JP2004067518A - Method for treating hair - Google Patents
Method for treating hair Download PDFInfo
- Publication number
- JP2004067518A JP2004067518A JP2002224480A JP2002224480A JP2004067518A JP 2004067518 A JP2004067518 A JP 2004067518A JP 2002224480 A JP2002224480 A JP 2002224480A JP 2002224480 A JP2002224480 A JP 2002224480A JP 2004067518 A JP2004067518 A JP 2004067518A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- basic
- agent
- dyeing
- skin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 36
- 239000000981 basic dye Substances 0.000 claims abstract description 11
- 239000007844 bleaching agent Substances 0.000 claims description 6
- 239000000118 hair dye Substances 0.000 claims description 5
- 238000004043 dyeing Methods 0.000 abstract description 30
- 230000000694 effects Effects 0.000 abstract description 14
- 239000000203 mixture Substances 0.000 description 12
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 7
- 239000000975 dye Substances 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 7
- 239000007800 oxidant agent Substances 0.000 description 7
- 238000007796 conventional method Methods 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- -1 BASIC V OLET 11: 1 Chemical compound 0.000 description 4
- 239000000980 acid dye Substances 0.000 description 4
- 239000002552 dosage form Substances 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 238000010186 staining Methods 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
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- 239000001026 semi permanent hair color Substances 0.000 description 3
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
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- RFQSMLBZXQOMKK-UHFFFAOYSA-N [3-[(4,8-diamino-6-bromo-1,5-dioxonaphthalen-2-yl)amino]phenyl]-trimethylazanium;chloride Chemical compound [Cl-].C[N+](C)(C)C1=CC=CC(NC=2C(C3=C(N)C=C(Br)C(=O)C3=C(N)C=2)=O)=C1 RFQSMLBZXQOMKK-UHFFFAOYSA-N 0.000 description 2
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- DWKARHJHPSUOBW-UHFFFAOYSA-N trimethyl-[3-[(2e)-2-(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)hydrazinyl]phenyl]azanium;chloride Chemical compound [Cl-].CC1=NN(C=2C=CC=CC=2)C(O)=C1N=NC1=CC=CC([N+](C)(C)C)=C1 DWKARHJHPSUOBW-UHFFFAOYSA-N 0.000 description 2
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- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
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- QAMCXJOYXRSXDU-UHFFFAOYSA-N 2,4-dimethoxy-n-[2-(1,3,3-trimethylindol-1-ium-2-yl)ethenyl]aniline;chloride Chemical compound [Cl-].COC1=CC(OC)=CC=C1NC=CC1=[N+](C)C2=CC=CC=C2C1(C)C QAMCXJOYXRSXDU-UHFFFAOYSA-N 0.000 description 1
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- AXDJCCTWPBKUKL-UHFFFAOYSA-N 4-[(4-aminophenyl)-(4-imino-3-methylcyclohexa-2,5-dien-1-ylidene)methyl]aniline;hydron;chloride Chemical compound Cl.C1=CC(=N)C(C)=CC1=C(C=1C=CC(N)=CC=1)C1=CC=C(N)C=C1 AXDJCCTWPBKUKL-UHFFFAOYSA-N 0.000 description 1
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- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- WLKAMFOFXYCYDK-UHFFFAOYSA-N [5-amino-4-[[3-[(2-amino-4-azaniumyl-5-methylphenyl)diazenyl]-4-methylphenyl]diazenyl]-2-methylphenyl]azanium;dichloride Chemical compound [Cl-].[Cl-].CC1=CC=C(N=NC=2C(=CC([NH3+])=C(C)C=2)N)C=C1N=NC1=CC(C)=C([NH3+])C=C1N WLKAMFOFXYCYDK-UHFFFAOYSA-N 0.000 description 1
- IURGIPVDZKDLIX-UHFFFAOYSA-M [7-(diethylamino)phenoxazin-3-ylidene]-diethylazanium;chloride Chemical compound [Cl-].C1=CC(=[N+](CC)CC)C=C2OC3=CC(N(CC)CC)=CC=C3N=C21 IURGIPVDZKDLIX-UHFFFAOYSA-M 0.000 description 1
- HSWXSHNPRUMJKI-UHFFFAOYSA-N [8-[(2-methoxyphenyl)hydrazinylidene]-7-oxonaphthalen-2-yl]-trimethylazanium;chloride Chemical compound [Cl-].COC1=CC=CC=C1N\N=C/1C2=CC([N+](C)(C)C)=CC=C2C=CC\1=O HSWXSHNPRUMJKI-UHFFFAOYSA-N 0.000 description 1
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- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
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- HWYNRVXFYFQSID-UHFFFAOYSA-M benzo[a]phenoxazin-9-ylidene(dimethyl)azanium;chloride Chemical compound [Cl-].C1=CC=C2C(N=C3C=CC(C=C3O3)=[N+](C)C)=C3C=CC2=C1 HWYNRVXFYFQSID-UHFFFAOYSA-M 0.000 description 1
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- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- VYXSBFYARXAAKO-UHFFFAOYSA-N ethyl 2-[3-(ethylamino)-6-ethylimino-2,7-dimethylxanthen-9-yl]benzoate;hydron;chloride Chemical compound [Cl-].C1=2C=C(C)C(NCC)=CC=2OC2=CC(=[NH+]CC)C(C)=CC2=C1C1=CC=CC=C1C(=O)OCC VYXSBFYARXAAKO-UHFFFAOYSA-N 0.000 description 1
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- 229930195733 hydrocarbon Natural products 0.000 description 1
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
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- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
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- Cosmetics (AREA)
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Abstract
Description
【０００１】
【発明の属する技術分野】
本発明は、手や皮膚に染まらず、毛髪に対して優れた発色・染毛効果を有する毛髪処理方法に関する。
【０００２】
【従来の技術及び発明が解決しようとする課題】
近年、自分の髪のニュアンスを変えたり、白髪を隠したいという消費者の要望が高まり、毛髪を染毛する多くの商品が開発されている。最も汎用されているものとしては、パラフェニレンジアミン等の酸化染料を含有する第１剤と酸化剤を含有する第２剤よりなる２剤型の酸化染毛剤であり、これは、使用時に２剤を混合しアルカリ性下で過酸化水素等の酸化剤を作用させて酸化・発色せしめるものである。しかし、酸化染毛剤は、扱い方によっては、毛髪損傷や皮膚刺激を余計に引き起こす場合もある。また、酸化染料を用いず、酸性染料やニトロ染料等の直接染料を用いた、頭皮や頭髪に対して影響の少ない半永久染毛料が開発されてきた。半永久染毛剤としては、酸性染料を用いたヘアマニキュア等が市販品として挙げられる。しかし、これら半永久染毛料は、未処理の毛髪では充分な発色が得られにくく、酸性染料を用いたものは、手や皮膚に染着しやすく、使用時には専用の手袋を着けて染毛し、また、皮膚に着色した場合は専用のリムーバー等を使用して落とさなければならず、使用時に皮膚や周囲に着かないように注意したり、非常に煩雑な操作を強いられるのが現状である。
【０００３】
そこで、手や顔等の皮膚に染着せず、優れた染毛・発色効果を有し、かつ酸化染料を用いた場合に比べ、毛髪へのダメージの少ない毛髪処理方法の開発が強く望まれていた。
【０００４】
【課題を解決するための手段】
本発明者は、斯かる実情に鑑み鋭意検討した結果、脱色剤で処理した毛髪を塩基性染料を含有する毛髪処理剤で染毛することにより、手や皮膚に染まらず、毛髪に対しては高い染毛効果と、毛髪のダメージを最小限に抑えることを見出し、本発明を完成するに至った。
【０００５】
すなわち、本発明は、脱色剤により処理した毛髪に、塩基性染料を含有する毛髪処理剤を適用することを特徴とする毛髪処理方法を提供するものである。
【０００６】
【発明の実施の形態】
以下、本発明を詳細に説明する。
【０００７】
本発明の毛髪処理方法は、第１過程として脱色剤により毛髪を脱色処理し、次いで、第２過程として塩基性染料を含有する毛髪処理剤により毛髪を染色処理することを特徴とする。本発明の脱色処理と染色処理とを行う間隔は、特に制限されないが、脱色処理直後に染色処理を行うと、良好な染毛効果を得ることができる。
【０００８】
本発明で用いられる脱色剤としては、特に限定されることなく、種々の剤型のものが対象となる。通常、過酸化水素等の酸化剤をを配合する１剤型のもの、アルカリ剤と酸化剤との組み合わせからなる２剤型のもの、アルカリ剤と酸化剤と過硫酸カリウム等を含む粉末活性化剤の３剤型等の多剤型も挙げられ、それぞれ公知のものを用いることができる。また、形態も、粉末または液状の他、クリーム状、ペースト状、ゲル状のものでも差し支えない。使用方法としては、毛髪に塗布し、例えば５〜３０分間放置した後、洗い流す。
【０００９】
本発明の脱色剤に用いられるアルカリ剤も特に限定されることなく、通常用いられているものを任意に使用することができる。具体的には、アンモニア水、モノエタノールアミン、トリエタノールアミン、水酸化ナトリウム、水酸化カリウム等が挙げられ、その配合量は通常脱色剤に用いられる範囲であれば特に限定されない。例えば毛髪に塗付する状態を規準にして０．５〜１０質量％であり、ｐＨ８〜１３に調整される量を配合する。
【００１０】
本発明の脱色剤に用いられる酸化剤も、特に制限はなく、脱色剤に通常用いられる、いずれのものも使用することができる。例えば、過酸化水素、過炭酸カリウム又はナトリウム塩、過ホウ酸カリウム又はナトリウム塩、臭素酸カリウム又はナトリウム塩、過ヨウ素酸カリウム又はナトリウム塩、過酸化尿素、硫酸ナトリウム・過酸化水素付加物、ピロリン酸ナトリウム・過酸化水素付加物等が挙げられる。また、その配合量は毛髪に塗付する状態を規準にして、通常脱色剤に用いられる範囲の０．１〜２０質量％であれば特に限定されない。
【００１１】
本発明の毛髪処理剤に用いられる塩基性染料としては、ＢＡＳＩＣ ＢＬＵＥ３、ＢＡＳＩＣ ＢＬＵＥ ６、ＢＡＳＩＣ ＢＬＵＥ ７、ＢＡＳＩＣ ＢＬＵＥ ９、ＢＡＳＩＣ ＢＬＵＥ ２６、ＢＡＳＩＣ ＢＬＵＥ ４１、ＢＡＳＩＣ ＢＬＵＥ ９９、ＢＡＳＩＣ ＢＲＯＷＮ ４、ＢＡＳＩＣ ＢＲＯＷＮ １６、ＢＡＳＩＣ ＢＲＯＷＮ １７、ＢＡＳＩＣ ＧＲＥＥＮ １、ＢＡＳＩＣ ＧＲＥＥＮ ４、ＢＡＳＩＣ ＯＲＡＮＧＥ １、ＢＡＳＩＣ ＯＲＡＮＧＥ ２、ＢＡＳＩＣ ＲＥＤ １、ＢＡＳＩＣ ＲＥＤ ２、ＢＡＳＩＣ ＲＥＤ ２２、ＢＡＳＩＣ ＲＥＤ ４６、ＢＡＳＩＣ ＲＥＤ ７６、ＢＡＳＩＣ ＲＥＤ １１８、ＢＡＳＩＣ ＶＩＯＬＥＴ １、ＢＡＳＩＣ ＶＩＯＬＥＴ ３、ＢＡＳＩＣ ＶＩＯＬＥＴ ４、ＢＡＳＩＣ ＶＩＯＬＥＴ １０、ＢＡＳＩＣ ＶＩＯＬＥＴ １１：１、ＢＡＳＩＣ ＶＩＯＬＥＴ １４、ＢＡＳＩＣ ＶＩＯＬＥＴ １６、ＢＡＳＩＣ ＹＥＬＬＯＷ １１、ＢＡＳＩＣ ＹＥＬＬＯＷ ２８、ＢＡＳＩＣ ＹＥＬＬＯＷ ５７等が挙げられ、これらの塩基性染料は、Ｃｏｓｍｅｔｉｃ Ｉｎｇｒｅｄｉｅｎｔ Ｄｉｃｔｉｏｎａｒｙ ａｎｄ Ｈａｎｄｂｏｏｋ（Ｔｈｅ Ｃｏｓｍｅｔｉｃ，Ｔｏｉｌｅｔｒｙ，ａｎｄ Ｆｒａｇｒａｎｃｅ Ａｓｓｏｃｉａｔｉｏｎ、第８巻、２０００年）に記載された公知の染料である。これら塩基性染料の中でも、ＢＡＳＩＣ ＢＬＵＥ ９９、ＢＡＳＩＣ ＢＲＯＷＮ １６、ＢＡＳＩＣ ＢＲＯＷＮ １７、ＢＡＳＩＣ ＲＥＤ ７６、ＢＡＳＩＣ ＹＥＬＬＯＷ ５７が特に好ましく、Ｗｉｌｌｉａｍｓ社よりＡＲＩＡＮＯＲ Ｓｉｅｎｎａ Ｂｒｏｗｎ、ＡＲＩＡＮＯＲ Ｍａｈｏｇａｎｙ、ＡＲＩＡＮＯＲ Ｍａｄｄｅｒ Ｒｅｄ、ＡＲＩＡＮＯＲ Ｓｔｅｅｌ Ｂｌｕｅ、ＡＲＩＡＮＯＲ Ｓｔｒａｗ Ｙｅｌｌｏｗ等の商品名で市販されている。
【００１２】
本発明の毛髪処理剤において、これらの塩基性染料は、それぞれ単独で用いることができるし、また二種以上を組み合わせて用いることもできる。また、これらの塩基性染料の毛髪処理剤中への配合量は、毛髪に塗付する状態を規準にして好ましくは０．１〜３．０質量％（以下、単に％と記する）、更に好ましくは、０．３〜１．０％の範囲である。塩基性染料の配合量が０．１％未満の場合には充分な染色効果が得られない場合があり、２．０％を超えると手や皮膚への染着が激しくなり使用上問題を生じる場合がある。本発明の塩基性染料を含む毛髪処理剤の使用方法としては、脱色剤で脱色した毛髪に塗布し、例えば５〜３０分間放置した後、洗い流す。
【００１３】
本発明の毛髪処理剤は所望により、本発明の効果を損しない範囲で、通常化粧料に一般に配合される成分、例えばエタノール、イソプロパノール等のアルコール、ラノリン誘導体、蛋白質誘導体や、メチルポリシロキサン、メチルフェニルポリシロキサン等のシリコーン油、ポリエチレングリコールの脂肪酸エステル油、ツバキ油、オリーブ油等の植物油等の油性成分、プロピレングリコール、グリセリン、ポリエチレングリコール等の保湿成分、ポリオキシエチレンアルキルエーテル等の非イオン界面活性剤アルキルスルホン酸塩等のアニオン界面活性剤、流動パラフィン、ワセリン、スクワラン等の炭化水素、水溶性高分子物質（アニオン性、非イオン性、カチオン性のものを含む）、金属イオン封鎖剤、防腐剤、ｐＨ調整剤、ビタミン類、紫外線吸収剤、酸化防止剤、色素、香料及び噴射剤等を含むことができる。また、剤型としてエアゾール、液状、乳液状、クリーム状、ゲル状等様々な剤型タイプにすることができ、特に剤型を問わない。
【００１４】
本発明の毛髪処理剤としては、ヘアマニキュア等の染毛剤、カラーリンス、カラーシャンプー、カラースタイリング剤等が挙げられる。そして、本発明の脱色剤と毛髪処理剤は、それぞれの容器に充填され、それらを組合せ、セットにして１つの商品単位として販売するのが好ましい。
【００１５】
【実施例】
以下、本発明を実施例等により、さらに具体的に説明するが、これらにより本発明の技術的範囲が限定解釈されるべきものではない。尚、実施例に先立って各実施例で採用した脱色剤、試験法及び評価法を説明する。
【００１６】
（１）脱色処理の有効性試験
未処理の毛髪と、前に脱色剤により処理した毛髪から、それぞれ作成したヘアーピース（１０ｃｍ、１ｇ）に毛髪処理剤０．５ｇを塗布し、５分間放置する。その後、温水で３０秒間洗浄して乾燥した後、２０名の専門パネルにより染毛状態を観察し、下記規準により評価した。
［評 価］ ［内容］
◎ ： 染毛効果が高いと答えたパネラーの数が１７人以上
○ ： 染毛効果が高いと答えたパネラーの数が１２人以上１７人未満
△ ： 染毛効果が高いと答えたパネラーの数が８人以上１２人未満
× ： 染毛効果が高いと答えたパネラーの数が８人未満
【００１８】
（２）皮膚への染着性試験
専門パネル２０名の上腕内側部の３ｃｍ×３ｃｍの面積部に毛髪処理剤０．５ｇを塗布し、５分間放置する。その後、温水で３０秒間洗浄して乾燥した後、下記規準により評価した。
［評 価］ ［内容］
◎ ： 皮膚への染着が少ないと答えた被験者の数が１７人以上
○ ： 皮膚への染着が少ないと答えた被験者の数が１２人以上１７人未満
△ ： 皮膚への染着が少ないと答えた被験者の数が８人以上１２人未満
× ： 皮膚への染着が少ないと答えた被験者の数が８人未満
【００１９】
（３）染毛性試験及び官能評価
前に脱色剤により処理した毛髪から作成したヘアーピース（１０ｃｍ、１ｇ）に毛髪処理剤０．５ｇを塗布し、５分間放置する。その後、温水で３０秒間洗浄して乾燥した後、２０名の専門パネルにより染毛状態、髪のくし通り、ぱさつきのなさを観察した。染毛性は前述の規準により、また、髪のくし通り、ぱさつきのなさは下記規準により評価した。
【００２０】
＜髪のくし通り＞
［評 価］ ［内容］
◎ ： くし通りが良いと答えたパネラーの数が１７人以上
○ ： くし通りが良いと答えたパネラーの数が１２人以上１７人未満
△ ： くし通りが良いと答えたパネラーの数が８人以上１２人未満
× ： くし通りが良いと答えたパネラーの数が８人未満
【００２１】
＜ぱさつきのなさ＞
［評 価］ ［内容］
◎ ： ぱさつきがないと答えたパネラーの数が１７人以上
○ ： ぱさつきがないと答えたパネラーの数が１２人以上１７人未満
△ ： ぱさつきがないと答えたパネラーの数が８人以上１２人未満
× ： ぱさつきがないと答えたパネラーの数が８人未満
【００２２】
実施例１−５、比較例１−６
表１に示す配合組成の毛髪処理剤組成物を常法に従って調製し、皮膚染着性、染毛性を評価した。その結果を併せて表１に示す。
【００２３】
【表１】
表１から明らかなように、実施例１〜５の毛髪処理剤組成物は、脱色剤による前処理を行っていない比較例１〜２、比較例３、及び酸性染料を用いた比較例５〜６と比較して、明らかに皮膚染着性、染毛性のいずれの項目においても優れていた。
【００２５】
実施例１−５、比較例７−８
表１の毛髪処理剤組成物の他に、表２に示す配合組成の酸化染料を配合した毛髪処理剤組成物を常法に従って調製し、皮膚染着性、染毛性、これらを使用した時の髪のくし通り、ぱさつきのなさを評価した。その結果を表３に示す。
【００２６】
【表２】
【表３】
表３から明らかなように、実施例１〜５の毛髪処理剤組成物は、比較例７〜８と比較して、明らかに皮膚染着性、染毛性、髪のくし通り、ぱさつきのなさのいずれの項目においても優れていた。
【００２９】
常法により上記組成の染毛剤を調製し、脱色剤により処理した毛髪に用いた結果、皮膚染着性、染毛性、髪のくし通り、ぱさつきのなさのいずれの項目においても優れていた。
【００３１】
常法により上記組成のトリートメント剤を調製し、脱色剤により処理した毛髪に用いた結果、皮膚染着性、染毛性、髪のくし通り、ぱさつきのなさのいずれの項目においても優れていた。
【００３３】
常法により上記組成のスタイリングミストを調製し、脱色剤により処理した毛髪に用いた結果、皮膚染着性、染毛性、髪のくし通り、ぱさつきのなさのいずれの項目においても優れていた。
【００３５】
尚、以上の実施例、比較例において用いた香料は下記のものである。
【００３６】
【表４】
【発明の効果】
本発明の毛髪処理方法は、手や皮膚に染まらず、毛髪に対して優れた発色・染毛効果を与えるものである。[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a hair treatment method that does not stain hands and skin and has an excellent coloring and dyeing effect on hair.
[0002]
Problems to be solved by the prior art and the invention
In recent years, there has been an increasing demand from consumers to change the nuances of their own hair or hide their gray hair, and many products for dyeing hair have been developed. Most commonly used is a two-part oxidative hair dye consisting of a first agent containing an oxidation dye such as paraphenylenediamine and a second agent containing an oxidizing agent. The mixture is mixed with an oxidizing agent such as hydrogen peroxide under alkaline conditions to cause oxidation and color development. However, oxidative hair dyes may cause extra hair damage and skin irritation depending on how they are handled. Also, semi-permanent hair dyes which use direct dyes such as acid dyes and nitro dyes without using oxidation dyes and have little effect on the scalp and hair have been developed. Examples of the semi-permanent hair dye include commercially available products such as hair manicure using an acid dye. However, these semi-permanent hair dyes are difficult to obtain sufficient color development with untreated hair, and those using acid dyes are easy to dye on hands and skin.During use, wear special gloves and dye hair. In addition, if the skin is colored, it must be removed using a special remover or the like, and at present, care must be taken not to get on the skin or the surroundings, and very complicated operations are forced at the time of use.
[0003]
Therefore, there is a strong demand for the development of a hair treatment method that does not stain on the skin of hands and face, has an excellent hair dyeing and coloring effect, and causes less damage to hair than when an oxidation dye is used. Was.
[0004]
[Means for Solving the Problems]
The present inventor has conducted intensive studies in view of such circumstances, and as a result, by dyeing hair treated with a depigmenting agent with a hair treating agent containing a basic dye, the hair and hair are not dyed on hands and skin. The present inventors have found that the present invention has a high hair dyeing effect and minimizes hair damage, and has completed the present invention.
[0005]
That is, the present invention provides a hair treatment method comprising applying a hair treatment agent containing a basic dye to hair treated with a bleaching agent.
[0006]
BEST MODE FOR CARRYING OUT THE INVENTION
Hereinafter, the present invention will be described in detail.
[0007]
The hair treatment method of the present invention is characterized in that, as a first step, hair is decolorized with a depigmenting agent, and then, as a second step, the hair is dyed with a hair treatment agent containing a basic dye. The interval at which the decoloring treatment and the dyeing treatment of the present invention are performed is not particularly limited. However, if the dyeing treatment is performed immediately after the decolorization treatment, a good hair dyeing effect can be obtained.
[0008]
The decolorizing agent used in the present invention is not particularly limited, and includes various types of dosage forms. Usually, a one-part type in which an oxidizing agent such as hydrogen peroxide is blended, a two-part type comprising a combination of an alkaline agent and an oxidizing agent, a powder activation containing an alkaline agent, an oxidizing agent, potassium persulfate, etc. A multi-part type, such as a three-part type, can also be used, and each known type can be used. The form may be a powder, a liquid, a cream, a paste, or a gel. As a method of use, it is applied to the hair, left for 5 to 30 minutes, for example, and then washed away.
[0009]
The alkaline agent used in the decolorizing agent of the present invention is not particularly limited, and any commonly used alkaline agent can be used. Specific examples include aqueous ammonia, monoethanolamine, triethanolamine, sodium hydroxide, potassium hydroxide, and the like. The blending amount is not particularly limited as long as it is within a range usually used for a decolorizing agent. For example, the amount is 0.5 to 10% by mass based on the state of application to the hair, and the amount is adjusted to pH 8 to 13.
[0010]
The oxidizing agent used in the decolorizing agent of the present invention is not particularly limited, and any of the oxidizing agents commonly used in decolorizing agents can be used. For example, hydrogen peroxide, potassium or sodium percarbonate, potassium or sodium perborate, potassium or sodium bromate, potassium or sodium periodate, urea peroxide, sodium sulfate / hydrogen peroxide adduct, pyrroline Sodium acid / hydrogen peroxide adduct and the like. The amount of the compound is not particularly limited as long as it is 0.1 to 20% by mass of the range usually used for the decoloring agent, based on the state of application to the hair.
[0011]
Examples of the basic dye used in the hair treatment agent of the present invention include BASIC BLUE3, BASIC BLUE 6, BASIC BLUE 7, BASIC BLUE 9, BASIC BLUE 26, BASIC BLUE 41, BASIC BLUE 99, BASIC BROWN 4, and BASIC BROWN. BASIC BROWN 17, BASIC GREEN 1, BASIC GREEN 4, BASIC ORANGE 1, BASIC ORANGE 2, BASIC RED 1, BASIC RED 2, BASIC RED 22, BASIC RED 46, BASIC VIC RED 76, BASIC VIC LIC 76 3, BASIC VIOLET 4, BASIC VIOLET 10, BASIC V OLET 11: 1, BASIC VIOLET 14, BASIC VIOLET 16, BASIC YELLOW 11, BASIC YELLOW 28, BASIC YELLOW 57, and the like. , Vol. 8, 2000). Among these basic dyes, BASIC BLUE 99, BASIC BROWN 16, BASIC BROWN 17, BASIC RED 76, and BASIC YELLOW 57 are particularly preferable. It is commercially available under a trade name such as Yellow.
[0012]
In the hair treatment composition of the present invention, these basic dyes can be used alone or in combination of two or more. The amount of these basic dyes to be incorporated into the hair treatment agent is preferably 0.1 to 3.0% by mass (hereinafter simply referred to as%), based on the state of application to the hair. Preferably, it is in the range of 0.3 to 1.0%. When the amount of the basic dye is less than 0.1%, a sufficient dyeing effect may not be obtained. On the other hand, when the amount is more than 2.0%, dyeing on hands and skin becomes intense, causing a problem in use. There are cases. As a method of using the hair treating agent containing a basic dye of the present invention, the hair is bleached with a bleaching agent, applied, and left for 5 to 30 minutes, for example, and then washed away.
[0013]
The hair treatment agent of the present invention may be, if desired, a component generally incorporated into cosmetics, for example, alcohols such as ethanol and isopropanol, lanolin derivatives, protein derivatives, methylpolysiloxane, and methyl, as long as the effects of the present invention are not impaired. Oil components such as silicone oils such as phenylpolysiloxane, fatty acid ester oils of polyethylene glycol, camellia oil, olive oil and other vegetable oils, moisturizing components such as propylene glycol, glycerin and polyethylene glycol, and nonionic surfactants such as polyoxyethylene alkyl ether Anionic surfactants such as alkyl sulfonates, hydrocarbons such as liquid paraffin, petrolatum, squalane, water-soluble polymer substances (including anionic, nonionic and cationic), sequestering agents, preservatives Agents, pH adjusters, vitamins It may contain an ultraviolet absorber, an antioxidant, a dye, a perfume and propellant, and the like. In addition, the dosage form can be various dosage forms such as aerosol, liquid, emulsion, cream, and gel, and the dosage form is not particularly limited.
[0014]
Examples of the hair treatment agent of the present invention include a hair dye such as a hair manicure, a color rinse, a color shampoo, and a color styling agent. It is preferable that the decolorizing agent and the hair treatment agent of the present invention are filled in respective containers, combined, and sold as a single product unit.
[0015]
【Example】
Hereinafter, the present invention will be described more specifically with reference to Examples and the like, but the technical scope of the present invention should not be limitedly interpreted by these. Prior to the examples, the decolorizing agent, test method and evaluation method used in each example will be described.
[0016]
(1) Effectiveness test of bleaching treatment From untreated hair and hair previously treated with a bleaching agent, apply 0.5 g of a hair treating agent to each created hair piece (10 cm, 1 g) and leave it for 5 minutes. . Then, after washing with warm water for 30 seconds and drying, the hair dyeing state was observed by a specialized panel of 20 persons, and evaluated according to the following criteria.
[Evaluation] [Contents]
◎: 17 or more panelists answered that the hair dyeing effect was high ○: 12 or more panelists answered that the hair dyeing effect was high △: Number of panelists who answered that the hair dyeing effect was high 8 or more and less than 12 ×: less than 8 panelists answered that the hair dyeing effect was high.
(2) Dyeing test on skin A hair treatment agent (0.5 g) is applied to a 3 cm x 3 cm area of the upper part of the upper arm of 20 specialized panels and left for 5 minutes. Then, after washing with warm water for 30 seconds and drying, evaluation was made according to the following criteria.
[Evaluation] [Contents]
◎: 17 or more subjects who answered that there was little staining on the skin ○: 12 or more but less than 17 subjects who answered that there was little staining on the skin △: There was little staining on the skin 8 or more and less than 12 ×: less than 8 subjects answered that there was little staining on the skin.
(3) A hair treatment agent (10 cm, 1 g) prepared from hair treated with a bleaching agent before the hair dyeing test and sensory evaluation is coated with 0.5 g of a hair treatment agent and left for 5 minutes. Then, after washing with warm water for 30 seconds and drying, a professional panel of 20 persons observed the hair dyeing state, the comb of the hair, and the lack of stickiness. The hair dyeing property was evaluated according to the above-mentioned criteria, and the hair comb and non-stickiness were evaluated according to the following criteria.
[0020]
<Hair comb>
[Evaluation] [Contents]
◎: 17 or more panelists answered that combing is good ○: 12 or more and less than 17 panelists answered that combing is good △: 8 panelists answered that combing is good Less than 12 ×: fewer than 8 panelists answered that combing was good.
<No satsuki>
[Evaluation] [Contents]
◎: １７ 17 or more panelists answered that there was no ○ ○: 数 12 or more and less than 17 panelists answered that there was no △ ：: 数 8 or more of 12 panelists answered that there was no rust Less than ×: less than 8 panelists answered that there was no roughness.
Example 1-5, Comparative Example 1-6
A hair treatment composition having the composition shown in Table 1 was prepared according to a conventional method, and the skin-dying properties and hair-dying properties were evaluated. Table 1 also shows the results.
[0023]
[Table 1]
As is clear from Table 1, the hair treatment compositions of Examples 1 to 5 were not subjected to pretreatment with a decolorizing agent, and were not subjected to Comparative Examples 1 and 2, Comparative Example 3, and Comparative Examples 5 and 5 using an acid dye. Compared with No. 6, the skin dyeing property and the hair dyeing property were clearly superior.
[0025]
Example 1-5, Comparative Example 7-8
In addition to the hair treatment composition shown in Table 1, a hair treatment composition containing an oxidation dye having the composition shown in Table 2 was prepared in accordance with a conventional method. The hair was combed and evaluated for lack of roughness. Table 3 shows the results.
[0026]
[Table 2]
[Table 3]
As is evident from Table 3, the hair treatment compositions of Examples 1 to 5 clearly show skin-dying properties, hair-dying properties, combing of hair, and non-stickiness as compared with Comparative Examples 7 and 8. Was excellent in any of the items.
[0029]
A hair dye having the above composition was prepared by a conventional method, and was used for hair treated with a decolorizing agent. As a result, it was excellent in any of the items of skin dyeing properties, hair dyeing properties, combing of hair, and lack of dryness. .
[0031]
A treatment agent having the above composition was prepared by a conventional method and used on hair treated with a depigmenting agent. As a result, it was excellent in any of skin dyeing properties, hair dyeing properties, combing of hair, and lack of stickiness.
[0033]
A styling mist having the above composition was prepared by a conventional method and used for hair treated with a bleaching agent. As a result, the styling mist was excellent in all of the items such as skin dyeing properties, hair dyeing properties, combing of hair, and lack of stickiness.
[0035]
The following fragrances were used in the above Examples and Comparative Examples.
[0036]
[Table 4]
【The invention's effect】
The hair treatment method of the present invention does not stain hands and skin, and provides an excellent coloring and dyeing effect to hair.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002224480A JP2004067518A (en) | 2002-08-01 | 2002-08-01 | Method for treating hair |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002224480A JP2004067518A (en) | 2002-08-01 | 2002-08-01 | Method for treating hair |
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| Publication Number | Publication Date |
|---|---|
| JP2004067518A true JP2004067518A (en) | 2004-03-04 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002224480A Pending JP2004067518A (en) | 2002-08-01 | 2002-08-01 | Method for treating hair |
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| Country | Link |
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| JP (1) | JP2004067518A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2021011436A (en) * | 2019-07-04 | 2021-02-04 | 株式会社サニープレイス | Hair color method |
| JP2021011437A (en) * | 2019-07-04 | 2021-02-04 | 株式会社サニープレイス | Hair coloring composition |
| JP2021123565A (en) * | 2020-02-05 | 2021-08-30 | 株式会社ダリヤ | Wool dye composition |
| JP2025089341A (en) * | 2020-06-08 | 2025-06-12 | 花王株式会社 | Cosmetic Composition |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5522638A (en) * | 1978-08-03 | 1980-02-18 | Haruo Yamaguchi | Hairdye |
| JPH0347113A (en) * | 1989-04-24 | 1991-02-28 | Kao Corp | Hair-treatment composition, bleaching composition and hair-color conditioning composition |
| JPH08175940A (en) * | 1994-12-27 | 1996-07-09 | Shiyuwarutsukofu Kk | Hair dyeing method and hair dyeing agent composition used therefor |
| JP2001288054A (en) * | 2000-04-07 | 2001-10-16 | Kao Corp | Hair dye |
| JP2002154935A (en) * | 2000-11-21 | 2002-05-28 | Hoyu Co Ltd | Hair treating agent composition |
-
2002
- 2002-08-01 JP JP2002224480A patent/JP2004067518A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5522638A (en) * | 1978-08-03 | 1980-02-18 | Haruo Yamaguchi | Hairdye |
| JPH0347113A (en) * | 1989-04-24 | 1991-02-28 | Kao Corp | Hair-treatment composition, bleaching composition and hair-color conditioning composition |
| JPH08175940A (en) * | 1994-12-27 | 1996-07-09 | Shiyuwarutsukofu Kk | Hair dyeing method and hair dyeing agent composition used therefor |
| JP2001288054A (en) * | 2000-04-07 | 2001-10-16 | Kao Corp | Hair dye |
| JP2002154935A (en) * | 2000-11-21 | 2002-05-28 | Hoyu Co Ltd | Hair treating agent composition |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2021011436A (en) * | 2019-07-04 | 2021-02-04 | 株式会社サニープレイス | Hair color method |
| JP2021011437A (en) * | 2019-07-04 | 2021-02-04 | 株式会社サニープレイス | Hair coloring composition |
| JP7111365B2 (en) | 2019-07-04 | 2022-08-02 | 株式会社サニープレイス | hair color method |
| JP7112698B2 (en) | 2019-07-04 | 2022-08-04 | 株式会社サニープレイス | Hair coloring agent composition |
| JP2021123565A (en) * | 2020-02-05 | 2021-08-30 | 株式会社ダリヤ | Wool dye composition |
| JP7437739B2 (en) | 2020-02-05 | 2024-02-26 | 株式会社ダリヤ | hair dye composition |
| JP2025089341A (en) * | 2020-06-08 | 2025-06-12 | 花王株式会社 | Cosmetic Composition |
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