JP2005343974A - Silicone composition for solvent-free release paper - Google Patents

Abstract

PROBLEM TO BE SOLVED: To reduce the amount of mist generated even when high viscosity silicone is included when solvent-free release paper silicone is applied at high speed.
(A) Organopolysiloxane having at least two alkenyl groups in one molecule and an alkenyl group content of 0.002 to 0.60 mol / 100 g, (B) silicon in one molecule Polyorganohydrogensiloxane having at least two hydrogen atoms bonded to the atoms, (C) 0.3 to 30 mol% of (meth) acrylic groups based on all organic groups bonded to silicon atoms in one molecule A hydrosilylation reaction is carried out in advance using a platinum group metal compound as a catalyst for a mixture containing at least 10 mole ratio of SiH of component (B) / (meth) acrylic group of component (C) in a molar ratio. A silicone composition containing the obtained compound and (D) a catalytic amount of a platinum group metal compound.
[Selection figure] None

Description

  The present invention relates to a silicone composition for solventless release paper.

  Various silicone compositions for release paper are known. Among them, solvent-type silicone compositions have been widely used in terms of release characteristics and relatively low substrate selectivity. However, in recent years, there has been an increasing demand for solventless silicone compositions from the aspects of safety and hygiene. Various types of solventless silicone compositions are known (see Patent Documents 1 to 4).

  In addition, with the aim of improving productivity, this solventless release paper silicone has been applied at a high speed. In general, when solventless silicone is applied at a high speed, a phenomenon in which silicone called mist is scattered in a mist form at the coater head. This mist amount tends to increase as the coating speed increases. As a method for improving this mist, Chung et al. (See Patent Document 5) show that the amount of mist during high-speed coating can be reduced by adding an oxyalkylene-modified silicone compound to a solventless silicone.

  Also, a mixture containing either an alkenyl group-containing siloxane or a polyorganohydrogensiloxane in a large excess (SiH / alkenyl is 4.6 or more or alkenyl group / SiH is 4.6 or more) is reacted in advance with a platinum catalyst or the like. It is shown that the amount of mist at the time of high-speed coating can be similarly reduced by adding the above compounds to solventless silicone (see Patent Documents 6 to 7).

JP 49-47426 A Japanese Patent Laid-Open No. 50-141591 Japanese Patent Publication No.52-39791 JP 57-77395 A US Pat. No. 5,562,023 Japanese translation of PCT publication No. 2004-501262 JP-T-2004-501264

  On the other hand, slipperiness similar to that of solvent-type silicone is often required for solvent-free silicone, and as a solution to this problem, mixing high-viscosity silicone with solvent-free silicone is often used. By adding a high viscosity silicone to the solventless silicone, slipping of the cured film can be imparted, but mist as described above is likely to occur when this silicone is applied. Even in such a case, development of an effective mist inhibitor has been desired.

  As a result of intensive studies to achieve the above object, the present inventor obtained an addition product obtained by subjecting a (meth) acryl group-containing polyorganosiloxane and a large excess of polyhydrogenorganosiloxane to an addition reaction with a platinum group complex. Amount of mist generated when added to solvent-free release paper silicone at high speed, especially when high-viscosity silicone is contained in solvent-free silicone Has been found to be able to be reduced, and has led to the present invention.

That is, the present invention
(A) A polyorganosiloxane having at least two alkenyl groups in one molecule and having an alkenyl group content of 0.002 to 0.60 mol / 100 g and a viscosity at 25 ° C. of 50 to 100,000 mPa · s. Part (B) A polyorganohydrogensiloxane having at least two hydrogen atoms bonded to silicon atoms in one molecule, wherein the number of moles of hydrogen atoms bonded to silicon atoms is 0. Mass parts corresponding to 5 to 5 moles (C) (Meth) acrylic group-containing polyorganosiloxane represented by the following average composition formula (1)

Ｒ^１は水素原子または炭素数１〜４のアルキル基あるいはフェニル基、α、βは０、１、２または３である。Ｒ^２は一般式（２）で示される基で、

R ¹ is a hydrogen atom, an alkyl group having 1 to 4 carbon atoms or a phenyl group, and α and β are 0, 1, 2, or 3. R ² is a group represented by the general formula (2),

（ここにＲ^３は水素原子またはメチル基、ｎは１〜３）
１分子中のケイ素原子に結合している全有機基に対して０．３〜３０モル％は一般式（２）で示される基であり、ｂは０〜５、１分子中の平均ケイ素原子数はａ＋（ｄ＋ｅ）×ｂ＋ｃ＝５〜５００と、１分子中にケイ素原子に結合した水素原子を少なくとも２個有するポリオルガノハイドロジェンシロキサンでケイ素原子に結合した水素原子のモル数と上記アクリル基含有ポリオルガノシロキサンの（メタ）アクリル基量のモル数の比率（ＳｉＨ数／（メタ）アクリル基数）が少なくとも１０以上の混合物を、白金族金属系化合物を触媒として用いハイドロシリレーション反応を行って得られた化合物
０．１〜１０質量部
（Ｄ）触媒量の白金族金属系化合物
を含有するシリコーン組成物からなる無溶剤型剥離紙用シリコーンを高速塗工した場合、特に無溶剤型シリコーン中に高粘度のシリコーンが含まれている場合でも発生するミストの量を低減できることを見出し本発明をなすに至ったものである。

(Where R ³ is a hydrogen atom or a methyl group, n is 1 to 3)
0.3 to 30 mol% is a group represented by the general formula (2) with respect to all organic groups bonded to silicon atoms in one molecule, and b is 0 to 5 and an average silicon atom in one molecule. The number is a + (d + e) × b + c = 5 to 500, and the number of moles of hydrogen atoms bonded to silicon atoms in the polyorganohydrogensiloxane having at least two hydrogen atoms bonded to silicon atoms in one molecule and the acrylic group Hydrosilylation reaction is carried out using a mixture of at least 10 mole ratio of the (meth) acrylic group amount of the polyorganosiloxane contained (SiH number / (meth) acrylic group number) using a platinum group metal compound as a catalyst. The resulting compound
When the silicone for solvent-free release paper comprising a silicone composition containing 0.1 to 10 parts by mass (D) catalytic amount of a platinum group metal compound is applied at high speed, the solvent-free silicone has a particularly high viscosity. The present inventors have found that the amount of mist generated even when silicone is contained can be reduced.

  The silicone composition of the present invention has the effect of reducing the amount of mist generated when the solvent-free release paper silicone is applied at high speed.

Hereinafter, the present invention will be described in more detail.
Component (A) that constitutes the solvent-free release paper silicone has at least two alkenyl groups in one molecule and has an alkenyl group content of 0.002 to 0.60 mol / 100 g. As the polyorganosiloxane having a viscosity of 50 to 100,000 mPa · s, the following average formula (3)
R ⁴ _f R ⁵ _g SiO _{(4-f-g) / 2} (3)
Wherein R ⁴ is the same or different substituted or unsubstituted hydrocarbon group, R ⁵ is an alkenyl group represented by — (CH ₂ ) _h —CH═CH ₂ (h is 0 to 6), f is 0 to 3, g is 3 or less and a positive number other than 0, and f + g is 1 to 3).

The alkenyl group R ⁵ directly bonded to the silicon atom in one molecule of the polyorganosiloxane may be an amount such that the alkenyl group content is 0.02 to 0.60 mol / 100 g. If the amount of alkenyl groups is less than 0.02 mol / 100 g, a substantial curing rate may not be obtained, and if it exceeds 0.6 mol / 100 g, the peeling characteristics are deteriorated.

Examples of R ⁴ other than an alkenyl group bonded to a silicon atom include a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, an octyl group, a decyl group, a dodecyl group, a tetradecyl group, a hexadecyl group, An alkyl group such as an octadecyl group; a cycloalkyl group such as a cyclohexyl group; an aryl group such as a phenyl group, a naphthyl group, or a tolyl group; or a part or all of hydrogen atoms bonded to carbon atoms of these groups are halogen atoms Unsubstituted or substituted with 1 to 30 carbon atoms of the same or different species, such as chloromethyl, 3,3,3-trifluoropropyl, cyanopropyl, phenol, hindered phenol, etc. Or a substituted monovalent hydrocarbon group etc. are illustrated. In the present invention, a methyl group, a phenyl group, and an alkyl group having 2 to 8 carbon atoms are particularly preferable. In particular, groups other than alkenyl groups bonded to silicon atoms are preferably at least 50 mol% of all substituents based on methyl groups.

  f is 0 ≦ f ≦ 3, g is 0 <g ≦ 3, f + g is 1 ≦ f + g ≦ 3, particularly f is 0.5 ≦ f ≦ 2.5, g is 0.0002 ≦ g ≦ 1, f + g Is preferably 1.5 ≦ f + g ≦ 2.5.

  This polyorganosiloxane may be either linear or branched, and its end may be any organic group such as, for example, a methyl group, a hydroxyl group, an alkenyl group, a phenyl group, an acryloxyalkyl group, An alkenyl group is preferred. The viscosity of the polyorganosiloxane may be 50 to 100,000 mPa · s, preferably 100 to 2000 mPa · s at 25 ° C.

Next, the polyorganohydrogenpolysiloxane as component (B) has two or more hydrogen atoms (SiH groups) directly bonded to silicon atoms in one molecule, and these SiH groups and alkenyl groups of polyorganosiloxane (A). A cured film is formed by the addition reaction with, and those represented by the following average formula (4) are preferred.
R ⁶ _{pH q} SiO _{(4-pq) / 2} (4)
In the formula, R ⁶ is an unsubstituted or substituted monovalent hydrocarbon group, preferably having 1 to 8 carbon atoms and having no aliphatic unsaturated bond.

Examples of R ⁶ include alkyl groups such as methyl group, ethyl group, and propyl group, aryl groups such as phenyl group, and halogen-substituted alkyl groups such as 3,3,3-trifluoropropyl group.

  Further, p and q are 0.5 ≦ p ≦ 1.5, 0.5 ≦ q ≦ 1.5, 0 ≦ p + q ≦ 3.0, particularly 0.8 ≦ p ≦ 1.0, 0.8 ≦ q. It is preferable that ≦ 1.0 and 1.6 ≦ p + q ≦ 2.0.

  The polyorganohydrogensiloxane may be blended so that the number of moles of hydrogen atoms bonded to silicon atoms is equal to 0.5 parts by weight of the alkenyl group in component (A). . If the blending amount is 0.5 mol or less, curing is insufficient, and if it exceeds 5 mol, the peeling force becomes larger than necessary.

  Examples of the (meth) acryl group-containing polyorganopolysiloxane that is the main raw material of the component (C) include those represented by the following average composition formula (1).

ここで、Ｒ^１は水素原子または炭素数１〜４のアルキル基あるいはフェニル基であり具体的にメチル基、エチル基、プロピル基等のアルキル基、フェニル基等のアリール基があげられる。α、βは０、１、２または３である。

Here, R ¹ is a hydrogen atom, an alkyl group having 1 to 4 carbon atoms or a phenyl group, and specific examples thereof include an alkyl group such as a methyl group, an ethyl group and a propyl group, and an aryl group such as a phenyl group. α and β are 0, 1, 2 or 3.

R ² is a group represented by the following general formula (2).

（ここにＲ^３は水素原子またはメチル基、ｎは１〜３）

(Where R ³ is a hydrogen atom or a methyl group, n is 1 to 3)

  (C) 0.3-30 mol% is group shown by General formula (2) with respect to all the organic groups couple | bonded with the silicon atom in a component molecule, b is 0-5, The average number of silicon atoms a + (d + e) × b + c is 5 to 500, preferably 50 to 200.

  Component (C) includes the (meth) acrylic group-containing polyorganopolysiloxane and polyorganohydrogensiloxane, the number of moles of hydrogen atoms bonded to the silicon atoms of the polyorganohydrogensiloxane, and the acrylic group-containing polyorganosiloxane. The ratio of moles of (meth) acrylic groups (SiH number / (meth) acrylic group number) is at least 10 or more, preferably 10 to 100, and a platinum group metal compound is used as a catalyst in this mixture. A silylation reaction can be performed.

  As this platinum group metal compound used at this time, a known addition reaction catalyst can be used. Examples of such platinum group metal-based catalysts include platinum-based, palladium-based, rhodium-based, and ruthenium-based catalysts. Of these, platinum-based catalysts are particularly preferably used. Examples of the platinum-based catalyst include chloroplatinic acid, alcohol solution or aldehyde solution of chloroplatinic acid, complexes of chloroplatinic acid with various olefins or vinyl siloxane, and the like. The amount of the platinum group metal catalyst added is a catalyst amount, but considering the storage stability of the product, the platinum group metal is added to the total amount of (meth) acryl group-containing polyorganopolysiloxane and polyorganohydrogensiloxane. The amount is preferably in the range of 1 to 100 ppm.

  Reaction conditions are not particularly limited as long as this reaction proceeds, but the reaction may be performed at 20 to 100 ° C. for about 1 to 20 hours. Moreover, as the usage-amount of this component (C), the usage-amount of 0.1-10 mass parts is sufficient with respect to 100 mass parts of component (A), and when it is less than 0.1 weight part, sufficient mist suppression effect will be acquired. If the amount exceeds 10 parts by mass, the peeling force increases, which is not preferable.

  Next, the platinum group metal catalyst used as the component (D) is a catalyst for promoting the addition reaction between the polyorganosiloxane (A) and the polyorganohydrogensiloxane (B), and is a known addition reaction catalyst. Can be used. Examples of such platinum group metal-based catalysts include platinum-based, palladium-based, rhodium-based, and ruthenium-based catalysts. Of these, platinum-based catalysts are particularly preferably used. Examples of the platinum-based catalyst include chloroplatinic acid, alcohol solution or aldehyde solution of chloroplatinic acid, complexes of chloroplatinic acid with various olefins or vinyl siloxane, and the like. Although the addition amount of these platinum group metal catalysts is a catalytic amount, while obtaining a good cured film, from the economical viewpoint, the total amount of polyorganosiloxane (A) and polyorganohydrogensiloxane (B) The platinum metal content is preferably in the range of 1 to 1000 ppm.

  The silicone composition of the present invention can be obtained by blending predetermined amounts of the above components (A) to (D). In addition to the above components, as an optional component, for example, the catalytic activity of a platinum group metal catalyst can be obtained. For the purpose of suppression, known control agents such as various organic nitrogen compounds, organic phosphorus compounds, acetylene compounds, oxime compounds, and organic chloro compounds can be used. For example, acetylenic alcohols such as 3-methyl-1-butyn-3-ol, 3,5-dimethyl-1-hexyn-3-ol, 3-methyl-1-penten-3-ol, and phenylbutynol, 3 -Acetylene compounds such as methyl-3--1-penten-1-yne and 3,5-dimethyl-1-hexyne-3-yne, and these acetylene compounds and alkoxysilane or siloxane or hydrogensilane or siloxane Examples include reactants, vinylsiloxanes such as tetramethylvinylsiloxane cyclics, organic nitrogen compounds such as benzotriazole, and other organic phosphorus compounds, oxime compounds, and organic chromium compounds.

  Moreover, the compounding quantity of this compound as a control agent should just be the quantity from which favorable treatment-bath stability is acquired, and generally 0.01-10 weight with respect to 100 weight part of (I) component and (II) component. Parts, preferably 0.05 to 5 parts by weight.

  On the other hand, for the purpose of controlling the peeling force, a silicone resin, silica, or a polyorganosiloxane having no hydrogen atom (SiH group) or alkenyl group bonded to a silicon atom can be added as necessary. In addition, the addition amount of an arbitrary component can be made into a normal amount in the range which does not inhibit the effect of this invention. In preparing the silicone composition of the present invention, it is preferable to add components (D) after mixing components (A) to (C) and optional components, if necessary, uniformly in advance. In addition, each component may be used individually by 1 type of each component, or may use 2 or more types together.

  The silicone composition thus prepared is applied to various substrates and cured by heat. The base material is not particularly limited and can be applied to all base materials generally used for release paper. Specific examples include glassine paper, crecote paper, high-quality paper, polyethylene laminated paper, and plastic film. It is done. Moreover, there is no restriction | limiting in particular also in the coating amount of a silicone composition, However, Usually, what is necessary is just about 0.05-3.0 g / m2. In addition, hardening of the said silicone composition should be performed at 50-200 degreeC. In this case, the heating time can be 1 second to 5 minutes.

  EXAMPLES Hereinafter, although an Example and a comparative example are shown and this invention is demonstrated concretely, this invention is not limited by this. In the following examples, the physical properties in the table are measured by the following test methods.

The method for adjusting the component (C) of the present invention is as follows.
[Synthesis Example 1]
In the lower average composition, it is represented by a1 + (d1 + e1) × b1 + c1 = 120, b = 1,

下記式で表されるアクリル基を全有機基に対して５ｍｏｌ％有し、残りの全有機基がメチル基である粘度１２０ｍＰ・ｓのアクリル基含有ポリオルガノシロキサン４０質量部と、

40 parts by mass of an acrylic group-containing polyorganosiloxane having a viscosity of 120 mP · s having an acrylic group represented by the following formula of 5 mol% based on the total organic groups and the remaining total organic groups being methyl groups;

下記平均式で表されるポリオルガノハイドロジェンシロキサンを２８８質量部を良く混合し、

288 parts by mass of polyorganohydrogensiloxane represented by the following average formula are mixed well,

さらに、塩化白金酸とビニルシロキサンの錯塩を２．０質量部（白金原子として約３０ｐｐｍ）を添加し良く混合する。次にこの混合物を攪拌しながら８０℃まで加温し、その温度で５時間反応させ粘度約１００ｍＰ・ｓの淡黄色液体（Ｃ−１）を得た。

Furthermore, 2.0 parts by mass (about 30 ppm as platinum atoms) of a complex salt of chloroplatinic acid and vinylsiloxane is added and mixed well. Next, this mixture was heated to 80 ° C. with stirring, and reacted at that temperature for 5 hours to obtain a pale yellow liquid (C-1) having a viscosity of about 100 mP · s.

[Synthesis Example 2]
In the average composition, a1 + (d1 + e1) × b1 + c1 = 50, b1 = 0, and represented by the following formula, the acrylic group has about 2 mol% with respect to all organic groups, and the remaining all organic groups are methyl groups. 50 parts by mass of an acrylic group-containing polyorganosiloxane having a viscosity of 50 mP · s

下記平均式で表されるポリオルガノハイドロジェンシロキサンを２００質量部を良く混合し、

200 parts by mass of polyorganohydrogensiloxane represented by the following average formula are mixed well,

さらに、塩化白金酸とビニルシロキサンの錯塩を０．０８質量部（白金原子として約２ｐｐｍ）を添加し良く混合する。次にこの混合物を攪拌しながら２５℃で２０時間反応させ粘度約３５００ｍＰ・ｓの淡黄色液体（Ｃ−２）を得た。

Further, 0.08 parts by mass (about 2 ppm as platinum atoms) of a complex salt of chloroplatinic acid and vinylsiloxane is added and mixed well. Next, this mixture was reacted at 25 ° C. for 20 hours with stirring to obtain a pale yellow liquid (C-2) having a viscosity of about 3500 mP · s.

[Example 1]
The component (A) has a viscosity at 25 ° C. of 400 mPa · s and a vinyl value of 0.02 mol / 100 g. Both end vinyl group-containing polydimethylsiloxane 98 parts by mass, the component (B) has the following average formula It is represented by

[Example 2]
The component (A) has a viscosity at 25 ° C. of 400 mPa · s and a vinyl value of 0.02 mol / 100 g. Both end vinyl group-containing polydimethylsiloxane 98 parts by mass, the component (B) has the following average formula 2.0 parts by mass of a polyorganohydrogensiloxane represented by

エチニルシクロヘキサノール０．３質量部を均一に混合し、さらに、成分（Ｃ）として前記で合成した淡黄色液体（Ｃ−２）を０．５質量部、成分（Ｄ）として塩化白金酸とビニルシロキサンの錯塩を２質量部（白金原子として約１００ｐｐｍ）を添加しさらに均一に混合し、ミスト発生実験に使用した。

0.3 parts by mass of ethynylcyclohexanol was uniformly mixed, and 0.5 parts by mass of the pale yellow liquid (C-2) synthesized above as component (C) and chloroplatinic acid and vinyl as component (D) 2 parts by mass (about 100 ppm as platinum atoms) of a siloxane complex salt was added and mixed uniformly, and used for a mist generation experiment.

[Example 3]
The component (A) has a viscosity at 25 ° C. of 400 mPa · s and a vinyl value of 0.02 mol / 100 g. Both end vinyl group-containing polydimethylsiloxane 98 parts by mass, the component (B) has the following average formula 2.0 parts by mass of a polyorganohydrogensiloxane represented by

エチニルシクロヘキサノール０．３質量部を均一に混合し、さらに、成分（Ｃ）として前記で合成した淡黄色液体（Ｃ−２）を１．０質量部、成分（Ｄ）として塩化白金酸とビニルシロキサンの錯塩を２質量部（白金原子として約１００ｐｐｍ）を添加しさらに均一に混合し、ミスト発生実験に使用した。

0.3 parts by mass of ethynylcyclohexanol was mixed uniformly, and further, 1.0 part by mass of the pale yellow liquid (C-2) synthesized above as component (C) and chloroplatinic acid and vinyl as component (D) 2 parts by mass (about 100 ppm as platinum atoms) of a siloxane complex salt was added and mixed uniformly, and used for a mist generation experiment.

[Example 4]
The component (A) of the present invention has a viscosity at 25 ° C. of 400 mPa · s and a vinyl value of 0.02 mol / 100 g. 2.0 parts by mass of a polyorganohydrogensiloxane represented by

エチニルシクロヘキサノール０．３質量部を均一に混合し、さらに、成分（Ｃ）として前記で合成した淡黄色液体（Ｃ−２）を４．０質量部、成分（Ｄ）として塩化白金酸とビニルシロキサンの錯塩を２質量部（白金原子として約１００ｐｐｍ）を添加しさらに均一に混合し、ミスト発生実験に使用した。

0.3 parts by mass of ethynylcyclohexanol was uniformly mixed, and 4.0 parts by mass of the pale yellow liquid (C-2) synthesized above as component (C) and chloroplatinic acid and vinyl as component (D) 2 parts by mass (about 100 ppm as platinum atoms) of a siloxane complex salt was added and mixed uniformly, and used for a mist generation experiment.

[Example 5]
As component (A) of the present invention, the viscosity at 25 ° C. is 400 mPa · s and the vinyl value is 0.02 mol / 100 g. Both end vinyl group-containing polydimethylsiloxane 45 parts by mass and the viscosity at 25 ° C. is 100 mPa · s. 45 parts by mass of both end vinyl group-containing polydimethylsiloxanes having a vinyl value of 0.04 mol / 100 g, 2.2 parts by mass of polyorganohydrogensiloxane represented by the following formula as an average component (B),

エチニルシクロヘキサノール０．３質量部を均一に混合し、さらに、高粘度のシリコーンとして両末端が水酸基である２５℃の粘度が１０００００ｍＰ・ｓのポリジメチルシロキサン７質量部、成分（Ｃ）として前記で合成した淡黄色液体（Ｃ−２）を１．０質量部、成分（Ｄ）として塩化白金酸とビニルシロキサンの錯塩を２質量部（白金原子として約１００ｐｐｍ）を添加しさらに均一に混合し、ミスト発生実験に使用した。

0.3 parts by mass of ethynylcyclohexanol is uniformly mixed, and further, 7 parts by mass of polydimethylsiloxane having a viscosity of 100000 mP · s at 25 ° C., which is a hydroxyl group at both ends as a high-viscosity silicone, and the above as component (C) 1.0 parts by weight of the synthesized pale yellow liquid (C-2), 2 parts by weight (about 100 ppm as platinum atoms) of a complex salt of chloroplatinic acid and vinylsiloxane as component (D), and further uniformly mixed, Used for mist generation experiments.

[Comparative Example 1]
A silicone composition was prepared in the same manner as in Example 1 except that the component (C) was not added, and this was used as Comparative Example 1 and used in a mist generation experiment.

[Comparative Example 2]
A silicone composition was prepared in the same manner as in Example 5 except that the component (C) was not added, and this was used as Comparative Example 2, which was used in the mist generation experiment.

《Mist generation experiment》
Using a coater head consisting of five rolls as shown in Figure 1 below,

[Figure 1]

Between the rolls D and E, the above-adjusted silicone (Examples 1 to 4 and Comparative Examples 1 and 2) is placed and adjusted so that each roll has the speed shown in Table 1, and the coater head is operated at this speed. At this time, the amount of mist-like silicone particles (mist) generated between the rolls A and B was measured for 1 minute using a particle counter 8520DustTrak manufactured by Transtec Corporation.

  Table 2 shows the mist reduction rate when the amount of mist generated in Comparative Examples 1 and 2 is 100 and a mist inhibitor (component C) is added to the same composition (Examples 1 to 4).

Description of Table 2 It turns out that the generation amount of mist at the time of high-speed coating can be reduced by containing the component (C) of the present invention in Examples 1 to 4, and the component (C) of the present invention has a mist suppressing effect. I understand that. In Example 5, it is understood that the present invention has a sufficient mist suppressing effect even in a system in which a high viscosity silicone is added to a solventless silicone.

Claims (3)

(A) Organopolysiloxane having at least two alkenyl groups in one molecule and having an alkenyl group content of 0.002 to 0.60 mol / 100 g and a viscosity at 25 ° C. of 50 to 100,000 mPa · s 100 Part (B) A polyorganohydrogensiloxane having at least two hydrogen atoms bonded to silicon atoms in one molecule, wherein the number of moles of hydrogen atoms bonded to silicon atoms is 0. Mass parts corresponding to 5 to 5 moles (C) (Meth) acrylic group-containing polyorganosiloxane represented by the following average composition formula (1)

R ¹ is a hydrogen atom, an alkyl group having 1 to 4 carbon atoms or a phenyl group, and α and β are 0, 1, 2, or 3. R ² is a group represented by the general formula (2),

(Where R ³ is a hydrogen atom or a methyl group, n is 1 to 3)
0.3 to 30 mol% is a group represented by the general formula (2) with respect to all organic groups bonded to silicon atoms in one molecule, and b is 0 to 5 and an average silicon atom in one molecule. The number is a + (d + e) × b + c = 5 to 500, and the number of moles of hydrogen atoms bonded to silicon atoms in the polyorganohydrogensiloxane having at least two hydrogen atoms bonded to silicon atoms in one molecule and the acrylic group A hydrosilylation reaction is performed in advance using a mixture in which the ratio of the number of moles of the (meth) acrylic group in the polyorganosiloxane contained (SiH number / (meth) acrylic group number) is at least 10 or more using a platinum group metal compound as a catalyst. Compound obtained.
0.1 to 10 parts by mass (D) a catalytic amount of a platinum group metal compound.
Containing silicone composition The organopolysiloxane of component (A) has the following average formula (3)
R ⁴ _f R ⁵ _g SiO _{(4-f-g) / 2} (3)
Wherein R ⁴ is the same or different substituted or unsubstituted hydrocarbon group, R ⁵ is an alkenyl group represented by — (CH ₂ ) _h —CH═CH ₂ (h is 0 to 6), The silicone composition according to claim 1, wherein f is 0 to 3, g is 3 or less and a positive number other than 0, and f + g is 1 to 3. Component (B) is an organohydrodienesiloxane having the following average formula (4)
R ⁶ _{pH q} SiO _{(4-pq) / 2} (4)
(In the formula, R ⁶ is an unsubstituted or substituted monovalent hydrocarbon group having 1 to 8 carbon atoms having no aliphatic unsaturated bond, at least 80% is a methyl group, and a and b are 0 0.7 ≦ a ≦ 2.1, 0.001 ≦ b ≦ 1.0, and 0.8 ≦ a + b ≦ 2.6.)) Bonded to a silicon atom in one molecule The silicone composition of claim 1 having at least two atoms.