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JP2005161797A - Manufacturing method and manufacturing apparatus for prepreg - Google Patents

Manufacturing method and manufacturing apparatus for prepreg Download PDF

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JP2005161797A
JP2005161797A JP2003407180A JP2003407180A JP2005161797A JP 2005161797 A JP2005161797 A JP 2005161797A JP 2003407180 A JP2003407180 A JP 2003407180A JP 2003407180 A JP2003407180 A JP 2003407180A JP 2005161797 A JP2005161797 A JP 2005161797A
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roll
reinforcing fiber
prepreg
fiber bundle
resin
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Moritomo Kozai
盛智 香西
Daisaku Akase
大策 赤瀬
Hiroyuki Takagishi
宏至 高岸
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Toray Industries Inc
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Toray Industries Inc
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a manufacturing method and a manufacturing apparatus for a prepreg suitable for fabricating a bundle of thin reinforcing fibers in particular into the prepreg. <P>SOLUTION: The present invention relates to a manufacturing method for the prepreg of impregnating the bundle of a plurality of running reinforcing fibers paralleled in one direction with a resin. The bundle of the reinforcing fibers is supplied to a resin impregnating portion, after the bundle is passed while the bundle is made to come into contact with a roll having a protrusion parallel to the axial direction on the surface in a direction perpendicular to the axial direction, keeping a ratio ¾Vr/Vf¾ of an absolute value of the roll velocity Vr in the circumferential direction to an absolute value of the transferring velocity Vf of the reinforcing fibers in the range of ¾Vr/Vf¾<1. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、強化繊維束から一方向性プリプレグを製造する製造方法および製造装置に関する。   The present invention relates to a manufacturing method and a manufacturing apparatus for manufacturing a unidirectional prepreg from a reinforcing fiber bundle.

よく知られているように、FRP(繊維強化プラスチック)の成形に一方向性プリプレグが用いられる。そのような一方向性プリプレグは、たとえば、複数本の、炭素繊維束等の強化繊維束を一方向に並行するように引き揃え、必要に応じて各強化繊維束を開繊、拡幅して強化繊維シートとした後、その強化繊維シートに、Bステージのエポキシ樹脂等のマトリクス樹脂を塗布した離型紙をその樹脂塗布面において重ね合わせ、離型紙上のマトリクス樹脂を強化繊維シートに転移、含浸することによって製造される。いわゆるホットメルト法と呼ばれる方法であるが、このとき樹脂を含浸する部分において強化繊維束の糸幅にバラツキがあると、得られる一方向性プリプレグにワレができたり、ワレができないまでも強化繊維の表面凹凸が大きくなったりする。その場合、当然、成形されるFRPは特性の不均一なものとなる。すなわち、強化繊維束の糸幅バラツキの有無は、一方向性プリプレグの特性、ひいてはFRPの特性を左右する。   As is well known, unidirectional prepregs are used for molding FRP (fiber reinforced plastic). Such a unidirectional prepreg, for example, aligns a plurality of reinforcing fiber bundles such as carbon fiber bundles in parallel in one direction, and opens and widens each reinforcing fiber bundle as necessary to strengthen it. After forming the fiber sheet, a release paper coated with a matrix resin such as a B-stage epoxy resin is superimposed on the reinforcing fiber sheet on the resin application surface, and the matrix resin on the release paper is transferred to and impregnated into the reinforcing fiber sheet. Manufactured by. This is a so-called hot melt method, but if there is variation in the yarn width of the reinforcing fiber bundle at the portion impregnated with the resin, the resulting unidirectional prepreg can be cracked or reinforced even if cracking is not possible. The surface unevenness of the surface becomes large. In that case, of course, the molded FRP has non-uniform characteristics. That is, the presence or absence of yarn width variation in the reinforcing fiber bundle affects the characteristics of the unidirectional prepreg, and thus the characteristics of the FRP.

さて、一般にプリプレグを作製する場合、強化繊維束はクリールに設置した強化繊維束ボビンから引き出され、ガイドロールや、強化繊維のピッチ間隔を揃えるコーム等を経て樹脂含浸部へと、あるいは開繊部を経て樹脂含浸部へと供給される(例えば、特許文献1参照)。その際、ガイドロール間のフリーゾーンやコームでは強化繊維束の張力変動や糸振り角度変動等により強化繊維束に反転が生じる場合がある。強化繊維束が反転すると反転個所では強化繊維束の糸幅が部分的に狭くなってしまう。特にテープ状に巻き取られているいわゆる無撚り扁平強化繊維の場合は、反転が生じた強化繊維束をそのまま含浸部に供給すると反転部分では強化繊維束が捻れた状態となり、元の糸幅の半分程度になることもあり、その結果、製造されるプリプレグが不良となる場合がある。また、樹脂含浸部の上流に強化繊維束の開繊装置を設置した場合においても、強化繊維束の反転部分は十分に開繊されず、上記と同様な不良が生じることは言うまでもない。   In general, when preparing a prepreg, a reinforcing fiber bundle is drawn from a reinforcing fiber bundle bobbin installed in a creel, passed through a guide roll, a comb that aligns the pitch interval of reinforcing fibers, etc., or into a resin-impregnated part, or a spread part. And supplied to the resin-impregnated portion (for example, see Patent Document 1). At that time, in the free zone or the comb between the guide rolls, the reinforcing fiber bundle may be reversed due to the tension fluctuation of the reinforcing fiber bundle or the fluctuation of the yarn swing angle. When the reinforcing fiber bundle is reversed, the yarn width of the reinforcing fiber bundle is partially narrowed at the reversed portion. In particular, in the case of a so-called untwisted flat reinforcing fiber wound up in a tape shape, if the reinforcing fiber bundle that has been inverted is supplied to the impregnation part as it is, the reinforcing fiber bundle is twisted at the inverted part, and the original yarn width is reduced. In some cases, the prepreg produced may be defective. Further, even when a reinforcing fiber bundle opening device is installed upstream of the resin-impregnated portion, it is needless to say that the reversal portion of the reinforcing fiber bundle is not sufficiently opened and the same defect as described above occurs.

繊維強化束の反転を防止する方法としては、階段状のクリールを設置し、コームへの水平方向の振り角を小さくする方法(例えば、特許文献1参照)や強化繊維束より低速で回転するローラーからなる反転防止装置を使用する方法などがある(例えば、特許文献2参照)。このうち、階段状のクリールを設置する方法においてはコーム部分での捻れ防止にはある程度効果はあるものの、強化繊維束の幅方向が、コームでは作製するプリプレグの幅方向に対して90°回転した方向であり、樹脂含浸部では作製するプリプレグの幅方向に対して水平方向であるためにコームから樹脂含浸部の間で強化繊維束が最低90°以上回転する必要があることから捻れが生じやすいにもかかわらず、ここで生じた捻れを解消することはできない。また、強化繊維束より低速で回転するローラーからなる反転防止装置を使用する方法においてもフィラメント数が12,000本以上で糸幅が6mm以上の強化繊維束に適用した場合にはある程度反転を防止する効果はあるものの、フィラメント数が3,000〜12,000本程度で糸幅が2〜6mm程度の細幅糸に適用した場合には糸幅が細いために反転部分がローラーを乗り越えてしまう場合があり、十分な効果が得られない。
特開2002−020033号公報(全頁) 特開平11−156852号公報(全頁)
As a method for preventing the reversal of the fiber reinforced bundle, a stepwise creel is installed to reduce the horizontal swing angle to the comb (for example, see Patent Document 1) or a roller that rotates at a lower speed than the reinforced fiber bundle. There is a method of using an anti-inversion device made of Of these, the method of installing the step-like creel has some effect in preventing twisting at the comb portion, but the width direction of the reinforcing fiber bundle is rotated by 90 ° with respect to the width direction of the prepreg to be produced by the comb. The resin-impregnated part is horizontal with respect to the width direction of the prepreg to be produced, and therefore the reinforcing fiber bundle needs to be rotated at least 90 ° between the comb and the resin-impregnated part, so that twisting is likely to occur. Nevertheless, the twist that occurs here cannot be resolved. Also, in the method of using a reversal prevention device comprising a roller that rotates at a lower speed than the reinforcing fiber bundle, when applied to a reinforcing fiber bundle having 12,000 filaments or more and a yarn width of 6 mm or more, reversal is prevented to some extent. However, when applied to a narrow yarn having a filament number of about 3,000 to 12,000 and a yarn width of about 2 to 6 mm, the reversal part gets over the roller because the yarn width is thin. In some cases, sufficient effects cannot be obtained.
JP 2002-020033 A (all pages) JP 11-156852 A (all pages)

本発明の目的は、従来の技術の上述した問題点を解決し、特に細幅の強化繊維束を使用してプリプレグに加工する場合に好適なプリプレグの製造方法および製造装置を提供することにある。   An object of the present invention is to solve the above-mentioned problems of the prior art, and to provide a prepreg manufacturing method and a manufacturing apparatus suitable particularly when processing a prepreg using a narrow reinforcing fiber bundle. .

上記課題を解決するために、本発明は一方向に平行するように引き揃えられ走行する複数本の強化繊維束に樹脂を含浸させるプリプレグの製造方法において、樹脂含浸部の上流側において軸方向に振動し、かつ軸方向に平行な突起を表面に有するロールを、ロールの周速度Vrと強化繊維の搬送速度Vfの絶対値の比|Vr/Vf|を、|Vr/Vf|<1の範囲内としつつ、強化繊維束を軸方向に対して直角方向に接触させながら通過させた後に樹脂含浸部に供給するプリプレグの製造方法である。   In order to solve the above-described problems, the present invention provides a method for manufacturing a prepreg in which a plurality of reinforcing fiber bundles that are aligned and run parallel to one direction are impregnated with a resin, in the axial direction on the upstream side of the resin-impregnated portion. The ratio of the absolute value of the peripheral speed Vr of the roll and the conveying speed Vf of the reinforcing fiber | Vr / Vf | is in the range of | Vr / Vf | <1. This is a method for producing a prepreg that is supplied to a resin-impregnated portion after passing through a reinforcing fiber bundle while being in contact with each other in a direction perpendicular to the axial direction.

さらに、上記課題を解決するために、本発明は次の構成を有する。すなわち、軸方向に振動し、かつ軸方向に平行な突起を表面に有するロールの回転方向と強化繊維束の搬送方向とを同一とし、軸方向に振動し、かつ軸方向に平行な突起を表面に有するロールの振幅を0.5〜20mm、軸方向に振動し、かつ軸方向に平行な突起を表面に有するロールの振動数を0.5〜30Hzとするプリプレグの製造方法である。   Furthermore, in order to solve the said subject, this invention has the following structure. That is, the rotation direction of the roll that vibrates in the axial direction and has protrusions parallel to the axial direction on the surface is the same as the conveyance direction of the reinforcing fiber bundle, and the protrusion that vibrates in the axial direction and parallel to the axial direction The roll has an amplitude of 0.5 to 20 mm, vibrates in the axial direction, and a roll having a protrusion parallel to the axial direction on the surface has a frequency of 0.5 to 30 Hz.

さらにまた、上記課題を解決するために、本発明は強化繊維束を案内するガイド部と、該ガイド部を介して搬送されてくる強化繊維束を所定間隔に整列させる整列部と、該整列部により整列させた強化繊維束に樹脂を含浸させる含浸部とを備えるプリプレグの製造装置において、前記整列部と含浸部との間にロール軸方向に振動し、かつロール軸方向に平行な突起を表面に有する駆動ロールを少なくとも1本設けたプリプレグの製造装置である。   Furthermore, in order to solve the above-described problems, the present invention provides a guide portion that guides the reinforcing fiber bundle, an aligning portion that aligns the reinforcing fiber bundle conveyed through the guide portion at a predetermined interval, and the aligning portion. In a prepreg manufacturing apparatus comprising an impregnation portion for impregnating a resin into a bundle of reinforcing fibers aligned by a surface, a projection that vibrates in the roll axis direction and is parallel to the roll axis direction between the alignment portion and the impregnation portion. Is a prepreg manufacturing apparatus provided with at least one drive roll.

本発明は一方向に平行するように引き揃えられ走行する複数本の強化繊維束に樹脂を含浸させるプリプレグの製造方法において、樹脂含浸部の上流側において軸方向に振動し、かつ軸方向に平行な突起を表面に有するロールを、ロールの周速度Vrと強化繊維の搬送速度Vfの絶対値の比|Vr/Vf|を、|Vr/Vf|<1の範囲内としつつ、強化繊維束を軸方向に対して直角方向に接触させながら通過させた後に樹脂含浸部に供給するプリプレグの製造方法であり、強化繊維束の捻れや反転が樹脂含浸部に持ち込まれることを防止し、ワレ欠点や平滑性不良部位の発生を抑えながらプリプレグを製造することができる。   The present invention relates to a method for manufacturing a prepreg in which a plurality of reinforcing fiber bundles that are aligned and run parallel to one direction are impregnated with resin, and vibrates in the axial direction upstream of the resin-impregnated portion and parallel to the axial direction. The rolls having various protrusions on the surface, the ratio of absolute values of the roll peripheral speed Vr and the reinforcing fiber transport speed Vf, | Vr / Vf |, is in the range of | Vr / Vf | <1, It is a manufacturing method of a prepreg that is supplied to a resin-impregnated part after passing while contacting in a direction perpendicular to the axial direction, and prevents twisting and inversion of the reinforcing fiber bundle from being brought into the resin-impregnated part. A prepreg can be produced while suppressing the occurrence of poor smoothness sites.

次に、本発明について、さらに詳しく説明する。   Next, the present invention will be described in more detail.

一般的なプリプレグの製造方法において、強化繊維束はガイド部、整列部を介して一方向に引き揃えられた後に樹脂含浸部に送られるが、樹脂含浸部に至るまでのガイド部や整列部を通過する際に強化繊維束が捻れたり反転したりすることがある。本発明においては強化繊維束を一方向に引き揃える整列部の後で、軸方向に振動し、かつ軸方向に平行な突起を表面に有する駆動ロールに、強化繊維束を軸方向に対して直角方向に接触させることで、強化繊維束はロール上で一定の形態を保持するため、捻れや反転がロールの手前で堰き止められる。その結果、捻れや反転がロールを越えて樹脂含浸部に供給されることなく、好適なプリプレグが得られる。   In a general prepreg manufacturing method, the reinforcing fiber bundle is sent to the resin impregnated part after being aligned in one direction via the guide part and the aligning part. When passing, the reinforcing fiber bundle may be twisted or inverted. In the present invention, the reinforcing fiber bundle is perpendicular to the axial direction on a driving roll having a projection on the surface that vibrates in the axial direction and is parallel to the axial direction after the alignment portion that aligns the reinforcing fiber bundle in one direction. By bringing them into contact with each other in the direction, the reinforcing fiber bundle maintains a certain shape on the roll, so that twisting and reversal are dammed before the roll. As a result, a suitable prepreg can be obtained without twisting or reversing exceeding the roll and being supplied to the resin-impregnated portion.

ここで、軸方向に振動し、かつ軸方向に平行な突起を表面に有する駆動ロールの周速度Vrと強化繊維の搬送速度Vfの絶対値の比|Vr/Vf|が、|Vr/Vf|<1の範囲内であることが重要であり、それ以外の範囲にある場合には捻れや反転が駆動ロールを越えて樹脂含浸部に供給されたり、あるいは軸方向に振動し、かつ軸方向に平行な突起を表面に有する駆動ロールと強化繊維束との擦過により強化繊維束が傷んでプリプレグとした場合の品位悪化につながることがある。なお、軸方向に振動し、かつ軸方向に平行な突起を表面に有する駆動ロールの周速度Vrと強化繊維束の搬送速度Vfの絶対値の比|Vr/Vf|が、0.05≦|Vr/Vf|≦0.5であればより好ましく、0.05≦|Vr/Vf|≦0.4であれば更に好ましい。かかる範囲内であれば、より効果的に捻れや反転の含浸部への供給を防止することができる。   Here, the ratio | Vr / Vf | of the absolute value of the peripheral speed Vr of the driving roll that vibrates in the axial direction and has protrusions parallel to the axial direction on the surface and the conveying speed Vf of the reinforcing fiber is | Vr / Vf | It is important that it is within the range of <1. If it is in the range other than that, twist or inversion exceeds the driving roll and is supplied to the resin impregnated part, or vibrates in the axial direction, and in the axial direction. The reinforced fiber bundle may be damaged by rubbing between the driving roll having parallel protrusions on the surface and the reinforcing fiber bundle, leading to deterioration in quality when a prepreg is obtained. Note that the ratio | Vr / Vf | of the absolute value of the circumferential speed Vr of the driving roll that vibrates in the axial direction and has protrusions parallel to the axial direction on the surface and the conveying speed Vf of the reinforcing fiber bundle is 0.05 ≦ | More preferably, Vr / Vf | ≦ 0.5, and even more preferably 0.05 ≦ | Vr / Vf | ≦ 0.4. Within such a range, it is possible to more effectively prevent the twisted or inverted supply to the impregnated portion.

また、軸方向に振動し、かつ軸方向に平行な突起を表面に有する駆動ロールを強化繊維束の搬送方向と同一にすることにより、かかる駆動ロールと強化繊維束との擦過による強化繊維束の傷みを抑制することができる。   Further, by making the drive roll that vibrates in the axial direction and has protrusions parallel to the axial direction on the surface thereof, the direction of the reinforcing fiber bundle by rubbing between the drive roll and the reinforcing fiber bundle becomes the same. Damage can be suppressed.

さらに、軸方向に振動し、かつ軸方向に平行な突起を表面に有する駆動ロールの振幅や周波数は使用する強化繊維束によって適宜選択されるものであり特に規定はないが、振幅0.5〜20mm程度、周波数0.5〜30Hz程度であれば強化繊維束を傷めることも少なく、好ましい。さらに振幅1〜15mm程度、周波数3〜20Hz程度であればより好ましい。   Furthermore, the amplitude and frequency of the driving roll that vibrates in the axial direction and has protrusions parallel to the axial direction on the surface are appropriately selected depending on the reinforcing fiber bundle to be used, and are not particularly specified. If it is about 20 mm and the frequency is about 0.5 to 30 Hz, the reinforcing fiber bundle is rarely damaged, which is preferable. Furthermore, it is more preferable if the amplitude is about 1 to 15 mm and the frequency is about 3 to 20 Hz.

上記において、強化繊維束は、たとえば、炭素繊維束、ガラス繊維束、アラミド繊維束のようなものである。なかでも、本発明は、比較的高弾性率で、単繊維切れや毛羽を生じやすい炭素繊維束を使用する場合に好適であり、炭素繊維束としては、たとえば、ポリアクリロニトリル系繊維やピッチ系繊維を原料繊維とするものが物性的に好ましい。   In the above, the reinforcing fiber bundle is, for example, a carbon fiber bundle, a glass fiber bundle, or an aramid fiber bundle. Among them, the present invention is suitable when a carbon fiber bundle having a relatively high elastic modulus and easily causing single fiber breakage or fluff is used. Examples of the carbon fiber bundle include polyacrylonitrile fiber and pitch fiber. The material is preferably made of raw material fibers.

本発明においては強化繊維束のフィラメント数は1,000〜100,000本のものを用いることができるが、特にフィラメント数が3,000〜12,000本程度で糸幅が2〜6mm程度の炭素繊維束を使用する場合に、前記駆動ロールが軸方向に振動する効果が顕著に現れるため好適である。   In the present invention, the number of filaments of the reinforcing fiber bundle can be 1,000 to 100,000, and in particular, the number of filaments is about 3,000 to 12,000 and the yarn width is about 2 to 6 mm. In the case of using a carbon fiber bundle, the effect that the drive roll vibrates in the axial direction is remarkable, which is preferable.

強化繊維束の走行速度Vfは、遅すぎるとプリプレグ生産の効率が悪くなり、速すぎると樹脂含浸のための装置が大きくなってくるので、3〜20m/分程度とするのが好ましく、4〜15m/分程度であればより好ましい。   If the traveling speed Vf of the reinforcing fiber bundle is too slow, the efficiency of prepreg production is deteriorated, and if it is too fast, the apparatus for impregnating the resin becomes large, and is preferably about 3 to 20 m / min. It is more preferable if it is about 15 m / min.

また、軸方向に平行な突起を表面に有するロールに供給する際の強化繊維束の張力は特に規定はないが、フィラメント数1,000本あたり、0.05〜0.82Nとすることが好ましく、0.08〜0.65Nであればより好ましい。張力が1,000本あたり0.05N未満の場合には強化繊維束の走行性が悪化し、プロセス性が低下することがあり、張力が1,000本あたり0.82Nを超える場合にはガイド等で強化繊維束が擦過された際に強化繊維束が毛羽立ちやすくなることがある。さらに、軸方向に振動し、かつ軸方向に平行な突起を表面に有するロールに供給する強化繊維束は、ヒーター等で予め強化繊維束に付着しているサイジング剤が軟化する温度である50〜180℃程度に加温させておけば、強化繊維束の収束性が適度に除かれ、軸方向に振動し、かつ軸方向に平行な突起を表面に有するロール上での強化繊維の走行性が安定するので好ましく、70〜130℃であればより好ましい。50℃未満の場合にはサイジング剤の軟化が十分ではないことがあり、180℃を超える場合にはサイジング剤自体の減量や変質によりFRPとしたときの特性に悪影響が出る場合がある。   Further, the tension of the reinforcing fiber bundle when supplying the roll having protrusions parallel to the axial direction on the surface is not particularly limited, but is preferably 0.05 to 0.82 N per 1,000 filaments. 0.08 to 0.65N is more preferable. When the tension is less than 0.05N per 1,000 fibers, the running performance of the reinforcing fiber bundle may be deteriorated and the processability may be deteriorated. When the tension exceeds 0.82N per 1,000 fibers, the guide When the reinforcing fiber bundle is abraded with the like, the reinforcing fiber bundle may be easily fuzzed. Further, the reinforcing fiber bundle that vibrates in the axial direction and that is supplied to the roll having protrusions parallel to the axial direction on the surface thereof is a temperature at which the sizing agent that is attached to the reinforcing fiber bundle in advance with a heater or the like is softened. If heated to about 180 ° C., the convergence of the reinforcing fiber bundle is moderately removed, and the running properties of the reinforcing fiber on a roll that vibrates in the axial direction and has protrusions parallel to the axial direction on the surface. It is preferable because it is stable, and 70 to 130 ° C. is more preferable. When the temperature is less than 50 ° C., the sizing agent may not be sufficiently softened. When the temperature exceeds 180 ° C., the characteristics of the FRP may be adversely affected due to the weight loss or alteration of the sizing agent itself.

本発明のプリプレグの製造装置は、強化繊維束を案内するガイド部と、該ガイド部を介して搬送されてくる強化繊維束を所定間隔に整列させる整列部と、該整列部により整列させた強化繊維束に樹脂を含浸させる含浸部とを備えるプリプレグの製造装置において、前記整列部と含浸部との間にロール軸方向に振動し、かつロール軸方向に平行な突起を表面に有する駆動ロールを少なくとも1本設けることを特徴とする。   The prepreg manufacturing apparatus of the present invention includes a guide unit that guides a reinforcing fiber bundle, an alignment unit that aligns the reinforcing fiber bundles conveyed through the guide unit at predetermined intervals, and a reinforcement that is aligned by the alignment unit. In a prepreg manufacturing apparatus comprising an impregnation unit for impregnating a fiber bundle with resin, a driving roll that vibrates in the roll axis direction between the alignment unit and the impregnation unit and has a protrusion parallel to the roll axis direction on the surface. At least one is provided.

ここで、ガイド部はボビン等のパッケージから繰り出した必要本数の強化繊維束を案内しながら搬送するのが一般的であるが、その方法は特に限定されるものではない。ガイド部は繰り出した強化繊維束を方向転換させるためのローラーやピン等を備えていてもよい。   Here, the guide part generally conveys a necessary number of reinforcing fiber bundles fed out from a package such as a bobbin while being guided, but the method is not particularly limited. The guide part may be provided with a roller, a pin or the like for changing the direction of the fed reinforcing fiber bundle.

また、整列部は強化繊維束を引き揃えるのに平行に均一に引き揃えるために等ピッチ間隔にピンを配したコームあるいは等ピッチ間に溝を有するロール等を使用するのが一般的であるが、その手段は特に限定されるものではない。   Further, in order to align the reinforcing fiber bundles in parallel, the alignment portion generally uses combs with pins arranged at equal pitch intervals or rolls having grooves between equal pitches. The means is not particularly limited.

以下、本発明を図面に示す実施形態に基づいて、さらに詳しく説明する。   Hereinafter, the present invention will be described in more detail based on embodiments shown in the drawings.

図1は本発明の一形態に係るプリプレグの製造装置を示すものであり、強化繊維束2、2、・・・を案内するガイド部3と、該ガイド部3を介して搬送されてくる強化繊維束を所定間隔に整列させる整列部であるコーム4と、該整列部により整列させた強化繊維束に樹脂を含浸させる含浸部8とを備えている。ここでガイド部3は、ガイドロール31および32を有する。   FIG. 1 shows a prepreg manufacturing apparatus according to an embodiment of the present invention, in which a guide portion 3 for guiding reinforcing fiber bundles 2, 2,..., And a reinforcement conveyed through the guide portion 3. The comb 4 is an alignment portion that aligns the fiber bundles at a predetermined interval, and the impregnation portion 8 that impregnates the reinforcing fiber bundles aligned by the alignment portion with resin. Here, the guide portion 3 has guide rolls 31 and 32.

多数個のパッケージ1、1、・・・から繰り出される多数本の強化繊維束2、2、・・・は、自由回転するガイドロール31、32、コーム4を経て一方向に互いに並行するようにシート状に引き揃えられ、軸方向に振動し、かつ軸方向に平行な突起を表面に有する駆動ロール6に送られる。   The multiple reinforcing fiber bundles 2, 2,... Fed out from the multiple packages 1, 1,... Are parallel to each other in one direction via the freely rotating guide rolls 31 and 32 and the comb 4. The sheet is fed into a sheet shape, vibrated in the axial direction, and sent to a driving roll 6 having protrusions parallel to the axial direction on the surface.

強化繊維束2、2、・・・はロール6に入る前に予めヒーター5で加熱される。加熱手段および加熱温度は特に規定はないが、ヒーターであれば広範囲を比較的簡単に加熱できるため好ましく、加熱温度は強化繊維束に付着しているサイジング剤が軟化する50〜180℃であれば好ましい。ロール6は例えば図2あるいは図3に示す形状である。   The reinforcing fiber bundles 2, 2,... Are preheated by the heater 5 before entering the roll 6. The heating means and the heating temperature are not particularly defined, but a heater is preferable because a wide range can be heated relatively easily. The heating temperature is 50 to 180 ° C. at which the sizing agent adhering to the reinforcing fiber bundle is softened. preferable. The roll 6 has, for example, the shape shown in FIG.

ここで、ロール6の突起高さtをロール半径rに対して、r{[1/cos(θ/2)]−1}を超える高さとすることによって、強化繊維束をローラー表面に接触させないようにし、糸条の損傷を防ぐことができる。なお、前記駆動ロールの突起高さtは必要以上に高くする必要はなく、10r{[1/cos(θ/2)]−1}未満であればロール加工もしやすく、好ましい。   Here, by setting the protrusion height t of the roll 6 to a height exceeding r {[1 / cos (θ / 2)]-1} with respect to the roll radius r, the reinforcing fiber bundle is not brought into contact with the roller surface. Thus, damage to the yarn can be prevented. Note that the protrusion height t of the drive roll need not be higher than necessary, and is preferably less than 10r {[1 / cos (θ / 2)]-1} because roll processing is easy.

また、隣接する突起間とロール軸とのなす角θは5〜50°が好ましく、10〜45°がより好ましい。θが5°未満の場合には、突起のピッチが狭すぎて撚りを止める力が弱くなることがあり、50°を超える場合には、突起部の曲率が大きくなり、強化繊維束の単繊維切れ、及び毛羽が発生することがある。ここで、駆動ロールは硬質クロムメッキ、セラミックス、ポリフッ化エチレン処理した金属などからなり、その半径rは20〜100mm程度であれば好ましく、25〜80mmであればより好ましい。半径rが20mm未満の場合には強化繊維束の張力によりロールが変形してしまう可能性があり、また半径rが100mmを超えると設備が大型化するとともに捻れを防止する効果が減少する場合がある。また駆動ロールの表面粗さは3〜20Sの梨地表面とすることが好ましく、6〜16Sの表面粗さとすることがさらに好ましい。表面粗さが3S未満の場合は強化繊維束のローラーへの接触面積が多くなり、例えば強化繊維束のサイジング剤等の汚れがロールに付着した場合に強化繊維束の単繊維が巻き付きやすくなる。また、表面粗さが20Sを超えるとロールの表面の凹凸で強化繊維束が傷つきやすくなり、糸切れや糸傷みにつながる傾向にある。   Further, the angle θ between the adjacent protrusions and the roll axis is preferably 5 to 50 °, more preferably 10 to 45 °. If θ is less than 5 °, the pitch of the protrusions may be too narrow and the force to stop twisting may be weakened. If it exceeds 50 °, the curvature of the protrusions will increase and the single fiber of the reinforcing fiber bundle Cutting and fluffing may occur. Here, the drive roll is made of hard chrome plating, ceramics, polyfluorinated ethylene-treated metal or the like, and the radius r is preferably about 20 to 100 mm, more preferably 25 to 80 mm. When the radius r is less than 20 mm, the roll may be deformed due to the tension of the reinforcing fiber bundle. When the radius r exceeds 100 mm, the size of the equipment increases and the effect of preventing twisting may decrease. is there. The surface roughness of the drive roll is preferably a 3-20S satin surface, and more preferably 6-16S. When the surface roughness is less than 3S, the contact area of the reinforcing fiber bundle with the roller increases. For example, when dirt such as a sizing agent of the reinforcing fiber bundle adheres to the roll, the single fiber of the reinforcing fiber bundle is easily wound. On the other hand, if the surface roughness exceeds 20S, the reinforcing fiber bundle is likely to be damaged due to the irregularities on the surface of the roll, which tends to lead to yarn breakage or yarn damage.

ロール6はモーター及び変速機により駆動と速度制御がなされている。また、ロール6への振動付与方法については特に限定されるものではないが、振動モーターやクランク機構などを使用することができる。   The roll 6 is driven and controlled by a motor and a transmission. Further, the method for imparting vibration to the roll 6 is not particularly limited, but a vibration motor, a crank mechanism, or the like can be used.

さらに、ロール6は軸方向に振動するとともに、強化繊維束と同方向回転し、その周速度Vrと強化繊維の搬送速度Vfの絶対値の比|Vr/Vf|を|Vr/Vf|<1の範囲内となるようにしている。   Further, the roll 6 vibrates in the axial direction and rotates in the same direction as the reinforcing fiber bundle, and the ratio | Vr / Vf | of the absolute value of the peripheral speed Vr and the reinforcing fiber transport speed Vf is set to | Vr / Vf | <1. Within the range.

軸方向に振動し、かつ軸方向に平行な突起を表面に有する駆動ロール6を通過した強化繊維束2、2、・・・は、ガイドロール7を経て樹脂含浸部8に送られる。樹脂含浸部8では強化繊維束2、2、・・・の上下面に、導入ロール81、81を介して導入される、Bステージのエポキシ樹脂、不飽和ポリエステル樹脂等のマトリクス樹脂を塗布した離型紙9、9をその樹脂塗布面が強化繊維束2、2、・・・側を向くように重ね合わせ、ヒータ82で予熱した後、加熱された含浸ロール83、83間に通して離型紙9、9上のマトリクス樹脂を強化繊維束2、2、・・・に転移、含浸する。すなわち、一方向性プリプレグとする。マトリクス樹脂の転移、含浸後は、引取ロール84、84を経て上側の離型紙10を剥ぎ取り、下側の離型紙10ごとロール状に巻き取り、一方向性プリプレグのロール体11とする。   The reinforcing fiber bundles 2, 2,... That have vibrated in the axial direction and passed through the driving roll 6 having protrusions parallel to the axial direction on the surface are sent to the resin-impregnated portion 8 through the guide roll 7. In the resin-impregnated portion 8, the upper and lower surfaces of the reinforcing fiber bundles 2, 2,... Are separated by applying a matrix resin such as B-stage epoxy resin or unsaturated polyester resin introduced through the introduction rolls 81, 81. The pattern papers 9, 9 are overlapped so that their resin-coated surfaces face the reinforcing fiber bundles 2, 2,..., Preheated by the heater 82, and then passed between heated impregnating rolls 83, 83 to release the release paper 9 , 9 is transferred and impregnated into the reinforcing fiber bundles 2, 2,... That is, it is set as a unidirectional prepreg. After the transfer and impregnation of the matrix resin, the upper release paper 10 is peeled off through the take-up rolls 84 and 84, and the lower release paper 10 is taken up into a roll shape to obtain a roll body 11 of a unidirectional prepreg.

また、図4に示すように、軸方向に振動し、かつ軸方向に平行な突起を表面に有する駆動ロール6、ガイドロール7の下流側に開繊手段12を設けても良い。開繊手段は特に規定はなく、公知の技術が適宜使用されるが、例えば特開03−146735に記載されているような、3本のバ−上を緊張状態で通過させ,強化繊維束を拡開するような手段や特開平10−292238に記載されている、複数のローラ群上を所定角度に屈曲させながら通過させて開繊する手段を用いることができる。   Further, as shown in FIG. 4, the fiber opening means 12 may be provided on the downstream side of the drive roll 6 and the guide roll 7 that vibrate in the axial direction and have protrusions parallel to the axial direction on the surface. There are no particular restrictions on the opening means, and known techniques are used as appropriate. For example, as described in JP-A 03-146735, three bars are passed through in tension, and the reinforcing fiber bundle is passed through. A means for expanding and a means described in Japanese Patent Laid-Open No. 10-292238 can be used for passing and opening a plurality of roller groups while bending them at a predetermined angle.

(実施例1)
図1に示した装置を用い、強化繊維束2、2、・・・として、平均単繊維径7μm、単繊維数12,000本、繊度0.8kg/m、パッケージ上の糸幅6mmの炭素繊維束(東レ株式会社製“トレカ”T700SC−12K)を用い、その188本をコーム4にて5.3mmピッチで一方向に並列するように引き揃え、8m/分の速度で、軸方向に振動し、かつ軸方向に平行な突起を表面に有するロール6に供給した。供給時の単繊維1,000本あたりの張力は0.26Nに設定した。
(Example 1)
Using the apparatus shown in FIG. 1, as the reinforcing fiber bundles 2, 2,..., Carbon having an average single fiber diameter of 7 μm, the number of single fibers of 12,000, a fineness of 0.8 kg / m, and a yarn width of 6 mm on the package. Using a fiber bundle (Toray Industries, Inc. “Torayca” T700SC-12K), 188 of them were aligned in a comb 4 so as to be parallel in one direction at a pitch of 5.3 mm, and axially at a speed of 8 m / min. The roll 6 which vibrates and has a protrusion parallel to the axial direction on the surface was supplied. The tension per 1,000 single fibers at the time of supply was set to 0.26N.

軸方向に振動し、かつ軸方向に平行な突起を表面に有するロール6としては直径50mm、突起高さ5mm、突起先端は半径2mmの加工、隣接する突起間とロール軸とのなす角(θ)を45°とし、表面粗さ10Sの梨地表面に加工されている硬質クロムメッキロールを用いた。それを振幅10mm、振動数3Hzで軸方向に振動させた。   The roll 6 that vibrates in the axial direction and has protrusions parallel to the axial direction on the surface has a diameter of 50 mm, a protrusion height of 5 mm, and a protrusion tip having a radius of 2 mm. The angle formed between the adjacent protrusions and the roll axis (θ ) Was set to 45 °, and a hard chrome plating roll processed on a satin surface having a surface roughness of 10S was used. It was vibrated in the axial direction with an amplitude of 10 mm and a frequency of 3 Hz.

さらにロール6は周速度2m/分で強化繊維束と同一な方向に回転させ、ロール6の周速度Vrと強化繊維束の搬送速度Vfとの比|Vr/Vf|を0.25とした。   Furthermore, the roll 6 was rotated in the same direction as the reinforcing fiber bundle at a peripheral speed of 2 m / min, and the ratio | Vr / Vf | of the peripheral speed Vr of the roll 6 and the conveying speed Vf of the reinforcing fiber bundle was set to 0.25.

なお、ヒーター5としては赤外線ヒーターを用い、ヒーター5では炭素繊維束が77℃になるように加熱した。この77℃という温度は、上記炭素繊維束に付着せしめられているサイジング剤の軟化点温度である。   Note that an infrared heater was used as the heater 5, and the heater 5 was heated so that the carbon fiber bundle became 77 ° C. This temperature of 77 ° C. is the softening point temperature of the sizing agent adhered to the carbon fiber bundle.

ロール6を通過した強化繊維束には捻れや反転が見られず、ガイドロール7を経て樹脂含浸部8に送られてた。   The reinforcing fiber bundle that passed through the roll 6 was not twisted or reversed, and was sent to the resin-impregnated portion 8 through the guide roll 7.

樹脂含浸部8では離型紙9、9として、一面にBステージのエポキシ樹脂を幅1,005mm、目付37g/m2で塗布したものを用いた。また、ヒータによる加熱温度は120℃とし、含浸ロールの線圧は1,000kg/1,000mm幅とした。得られたプリプレグは、幅1000mm、目付が150g/m2、繊維重量含有率が67%であり、プリプレグにワレや平滑不良部などの欠点はなかった。
(実施例2)
軸方向に振動し、かつ軸方向に平行な突起を表面に有するロール6を周速度2m/分で強化繊維束と反対の方向に回転させた以外は実施例1と同様の条件でプリプレグを作製した。
In the resin impregnated portion 8, as the release papers 9, 9, a B-stage epoxy resin coated on one side with a width of 1,005 mm and a basis weight of 37 g / m 2 was used. The heating temperature by the heater was 120 ° C., and the linear pressure of the impregnating roll was 1,000 kg / 1,000 mm width. The obtained prepreg had a width of 1000 mm, a basis weight of 150 g / m 2 and a fiber weight content of 67%, and the prepreg had no defects such as cracks and defective smoothness.
(Example 2)
A prepreg is produced under the same conditions as in Example 1 except that the roll 6 that vibrates in the axial direction and has protrusions parallel to the axial direction on the surface is rotated in the direction opposite to the reinforcing fiber bundle at a peripheral speed of 2 m / min. did.

ロール6を通過した強化繊維束には捻れや反転が見られず、ガイドロール7を経て樹脂含浸部8に送られていたが、ロールとの接触により強化繊維束の傷みが少し見られた。得られたプリプレグは、強化繊維束の傷みによるケバ欠点が少量見られたものの、プリプレグ製品として問題のあるものではなかった。
(実施例3)
実施例1と同様の炭素繊維束を94本を10.6mmピッチで一方向に並列するように引き揃え、6m/分の速度で図4に示した装置に供給し、離型紙9、9に塗布したエポキシ樹脂の目付を22g/m2とした以外は実施例1と同様の条件でプリプレグを作製した。なお、軸方向に振動し、かつ軸方向に平行な突起を表面に有するロール6の周速度Vrと強化繊維束の搬送速度Vfとの比|Vr/Vf|は0.33であり、開繊手段12としては特開平10−292238の実施例1に記載されている、複数のローラ群上を所定角度に屈曲させながら通過させて開繊する手段を使用した。
The reinforcing fiber bundle that passed through the roll 6 was not twisted or reversed, and was sent to the resin impregnated portion 8 through the guide roll 7, but the reinforcing fiber bundle was slightly damaged by contact with the roll. The obtained prepreg was not problematic as a prepreg product although a small amount of keratin defects due to the damage of the reinforcing fiber bundle was observed.
(Example 3)
94 carbon fiber bundles similar to those in Example 1 are aligned so as to be aligned in one direction at a pitch of 10.6 mm, and supplied to the apparatus shown in FIG. 4 at a speed of 6 m / min. A prepreg was produced under the same conditions as in Example 1 except that the basis weight of the applied epoxy resin was 22 g / m 2 . The ratio | Vr / Vf | of the peripheral speed Vr of the roll 6 that vibrates in the axial direction and has protrusions parallel to the axial direction on the surface and the conveying speed Vf of the reinforcing fiber bundle is 0.33, As the means 12, a means described in Example 1 of Japanese Patent Laid-Open No. 10-292238, which is opened by passing through a plurality of roller groups while being bent at a predetermined angle, was used.

ロール6を通過した強化繊維束には捻れや反転が見られず、ガイドロール7、開繊手段12を経て樹脂含浸部8に送られていた。得られたプリプレグは、幅1000mm、目付が119g/m2で、繊維重量含有率が63%であり、プリプレグにワレや平滑不良部などの欠点はなかった。
(実施例4)
ロール6の周速度Vrを5m/分で強化繊維束と同一な方向に回転させ、強化繊維束の搬送速度Vfとの比|Vr/Vf|を0.63とした以外は実施例1と同様にし、プリプレグを作製した。
The reinforcing fiber bundle that passed through the roll 6 was not twisted or reversed, and was sent to the resin impregnated portion 8 through the guide roll 7 and the fiber opening means 12. The obtained prepreg had a width of 1000 mm, a basis weight of 119 g / m 2 and a fiber weight content of 63%, and the prepreg had no defects such as cracks and defective smoothness.
Example 4
Similar to Example 1, except that the peripheral speed Vr of the roll 6 is rotated in the same direction as the reinforcing fiber bundle at 5 m / min, and the ratio | Vr / Vf | with respect to the conveying speed Vf of the reinforcing fiber bundle is set to 0.63. A prepreg was prepared.

ロール6を通過した強化繊維束には若干の捻れが見られたが、得られたプリプレグにおいてはワレや平滑不良部などの欠点となるものはなかった。
(比較例1)
ロール6を設置しない以外は実施例1と同様にプリプレグを製造した。
The reinforcing fiber bundle that passed through the roll 6 was slightly twisted. However, the obtained prepreg had no defects such as cracks and poor smoothness.
(Comparative Example 1)
A prepreg was produced in the same manner as in Example 1 except that the roll 6 was not installed.

ガイドロール7を経て樹脂含浸部8に送られる強化繊維束は捻れや反転を含み、得られたプリプレグは強化繊維束の捻れや反転部でワレ欠点が発生し、かつ、平滑不良部が多発し、プリプレグとしての品位に劣るものであった。
(比較例2)
軸方向に振動し、かつ軸方向に平行な突起を表面に有するロール6の周速度Vrを9m/分で強化繊維束と同一な方向に回転させ、強化繊維束の搬送速度Vfとの比|Vr/Vf|を1.13とした以外は実施例1と同様にし、プリプレグを作製した。
The reinforcing fiber bundle sent to the resin-impregnated portion 8 through the guide roll 7 includes twisting and reversal, and the obtained prepreg has crack defects at the twisting and reversing portion of the reinforcing fiber bundle, and many smooth defective portions occur. The quality of the prepreg was inferior.
(Comparative Example 2)
The ratio of the circumferential speed Vr of the roll 6 that vibrates in the axial direction and has protrusions parallel to the axial direction to the same direction as the reinforcing fiber bundle at a speed of 9 m / min. A prepreg was produced in the same manner as in Example 1 except that Vr / Vf | was changed to 1.13.

ガイドロール7を経て樹脂含浸部8に送られる強化繊維束は捻れや反転を含み、得られたプリプレグは強化繊維束の捻れや反転部でワレ欠点が発生し、かつ、平滑不良部が多発し、プリプレグとしての品位に劣るものであった。
(比較例3)
軸方向に振動し、かつ軸方向に平行な突起を表面に有するロール6の周速度Vrを10m/分で強化繊維束と同一な方向に回転させ、強化繊維束の搬送速度Vfとの比|Vr/Vf|を1.25とした以外は実施例2と同様にし、プリプレグを作製した。
The reinforcing fiber bundle sent to the resin-impregnated portion 8 through the guide roll 7 includes twisting and reversing, and the obtained prepreg has crack defects at the twisting and reversing portion of the reinforcing fiber bundle, and many smooth defective portions occur. The quality of the prepreg was inferior.
(Comparative Example 3)
A ratio of the circumferential speed Vr of the roll 6 that vibrates in the axial direction and has protrusions parallel to the axial direction to the same direction as the reinforcing fiber bundle at a speed of 10 m / min. A prepreg was produced in the same manner as in Example 2 except that Vr / Vf | was changed to 1.25.

ロール6を通過した強化繊維束には捻れや反転が見られず、ガイドロール7を経て樹脂含浸部8に送られていたが、ロールとの接触により強化繊維束の傷みが顕著に見られた。得られたプリプレグは、強化繊維束の傷みによるケバ欠点が多発し、プリプレグとしての品位に劣るものであった。
(比較例4)
実施例3において、ロール6の代わりに無振動かつフリー回転する同型ロールを設置した。それ以外は実施例2と同様にプリプレグを製造した。
The reinforcing fiber bundle that passed through the roll 6 was not twisted or reversed, and was sent to the resin impregnated portion 8 through the guide roll 7, but the damage of the reinforcing fiber bundle was noticeable due to contact with the roll. . The obtained prepreg was inferior in quality as a prepreg because of frequent defects due to damage of the reinforcing fiber bundle.
(Comparative Example 4)
In Example 3, instead of the roll 6, an isomorphous roll that is free of vibration and rotates freely was installed. Otherwise, a prepreg was produced in the same manner as in Example 2.

ガイドロール7を経て開繊手段12に送られる強化繊維束は捻れや反転を含み、開繊手段12で拡幅されて樹脂含浸部8に送られる強化繊維束も捻れや反転部で糸幅が局所的に細幅となっていた。得られたプリプレグは強化繊維束の捻れや反転による細幅部でワレ欠点が多発し、プリプレグとしての品位に劣るものであった。   The reinforcing fiber bundle sent to the opening means 12 through the guide roll 7 includes twisting and reversing, and the reinforcing fiber bundle that is widened by the opening means 12 and sent to the resin-impregnated portion 8 is also locally twisted and reversed at the yarn width. It was narrow. The obtained prepreg was inferior in quality as a prepreg due to frequent cracking defects at narrow portions due to twisting and reversal of the reinforcing fiber bundle.

本発明の一形態に係るプリプレグの製造装置の概略側面図である。It is a schematic side view of the manufacturing apparatus of the prepreg which concerns on one form of this invention. 本発明の一形態に係る軸方向に振動し、かつ軸方向に平行な突起を表面に有するロール6の概略側面図である。It is a schematic side view of the roll 6 which vibrates to the axial direction which concerns on one form of this invention, and has a processus | protrusion parallel to an axial direction on the surface. 本発明の一形態に係る軸方向に振動し、かつ軸方向に平行な突起を表面に有するロール6の全体図である。It is a whole view of the roll 6 which vibrates to the axial direction which concerns on one form of this invention, and has a processus | protrusion parallel to an axial direction on the surface. 本発明の一形態に係るプリプレグの製造装置の別の例の概略側面図である。It is a schematic side view of another example of the manufacturing apparatus of the prepreg which concerns on one form of this invention.

符号の説明Explanation of symbols

1:パッケージ
2:強化繊維束
3:ガイド部
31:ガイドロール
32:ガイドロール
4:コーム
5:ヒーター
6:軸方向に振動し、かつ軸方向に平行な突起を表面に有する駆動ロール
7:ガイドロール
8:樹脂含浸部
81:導入ロール
82:ヒータ
83:含浸ロール
84:引取りロール
9:マトリクス樹脂を塗布した離型紙
10:離型紙
11:一方向性プリプレグのロール体
12:開繊手段
1: Package 2: Reinforced fiber bundle 3: Guide part 31: Guide roll 32: Guide roll 4: Comb 5: Heater 6: Drive roll having projections on the surface that vibrate in the axial direction and parallel to the axial direction 7: Guide Roll 8: Resin impregnation part 81: Introduction roll 82: Heater 83: Impregnation roll 84: Take-off roll 9: Release paper coated with matrix resin 10: Release paper 11: Roll body of unidirectional prepreg 12: Opening means

Claims (11)

一方向に平行するように引き揃えられ走行する複数本の強化繊維束に樹脂を含浸させるプリプレグの製造方法において、樹脂含浸部の上流側において軸方向に振動し、かつ軸方向に平行な突起を表面に有するロールを、ロールの周速度Vrと強化繊維の搬送速度Vfの絶対値の比|Vr/Vf|を、|Vr/Vf|<1の範囲内としつつ、強化繊維束を軸方向に対して直角方向に接触させながら通過させた後に樹脂含浸部に供給するプリプレグの製造方法。   In a method for manufacturing a prepreg in which a plurality of reinforcing fiber bundles that are aligned and run parallel to one direction are impregnated with resin, a vibration that vibrates in the axial direction on the upstream side of the resin-impregnated portion and that has a projection parallel to the axial direction. While the roll having the surface has a ratio | Vr / Vf | of the absolute value of the peripheral speed Vr of the roll and the conveying speed Vf of the reinforcing fiber within the range of | Vr / Vf | <1, the reinforcing fiber bundle is axially A method for producing a prepreg that is supplied to a resin-impregnated portion after passing through while being brought into contact with a right angle direction. 前記ロールの周速度Vrと強化繊維の搬送速度Vfの絶対値の比|Vr/Vf|が、0.05≦|Vr/Vf|≦0.5の範囲内である、請求項1記載のプリプレグの製造方法。   The prepreg according to claim 1, wherein a ratio | Vr / Vf | of the absolute value of the peripheral speed Vr of the roll and the conveying speed Vf of the reinforcing fiber is in a range of 0.05 ≦ | Vr / Vf | ≦ 0.5. Manufacturing method. 前記ロールの回転方向と強化繊維束の搬送方向が同一である、請求項1または2記載のプリプレグの製造方法。   The manufacturing method of the prepreg of Claim 1 or 2 whose rotation direction of the said roll and conveyance direction of a reinforced fiber bundle are the same. 前記ロールの振幅が0.5〜20mmである、請求項1〜3のいずれかに記載のプリプレグの製造方法。   The manufacturing method of the prepreg in any one of Claims 1-3 whose amplitude of the said roll is 0.5-20 mm. 前記ロールの振動数が0.5〜30Hzである、請求項1〜4のいずれかに記載のプリプレグの製造方法。   The manufacturing method of the prepreg in any one of Claims 1-4 whose vibration frequency of the said roll is 0.5-30Hz. 前記ロールと樹脂含浸部との間で強化繊維束を開繊させる請求項1〜5のいずれかに記載のプリプレグの製造方法。   The method for producing a prepreg according to any one of claims 1 to 5, wherein a reinforcing fiber bundle is opened between the roll and the resin-impregnated portion. 強化繊維束が炭素繊維束である、請求項1〜6のいずれかに記載のプリプレグの製造方法。   The method for producing a prepreg according to claim 1, wherein the reinforcing fiber bundle is a carbon fiber bundle. 強化繊維束を案内するガイド部と、該ガイド部を介して搬送されてくる強化繊維束を所定間隔に整列させる整列部と、該整列部により整列させた強化繊維束に樹脂を含浸させる含浸部とを備えるプリプレグの製造装置において、前記整列部と含浸部との間にロール軸方向に振動し、かつロール軸方向に平行な突起を表面に有する駆動ロールを少なくとも1本設けたプリプレグの製造装置。   A guide part for guiding the reinforcing fiber bundle, an aligning part for aligning the reinforcing fiber bundles conveyed via the guide part at a predetermined interval, and an impregnating part for impregnating the reinforcing fiber bundle aligned by the aligning part with resin And a prepreg manufacturing apparatus provided with at least one drive roll having a protrusion on the surface that vibrates in the roll axis direction between the alignment section and the impregnation section. . 前記駆動ロールの突起高さtをロール半径rに対して、r{[1/cos(θ/2)]−1}を超える高さとし、隣接する突起間とロール軸とのなす角θが5〜50°である請求項8記載のプリプレグの製造装置。   The protrusion height t of the driving roll is set to a height exceeding r {[1 / cos (θ / 2)]-1} with respect to the roll radius r, and the angle θ formed between the adjacent protrusions and the roll axis is 5 The apparatus for producing a prepreg according to claim 8, which is ˜50 °. 前記駆動ロールの表面粗さが3〜20Sの梨地表面である請求項8または9記載のプリプレグの製造装置。   The prepreg manufacturing apparatus according to claim 8 or 9, wherein the driving roll has a satin surface having a surface roughness of 3 to 20S. 請求項1〜7のいずれかに記載の方法によって製造されたプリプレグ。   The prepreg manufactured by the method in any one of Claims 1-7.
JP2003407180A 2003-12-05 2003-12-05 Manufacturing method and manufacturing apparatus for prepreg Pending JP2005161797A (en)

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US20200385540A1 (en) * 2017-12-22 2020-12-10 Toray Industries, Inc. A tape-shaped prepreg and a method for production thereof
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