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JP2004330078A - Food pulverization method and food and drink - Google Patents

Food pulverization method and food and drink Download PDF

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Publication number
JP2004330078A
JP2004330078A JP2003129192A JP2003129192A JP2004330078A JP 2004330078 A JP2004330078 A JP 2004330078A JP 2003129192 A JP2003129192 A JP 2003129192A JP 2003129192 A JP2003129192 A JP 2003129192A JP 2004330078 A JP2004330078 A JP 2004330078A
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JP
Japan
Prior art keywords
food
powder
coarse particles
dispersion
pulverizing
Prior art date
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Pending
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JP2003129192A
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Japanese (ja)
Inventor
Toyohiko Doi
豊彦 土井
Hideki Morita
英樹 森田
希人 ▲濱▼谷
Mareto Hamaya
Tatsuya Saeki
達也 佐伯
Takashi Suzuki
隆 鈴木
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SANMARU KIKAI KOGYO KK
Morinaga Milk Industry Co Ltd
Original Assignee
SANMARU KIKAI KOGYO KK
Morinaga Milk Industry Co Ltd
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Priority to JP2003129192A priority Critical patent/JP2004330078A/en
Publication of JP2004330078A publication Critical patent/JP2004330078A/en
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Abstract

【課題】製品の品質に影響なく食品を微粉末に粉砕できる食品の微粉砕方法およびこの微粉砕方法を利用した飲食物を提供する。
【解決手段】粉砕されるべき粗大粒子を分散媒に分散させた分散液を湿式粉砕機に通液して前記粗大粒子を微粉末に粉砕し、前記粗大粒子が食品である食品の微粉砕方法において、前記分散媒に不溶もしくは難溶であり、かつ食品添加物である粉体を前記分散液に添加して前記湿式粉砕機に通液する。この微粉砕方法によれば、食品の粗大粒子を効果的に微粉末とすることができる。また、粉砕工程中に粉体が摩耗、破砕したとしても、粉体が食品添加物であるので、製品中に混入しても食品の品質に直接悪影響がない。
【選択図】 なし
The present invention provides a method of pulverizing a food, which can pulverize the food into fine powder without affecting the quality of the product, and a food and drink using the pulverization method.
A method of finely pulverizing a food in which the coarse particles are food is performed by passing a dispersion obtained by dispersing coarse particles to be pulverized in a dispersion medium through a wet pulverizer to pulverize the coarse particles into fine powder. , A powder which is insoluble or hardly soluble in the dispersion medium and is a food additive is added to the dispersion and passed through the wet pulverizer. According to this pulverization method, coarse particles of food can be effectively turned into fine powder. Further, even if the powder is worn or crushed during the pulverizing step, the powder is a food additive, so that even if the powder is mixed into the product, there is no direct adverse effect on the quality of the food.
[Selection diagram] None

Description

【0001】
【発明の属する技術分野】
本発明は、食品である粗大粒子を湿式にて微粉末に粉砕する食品の微粉砕方法および食品微粉末を含有する飲食物に関する。
【0002】
【従来の技術】
食品の分野においては、食品を粉砕して微粉末に加工することが広く行われている。食品微粉末は、原料の一つとして食料品、飲料品などに配合する場合でも利用しやすい形態である。例えば、ココアや抹茶などの飲料品の用途で液体に分散させたときには、微粉末は沈降しにくく、分散液の安定性が増す(例えば、特許文献1〜3参照)。
また、植物体や、酵母などの菌体などに由来する食品の場合、粉砕により細胞壁が破砕されるので、消化吸収性が改善され、細胞質中のタンパク質やビタミン、ミネラル等を利用しやすくなることから、栄養学的見地からも粉砕処理の重要性は高い(例えば、特許文献4参照)。
【0003】
食品の微粉末の製造は、材料を粗粉砕して粒状、粉状、破片状の粗大粒子とし、さらに粗大粒子を微粉末に粉砕することによって行われている。粗大粒子の粉砕方法としては、粗大粒子を水などの液中に分散させて行う湿式粉砕法と、液体を介在させず、粗大粒子を乾燥状態で粉砕する乾式粉砕法とがあるが、食品微粉末を製造する際には、粉砕時の摩擦熱等による食品の劣損を避けるため、湿式粉砕法が一般的に用いられている。
湿式粉砕法を実施するための湿式粉砕機としては、粉砕されるべき粗大粒子を、粉砕用の媒体とともに水などの分散媒に分散させて撹拌する媒体撹拌ミルが一般的に使用されている。粉砕用の媒体としては、セラミックス、ガラス、鋼などからなるビーズ(ボール、メディアなどということもあるが、本明細書中ではビーズという)が使用される(例えば、特許文献5〜8参照)。
【0004】
【特許文献1】
特開平11−018744号公報
【特許文献2】
特開平11−169079号公報
【特許文献3】
特開平11−318340号公報
【特許文献4】
特開昭63−273468号公報
【特許文献5】
特開平07−088391号公報
【特許文献6】
特開平11−033377号公報
【特許文献7】
特開2000−143707号公報
【特許文献8】
特開2000−237563号公報
【0005】
【発明が解決しようとする課題】
しかしながらビースを用いた湿式粉砕機の場合、粉砕工程中に摩耗したり、クラックなどで損傷したりして、摩耗粉や損傷による剥離片が製品中に混入するおそれがある。食品分野では、異物の混入は、特に製品の品質に直接悪影響を与えることから、製品の品質に影響なく食品を微粉砕できる微粉砕方法の開発が望まれている。
【0006】
本発明は、上記事情に鑑みてなされたものであって、製品の品質に影響なく食品を微粉末に粉砕できる食品の微粉砕方法およびこの微粉砕方法を利用した飲食物を提供することを課題とする。
【0007】
【課題を解決するための手段】
前記課題を解決するため、本発明は、粉砕されるべき粗大粒子を分散媒に分散させた分散液を湿式粉砕機に通液して前記粗大粒子を微粉末に粉砕し、前記粗大粒子が食品である食品の微粉砕方法において、前記分散媒に不溶もしくは難溶であり、かつ食品添加物である粉体を前記分散液に添加して前記湿式粉砕機に通液することを特徴とする食品の微粉砕方法を提供する。
本発明の微粉砕方法によれば、食品の粗大粒子を効果的に微粉末とすることができる。また、粉砕工程中に前記粉体が摩耗、破砕したとしても、該粉体が食品添加物であるので製品中に混入しても品質に直接悪影響がなく、粉砕工程を安定的に実施することができる。
前記湿式粉砕機としては、ホモジナイザーが例示できる。
【0008】
前記粉体の添加量は、前記粗大粒子に対する質量として、0.5倍〜2倍の範囲内であることが好ましい。これにより、粗大粒子を効率的に微粉砕できる。
前記粉体としては、無機質のもの、有機質のもの等、いずれも選択できるが、粉砕効率の点からみて、無機質粉体が好ましい。前記無機質粉体は、カルシウム塩および/またはマグネシウム塩であることが好ましい。この場合、粗大粒子の粉砕工程により、食品中にカルシウム塩やマグネシウム塩を添加できることになり、無機質が強化された食品微粉末を得ることができる。
【0009】
さらに本発明は、上述の食品の微粉砕方法により得られた食品微粉末を含有する飲食物を提供する。このような飲食物によれば、微粉砕により食品が微粉末とされているので、消化吸収性、形態安定性などを改善できる。
【0010】
【発明の実施の形態】
以下、実施の形態に基づいて、本発明を詳しく説明する。
本発明の食品の微粉砕方法は、粉砕されるべき食品の粗大粒子と、分散媒に不溶もしくは難溶の粉体とを、分散媒に分散させて分散液を調製し、得られた分散液を湿式粉砕機に通液して前記粗大粒子を微粉末に粉砕する微粉砕方法である。
【0011】
本発明において、湿式粉砕機によって処理される分散液としては、粉砕されるべき粗大粒子と、食品添加物である粉体とを、前記液状分散液に分散させた分散液を用いる。
分散媒としては、いかなる液体であってもよいが、得られた微粉末を食料品や飲料品などの飲食物に応用することを考慮すれば、水が最も望ましい。ここで「水」とは、温度によって限定されるものではなく、湯であってもよいことはいうまでもない。また、純粋なもの以外に、種々の溶質が溶解された溶解液であってもよく、例えば、水に種々の溶質が溶解された水溶液であってもよい。
【0012】
本発明が適用できる食品としては、動物、植物、菌類に由来する種々の食品があるが、例えば、ココア、抹茶、小豆(あんこ)、黄粉、栗、コーヒー、紅茶、ウーロン茶、緑茶、麦茶、大豆、パン酵母、ビール酵母、清酒酵母、ブドウ酒酵母などが例示できる。
原料となる食品は、分散媒に分散させて湿式粉砕機に通液できる程度の粗大粒子とする必要がある。このため、必要に応じて、粉砕、摩砕などにより、粒子化あるいは粉末化しておくことが好ましい。
【0013】
粉体は、前記分散媒に不溶もしくは難溶であり、かつ食品添加物であるものが用いられる。ここで、不溶もしくは難溶であるとは、粉砕工程に先立って粉体を液状分散液に分散させる際に溶解してしまうことのないことをいう。粉砕工程中、粉体が摩耗もしくは粉砕されたり、損傷したりすることによって、粉体の一部あるいは全部が、分散媒に分散もしくは溶解された状態となることは差し支えない。
本発明において、粉体は、食品添加物として認可されたものが用いられる。食品添加物であるから、セラミックスなどのように極めて高硬度のものは得がたいが、粉砕工程中に摩耗もしくは粉砕したり、損傷したりして、摩耗粉などが製品中に混入したとしても、製品の品質に直接悪影響を与えるおそれがない。
【0014】
上記粉体の具体例としては、炭酸カルシウム、硫酸カルシウム、リン酸カルシウムなどのカルシウム塩、炭酸マグネシウムなどのマグネシウム塩、ドロマイト(炭酸カルシウムマグネシウム)などのカルシウムとマグネシウムとを含有する塩類などが例示できる。もちろん、ミルクカルシウム、牛骨カルシウム、卵殻カルシウム、真珠貝、真珠末、牡蛎殻、ホタテ貝殻、サンゴ末、魚骨粉など、上記カルシウム塩を主成分とする動物由来の材料を用いることも好ましい。
粉体の添加量としては、特に限定されるものではないが、好ましくは食品の粗大粒子に対する質量として、0.5倍〜2倍の範囲内とするのが好ましい。この範囲であると、粉体と食品の粗大粒子とがほどよく混合し、粉体による食品の粉砕効率が高いものとなる。
【0015】
食品の粗大粒子と粉体とを分散媒中に分散させる工程は、特に限定はなく、連続式でもバッチ式でもよい。例えばバッチ式であれば、まず、所定量の分散媒と食品の粗大粒子と粉体とをタンクに投入して十分に撹拌し、その後、後述の湿式粉砕機に通液する様態が例示できる。また、連続式であれば、所定の流量にて分散媒を流路に流しながら、所定量の食品の粗大粒子と粉体とを連続的に分散媒に混入し、そのまま連続的に湿式粉砕機に通液する様態が例示できる。食品の粗大粒子と粉体との混入および分散の順序は、特に限定はなく、両者を一緒に分散媒に混入して分散させてもよいし、食品の粗大粒子を分散させてから粉体を混入して分散させてもよい。また、粉体を分散させてから食品の粗大粒子を混入して分散させてもよい。要は、食品の粗大粒子と粉体とが分散媒に分散されて、湿式粉砕機に通液できる状態になっていればよい。
【0016】
湿式粉砕機としては、公知の湿式粉砕方法により、上記分散液を処理して分散液中の粗大粒子を粉砕でできるものではあればよく、ホモジナイザーや媒体分散機、媒体撹拌ミルなどが例示される。
分散液を湿式粉砕機に通液して粉砕処理を行う方法としては、後述するように、それぞれの湿式粉砕機に応じた周知の方法を用いればよい。
【0017】
例えば、ホモジナイザー(均質機ともいう)の場合(例えば、酪農技術普及学会発行、乳業機械工学便覧 上巻(1974年)を参照)、高圧ポンプによって液状物に高圧をかけた状態で均質バルブに通し、低圧部に流れる際に、せん断や衝撃、あるいはキャビテーションや爆発的作用によって液状物中の粒子が粉砕されるものである。処理圧力としては、100〜170kgf/cm程度が普通である。
【0018】
媒体分散機は、例えば本発明の出願人による特開平11−18744号公報に記載された公知の装置である。この媒体分散機は、一端に供給口を有し、他端に排出口を有する処理槽と、該処理槽の内壁に近接して処理槽内に収容され、供給口側から排出口側に延在して配置された筒状の回転体とを備えている。処理槽の内壁と回転体の外周面との間に、供給口から排出口に至る分散液の流路が設けられている。回転体の外周面には、処理槽の内壁と回転体の外周面との間隔をなるべく狭くするように、食品の流れを案内するための案内面を有する凹凸が形成されている。
供給口から処理槽内に通液された分散液は、処理層内で、供給口側と排出口側とを結ぶ軸を回転軸として回転する回転体により、流れを撹乱されながら衝撃力や運動力を与えられ、粉砕されて排出口から排出される。
【0019】
上述のようにして、食品の粗大粒子と粉体を含む分散液を湿式粉砕機食品に通液することにより、食品を微粉末に粉砕することができる。
微粉末の平均粒径は、食品の種類や目的によっても異なるが、例えば、ココアの場合、好ましくは平均粒径が15μm以下、より好ましくは平均粒径が10μm以下である。また、抹茶の場合、好ましくは平均粒径が10μm以下、より好ましくは平均粒径が5μm以下である。
一回の通液処理で食品粒子の平均粒径が望ましい範囲に達しない場合、十分に細かく粉砕されるまで、湿式粉砕機への通液処理を繰り返してよい。本発明の場合、湿式粉砕機に通液される分散液に、上述の粉体が混入されているので、個々の通液処理を繰り返す場合にも、繰り返し回数を従来よりも少なくすることができ、粉砕処理に要する時間や費用を低減させることができるのである。
【0020】
上述の食品の微粉砕方法により得られた食品微粉末は、飲食物に配合することができる。本発明でいう飲食物とは、人または家畜などの動物が経口摂取する加工製品を意味し、飲料品、食料品のほか、医薬品、ペットフード、飼料なども、本発明の飲食物の範囲に包含される。
具体的には、例えば、ビスケット、クッキー、チョコレート、キャラメル、アイスクリーム、キャンディー、ハンバーグ、ハム、ソーセージ、スープ、ソース、マスタード、豆腐などの食料品、乳飲料、小豆飲料、黄粉飲料、栗飲料、ココア飲料、緑茶飲料などの飲料品、錠剤、散剤、ゼリー剤等の形態で経口投与される医薬品が例示される。
【0021】
上記粉砕方法によって得られた食品微粉末を飲食物に配合する際、液状分散媒に分散させたまま添加してもよい。また、ふるいや遠心分離機などを用いて分散液から食品の微粉末を分離し、得られたパウダーを飲食物に添加するようにしてもよい。
このような飲食物によれば、微粉砕により食品が微粉末とされているので、消化吸収性、形態安定性などを改善できる。
【0022】
【実施例】
市販のパン酵母と、ミルクカルシウムとを水道水と混合して、分散液を調製した。ミルクカルシウムとしては、ニュージーランド国デイリーボード社製、商品名「アラミン」を用いた。
それぞれの分散液について、粉砕されるべき食品の粗大粒子であるパン酵母は0.5kg、分散媒である水道水は10リットル用いた。
粉体であるミルクカルシウムの添加量は、0kg(比較例),0.25kg,0.5kg,0.75kg,1.0kgの5とおりとした。
【0023】
各分散液を通常のホモジナイザー(三丸機械工業製)に均質化処理させることにより、パン酵母の微粉砕を行った。このホモジナイザーは、ホッパーから供給された分散液を、均質バルブに流入させる装置であり、ホモジナイザーから流出した処理液は、該処理液の温度が上昇しないように冷水により冷却されている蛇管を通って、再度ホッパーに戻され、ホモジナイザーを複数回循環できるようになっている。
ホモジナイザーの処理圧力は50MPaとし、処理流量は200リットル/時間とした。粉砕処理の一回の処理時間は約3分間である。
【0024】
粉砕の効率を測定するため、粉砕処理後の処理液の一部をサンプリングした。サンプリングされた処理液は、サンプリング後、直ちに氷水で冷却した。
粉砕効率は、サンプリングした処理液を市販のペトリフィルム(3M社製)上で、温度を20〜30℃に保って3日間培養した後、発生したコロニーの個数をカウントすることで算出した。すなわち、発生したコロニー数を生酵母菌体数とみなして酵母の生存率を得た。
【0025】
図1に、処理圧力50MPaにおけるホモジナイザーの処理回数と、酵母の生存率との関係の一例を示す。図1において、(A−1)は、ミルクカルシウムの添加量が0の場合である。(A−2)は、ミルクカルシウムの添加量が0.25kgの場合である。(A−3)は、ミルクカルシウムの添加量が0.5kgの場合である。(A−4)は、ミルクカルシウムの添加量が0.75kgの場合である。(A−5)は、ミルクカルシウムの添加量が1kgの場合である。
図1に示す結果から、ミルクカルシウムを添加しない場合に比べ、ミルクカルシウムを添加した場合では、より少ない処理回数で酵母を破砕し、生存率を大幅に減少させることができたことが分かる。この結果は、ミルクカルシウムを添加したことによる摩砕の効果が加わったためと考えられる。
【0026】
ミルクカルシウムの添加量ごとに、図1に示す処理回数に対する生存率の関係を直線に当てはめ、生存率の減少を示す直線の傾き(生存率の傾き)を算出した。図2に、ミルクカルシウムの添加量と生存率の傾きとの関係の一例を示すグラフを示す。図2に示すように、ミルクカルシウムの添加量が0.5kgの場合に、傾きの絶対値が最大となり、生存率の減少率が最も高いことが分かる。
また、ミルクカルシウムの添加量が0.25〜0.75kgである範囲であれば、より好適であるといえるが、この範囲は、酵母に対する質量としては0.5〜2倍の範囲内に相当し、水道水に対する質量比としては2.5〜7.5質量%に相当し、分散液全体に占める割合としては、2.3〜6.7質量%の範囲に相当することになる。
【0027】
ミルクカルシウムの添加量をx、生存率の傾きをyとすると、下記式(1)が成り立つ。式(1)において、m=0.168であり、l=−0.179である。また、exp()は、eを自然対数の底とするとき、exp(t)≡eを表す。
【0028】
y = 4.46×10−4 exp(x/m)+0.222 exp(x/l)−0.325 ………(1)
【0029】
次に、市販のパン酵母と、ミルクカルシウム(上記「アラミン」)とを水道水と混合してなる分散液を、パン酵母およびミルクカルシウムの添加量を変えて4種類調製し、上記ホモジナイザーを用いて粉砕処理を行い、ホモジナイザー処理を行うごとに、得られた処理液(懸濁液)の濃度(個/ml)、処理液の粘度(mPa・s)、および粉砕後の食品の微粉末の平均粒径(μm)を測定した。
ここで、「処理液の濃度」とは、処理液中の粒子の単位体積あたりの個数であり、粒子の粒度分布から算出した。
【0030】
測定結果を図3および図4に示す。図3,図4において、(B−1)は、パン酵母の添加量を0.5kg,ミルクカルシウムの添加量を0とした場合を示す。(B−2)は、パン酵母の添加量を1kg,ミルクカルシウムの添加量を0.5kgとした場合を示す。(B−3)は、パン酵母の添加量を0.5kg,ミルクカルシウムの添加量を0.25kgとした場合を示す。(B−4)は、パン酵母の添加量を1kg,ミルクカルシウムの添加量を1kgとした場合を示す。
【0031】
図3に示すように、処理液の濃度と、粉砕後の食品の微粉末の平均粒径の逆数とは、ほぼ良好な直線関係を示した。このことから、処理液の濃度が上昇するほど、平均粒径の逆数が増加し、平均粒径が小さくなっていることが分かる。
また、図4に示すように、処理液の濃度と、処理液の粘度とは、ほぼ良好な直線関係を示した。このことから、処理液の濃度が上昇するほど、処理液の粘度が増加していることが分かる。
【0032】
図3に示す処理液の濃度と平均粒径の逆数との関係を直線に当てはめ、この傾きTとする。また、図4に示す処理液の濃度と処理液の粘度との関係を直線に当てはめ、この傾きをTηとする。
このとき、図1に示す生存率の傾きをyとすると、aを定数として、下記式(2)が成立する。また、式(2)において、m,lは、式(1)で用いたものに等しい定数である。
【0033】
y = a×T /Tη ………… (2)
【0034】
このように、粉砕処理を行うにあたっては、事前実験を行って粉砕処理による処理液の物性を測定し、粉体自体の粉砕による処理液の粘度の上昇による粉砕効果の減少を評価しておくことが好ましい。これにより、粉体の適切な添加量を決定することができる。
なお、本実施例で説明した評価方法は、粉砕すべき粗大粒子が酵母である場合に限定されるものではなく、また、粉体がミルクカルシウムである場合に限定されるものではない。他の種類の食品の粗大粒子や、粉体を用いた場合にも、同様の方法が適用可能であることはいうまでもない。
【0035】
【発明の効果】
以上説明したように、本発明の食品の微粉砕方法によれば、食品の粗大粒子を効果的に微粉末とすることができる。また、粉砕工程中に粉体が摩耗、破砕したとしても、粉体が食品添加物であるので、製品中に混入しても食品の品質に直接悪影響がない。
特に、粉体がカルシウム塩および/またはマグネシウム塩である場合、粉砕工程により、食品中にカルシウム塩やマグネシウム塩を効率的に添加することができることになり、無機質が強化された食品微粉末を得ることができる。
【図面の簡単な説明】
【図1】粉砕処理の処理回数と、酵母の生存率(生存率)との関係の一例を示すグラフである。
【図2】粉体の添加量を横軸におき、図1の処理回数と生存率との関係を直線に当てはめた傾きを縦軸においたグラフである。
【図3】粉砕処理による処理液の濃度と、粉砕後の食品の微粉末の平均粒径との関係の一例を示すグラフである。
【図4】粉砕処理による処理液の濃度と、処理液の粘度との関係の一例を示すグラフである。
[0001]
TECHNICAL FIELD OF THE INVENTION
TECHNICAL FIELD The present invention relates to a method of finely pulverizing food, which is a method of pulverizing coarse particles, which are food, into fine powder by a wet method, and a food and drink containing the fine food powder.
[0002]
[Prior art]
In the field of foods, it is widely practiced to grind foods and process them into fine powders. Food fine powder is in a form that can be easily used even when it is blended into foods, beverages, and the like as one of the raw materials. For example, when dispersed in a liquid for use in beverages such as cocoa and matcha, the fine powder is less likely to settle and the stability of the dispersion is increased (for example, see Patent Documents 1 to 3).
In addition, in the case of foods derived from plants, fungi such as yeast, cell walls are crushed by pulverization, so that digestibility is improved, and proteins, vitamins, minerals, and the like in the cytoplasm are easily used. Therefore, the importance of the grinding treatment is high from a nutritional point of view (for example, see Patent Document 4).
[0003]
The production of fine powder of food is performed by coarsely pulverizing the material into coarse particles such as granules, powders, and fragments, and then pulverizing the coarse particles into fine powder. As a method for grinding coarse particles, there are a wet grinding method in which the coarse particles are dispersed in a liquid such as water, and a dry grinding method in which the coarse particles are crushed in a dry state without intervening liquid. In producing powder, a wet pulverization method is generally used in order to avoid inferior deterioration of food due to frictional heat during pulverization.
As a wet pulverizer for performing a wet pulverization method, a medium stirring mill that disperses coarse particles to be pulverized together with a pulverizing medium in a dispersion medium such as water and stirs them is generally used. As a pulverizing medium, beads made of ceramics, glass, steel or the like (sometimes referred to as balls and media, but referred to as beads in the present specification) are used (for example, see Patent Documents 5 to 8).
[0004]
[Patent Document 1]
JP-A-11-018744 [Patent Document 2]
JP-A-11-169079 [Patent Document 3]
JP-A-11-318340 [Patent Document 4]
JP-A-63-273468 [Patent Document 5]
Japanese Patent Application Laid-Open No. 07-088391 [Patent Document 6]
JP-A-11-033377 [Patent Document 7]
JP 2000-143707 A [Patent Document 8]
JP 2000-237563 A
[Problems to be solved by the invention]
However, in the case of a wet pulverizer using a bead, there is a possibility that abrasion powder or a peeled piece due to damage may be mixed into a product due to abrasion during a pulverization process or damage due to a crack or the like. In the field of foods, the incorporation of foreign matter has a direct adverse effect on the quality of products in particular. Therefore, it is desired to develop a pulverization method capable of pulverizing food without affecting the quality of products.
[0006]
The present invention has been made in view of the above circumstances, and it is an object of the present invention to provide a method of finely pulverizing food, which can pulverize food into fine powder without affecting the quality of the product, and to provide food and drink using the finely pulverizing method. And
[0007]
[Means for Solving the Problems]
In order to solve the above-mentioned problem, the present invention provides a method in which a dispersion obtained by dispersing coarse particles to be ground in a dispersion medium is passed through a wet pulverizer to pulverize the coarse particles into fine powder, and the coarse particles are used as food. In the method of finely pulverizing food, the food is insoluble or hardly soluble in the dispersion medium, and a powder as a food additive is added to the dispersion and passed through the wet pulverizer. To provide a method of pulverizing.
According to the fine pulverization method of the present invention, coarse particles of food can be effectively turned into fine powder. Further, even if the powder is worn or crushed during the pulverizing process, the powder is a food additive, so that even if the powder is mixed into the product, the quality is not directly adversely affected, and the pulverizing process is stably performed. Can be.
As the wet pulverizer, a homogenizer can be exemplified.
[0008]
The amount of the powder added is preferably in the range of 0.5 times to 2 times the mass of the coarse particles. Thereby, the coarse particles can be finely pulverized efficiently.
As the powder, any of inorganic powder and organic powder can be selected, but from the viewpoint of pulverization efficiency, inorganic powder is preferable. Preferably, the inorganic powder is a calcium salt and / or a magnesium salt. In this case, a calcium salt or a magnesium salt can be added to the food by the step of pulverizing the coarse particles, so that a fine food powder with enhanced inorganic properties can be obtained.
[0009]
Further, the present invention provides a food or drink containing the fine food powder obtained by the above-mentioned method for finely pulverizing food. According to such foods and drinks, since the food is made into fine powder by pulverization, it is possible to improve digestive absorption, form stability, and the like.
[0010]
BEST MODE FOR CARRYING OUT THE INVENTION
Hereinafter, the present invention will be described in detail based on embodiments.
The method of finely pulverizing food of the present invention is a method of preparing a dispersion by dispersing coarse particles of food to be pulverized and powder insoluble or hardly soluble in a dispersion medium in a dispersion medium to obtain a dispersion. Is passed through a wet pulverizer to pulverize the coarse particles into fine powder.
[0011]
In the present invention, a dispersion obtained by dispersing coarse particles to be pulverized and powder as a food additive in the liquid dispersion is used as the dispersion to be treated by the wet pulverizer.
The dispersion medium may be any liquid, but water is the most desirable in consideration of applying the obtained fine powder to foods and drinks such as foods and beverages. Here, "water" is not limited by temperature, but may be hot water. In addition to the pure solution, a solution in which various solutes are dissolved may be used. For example, an aqueous solution in which various solutes are dissolved in water may be used.
[0012]
Examples of the food to which the present invention can be applied include various foods derived from animals, plants, and fungi. For example, cocoa, matcha, red beans (anko), yellow powder, chestnut, coffee, black tea, oolong tea, green tea, barley tea, and soybean , Baker's yeast, beer yeast, sake yeast, wine yeast and the like.
It is necessary to disperse the food material as a raw material into coarse particles that can be dispersed in a dispersion medium and passed through a wet pulverizer. For this reason, it is preferable to form particles or powder by pulverization, grinding or the like as necessary.
[0013]
As the powder, one that is insoluble or hardly soluble in the dispersion medium and that is a food additive is used. Here, “insoluble or hardly soluble” means that the powder is not dissolved when the powder is dispersed in the liquid dispersion prior to the pulverizing step. During the pulverization process, a part or all of the powder may be dispersed or dissolved in the dispersion medium by abrasion, pulverization, or damage of the powder.
In the present invention, a powder approved as a food additive is used. Because it is a food additive, it is difficult to obtain extremely hard materials such as ceramics.However, even if abrasion powder is mixed into the product due to abrasion, crushing, or damage during the crushing process, There is no direct risk of adversely affecting the quality of the product.
[0014]
Specific examples of the powder include calcium salts such as calcium carbonate, calcium sulfate and calcium phosphate, magnesium salts such as magnesium carbonate, and salts containing calcium and magnesium such as dolomite (calcium magnesium carbonate). Of course, it is also preferable to use an animal-derived material containing the above calcium salt as a main component, such as milk calcium, cow bone calcium, eggshell calcium, pearl shell, pearl powder, oyster shell, scallop shell, coral powder, and fish bone powder.
The amount of the powder to be added is not particularly limited, but is preferably in the range of 0.5 times to 2 times the mass of the coarse particles of the food. Within this range, the powder and the coarse particles of the food are mixed satisfactorily, and the efficiency of pulverizing the food by the powder is high.
[0015]
The step of dispersing the coarse particles and the powder of the food in the dispersion medium is not particularly limited, and may be a continuous type or a batch type. For example, in the case of a batch system, a mode in which a predetermined amount of a dispersion medium, coarse particles of food, and powder are first charged into a tank, sufficiently stirred, and then passed through a wet pulverizer described later can be exemplified. In the case of a continuous type, a predetermined amount of food coarse particles and powder are continuously mixed into the dispersion medium while flowing the dispersion medium through the flow path at a predetermined flow rate. Can be exemplified. The order of mixing and dispersing the coarse particles of the food and the powder is not particularly limited, and both may be mixed and dispersed together in a dispersion medium, or the powder may be dispersed after dispersing the coarse particles of the food. They may be mixed and dispersed. Further, after the powder is dispersed, coarse particles of food may be mixed and dispersed. In short, it is only necessary that the coarse particles and the powder of the food are dispersed in the dispersion medium so that the food can pass through the wet pulverizer.
[0016]
The wet pulverizer may be any one capable of treating the above-mentioned dispersion liquid and pulverizing coarse particles in the dispersion liquid by a known wet pulverization method, and examples thereof include a homogenizer, a medium disperser, and a medium stirring mill. .
As a method of performing the pulverizing treatment by passing the dispersion through a wet pulverizer, a well-known method corresponding to each wet pulverizer may be used as described later.
[0017]
For example, in the case of a homogenizer (also referred to as a homogenizer) (for example, see the Dairy Technology Promotion Association, see Dairy Machinery Engineering Handbook, Volume 1974), a high-pressure pump is used to apply high pressure to a liquid material and pass through a homogenous valve. When flowing into the low-pressure part, particles in the liquid material are crushed by shearing, impact, cavitation or explosive action. The processing pressure is usually about 100 to 170 kgf / cm 2 .
[0018]
The medium dispersing machine is, for example, a known device described in Japanese Patent Application Laid-Open No. 11-18744 by the present applicant. The medium dispersing machine has a processing tank having a supply port at one end and a discharge port at the other end, and is housed in the processing tank near the inner wall of the processing tank, and extends from the supply port side to the discharge port side. And a cylindrical rotating body that is arranged and disposed. A flow path of the dispersion from the supply port to the discharge port is provided between the inner wall of the processing tank and the outer peripheral surface of the rotating body. Irregularities having a guide surface for guiding the flow of food are formed on the outer peripheral surface of the rotating body so as to minimize the distance between the inner wall of the processing tank and the outer peripheral surface of the rotating body.
The dispersion liquid passed from the supply port into the processing tank is subjected to impact force and motion while the flow is disturbed by the rotating body that rotates around the axis connecting the supply port side and the discharge port side in the processing layer. It is emulsified and crushed and discharged from the outlet.
[0019]
As described above, the food can be pulverized into fine powder by passing the dispersion containing the coarse particles and the powder of the food through the wet pulverizer food.
The average particle size of the fine powder varies depending on the type and purpose of the food. For example, in the case of cocoa, the average particle size is preferably 15 μm or less, more preferably 10 μm or less. In the case of matcha, the average particle size is preferably 10 μm or less, more preferably 5 μm or less.
If the average particle size of the food particles does not reach the desired range in one pass-through treatment, the passage through the wet-type pulverizer may be repeated until the food particles are sufficiently pulverized. In the case of the present invention, since the above-mentioned powder is mixed in the dispersion liquid passed through the wet mill, the number of times of repetition can be reduced as compared with the conventional case even when individual liquid passing processing is repeated. In addition, the time and cost required for the pulverizing process can be reduced.
[0020]
The food fine powder obtained by the above-mentioned method of finely pulverizing food can be blended into food and drink. Foods and drinks as referred to in the present invention mean processed products that are orally ingested by animals such as humans and livestock.In addition to drinks and foods, pharmaceuticals, pet foods, feeds, and the like are also included in the scope of the foods and drinks of the present invention. Included.
Specifically, for example, biscuits, cookies, chocolate, caramel, ice cream, candies, hamburgers, ham, sausage, soups, sauces, mustard, food products such as tofu, milk drinks, red bean drinks, yellow powder drinks, chestnut drinks, Drugs orally administered in the form of beverages such as cocoa beverages and green tea beverages, tablets, powders, jellies and the like are exemplified.
[0021]
When blending the food fine powder obtained by the above-mentioned pulverization method into food or drink, it may be added while being dispersed in a liquid dispersion medium. Alternatively, fine powder of food may be separated from the dispersion using a sieve or a centrifuge, and the resulting powder may be added to food or drink.
According to such foods and drinks, since the food is made into fine powder by pulverization, it is possible to improve digestive absorption, form stability, and the like.
[0022]
【Example】
Commercially available baker's yeast and milk calcium were mixed with tap water to prepare a dispersion. As milk calcium, "Alamine" (trade name, manufactured by Daily Board, New Zealand) was used.
For each dispersion, 0.5 kg of baker's yeast as coarse particles of food to be ground and 10 liters of tap water as a dispersion medium were used.
The amount of the powdered milk calcium added was 0 kg (comparative example), 0.25 kg, 0.5 kg, 0.75 kg, and 1.0 kg.
[0023]
Each of the dispersions was homogenized in a normal homogenizer (manufactured by Sanmaru Kikai Co., Ltd.) to pulverize the baker's yeast. This homogenizer is a device that allows the dispersion liquid supplied from the hopper to flow into a homogeneous valve, and the processing liquid flowing out of the homogenizer passes through a flexible tube cooled by cold water so that the temperature of the processing liquid does not increase. Is returned to the hopper again so that the homogenizer can be circulated a plurality of times.
The processing pressure of the homogenizer was 50 MPa, and the processing flow rate was 200 liter / hour. One processing time of the pulverizing process is about 3 minutes.
[0024]
In order to measure the efficiency of the pulverization, a part of the processing solution after the pulverization was sampled. The sampled solution was cooled with ice water immediately after sampling.
The crushing efficiency was calculated by counting the number of generated colonies after culturing the sampled treatment liquid on a commercially available Petri film (manufactured by 3M) at a temperature of 20 to 30 ° C. for 3 days. That is, the viability of yeast was obtained by regarding the number of generated colonies as the number of viable yeast cells.
[0025]
FIG. 1 shows an example of the relationship between the number of treatments of the homogenizer at a treatment pressure of 50 MPa and the survival rate of the yeast. In FIG. 1, (A-1) is a case where the addition amount of milk calcium is 0. (A-2) is the case where the addition amount of milk calcium is 0.25 kg. (A-3) is a case where the addition amount of milk calcium is 0.5 kg. (A-4) is the case where the addition amount of milk calcium is 0.75 kg. (A-5) is a case where the added amount of milk calcium is 1 kg.
From the results shown in FIG. 1, it can be seen that, when milk calcium was added, the yeast was crushed with a smaller number of treatments and the viability was significantly reduced as compared with the case where milk calcium was not added. This result is considered to be due to the addition of the milling effect due to the addition of milk calcium.
[0026]
The relationship between the number of treatments and the survival rate shown in FIG. 1 was fitted to a straight line for each addition amount of milk calcium, and the slope of the straight line indicating the decrease in the survival rate (the slope of the survival rate) was calculated. FIG. 2 is a graph showing an example of the relationship between the amount of added milk calcium and the gradient of the survival rate. As shown in FIG. 2, when the amount of added milk calcium is 0.5 kg, the absolute value of the slope becomes maximum, and it can be seen that the rate of decrease in the survival rate is the highest.
In addition, it is more preferable that the amount of milk calcium added is in the range of 0.25 to 0.75 kg, but this range is equivalent to the range of 0.5 to 2 times as much as the mass of yeast. Then, the mass ratio to tap water is equivalent to 2.5 to 7.5 mass%, and the ratio to the whole dispersion is equivalent to the range of 2.3 to 6.7 mass%.
[0027]
Assuming that the added amount of milk calcium is x and the slope of the survival rate is y, the following equation (1) holds. In the equation (1), m = 0.168 and 1 = −0.179. Also, exp (), when the base of the natural logarithm e, representing the exp (t) ≡e t.
[0028]
y = 4.46 × 10 −4 exp (x / m) +0.222 exp (x / l) −0.325 (1)
[0029]
Next, four types of dispersions prepared by mixing commercially available baker's yeast and milk calcium (the above-mentioned “alamine”) with tap water were prepared by changing the amounts of the baker's yeast and milk calcium, and the homogenizer was used. Each time the homogenizer treatment is performed, the concentration (pieces / ml) of the obtained treatment liquid (suspension), the viscosity (mPa · s) of the treatment liquid, and the fine powder The average particle size (μm) was measured.
Here, the “concentration of the processing solution” is the number of particles in the processing solution per unit volume, and was calculated from the particle size distribution of the particles.
[0030]
The measurement results are shown in FIGS. 3 and 4, (B-1) shows the case where the addition amount of baker's yeast was 0.5 kg and the addition amount of milk calcium was 0. (B-2) shows the case where the addition amount of baker's yeast was 1 kg and the addition amount of milk calcium was 0.5 kg. (B-3) shows the case where the addition amount of baker's yeast was 0.5 kg and the addition amount of milk calcium was 0.25 kg. (B-4) shows the case where the addition amount of baker's yeast was 1 kg and the addition amount of milk calcium was 1 kg.
[0031]
As shown in FIG. 3, the concentration of the treatment liquid and the reciprocal of the average particle size of the fine powder of the pulverized food showed a substantially good linear relationship. This indicates that the reciprocal of the average particle diameter increases and the average particle diameter decreases as the concentration of the processing liquid increases.
In addition, as shown in FIG. 4, the concentration of the processing liquid and the viscosity of the processing liquid showed a substantially good linear relationship. This indicates that the viscosity of the processing liquid increases as the concentration of the processing liquid increases.
[0032]
Fitting a straight line the relationship between the concentration of the treatment liquid shown in FIG. 3 the reciprocal of the average particle diameter, and the inclination T c. Further, the relationship between the concentration of the processing liquid and the viscosity of the processing liquid shown in FIG. 4 is fitted to a straight line, and this slope is defined as T η .
At this time, assuming that the gradient of the survival rate shown in FIG. 1 is y, the following equation (2) is established with a being a constant. In the equation (2), m and l are constants equal to those used in the equation (1).
[0033]
y = a × T c m / T η l ............ (2)
[0034]
As described above, in performing the pulverization treatment, the physical properties of the treatment liquid by the pulverization treatment should be measured by performing preliminary experiments, and the decrease in the pulverization effect due to the increase in the viscosity of the treatment liquid due to the pulverization of the powder itself should be evaluated. Is preferred. Thereby, an appropriate amount of powder to be added can be determined.
The evaluation method described in this example is not limited to the case where the coarse particles to be pulverized are yeast, and is not limited to the case where the powder is milk calcium. It goes without saying that the same method can be applied to the case where coarse particles or powders of other types of food are used.
[0035]
【The invention's effect】
As described above, according to the method of finely pulverizing food of the present invention, coarse particles of food can be effectively turned into fine powder. Further, even if the powder is worn or crushed during the pulverizing process, the powder is a food additive, so that even if the powder is mixed into the product, there is no direct adverse effect on the quality of the food.
In particular, when the powder is a calcium salt and / or a magnesium salt, the calcium salt and the magnesium salt can be efficiently added to the food by the pulverization step, and a fine food powder with enhanced inorganics can be obtained. be able to.
[Brief description of the drawings]
FIG. 1 is a graph showing an example of the relationship between the number of times of pulverization and the survival rate (survival rate) of yeast.
FIG. 2 is a graph in which the horizontal axis represents the amount of powder added, and the vertical axis represents the slope obtained by fitting the relationship between the number of treatments and the survival rate in FIG. 1 to a straight line.
FIG. 3 is a graph showing an example of the relationship between the concentration of a processing solution obtained by a pulverization process and the average particle size of fine powder of a pulverized food.
FIG. 4 is a graph showing an example of a relationship between a concentration of a processing liquid by a pulverizing process and a viscosity of the processing liquid.

Claims (5)

粉砕されるべき粗大粒子を分散媒に分散させた分散液を湿式粉砕機に通液して前記粗大粒子を微粉末に粉砕し、前記粗大粒子が食品である食品の微粉砕方法において、
前記分散媒に不溶もしくは難溶であり、かつ食品添加物である粉体を前記分散液に添加して前記湿式粉砕機に通液することを特徴とする食品の微粉砕方法。
In a method of finely pulverizing a food, wherein the coarse particles are crushed into fine powder by passing a dispersion obtained by dispersing coarse particles to be crushed in a dispersion medium into a wet crusher, wherein the coarse particles are food.
A method of finely pulverizing food, comprising adding a powder which is insoluble or hardly soluble in the dispersion medium and is a food additive to the dispersion and passing the powder through the wet pulverizer.
前記湿式粉砕機が、ホモジナイザーであることを特徴とする請求項1に記載の食品の微粉砕方法。The method according to claim 1, wherein the wet mill is a homogenizer. 前記粉体の添加量が、前記粗大粒子に対する質量として、0.5倍〜2倍の範囲内であることを特徴とする請求項1または2に記載の食品の微粉砕方法。3. The method according to claim 1, wherein the amount of the powder added is 0.5 to 2 times the mass of the coarse particles. 4. 前記粉体が、カルシウム塩および/またはマグネシウム塩であることを特徴とする請求項1ないし3のいずれかに記載の食品の微粉砕方法。The method according to any one of claims 1 to 3, wherein the powder is a calcium salt and / or a magnesium salt. 請求項1ないし3のいずれかに記載の食品の微粉砕方法により得られた食品微粉末を含有することを特徴とする飲食物。A food or drink comprising a fine food powder obtained by the method for finely pulverizing food according to any one of claims 1 to 3.
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JP2022117892A (en) * 2021-02-01 2022-08-12 森永製菓株式会社 Beverage and its manufacturing method

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WO2008126797A1 (en) 2007-04-06 2008-10-23 Activus Pharma Co., Ltd. Method for producing pulverized organic compound particle
US8226983B2 (en) 2007-04-06 2012-07-24 Activus Pharma Co., Ltd. Method for producing pulverized organic compound particle
EP2679219A1 (en) 2007-04-06 2014-01-01 Activus Pharma Co., Ltd. Method for producing finely pulverized organic compound particle
JP2022117892A (en) * 2021-02-01 2022-08-12 森永製菓株式会社 Beverage and its manufacturing method

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