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JP2005205666A - Laminated cylindrical body with excellent heat insulation and heat distortion resistance and plunger sleeve for die casting machine - Google Patents

Laminated cylindrical body with excellent heat insulation and heat distortion resistance and plunger sleeve for die casting machine Download PDF

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JP2005205666A
JP2005205666A JP2004013088A JP2004013088A JP2005205666A JP 2005205666 A JP2005205666 A JP 2005205666A JP 2004013088 A JP2004013088 A JP 2004013088A JP 2004013088 A JP2004013088 A JP 2004013088A JP 2005205666 A JP2005205666 A JP 2005205666A
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metal
cylinder
laminated
cylindrical body
metal cylinder
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Takahiro Gama
隆弘 蒲
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Kubota Corp
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Abstract

【課題】ダイカストマシン用プランジャースリーブ等として好適な断熱保温性及び耐熱変形性等に優れた積層円筒体を提供する。
【解決手段】第1の積層円筒体10は、未焼結セラミックス層を挟んで金属円筒を同心円状に重ね合せ、少なくとも最内層の金属円筒(第1金属円筒)11とその外側の金属円筒(第2金属円筒)12とに挟まれたセラミックス層に金属細線等の層間連結金属材3が分散配置した積層組付け体を、熱間塑性加工に付し肉厚方向に圧縮すると共に層間連結金属材3と第1金属円筒11及び第2金属円筒12との接触部を拡散接合させた積層成形体である。第2の積層円筒体は、積層組付け体を熱間塑性加工し肉厚方向に圧縮して形成された積層成形体からなり、該積層成形体に分散形成された小孔を介して、第1金属円筒11とその外側の金属円筒とが溶接により結合されている。第1金属円筒の肉厚は好ましくは約3-15mm,セラミックス層の層厚は好ましくは1mm以下である。
【選択図】図1
The present invention provides a laminated cylindrical body excellent in heat insulation and heat distortion resistance suitable as a plunger sleeve for a die casting machine.
A first laminated cylinder 10 1 Not across the sintered ceramics layer superposed a metal cylinder concentrically, at least the innermost layer of the metal cylinder (first metal cylinder) 11 and its outer metal cylinder (Layer 2 metal cylinder) Laminated assembly in which interlaminar interconnect metal 3 such as fine metal wires is dispersedly disposed in a ceramic layer sandwiched between 12 is subjected to hot plastic working and compressed in the thickness direction and interlaminar connection It is a laminated molded body in which contact portions between the metal material 3 and the first metal cylinder 11 and the second metal cylinder 12 are diffusion bonded. The second laminated cylindrical body is a laminated molded body formed by hot plastic processing the laminated assembly and compressing it in the thickness direction, and through the small holes dispersedly formed in the laminated molded body, One metal cylinder 11 and the outer metal cylinder are joined by welding. The thickness of the first metal cylinder is preferably about 3-15 mm, and the thickness of the ceramic layer is preferably 1 mm or less.
[Selection] Figure 1

Description

本発明は、セラミックス層を挟む積層構造による卓抜した断熱保温性を有すると共に、積層構造に生じ易い熱変形を抑制防止するための耐熱変形性を具備し、ダイカストマシンのプランジャースリーブ等としてして好適に使用される積層円筒体に関する。   The present invention has an excellent heat insulation and heat retaining property due to a laminated structure sandwiching a ceramic layer, and has a heat resistant deformability for suppressing and preventing thermal deformation that tends to occur in the laminated structure, as a plunger sleeve of a die casting machine, etc. The present invention relates to a suitably used laminated cylindrical body.

非鉄金属(アルミニウム合金,マグネシウム合金等)を射出鋳造するダイカストマシンの鋳造操作はプランジャースリーブを介して行なわれる。ダイカストマシンは金型及びスリーブの配置構成により、図22の横型装置と図23の竪型装置とに大別される。プランジャースリーブ(70)はダイプレート(91)に固定されて金型(92)に接続されている。横型装置(図13)のスリーブ(70)は後部側に給湯口(71)を有し、金属溶湯(M)は該開口(71)からスリーブ内に供給され、縦型装置(図14)のスリーブ(70)(給湯口を有しない円筒体)への給湯は、鎖線のように傾動させたスリーブ(70)の上端の開口から行なわれる。スリーブ(70)に供給された金属溶湯(M)はプランジャーチップ(80)により金型(92)のキャビティ(93)内に射出(圧入)される。スリーブ(70)は、非鉄金属溶湯に対する腐食抵抗性、耐熱衝撃性、及びスリーブ内を進退駆動されるプランジャーチップ(80)に対する摺動性と摺動摩耗抵抗性を必要とすることから、SKD61に代表される合金工具鋼(JIS-G4404)製の円筒体が使用されている。   The casting operation of a die casting machine for injection casting non-ferrous metals (aluminum alloy, magnesium alloy, etc.) is performed via a plunger sleeve. The die casting machine is roughly classified into a horizontal apparatus shown in FIG. 22 and a saddle type apparatus shown in FIG. 23 according to the arrangement of the mold and the sleeve. The plunger sleeve (70) is fixed to the die plate (91) and connected to the mold (92). The sleeve (70) of the horizontal device (FIG. 13) has a hot water supply port (71) on the rear side, and the molten metal (M) is supplied into the sleeve from the opening (71), and the sleeve of the vertical device (FIG. 14). Hot water is supplied to the sleeve (70) (cylindrical body having no hot water outlet) from the opening at the upper end of the sleeve (70) tilted like a chain line. The molten metal (M) supplied to the sleeve (70) is injected (press-fitted) into the cavity (93) of the mold (92) by the plunger tip (80). Since the sleeve (70) requires corrosion resistance against non-ferrous metal melt, thermal shock resistance, and slidability and sliding wear resistance against the plunger tip (80) driven forward and backward in the sleeve, the SKD61. A cylindrical body made of alloy tool steel represented by (JIS-G4404) is used.

上記鋳造操業において、プランジャースリーブ(70)に供給された金属溶湯の温度降下が大きいことが従来問題とされている。これはプランジャースリーブの熱伝導率(α)が高く(SKD61:α約34W/m/K)、スリーブとの接触による熱損失が大きいことによる。スリーブ内の溶湯の降温が大きいと、鋳造温度の適正管理・鋳造品質の安定維持の妨げとなり、また温度低下によりスリーブの内面に溶湯が凝着すると、スリーブ内を進退運動するプランジャーチップ(80)の耐用寿命に悪影響を与えるほか、溶湯の凝固片が鋳造製品に混入し製品品質を損なう原因ともなる。溶湯の温度降下を見込んで、スリーブへの給湯温度を高めに設定することは、熱エネルギーコストの負担増となるばかりか、構成部品の熱的損傷を助長することになり好ましくない。   In the above casting operation, it is a conventional problem that the temperature drop of the molten metal supplied to the plunger sleeve (70) is large. This is because the plunger sleeve has a high thermal conductivity (α) (SKD61: α of about 34 W / m / K) and a large heat loss due to contact with the sleeve. When the temperature of the molten metal in the sleeve is large, proper control of the casting temperature and stable maintenance of the casting quality are hindered, and when the molten metal adheres to the inner surface of the sleeve due to the temperature drop, the plunger tip (80 ) Is adversely affected by the service life of molten metal, and solidified pieces of molten metal may be mixed into the cast product and impair product quality. Setting the temperature of the hot water supply to the sleeve to be high in anticipation of the temperature drop of the molten metal is not preferable because it not only increases the heat energy cost but also promotes thermal damage to the components.

上記溶湯の降温を抑制防止するプランジャースリーブの工夫として次のような提案がなされている。
(a)スリーブの肉厚内部に流体流路を形成し、加熱油(約200℃)を循環流通させる。
(b)スリーブ(SKD61等)の内側に、熱伝導率の低いセラミックスからなる円筒体を嵌め込んで固定する(特許文献1)。
(c)スリーブ(SKD61等)の外側に、熱伝導率の低いステンレス鋼等からなる円筒を重合し、重合界面をろう付け,拡散接合,または熱間静水圧処理で接合する(特許文献2)。
特開平02-179346号公報 特開平11-300461号公報
The following proposals have been made as a device for the plunger sleeve that suppresses and prevents the molten metal from falling.
(a) A fluid flow path is formed inside the thickness of the sleeve, and heated oil (about 200 ° C.) is circulated and circulated.
(b) A cylindrical body made of ceramic with low thermal conductivity is fitted and fixed inside the sleeve (SKD61 etc.) (Patent Document 1).
(c) A cylinder made of stainless steel or the like having low thermal conductivity is polymerized on the outside of the sleeve (SKD61, etc.), and the polymerization interface is joined by brazing, diffusion bonding, or hot isostatic pressure treatment (Patent Document 2) .
Japanese Patent Laid-Open No. 02-179346 Japanese Patent Laid-Open No. 11-300461

しかし、スリーブの肉厚内部に流体流路を形成して加熱流体を流通させる内部加熱構造(上記a)は,装置構成が複雑化しメンテナンスの負担が大きく実用性に乏しい。
スリーブの内側にセラミックスの円筒を嵌合した構造(上記b)では、セラミックス(脆性材料)が直接高温の金属溶湯と接触するので、熱衝撃による損傷が生じ易く安定性に乏しい。しかもスリーブの最内面がプランジャーチップとの摺動性に乏しい場合、スリーブとチップの摺接面の損傷により摺接界面に溶湯の差込が生じ易く、摺動抵抗の増大,金型への射出速度の低下等により、鋳造操作の円滑性が損なわれることになる。このためセラミックス円筒はプランジャーチップに対する良好な摺動性を必要とするが、適用し得るセラミックス材種の選択は容易でない。
スリーブの外側にステンレス鋼等の円筒を重合して接合した構造(上記c)による断熱保温性能はそれほど大きくなく、満足し得るものとはいえない。
However, the internal heating structure (above (a)) in which a fluid flow path is formed in the wall thickness of the sleeve to circulate the heating fluid has a complicated apparatus configuration, a large maintenance burden, and poor practicality.
In the structure (b), in which a ceramic cylinder is fitted inside the sleeve, the ceramic (brittle material) is in direct contact with the high-temperature molten metal, so that damage due to thermal shock is likely to occur and the stability is poor. In addition, when the innermost surface of the sleeve is poorly slidable with the plunger tip, the sliding contact surface between the sleeve and the tip is easily damaged, so that the molten metal can easily be inserted into the sliding contact interface, increasing the sliding resistance, The smoothness of the casting operation is impaired due to a decrease in the injection speed or the like. For this reason, the ceramic cylinder requires good slidability with respect to the plunger tip, but it is not easy to select an applicable ceramic material type.
The heat insulation and heat retention performance by the structure (c) described above, in which a cylinder of stainless steel or the like is joined to the outside of the sleeve, is not so large and cannot be said to be satisfactory.

本発明は、断熱保温性、及び構造部材としての安定性やメンテナンス性等に優れ、ダイカストマシンのプランジャースリーブに適用される場合は、供給された金属溶湯の温度低下を効果的に抑制防止してダイカスト鋳造の温度管理を容易にし、鋳造操業及び鋳造品質の向上安定化を可能とする積層円筒体を提供するものである。   The present invention is excellent in heat insulation and heat retention, stability as a structural member, maintainability, and the like, and when applied to a plunger sleeve of a die casting machine, effectively suppresses and prevents a temperature drop of the supplied molten metal. Thus, it is an object of the present invention to provide a laminated cylindrical body that facilitates temperature control of die casting and can improve and stabilize casting operation and casting quality.

本発明に係る第1の積層円筒体は、金属円筒(1)を、繊維状又は粉末状の未焼結セラミックス層(2)を挟んで同心円状に重ね合せ、少なくとも最内層の金属円筒(第1金属円筒)(11)とその外側の金属円筒(第2金属円筒)(12)とに挟まれたセラミックス層に、そのセラミックス層を貫通して第1金属円筒の外周面と第2金属円筒の内周面とに接触する層間連結金属材(3)が分散配置されているカプセル状積層組付け体を、熱間塑性加工に付して肉厚方向に圧縮すると共に層間連結金属材(3)と第1金属円筒(11)及び第2金属円筒(12)との接触部を拡散接合させてなる、第1金属円筒と第2金属円筒とが層間連結金属材を介して相互に結合された積層成形体であることを特徴としている(請求項1)。   In the first laminated cylindrical body according to the present invention, a metal cylinder (1) is concentrically overlapped with a fibrous or powdery unsintered ceramic layer (2) interposed therebetween, and at least the innermost metal cylinder (first 1 metal cylinder) (11) and the outer metal cylinder (second metal cylinder) (12) sandwiched between the ceramic layer and the outer peripheral surface of the first metal cylinder and the second metal cylinder The capsule-like laminated assembly in which the interlayer connection metal material (3) in contact with the inner peripheral surface is dispersedly arranged is subjected to hot plastic working and compressed in the thickness direction and the interlayer connection metal material (3 ) And the first metal cylinder (11) and the second metal cylinder (12) are joined to each other through an interlayer coupling metal material. The first metal cylinder and the second metal cylinder are formed by diffusion bonding. It is characterized in that it is a laminated molded body (claim 1).

本発明の第2の積層円筒体は、金属円筒(1)を、繊維状又は粉末状の未焼結セラミックス層(2)を介して同心円状に重ね合せてなるカプセル状積層組付け体を熱間塑性加工により肉厚方向に圧縮して形成された積層成形体からなり、該積層成形体に分散形成された小孔を介して、最内層の金属円筒とその外側の金属円筒とが溶接(5)により結合されていることを特徴としている(請求項2)。   The second laminated cylindrical body of the present invention heats a capsule-like laminated assembly formed by concentrating metal cylinders (1) concentrically via a fibrous or powdered unsintered ceramic layer (2). It consists of a laminated molded body formed by compressing in the thickness direction by interplastic processing, and the innermost metal cylinder and the outer metal cylinder are welded via small holes dispersedly formed in the laminated molded body ( 5). (Claim 2)

本発明の第3の積層円筒体は、金属外筒体(30)とその内側に焼嵌めにより固定された内筒体(20)とからなり、該内筒体は、上記第1の積層円筒体からなることを特徴としている(請求項2)。 The third laminated cylindrical body of the present invention comprises a metal outer cylindrical body (30) and an inner cylindrical body (20 1 ) fixed to the inner side by shrink fitting, and the inner cylindrical body is the first laminated cylindrical body. It is characterized by comprising a cylindrical body (claim 2).

本発明の第4の積層円筒体は、金属外筒体(30)とその内側に焼嵌めにより固定された内筒体(20)とからなり、該内筒体は上記第2の積層円筒体からなることを特徴としている(請求項4)。 The fourth laminated cylindrical body of the present invention comprises a metal outer cylindrical body (30) and an inner cylindrical body (20 2 ) fixed to the inside by shrink fitting, and the inner cylindrical body is the second laminated cylindrical body. It is characterized by comprising a body (claim 4).

本発明のダイカストマシン用プランジャースリーブは、上記第1〜第4の積層円筒体を形成する金属円筒,外筒体等に所要の鋼材種を適用して構成される積層円筒体からなる(請求項9)。   A plunger sleeve for a die casting machine according to the present invention comprises a laminated cylindrical body configured by applying a required steel material type to a metal cylinder, an outer cylindrical body or the like forming the first to fourth laminated cylindrical bodies (claims). Item 9).

金属の熱間塑性加工温度域ではセラミックスの焼結反応やセラミックスと金属との相互反応はなく、本発明の積層円筒体内のセラミックス層は、実質的に未焼結状態の繊維又は粉末の層として金属円筒同士の重合面間に介在している。セラミックスの焼結品を断熱材とする従来の「金属-セラミックス」積層構造では、比較的厚肉のセラミックス層を必要とするのに対し、本発明の積層円筒体におけるセラミックス層は、その層厚から予測される断熱効果をはるかに超える顕著な熱遮断性能を示す。ダイカストマシン用プランジャースリーブの用途では、約1mm以下(例えば0.1〜0.5mm)の薄いセラミックス層の熱遮断効果として、鋳造温度の安定維持のための明瞭な溶湯降温抑制効果が得られる。   There is no sintering reaction of ceramics or interaction between ceramics and metals in the hot plastic working temperature range of metal, and the ceramic layer in the laminated cylinder of the present invention is a substantially unsintered fiber or powder layer. It is interposed between the overlapping surfaces of the metal cylinders. The conventional “metal-ceramics” laminated structure using a sintered ceramic product as a heat insulating material requires a relatively thick ceramic layer, whereas the ceramic layer in the laminated cylindrical body of the present invention has a layer thickness. The thermal insulation performance far exceeds the thermal insulation effect predicted from In the use of a plunger sleeve for a die casting machine, a clear molten metal temperature-inhibiting effect for maintaining a stable casting temperature can be obtained as a heat shielding effect of a thin ceramic layer of about 1 mm or less (for example, 0.1 to 0.5 mm).

この卓抜した断熱保温効果は、セラミックス層が未焼結層であること及び未焼結セラミックス層と金属円筒との界面の特異性、殊にその界面熱抵抗が著しく高いことによると考えられる。また、セラミックス層が実質的に未焼結の繊維ないし粉末からなる層であることは、焼結セラミックス層(実質的に剛性体である)と異なって、積層円筒体の製造工程(熱間塑性加工)や実機使用時における積層構造の熱膨張収縮変化に追従して変形することができ、熱応力吸収緩和層として機能し熱応力に起因する不具合の回避に奏効する。   This outstanding heat insulation heat retention effect is considered to be due to the fact that the ceramic layer is an unsintered layer and that the interface between the unsintered ceramic layer and the metal cylinder has a particularly high interfacial thermal resistance. Further, the fact that the ceramic layer is a layer made of substantially unsintered fibers or powder is different from the sintered ceramic layer (substantially rigid body) in that the manufacturing process of the laminated cylindrical body (hot plasticity) It can be deformed following the thermal expansion / contraction change of the laminated structure during processing and actual use, functions as a thermal stress absorption relaxation layer, and is effective in avoiding problems caused by thermal stress.

本発明の積層円筒体を、その内側に加熱流体が供給される用途(ダイカストマシン用スリーブ等)に供する場合、セラミックス層による断熱保温効果をより高めるためには、加熱流体と接触する最内層の金属円筒(第1金属円筒)の肉厚をできるだけ薄くすること(=セラミックス層をできるだけ内周面側に近付けること)が有利である。この場合、第1金属円筒を薄肉化するほど、スリーブの中空孔の口径変形(第1金属円筒の膨出変形による真円度低下)が生じ易く、その変形はプランジャーチップの進退運動に伴うスリーブ及びチップ自身の擦過損傷を助長することになる。この点に関して本発明は、第1の積層円筒体(請求項1)及び第3(請求項3)の積層円筒体では、層間連結金属材を介して第1金属円筒をその内側の金属円筒に結合し、他方第2の積層円筒体(請求項2)及び第4の積層円筒体(請求項4)では、小孔を介して層厚方向に形成された溶接により第1金属円筒をその内側の金属円筒に結合せしめ、その連結構造による補強効果として積層円筒体の耐熱変形性を増強し、最内層金属円筒の口径変形を軽減緩和している。   When the laminated cylindrical body of the present invention is used for an application in which a heating fluid is supplied to the inside thereof (such as a sleeve for a die-casting machine), in order to further enhance the heat insulation heat retaining effect by the ceramic layer, It is advantageous to make the thickness of the metal cylinder (the first metal cylinder) as thin as possible (= close the ceramic layer as close to the inner peripheral surface as possible). In this case, the thinner the first metal cylinder is, the more likely it is that the diameter of the hollow hole of the sleeve is deformed (decrease in roundness due to the bulging deformation of the first metal cylinder). This will promote fretting damage of the sleeve and the chip itself. In this regard, according to the present invention, in the first laminated cylinder (Claim 1) and the third laminated cylinder (Claim 3), the first metal cylinder is formed into an inner metal cylinder through an interlayer connecting metal material. On the other hand, in the second laminated cylinder (Claim 2) and the fourth laminated cylinder (Claim 4), the first metal cylinder is connected to the inside by welding formed in the layer thickness direction through a small hole. As a reinforcing effect by the connection structure, the heat resistance deformation property of the laminated cylindrical body is enhanced, and the diameter deformation of the innermost layer metal cylinder is reduced and mitigated.

本発明に係る第1の積層円筒体及び第2の積層円筒体は、熱間塑性加工による一体成形品として得られる積層成形体であり、以下の説明では、前者(第1の積層円筒体)を「積層円筒体(10)」、後者(第2の積層円筒体)を「積層円筒体(10)」と指称する。
また第3の積層円筒体は、第1の積層円筒体を内筒体とし、これを別途用意した外筒体の中空孔内に焼嵌めにより嵌合一体化したものであり、これを「積層円筒体(10)」と指称する。第4の積層円筒体は、前記第2の積層円筒体を内筒体とし、これを別途用意した外筒体の中空孔内に焼嵌めにより嵌合一体化したものであり、これを「積層円筒体(10)」と指称する。
The first laminated cylindrical body and the second laminated cylindrical body according to the present invention are laminated molded bodies obtained as an integrally molded product by hot plastic working. In the following explanation, the former (first laminated cylindrical body) Is referred to as “laminate cylinder (10 1 )”, and the latter (second laminate cylinder) is referred to as “laminate cylinder (10 2 )”.
Further, the third laminated cylindrical body is obtained by fitting and integrating the first laminated cylindrical body into the hollow hole of the separately prepared outer cylindrical body by shrink fitting. Cylindrical body (10 3 ) ". In the fourth laminated cylinder, the second laminated cylinder is used as an inner cylinder, which is fitted and integrated into the hollow hole of the separately prepared outer cylinder by shrink fitting. Cylindrical body (10 4 ) ”.

まず第1の積層円筒体(10)及び第2の積層円筒体(10)について具体例を挙げて詳しく説明する。
[第1の積層円筒体(10)]
第1の積層円筒体(10)は、少なくとも2つの金属円筒と金属円筒同士の重合面を遮断するセラミックス層とからなる。図1は、積層円筒体(10)の層構造を例示している。この積層円筒体(10)は、3つの金属円筒(1)(11,12,13)と、これらの金属円筒(1)同士の重合面の接触を遮断する2つのセラミックス層(2)(21,22)とからなる積層構造を有している。図2は、図1のA部を拡大して示し、図3は図1のI-I矢視断面を示す。積層円筒体(10)の最内層の金属円筒(11)(以下「第1金属円筒」)とこれに隣接する金属円筒(12)(以下「第2金属円筒」)とに挟まれたセラミックス層(21)には層間結合金属材(3)が分散配置されている。層間結合金属材(3)はセラミックス層(21)を貫通して第1金属円筒(11)の外周面と第2金属円筒(12)の内周面とに接触している。第1金属円筒(11)と第2金属円筒(12)とは、層間結合金属材(3)の接触部分の拡散接合により相互に結合されている。
First, the first laminated cylinder (10 1 ) and the second laminated cylinder (10 2 ) will be described in detail with specific examples.
[First laminated cylindrical body (10 1 )]
The first laminated cylindrical body (10 1 ) includes at least two metal cylinders and a ceramic layer that blocks a polymerization surface between the metal cylinders. FIG. 1 illustrates the layer structure of a laminated cylindrical body (10 1 ). This laminated cylindrical body (10 1 ) is composed of three metal cylinders (1) (11, 12, 13) and two ceramic layers (2) (2) that block the contact of the overlapping surfaces of these metal cylinders (1). 21, 22). 2 is an enlarged view of the portion A in FIG. 1, and FIG. 3 is a cross-sectional view taken along arrow II in FIG. Ceramics sandwiched between the innermost metal cylinder (11) (hereinafter referred to as “first metal cylinder”) and the metal cylinder (12) adjacent thereto (hereinafter referred to as “second metal cylinder”) of the laminated cylindrical body (10 1 ). In the layer (21), the inter-layer bonding metal material (3) is dispersedly arranged. The interlayer bonding metal material (3) penetrates the ceramic layer (21) and is in contact with the outer peripheral surface of the first metal cylinder (11) and the inner peripheral surface of the second metal cylinder (12). The first metal cylinder (11) and the second metal cylinder (12) are coupled to each other by diffusion bonding at the contact portion of the interlayer coupling metal material (3).

図4は、前記図1の積層円筒体(10)を、熱間塑性加工成形体として形成するためのカプセル状積層組付け体(A1)の例を示している。カプセル状積層組付け体(A1)は、セラミックス層(21)(22)を介して金属円筒(11)(12)(13)を同心円状に重合したうえ、両端の開口部にドーナツ盤状の端板(15)をあてがって溶接(w)で接合封止することにより構成される。セラミックス層(21)(22)は、繊維状又は粉末状のセラミックスからなる未焼結のセラミックス層であり、第1金属円筒(11)と第2金属円筒(12)に挟まれた第1セラミックス層(21)には、層間結合金属材(3)が分散配置されている。層間結合金属材(3)の一方の端部は第1金属円筒(11)の外周面に接触し、他方の端部は第2金属円筒(12)の内周面に接触している。 FIG. 4 shows an example of a capsule-like laminated assembly (A1) for forming the laminated cylindrical body (10 1 ) of FIG. 1 as a hot-plastic processed product. The capsule-shaped laminated assembly (A1) is formed by concentrically polymerizing the metal cylinders (11), (12), and (13) through the ceramic layers (21) and (22), and has a donut disk-like shape at the openings at both ends. It is configured by attaching and sealing the end plate (15) by welding (w). The ceramic layers (21) and (22) are unsintered ceramic layers made of fibrous or powdered ceramics, and the first ceramics sandwiched between the first metal cylinder (11) and the second metal cylinder (12). In the layer (21), the interlayer bonding metal material (3) is dispersedly arranged. One end of the interlayer-bonded metal material (3) is in contact with the outer peripheral surface of the first metal cylinder (11), and the other end is in contact with the inner peripheral surface of the second metal cylinder (12).

上記カプセル状積層組付け体(A1)のセラミックス層(2)は粉末又は繊維状セラミックスを使用して形成される。図5は、上記カプセル状積層組付け体(A1)の形成に使用されるセラミックス繊維シート(2S)の例を示している。セラミックス繊維シート(2S)には、層間接合金属材(3)として金属線(3)、例えばステンレス鋼(ステンレス鋼は合金工具鋼等に比し低い熱伝導率を有する)の細径線等が分散配置されている。そのII-II断面を図6[1] [2] [3]に示す。同図[1]は金属線(3a)をセラミックス繊維シート(2S)に波状に刺し通して表裏両面に交互に露出させた例、同図[2]は短寸に切断した金属線(3b)をセラミックス繊維シート(2S)に刺し通してコ字状に折り曲げて取付けた例、同図[3]は短寸に切断した金属線(3c)をセラミックス繊維シート(2S)に刺し通して平坦に折り曲げてシート表面に伏着させた例である。金属線(3a)〜(3c)は、セラミックス繊維シート(2S)への取り付け(係着)ハンドリング性の点から、例えば線径:約0.05〜1mm程度の線材が好ましく使用される。   The ceramic layer (2) of the capsule-like laminated assembly (A1) is formed using powder or fibrous ceramics. FIG. 5 shows an example of the ceramic fiber sheet (2S) used for forming the capsule-shaped laminated assembly (A1). The ceramic fiber sheet (2S) has a metal wire (3) as an interlayer bonding metal material (3), for example, a thin wire of stainless steel (stainless steel has a lower thermal conductivity than alloy tool steel, etc.). Distributed. The II-II cross section is shown in Fig. 6 [1] [2] [3]. Figure [1] shows an example in which a metal wire (3a) is pierced into a ceramic fiber sheet (2S) and exposed alternately on the front and back surfaces. [2] is a metal wire (3b) cut short. Is inserted into the ceramic fiber sheet (2S) and bent into a U shape, and [3] in FIG. 3 is a flat cut by piercing the ceramic fiber sheet (2S) with the metal wire (3c) cut into short pieces. This is an example in which the sheet is bent and adhered to the sheet surface. For the metal wires (3a) to (3c), for example, a wire having a wire diameter of about 0.05 to 1 mm is preferably used from the viewpoint of handling (attachment) to the ceramic fiber sheet (2S).

図7は、図5のセラミックス繊維シート(2S)を金属円筒(1)(11,12)に巻き付ける様子を示している。セラミックス繊維シートを使用する場合は、シートの重ね枚数の増減により層厚を容易に調整することができるほか、層間接合金属材(3)を分散配置するハンドリング操作も粉末状セラミックスの場合に比べ極めて容易である。なお、層間接合金属材(3)をセラミックス層(2)に分散配置することに付随する熱遮断性能の低下は極く僅少である。層間接合金属材(3)として、例えば線径1mmの金属線材を使用する場合、セラミックス層(2)を層厚方向に貫通する伝導伝熱面積(線材の径方向断面積)は、π×1mm/4(≒0.8mm)であるから、仮にセラミックス層の面積1cm当りの金属線材の貫通本数を1本とする高密度の分散配置の場合でも、線材の貫通によるセラミックス層の面積減少率は約0.8%(=0.8mm/100 mm×100%)に過ぎず、従ってセラミックス層(2)の熱遮断層としての機能は十分に維持される。 FIG. 7 shows a state in which the ceramic fiber sheet (2S) of FIG. 5 is wound around the metal cylinder (1) (11, 12). When using ceramic fiber sheets, the layer thickness can be easily adjusted by increasing or decreasing the number of stacked sheets, and the handling operation to disperse and arrange the inter-layer joining metal material (3) is also extremely difficult compared to powder ceramics. Easy. In addition, the fall of the heat insulation performance accompanying the dispersion | distribution arrangement | positioning of the interlayer joining metal material (3) in a ceramic layer (2) is very slight. For example, when a metal wire having a wire diameter of 1 mm is used as the interlayer bonding metal material (3), the conduction heat transfer area (diameter cross-sectional area of the wire) penetrating the ceramic layer (2) in the layer thickness direction is π × 1 mm. Since it is 2/4 (≒ 0.8mm 2 ), even in the case of a high-density dispersed arrangement in which the number of penetrations of the metal wire per 1 cm 2 of the ceramic layer is one, the area reduction of the ceramic layer due to the penetration of the wire the rate is only about 0.8% (= 0.8mm 2/100 mm 2 × 100%), thus functions as a heat blocking layer of the ceramic layer (2) is sufficiently maintained.

上記カプセル状積層組付け体(A1)の熱間塑性加工は、熱間静水等方圧加圧加工(HIP)、又は熱間押出し加工等により行なわれる。カプセル状積層組付け体(A1)を熱間塑性加工、例えばHIP処理にかけると、金属円筒(11)(12)(13)は加熱・加圧下の塑性変形により、セラミックス層(21)(22)を挟圧しながら、相互に圧着されると共に、層間接合金属材(3)と金属円筒(11)及び(12)との接触面の接合(拡散接合)が生じる。金属の熱間塑性加工を行なう温度域では、セラミックス層(21)(22)の焼結反応や金属円筒との界面反応はなく、実質的に未焼結の繊維又は粉末の状態を保持して金属円筒の重合面の間に圧縮緻密化した層となる。熱間塑性加工の後、端板(15)(15)を機械加工により除去して図1に示した積層円筒体(10)を得る。 The hot plastic working of the capsule-like laminated assembly (A1) is performed by hot isostatic pressing (HIP) or hot extrusion. When the capsule-like laminated assembly (A1) is subjected to hot plastic working, for example, HIP treatment, the metal cylinders (11), (12), and (13) are deformed by plastic deformation under heat and pressure, and the ceramic layers (21) (22). ) Are pressed against each other, and bonding (diffusion bonding) of the contact surfaces between the interlayer bonded metal material (3) and the metal cylinders (11) and (12) occurs. In the temperature range where hot plastic working of metal is performed, there is no sintering reaction of the ceramic layers (21) and (22) and no interface reaction with the metal cylinder, and the state of substantially unsintered fiber or powder is maintained. It becomes a compression-densified layer between the overlapping surfaces of the metal cylinder. After the hot plastic working, the end plates (15) and (15) are removed by machining to obtain the laminated cylindrical body (10 1 ) shown in FIG.

図1及び図4等では、層間接合金属材(3)を第1セラミックス層(21)のみに介在させた例を示しているが、所望によりその外側のセラミックス層(22)にも、層間接合金属材(3)を分散配置したセラミックスシート(2S)(図5,図6)が使用され、それにより第1金属円筒(11)とその内側の金属円筒(12)(13)との結合構造による補強効果をより高めることができる。   FIGS. 1 and 4 show examples in which the interlayer bonding metal material (3) is interposed only in the first ceramic layer (21). However, if desired, the interlayer bonding metal material (3) may also be bonded to the outer ceramic layer (22). The ceramic sheet (2S) (FIGS. 5 and 6) in which the metal material (3) is dispersedly arranged is used, thereby connecting the first metal cylinder (11) and the inner metal cylinders (12) and (13). The reinforcement effect by can be further enhanced.

[第2の積層円筒体(10)]
第2の積層円筒体(10)は、少なくとも2つの金属円筒と金属円筒同士の重合面を遮断するセラミックス層とからなる。図8は、第2の積層円筒体(10)の断面構造の例を示し、図9はそのIII-III矢視断面を示している。この積層円筒体(10)は、3つの金属円筒(1)(11,12,13)と各金属円筒(1)同士の重合界面に介在する2つのセラミックス層(2)(21,22)とからなる積層構造を有すると共に、最内層の金属円筒(第1金属円筒)(11)とその内側の金属円筒(12)(13)とが、セラミックス層(2)(21,22)を貫通する溶接(5)により結合されている。
[Second laminated cylindrical body (10 2 )]
The second laminated cylindrical body (10 2 ) includes at least two metal cylinders and a ceramic layer that blocks a polymerization surface between the metal cylinders. FIG. 8 shows an example of a cross-sectional structure of the second laminated cylindrical body (10 2 ), and FIG. 9 shows a cross section taken along the line III-III. The laminated cylindrical body (10 2 ) is composed of three ceramic cylinders (2) (21, 22) interposed between the three metal cylinders (1) (11, 12, 13) and the polymerization interface between the metal cylinders (1). The innermost metal cylinder (first metal cylinder) (11) and the inner metal cylinders (12) (13) penetrate the ceramic layers (2) (21, 22). Connected by welding (5).

図11は、図8の積層円筒体(10)を、熱間塑性加工成形体として形成するためのカプセル状積層組付け体(A2)を示している。このカプセル状積層組付け体(A2)は、前記積層円筒体(10)を製作するためのカプセル状積層組付け体(A1)と同じように、セラミックス層(21)(22)を介して金属円筒(11)(12)(13)を同心円状に重合したうえ、両端の開口部にドーナツ盤状の端板(15)をあてがって溶接(w)で接合封止することにより形成される。ただし、この場合のセラミックス層(2)は層間接合金属材(3)(図4)を介在させる必要はない。セラミックス層(21)(22)として、セラミックス繊維シート(2S)を使用する場合は、図7のように金属円筒(1)に巻き付け装着することができ、カプセル状積層組付け体の形成操作が容易である。 FIG. 11 shows a capsule-like laminated assembly (A2) for forming the laminated cylindrical body (10 2 ) of FIG. 8 as a hot plastic working compact. This capsule-like laminated assembly (A2) is interposed via ceramic layers (21) and (22) in the same manner as the capsule-like laminated assembly (A1) for producing the laminated cylindrical body (10 1 ). The metal cylinders (11), (12), and (13) are polymerized concentrically, and the doughnut-shaped end plates (15) are attached to the openings at both ends, and then joined and sealed by welding (w). . However, the ceramic layer (2) in this case is not required to interpose the interlayer bonding metal material (3) (FIG. 4). When the ceramic fiber sheet (2S) is used as the ceramic layer (21) (22), it can be wound around the metal cylinder (1) as shown in FIG. Easy.

上記カプセル状積層組付け体(A)の熱間塑性加工を、熱間塑性加工(例えばHIP処理)にかけると、金属円筒(11)(12)(13)は加熱・加圧下の塑性変形により、セラミックス層(21)(22)を挟圧しながら、相互に圧着されて緊密な積層成形体が形成される。金属の熱間塑性加工を行なう温度域ではセラミックス層(21)(22)の焼結反応や金属円筒との界面反応はなく、実質的に未焼結の繊維又は粉末の状態を保持して金属円筒の重合面の間に圧縮緻密化した層が形成される。 When the hot plastic working (for example, HIP treatment) of the capsule-shaped laminated assembly (A 2 ) is subjected to hot plastic working (for example, HIP treatment), the metal cylinders (11), (12) and (13) are plastically deformed under heating and pressure. As a result, the ceramic layers (21) and (22) are clamped to form a tight laminated molded body. There is no sintering reaction of the ceramic layers (21) and (22) and no interfacial reaction with the metal cylinder in the temperature range in which the metal is subjected to hot plastic working. A compression-densified layer is formed between the overlapping surfaces of the cylinder.

熱間塑性加工の後、端板(15)(15)を機械加工により除去して積層円筒体を取り出した後、図10に示すように、その積層円筒体(10’)の外側から径方向に指向する溶接施工用の小孔(4)を分散穿設する。小孔(4)の孔径は、例えば約5〜10mmであり、最内層の第1金属円筒(11)に達する深さに形成される。小孔(4)の分散密度は、孔径の大きさに応じて適宜設定すればよい。小孔(4)の溶接は、溶接材として金属円筒(1)と同種又は近似のものを使用し、肉盛溶接(例えば粉体プラズマ溶接,MIG溶接等)により行えばよく、各小孔(4)に溶接(5)を形成して図8の積層円筒体(10)を得る。 After the hot plastic working, the end plates (15) and (15) are removed by machining to take out the laminated cylindrical body. Then, as shown in FIG. 10, the diameter is measured from the outside of the laminated cylindrical body (10 2 ′). Small holes (4) for welding that are oriented in the direction are distributed and drilled. The hole diameter of the small hole (4) is, for example, about 5 to 10 mm, and is formed to a depth that reaches the innermost first metal cylinder (11). What is necessary is just to set suitably the dispersion density of a small hole (4) according to the magnitude | size of a hole diameter. The small hole (4) may be welded by using the same or similar material as the metal cylinder (1) as a welding material, and by overlay welding (eg, powder plasma welding, MIG welding, etc.). A weld (5) is formed on 4) to obtain the laminated cylindrical body (10 2 ) of FIG.

なお、小孔(4)の形成とその肉盛溶接(5)の施工は、必ずしも熱間塑性加工の後である必要はなく、図11のカプセル状積層組付け体(A)に、その外周面側から小孔(4)(図示せず)を分散穿設して溶接(5)を施工したうえ、熱間塑性加工するようにしてもよい。この場合は、熱間塑性加工成形体として、図8に示す積層円筒体(10)が得られ、従って熱間塑性加工後の小孔(4)の形成及び溶接(5)の施工は不要となる。 The formation of the small hole (4) and the construction of the overlay welding (5) do not necessarily have to be performed after the hot plastic working, and the capsule-like laminated assembly (A 2 ) in FIG. Small holes (4) (not shown) may be dispersedly drilled from the outer peripheral surface side, weld (5) may be applied, and hot plastic working may be performed. In this case, the laminated cylindrical body (10 2 ) shown in FIG. 8 is obtained as the hot plastic working formed body, and therefore the formation of the small hole (4) and the welding (5) after the hot plastic working are unnecessary. It becomes.

上記第1の積層円筒体(10)及び第2の積層円筒体(10)を構成する金属円筒(1)(11,12,13)、セラミックス層(2)(21,22)等の材種は、積層円筒体の具体的用途・使用環境条件等に応じて適宜選択される。
ダイカストマシン用プランジャースリーブを例に挙げれば次のとおりである。第1金属円筒(11)(金属溶湯の接触面およびプランジャーチップの摺動面となる)は、金属溶湯に対する耐腐食性、プランジャーチップの摺動性および摺動磨耗抵抗性等を有するものであれば材種を問わないが、従来プランジャースリーブ材料として使用されているSKD61(C:0.32-0.42%,Si:0.8-1.2%,Mn:0.5%以下,Cr:4.5-5.5%,Mo:1.0-1.5%,V:0.8-1.2%)に代表される合金工具鋼(JIS-G4404)が好適である。第1金属円筒(11)の外側の金属円筒(12,13)は、プランジャースリーブに必要な機械強度が得られるものであればよく、SKD61等の合金工具鋼等のほかに、S45C等の機械構造用炭素鋼(JIS-G4051)、SS400等の一般構造用鋼(JIS-G3101)等が適用される。
Metal cylinders (1) (11, 12, 13), ceramic layers (2) (21, 22), etc. constituting the first laminated cylinder (10 1 ) and second laminated cylinder (10 2 ) The material type is appropriately selected according to the specific application, usage environment conditions, etc. of the laminated cylindrical body.
An example of a plunger sleeve for a die casting machine is as follows. The first metal cylinder (11) (which becomes the contact surface of the molten metal and the sliding surface of the plunger tip) has corrosion resistance to the molten metal, the sliding property of the plunger tip, the sliding wear resistance, etc. If so, the material type is not limited, but SKD61 (C: 0.32-0.42%, Si: 0.8-1.2%, Mn: 0.5% or less, Cr: 4.5-5.5%, Mo, which is conventionally used as a plunger sleeve material : Alloy tool steel (JIS-G4404) typified by 1.0-1.5%, V: 0.8-1.2%) is suitable. The metal cylinders (12, 13) outside the first metal cylinder (11) are only required to have the mechanical strength necessary for the plunger sleeve. In addition to alloy tool steel such as SKD61, S45C or the like Carbon steel for machine structure (JIS-G4051), general structural steel such as SS400 (JIS-G3101), etc. are applied.

金属円筒(1)同士の重合面間に介在するセラミックス層(2)は、酸化物系(AlO,SiO, AlO-SiO,ZrO等),窒化物系(SiN等),炭化物系(SiC等)等、その材種は制限されない。セラミックス層(2)を複数層とする場合の各層は同種又は異種の材種が適宜使用される。繊維シートを使用する場合の好適なシート材の例として、AlO-SiOセラミックス繊維シートが挙げられる。 The ceramic layer (2) interposed between the polymerized surfaces of the metal cylinders (1) is composed of oxide (Al 2 O 3 , SiO 2 , Al 2 O 3 —SiO 2 , ZrO 2 etc.), nitride (Si 3 N 4, etc.), carbide (SiC, etc.) or the like, its grade is not limited. When the ceramic layer (2) has a plurality of layers, the same kind or different kinds of materials are appropriately used for each layer. An example of a suitable sheet material when using a fiber sheet is an Al 2 O 3 —SiO 2 ceramic fiber sheet.

金属円筒(1)及びセラミックス層(2)の積層数や各層の層厚は、積層円筒体のサイズ及び用途・具体的使用条件等に応じて適宜設計される。ダイカストマシン用プランジャースリーブについて述べれば、金属溶湯と接触する第1金属円筒(11)の肉厚は、セラミックス層(21)による断熱保温効果をより高める点から約15mm以下であることが好ましく、より好ましくは10mm以下である。但し過度に薄くすると最内層として必要な強度の不足をきたすおそれがあるので、少なくとも約3mm程度の肉厚をもたせるのが好ましい。
セラミックス層(2)(21,22…)のそれぞれの層厚は、内筒体の積層構造の堅牢性が損なわれないように、約1mm以下であることが好ましく、より好ましくは0.2〜0.5mmである。このような極く薄い層であっても卓抜した断熱保温効果が得られる。セラミックス層(2)の層数は1〜4層程度で十分である。
The number of layers of the metal cylinder (1) and the ceramic layer (2) and the layer thickness of each layer are appropriately designed according to the size, application, specific use conditions, etc. of the stacked cylinder. As for the plunger sleeve for the die casting machine, the thickness of the first metal cylinder (11) in contact with the molten metal is preferably about 15 mm or less from the viewpoint of further enhancing the heat insulating effect by the ceramic layer (21). More preferably, it is 10 mm or less. However, if the thickness is excessively thin, there is a risk that the strength required for the innermost layer may be insufficient. Therefore, it is preferable to have a thickness of at least about 3 mm.
It is preferable that each layer thickness of ceramic layer (2) (21,22 ...) is about 1 mm or less so that the robustness of the laminated structure of an inner cylinder may not be impaired, More preferably, 0.2- 0.5 mm. Even with such an extremely thin layer, an excellent heat insulation and heat insulation effect can be obtained. About 1 to 4 layers are sufficient for the ceramic layer (2).

積層円筒体(10)(10)を形成する熱間塑性加工条件は金属円筒の材種等により異なるが、前記プランジャースリーブとしての積層円筒体をHIPで成形する場合、温度:約300〜1000℃、加圧力:約50〜200MPaの条件で効率よく達成することができる。得られた積層円筒体(10)(10)に給湯口(71)の形成、その他必要な機械加工が施され、更に口金部材(72)等の部品を装着されて製品プランジャースリーブに仕上げられる。 The hot plastic working conditions for forming the laminated cylindrical body (10 1 ) (10 2 ) vary depending on the material type of the metal cylinder, but when the laminated cylindrical body as the plunger sleeve is molded by HIP, the temperature: about 300 It can be efficiently achieved under the conditions of ˜1000 ° C. and applied pressure: about 50 to 200 MPa. The resulting laminated cylindrical body (10 1 ) (10 2 ) is subjected to formation of a hot water inlet (71) and other necessary machining, and parts such as a base member (72) are further attached to the product plunger sleeve. Finished.

次に第3の積層円筒体(10)及び第4の積層円筒体(10)について説明する。
[第3の積層円筒体(10)]
第3の積層円筒体(10)は、金属外筒体(30)と、これに焼嵌めされた多層構造の内筒体(20)とからなる。図12に第3の積層円筒体(10)の例を示す。図13はそのB部を拡大して示し、図14はそのIV-IV矢視断面を示している。
内筒体(20)は、前記第1の積層円筒体(10)と同じ積層構造を有する熱間塑性加工成形体である。図示の内筒体(20)は、3つの金属円筒(1)(11,12,13)と、その金属円筒(1)同士の重合面の接触を遮断する2つのセラミックス層(2)(21,22)とが同心円状に積層された層構造を有している。その最内層の第1金属円筒(11)とこれに隣接する第2金属円筒(12)との間のセラミックス層(21)には、前記第1の積層円筒体(10)と同じように、層間結合金属材(3)が分散配置され、セラミックス層(21)を層厚方向に貫通して第1金属円筒(11)の外周面及び第2金属円筒(12)に当接し、その層間結合金属材(3)を介して第1金属円筒(11)と第2金属円筒(12)とが相互に接合(拡散接合)されている。
Next, the third laminated cylinder (10 3 ) and the fourth laminated cylinder (10 4 ) will be described.
[Third laminated cylinder (10 3 )]
The third laminated cylindrical body (10 3 ) includes a metal outer cylindrical body (30) and a multilayered inner cylindrical body (20 1 ) that is shrink-fitted thereto. FIG. 12 shows an example of the third laminated cylindrical body (10 3 ). FIG. 13 shows an enlarged view of the portion B, and FIG. 14 shows a section taken along the arrow IV-IV.
The inner cylindrical body (20 1 ) is a hot plastic working formed body having the same laminated structure as the first laminated cylindrical body (10 1 ). The illustrated inner cylinder (20 1 ) includes three metal cylinders (1) (11, 12, 13) and two ceramic layers (2) (2) that block contact between the metal cylinders (1). 21 and 22) have a layer structure in which concentric layers are laminated. The ceramic layer (21) between the innermost first metal cylinder (11) and the second metal cylinder (12) adjacent to the first metal cylinder (11) is the same as the first laminated cylinder (10 1 ). The inter-layer bonding metal material (3) is dispersedly arranged, penetrates the ceramic layer (21) in the layer thickness direction, and comes into contact with the outer peripheral surface of the first metal cylinder (11) and the second metal cylinder (12). The first metal cylinder (11) and the second metal cylinder (12) are bonded to each other (diffusion bonding) via the bonding metal material (3).

図16は、第3の積層円筒体(10)の内筒体(20)を、熱間塑性加工成形体として形成するためのカプセル状積層組付け体(A3)の例を示している。カプセル状積層組付け体(A3)の組立て要領は、前記第1の積層円筒体(10)を形成するカプセル状積層組付け体(A1)[図4]のそれと同じであり、セラミックス層(21)(22)を介して金属円筒(11)(12)(13)を同心円状に重合したうえ、両端の開口部にドーナツ盤状の端板(15)をあてがって溶接(w)で接合封止することにより組立てられる。積層組付け体(A3)の第1金属円筒(11)と第2金属円筒(12)に挟まれたセラミックス層(21)には層間結合金属材(3)が分散配置されており、該セラミックス層(21)として、図5,図6に示したセラミックス繊維シート(2S)を適用すれば、図7のように金属円筒(1)の胴部周面に巻き回すことにより積層組付け体(A3)の組み立てを効率化できることも、前記第1の積層円筒体(101)のカプセル状積層組付け体(A1)[図4]のそれと同じである。 FIG. 16 shows an example of a capsule-like laminated assembly (A3) for forming the inner cylindrical body (20 1 ) of the third laminated cylindrical body (10 3 ) as a hot plastic working molded body. . The procedure for assembling the capsule laminated assembly (A3) is the same as that of the capsule laminated assembly (A1) [FIG. 4] forming the first laminated cylindrical body (10 1 ). 21) Metal cylinders (11), (12) and (13) are polymerized concentrically through 22 and (22), and a doughnut-shaped end plate (15) is applied to the openings at both ends and joined by welding (w). It is assembled by sealing. The ceramic layer (21) sandwiched between the first metal cylinder (11) and the second metal cylinder (12) of the laminated assembly (A3) has an interlaminar bonded metal material (3) dispersed therein, and the ceramics If the ceramic fiber sheet (2S) shown in FIGS. 5 and 6 is applied as the layer (21), the laminated assembly (FIG. 7) is wound around the body peripheral surface of the metal cylinder (1) as shown in FIG. The efficiency of the assembly of A3) is also the same as that of the capsule-like laminated assembly (A1) [FIG. 4] of the first laminated cylindrical body (101).

上記カプセル状積層組付け体(A3)を熱間静水等方加圧加工(HIP)等の熱間塑性加工に付せば、金属円筒(11)(12)(13)は加熱・加圧下の塑性変形により、セラミックス層(21)(22)を挟圧しながら相互に圧着されると共に、層間接合金属材(31)と金属円筒(11)及び(12)との接触面の接合(拡散接合)が生じる。金属の熱間塑性加工を行なう温度域では、セラミックス層(21)(22)の焼結反応や金属円筒との界面反応はなく、実質的に未焼結の繊維又は粉末の状態を保持して金属円筒の重合面の間に圧縮緻密化した層となる。熱間塑性加工の後、端板(15)(15)を機械加工により除去して内筒体(20)を得る。ついで、該内筒体(20)を、図15のように、別途用意した金属外筒体(30)の中空孔に焼嵌めにより嵌装固定することにより、第3の積層円筒体(40)[図12]に仕上げられる。 If the capsule-like laminated assembly (A3) is subjected to hot plastic working such as hot isostatic pressing (HIP), the metal cylinders (11), (12) and (13) are heated and pressurized. By the plastic deformation, the ceramic layers (21) and (22) are pressed against each other while being sandwiched, and the contact surfaces between the interlayer bonded metal material (31) and the metal cylinders (11) and (12) are bonded (diffusion bonding). Occurs. In the temperature range where hot plastic working of metal is performed, there is no sintering reaction of the ceramic layers (21) and (22) and no interface reaction with the metal cylinder, and the state of substantially unsintered fiber or powder is maintained. It becomes a compression-densified layer between the overlapping surfaces of the metal cylinder. After the hot plastic working, the end plates (15) and (15) are removed by machining to obtain the inner cylinder (20 1 ). Next, as shown in FIG. 15, the inner cylindrical body (20 1 ) is fitted and fixed in a hollow hole of a separately prepared metal outer cylindrical body (30) by shrink fitting, so that a third laminated cylindrical body (40 1 ) Finished in [Fig. 12].

図12〜図16では、層間接合金属材(3)を第1セラミックス層(21)のみに介在させているが、所望によりその外側のセラミックス層(22)にも、層間接合金属材(3)を分散配置したセラミックスシート(2S)(図5,図6)を使用すれば、第1金属円筒(11)とその内側の金属円筒(12)(13)との結合構造による補強効果をより高めることができる。   In FIGS. 12 to 16, the interlayer bonding metal material (3) is interposed only in the first ceramic layer (21), but if desired, the interlayer bonding metal material (3) may also be disposed on the outer ceramic layer (22). If the ceramic sheet (2S) (FIGS. 5 and 6) in which particles are dispersed is used, the reinforcing effect by the coupling structure of the first metal cylinder (11) and the inner metal cylinders (12) and (13) is further enhanced. be able to.

次に第4の積層円筒体(10)について説明する。
[第4の積層円筒体(10)]
第4の積層円筒体(10)は、金属外筒体(30)と、これに焼嵌めされた多層構造の内筒体(20)とからなる。図17は第3の積層円筒体(40)の例であり、そのV-V矢視断面を図18に示す。
この内筒体(20)は、前記第2の積層円筒体(10)と同じ積層構造を有する熱間塑性加工成形体である。図示の内筒体(20)は、3つの金属円筒(1)(11,12,13)と、金属円筒(11,12,13)同士の重合面の接触を遮断する2つのセラミックス層(2)(21,22)とが同心円状に積層された層構造を有すると共に、最内層の金属円筒(第1金属円筒)(11)とその内側の金属円筒(12)(13)とが、セラミックス層(21,22)を貫通する溶接(5)により結合されている。
Next, the fourth laminated cylindrical body (10 4 ) will be described.
[Fourth laminated cylinder (10 4 )]
The fourth laminated cylindrical body (10 4 ) includes a metal outer cylindrical body (30) and a multilayered inner cylindrical body (20 2 ) shrink-fitted thereto. FIG. 17 is an example of the third laminated cylindrical body (40 2 ), and a cross section taken along the arrow VV is shown in FIG.
The inner cylindrical body (20 2 ) is a hot plastic working molded body having the same laminated structure as the second laminated cylindrical body (10 2 ). The illustrated inner cylinder (20 2 ) is composed of three ceramic cylinders (1) (11, 12, 13) and two ceramic layers that block contact between the polymer cylinders (11, 12, 13). 2) (21, 22) has a layer structure in which concentric layers are laminated, and an innermost metal cylinder (first metal cylinder) (11) and inner metal cylinders (12), (13), Bonded by welding (5) penetrating the ceramic layers (21, 22).

図21は、第4の積層円筒体(10)の内筒体(20)を熱間塑性加工成形体として形成するためのカプセル状積層組付け体(A4)を示している。このカプセル状積層組付け体(A4)は、前記第2の積層円筒体(10)を製作するためのカプセル状積層組付け体(A2)[図11]のそれと同じであり、セラミックス層(21)(22)を介して金属円筒(11)(12)(13)を同心円状に重合し、両端の開口部にドーナツ盤状の端板(15)をあてがい溶接(w)で接合封止することにより形成される。セラミックス層(21)(22)としてセラミックス繊維シート(2S)を使用する場合は、図7のように金属円筒(1)に巻き付け装着することができ、カプセル状積層組付け体の形成操作が容易である。この場合のセラミックス層(2)は層間接合金属材(3)(図4)は不要である。 FIG. 21 shows a capsule-like laminated assembly (A4) for forming the inner cylindrical body (20 2 ) of the fourth laminated cylindrical body (10 4 ) as a hot plastic working formed body. This capsule-like laminated assembly (A4) is the same as that of the capsule-like laminated assembly (A2) [FIG. 11] for manufacturing the second laminated cylindrical body (10 2 ). 21) Metal cylinders (11), (12), and (13) are polymerized concentrically via 22 and (22), and a donut disk-like end plate (15) is attached to both openings by welding and sealing (w) It is formed by doing. When the ceramic fiber sheet (2S) is used as the ceramic layers (21) and (22), it can be wound and mounted on the metal cylinder (1) as shown in FIG. It is. In this case, the ceramic layer (2) does not require the interlayer bonding metal material (3) (FIG. 4).

上記カプセル状積層組付け体(A4)を、HIP等の熱間塑性加工にかけると、金属円筒(11)(12)(13)は加熱・加圧下の塑性変形により、セラミックス層(21)(22)を挟圧しながら、相互に圧着されて緊密な積層成形体が形成される。金属の熱間塑性加工を行なう温度域ではセラミックス層(21)(22)の焼結反応や金属円筒との界面反応はなく、実質的に未焼結の繊維又は粉末の状態を保持して金属円筒の重合面の間に圧縮緻密化した層が形成される。   When the capsule-like laminated assembly (A4) is subjected to hot plastic processing such as HIP, the metal cylinders (11), (12), and (13) are deformed by plastic deformation under heating and pressure, and the ceramic layer (21) ( While sandwiching 22), they are pressure-bonded to each other to form a close laminated molded body. There is no sintering reaction of the ceramic layers (21) and (22) and no interfacial reaction with the metal cylinder in the temperature range in which the metal is subjected to hot plastic working, and the metal is kept in a substantially unsintered fiber or powder state. A compression-densified layer is formed between the overlapping surfaces of the cylinder.

熱間塑性加工の後、端板(15)(15)を機械加工により除去して積層円筒体を取り出したうえ、前記第2の積層円筒体(10)[図8]を形成する場合と同じように、溶接施工用の小孔(4)を分散穿設し、図20に示す積層円筒体(20’)を得る。小孔(4)は最内層の第1金属円筒(11)に達する深さに形成されている。各小孔(4)内に、常法に従って肉盛溶接を施工して内筒体(20)を得る。得られた内筒体(20)を、図19のように、別途用意した金属外筒体(30)の中空孔に焼嵌め固定することにより、第4の積層円筒体(10)[図17]を得る。 After hot plastic working, the end plates (15) and (15) are removed by machining to take out the laminated cylindrical body, and then the second laminated cylindrical body (10 2 ) [FIG. 8] is formed. Similarly, small holes (4) for welding are distributed and drilled to obtain a laminated cylindrical body (20 2 ′) shown in FIG. The small hole (4) is formed to a depth reaching the innermost first metal cylinder (11). In each small hole (4), overlay welding is performed according to a conventional method to obtain an inner cylinder (20 2 ). The obtained inner cylinder (20 2 ) is shrink-fitted and fixed in a hollow hole of a separately prepared metal outer cylinder (30) as shown in FIG. 19, so that the fourth laminated cylinder (10 2 ) [ FIG. 17] is obtained.

なお、内筒体(20)の小孔(4)の形成とその肉盛溶接(5)の施工は、必ずしも熱間塑性加工の後である必要はなく、図21のカプセル状積層組付け体(A4)に、その外周面側から小孔(4)(図示せず)を分散穿設し溶接(5)(図示せず)を施工したうえ、熱間塑性加工するようにしてもよい。この場合は、熱間塑性加工成形体として、図19に示す内筒体(20)が得られる。 The formation of the small hole (4) of the inner cylinder (20 2 ) and the build-up welding (5) do not necessarily have to be performed after the hot plastic working, and the capsule-like laminated assembly shown in FIG. Small holes (4) (not shown) may be formed in the body (A4) from the outer peripheral surface side, and welding (5) (not shown) may be applied, followed by hot plastic working. . In this case, an inner cylindrical body (20 2 ) shown in FIG. 19 is obtained as a hot plastic working formed body.

第3及び第4の積層円筒体(10)(10)のそれぞれの内筒体(20)(20)を、第1の積層円筒体(10)[図1]及び第2の積層円筒体(10)[図8]と対比すると、第1及び第2の積層円筒体(10)(10)ではそれ自体で構造部材として必要な強度が得られるように、第1金属円筒(11)を包囲する第2金属円筒(12)(13)を比較的厚肉に設計することを要するのに対し、第3及び第4の積層円筒体(40)及び積層円筒体(40)における内筒体(20)(20)は、これを包囲する金属外筒体(30)により補強される。このため、内筒体(20)(20)における第1金属円筒(11)を囲む外側の金属円筒(12,13)は、第1及び第2の積層円筒体(10)(10)の金属円筒(12,13)に比し、比較的薄肉に設計することができる。従ってそのカプセル状積層組付け体(A3)(A4)[図16,図21]のサイズをそれだけ小さくすることができ、このことは熱間塑性加工の施工上の制約(例えばHIP装置の規模・容量の制約等)を緩和・回避するのに有効である。 Respective inner cylinders (20 1 ) (20 2 ) of the third and fourth laminated cylindrical bodies (10 3 ) (10 4 ) are replaced with the first laminated cylindrical bodies (10 1 ) [FIG. 1] and second In contrast to the laminated cylindrical body (10 2 ) [FIG. 8], the first and second laminated cylindrical bodies (10 1 ) (10 2 ) While the second metal cylinder (12) (13) surrounding the one metal cylinder (11) needs to be designed to be relatively thick, the third and fourth laminated cylinders (40 1 ) and the laminated cylinder The inner cylinder (20 1 ) (20 2 ) in the body (40 2 ) is reinforced by the metal outer cylinder (30) surrounding the inner cylinder (20 1 ) (20 2 ). For this reason, the outer metal cylinders (12, 13) surrounding the first metal cylinder (11) in the inner cylinders (20 1 ) (20 2 ) are the first and second stacked cylinders (10 1 ) (10 Compared with the metal cylinder (12, 13) of 2 ), it can be designed to be relatively thin. Accordingly, the size of the capsule-like laminated assembly (A3) (A4) [FIGS. 16 and 21] can be reduced accordingly. This is because of restrictions in hot plastic working (for example, the scale of the HIP device) This is effective to alleviate or avoid capacity constraints.

上記第3及び第4の積層円筒体(10)(10)のそれぞれの内筒体(20)(20)を構成する金属円筒(1)、セラミックス層(2)の積層数や各層の層厚は、積層円筒体のサイズ及び用途・具体的使用条件等に応じて適宜設計される。ダイカストマシン用プランジャースリーブについて述べれば、内筒体(20)(20)は、前記第1及び第2の積層円筒体(10)(10)と同じように、第1金属円筒(11)は、金属溶湯に対する耐腐食性、プランジャーチップの摺動性および摺動磨耗抵抗性等の点から、SKD61に代表される合金工具鋼(JIS-G4404)が好適である。金属円筒(12,13)は、SKD61等の合金工具鋼等のほかに、S45C等の機械構造用炭素鋼(JIS-G4051)、SS400等の一般構造用鋼(JIS-G3101)等であってよい。金属溶湯と接触する第1金属円筒(11)の肉厚は、セラミックス層(21)による断熱保温効果をより高めるために、好ましくは約15mm以下、より好ましくは10mm以下であり、また最内層として必要な強度の不足を回避するために、少なくとも約3mm程度の肉厚であるのが好ましい。セラミックス層(21,22…)についても前記第1及び第2の積層円筒体(10)(10)のそれと同様であり、内筒体の積層構造の堅牢性が損なわれないように、約1mm以下であることが好ましく、より好ましくは0.2〜0.5mmであり、その層数は1〜4層程度であってよい。 The number of layers of the metal cylinder (1) and the ceramic layer (2) constituting the inner cylinders (20 1 ) (20 2 ) of the third and fourth stacked cylinders (10 3 ) (10 4 ) The layer thickness of each layer is appropriately designed according to the size and application / specific use conditions of the laminated cylindrical body. The plunger sleeve for the die casting machine will be described. The inner cylindrical body (20 1 ) (20 2 ) is the same as the first and second laminated cylindrical bodies (10 1 ) (10 2 ) as the first metal cylinder. (11) is preferably an alloy tool steel represented by SKD61 (JIS-G4404) from the viewpoints of corrosion resistance against molten metal, plunger tip slidability and sliding wear resistance. The metal cylinders (12, 13) are not only alloy tool steels such as SKD61, but also carbon steels for mechanical structures such as S45C (JIS-G4051), general structural steels such as SS400 (JIS-G3101), etc. Good. The thickness of the first metal cylinder (11) that is in contact with the molten metal is preferably about 15 mm or less, more preferably 10 mm or less, in order to further enhance the heat insulation and thermal insulation effect by the ceramic layer (21). In order to avoid a lack of necessary strength, it is preferable that the thickness is at least about 3 mm. The ceramic layers (21, 22...) Are the same as those of the first and second laminated cylindrical bodies (10 1 ) (10 2 ), and the robustness of the laminated structure of the inner cylinder is not impaired. The thickness is preferably about 1 mm or less, more preferably 0.2 to 0.5 mm, and the number of layers may be about 1 to 4 layers.

また上記内筒体(20)(20)を焼嵌め固定するための金属外筒体(30)は、従来のスリーブ材であるSKD61等の合金工具鋼のほか、S45C等の機械構造用炭素鋼(JIS-G4051)、SS400等の一般構造用鋼(JIS-G3101)等であってよい。金属外筒体(30)と内筒体(20)又は(20)との焼嵌め固定は、例えば300〜500℃の温度域で行われる。
金属外筒体(30)に内筒体(20)又は(20)を焼嵌めにより一体化して形成された第3の積層円筒体(10),第4の積層円筒体(10)は、機械加工により所要形状に成形され、更に口金(72)等の必要な部材を装着して製品プランジャースリーブに仕上げられる。
Further, the metal outer cylinder (30) for shrink-fitting and fixing the inner cylinders (20 1 ) (20 2 ) is used for machine tool structures such as S45C as well as alloy tool steel such as SKD61 which is a conventional sleeve material. Carbon steel (JIS-G4051), general structural steel (JIS-G3101) such as SS400 may be used. The shrink-fitting and fixing between the metal outer cylinder (30) and the inner cylinder (20 1 ) or (20 2 ) is performed in a temperature range of 300 to 500 ° C., for example.
A third laminated cylindrical body (10 3 ), a fourth laminated cylindrical body (10 4 ) formed by integrating the inner cylindrical body (20 1 ) or (20 2 ) by shrink fitting to the metal outer cylindrical body (30). ) Is formed into a required shape by machining, and a product plunger sleeve is finished by attaching necessary members such as a die (72).

産業上の利用分野Industrial application fields

本発明の積層円筒体は、セラミックス層による卓抜した熱遮断性を有すると共に、セラミックス層を含む多層構造でありながら、内筒体の分割構造としたことによる補強効果として良好な耐熱変形性を兼備し、従ってこれらの特性を要求される用途、例えばダイカストマシンのプランジャースリーブとして適用される場合は、金属溶湯の温度降下とそれに起因する鋳造品質及び鋳造操業上の不具合が回避されると共に、温度低下を見込んだ高温給湯とそれに伴う熱エネルギコストの無駄が解消され、金属溶湯の温度管理が容易化され、またスリーブの損傷が軽減緩和により耐用寿命が改善される等、鋳造操業の効率化等に奏効するものである。   The laminated cylindrical body of the present invention has an excellent thermal barrier property due to the ceramic layer, and also has a good heat distortion resistance as a reinforcing effect due to the split structure of the inner cylindrical body while having a multilayer structure including the ceramic layer. Therefore, when it is applied as a plunger sleeve of a die casting machine, for example, where these characteristics are required, the temperature drop of the molten metal and the resulting casting quality and casting operation problems are avoided, and the temperature Efficient casting operations such as high-temperature hot water supply that is expected to decline and the waste of heat energy costs associated with it are eliminated, temperature management of the molten metal is facilitated, and the service life is improved by mitigating and reducing sleeve damage. It is effective.

本発明の第1の積層円筒体の積層構造を模式的に示す軸方向断面図である。It is an axial direction sectional view showing typically the lamination structure of the 1st lamination cylinder of the present invention. 図1のA部の拡大図である。It is an enlarged view of the A section of FIG. 図1のI-I矢視断面図である。It is the II sectional view taken on the line of FIG. 図1の積層円筒体を熱間塑性加工成形体として製作するためのカプセル状積層組付け体の例を示す軸方向断面図である。FIG. 2 is an axial cross-sectional view showing an example of a capsule-like laminated assembly for producing the laminated cylindrical body of FIG. 1 as a hot plastic working formed body. 図4のカプセル状積層組付け体の組立てに使用されるセラミックスシートの例を示す平面図である。It is a top view which shows the example of the ceramic sheet | seat used for the assembly of the capsule-shaped laminated assembly of FIG. 図5のII-II矢視断面図である。It is II-II arrow sectional drawing of FIG. 図4のカプセル状積層組付け体の組立てるためのセラミックスシートを金属円筒に巻き付ける状態を示す斜視説明図である。FIG. 5 is a perspective explanatory view showing a state in which a ceramic sheet for assembling the capsule-shaped laminated assembly of FIG. 4 is wound around a metal cylinder.

本発明の第2の積層円筒体の積層構造を模式的に示す軸方向断面図である。It is an axial direction sectional view showing typically the lamination structure of the 2nd lamination cylinder of the present invention. 図8のIII-III矢視断面図である。It is the III-III arrow sectional drawing of FIG. 図8の積層円筒体の溶接施工前の状態を示す軸方向断面図である。It is an axial sectional view showing a state before welding construction of the laminated cylindrical body of FIG. 図8の積層円筒体を熱間塑性加工成形体として製作するためのカプセル状積層組付け体の例を示す軸方向断面図である。It is an axial direction sectional view which shows the example of the capsule-shaped laminated assembly for manufacturing the laminated cylindrical body of FIG. 8 as a hot plastic-working molded object.

本発明の第3の積層円筒体の積層構造を模式的に示す軸方向断面図である。It is an axial direction sectional view showing typically the lamination structure of the 3rd lamination cylinder of the present invention. 図12のB部の拡大図である。It is an enlarged view of the B section of FIG. 図12のIV-IV矢視断面図である。It is IV-IV arrow sectional drawing of FIG. 図12の積層円筒体を形成する金属外筒体と内筒体との嵌装状態を示す軸方向断面説明図である。It is an axial direction cross-sectional explanatory drawing which shows the fitting state of the metal outer cylinder and inner cylinder which form the lamination | stacking cylindrical body of FIG. 図12の積層円筒体の内筒体を熱間塑性加工成形体として製作するためのカプセル状積層組付け体の例を示す軸方向断面図である。FIG. 13 is an axial cross-sectional view showing an example of a capsule-shaped laminated assembly for producing the inner cylindrical body of the laminated cylindrical body of FIG.

本発明の第4の積層円筒体の積層構造を模式的に示す軸方向断面図である。It is an axial direction sectional view showing typically the lamination structure of the 4th lamination cylinder of the present invention. 図17のV-V矢視断面図である。It is the VV arrow directional cross-sectional view of FIG. 図12の積層円筒体を形成する金属外筒体と内筒体との嵌装状態を示す軸方向断面説明図である。It is an axial direction cross-sectional explanatory drawing which shows the fitting state of the metal outer cylinder and inner cylinder which form the lamination | stacking cylindrical body of FIG. 図17の積層円筒体を構成に使用される内筒体の溶接施工前の状態を示す軸方向断面図である。FIG. 18 is an axial cross-sectional view showing a state before welding construction of an inner cylindrical body used for configuring the laminated cylindrical body of FIG. 17. 図17の積層円筒体の内筒体を熱間塑性加工成形体として製作するためのカプセル状積層組付け体の例を示す軸方向断面図である。FIG. 18 is an axial cross-sectional view showing an example of a capsule-like laminated assembly for producing the inner cylindrical body of the laminated cylindrical body of FIG.

横型ダイカストマシンのプランジャースリーブ配置構成を示す断面説明図である。It is a section explanatory view showing the arrangement arrangement of the plunger sleeve of the horizontal die casting machine. 堅型ダイカストマシンのプランジャースリーブ配置構成を示す断面説明図である。It is a section explanatory view showing the arrangement arrangement of the plunger sleeve of the rigid die casting machine.

符号の説明Explanation of symbols

1(11,12,13):金属円筒 2(21,22) :セラミックス層
2S:セラミックス繊維シート 3(3a,3b,3c):層間結合金属材
4:溶接用小孔 5:溶接
10(10,10,10,10):積層円筒体
20,20:内筒体
30:金属外筒体
1 (11,12,13): Metal cylinder 2 (21,22): Ceramic layer 2S: Ceramic fiber sheet 3 (3a, 3b, 3c): Interlayer bonded metal material
4: Small hole for welding 5: Welding 10 (10 1 , 10 2 , 10 3 , 10 4 ): Laminated cylindrical body
20 1 , 20 2 : Inner cylinder 30: Metal outer cylinder

15:端板
70:プランジャースリーブ 71:給湯口
72:口金 80:プランジャーチップ
91:ダイプレート 92:金型
93:キャビティ
A1,A2,A3,A4:カプセル状積層組付け体
M:金属溶湯
w:溶接
15: End plate 70: Plunger sleeve 71: Hot water inlet 72: Base 80: Plunger chip 91: Die plate 92: Mold 93: Cavity A1, A2, A3, A4: Capsule laminated assembly M: Molten metal w: Welding

Claims (9)

金属円筒(1)を、繊維状又は粉末状の未焼結セラミックス層(2)を挟んで同心円状に重ね合せ、少なくとも最内層の金属円筒(第1金属円筒)(11)とその外側の金属円筒(第2金属円筒)(12)とに挟まれたセラミックス層に、そのセラミックス層を貫通して第1金属円筒の外周面と第2金属円筒の内周面とに接触する層間連結金属材(3)が分散配置されているカプセル状積層組付け体を、熱間塑性加工に付して肉厚方向に圧縮すると共に層間連結金属材(3)と第1金属円筒(11)及び第2金属円筒(12)との接触部を拡散接合させてなる、第1金属円筒と第2金属円筒とが層間連結金属材を介して相互に結合された積層成形体であることを特徴とする断熱性・耐熱変形性に優れた積層円筒体。   The metal cylinder (1) is concentrically overlapped with the unsintered ceramic layer (2) in the form of fiber or powder, and at least the innermost metal cylinder (first metal cylinder) (11) and the outer metal An interlayer connection metal material that penetrates the ceramic layer and contacts the outer peripheral surface of the first metal cylinder and the inner peripheral surface of the second metal cylinder in the ceramic layer sandwiched between the cylinders (second metal cylinder) (12) The capsule-like laminated assembly in which (3) is dispersedly arranged is subjected to hot plastic working and compressed in the thickness direction, and the interlayer connecting metal material (3), the first metal cylinder (11), and the second A heat insulation characterized in that the first metal cylinder and the second metal cylinder are laminated and bonded to each other via an interlayer connecting metal material, which is formed by diffusion bonding a contact portion with the metal cylinder (12). Laminated cylinder with excellent heat resistance and heat distortion resistance. 金属円筒(1)を、繊維状又は粉末状の未焼結セラミックス層(2)を挟んで同心円状に重ね合せてなるカプセル状積層組付け体を熱間塑性加工により肉厚方向に圧縮して形成された積層成形体からなり、該積層成形体に分散形成された小孔を介して、最内層の金属円筒とその外側の金属円筒とが溶接(5)により結合されていることを特徴とする断熱性・耐熱変形性に優れた積層円筒体。   A capsule-shaped laminated assembly formed by concentrating metal cylinders (1) concentrically with a fibrous or powdery unsintered ceramic layer (2) in between is compressed in the thickness direction by hot plastic working. It is composed of a formed layered product, and the innermost metal cylinder and the outer metal cylinder are joined by welding (5) through small holes dispersedly formed in the layered product. Laminated cylindrical body with excellent heat insulation and heat distortion resistance. 金属外筒体(30)とその内側に焼嵌めにより固定された内筒体(20)とからなり、該内筒体は請求項1に記載の積層円筒体からなることを特徴とする断熱性・耐熱変形性に優れた積層円筒体。 A heat insulation characterized by comprising a metal outer cylinder (30) and an inner cylinder (20 1 ) fixed to the inside thereof by shrink fitting, the inner cylinder comprising the laminated cylinder according to claim 1. Laminated cylinder with excellent heat resistance and heat distortion resistance. 金属外筒体(30)とその内側に焼嵌めにより固定された内筒体(20)とからなり、該内筒体は請求項2に記載の積層円筒体からなることを特徴とする断熱性・耐熱変形性に優れた積層円筒体。 A heat insulation characterized by comprising a metal outer cylinder (30) and an inner cylinder (20 2 ) fixed to the inside thereof by shrink fitting, the inner cylinder comprising the laminated cylinder according to claim 2. Laminated cylinder with excellent heat resistance and heat distortion resistance. 最内層の金属円筒(第1金属円筒)は合金工具鋼からなり、該第1金属層を除く他の金属円筒は合金工具鋼又は炭素鋼からなる請求項1又は請求項2に記載の断熱性・耐熱変形性に優れた積層円筒体。   The heat insulating property according to claim 1 or 2, wherein the innermost metal cylinder (first metal cylinder) is made of an alloy tool steel, and the other metal cylinder excluding the first metal layer is made of an alloy tool steel or carbon steel. -A laminated cylindrical body with excellent heat distortion resistance. 内筒体の最内層の金属円筒(第1金属円筒)は合金工具鋼からなり、第1金属層を除く他の金属円筒、及び外筒体は合金工具鋼又は炭素鋼からなる請求項3又は請求項4に記載の断熱性・耐熱変形性に優れた積層円筒体。   The innermost metal cylinder (first metal cylinder) of the inner cylinder is made of alloy tool steel, and the other metal cylinders excluding the first metal layer and the outer cylinder are made of alloy tool steel or carbon steel. A laminated cylindrical body excellent in heat insulation and heat distortion resistance according to claim 4. セラミックス層(2)は、セラミックス繊維シートからなる請求項1ないし請求項6のいずれか1項に記載の断熱性・耐熱変形性に優れた積層円筒体。   The laminated cylindrical body excellent in heat insulation and heat distortion resistance according to any one of claims 1 to 6, wherein the ceramic layer (2) is made of a ceramic fiber sheet. カプセル状積層組付け体の熱間塑性加工は熱間静水等方圧加圧加工である請求項1ないし請求項7のいずれか1項に記載の断熱性・耐熱変形性に優れた積層円筒体。   The laminated cylindrical body excellent in heat insulation and heat distortion resistance according to any one of claims 1 to 7, wherein the hot plastic working of the capsule-like laminated assembly is hot isostatic pressing. . 請求項7又は請求項8に記載の積層円筒体からなるダイカストマシン用プランジャースリーブ。   A plunger sleeve for a die casting machine comprising the laminated cylindrical body according to claim 7 or 8.
JP2004013088A 2004-01-21 2004-01-21 Laminated cylindrical body with excellent heat insulation and heat distortion resistance and plunger sleeve for die casting machine Pending JP2005205666A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007152377A (en) * 2005-12-02 2007-06-21 Toshiba Mach Co Ltd Molten metal supply tube for aluminum die casting, and method for manufacturing the same
KR20190030764A (en) 2016-08-31 2019-03-22 히타치 긴조쿠 가부시키가이샤 Sleeve for die casting and manufacturing method thereof
CN110834444A (en) * 2019-11-26 2020-02-25 江苏大学 A kind of preparation method of interlayer toughened composite material

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007152377A (en) * 2005-12-02 2007-06-21 Toshiba Mach Co Ltd Molten metal supply tube for aluminum die casting, and method for manufacturing the same
KR20190030764A (en) 2016-08-31 2019-03-22 히타치 긴조쿠 가부시키가이샤 Sleeve for die casting and manufacturing method thereof
KR20210113449A (en) 2016-08-31 2021-09-15 히타치 긴조쿠 가부시키가이샤 Sleeve for die casting and method for producing same
CN113732263A (en) * 2016-08-31 2021-12-03 日立金属株式会社 Sleeve for die casting and method for manufacturing same
CN110834444A (en) * 2019-11-26 2020-02-25 江苏大学 A kind of preparation method of interlayer toughened composite material
CN110834444B (en) * 2019-11-26 2021-11-23 江苏大学 Preparation method of interlayer toughening composite material

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