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JP2004087824A - Electric double layer capacitor - Google Patents

Electric double layer capacitor Download PDF

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Publication number
JP2004087824A
JP2004087824A JP2002247302A JP2002247302A JP2004087824A JP 2004087824 A JP2004087824 A JP 2004087824A JP 2002247302 A JP2002247302 A JP 2002247302A JP 2002247302 A JP2002247302 A JP 2002247302A JP 2004087824 A JP2004087824 A JP 2004087824A
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Japan
Prior art keywords
electric double
layer capacitor
electrode
layers
double layer
Prior art date
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Ceased
Application number
JP2002247302A
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Japanese (ja)
Inventor
Kazutoshi Takeda
竹田 和俊
Tsugio Sakai
酒井 次夫
Shinichi Takasugi
高杉 信一
Yoshifumi Maehara
前原 芳文
Masahito Takenaka
竹中 雅人
Morinobu Endo
遠藤 守信
Tetsuo Uchiyama
内山 哲夫
Tatsuya Suzuki
鈴木 達也
Yoshikazu Fujisawa
藤澤 義和
Minoru Noguchi
野口 実
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honda Motor Co Ltd
SII Micro Parts Ltd
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Honda Motor Co Ltd
SII Micro Parts Ltd
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Priority to JP2002247302A priority Critical patent/JP2004087824A/en
Publication of JP2004087824A publication Critical patent/JP2004087824A/en
Ceased legal-status Critical Current

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/13Energy storage using capacitors

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  • Electric Double-Layer Capacitors Or The Like (AREA)

Abstract

【課題】電気二重層キャパシタの電極に対する電解液の含浸性向上を図る。
【解決手段】二層以上から構成した電極を用いた電気二重層キャパシタであり、活性炭を主成分とするシートを二層以上積層して構成し、積層した電極の層間に導電体を介在させた電極を用いた電気二重層キャパシタ。
【選択図】  図1
An object of the present invention is to improve the impregnation of an electrode of an electric double layer capacitor with an electrolyte.
An electric double layer capacitor using an electrode composed of two or more layers is formed by laminating two or more sheets mainly composed of activated carbon, and a conductor is interposed between layers of the laminated electrodes. Electric double layer capacitor using electrodes.
[Selection diagram] Fig. 1

Description

【0001】
【発明の属する技術分野】
本発明は、電気二重層キャパシタに関する。
【0002】
【従来の技術】
従来の電気二重層キャパシタは、積層されていない電極、すなわち一層からなる電極を使用していた。例えば、特許第3195475号公報(特開平06−215738号公報)に記載されている。
【0003】
【発明が解決しようとする課題】
しかし、従来の電気二重層キャパシタは内部抵抗が高いため、大電流での充電・放電ができなかった。そのため、大電流での充電容量が小さく、かつ大電流での放電容量が小さいという問題点があった。この問題点は、従来の電気二重層キャパシタの電極は、単層で構成されているため、電極と電解液との接触面積が少なく、電解液の浸透性と電解液の含浸性が悪いためである。特に、電気二重層キャパシタの厚みが厚くなる場合、使用される電極が厚くなるため、この問題点はより顕著に現われる。
【0004】
【課題を解決するための手段】
これらの課題を解決するために、本発明は二層以上から構成した電極を用いる電気二重層キャパシタである。本発明は二層以上から構成した電極、セパレータ、二層以上から構成した電極にて構成する電気二重層キャパシタである。本発明は活性炭を主成分とするシートを二層以上積層して構成した電極を用いる電気二重層キャパシタである。本発明は活性炭を主成分とするシートを二層以上積層した電極、セパレータ、活性炭を主成分とするシートを二層以上積層した電極にて構成する電気二重層キャパシタである。本発明は前記層間に導電体を介在させた電気二重層キャパシタである。本発明は前記導電体がアルミニウム、炭素導電性接着剤、炭素シート、炭素フェルト、炭素紙である電気二重層キャパシタである。本発明は前記層間に多孔性導電体を介在させた電気二重層キャパシタである。本発明は前記多孔性導電体が炭素繊維である電気二重層キャパシタである。
【0005】
すなわち、本願発明の特徴は、二層以上から構成され、二層間には導電体を介在させた電極を有する電気二重層キャパシタという構成にある。
【0006】
このように構成された本発明では、(1)内部抵抗を小さくできた、(2)大電流での充電・放電が可能となった、(3)放電容量を大きくできた等の効果が得られた。このような上記の効果が発現する理由は、本発明に係わる電極は、二層以上が積層しているため、電解液の浸透性、含浸性が向上するからである。ここで、電解液の浸透性とは、電解液が電極に浸透する特性で、短時間に浸透するほど浸透性が優れていることになる。電解液の含浸性とは、電解液が電極内に浸透したのち、含まれ、保持されている電解液量を言う。電解液量は、通常電解液重量にて測定される。この電解液量が多いものほど電解液の含浸性が優れている。
【0007】
本発明は二層以上から構成した電極、セパレータ、二層以上から構成した電極にて構成する電気二重層キャパシタであるので、正極、負極とも電解液の浸透性と含浸性が向上し、(1)内部抵抗を小さくできた、(2)大電流での充電・放電が可能となった、(3)放電容量を大きくできた等の上記記載の効果が得られる。本発明は活性炭を主成分とするシートを二層以上積層して構成した電極を用いる電気二重層キャパシタであるので、大容量のキャパシタが得られる。これは、活性炭の比表面積が大きく、活性炭と電解液との接触面積が多くなり、吸着・脱吸着するイオン数が多くなるためである。活性炭はヤシ殻、石炭ピッチ、フェノール樹脂を原料とし、さらに、二層以上から構成した電極であるので、電解液の浸透性と含浸性が向上し、上記の効果が一層大きく得られる。
【0008】
本発明は活性炭を主成分とするシートを二層以上積層した電極、セパレータ、活性炭を主成分とするシートを二層以上積層した電極にて構成する電気二重層キャパシタであるので、正極、負極とも電解液の浸透性と含浸性が向上し、(1)内部抵抗を小さくできた、(2)大電流での充電・放電が可能となった、(3)放電容量を大きくできた等の上記記載の効果が得られる。本発明は前記層間に導電体を介在させた電気二重層キャパシタであるので、層間の接触電気抵抗が小さくなり、一層、(1)内部抵抗を小さくできた、(2)大電流での充電・放電が可能となった、(3)放電容量を大きくできた等の効果が得られる。
【0009】
本発明は前記導電体がアルミニウム、炭素導電性接着剤、炭素シート、炭素フェルト、炭素紙である電気二重層キャパシタである。これら材料は、電池の中に使用しても安定であるので望ましい材料である。本発明は前記層間に多孔性導電体を介在させた電気二重層キャパシタである。この多孔性導電体は多くの孔を有しているので電解液を浸透したり、含浸したりする特性が優れている。本発明は前記多孔性導電体が炭素繊維である電気二重層キャパシタである。炭素繊維は均一な厚みのものが得られ、電気導電性に優れ、かつ多孔を有していいるので電解液を浸透したり、含浸したりする特性が優れている。
【0010】
以上詳述したとおり、本発明の電気二重層キャパシタの電極は、二層以上で構成されているため、電極と電解液との接触面積が多くなり、電解液の浸透性と電解液の含浸性が良好となる。特に、電気二重層キャパシタの厚みが厚くなって、使用される電極が厚くなる場合に、一層有効である。本発明の電気二重層キャパシタは、内部抵抗が小さくなり、大電流での充電・放電ができ、大電流での充電容量・放電容量が大きくなる効果を有する。
【0011】
【発明の実施の形態】
本発明の実施の形態について説明する。
【0012】
(実施形態1)
図1は、本発明の電気二重層キャパシタの部分断面図である。1は正極缶であり、内面に集電体として導電性ペースト2が塗布されている。正極缶1の中に、正極電極として、電極3、導電性接着剤からなる導電体4、電極3を重ねて配設する。一方、負極缶7の内面に集電体として導電性ペースト2が塗布されている。負極缶7の中に、負極電極として、電極3、導電性接着剤からなる導電体4、電極3、セパレータ5を重ねて配設する。有機電解液として1モルのテトラエチルリン酸のホウフッ化塩を溶解したプロピレンカーボネートの所定量を電池缶に注入する。正極缶1はガスケット6を介して負極缶7とでカシメ封口され、電気二重層キャパシタとする。なお、電極3は活性炭を主体としており、シート状もしくは成形体等のものが使用に適している。シート状もしくは成形体とする理由は、電極3の活性炭含有量を多くして、高容量化を図る上で有利であるからである。ボタン型、コイン型の電気二重層キャパシタなので、電極3はディスク状が望ましいが、これに拘らない。本実施形態では、電極3が二層の場合について説明したが、三層以上でも構わない。また、アルミニウム箔に二層以上の電極を貼りあわせたり、ラミネートしたり、接着したりすることも採用できる。
【0013】
(実施形態2)
電極3と電極3とを直接積層している点以外は、実施形態1と同じ構成の電気二重層キャパシタである。本実施形態では、電極3が二層の場合について説明したが、三層以上でも構わない。
【0014】
(実施形態3)
導電体4が炭素フェルトである点以外は、実施形態1と同じ構成の電気二重層キャパシタである。炭素フェルト以外に、導電体4としてアルミニウム、炭素シート、炭素紙が使用できる。炭素フェルト、アルミニウム、炭素シート、炭素紙は厚みがほぼ一定であるので、電極の積層化の厚みをコントロールする上で有利である。本実施形態では、電極3が二層の場合について説明したが、三層以上でも構わない。
【0015】
(実施形態4)
導電体4に多孔性導電体として炭素繊維を使用した点以外は、実施形態1と同じ構成の電気二重層キャパシタである。本実施形態では、電極3が二層の場合について説明したが、三層以上でも構わない。
【0016】
(比較例)
図2は、従来の電気二重層キャパシタの部分断面図である。11は正極缶であり、内面に導電性ペースト12が塗布されている。正極缶11の中に、正極電極として単層の電極13が配設されている。一方、負極缶17の内面に導電性ペースト12が塗布されている。負極缶17の中に、負極電極として単層の電極13が配設されている。有機電解液として1モルのテトラエチルリン酸のホウフッ化塩を溶解したプロピレンカーボネートの所定量を電池缶に注入する。正極缶11はガスケット16を介して負極缶17とでカシメ封口され、電気二重層キャパシタとする。
【0017】
(実施形態5)
厚み40μmのアルミニウム箔に、厚み50μmの活性炭を主体とするシートを三層積層(厚み150μm)して電極とし、18650サイズ(外形18mm、高さ6.5mm)の円筒型電気二重層キャパシタを組み立てた。厚み150μmの電極使用した電気二重層キャパシタに比べ、三層からなる電極を使用した電気二重層キャパシタは、内部抵抗が小さくなり、結果として、大きな充電電流での充電と大きな放電電流での放電が可能となり、放電容量が大きくなった。
【0018】
(実施形態6)
実施形態1,2,3,4および比較例につき、外形6.8mm、高さ2.1mmのサイズの電気二重層キャパシタを試作した。充電時の内部抵抗、放電容量を測定した。充電条件は2.5Vの充電規制を行いながら、定電流25mA、30分間充電である。放電条件は100μAで定電流放電を行った。内部抵抗はf=1KHzでの交流法による測定である。その結果を次の表1に示す。データはn=50個の平均値である。
【0019】
【表1】

Figure 2004087824
【0020】
実施形態1は、層間を導電性接着剤で接着していることと、二層からなる電極を採用しているため、層間の電気的接触の向上と電解液の浸透性と含浸性の向上により、内部抵抗と放電容量が大幅に向上している。電解液は層間にも入り込み、層の中に浸透、含浸してゆくので、電極全体に浸透し、含浸してゆくことになる。実施形態2は層間同士を直接積層して接触していることと、二層からなる電極を採用しているため、層間の電気的接触の向上と電解液の浸透性と含浸性の向上により、内部抵抗と放電容量が大幅に向上している。電解液は層間にも入り込み、層の中に浸透、含浸してゆくので、電極全体に浸透し、含浸してゆくことになる。ただ、層同士を確実に電気的に接続する点では、実施形態1のように導電性接着剤等の使用が望ましい。実施形態3は、層間に炭素フェルトを介在させて層同士を接触していることと、二層からなる電極を採用しているため、層間の電気的接触の向上と電解液の浸透性と含浸性の向上により、内部抵抗と放電容量が大幅に向上している。この炭素フェルトを通して電解液は層間にも入り込み、層の中に浸透、含浸してゆくので、電極全体に浸透し、含浸してゆくことになる。
【0021】
また、炭素フェルトは電気導電性に優れているので層間の電気的接続も確実になる。実施形態4は、層間に炭素繊維を介在させて層同士を接触していることと、二層からなる電極を採用しているため、層間の電気的接触の向上と電解液の浸透性と含浸性の向上により、内部抵抗と放電容量が大幅に向上している。この炭素繊維を通して電解液は層間にも入り込み、層の中に浸透、含浸してゆくので、電極全体に浸透し、含浸してゆくことになる。また、炭素繊維は電気導電性に優れているので層間の電気的接続も確実になる。本発明の電気二重層キャパシタは、従来の電気二重層キャパシタである比較例に比べて内部抵抗で約1/10〜1/20に低減し、放電容量で約30〜50%アップしている。
【0022】
【発明の効果】
本発明によれば以上説明したような手段を採用することによって、本発明の電気二重層キャパシタは、内部抵抗が小さくなり、大電流での充電と放電ができ、大電流での充電容量と放電容量が大きくなる効果を有する。
【図面の簡単な説明】
【図1】本発明の電気二重層キャパシタの一実施形態を示す部分断面図である。
【図2】従来の電気二重層キャパシタの部分断面図である。
【符号の説明】
1,11 正極缶
2,12 導電性ペースト
3,13 電極
4 導電体
5,15 セパレータ
6,16 ガスケット
7,17 負極缶。[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to an electric double layer capacitor.
[0002]
[Prior art]
Conventional electric double layer capacitors use electrodes that are not stacked, that is, single-layer electrodes. For example, it is described in Japanese Patent No. 3195475 (JP-A-06-215738).
[0003]
[Problems to be solved by the invention]
However, the conventional electric double layer capacitor cannot charge / discharge with a large current due to high internal resistance. Therefore, there is a problem that the charge capacity at a large current is small and the discharge capacity at a large current is small. This problem is because the electrode of the conventional electric double layer capacitor is formed of a single layer, so that the contact area between the electrode and the electrolyte is small, and the permeability of the electrolyte and the impregnation of the electrolyte are poor. is there. In particular, when the thickness of the electric double layer capacitor is large, the problem is more remarkable because the electrodes used are thick.
[0004]
[Means for Solving the Problems]
In order to solve these problems, the present invention is an electric double layer capacitor using an electrode composed of two or more layers. The present invention is an electric double layer capacitor including an electrode and a separator composed of two or more layers, and an electrode composed of two or more layers. The present invention is an electric double layer capacitor using an electrode constituted by laminating two or more sheets mainly composed of activated carbon. The present invention relates to an electric double-layer capacitor including an electrode in which two or more sheets mainly composed of activated carbon are laminated, a separator, and an electrode in which two or more sheets mainly composed of activated carbon are laminated. The present invention is an electric double layer capacitor in which a conductor is interposed between the layers. The present invention is the electric double layer capacitor in which the conductor is aluminum, a carbon conductive adhesive, a carbon sheet, carbon felt, or carbon paper. The present invention is an electric double layer capacitor in which a porous conductor is interposed between the layers. The present invention is an electric double layer capacitor in which the porous conductor is a carbon fiber.
[0005]
That is, the feature of the present invention resides in a structure of an electric double layer capacitor having two or more layers and having an electrode with a conductor interposed between the two layers.
[0006]
According to the present invention configured as described above, effects such as (1) reduction in internal resistance, (2) charge / discharge with a large current, and (3) increase in discharge capacity are obtained. Was done. The reason that the above-described effects are exhibited is that the electrode according to the present invention has two or more layers, so that the permeability and impregnation of the electrolytic solution are improved. Here, the permeability of the electrolyte is a property that the electrolyte penetrates the electrode, and the more the electrolyte permeates in a shorter time, the better the permeability. The impregnating property of the electrolyte refers to the amount of the electrolyte contained and retained after the electrolyte has penetrated into the electrode. The amount of the electrolyte is usually measured by the weight of the electrolyte. The larger the amount of the electrolytic solution, the better the impregnation property of the electrolytic solution.
[0007]
Since the present invention is an electric double-layer capacitor composed of an electrode composed of two or more layers, a separator and an electrode composed of two or more layers, both the positive electrode and the negative electrode have improved electrolyte permeability and impregnation, and (1) The following effects can be obtained: (1) the internal resistance could be reduced, (2) charging / discharging at a large current became possible, and (3) the discharging capacity was increased. Since the present invention is an electric double layer capacitor using an electrode constituted by laminating two or more sheets mainly composed of activated carbon, a large capacity capacitor can be obtained. This is because the specific surface area of the activated carbon is large, the contact area between the activated carbon and the electrolytic solution is increased, and the number of ions to be adsorbed and desorbed is increased. Activated carbon is an electrode composed of coconut shell, coal pitch, and phenolic resin as raw materials, and is further composed of two or more layers. Therefore, the permeability and impregnation of the electrolytic solution are improved, and the above effects can be further enhanced.
[0008]
Since the present invention is an electric double-layer capacitor composed of an electrode in which two or more layers of sheets mainly containing activated carbon are laminated, a separator, and an electrode in which two or more layers of sheets mainly containing activated carbon are laminated, both the positive electrode and the negative electrode are used. The permeation and impregnation of the electrolytic solution were improved, (1) the internal resistance could be reduced, (2) charging and discharging at a large current became possible, and (3) the discharging capacity was increased. The effects described are obtained. Since the present invention is an electric double layer capacitor in which a conductor is interposed between the layers, the contact electric resistance between the layers is reduced, and (1) the internal resistance can be further reduced, and (2) charging and charging with a large current. The following effects are obtained: discharge is enabled, and (3) discharge capacity is increased.
[0009]
The present invention is the electric double layer capacitor in which the conductor is aluminum, a carbon conductive adhesive, a carbon sheet, carbon felt, or carbon paper. These materials are desirable because they are stable when used in batteries. The present invention is an electric double layer capacitor in which a porous conductor is interposed between the layers. Since this porous conductor has many pores, it has excellent characteristics of penetrating and impregnating the electrolyte. The present invention is an electric double layer capacitor in which the porous conductor is a carbon fiber. The carbon fiber has a uniform thickness, is excellent in electric conductivity, and is porous, so that it has excellent characteristics of penetrating or impregnating the electrolytic solution.
[0010]
As described above in detail, since the electrode of the electric double layer capacitor of the present invention is composed of two or more layers, the contact area between the electrode and the electrolyte is increased, and the permeability of the electrolyte and the impregnation of the electrolyte are increased. Is good. In particular, this is more effective when the thickness of the electric double layer capacitor is increased and the electrodes used are increased. The electric double layer capacitor of the present invention has an effect that the internal resistance is reduced, charging and discharging can be performed with a large current, and the charging capacity and discharging capacity with a large current can be increased.
[0011]
BEST MODE FOR CARRYING OUT THE INVENTION
An embodiment of the present invention will be described.
[0012]
(Embodiment 1)
FIG. 1 is a partial sectional view of the electric double layer capacitor of the present invention. Reference numeral 1 denotes a positive electrode can, and a conductive paste 2 is applied on the inner surface as a current collector. In a positive electrode can 1, an electrode 3, a conductor 4 made of a conductive adhesive, and an electrode 3 are arranged in a stacked manner as a positive electrode. On the other hand, the conductive paste 2 is applied to the inner surface of the negative electrode can 7 as a current collector. In a negative electrode can 7, an electrode 3, a conductor 4 made of a conductive adhesive, an electrode 3, and a separator 5 are arranged in a stacked manner as a negative electrode. A predetermined amount of propylene carbonate in which 1 mol of borofluoride of tetraethylphosphoric acid is dissolved as an organic electrolyte is poured into a battery can. The positive electrode can 1 is crimp-sealed with the negative electrode can 7 via a gasket 6 to form an electric double layer capacitor. The electrode 3 is mainly made of activated carbon, and a sheet-like or molded article is suitable for use. The reason why the electrode 3 is formed into a sheet or a molded article is that it is advantageous to increase the activated carbon content of the electrode 3 to increase the capacity. Since it is a button type or coin type electric double layer capacitor, the electrode 3 is preferably in a disk shape, but is not limited to this. In the present embodiment, the case where the electrode 3 has two layers has been described, but three or more layers may be used. Further, it is also possible to apply, laminate, or bond two or more layers of electrodes to the aluminum foil.
[0013]
(Embodiment 2)
This is an electric double layer capacitor having the same configuration as that of the first embodiment except that the electrodes 3 and 3 are directly laminated. In the present embodiment, the case where the electrode 3 has two layers has been described, but three or more layers may be used.
[0014]
(Embodiment 3)
The electric double layer capacitor has the same configuration as that of the first embodiment except that the conductor 4 is carbon felt. In addition to carbon felt, aluminum, a carbon sheet, and carbon paper can be used as the conductor 4. Since carbon felt, aluminum, carbon sheet, and carbon paper have a substantially constant thickness, it is advantageous in controlling the thickness of electrode lamination. In the present embodiment, the case where the electrode 3 has two layers has been described, but three or more layers may be used.
[0015]
(Embodiment 4)
The electric double layer capacitor has the same configuration as that of the first embodiment except that carbon fibers are used as the porous conductor for the conductor 4. In the present embodiment, the case where the electrode 3 has two layers has been described, but three or more layers may be used.
[0016]
(Comparative example)
FIG. 2 is a partial sectional view of a conventional electric double layer capacitor. Reference numeral 11 denotes a positive electrode can, and a conductive paste 12 is applied on the inner surface. In the positive electrode can 11, a single-layer electrode 13 is provided as a positive electrode. On the other hand, the conductive paste 12 is applied to the inner surface of the negative electrode can 17. In the negative electrode can 17, a single-layer electrode 13 is provided as a negative electrode. A predetermined amount of propylene carbonate in which 1 mol of borofluoride of tetraethylphosphoric acid is dissolved as an organic electrolyte is poured into a battery can. The positive electrode can 11 is crimp-sealed with the negative electrode can 17 via a gasket 16 to form an electric double layer capacitor.
[0017]
(Embodiment 5)
An electrode is formed by laminating three layers (150 μm in thickness) of a sheet mainly composed of activated carbon with a thickness of 50 μm on an aluminum foil having a thickness of 40 μm, and assembling a cylindrical electric double-layer capacitor of 18650 size (outer diameter 18 mm, height 6.5 mm). Was. Compared with an electric double layer capacitor using a 150 μm-thick electrode, an electric double layer capacitor using a three-layer electrode has a lower internal resistance, and as a result, charging with a large charging current and discharging with a large discharging current can be performed. Enabled and the discharge capacity increased.
[0018]
(Embodiment 6)
With respect to the embodiments 1, 2, 3, 4 and the comparative example, an electric double layer capacitor having an outer shape of 6.8 mm and a height of 2.1 mm was prototyped. The internal resistance and the discharge capacity during charging were measured. The charging conditions are charging at a constant current of 25 mA for 30 minutes while charging is regulated at 2.5 V. The discharge was performed at a constant current of 100 μA. The internal resistance is measured by an alternating current method at f = 1 KHz. The results are shown in Table 1 below. The data is the average of n = 50.
[0019]
[Table 1]
Figure 2004087824
[0020]
In the first embodiment, since the layers are adhered with the conductive adhesive and the electrode composed of two layers is employed, the electric contact between the layers is improved, and the permeability and impregnation of the electrolytic solution are improved. In addition, the internal resistance and discharge capacity have been greatly improved. The electrolyte penetrates into the layers and penetrates and impregnates into the layers, so that it penetrates and impregnates the entire electrode. In Embodiment 2, since the layers are directly laminated and in contact with each other, and the electrode is composed of two layers, the electric contact between the layers is improved, and the permeability and impregnation of the electrolytic solution are improved. The internal resistance and discharge capacity have been greatly improved. The electrolyte penetrates into the layers and penetrates and impregnates into the layers, so that it penetrates and impregnates the entire electrode. However, in order to surely electrically connect the layers, it is desirable to use a conductive adhesive or the like as in the first embodiment. In Embodiment 3, since the layers are in contact with each other with a carbon felt interposed between the layers and an electrode composed of two layers is employed, the electric contact between the layers is improved, and the permeability and impregnation of the electrolytic solution are improved. Due to the improvement of the performance, the internal resistance and the discharge capacity have been greatly improved. The electrolytic solution penetrates between the layers through the carbon felt and penetrates and impregnates into the layers, so that it penetrates and impregnates the entire electrode.
[0021]
In addition, since carbon felt is excellent in electric conductivity, electric connection between layers is also ensured. The fourth embodiment employs the fact that the layers are in contact with each other with carbon fibers interposed between the layers and that the electrodes are composed of two layers. Due to the improvement of the performance, the internal resistance and the discharge capacity have been greatly improved. The electrolytic solution penetrates between the layers through the carbon fiber and penetrates and impregnates into the layers, so that it penetrates and impregnates the entire electrode. In addition, since the carbon fiber is excellent in electrical conductivity, electrical connection between layers is also ensured. The electric double layer capacitor of the present invention has an internal resistance reduced to about 1/10 to 1/20 and a discharge capacity increased by about 30 to 50% as compared with a comparative example which is a conventional electric double layer capacitor.
[0022]
【The invention's effect】
According to the present invention, by employing the above-described means, the electric double layer capacitor of the present invention has a low internal resistance, can be charged and discharged at a large current, and has a large capacity and a discharged capacity at a large current. This has the effect of increasing the capacity.
[Brief description of the drawings]
FIG. 1 is a partial sectional view showing an embodiment of an electric double layer capacitor of the present invention.
FIG. 2 is a partial cross-sectional view of a conventional electric double layer capacitor.
[Explanation of symbols]
1,11 Positive electrode can 2,12 Conductive paste 3,13 Electrode 4 Conductor 5,15 Separator 6,16 Gasket 7,17 Negative electrode can.

Claims (9)

二層以上から構成した電極を用いることを特徴とする電気二重層キャパシタ。An electric double layer capacitor using an electrode composed of two or more layers. 二層以上から構成した電極、セパレータ、二層以上から構成した電極にて構成することを特徴とする電気二重層キャパシタ。An electric double-layer capacitor, comprising an electrode composed of two or more layers, a separator, and an electrode composed of two or more layers. 活性炭を主成分とするシートを二層以上積層して構成した電極を用いることを特徴とする電気二重層キャパシタ。An electric double layer capacitor using an electrode formed by laminating two or more sheets mainly composed of activated carbon. 活性炭を主成分とするシートを二層以上積層した電極、セパレータ、活性炭を主成分とするシートを二層以上積層した電極にて構成することを特徴とする電気二重層キャパシタ。An electric double layer capacitor comprising: an electrode in which two or more sheets mainly composed of activated carbon are laminated; a separator; and an electrode in which two or more sheets mainly composed of activated carbon are laminated. 前記二層以上積層した電極の層間に、導電体を介在させたことを特徴とする請求項1乃至4のいずれかに記載の電気二重層キャパシタ。The electric double layer capacitor according to any one of claims 1 to 4, wherein a conductor is interposed between the two or more stacked electrodes. 二層以上電極が積層された電極であり、前記積層された電極の層間に導電体を有することを特徴とする電気二重層キャパシタ。An electric double layer capacitor comprising: an electrode in which two or more layers of electrodes are stacked; and a conductor between layers of the stacked electrodes. 前記導電体は、アルミニウム、炭素導電性接着剤、炭素シート、炭素フェルト、炭素紙であることを特徴とする請求項5または6に記載の電気二重層キャパシタ。The electric double layer capacitor according to claim 5, wherein the conductor is aluminum, a carbon conductive adhesive, a carbon sheet, carbon felt, or carbon paper. 二層以上積層した電極の層間に、多孔性導電体を介在させたことを特徴とする請求項1乃至6のいずれかに記載の電気二重層キャパシタ。7. The electric double layer capacitor according to claim 1, wherein a porous conductor is interposed between two or more laminated electrodes. 多孔性導電体は、炭素繊維であることを特徴とする請求項8に記載の電気二重層キャパシタ。The electric double layer capacitor according to claim 8, wherein the porous conductor is a carbon fiber.
JP2002247302A 2002-08-27 2002-08-27 Electric double layer capacitor Ceased JP2004087824A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7414825B2 (en) 2005-06-27 2008-08-19 Sanyo Electric Co., Ltd. Electrochemical device
WO2009026442A1 (en) * 2007-08-23 2009-02-26 The Boeing Company Conductive scrim embedded structural adhesive films

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7414825B2 (en) 2005-06-27 2008-08-19 Sanyo Electric Co., Ltd. Electrochemical device
WO2009026442A1 (en) * 2007-08-23 2009-02-26 The Boeing Company Conductive scrim embedded structural adhesive films
US7628879B2 (en) 2007-08-23 2009-12-08 The Boeing Company Conductive scrim embedded structural adhesive films
EP2527415A1 (en) * 2007-08-23 2012-11-28 The Boeing Company Conductive scrim embedded structural adhesive films

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