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JP2004010941A - Aluminum alloy sheet for bottle-type beverage can - Google Patents

Aluminum alloy sheet for bottle-type beverage can Download PDF

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Publication number
JP2004010941A
JP2004010941A JP2002164246A JP2002164246A JP2004010941A JP 2004010941 A JP2004010941 A JP 2004010941A JP 2002164246 A JP2002164246 A JP 2002164246A JP 2002164246 A JP2002164246 A JP 2002164246A JP 2004010941 A JP2004010941 A JP 2004010941A
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Japan
Prior art keywords
aluminum alloy
bottle
type beverage
beverage
workability
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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JP2002164246A
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Japanese (ja)
Inventor
Toshihiro Harada
原田 俊宏
Mitsuru Saito
齊藤 充
Hiroshi Saito
齊藤 洋
Koichi Ohori
大堀 紘一
Masashi Kato
加藤 正志
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MA Aluminum Corp
Original Assignee
Mitsubishi Aluminum Co Ltd
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Priority to JP2002164246A priority Critical patent/JP2004010941A/en
Publication of JP2004010941A publication Critical patent/JP2004010941A/en
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Abstract

<P>PROBLEM TO BE SOLVED: To provide an aluminum alloy sheet for a bottle-type beverage can having superior curling workability for an opening edge at a mouth neck part. <P>SOLUTION: This aluminum alloy sheet is characterized by employing an aluminum alloy having a composition consisting of wt.%, 0.1-0.5% Si, 0.3-0.7% Fe, 0.05-0.5% Cu, 0.5-1.5% Mn, 0.4-1.5% Mg, 0.001-0.05% Cr, 0.05-0.5% Zn, 0.001-0.05% Ti, and the balance Al with unavoidable impurities. <P>COPYRIGHT: (C)2004,JPO

Description

【0001】
【発明の属する技術分野】
本発明は、胴部、肩部、口頸部が一体成形されたボトル型飲料缶用のアルミニウム合金板に係わり、特に口頸部開口端のカール加工性に優れたボトル型飲料缶用のアルミニウム合金板に係わるものである。
【0002】
【従来の技術】
従来、飲料用アルミニウム缶は、アルミニウム合金板から絞り、しごき( Deep drawing & Ironing:DI)加工を行い、缶胴部と缶底部が一体の2ピース缶、あるいは缶胴部と缶底部が別の3ピース缶のいずれかであり、イージーオープンエンドと呼ばれる缶蓋の簡易開口部をプルタブ操作により開口する方式が主流であった。従来の飲料用アルミニウム缶において、缶蓋との巻き締め部となる缶胴部の開口端はネック加工による縮径の後、伸びフランジ加工が施される。そしてネッキング以降の加工は塗装焼き付けの後に行うため、フランジ加工性は材料の塗装焼き付け後の引張強度特性、特に耐力特性に大きく左右される。そのため飲料用アルミニウム缶用アルミニウム合金板の塗装焼き付け後の耐力特性は、その上限が所定以上のフランジ加工性が得られることにより、下限が所定以上の缶胴部の軸加重座屈強度が得られるように規定されていた。
【0003】
最近缶入り飲料水などの需要増加に伴って、容器から直接引用することが容易で、キャップにより再密封(リシール)できるようなアルミニウム合金製のボトル型の飲料缶が開発され、その需要が急速に高まってきている。
ボトル型の飲料缶は図1に示すように、底部16を有する円筒状の胴部11の上部に、直径が減少する肩部12を介して頸部13が形成されている。頸部13にはキャップ(図示省略)をねじ込むためのネジ部14が形成されており、ネジ部14の先端には口当たりを良くするためのカール部15が形成されている。
【0004】
図1に示すようなボトル型飲料缶の製造方法の概要を示せば図2の通りとなる。すなわち、例えば JIS 3004合金のようなAl−Mn−Mg系合金のブランク材1に深絞り加工を施し、カップ2を形成する。
次いでカップ2にしごき加工を施して缶体3を形成する。
【0005】
缶体3には縮径加工を施して肩部12と頸部13を形成し、口頸部開口端を外側へ伸びフランジ成形後、さらに縮みフランジ成形して折り返す「カール加工」と呼ばれる加工を施こす。この加工は従来の缶胴開口部のフランジ加工に比べてより一層厳しい加工となる。またボトル型飲料缶の胴部から口頸部にかけての縮径率は、従来の缶における胴部から缶蓋の巻き締め部への縮径率に比べて非常に高く、材料の加工硬化がより進んだ状態にあるといえる。
したがって、飲料用アルミニウム缶用のアルミニウム合金板の塗装焼き付け後の耐力特性の上限値は、従来の缶用材料の場合よりも低くすることが要求されるようになる。
【0006】
一方、ボトル型飲料缶の口頸部には、キャップによる再密封を行うためのネジ部が設けてあり、缶の軸方向の荷重が付加された場合にこのネジ部が座屈変形する恐れがあるため、アルミニウム合金板の塗装焼き付け後の耐力特性の下限値はあまり低くするわけにはいかない。
このようにボトル型飲料缶においては、従来のアルミニウム缶の主流であったDI缶に比較して頸部に一段と厳しい塑性加工を施すため、素材にも一段と高い特性が要求される。
以上のような理由から、飲料用アルミニウム缶用のアルミニウム合金板の塗装焼き付け後の耐力特性は、従来の飲料缶用の材料に比べて低く抑え、しかも狭い範囲で厳密に管理されねばならない。
【0007】
従来の飲料缶用のアルミニウム合金板材としては種々合金が提案されており、例えば良好な耳率と高い強度を有する飲料アルミニウム缶用のアルミニウム合金として、 重量%でSi:0.1〜0.7%、Fe:0.1〜0.7%、Cu:0.05〜0.3%、Mn:0.1〜2.0%、Mg:0.1〜2.0%を含有し、残部が不可避的不純物を含むAlからなる組成を有するアルミニウム合金が提案されている(特開昭59−162261号公報参照)。
また、高強度を保持しつつ低耳率化、高成形性を可能とする飲料アルミニウム缶用のアルミニウム合金として、重量%でCu:0.10〜0.80%、Mn:0.5〜2.0%、Mg:0.5〜2.0%及びFe:0.2〜0.7%を含有し、残部が不可避的不純物を含むAlからなる組成を有するアルミニウム合金が提案されている(特開昭63−282245号公報参照)。
さらには、耳率が低く成形性を向上させる飲料アルミニウム缶用のアルミニウム合金として、 重量%でSi:0.05〜0.5%、Fe:0.1〜0.7%、Cu:0.05〜0.5%、Mn:0.5〜1.8%、Mg:0.5〜2.0%、Ti:0.001〜0.20%、Cr:0.05〜0.3%、Zn:0.10〜0.5%を含有し、残部が不可避的不純物を含むAlからなる組成を有するアルミニウム合金が提案されている(特開平6−101002号公報参照)。
【0008】
【発明が解決しようとする課題】
しかしながらこれら従来のアルミニウム合金では、塗装焼き付け後の耐力特性が低すぎたり、あるいは材料の強度を高めるあまり塗装焼き付け後の耐力特性の上限値が高すぎたりして、適正範囲に厳密に管理されているものは見当たらない。したがって、口頸部開口端のカール加工性に優れた缶材が得られず、口頸部開口端のカール加工の際にひび割れが発生して生産歩留まりが低下する問題点があった。
【0009】
【課題を解決するための手段】
本発明は上記問題点を解決するためになされたものであって、重量%でSi:0.1〜0.5%、Fe:0.3〜0.7%、Cu:0.05〜0.5%、Mn:0.5〜1.5%、Mg:0.4〜1.5%、Cr:0.001〜0.05%、Zn:0.05〜0.5%、Ti:0.001〜0.05%を含有し、残部が不可避的不純物を含むAlからなる組成を有するアルミニウム合金を、ボトル型飲料缶用の板材とした。
本発明のアルミニウム合金組成は、好ましくは重量%でSi:0.2〜0.3%、Fe:0.4〜0.5%、Cu:0.2〜0.3%、Mn:0.7〜1.1%、Mg:0.5〜0.8%、Cr:0.001〜0.05%、Zn:0.1〜0.2%、Ti:0.001〜0.05%を含有し、残部が不可避的不純物を含むAlからなるものがよい。
【0010】
このような組成のアルミニウム合金とし、塗装焼付け後の耐力値が225〜240MPaとなるようにすれば、口頸部開口端のカール加工性に優れ、割れの発生がなく飲料缶の製造歩留まりを高めることが可能となる。
【0011】
【発明の実施の形態】
先ず本発明のアルミニウム合金の組成限定理由から説明する。
シリコン(Si)は同時に含有されるMgとともに化合物を形成し、固溶硬化、析出硬化、分散硬化作用を及ぼすほか、Al、Mn、Feなどとも金属間化合物を形成して、しごき成型時にダイスに対する焼き付きを防止する効果を発揮する。Si含有量が0.1%未満では、所望の潤滑性能を発揮できず、ダイスへの焼き付きを防止するのに不十分である。一方、Si含有量が0.5%を越えると脆くなり加工性が劣化する。従ってSiの適正含有量は0.1〜0.5%、好ましくはSi:0.2〜0.3%、と設定する。
【0012】
鉄(Fe)及びクロム(Cr)は析出物の結晶微細化と、しごき成形加工時にダイスに対する焼き付きを防止する効果を発揮する。Feの場合には含有量が0.3%未満では所望の効果が得られず、一方、Fe含有量が0.7%を越えると脆くなり加工性が劣化する。従ってFeの適正含有量は0.3〜0.7%、好ましくはFe:0.4〜0.5%と設定する。Crの場合には、Cr含有量が0.001%未満では所望の効果が得られず、一方、Cr含有量が0.05%を越えると脆くなり加工性が劣化する。従ってCrの適正含有量は0.001〜0.05%とする。
【0013】
銅(Cu)はMgと金属間化合物を形成し易く、固溶硬化、析出硬化、分散硬化作用に寄与する。また、缶の化成処理後の表面のムラを抑える。Cu含有量が0.05%未満ではこれらの効果が乏しく、またCu含有量が0.5%を越えると加工性が劣化する。従って、Cuの適正な含有量は0.05〜0.5%、好ましくはCu:0.2〜0.3%に設定する。
マンガン(Mn)はFe、Si、Al等とともに金属間化合物を形成し易く、晶出相及び分散相となって分散効果作用を発揮するとともに、しごき成型加工時にダイスに対する焼き付きを防止する効果を発揮する。Mn含有量が0.5%未満では所望の硬化特性が得られず、一方、Mn含有量が1.5%を越えると脆くなり加工性が劣化する。従ってMnの適正含有量は0.5〜1.5%、好ましくはMn:0.7〜1.1%と設定する。
マグネシウム(Mg)は固溶体強化作用を有し、圧延加工時に加工硬化性を高めるとともに、前記SiやCuと共存することで分散硬化と析出硬化作用を発揮する。Mg含有量が0.4%未満ではこれらの作用効果が十分発揮されず、またMg含有量が1.5%を越えると加工性が劣化し、特にカール加工性が低下する。従って、Mgの適正含有量は0.4〜1.5%、好ましくは0.5〜0.8%に設定する。
【0014】
亜鉛(Zn)は析出するMg、Si、Cuの金属間化合物を微細化する作用を有し、さらに缶の化成処理後の表面を均質にする。Zn含有量が0.05%未満では化成処理後に均質な表面が得られず、Zn含有量が0.5%を越えると加工性と耐食性が劣化する。従ってZnの適正な含有量は0.05〜0.5%、好ましくはZn:0.1〜0.2%とする。
チタン(Ti)は結晶粒を微細化し、加工性を改善する効果を発揮する。Ti含有量が0.001%未満ではこれらの効果が発揮されず、また0.05%を越えると粗大な化合物ができて加工性が劣化する。したがって、Tiの適正な含有量は0.001〜0.05%とする。
【0015】
塗装焼付け後の耐力が225MPa未満では、コラム強度(缶の軸方向の座屈強度)が不足し、塗装焼付け後の耐力が240MPaを越えるとカール加工性が悪化し、加工時にカール割れが発生する。したがって、塗装焼き付け後の耐力は225〜240MPaとする。
【0016】
【実施例】
以下実施例を用いて本発明を具体的に説明する。
素材として表1に示すアルミニウム合金を使用した。それぞれの合金の溶湯を常法により脱ガス、介在物除去を行い、半連続鋳造により厚さ550mm、幅1.5m、長さ4.5mのスラブに鋳造した。ついで、600℃に加熱して均質化処理を行った後、板厚6.5mmまで熱間圧延し、引き続き板厚1.2mmまで冷間圧延をした。
冷間圧延後の板材を連続焼鈍炉で350℃に加熱して第1段の中間焼鈍処理を行った後、冷間圧延を施して板厚1.0mmまで冷間圧延した。
さらに、連続焼鈍炉で550℃に加熱して第2段の中間焼鈍処理を行った後、最終板厚0.4mmまで冷間圧延を行ってボトル型飲料缶用のアルミニウム合金板を得た。
【0017】
【表1】

Figure 2004010941
【0018】
このようにして得られたアルミニウム合金板のブランク材を使用して、図2の工程図に従ってボトル型飲料缶に加工した。次いで、210℃×10minの条件で塗装焼き付け相当の熱処理を行い、塗装焼き付け後の引張試験により耐力を測定した。また、缶全体の座屈試験を行ってコラム強度を求め、1700N以上に○印を、1700N未満に×印を付して評価した。
【0019】
カール加工性は口頸部の開口端にカール加工を施し、目視で判定を行った。カール部に割れが全く認められなかった場合には○印を、カール部に微小なヒビ割れが認められた場合は△印を、強度なひび割れが認められた場合には×印を付した。
表面均質性はDI加工後の化成処理後の表面を目視観察して均質なものには○印を、ムラがやや認められた場合には△印を、強度なムラが認められた場合には×印を付した。
これらの結果を表1に併記する。
【0020】
【発明の効果】
本発明のアルミニウム合金板を使用すれば、コラム強度が高く、カール加工性も良く割れが発生しないボトル型飲料缶用アルミニウム合金板が得られる。
【図面の簡単な説明】
【図1】本発明の対象となるボトル型飲料缶の断面構造を示す図である。
【図2】図1に示すボトル型飲料缶の概略製造工程を示す図である。
【符号の説明】
1・・・・・ブランク材、2・・・・・カップ、3・・・・・缶体、10・・・・・ボトル型飲料缶、11・・・・・胴部、12・・・・・肩部、13・・・・・口頸部、14・・・・・ネジ部、15・・・・・カール部、16・・・・・底部、31・・・・・耳[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to an aluminum alloy plate for a bottle-type beverage can having a body, a shoulder, and a mouth and neck integrally formed, and particularly to an aluminum alloy for a bottle-type beverage can excellent in curl workability at an opening end of the mouth and neck. It relates to an alloy plate.
[0002]
[Prior art]
Conventionally, aluminum cans for beverages are drawn from an aluminum alloy plate and subjected to ironing (Deep drawing & Ironing: DI) processing to form a two-piece can in which the can body and the can bottom are integrated, or the can body and the can bottom are separated. One of the three-piece cans, in which a simple open end of the can lid called an easy open end is opened by a pull tab operation, has been the mainstream. In a conventional aluminum can for beverages, an opening end of a can body serving as a part to be fastened to a can lid is reduced in diameter by neck processing and then subjected to stretch flange processing. Since the processing after necking is performed after baking, the workability of the flange greatly depends on the tensile strength characteristics of the material after baking, especially the proof stress characteristics. Therefore, the yield strength characteristics of the aluminum alloy plate for aluminum cans for beverages after baking is obtained by obtaining a flange workability having an upper limit of not less than a predetermined value, thereby obtaining a shaft load buckling strength of a can body having a lower limit of not less than a predetermined value. Was stipulated.
[0003]
Recently, with the increase in demand for canned drinking water, bottled drink cans made of aluminum alloy that can be easily quoted directly from the container and can be resealed with a cap have been developed. Is increasing.
As shown in FIG. 1, the bottle-shaped beverage can has a neck 13 formed on a cylindrical body 11 having a bottom 16 via a shoulder 12 having a reduced diameter. A screw portion 14 for screwing a cap (not shown) is formed in the neck portion 13, and a curl portion 15 for improving the mouthfeel is formed at the tip of the screw portion 14.
[0004]
FIG. 2 shows an outline of a method for manufacturing a bottle-type beverage can as shown in FIG. That is, for example, a cup 2 is formed by subjecting a blank material 1 of an Al-Mn-Mg-based alloy such as JIS 3004 alloy to deep drawing.
Next, ironing is performed on the cup 2 to form the can body 3.
[0005]
The can body 3 is subjected to a diameter reduction process to form a shoulder portion 12 and a neck portion 13, and the opening end of the mouth and neck portion is extended outwardly. Give This processing is more severe processing than the conventional flange processing of the can body opening. Also, the diameter reduction ratio from the body to the mouth and neck of the bottle-type beverage can is much higher than the reduction ratio from the body of the conventional can to the tightened portion of the can lid, and the work hardening of the material is more. It can be said that it is in an advanced state.
Therefore, it is required that the upper limit of the proof stress characteristic of the aluminum alloy plate for the beverage aluminum can after baking is lower than that of the conventional can material.
[0006]
On the other hand, the mouth and neck of the bottle-type beverage can have a screw portion for resealing with the cap, and when a load in the axial direction of the can is applied, the screw portion may be buckled. For this reason, the lower limit of the proof stress characteristics of the aluminum alloy plate after baking is not too low.
As described above, in the bottle-type beverage can, the neck is subjected to more severe plastic processing than the DI can which has been the mainstream of the conventional aluminum can, so that the material is required to have higher properties.
For the above reasons, the yield strength after painting and baking of an aluminum alloy plate for an aluminum can for beverages must be kept lower than that of conventional materials for beverage cans, and must be strictly controlled in a narrow range.
[0007]
Various alloys have been proposed as conventional aluminum alloy plate materials for beverage cans. For example, as an aluminum alloy for beverage aluminum cans having good ear ratio and high strength, Si: 0.1 to 0.7% by weight. %, Fe: 0.1 to 0.7%, Cu: 0.05 to 0.3%, Mn: 0.1 to 2.0%, Mg: 0.1 to 2.0%, with the balance being the balance Has been proposed (see JP-A-59-162261).
In addition, as an aluminum alloy for a beverage aluminum can that can achieve a low ear ratio and high moldability while maintaining high strength, Cu: 0.10 to 0.80%, Mn: 0.5 to 2 by weight%. An aluminum alloy containing 0.0%, Mg: 0.5 to 2.0%, and Fe: 0.2 to 0.7% and having a balance of Al containing unavoidable impurities has been proposed. See JP-A-63-282245).
Further, as an aluminum alloy for beverage aluminum cans having a low ear ratio and improving moldability, Si: 0.05 to 0.5%, Fe: 0.1 to 0.7%, and Cu: 0. 0.5 to 0.5%, Mn: 0.5 to 1.8%, Mg: 0.5 to 2.0%, Ti: 0.001 to 0.20%, Cr: 0.05 to 0.3% An aluminum alloy containing 0.10 to 0.5% of Zn and having a balance of Al containing unavoidable impurities has been proposed (see JP-A-6-101002).
[0008]
[Problems to be solved by the invention]
However, in these conventional aluminum alloys, the proof stress characteristics after paint baking are too low, or the upper limit value of the proof stress characteristics after paint baking is too high to increase the strength of the material, and is strictly controlled to an appropriate range. There is nothing found. Therefore, there was a problem that a can material excellent in curl workability at the mouth and neck opening end could not be obtained, and cracking occurred during curling at the mouth and neck opening end, resulting in a decrease in production yield.
[0009]
[Means for Solving the Problems]
The present invention has been made in order to solve the above-mentioned problems. Si: 0.1 to 0.5%, Fe: 0.3 to 0.7%, and Cu: 0.05 to 0% by weight. 0.5%, Mn: 0.5-1.5%, Mg: 0.4-1.5%, Cr: 0.001-0.05%, Zn: 0.05-0.5%, Ti: An aluminum alloy containing 0.001 to 0.05% and a balance of Al containing inevitable impurities was used as a plate material for bottle-type beverage cans.
The aluminum alloy composition of the present invention is preferably 0.2 to 0.3% by weight of Si, 0.4 to 0.5% of Fe, 0.2 to 0.3% of Cu, 0.2 to 0.3% by weight of Mn. 7 to 1.1%, Mg: 0.5 to 0.8%, Cr: 0.001 to 0.05%, Zn: 0.1 to 0.2%, Ti: 0.001 to 0.05% And the balance is preferably made of Al containing unavoidable impurities.
[0010]
When the aluminum alloy having such a composition is used and the proof stress after baking is set to 225 to 240 MPa, the curl workability of the mouth and neck opening ends is excellent, and the production yield of the beverage can is increased without cracking. It becomes possible.
[0011]
BEST MODE FOR CARRYING OUT THE INVENTION
First, the reason for limiting the composition of the aluminum alloy of the present invention will be described.
Silicon (Si) forms a compound with the simultaneously contained Mg and exerts solid solution hardening, precipitation hardening, and dispersion hardening. In addition, it forms an intermetallic compound with Al, Mn, Fe, etc., and forms an intermetallic compound with the die during ironing. It has the effect of preventing image sticking. If the Si content is less than 0.1%, the desired lubricating performance cannot be exhibited, and it is insufficient to prevent seizure on a die. On the other hand, if the Si content exceeds 0.5%, it becomes brittle and the workability deteriorates. Therefore, the appropriate content of Si is set to 0.1 to 0.5%, preferably 0.2 to 0.3%.
[0012]
Iron (Fe) and chromium (Cr) have the effect of miniaturizing the crystal of the precipitate and preventing seizure on the die during ironing. In the case of Fe, if the content is less than 0.3%, the desired effect cannot be obtained. On the other hand, if the Fe content exceeds 0.7%, it becomes brittle and the workability deteriorates. Therefore, the proper content of Fe is set to 0.3 to 0.7%, preferably, to 0.4 to 0.5%. In the case of Cr, if the Cr content is less than 0.001%, the desired effect cannot be obtained. On the other hand, if the Cr content exceeds 0.05%, the Cr becomes brittle and the workability deteriorates. Therefore, the appropriate content of Cr is set to 0.001 to 0.05%.
[0013]
Copper (Cu) easily forms an intermetallic compound with Mg, and contributes to solid solution hardening, precipitation hardening, and dispersion hardening. Further, the unevenness of the surface of the can after the chemical conversion treatment is suppressed. If the Cu content is less than 0.05%, these effects are poor, and if the Cu content exceeds 0.5%, the workability deteriorates. Therefore, the appropriate content of Cu is set to 0.05 to 0.5%, preferably, to 0.2 to 0.3% Cu.
Manganese (Mn) easily forms an intermetallic compound together with Fe, Si, Al, etc., exhibits a dispersing effect as a crystallized phase and a dispersed phase, and also has an effect of preventing seizure on a die during ironing. I do. If the Mn content is less than 0.5%, desired curing properties cannot be obtained, while if the Mn content exceeds 1.5%, the material becomes brittle and the workability deteriorates. Therefore, the appropriate content of Mn is set to 0.5 to 1.5%, preferably, Mn: 0.7 to 1.1%.
Magnesium (Mg) has a solid solution strengthening effect, enhances work hardening during rolling, and exhibits a dispersion hardening and a precipitation hardening effect when coexisting with Si or Cu. If the Mg content is less than 0.4%, these functions and effects are not sufficiently exhibited, and if the Mg content exceeds 1.5%, workability is deteriorated, and particularly curl workability is deteriorated. Therefore, the appropriate content of Mg is set to 0.4 to 1.5%, preferably 0.5 to 0.8%.
[0014]
Zinc (Zn) has an action of miniaturizing precipitated intermetallic compounds of Mg, Si, and Cu, and further homogenizes the surface of the can after the chemical conversion treatment. If the Zn content is less than 0.05%, a uniform surface cannot be obtained after the chemical conversion treatment, and if the Zn content exceeds 0.5%, workability and corrosion resistance deteriorate. Therefore, the appropriate content of Zn is 0.05 to 0.5%, preferably Zn: 0.1 to 0.2%.
Titanium (Ti) has the effect of refining crystal grains and improving workability. If the Ti content is less than 0.001%, these effects cannot be exerted. If the Ti content exceeds 0.05%, a coarse compound is formed and workability is deteriorated. Therefore, the appropriate content of Ti is set to 0.001 to 0.05%.
[0015]
If the yield strength after baking is less than 225 MPa, the column strength (buckling strength in the axial direction of the can) is insufficient. . Therefore, the proof stress after paint baking is 225 to 240 MPa.
[0016]
【Example】
Hereinafter, the present invention will be described specifically with reference to Examples.
The aluminum alloy shown in Table 1 was used as a material. The melt of each alloy was degassed and inclusions were removed by a conventional method, and cast into a slab having a thickness of 550 mm, a width of 1.5 m and a length of 4.5 m by semi-continuous casting. Then, after heating to 600 ° C. to perform a homogenization treatment, hot rolling was performed to a plate thickness of 6.5 mm, and then cold rolling was performed to a plate thickness of 1.2 mm.
After the cold-rolled sheet material was heated to 350 ° C. in a continuous annealing furnace to perform a first-stage intermediate annealing treatment, the sheet material was cold-rolled and cold-rolled to a sheet thickness of 1.0 mm.
Furthermore, after heating to 550 ° C. in a continuous annealing furnace to perform a second-stage intermediate annealing treatment, cold rolling was performed to a final plate thickness of 0.4 mm to obtain an aluminum alloy plate for a bottle-type beverage can.
[0017]
[Table 1]
Figure 2004010941
[0018]
Using the blank material of the aluminum alloy plate thus obtained, it was processed into a bottle-shaped beverage can according to the process diagram of FIG. Next, a heat treatment equivalent to baking was performed at 210 ° C. for 10 minutes, and the proof stress was measured by a tensile test after baking. The column strength was determined by performing a buckling test of the entire can, and the evaluation was performed by attaching a circle to 1700N or more and a cross to less than 1700N.
[0019]
The curl processability was determined by performing a curl process on the open end of the mouth and neck, and visually checking. When no crack was found in the curled portion, a mark was given, when a minute crack was found in the curled portion, a mark was given, and when a strong crack was found, a mark was given.
The surface homogeneity was evaluated by visually observing the surface after the chemical conversion treatment after DI processing, and when the surface was homogeneous, mark ○, when unevenness was slightly recognized, mark Δ, and when strong unevenness was recognized, X mark.
These results are also shown in Table 1.
[0020]
【The invention's effect】
When the aluminum alloy plate of the present invention is used, an aluminum alloy plate for a bottle-type beverage can having high column strength, good curl workability and no cracking can be obtained.
[Brief description of the drawings]
FIG. 1 is a diagram showing a cross-sectional structure of a bottle-type beverage can to which the present invention is applied.
FIG. 2 is a view showing a schematic manufacturing process of the bottle-type beverage can shown in FIG.
[Explanation of symbols]
1 ... blank material, 2 ... cup, 3 ... can body, 10 ... bottled beverage can, 11 ... body, 12 ... ..Shoulder, 13 ... Mouth and neck, 14 ... Screw, 15 ... Curl, 16 ... Bottom, 31 ... Ear

Claims (3)

重量%でSi:0.1〜0.5%、Fe:0.3〜0.7%、Cu:0.05〜0.5%、Mn:0.5〜1.5%、Mg:0.4〜1.5%、Cr:0.001〜0.05%、Zn:0.05〜0.5%、Ti:0.001〜0.05%を含有し、残部が不可避的不純物を含むAlからなる組成を有することを特徴とするボトル型飲料缶用アルミニウム合金板。% By weight: Si: 0.1 to 0.5%, Fe: 0.3 to 0.7%, Cu: 0.05 to 0.5%, Mn: 0.5 to 1.5%, Mg: 0 0.4 to 1.5%, Cr: 0.001 to 0.05%, Zn: 0.05 to 0.5%, Ti: 0.001 to 0.05%, the remainder being inevitable impurities. An aluminum alloy plate for a bottle-type beverage can, characterized in that it has a composition comprising Al. 前記アルミニウム合金の組成が、重量%でSi:0.2〜0.3%、Fe:0.4〜0.5%、Cu:0.2〜0.3%、Mn:0.7〜1.1%、Mg:0.5〜0.8%、Cr:0.001〜0.05%、Zn:0.1〜0.2%、Ti:0.001〜0.05%を含有し、残部が不可避的不純物を含むAlからなることを特徴とする請求項1に記載のボトル型飲料缶用アルミニウム合金板。The composition of the aluminum alloy is as follows: Si: 0.2-0.3%, Fe: 0.4-0.5%, Cu: 0.2-0.3%, Mn: 0.7-1 by weight%. 0.1%, Mg: 0.5-0.8%, Cr: 0.001-0.05%, Zn: 0.1-0.2%, Ti: 0.001-0.05% The aluminum alloy plate for a bottle-type beverage can according to claim 1, wherein the balance is made of Al containing unavoidable impurities. 塗装焼付け後の耐力値が225〜240MPaであることを特徴とする請求項1または請求項2に記載のボトル型飲料缶用アルミニウム合金板。The aluminum alloy plate for a bottle-type beverage can according to claim 1 or 2, wherein the proof stress value after baking is from 225 to 240 MPa.
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Cited By (7)

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Publication number Priority date Publication date Assignee Title
JP2004250790A (en) * 2003-01-31 2004-09-09 Kobe Steel Ltd Aluminum alloy sheet for bottle can
JP2006097076A (en) * 2004-09-29 2006-04-13 Kobe Steel Ltd Aluminum-alloy sheet for bottle can, and its manufacturing method
JP2007530794A (en) * 2004-03-31 2007-11-01 ハイドロ アルミニウム ドイチュラント ゲー エム ベー ハー Heat-resistant aluminum alloy for heat exchanger
JP2017531094A (en) * 2014-09-12 2017-10-19 ノベリス・インコーポレイテッドNovelis Inc. Alloys for highly formed aluminum products and methods for making the same
JP2018510967A (en) * 2015-03-13 2018-04-19 ノベリス・インコーポレイテッドNovelis Inc. Highly formed aluminum alloy for packaging products and method for producing the same
EP3137641B1 (en) 2014-04-30 2020-01-08 Alcoa USA Corp. Method of manufacturing an aluminum container made from aluminum sheet
US11433441B2 (en) 2016-08-30 2022-09-06 Kaiser Aluminum Warrick, Llc Aluminum sheet with enhanced formability and an aluminum container made from aluminum sheet

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004250790A (en) * 2003-01-31 2004-09-09 Kobe Steel Ltd Aluminum alloy sheet for bottle can
JP2007530794A (en) * 2004-03-31 2007-11-01 ハイドロ アルミニウム ドイチュラント ゲー エム ベー ハー Heat-resistant aluminum alloy for heat exchanger
JP2006097076A (en) * 2004-09-29 2006-04-13 Kobe Steel Ltd Aluminum-alloy sheet for bottle can, and its manufacturing method
EP3137641B1 (en) 2014-04-30 2020-01-08 Alcoa USA Corp. Method of manufacturing an aluminum container made from aluminum sheet
EP3137641B2 (en) 2014-04-30 2024-08-21 Kaiser Aluminum Warrick, LLC Method of manufacturing an aluminum container made from aluminum sheet
JP2017531094A (en) * 2014-09-12 2017-10-19 ノベリス・インコーポレイテッドNovelis Inc. Alloys for highly formed aluminum products and methods for making the same
KR101914888B1 (en) 2014-09-12 2018-11-02 노벨리스 인크. Alloys for highly shaped aluminum products and methods of making the same
US10947613B2 (en) 2014-09-12 2021-03-16 Novelis Inc. Alloys for highly shaped aluminum products and methods of making the same
JP2018510967A (en) * 2015-03-13 2018-04-19 ノベリス・インコーポレイテッドNovelis Inc. Highly formed aluminum alloy for packaging products and method for producing the same
US11433441B2 (en) 2016-08-30 2022-09-06 Kaiser Aluminum Warrick, Llc Aluminum sheet with enhanced formability and an aluminum container made from aluminum sheet

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