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JP2004063943A - Conductive pattern forming method - Google Patents

Conductive pattern forming method Download PDF

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Publication number
JP2004063943A
JP2004063943A JP2002222555A JP2002222555A JP2004063943A JP 2004063943 A JP2004063943 A JP 2004063943A JP 2002222555 A JP2002222555 A JP 2002222555A JP 2002222555 A JP2002222555 A JP 2002222555A JP 2004063943 A JP2004063943 A JP 2004063943A
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JP
Japan
Prior art keywords
intaglio
paste
pattern
transfer
conductive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP2002222555A
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Japanese (ja)
Inventor
Jun Kinoshita
木下 順
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Koa Corp
Original Assignee
Koa Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Koa Corp filed Critical Koa Corp
Priority to JP2002222555A priority Critical patent/JP2004063943A/en
Publication of JP2004063943A publication Critical patent/JP2004063943A/en
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  • Electrodes Of Semiconductors (AREA)
  • Manufacturing Of Printed Wiring (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a conductive pattern forming method which can improve the transfer properties of a conductive paste and position accuracy in transfer. <P>SOLUTION: A pattern groove 25 of a intaglio plate 21 is charged with conductive paste 23 and a uniform adhesion layer 34 is formed over the entire intaglio plate, including a recessed part generated by drying of paste. After the intaglio plate 21 and a transfer object 41 are stuck via the adhesion layer 34, the intaglio plate 21 is peeled and the paste is transferred to the transfer object. Therefore, the paste inside the intaglio plate pattern groove is transferred properly on the object of transfer. <P>COPYRIGHT: (C)2004,JPO

Description

【0001】
【発明の属する技術分野】
本発明は、例えば、凹版を用いて基板上に導電パターンを形成する導電パターン形成方法に関するものである。
【0002】
【従来の技術】
電子部品の小型化に伴い、電子部品の導電パターンを構成する導電ラインの微細化やライン抵抗を低抵抗化するための印刷方法、例えば、可撓性フィルムに微細な配線パターンを加工したフィルム状凹版を用いた凹版印刷方法が提案されている。
【0003】
また、凹版から基板上へ導電ペーストを転写する際の離型性を改善すべく、凹版の表面に2重構造の離型層を形成する提案もなされている(例えば、特開2000−353866号公報)。
【0004】
【発明が解決しようとする課題】
しかしながら、上記従来の凹版パターンを用いた転写方法は、被転写物であるアルミナ(Al基板等)上へ凹版内部のペーストが完全に転写できず、そのため、パターンに欠け、欠損、膜厚ばらつき等が発生する。
【0005】
また、従来の凹版印刷方法は、凹版上の加工溝に導電ペーストを充填した後、ペースト中の有機溶剤を蒸発させて乾燥させ、その乾燥に伴うペーストの体積減少に対処すべく、再度、加工溝内のくぼみ部分へ導電ペーストを充填し、それを乾燥させるという工程を複数回、繰り返した後、基板上にペーストを転写して、パターンを形成する必要がある。このため、複雑な工程が必要となる。
【0006】
さらに、このような方法では、導電ペーストを何度も充填しないと、そのペーストと、凹版表面に対向させるため基板上に形成した接着層との接着が良好に行われず、逆に、良好に接着させようとして加圧すると、凹版と被転写物の位置ずれによるパターンの位置ずれが生じやすいという問題がある。従って、加える圧力が大きい場合、転写パターンもずれやすく、パターン形状も悪くなるという問題がある。
【0007】
また、被転写物への転写中のハンドリングを行う際、凹版と被転写物間にずれが生じ、位置精度が低下するため、ハンドリングに制約があるとともに、作業性も低下するという問題がある。
【0008】
さらには、基板への接着層の形成にスピンナーを用いた場合、基板周囲において接着層が厚くなりやすいため、凹版を接着する際、中心部分で接着不良が起こりやすくなる。そのため、通常よりも加圧が必要となり、それが位置ずれの原因ともなる。
【0009】
本発明は、上述した課題に鑑みなされたものであり、その目的とするところは、導電ペーストの転写性と転写時の位置精度を向上できる導電パターン形成方法を提供することである。
【0010】
本発明の他の目的は、転写状態における製品の工程内での取り扱いを容易にし、作業性を向上できる導電パターン形成方法を提供することである。
【0011】
【課題を解決するための手段】
かかる目的を達成し、上述した課題を解決する一手段として、例えば、以下の構成を備える。すなわち、基板上に形成する導電パターンに対応するパターン溝を有する凹版を用いた導電パターン形成方法であって、上記凹版に形成されたパターン溝内に導電ペーストを充填する充填ステップと、上記充填された導電ペーストを乾燥させる乾燥ステップと、上記乾燥後、上記凹版の表面に接着剤による接着層を形成するステップと、上記接着層が形成された上記凹版と上記基板とを貼り合わせるステップと、上記貼り合わせた凹版と基板とを剥離して、上記充填された導電ペーストを上記基板上に転写するステップと、上記転写された導電ペーストを焼成して上記導電パターンを形成するステップとを備えることを特徴とする。
【0012】
例えば、上記接着層の形成の際、上記乾燥による上記導電ペーストの体積減少で生じた上記パターン溝内の空間にも上記接着剤が充填されることを特徴とする。
【0013】
また、例えば、上記充填ステップにおける上記パターン溝内の空間への上記導電ペーストの充填は、1回のみ行うことを特徴とする。
【0014】
【発明の実施の形態】
以下、添付図面を参照して、本発明に係る実施の形態例を詳細に説明する。図1は、本実施の形態例に係る凹版の表面処理工程を示すフローチャートである。また、図2は、本実施の形態例に係る、凹版による導電パターン形成の工程を示している。
【0015】
図1に示す最初の工程、すなわち、ステップS11では、凹版パターンを形成する。具体的には、樹脂あるいは金属からなるフィルム、板、ドラム等に、レーザ加工あるいは機械加工によって、基板上に形成する配線パターンに対応する凹溝型のパターン溝(適宜、加工溝ともいう)を形成する。
【0016】
続くステップS12において、金属あるいは樹脂のブレード(スキージ)を用いて、上記のパターン溝(加工溝)に導電ペーストを充填するとともに、ペースト充填後の凹版の表面を、例えば、スキージによって掻くことにより、余分なペーストを除去する。
【0017】
図2の(a)は、凹版におけるペーストの充填および掻き取りの様子を示している。同図に示すように、スキージ22を使用して、凹版21に形成されたパターン溝25内へペースト23を充填する。また、凹版21の表面における余分なペーストを掻き取って、それを除去する。
【0018】
図1のステップS13において、上記のステップS12でペーストが充填された凹版を、例えば、乾燥器中で乾燥させ、ペースト中の有機溶剤成分を蒸発させる。このとき、有機溶剤成分の蒸発により、凹版パターン溝内のペーストの体積が減少する。図2の(b)は、そのときの様子を示している。同図において、符号tは、乾燥時の体積減少によって生じた“くぼみ”を表している。
【0019】
次に、ステップS14において、上記のステップS12と同様の方法により、スキージ22を使用して、上述した乾燥によって体積減少したペーストの上面に接着剤を充填する。さらに、続くステップS15において、凹版の表面に、均一になるよう接着層を形成する。
【0020】
なお、ここでは、接着剤の充填(ステップS14)と接着層の形成(ステップS15)を、各々別工程で行う記載となっているが、これに限定されず、これらの処理を同時に1つの工程で行ってもよい。
【0021】
図2の(c)は、上記のステップS14,S15における接着剤の充填、および接着層の形成の様子を示している。同図に示すように、スキージ22を使用して、体積減少したペーストの凹部35に接着剤33を充填し、同時に、その接着剤33により、凹版21の表面に接着層34を均一に形成する。このような接着層34の形成により、後述するペーストの転写性と転写時の位置精度が向上する。
【0022】
なお、凹版表面における接着層34の形成は、上述したスキージ22による方法に限定されるものではない。例えば、塗布ローラによる塗布であってもよいし、スピンナーによるスピンコートの形成、さらには、スクリーン印刷によって接着層を形成する等、いずれの方法を用いてもよい。
【0023】
次に、ステップS17において、上記のごとくパターン溝に充填されたペーストを被転写物上へ転写するための貼り合わせを行う。具体的には、図2の(d)に示すように、その全面に接着層34が形成された凹版21を、例えば、酸化アルミニウム(Al)基板からなる被転写物41上において位置合わせし、凹版21を、図中の矢印45で示す方向へ加圧することで被転写物(基板)41に圧接させて、凹版21と被転写物41とを貼り合わせる。
【0024】
ここでは、凹版21の全面に接着層34が形成されているため、凹版21へ加える圧力がわずかであっても、凹版21と被転写物41との接着が可能になる。
【0025】
続くステップS18では、凹版21と被転写物41とを剥離し、パターン溝内のペーストを、接着層34とともに被転写物41上へ転写する。すなわち、ステップS17において圧接し、貼り合わせた凹版21と被転写物41から、凹版21を剥離する。こうすることで、図2の(e)に示すように、被転写物41上には、接着層34と、その接着層34に接着されたペースト46だけが残される。
【0026】
そして、最終工程であるステップS19において、上記ステップS18の工程でペースト46が転写された被転写物41を、所定温度のプロファイルのもとで焼成する(パターン化)。その結果、図2の(f)に示すように、加熱により接着層が焼失するとともに、ペーストと基板(被転写物)との密着反応が起こり、被転写物41上に配線パターン48が形成される(パターン形成)。
【0027】
以上説明したように、本実施の形態例によれば、凹版のパターン溝内に導電ペーストを充填した後に乾燥させ、その乾燥により生じたペーストの体積減少によるくぼみ部分を含む凹版の全面に均一な接着層を形成し、この接着層を介して凹版と被転写物とを貼り合わせてから凹版を剥離することで、少ない工程でペーストを被転写物へ転写でき、凹版パターン溝内の導電ペーストを被転写物上へ、位置ずれ等がなく良好に転写できる。
【0028】
すなわち、凹版パターン溝内のペーストの体積が減っても、その体積が減少してできたくぼみ内に接着剤を充填し、そのくぼみ部分と一体となった接着層を形成することにより、凹版のパターン溝内に充填されたペーストの被転写物表面への転写性が向上し、ペーストの位置ずれのない完全な転写が可能になる。
【0029】
また、このとき、凹版表面全体における接着層の形成により、転写時の凹版と被転写物との接着性(固定性)が高くなり、移送・搬送等のハンドリング時においても、凹版と被転写物間における位置ずれを抑えることができ、工程内における凹版と被転写物の転写状態での製品扱いが容易になるため、作業性が向上する。
【0030】
【発明の効果】
以上説明したように、本発明によれば、簡単な工程により、導電ペーストの転写性と転写時の位置決め精度を向上でき、効率よく凹版から基板へ導電ペーストを転写できる。
【0031】
また、本発明によれば、凹版と基板間の位置ずれを抑えることができ、製品の歩留まりの低下を防止できる。
【図面の簡単な説明】
【図1】本発明の実施の形態例に係る凹版の表面処理工程を示すフローチャートである。
【図2】実施の形態例に係る、凹版による導電パターンの形成工程を示す図である。
【符号の説明】
21  凹版
22  スキージ
23  ペースト
25  パターン溝(加工溝)
33  接着剤
34  接着層
35  凹部
41  被転写物
48  配線パターン
[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a conductive pattern forming method for forming a conductive pattern on a substrate using an intaglio, for example.
[0002]
[Prior art]
Along with the miniaturization of electronic components, a printing method for miniaturizing conductive lines constituting a conductive pattern of an electronic component and reducing line resistance, for example, a film shape obtained by processing a fine wiring pattern on a flexible film Intaglio printing methods using intaglio have been proposed.
[0003]
Further, in order to improve the releasability when the conductive paste is transferred from the intaglio onto the substrate, it has been proposed to form a double-layer release layer on the surface of the intaglio (for example, JP-A-2000-353866). Gazette).
[0004]
[Problems to be solved by the invention]
However, in the transfer method using the conventional intaglio pattern described above, the paste in the intaglio cannot be completely transferred onto alumina (Al 2 O 3 substrate or the like) as an object to be transferred. Thickness variation occurs.
[0005]
Further, in the conventional intaglio printing method, after filling the processing grooves on the intaglio with the conductive paste, the organic solvent in the paste is evaporated and dried, and in order to cope with the decrease in the volume of the paste accompanying the drying, processing is performed again. It is necessary to form a pattern by transferring the paste onto the substrate after repeating the process of filling the recessed portion in the groove with the conductive paste and drying the conductive paste a plurality of times. For this reason, a complicated process is required.
[0006]
Furthermore, in such a method, if the conductive paste is not filled many times, the paste and the adhesive layer formed on the substrate to face the intaglio surface are not bonded well, and conversely, the bonding is good. When pressure is applied to make the pattern, there is a problem that the pattern is likely to be misaligned due to misalignment between the intaglio plate and the transfer target. Therefore, when the applied pressure is large, there is a problem that the transfer pattern is easily shifted and the pattern shape is deteriorated.
[0007]
In addition, when handling during transfer to the transfer target, a gap occurs between the intaglio plate and the transfer target, and the positional accuracy is reduced. Therefore, there is a problem that the handling is restricted and the workability is also reduced.
[0008]
Furthermore, when a spinner is used to form an adhesive layer on a substrate, the adhesive layer is likely to be thicker around the substrate, so that when the intaglio is bonded, poor adhesion is likely to occur at the center. For this reason, pressure is required more than usual, which also causes displacement.
[0009]
The present invention has been made in view of the above-described problems, and an object of the present invention is to provide a conductive pattern forming method capable of improving transferability of a conductive paste and positional accuracy during transfer.
[0010]
Another object of the present invention is to provide a method for forming a conductive pattern, which facilitates handling of a product in a process in a transfer state and improves workability.
[0011]
[Means for Solving the Problems]
For example, the following configuration is provided as a means for achieving the object and solving the above-described problem. That is, a method of forming a conductive pattern using an intaglio having a pattern groove corresponding to a conductive pattern formed on a substrate, wherein a filling step of filling a conductive paste in the pattern groove formed in the intaglio, A drying step of drying the conductive paste, a step of forming an adhesive layer with an adhesive on the surface of the intaglio after the drying, a step of bonding the intaglio and the substrate on which the adhesive layer is formed, and Peeling off the bonded intaglio and substrate, transferring the filled conductive paste onto the substrate, and baking the transferred conductive paste to form the conductive pattern. Features.
[0012]
For example, when the adhesive layer is formed, a space in the pattern groove, which is generated by a decrease in volume of the conductive paste due to the drying, is filled with the adhesive.
[0013]
Also, for example, the filling of the conductive paste into the space in the pattern groove in the filling step is performed only once.
[0014]
BEST MODE FOR CARRYING OUT THE INVENTION
Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings. FIG. 1 is a flowchart showing the intaglio surface treatment step according to the present embodiment. FIG. 2 shows a step of forming a conductive pattern using an intaglio according to the present embodiment.
[0015]
In the first step shown in FIG. 1, that is, in step S11, an intaglio pattern is formed. Specifically, in a film, plate, drum, or the like made of resin or metal, a concave groove pattern groove (also referred to as a processing groove as appropriate) corresponding to a wiring pattern formed on a substrate by laser processing or mechanical processing. Form.
[0016]
In the following step S12, a conductive paste is filled into the pattern grooves (working grooves) using a metal or resin blade (squeegee), and the surface of the intaglio after the paste filling is scratched with, for example, a squeegee. Remove excess paste.
[0017]
FIG. 2A shows the state of filling and scraping of the paste in the intaglio. As shown in the figure, a paste 23 is filled into a pattern groove 25 formed in the intaglio 21 using a squeegee 22. Further, excess paste on the surface of the intaglio 21 is scraped off and removed.
[0018]
In step S13 in FIG. 1, the intaglio filled with the paste in step S12 is dried, for example, in a dryer to evaporate the organic solvent component in the paste. At this time, the volume of the paste in the intaglio pattern groove is reduced due to the evaporation of the organic solvent component. FIG. 2B shows the state at that time. In the figure, the symbol t represents a “dent” caused by a decrease in volume during drying.
[0019]
Next, in step S14, an adhesive is filled on the upper surface of the paste whose volume has been reduced by the above-described drying using the squeegee 22 in the same manner as in step S12. Further, in the following step S15, an adhesive layer is formed on the surface of the intaglio plate so as to be uniform.
[0020]
Here, the filling of the adhesive (step S14) and the formation of the adhesive layer (step S15) are described as being performed in separate steps, but the present invention is not limited to this. May be performed.
[0021]
FIG. 2C shows how the adhesive is filled and the adhesive layer is formed in steps S14 and S15 described above. As shown in the figure, the adhesive 33 is filled in the concave portion 35 of the paste whose volume has been reduced using the squeegee 22, and at the same time, the adhesive 33 uniformly forms the adhesive layer 34 on the surface of the intaglio 21. . By forming such an adhesive layer 34, the transferability of the paste described later and the positional accuracy at the time of transfer are improved.
[0022]
The formation of the adhesive layer 34 on the intaglio surface is not limited to the method using the squeegee 22 described above. For example, any method such as application by an application roller, formation of a spin coat by a spinner, and formation of an adhesive layer by screen printing may be used.
[0023]
Next, in step S17, bonding for transferring the paste filled in the pattern grooves as described above onto the transfer target is performed. Specifically, as shown in FIG. 2D, an intaglio 21 having an adhesive layer 34 formed on the entire surface thereof is placed on a transfer target 41 made of, for example, an aluminum oxide (Al 2 O 3 ) substrate. Then, the intaglio 21 is pressed against the transfer target (substrate) 41 by pressing in the direction indicated by the arrow 45 in the figure, and the intaglio 21 and the transfer target 41 are bonded to each other.
[0024]
Here, since the adhesive layer 34 is formed on the entire surface of the intaglio 21, even if the pressure applied to the intaglio 21 is slight, the intaglio 21 can be bonded to the transfer object 41.
[0025]
In the following step S18, the intaglio 21 and the transferred object 41 are peeled off, and the paste in the pattern groove is transferred onto the transferred object 41 together with the adhesive layer. That is, the intaglio 21 is peeled off from the intaglio 21 and the transferred material 41 that have been pressed and bonded in step S17. As a result, as shown in FIG. 2E, only the adhesive layer 34 and the paste 46 adhered to the adhesive layer 34 are left on the transfer object 41.
[0026]
Then, in step S19, which is the final step, the transfer target 41 on which the paste 46 has been transferred in step S18 is fired (patterned) under a profile of a predetermined temperature. As a result, as shown in FIG. 2 (f), the adhesive layer is burned off by heating, and the adhesion reaction between the paste and the substrate (transfer object) occurs, so that the wiring pattern 48 is formed on the transfer object 41. (Pattern formation).
[0027]
As described above, according to the present embodiment, after the conductive paste is filled into the pattern grooves of the intaglio, the paste is dried, and the entire surface of the intaglio including the concave portion due to the volume reduction of the paste caused by the drying is uniformly formed. By forming an adhesive layer, bonding the intaglio and the transferred object through the adhesive layer, and then peeling the intaglio, the paste can be transferred to the transferred object in a few steps, and the conductive paste in the intaglio pattern groove can be transferred. Good transfer can be performed on the transfer object without any displacement or the like.
[0028]
That is, even if the volume of the paste in the intaglio pattern groove is reduced, the adhesive is filled into the cavity formed by reducing the volume, and an adhesive layer is formed integrally with the cavity, thereby forming the intaglio. The transferability of the paste filled in the pattern groove to the surface of the transfer object is improved, and complete transfer without displacement of the paste becomes possible.
[0029]
Also, at this time, the adhesion (fixation) between the intaglio and the object to be transferred at the time of transfer is increased by the formation of the adhesive layer on the entire surface of the intaglio. The positional deviation between the substrates can be suppressed, and the product can be easily handled in the transfer state of the intaglio and the transfer target in the process, so that the workability is improved.
[0030]
【The invention's effect】
As described above, according to the present invention, the transferability of the conductive paste and the positioning accuracy at the time of transfer can be improved by a simple process, and the conductive paste can be efficiently transferred from the intaglio to the substrate.
[0031]
Further, according to the present invention, the displacement between the intaglio plate and the substrate can be suppressed, and a decrease in product yield can be prevented.
[Brief description of the drawings]
FIG. 1 is a flowchart showing an intaglio surface treatment step according to an embodiment of the present invention.
FIG. 2 is a view showing a step of forming a conductive pattern by using an intaglio according to the embodiment.
[Explanation of symbols]
21 intaglio 22 squeegee 23 paste 25 pattern groove (machined groove)
33 Adhesive 34 Adhesive layer 35 Depression 41 Transfer object 48 Wiring pattern

Claims (3)

基板上に形成する導電パターンに対応するパターン溝を有する凹版を用いた導電パターン形成方法であって、
前記凹版に形成されたパターン溝内に導電ペーストを充填する充填ステップと、
前記充填された導電ペーストを乾燥させる乾燥ステップと、
前記乾燥後、前記凹版の表面に接着剤による接着層を形成するステップと、
前記接着層が形成された前記凹版と前記基板とを貼り合わせるステップと、
前記貼り合わせた凹版と基板とを剥離して、前記充填された導電ペーストを前記基板上に転写するステップと、
前記転写された導電ペーストを焼成して前記導電パターンを形成するステップとを備えることを特徴とする導電パターン形成方法。
A conductive pattern forming method using an intaglio having a pattern groove corresponding to the conductive pattern formed on the substrate,
A filling step of filling a conductive paste into the pattern grooves formed in the intaglio,
A drying step of drying the filled conductive paste,
After the drying, forming an adhesive layer by an adhesive on the surface of the intaglio,
Bonding the intaglio and the substrate on which the adhesive layer is formed,
Peeling off the bonded intaglio and substrate, and transferring the filled conductive paste onto the substrate;
Baking the transferred conductive paste to form the conductive pattern.
前記接着層の形成の際、前記乾燥による前記導電ペーストの体積減少で生じた前記パターン溝内の空間にも前記接着剤が充填されることを特徴とする請求項1記載の導電パターン形成方法。2. The method of claim 1, wherein, when forming the adhesive layer, the adhesive is also filled in a space in the pattern groove, which is generated due to a decrease in volume of the conductive paste due to the drying. 3. 前記充填ステップにおける前記パターン溝内の空間への前記導電ペーストの充填は、1回のみ行うことを特徴とする請求項2記載の導電パターン形成方法。3. The conductive pattern forming method according to claim 2, wherein the filling of the conductive paste into the space in the pattern groove in the filling step is performed only once.
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