JP2004115968A - Easy-cleaning antifouling agent composition for clothing - Google Patents
Easy-cleaning antifouling agent composition for clothing Download PDFInfo
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Abstract
【課題】衣料等の繊維製品に優れた防汚性を付与し、しかも汚れが付着しても洗濯で容易に除去できる易洗性を有する易洗防汚処理剤組成物を提供する。
【解決手段】炭素数12〜26の炭化水素基を1つと炭素数1〜3の炭化水素基を2つ有するアミンオキシド化合物、及び水を含有する衣料用易洗防汚処理剤組成物。上記組成物を対象衣料に接触後乾燥させる。乾燥としては、アイロンによる加熱乾燥が良好。
【効果】洗濯後の汚れ除去性に優れる。
【選択図】 なしThe present invention provides an easy-fouling antifouling treatment composition which imparts excellent antifouling properties to textiles such as clothing and has easy-to-wash properties that can be easily removed by washing even if dirt adheres.
The composition comprises an amine oxide compound having one hydrocarbon group having 12 to 26 carbon atoms and two hydrocarbon groups having 1 to 3 carbon atoms, and water, which is an easily washable and stain-proofing agent composition for clothing. The composition is dried after contact with the target clothing. As for drying, heat drying with an iron is good.
[Effect] Excellent in dirt removal after washing.
[Selection diagram] None
Description
【0001】
【発明の属する技術分野】
本発明は衣料用易洗防汚処理剤組成物及び衣料の処理方法に関する。
【0002】
【従来の技術及び発明が解決しようとする課題】
衣料の洗浄は一般に弱アルカリ性洗剤を用いて洗濯機で洗浄することが一般的である。しかしながら、衿や袖口の皮脂に由来する汚れや、靴下に付着した泥汚れなどは非常に頑固な汚れであり、通常の洗濯では満足できるレベルまで洗浄することは難しい。
【0003】
これを解決する方法として、洗濯後の繊維製品に塗布、または浸漬処理することで繊維製品に防汚性を付与する処理剤が提案されている。例えば、繊維製品の表面に、当該繊維製品と汚れとの接触を防止し得る被覆剤を存在させ、当該繊維製品を使用した後、前記被覆剤を除去することを特徴とする繊維製品の汚れ防止方法が知られており、被覆剤として、カルボキシメチルセルロース、加工澱粉及び水不溶性の微粒子が挙げられている(例えば特許文献1)。また、防汚剤の基材として、アクリル酸及び/又はメタクリル酸系高分子化合物(例えば特許文献2〜4)や水不溶性粉体(例えば特許文献5)を用いる含有する防汚剤組成物が提案されている。また、皮膜を形成し得るポリマーを用いた防汚剤も知られている(例えば特許文献6)。しかしながらこれら処理剤においても未だ満足できる防汚効果を得ることができない。
【0004】
さらに、陽イオン性基を有する化合物を防汚剤として用いる技術も既に提案されている(例えば特許文献7)が、これら処理剤においても未だ満足できる防汚性を得ることができない。
【0005】
従って本発明の課題は、衣料等の繊維製品に優れた防汚性を付与し、しかも汚れが付着しても洗濯で容易に除去できる易洗性を有する衣料用易洗防汚処理剤を提供することにある。
【0006】
【特許文献1】
特開平10−263497号公報
【特許文献2】
特開2000−143738号公報
【特許文献3】
特開2000−199178号公報
【特許文献4】
特開2000−199179号公報
【特許文献5】
特開平9−273071号公報
【特許文献6】
特開平9−273079号公報
【特許文献7】
特表平11−505568号公報
【0007】
【課題を解決するための手段】
本発明は、炭素数12〜26の炭化水素基を1つと炭素数1〜3の炭化水素基を2つ有するアミンオキシド化合物、及び水を含有する衣料用易洗防汚処理剤組成物に関する。
【0008】
また、本発明は、上記本発明の衣料用易洗防汚処理剤組成物を対象衣料に接触後、乾燥させる衣料の易洗防汚処理方法に関する。
【0009】
なお、本発明による衣料の易洗防汚処理剤組成物とは、衣料に直接接触させた後、乾燥させることで衣料に防汚成分を付着させる処理剤組成物であり、衣料の洗濯に用いられる一般の洗浄剤とは明らかに区別される。
【0010】
【発明の実施の形態】
本発明の組成物は炭素数12〜26の炭化水素基を1つと炭素数1〜3の炭化水素基を2つ有するアミンオキシド化合物を含有し、該化合物の好ましい具体例として一般式(1)の化合物を挙げることができる。
【0011】
【化1】
【0012】
〔式中、R1は炭素数12〜26のアルキル基又はアルケニル基であり、R2は炭素数1〜6のアルキレン基であり、Aは−COO−、−CONH−、−OCO−、−NHCO−から選ばれる基である。aは0又は1も数であり、R3、R4は炭素数1〜3のアルキル基又はヒドロキシアルキル基である。〕。
【0013】
一般式(1)において、R1の炭素数は、好ましくは炭素数12〜22、より好ましくは13〜19、特に好ましくは15〜17、最も好ましくは15である。Aは、好ましくは−COO−又は−CONH−であり、最も好ましくは−CONH−である。R2の炭素数は、好ましくは2又は3であり、R3、R4は、好ましくはメチル基である。
【0014】
本発明の最も好ましいアミンオキシド化合物としては下記一般式(1−1)の化合物または一般式(1−2)の化合物が好適である。
【0015】
【化2】
【0016】
〔式中、R5は炭素数13〜21、好ましくは13〜19、特に好ましくは15〜17、最も好ましくは15のアルキル基又はアルケニル基であり、b、cは2又は3の数である〕。
【0017】
本発明では、炭素数12〜26の炭化水素基、例えば上記一般式中のR1又はR5は、単独のアルキル(又はアルケニル)鎖長でもよく、異なるアルキル(又はアルケニル)鎖長を有する混合アルキル基(又はアルケニル基)であってもよい。後者の場合には、パーム油、大豆油、なたね油、綿実油から選ばれる植物油及び豚脂、牛脂、魚油から選ばれる動物油から誘導される混合アルキル(又はアルケニル)鎖長を有するものが好適である。具体的にはパルミチル基(またはパルミチン酸残基)/ステアリル基(又はステアリン酸残基、もしくはオレイル基またはオレイン酸残基)のモル比が90/10〜20/80、好ましくは90/10〜30/70であることが易洗防汚効果の点から好ましい。
【0018】
本発明に係わる組成物は、上記アミンオキシド化合物を易洗防汚効果の点から好ましくは0.01〜30質量%、より好ましくは0.1〜20質量%、特に好ましくは0.5〜10質量%含有することが好適である。
【0019】
本発明に係わる組成物は上記アミンオキシド化合物を水に溶解させた水溶液の形態であり、用いる水は微量に存在する金属を除去したイオン交換水や蒸留水が好ましい。水の含有量は40〜99.5質量%、より好ましくは60〜99質量%、特に好ましくは80〜99質量%が好適である。また、該組成物の20℃におけるpHは、易洗防汚効果の点から好ましくは5〜8.5、より好ましくは6〜7.8、特に好ましくは6.5〜7.5が好適である。このようなpHに調整するために塩酸、硫酸、リン酸、クエン酸、コハク酸、乳酸から選ばれる酸、及び炭酸ナトリウム、炭酸カリウム、水酸化ナトリウム、水酸化カリウム、アルカノールアミンから選ばれるアルカリ剤を用いることが好ましい。本発明では特に塩酸、硫酸から選ばれる酸、及び炭酸ナトリウム、水酸化ナトリウムから選ばれるアルカリ剤を用いることが好ましい。
【0020】
本発明に係わる組成物は上記アミンオキシド化合物以外の界面活性剤を含有することができるが、本発明の効果を妨げるおそれがあるために含有量はアミンオキシド化合物に対して好ましくは80質量%以下、より好ましくは50質量%以下、特に好ましくは25質量%以下、最も好ましくは10質量%以下である。本発明に用いることができる界面活性剤としては、炭素数8〜15のアルキル基を有するアルキルベンゼンスルホン酸塩、炭素数8〜16のアルキル硫酸エステル塩、平均付加モル数が1〜4、アルキル基の炭素数が8〜16のポリオキシエチレンアルキルエーテル硫酸エステル塩から選ばれる陰イオン界面活性剤、平均付加モル数が4〜20、アルキル基の炭素数が8〜14のポリオキシエチレン(及び/又はポリオキシプロピレン)アルキルエーテル型非イオン界面活性剤、エステル基又はアミド基で分断されていてもよい炭素数が12〜22アルキル基を1つまたは2つ有する4級アンモニウム型陽イオン界面活性剤、炭素数10〜18のアルキル基を有するスルホベタイン型、又はカルボベタイン型両性界面活性剤を挙げることができる。
【0021】
本発明に係わる組成物は衣料に該組成物を接触させた後の乾燥を促進させる目的、又は該組成物の貯蔵安定性を改善する目的から、水溶性の溶剤を用いることが好ましい。具体的に好ましい溶剤としてはエタノール、プロパノール、イソプロパノール、エチレングリコール、プロピレングリコール、及びグリセリンが好適であり、特にエタノール及び/又はプロピレングリコールが好ましい。このような溶剤の比率は、組成物中に好ましくは0.1〜40質量%、より好ましくは1〜20質量%、特に好ましくは5〜20質量%含有される。
【0022】
本発明に係わる組成物は、易洗防汚効果を向上させる目的から炭素数1〜4の炭化水素基が1〜3個置換していてもよいアルキルベンゼンスルホン酸塩、又はナフタレンスルホン酸塩を含有することが好ましく、具体的に好ましい化合物としては、p−トルエンスルホン酸ナトリウム、m−キシレンスルホン酸ナトリウム、クメンスルホン酸ナトリウム及びナフタレンスルホン酸ナトリウムから選ばれる1種以上であり、特にp−トルエンスルホン酸ナトリウム及びナフタレンスルホン酸ナトリウムから選ばれる化合物が最も好ましい。このような化合物は組成物中に好ましくは0〜10質量%、より好ましくは0.01〜5質量%、特に好ましくは0.1〜1質量%含有される。
【0023】
本発明では上記組成物を対象衣料に接触後乾燥させる。対象衣料は着用前の汚れが付着する前の衣料であり、洗濯時の脱水終了後の衣料、あるいは乾燥後の衣料に接触させることが易洗防汚効果を効果的に得る目的から好ましい。接触させる方法としては、該組成物に対象衣料を浸漬させる方法、スプレーヤーを用いて該組成物を対象衣料に噴霧する方法、又は布帛、不織布、スポンジ等の可撓性で吸水性の基体に含浸させたもので繊維製品を擦る方法が好ましい。特にスプレーにより噴霧する方法が簡便に易洗防汚効果を得ることができるため好ましく、スプレーはトリガー式スプレー容器が好ましく、特に実開平4−37554号公報の第1図に示されているような液垂れや噴霧の均一性に優れる蓄圧式トリガーを用いることが良好である。
【0024】
本発明の組成物に用いるのに好ましいトリガー式スプレー容器は、1回のストロークで0.2g〜1.5g、好ましくは0.25〜1.2g、特に好ましくは0.3〜1.0g噴出するものが良好であり、特に地面に垂直に置いた対象物に15cm離れた場所からスプレーしたときの液のかかる面積が100〜800cm2、好ましくは150〜600cm2になる容器が好ましい。また、本発明では、上記アミンオキシド化合物が衣料100cm2当たり好ましくは0.001〜2g、より好ましくは0.01〜1g、特に好ましくは0.02〜0.5g付着するように均一に衣料にスプレーし、好ましくは濯ぐことなく、乾燥させることが易洗防汚効果の点から好適である。
【0025】
本発明では該組成物を対象衣料に接触後、好ましくは濯ぐことなく、乾燥を行う。乾燥は、自然乾燥や、乾燥機あるいはアイロンによる加熱乾燥が好ましく、特に、洗濯後乾燥した衣料に用いる場合には、アイロンによる加熱乾燥が最も好ましい。
【0026】
【実施例】
白いワイシャツ(REAL−LINE FASHIOM社製CREANEARROW)5枚を市販の衣料用洗剤(花王(株)アタック)を用いて洗濯機で洗浄し(東芝製2槽式洗濯機VH−360S1、洗剤濃度0.0667質量%、水道水30L使用、水温20℃、10分間、すすぎ2回)、自然乾燥させた。
【0027】
花王(株)製アイロン用スムーザー400mlの中身を抜いた手動式スプレー容器を匂いが無くなるまで洗浄し、自然乾燥させたもの(1回のストロークで0.3g噴出、15cm離れた場所から噴射させたときの付着面積420cm2)に表1の組成物400mlを入れた。
【0028】
上記乾燥後のワイシャツの衿の部分の半分に上記スプレーを用いてアミンオキシド化合物の付着量が0.02g/100cm2になるようにスプレーした(ただし、比較例1、2、4は、実施例3の噴霧量と同じとした)。その後アイロンをかけて乾燥した。
【0029】
処理後のワイシャツを5人の男性(20〜30代)に36時間(1日12時間で3日間)着用させ、着用後の衣料の衿部分を下記の基準で判定した。次に、この着用後の衣料を上記と同様の方法で洗濯し、自然乾燥させたワイシャツの衿部分を下記の基準で判定した。
【0030】
判定基準
0:処理した部分の方が、汚れが付着していない(又は汚れが落ちている)
1:処理した部分の方が、あまり汚れが付着していない(又はやや汚れが落ちている)
2:処理した部分と処理していない部分に差がない
3:処理した部分の方が、汚れが付着している(又は汚れが落ちていない)
ワイシャツ5枚の平均を求め、平均点が0.5未満の場合を◎、0.5以上1未満を○、1以上1.5未満を□、1.5以上2未満を△、2以上を×として評価し表1に示した。
【0031】
【表1】
【0032】
・アミンオキシド1:N−アルキル−N,N−ジメチルアミンオキシド(アルキル基:炭素数16/炭素数18=40/60、モル比)
・アミンオキシド2:N−アルカノイルオキシエチル−N,N−ジメチルアミンオキシド(アルカノイル基:硬化牛脂アルキル組成)
・アミンオキシド3:N−パルミトイルアミノプロピル−N,N−ジメチルアミンオキシド
・アミンオキシド4:N−デカノイルアミノプロピル−N,N−ジメチルアミンオキシド
・ポリアクリル酸:ナトリウム塩、重量平均分子量10000
・陰イオン界面活性剤1:ポリオキシエチレンラウリルエーテル硫酸エステル塩、エチレンオキシド平均付加モル数2.5
pH調節は0.1規定硫酸水溶液及び0.1規定水酸化ナトリウム水溶液で行った。[0001]
TECHNICAL FIELD OF THE INVENTION
TECHNICAL FIELD The present invention relates to an easy-cleaning antifouling composition for clothing and a method for treating clothing.
[0002]
Problems to be solved by the prior art and the invention
Generally, clothes are washed with a washing machine using a weak alkaline detergent. However, dirt derived from sebum on the collar and cuffs and mud dirt adhering to socks are very stubborn dirt, and it is difficult to wash to a satisfactory level with ordinary washing.
[0003]
As a method for solving this, a treatment agent that imparts antifouling properties to textiles by applying or dipping the textiles after washing has been proposed. For example, on the surface of a textile product, there is a coating agent capable of preventing contact between the textile product and dirt, and after using the textile product, removing the coating agent to prevent staining of the textile product. A method is known, and carboxymethylcellulose, modified starch, and water-insoluble fine particles are mentioned as coating agents (for example, Patent Document 1). Further, as a base material of the antifouling agent, an antifouling agent composition containing an acrylic acid and / or methacrylic acid-based polymer compound (for example, Patent Documents 2 to 4) or a water-insoluble powder (for example, Patent Document 5) is used. Proposed. Further, an antifouling agent using a polymer capable of forming a film is also known (for example, Patent Document 6). However, even with these treating agents, a satisfactory antifouling effect cannot be obtained yet.
[0004]
Furthermore, a technique using a compound having a cationic group as an antifouling agent has already been proposed (for example, Patent Document 7), but even with these treatment agents, satisfactory antifouling properties cannot be obtained yet.
[0005]
Accordingly, an object of the present invention is to provide an easy-cleaning antifouling agent for clothing that imparts excellent antifouling properties to textiles such as clothing and has easy-to-wash properties that can be easily removed by washing even if dirt adheres. Is to do.
[0006]
[Patent Document 1]
JP-A-10-263497 [Patent Document 2]
Japanese Patent Application Laid-Open No. 2000-143738 [Patent Document 3]
JP 2000-199178 A [Patent Document 4]
JP 2000-199179 A [Patent Document 5]
Japanese Patent Application Laid-Open No. 9-273071 [Patent Document 6]
Japanese Patent Application Laid-Open No. 9-273079 [Patent Document 7]
Japanese Unexamined Patent Publication No. Hei 11-505568
[Means for Solving the Problems]
The present invention relates to an amine oxide compound having one hydrocarbon group having 12 to 26 carbon atoms and two having two hydrocarbon groups having 1 to 3 carbon atoms, and an easy-cleaning antifouling agent composition for clothing containing water.
[0008]
The present invention also relates to a method for easily cleaning and soiling an article of clothing, which is dried after contacting the above-mentioned composition for easy-washing and soiling for clothing of the present invention with a target article of clothing.
[0009]
In addition, the easily washable antifouling agent composition for clothing according to the present invention is a treating agent composition that causes an antifouling component to adhere to clothing by being directly contacted with clothing and then dried, and used for washing clothing. It is clearly distinguished from common cleaning agents.
[0010]
BEST MODE FOR CARRYING OUT THE INVENTION
The composition of the present invention contains an amine oxide compound having one hydrocarbon group having 12 to 26 carbon atoms and two hydrocarbon groups having 1 to 3 carbon atoms, and a preferred specific example of the compound is represented by the general formula (1): Can be mentioned.
[0011]
Embedded image
[0012]
[Wherein, R 1 is an alkyl group or alkenyl group having 12 to 26 carbon atoms, R 2 is an alkylene group having 1 to 6 carbon atoms, and A is —COO—, —CONH—, —OCO—, and — It is a group selected from NHCO-. a is 0 or 1, and R 3 and R 4 are an alkyl group or a hydroxyalkyl group having 1 to 3 carbon atoms. ].
[0013]
In the general formula (1), the carbon number of R 1 is preferably 12 to 22, more preferably 13 to 19, particularly preferably 15 to 17, and most preferably 15. A is preferably -COO- or -CONH-, most preferably -CONH-. R 2 preferably has 2 or 3 carbon atoms, and R 3 and R 4 are preferably methyl groups.
[0014]
The most preferred amine oxide compound of the present invention is a compound of the following general formula (1-1) or a compound of the general formula (1-2).
[0015]
Embedded image
[0016]
Wherein R 5 is an alkyl or alkenyl group having 13 to 21, preferably 13 to 19, particularly preferably 15 to 17, most preferably 15 carbon atoms, and b and c are 2 or 3 ].
[0017]
In the present invention, the hydrocarbon group having 12 to 26 carbon atoms, for example, R 1 or R 5 in the above general formula may have a single alkyl (or alkenyl) chain length or a mixed alkyl (or alkenyl) chain length having a different alkyl (or alkenyl) chain length. It may be an alkyl group (or an alkenyl group). In the latter case, those having a mixed alkyl (or alkenyl) chain length derived from a vegetable oil selected from palm oil, soybean oil, rapeseed oil, cottonseed oil and an animal oil selected from lard, tallow, and fish oil are preferred. Specifically, the molar ratio of palmityl group (or palmitic acid residue) / stearyl group (or stearic acid residue, or oleyl group or oleic acid residue) is 90/10 to 20/80, preferably 90/10. A ratio of 30/70 is preferred from the viewpoint of easy washing and antifouling effects.
[0018]
In the composition according to the present invention, the amine oxide compound is preferably used in an amount of 0.01 to 30% by mass, more preferably 0.1 to 20% by mass, and particularly preferably 0.5 to 10% by mass from the viewpoint of easy washing and antifouling effect. It is preferred that the content be contained by mass%.
[0019]
The composition according to the present invention is in the form of an aqueous solution in which the above amine oxide compound is dissolved in water, and the water used is preferably ion-exchanged water or distilled water from which trace amounts of metals have been removed. The content of water is preferably 40 to 99.5% by mass, more preferably 60 to 99% by mass, and particularly preferably 80 to 99% by mass. The pH of the composition at 20 ° C. is preferably from 5 to 8.5, more preferably from 6 to 7.8, and particularly preferably from 6.5 to 7.5, from the viewpoint of easy-cleaning and antifouling effects. is there. An acid selected from hydrochloric acid, sulfuric acid, phosphoric acid, citric acid, succinic acid, and lactic acid, and an alkali agent selected from sodium carbonate, potassium carbonate, sodium hydroxide, potassium hydroxide, and alkanolamine to adjust to such a pH. It is preferable to use In the present invention, it is particularly preferable to use an acid selected from hydrochloric acid and sulfuric acid, and an alkali agent selected from sodium carbonate and sodium hydroxide.
[0020]
The composition according to the present invention may contain a surfactant other than the above-mentioned amine oxide compound. However, the content is preferably 80% by mass or less based on the amine oxide compound because the effect of the present invention may be hindered. , More preferably 50% by mass or less, particularly preferably 25% by mass or less, and most preferably 10% by mass or less. Examples of the surfactant that can be used in the present invention include an alkylbenzene sulfonate having an alkyl group having 8 to 15 carbon atoms, an alkyl sulfate ester having 8 to 16 carbon atoms, an average addition mole number of 1 to 4, and an alkyl group having an alkyl group. Anionic surfactants selected from polyoxyethylene alkyl ether sulfates having 8 to 16 carbon atoms, polyoxyethylenes having an average addition mole number of 4 to 20 and alkyl groups having 8 to 14 carbon atoms (and / or Or polyoxypropylene) alkyl ether type nonionic surfactants, quaternary ammonium type cationic surfactants having one or two C12 to C22 alkyl groups which may be interrupted by ester groups or amide groups A sulfobetaine-type or a carbobetaine-type amphoteric surfactant having an alkyl group having 10 to 18 carbon atoms. That.
[0021]
In the composition according to the present invention, it is preferable to use a water-soluble solvent for the purpose of promoting drying after the composition is brought into contact with clothing, or for improving the storage stability of the composition. Specific preferred solvents include ethanol, propanol, isopropanol, ethylene glycol, propylene glycol, and glycerin, and particularly preferably ethanol and / or propylene glycol. The proportion of such a solvent is preferably 0.1 to 40% by mass, more preferably 1 to 20% by mass, particularly preferably 5 to 20% by mass in the composition.
[0022]
The composition according to the present invention contains an alkylbenzene sulfonate or a naphthalene sulfonate in which a hydrocarbon group having 1 to 4 carbon atoms may be substituted with 1 to 3 carbon atoms for the purpose of improving the easy-cleaning antifouling effect. The compound is preferably at least one selected from sodium p-toluenesulfonate, sodium m-xylenesulfonate, sodium cumenesulfonate and sodium naphthalenesulfonate, and particularly preferably p-toluenesulfonate. Compounds selected from sodium silicate and sodium naphthalene sulfonate are most preferred. Such a compound is contained in the composition preferably in an amount of 0 to 10% by mass, more preferably 0.01 to 5% by mass, and particularly preferably 0.1 to 1% by mass.
[0023]
In the present invention, the composition is dried after contacting the target clothing. The target garment is the garment before the dirt before wearing is attached, and it is preferable to bring the garment into contact with the garment after dehydration at the time of washing or the garment after drying from the viewpoint of effectively obtaining the easy-washing and antifouling effect. As a method of contacting, a method of immersing the target clothing in the composition, a method of spraying the composition on the target clothing using a sprayer, or a fabric, nonwoven fabric, a flexible and water-absorbing substrate such as a sponge, etc. A method of rubbing the textile with the impregnated material is preferred. In particular, a method of spraying with a spray is preferable because an easy washing and antifouling effect can be easily obtained, and the spray is preferably a trigger type spray container, particularly as shown in FIG. 1 of Japanese Utility Model Application Laid-Open No. 4-37554. It is preferable to use a pressure accumulating trigger which is excellent in uniformity of dripping and spraying.
[0024]
Preferred trigger spray containers for use in the compositions of the present invention dispense 0.2 g to 1.5 g, preferably 0.25 to 1.2 g, particularly preferably 0.3 to 1.0 g in a single stroke. it is good which, in particular consuming liquid area 100~800Cm 2 when sprayed from 15cm away the object placed perpendicularly to the ground, preferably a container to be 150~600cm 2. Further, in the present invention, the amine oxide compound is uniformly applied to the clothing so as to adhere to the clothing preferably in an amount of 0.001 to 2 g, more preferably 0.01 to 1 g, particularly preferably 0.02 to 0.5 g per 100 cm 2 of the clothing. Spraying, and preferably drying without rinsing, is suitable from the viewpoint of easy washing and antifouling effect.
[0025]
In the present invention, after the composition is brought into contact with the target clothing, drying is preferably performed without rinsing. Drying is preferably natural drying or drying by heating with a dryer or an iron. Particularly, when using for clothes dried after washing, heating and drying with an iron is most preferred.
[0026]
【Example】
Five white shirts (CREANEARROW manufactured by REAL-LINE FASHIOM) were washed with a washing machine using a commercially available detergent for clothing (Kao Corporation Attack) (Toshiba 2-tank washing machine VH-360S1, detergent concentration: 0.1%). 0667% by mass, using 30 L of tap water, water temperature of 20 ° C., 10 minutes, rinsing twice) and air-dried.
[0027]
A hand-operated spray container with 400 ml of an iron smoother manufactured by Kao Corporation was washed until the smell disappeared, and was air-dried (0.3 g was ejected by one stroke, and ejected from a place 15 cm away). 400 ml of the composition shown in Table 1 was added to the attached area at the time of 420 cm 2 .
[0028]
A half of the collar portion of the dried shirt was sprayed using the above spray so that the amount of the amine oxide compound attached was 0.02 g / 100 cm 2 (however, Comparative Examples 1, 2, and 4 are Examples 3). Then, it was ironed and dried.
[0029]
The treated shirts were worn by five men (20s to 30s) for 36 hours (12 hours a day for 3 days), and the collar portions of the worn clothes were determined according to the following criteria. Next, the worn clothing was washed in the same manner as above, and the collar portion of the naturally dried shirt was determined according to the following criteria.
[0030]
Judgment criterion 0: Dirt is not attached to the processed part (or dirt is removed)
1: The treated part is not much stained (or is slightly stained)
2: There is no difference between the treated part and the untreated part 3: The treated part is stained (or the stain is not removed)
The average of five shirts is calculated, and when the average point is less than 0.5, ◎, 0.5 or more and less than 1, ○, 1 or more and less than 1.5, □, 1.5 or more and less than 2, △ or 2 or more It was evaluated as x and shown in Table 1.
[0031]
[Table 1]
[0032]
Amine oxide 1: N-alkyl-N, N-dimethylamine oxide (alkyl group: 16 carbon atoms / 18 carbon atoms = 40/60, molar ratio)
Amine oxide 2: N-alkanoyloxyethyl-N, N-dimethylamine oxide (alkanoyl group: hardened tallow alkyl composition)
Amine oxide 3: N-palmitoylaminopropyl-N, N-dimethylamine oxideAmine oxide 4: N-decanoylaminopropyl-N, N-dimethylamine oxidePolyacrylic acid: sodium salt, weight average molecular weight 10,000
Anionic surfactant 1: polyoxyethylene lauryl ether sulfate, ethylene oxide average molar number of addition 2.5
The pH was adjusted with a 0.1 N sulfuric acid aqueous solution and a 0.1 N sodium hydroxide aqueous solution.
Claims (2)
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| Application Number | Priority Date | Filing Date | Title |
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| JP2002282777A JP3883943B2 (en) | 2002-09-27 | 2002-09-27 | Easy-cleaning antifouling agent composition for clothing |
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| Application Number | Priority Date | Filing Date | Title |
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| JP2002282777A JP3883943B2 (en) | 2002-09-27 | 2002-09-27 | Easy-cleaning antifouling agent composition for clothing |
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| Publication Number | Publication Date |
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| JP2004115968A true JP2004115968A (en) | 2004-04-15 |
| JP3883943B2 JP3883943B2 (en) | 2007-02-21 |
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