊維に代える以外は、実施例1の本発明品1と同様にしてマニキュアを得た。
Example 4
Manicure:
A nail polish was obtained in the same manner as the product 1 of the present invention of Example 1 except that the colored interference fiber * 4 was replaced with the following colored interference fiber.
使用着色干渉繊維:
0.1%赤色202号で着色した繊維(ポリエチレンテレフタレート、ナイロン
を特開平11−1829に従い、交互に61層積層した、断面が楕円形状のも
のを2%のシリカで処理したもの。(9D(長軸70μm、短軸17μm)、
2mm)(赤色の干渉光を呈する)
Use colored interference fiber:
Fiber colored with 0.1% red 202 (polyethylene terephthalate, nylon, 61 layers laminated alternately according to Japanese Patent Laid-Open No. 11-1829, with an elliptical cross section treated with 2% silica. (9D (Long axis 70 μm, short axis 17 μm),
2mm) (presents red interference light)
以上のようにして得られたマニキュアは、外観の高彩度感がより優れ、外観の光輝性に優れ、化粧膜の高彩度感、質感改良効果がより優れ、つや感、安定性においても優れるものであった。 The nail polish obtained as described above has an excellent appearance of high saturation, an excellent appearance of glitter, an excellent effect of improving the high saturation and texture of the cosmetic film, and an excellent gloss and stability. It was.
実 施 例 5
マニキュアベースコート:
着色干渉繊維*4を、下記の着色干渉繊維に代える以外は、実施例3と同様にしてマニキュアベースコートを得た。
Example 5
Manicure base coat:
A manicure base coat was obtained in the same manner as in Example 3 except that the colored interference fiber * 4 was replaced with the following colored interference fiber.
使用着色干渉繊維:
0.1%青色1号で着色した繊維(ポリエチレンテレフタレート、ナイロン
を特開平11−1829に従い、交互に61層積層した、断面が楕円形状のも
のを3%のパーフルオロアルキルリン酸エステルジエタノールアミン塩で処理
したもの。(9D(長軸70μm、短軸17μm)、0.5mm)(青色の干渉
光を呈する)
Use colored interference fiber:
A fiber colored with 0.1% blue No. 1 (polyethylene terephthalate, nylon, 61 layers alternately laminated according to JP-A-11-1829, 3% perfluoroalkyl phosphate diethanolamine salt having an oval cross section) (9D (major axis 70 μm, minor axis 17 μm), 0.5 mm) (presents blue interference light)
以上のようにして得られたマニキュアベースコートは、外観の高彩度感がより優れ、外観の光輝性に優れ、化粧膜の高彩度感、質感改良効果がより優れ、つや感、安定性、マニキュアの化粧持ちの点においても優れたものであった。 The nail polish base coat obtained in the above way has a higher appearance of high saturation, excellent appearance, and a higher saturation of the cosmetic film, and better texture improvement effect, glossiness, stability, and long-lasting nail polish. This was also excellent.
本発明の美爪料は、高彩度で光輝性に優れる新規な質感が付与された外観と、使用した際に、塗布部位である爪に高い彩度を付与すると共に質感を光学的に変化させる化粧効果を有するものである。また、その安定性も良好である。 The beauty nail material of the present invention has an appearance with a new texture imparted with high chroma and excellent luster, and a makeup that, when used, imparts high chroma to the nail that is the application site and optically changes the texture. It has an effect. Moreover, its stability is also good.
従って、従来にない透明感や立体感、つや感等の化粧効果を爪に付与できる美爪料として有用性の高いものである。
Therefore, it is highly useful as a beauty nail material that can impart a makeup effect such as transparency, three-dimensional effect, glossiness, etc., to the nails.
Claims (9)
(A)着色された、屈折率の異なる2種類以上の高分子化合物を含む干渉繊維
(B)皮膜形成剤
(C)非芳香族系溶剤
を含有することを特徴とする美爪料。 The following components (A) to (C);
(A) Colored interference fiber containing two or more kinds of polymer compounds having different refractive indexes (B) Film-forming agent (C) A non-aromatic solvent is contained in the nail polish.
Furthermore, the beauty nail material in any one of Claims 1-8 containing water as a component (E).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2005098982A JP2005314390A (en) | 2004-03-30 | 2005-03-30 | Manicure preparation |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004101028 | 2004-03-30 | ||
| JP2005098982A JP2005314390A (en) | 2004-03-30 | 2005-03-30 | Manicure preparation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2005314390A true JP2005314390A (en) | 2005-11-10 |
Family
ID=35442173
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2005098982A Pending JP2005314390A (en) | 2004-03-30 | 2005-03-30 | Manicure preparation |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2005314390A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015098441A (en) * | 2013-10-15 | 2015-05-28 | 株式会社コーセー | Marbled manicure preparation |
| US9168209B2 (en) | 2013-03-13 | 2015-10-27 | Johnson & Johnson Consumer Inc. | Pigmented skin-care compositions |
| US9168394B2 (en) | 2013-03-13 | 2015-10-27 | Johnson & Johnson Consumer Inc. | Pigmented skin-care compositions |
| US9168393B2 (en) | 2013-03-13 | 2015-10-27 | Johnson & Johnson Consumer Inc. | Pigmented skin-care compositions |
| US9320687B2 (en) | 2013-03-13 | 2016-04-26 | Johnson & Johnson Consumer Inc. | Pigmented skin-care compositions |
| JP2017193491A (en) * | 2016-04-18 | 2017-10-26 | 株式会社ビューティガレージ | Nail color gel |
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| WO1998046815A1 (en) * | 1997-04-11 | 1998-10-22 | Teijin Limited | Fiber having optical interference function and its utilization |
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| WO2002041855A1 (en) * | 2000-11-23 | 2002-05-30 | L'oreal | Cosmetic composition comprising interferential particles and a colouring material |
| JP2002234821A (en) * | 2001-02-08 | 2002-08-23 | Kose Corp | Solvent based manicure preparation |
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|---|---|---|---|---|
| JPH07309719A (en) * | 1994-05-17 | 1995-11-28 | Shiseido Co Ltd | Nail-beautifying agent |
| JPH09157957A (en) * | 1995-12-08 | 1997-06-17 | Tanaka Kikinzoku Kogyo Kk | Coloring structure |
| WO1998046815A1 (en) * | 1997-04-11 | 1998-10-22 | Teijin Limited | Fiber having optical interference function and its utilization |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9168209B2 (en) | 2013-03-13 | 2015-10-27 | Johnson & Johnson Consumer Inc. | Pigmented skin-care compositions |
| US9168394B2 (en) | 2013-03-13 | 2015-10-27 | Johnson & Johnson Consumer Inc. | Pigmented skin-care compositions |
| US9168393B2 (en) | 2013-03-13 | 2015-10-27 | Johnson & Johnson Consumer Inc. | Pigmented skin-care compositions |
| US9320687B2 (en) | 2013-03-13 | 2016-04-26 | Johnson & Johnson Consumer Inc. | Pigmented skin-care compositions |
| JP2015098441A (en) * | 2013-10-15 | 2015-05-28 | 株式会社コーセー | Marbled manicure preparation |
| JP2017193491A (en) * | 2016-04-18 | 2017-10-26 | 株式会社ビューティガレージ | Nail color gel |
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