JP2005074880A - Inkjet recording sheet - Google Patents
Inkjet recording sheet Download PDFInfo
- Publication number
- JP2005074880A JP2005074880A JP2003309909A JP2003309909A JP2005074880A JP 2005074880 A JP2005074880 A JP 2005074880A JP 2003309909 A JP2003309909 A JP 2003309909A JP 2003309909 A JP2003309909 A JP 2003309909A JP 2005074880 A JP2005074880 A JP 2005074880A
- Authority
- JP
- Japan
- Prior art keywords
- water
- recording sheet
- ink
- acrylic
- image
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 125000003504 2-oxazolinyl group Chemical group O1C(=NCC1)* 0.000 claims abstract description 14
- 229920003169 water-soluble polymer Polymers 0.000 claims abstract description 14
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims abstract description 13
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 12
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004593 Epoxy Substances 0.000 claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 7
- 239000000049 pigment Substances 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 22
- 238000001035 drying Methods 0.000 abstract description 9
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 238000004040 coloring Methods 0.000 abstract 1
- YONVOYAHRUTYTG-UHFFFAOYSA-N ethyl carbamate;hydrate Chemical compound O.CCOC(N)=O YONVOYAHRUTYTG-UHFFFAOYSA-N 0.000 abstract 1
- 238000007641 inkjet printing Methods 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 14
- 239000007787 solid Substances 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 4
- 229920006026 co-polymeric resin Polymers 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 238000001454 recorded image Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 150000001541 aziridines Chemical class 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 235000010338 boric acid Nutrition 0.000 description 1
- 125000005619 boric acid group Chemical class 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Landscapes
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Ink Jet (AREA)
Abstract
Description
本発明はインクジェット用記録シートに関するものであり、特に、透明もしくは光沢を有しているインクジェット記録用シート関する。 The present invention relates to an ink jet recording sheet, and more particularly to an ink jet recording sheet having transparency or gloss.
従来の技術では、特に透明もしくは光沢を有しているインクジェット記録用シートの受像層は、ポリビニルアルコール、ポリビニルピロリドン、澱粉、水溶性セルロース誘導体が提案されている。しかし、この方法では特に水性顔料インクの吸収性、乾燥性が悪く、乾燥途中で受像層がひび割れる問題がある。更に耐水性も不十分なため、水滴や汗が受像層に付着した場合、記録画像が滲んだり、受像層が基材から剥がれ易いという問題があり、いまだ満足できる結果を得るに至っていない。そこで、耐水性を向上させる方法として、数々の架橋剤を用いることが検討されており、このような架橋剤として、例えば、イソシアネート類、アジリジン類、ホウ酸類等が挙げられる。しかし、このような架橋剤では充分な耐水性を得ることができず、透明度や光沢度が低下する問題がある。特開２０００-５２６４７、特開２００１-２１９６４５には、オキサゾリン基を有する水溶性ポリマーを含有する、インクジェット用記録シート用コーティング剤が開示されている。しかしながら、オキサゾリン基1種類のみの添加では、塗工液固形分中のオキサゾリン基含有水溶性ポリマーの固形分が４５％〜５０％でありながら、耐水性がいまだ不十分であり、また、充分な耐水性を得られたとしても、記録画像が滲んだり、インクの定着性の低下を引き起こすという欠点がある。また、オキサゾリン基含有水溶性ポリマー多く添加することでコスト的に不利である。従来のインクジェット用記録シートは、耐水性の向上と共に、インク吸収性、乾燥性が低下し、印刷画質の低下が問題であった。このため、インク吸収性と印刷物の耐水性とを備え持つインクジェット用記録シートは得られていない。
本発明の目的は、透明もしくは光沢を有しているインクジェット用記録シートにおいて、特に水性顔料インクの吸収性、乾燥性、発色性に優れ、且つ、耐水性が良好なインクジェット用記録シートを提供することにある。 An object of the present invention is to provide an inkjet recording sheet that is transparent or glossy, particularly excellent in water-absorbent pigment ink absorbability, drying properties, and color developability, and has good water resistance. There is.
目的を達成するため、本発明は、水性ウレタン樹脂、水性アクリル樹脂の2種からなり、架橋剤としてオキサゾリン基を有する水溶性ポリマー及びアクリル系の水溶性自己乳化型エポキシ硬化剤を含有することを特徴とするものである。 In order to achieve the object, the present invention comprises two types of aqueous urethane resin and aqueous acrylic resin, and contains a water-soluble polymer having an oxazoline group and an acrylic water-soluble self-emulsifying epoxy curing agent as a crosslinking agent. It is a feature.
本発明は透明もしくは光沢を有しているインクジェット用記録シートにおいて、特に水性顔料インクの吸収性、乾燥性、発色性に優れ、且つ、耐水性が良好なインクジェット用記録シートを提供することができる。 INDUSTRIAL APPLICABILITY The present invention can provide an ink jet recording sheet that is transparent or glossy, and that is particularly excellent in water pigment ink absorbability, drying properties, and color developability, and has good water resistance. .
本発明者は鋭意検討の結果、水性顔料インクを用いて画像を形成するインクジェット用記録シートにおいて、該記録シートの受像層が、水性ウレタン樹脂、水性アクリル樹脂の2種からなり、架橋剤としてオキサゾリン基を有する水溶性ポリマー及びアクリル系の水溶性自己乳化型エポキシ硬化剤を含有することを特徴とするインクジェット用記録シートを提供するに至った。 As a result of intensive studies, the inventor of the present invention, in an inkjet recording sheet that forms an image using an aqueous pigment ink, the image receiving layer of the recording sheet is composed of two types, an aqueous urethane resin and an aqueous acrylic resin, and oxazoline as a crosslinking agent. An ink-jet recording sheet comprising a water-soluble polymer having a group and an acrylic water-soluble self-emulsifying epoxy curing agent has been provided.
ウレタン樹脂は、ポリエステル系、ポリエーテル系等が例示できる。カチオン性ポリエーテル系ウレタン樹脂が好ましいが、必要に応じて他のウレタン樹脂を用いても良い。 Examples of the urethane resin include polyesters and polyethers. Cationic polyether urethane resins are preferred, but other urethane resins may be used as necessary.
アクリル樹脂は、アクリル 酸エステルおよびメタクリル酸エステルの重合体または共重合体等のアクリル 系重合体樹脂、または、エチレン−酢酸ビニル、エチレン−アクリル −酢酸ビニル、エチレン−塩化ビニル−酢酸ビニル等のエチレン−酢酸ビニル共重合体樹脂、アクリル・スチレン共重合体樹脂等が例示できる。カチオン性アクリル・スチレン共重合体樹脂が好ましいが、必要に応じて他のアクリル樹脂を用いても良い。 The acrylic resin may be an acrylic polymer resin such as a polymer or copolymer of acrylic acid ester and methacrylic acid ester, or ethylene such as ethylene-vinyl acetate, ethylene-acrylic-vinyl acetate, ethylene-vinyl chloride-vinyl acetate. -Vinyl acetate copolymer resin, acrylic-styrene copolymer resin, etc. can be illustrated. Cationic acrylic / styrene copolymer resins are preferred, but other acrylic resins may be used if necessary.
受像層固形分中のウレタン樹脂とアクリル樹脂の重量比は、ウレタン樹脂が６５〜８５％で、アクリル樹脂が１５〜３５％のものが好ましい。さらには、ウレタン樹脂が７０〜８０％で、アクリル樹脂が２０〜３０％のものが好ましい。ウレタン樹脂が６５％を下回るとインク吸収性が不十分であり、８５％を上回ると耐水性が悪くなる。アクリル樹脂が１５％を下回ると基材との密着が悪くなり耐水性が不十分であり、３５％より大きくなるとインク吸収性、乾燥性が不十分で且つ、印刷画像に滲みを生じる。 The weight ratio of the urethane resin and the acrylic resin in the solid content of the image receiving layer is preferably 65 to 85% for the urethane resin and 15 to 35% for the acrylic resin. Furthermore, it is preferable that the urethane resin is 70 to 80% and the acrylic resin is 20 to 30%. If the urethane resin is less than 65%, the ink absorbency is insufficient, and if it exceeds 85%, the water resistance is deteriorated. When the acrylic resin is less than 15%, the adhesion to the substrate is poor and the water resistance is insufficient. When the acrylic resin is greater than 35%, the ink absorbability and the drying property are insufficient and the printed image is blurred.
受像層固形分中に含まれるオキサゾリン基を有する水溶性ポリマーは０.３〜２.０％が好ましい。さらには、０.５〜１.５％が好ましい。受像層固形分中に含まれるオキサゾリン基を有する水溶性ポリマーが０.５％を下回ると充分な耐水性を得ることができず、１.５％を上回るとインク吸収性、乾燥性が低下する。アクリル系の水溶性自己乳化型エポキシ硬化剤は２.０〜３.７％が好ましい。さらには、２.５〜３.５％が好ましい。アクリル系の水溶性自己乳化型エポキシ硬化剤が２.５％を下回ると充分な耐水性を得られず、また、インクの定着力も低下する。また、３.５％を上回ると、インク吸収性が低下する。 The water-soluble polymer having an oxazoline group contained in the solid content of the image-receiving layer is preferably 0.3 to 2.0%. Furthermore, 0.5 to 1.5% is preferable. If the water-soluble polymer having an oxazoline group contained in the solid content of the image-receiving layer is less than 0.5%, sufficient water resistance cannot be obtained, and if it exceeds 1.5%, ink absorbency and drying properties are lowered. . The acrylic water-soluble self-emulsifying type epoxy curing agent is preferably 2.0 to 3.7%. Furthermore, 2.5 to 3.5% is preferable. If the acrylic water-soluble self-emulsifying type epoxy curing agent is less than 2.5%, sufficient water resistance cannot be obtained, and the fixing ability of the ink also decreases. On the other hand, if it exceeds 3.5%, the ink absorbability is lowered.
基材は、ポリエステル、ポリオレフィン、ポリ塩化ビニル等の合成樹脂フィルム、合成紙等の紙が挙げられる。また、基材はコロナ放電処理などの表面処理によりインク受像層のコーティング性を改善させることもできる。基材の厚みは２５〜４００μｍの範囲が好ましく、プリンタへの装着性や取り扱いを考慮すると５０〜３００μｍが好ましい。基材の厚みが２５μｍ未満では、ハンドリングやプリンタでの装着性が悪いほか、プリンタに装着した記録材がフィードされる際に皺が発生したり等正常に紙送りされないことがある。また、基材が４００μｍを超えるとプリンタへの装着が困難になったり、正常に紙送りされないことがある。 Examples of the base material include synthetic resin films such as polyester, polyolefin, and polyvinyl chloride, and paper such as synthetic paper. Further, the coating property of the ink image-receiving layer can be improved by surface treatment such as corona discharge treatment. The thickness of the substrate is preferably in the range of 25 to 400 [mu] m, and is preferably 50 to 300 [mu] m in consideration of the mountability to the printer and handling. If the thickness of the substrate is less than 25 μm, handling and printer mounting properties are not good, and paper may not be fed normally, such as wrinkles when the recording material mounted on the printer is fed. If the substrate exceeds 400 μm, it may be difficult to mount the printer on the printer or the paper may not be fed normally.
インク受像層の厚みは、５〜５０μｍが好ましく、さらには１０〜３０μｍが好ましいが、これに限定するものではない。上述により得られたインクジェット用記録シートは必要に応じて粘着層を設けることも可能である。 The thickness of the ink image-receiving layer is preferably 5 to 50 μm, more preferably 10 to 30 μm, but is not limited thereto. The ink jet recording sheet obtained as described above can be provided with an adhesive layer as required.
以下に実施例を挙げて本発明を具体的に説明するが、本発明がこれによって限定されるものではない。 EXAMPLES The present invention will be specifically described below with reference to examples, but the present invention is not limited thereto.
基材として帝人デュポンフィルム株式会社製ポリエステルフィルムを使用し、その基材の一方に、乾燥重量比がポリエーテル系ウレタン樹脂（第一工業製薬株式会社 スーパーフレックス６００ 固形分２５％）７２％、アクリル・スチレン共重合樹脂（中央理化工業株式会社 リカボンド FK-８２０ 固形分３９％）２４％、オキサゾリン基を有する水溶性ポリマー（固形分４０％）０.５％、アクリル系の水溶性自己乳化型エポキシ硬化剤として、メタクリル酸・アクリル酸ブチル・メタクリル酸メチル・スチレン共重合物とポリエチレンイミンのグラフト化物の塩化水素中和物（固形分４９％）３.５％となるようにイオン交換水に順次投入し攪拌処理を行なった後、乾燥塗膜が１６μｍとなるようにインク受像層を設けてインクジェット用記録シートを得た。 A polyester film manufactured by Teijin DuPont Films Ltd. is used as a base material. One of the base materials has a dry weight ratio of 72% polyether urethane resin (Daiichi Kogyo Seiyaku Co., Ltd. Superflex 600, solid content 25%), acrylic. -Styrene copolymer resin (Chuo Rika Kogyo Co., Ltd. Rikabond FK-820 solid content 39%) 24%, water-soluble polymer with oxazoline group (solid content 40%) 0.5%, acrylic water-soluble self-emulsifying epoxy As a curing agent, it is gradually added to ion-exchanged water so that the hydrogen chloride neutralized product (solid content 49%) of the grafted product of methacrylic acid / butyl acrylate / methyl methacrylate / styrene copolymer and polyethyleneimine is 3.5%. After stirring and stirring, an ink image-receiving layer is provided so that the dried coating film has a thickness of 16 μm. To obtain a recording sheet.
実施例１で用いたオキサゾリン基を有する水溶性ポリマーの乾燥重量比を１.５％、アクリル系の水溶性自己乳化型エポキシ硬化剤の乾燥重量比を２.５％とした以外は、実施例１と同様にしてインクジェット用記録シートを得た。
(比較例１)
Except that the dry weight ratio of the water-soluble polymer having an oxazoline group used in Example 1 was 1.5% and the dry weight ratio of the acrylic water-soluble self-emulsifying epoxy curing agent was 2.5%, In the same manner as in Example 1, an ink jet recording sheet was obtained.
(Comparative Example 1)
実施例１で用いたオキサゾリン基を有する水溶性ポリマー及びアクリル系の水溶性自己乳化型エポキシ硬化剤を添加しない以外は、実施例１と同様にしてインクジェット用記録シートを得た。
(比較例２)
An ink jet recording sheet was obtained in the same manner as in Example 1 except that the water-soluble polymer having an oxazoline group and the acrylic water-soluble self-emulsifying epoxy curing agent used in Example 1 were not added.
(Comparative Example 2)
実施例１で用いたオキサゾリン基を有する水溶性ポリマーを添加せず、アクリル系の水溶性自己乳化型エポキシ硬化剤を４.０％とした以外は、実施例１と同様にしてインクジェット用記録シートを得た。。
(比較例３)
Inkjet recording sheet in the same manner as in Example 1 except that the water-soluble polymer having an oxazoline group used in Example 1 was not added and the acrylic water-soluble self-emulsifying epoxy curing agent was 4.0%. Got. .
(Comparative Example 3)
実施例１で用いたアクリル系の水溶性自己乳化型エポキシ硬化剤を添加せず、オキサゾリン基を有する水溶性ポリマーを４.０％とした以外は、実施例１と同様にしてインクジェット用記録シートを得た。
(比較例４)
Inkjet recording sheet as in Example 1 except that the acrylic water-soluble self-emulsifying epoxy curing agent used in Example 1 was not added and the water-soluble polymer having an oxazoline group was 4.0%. Got.
(Comparative Example 4)
実施例１で用いたウレタン樹脂を添加しない以外は、実施例１と同様にしてインクジェット用被記録材を得た。
(比較例５)
An inkjet recording material was obtained in the same manner as in Example 1 except that the urethane resin used in Example 1 was not added.
(Comparative Example 5)
実施例１で用いたアクリル樹脂を添加しない以外は、実施例１と同様にしてインクジェット用記録シートを得た。 An ink jet recording sheet was obtained in the same manner as in Example 1 except that the acrylic resin used in Example 1 was not added.
このようにして得られたインクジェット用記録シートを、セイコーエプソン株式会社製、MC-２０００を用いイエロー・マゼンタ・シアン・ブラックの文字およびベタを印字し評価を行った。インク吸収性、乾燥性の評価は、印字後、綿棒で印字部表面を擦り、綿棒に付着したインクの状態を目視で確認した。○：綿棒にインクが付着しない、×：綿棒にインクが付着している。耐水性の評価は、印字物を水に浸漬し３時間放置後、指で擦り受像層の耐水性、インクの定着性を確認した。○：指で擦っても、受像層、インクがとれない、×：指で擦ると受像層及びインクが取れてしまう。発色性の評価は印字部を目視にて確認した。○：印刷画像が鮮明である、×：滲みが生じている The ink jet recording sheet thus obtained was evaluated by printing yellow, magenta, cyan, and black characters and solids using MC-2000 manufactured by Seiko Epson Corporation. The ink absorbability and the drying property were evaluated by rubbing the surface of the printed part with a cotton swab after printing, and visually confirming the state of the ink attached to the cotton swab. ○: Ink does not adhere to the cotton swab, ×: Ink adheres to the cotton swab. The water resistance was evaluated by immersing the printed matter in water and allowing it to stand for 3 hours, and then rubbing with a finger to confirm the water resistance of the image receiving layer and the ink fixing property. ○: Image receiving layer and ink cannot be removed by rubbing with a finger. ×: Image receiving layer and ink are removed by rubbing with a finger. The evaluation of color development was made by visually checking the printed part. ○: The printed image is clear, ×: Bleeding occurs
これらの結果を表１に示す。 These results are shown in Table 1.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003309909A JP4127531B2 (en) | 2003-09-02 | 2003-09-02 | Transparent inkjet recording sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003309909A JP4127531B2 (en) | 2003-09-02 | 2003-09-02 | Transparent inkjet recording sheet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2005074880A true JP2005074880A (en) | 2005-03-24 |
| JP4127531B2 JP4127531B2 (en) | 2008-07-30 |
Family
ID=34411933
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003309909A Expired - Fee Related JP4127531B2 (en) | 2003-09-02 | 2003-09-02 | Transparent inkjet recording sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4127531B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009248356A (en) * | 2008-04-02 | 2009-10-29 | Union Chemicar Co Ltd | Ink-jet receiving layer |
| CN101927632A (en) * | 2009-06-23 | 2010-12-29 | 精工爱普生株式会社 | Recording sheet for inkjet |
| JP2012006242A (en) * | 2010-06-24 | 2012-01-12 | Seiko Epson Corp | Inkjet recording medium |
-
2003
- 2003-09-02 JP JP2003309909A patent/JP4127531B2/en not_active Expired - Fee Related
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009248356A (en) * | 2008-04-02 | 2009-10-29 | Union Chemicar Co Ltd | Ink-jet receiving layer |
| CN101927632A (en) * | 2009-06-23 | 2010-12-29 | 精工爱普生株式会社 | Recording sheet for inkjet |
| EP2266811A1 (en) | 2009-06-23 | 2010-12-29 | Seiko Epson Corporation | Inkjet recording sheet |
| US8337011B2 (en) | 2009-06-23 | 2012-12-25 | Seiko Epson Corporation | Inkjet recording sheet |
| JP2012006242A (en) * | 2010-06-24 | 2012-01-12 | Seiko Epson Corp | Inkjet recording medium |
| US8512827B2 (en) | 2010-06-24 | 2013-08-20 | Seiko Epson Corporation | Ink jet recording medium |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4127531B2 (en) | 2008-07-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| AU6541999A (en) | Transfer media | |
| KR19990067291A (en) | Sheet for Inkjet Printing | |
| JPS6174879A (en) | Ink jet recording sheet | |
| JP2002249165A (en) | Plastic packaging material | |
| JPH10505800A (en) | Inkjet printing sheet | |
| US6455133B1 (en) | Ink imaging sheets | |
| US6911239B2 (en) | Recording material and method | |
| JP4127531B2 (en) | Transparent inkjet recording sheet | |
| JP4827096B2 (en) | Image-receiving layer transfer sheet for inkjet | |
| GB2366749A (en) | Recording material and method | |
| JP2006088341A (en) | Inkjet recording sheet | |
| WO2003097730A2 (en) | Photo album | |
| JPH05278322A (en) | Recording sheet | |
| JP3911177B2 (en) | Inkjet recording material | |
| JPH06247036A (en) | Ink-jet recording paper | |
| JP4527678B2 (en) | Inkjet recording material | |
| JP3112645B2 (en) | Inkjet recording materials | |
| JP2000318296A (en) | Ink jet recording sheet and method for producing the same | |
| JPH04265785A (en) | Ink absorbable mat film | |
| JPH10315614A (en) | Recording sheet | |
| JPH1178220A (en) | Composition for recording body and recording body | |
| JP2000015925A (en) | Resin composition for ink jet recording material and ink jet recording material | |
| JPH09183269A (en) | Inkjet recording sheet | |
| JP2003171585A (en) | Release layer forming ink and sheet using the same | |
| JPH10240439A (en) | Recording medium for producing mouse pad, kit for producing mouse pad including the same, and method for producing mouse pad using the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20060804 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20080125 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20080131 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20080317 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20080508 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20080508 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20110523 Year of fee payment: 3 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 4127531 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120523 Year of fee payment: 4 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130523 Year of fee payment: 5 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313113 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| S533 | Written request for registration of change of name |
Free format text: JAPANESE INTERMEDIATE CODE: R313533 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| LAPS | Cancellation because of no payment of annual fees |