JP2003289181A - Method of manufacturing substrate for multilayered printed wiring board - Google Patents
Method of manufacturing substrate for multilayered printed wiring boardInfo
- Publication number
- JP2003289181A JP2003289181A JP2002091836A JP2002091836A JP2003289181A JP 2003289181 A JP2003289181 A JP 2003289181A JP 2002091836 A JP2002091836 A JP 2002091836A JP 2002091836 A JP2002091836 A JP 2002091836A JP 2003289181 A JP2003289181 A JP 2003289181A
- Authority
- JP
- Japan
- Prior art keywords
- printed wiring
- wiring board
- resin
- multilayered printed
- laminate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 8
- 239000000758 substrate Substances 0.000 title abstract description 7
- 239000011347 resin Substances 0.000 claims abstract description 27
- 229920005989 resin Polymers 0.000 claims abstract description 27
- 239000012790 adhesive layer Substances 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 13
- 239000011229 interlayer Substances 0.000 abstract description 5
- 230000002950 deficient Effects 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 13
- 239000000463 material Substances 0.000 description 8
- 239000000843 powder Substances 0.000 description 7
- 239000011521 glass Substances 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- 239000004744 fabric Substances 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- 239000011889 copper foil Substances 0.000 description 4
- 239000004593 Epoxy Substances 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229920001721 polyimide Polymers 0.000 description 2
- 239000009719 polyimide resin Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 229920006231 aramid fiber Polymers 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000004924 electrostatic deposition Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Landscapes
- Production Of Multi-Layered Print Wiring Board (AREA)
Abstract
Description
【発明の詳細な説明】
【0001】
【発明の属する技術分野】本発明は、多層プリント配線
板などとして用いられる積層板の製造方法に関する。
【0002】
【従来の技術】多層プリント配線板用基板の製造方法は
ガラス布やアラミド繊維布等の基材に、エポキシ樹脂や
ポリイミド樹脂などの合成樹脂を含浸させたプリプレグ
と、金属箔張積層板の表面に回路を形成した内層回路用
基板とを積み重ね、これらを必要に応じて銅箔と重ね
る。以上のものを複数準備し、中間板もしくは鏡板と称
される金属板と、交互に多数枚重ね合せ、これらを加熱
加圧する、というのが一般的である。
【0003】
【発明が解決しようとする課題】最近では回路基板にイ
ンピーダンスコントロールが必要とされるものがある。
回路基板においてインピーダンスを決定する主要因は、
層間厚み、回路幅、誘電率、等であり、機器を設計通り
に動作させるにはこれらのばらつきが少ないことが要求
される。層間厚みについては、要求されるばらつきは±
10%以下であり、rambusメモリ等を搭載する用途ではさ
らに厳しい±8%以下が求められている。
【0004】しかしながら、一般に広く使用されている
多層化接着用のプリプレグは埋め込み性を最優先として
おり、内層回路の段差を埋め込むため、加熱時に流動性
を持たせるようにしているので、層間厚みのばらつきは
非常に大きくなる。たとえば一般的に使用されている多
層化接着用プリプレグを例にとると、公称厚み0.1mmの
もので、130℃から150℃における「樹脂流れ」が10%以
上、120℃から140℃における「溶融粘度」25〜60Pa・s、
160℃から180℃における「硬化時間」が110〜250秒程度
のものが多い。
【0005】このものを170℃、20kg/cm2で加熱加圧
すると、面内の端部が樹脂の流動によって薄くなってし
まい、層間厚みばらつきは13%を超えてしまい、インヒ゜ータ゛
ンスコントロール用途としては使えない。この対策として、樹脂
流れや、溶融粘度を変えて、流れにくくしたものを使用
することが考えられているが、樹脂性能の性能バランス
や、内層パターン形状によっては、微小空隙(ホ゛イト゛)が
発生し成形不良となってしまっていた。本特許の発明者
は上記問題点に鑑み、成形不良等を出すことなく、層間
厚みの精度向上を達成する方策を発明するに至った。以
下その内容を説明する。
【0006】
【課題を解決するための手段】本発明は次のものに関す
る。
(1) 少なくとも1枚の銅張積層板を回路形成し、こ
れらを接着剤層と重ねあわせて一体に成形して、多層プ
リント配線板を製造する方法において、接着材層とし
て、積層板表面に、未硬化樹脂を付着させたものを使用
することを特徴とする、多層プリント配線板用基板の製
造方法。
【0007】
【発明の実施の形態】一般的に多層プリント配線板を製
造する際には、内層回路用基板とプリプレグを交互に重
ねあわせて加熱加圧して成形するのが一般的であるが、
本発明は、このプリプレグの替わりに積層板の表面に未
硬化樹脂を付着させたものを使用する。プリプレグと
は、ガラスや有機物などからなる繊維(クロス)などに
樹脂を含浸させて半硬化させた状態のものをいう。積層
板は内層回路用基板と同種のものが好ましい。例えば内
層回路板にガラスエポキシ銅張積層板を使用する場合に
は、積層板にも同種のガラスエポキシ積層板を使用する
のが好ましい。
【0008】この積層板に未硬化の樹脂を付着させる方
法例としては、積層板に有機溶剤を付けて予め樹脂粉末
が付着し易くし、そののち散布や吹き付け等の方法で樹
脂粉末を付着させるという方法がある。有機溶剤には、
その後の工程で蒸発させることが容易なもの、つまり沸
点が低く、加熱成形後の積層板に残留しないものを用い
る。例えば、メタノール(沸点78.3℃)やエタノール
(沸点64.6℃)といったものが望ましい。他の方法とし
て、静電気による電着方式で行ってもよいし、ロール等
を使用した転写方式でもよい。
【0009】樹脂粉末は、エポキシ系樹脂やポリイミド
系樹脂などを半硬化させた状態のものの粉末を用いる。
被付着体であるプリプレグの樹脂と異なる種類、あるい
は同じ種類であっても、性能が異なるものを使用しても
良い。粉末を付着させた後、必要に応じて、乾燥や自然
放置させてから成形してもよい。
【0010】また、液状の樹脂を塗布して、スピンコー
ト法などにより、均一厚みにならしたのち加熱により半
硬化させるという方法もある。付着量は内層回路の埋め
込みに必要な体積をもとに決定する。概ね埋め込みに必
要な体積の3%から20%程度付着量を多くする。これ
は流れ性や、埋め込み以外の接着に必要な量を確保する
ためである。以上を重ね合わせて一体に成形するため、
加熱加圧する。この時、積層板に付着させた未硬化樹脂
が内層回路の段差を埋めるために使われ、層間の厚み
は、積層板の厚みによって確保される。プリプレグでは
なく、積層板にすることにより、樹脂の流れ過ぎによる
端部の板厚薄化などは発生しなくなる。
【0011】
【実施例及び比較例】まず、内層回路板として、基材層
厚み0.1mm、両面銅箔35μのガラスエポキシ両面銅張積
層板MCL-E-67(日立化成工業株式会社商品名)を準備
し、両面の銅箔を回路形成した。残銅箔面積は約70%
である。プリプレグとしては外側用、内側用、ともにガ
ラスクロス公称厚み0.095mm 樹脂分55%の公称厚み0.12m
mの多層化接着用プリプレグ GEA-67N (日立化成工業株
式会社商品名)を準備した。
【0012】積層板として、基材層厚み0.1mmのLE-E-67
(日立化成工業株式会社商品名)を準備し、この表面に
樹脂粉末を付着させた。樹脂粉末の量は、埋め込みに必
要な面積の10%増(27.0cm3/1000mm×1000mm 片面)
とした。以上のものを使用し表1に示す6層板を作成し
た。
【0013】表1から分かるように比較例1では中側プ
リプレグの基板端部にかすれ(樹脂不足による白化現
象)が発生しているが、実施例1ではそのような成形不
良は発生していない。また、実施例では、層間のあつみ
バラツキが少なく、層間の厚み精度が比較例に比べて大
幅に向上していることが分かる。
【0014】
【表1】【0015】
【発明の効果】本発明は、本発明は、プリプレグの替わ
りに積層板の表面に未硬化樹脂を付着させたものを使用
することにより、樹脂流れによる端部の薄化などを無く
すことができ、厚み精度の向上ができる。また、積層板
そのものを作る際の塗工布の樹脂分等を調整して、厚み
精度の高い積層板を作成し、これを本発明の多層プリン
ト配線板用基板に使用することにより、積層板の精度そ
のものを生かすことができる。Description: BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing a laminated board used as a multilayer printed wiring board or the like. 2. Description of the Related Art A method for manufacturing a substrate for a multilayer printed wiring board includes a prepreg in which a base material such as glass cloth or aramid fiber cloth is impregnated with a synthetic resin such as an epoxy resin or a polyimide resin, and a metal foil-clad laminate. An inner circuit board having a circuit formed on the surface of the board is stacked, and these are stacked with a copper foil as necessary. In general, a plurality of the above-described components are prepared, and a large number of the above-mentioned components are alternately stacked on a metal plate called an intermediate plate or a mirror plate, and these are heated and pressed. [0003] Recently, there is a circuit board that requires impedance control.
The main factors that determine the impedance on a circuit board are:
The interlayer thickness, the circuit width, the dielectric constant, and the like are required to be small in order to operate the device as designed. Regarding the interlayer thickness, the required variation is ±
It is 10% or less, and even more severe ± 8% or less is required for applications equipped with rambus memory. [0004] However, in general, prepregs for multi-layer bonding, which are widely used, give top priority to the embedding property. In order to embed the steps in the inner layer circuit, the prepreg is made to have fluidity at the time of heating. Variations are very large. For example, in the case of a commonly used multi-layer adhesive prepreg, for example, a resin with a nominal thickness of 0.1 mm has a “resin flow” of 10% or more at 130 ° C to 150 ° C and a “melt flow” at 120 ° C to 140 ° C. Viscosity '' 25-60 Pas,
In many cases, the “curing time” at 160 ° C. to 180 ° C. is about 110 to 250 seconds. When this material is heated and pressed at 170 ° C. and 20 kg / cm 2 , the in-plane end becomes thin due to the flow of the resin, and the interlayer thickness variation exceeds 13%. Not available. As a countermeasure, it is conceivable to use resin that has a low flow by changing the resin flow or melt viscosity.However, depending on the performance balance of the resin performance and the inner layer pattern shape, small voids (white holes) may be generated. Molding was poor. In view of the above problems, the inventor of the present invention has invented a method for improving the accuracy of the interlayer thickness without causing molding failure or the like. The contents will be described below. [0006] The present invention relates to the following. (1) At least one copper-clad laminate is formed as a circuit, and these are laminated with an adhesive layer and integrally molded to form a multilayer printed wiring board. A method for manufacturing a substrate for a multilayer printed wiring board, characterized by using an uncured resin adhered thereto. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS In general, when manufacturing a multilayer printed wiring board, it is general that an inner circuit board and a prepreg are alternately overlapped and molded by heating and pressing.
In the present invention, a material obtained by attaching an uncured resin to the surface of a laminate is used instead of the prepreg. The prepreg refers to a state in which a fiber (cloth) made of glass, an organic substance, or the like is impregnated with a resin and semi-cured. The laminate is preferably of the same type as the internal circuit board. For example, when a glass epoxy copper clad laminate is used for the inner circuit board, it is preferable to use the same type of glass epoxy laminate for the laminate. As an example of a method of adhering the uncured resin to the laminate, an organic solvent is applied to the laminate so that the resin powder is easily adhered in advance, and then the resin powder is adhered by a method such as spraying or spraying. There is a method. Organic solvents include
A material which is easy to evaporate in the subsequent steps, that is, a material having a low boiling point and which does not remain in the laminated plate after heat molding is used. For example, methanol (boiling point 78.3 ° C.) or ethanol (boiling point 64.6 ° C.) is desirable. As another method, an electrostatic deposition method using static electricity or a transfer method using a roll or the like may be used. As the resin powder, an epoxy resin or a polyimide resin in a semi-cured state is used.
A type different from the resin of the prepreg to be adhered or a type different from the same type of resin may be used. After the powder is attached, if necessary, the powder may be dried or allowed to stand naturally before molding. There is also a method in which a liquid resin is applied, the thickness is made uniform by a spin coating method or the like, and then semi-cured by heating. The amount of adhesion is determined based on the volume required for embedding the inner layer circuit. Generally, the adhesion amount is increased by about 3% to 20% of the volume required for embedding. This is to ensure the flowability and the amount necessary for bonding other than embedding. In order to form a single piece by overlapping the above,
Heat and press. At this time, the uncured resin adhered to the laminate is used to fill the steps of the inner layer circuit, and the thickness between the layers is secured by the thickness of the laminate. By using a laminate instead of a prepreg, the thickness of the end portion is not reduced due to excessive flow of the resin. Examples and Comparative Examples First, as an inner circuit board, a glass epoxy double-sided copper-clad laminate MCL-E-67 (trade name of Hitachi Chemical Co., Ltd.) having a base material layer thickness of 0.1 mm and a double-sided copper foil of 35 μm was used. Was prepared, and a copper foil on both sides was formed into a circuit. The remaining copper foil area is about 70%
It is. As prepreg, for outside and inside, both are glass cloth nominal thickness 0.095mm, resin thickness 55% nominal thickness 0.12m
A multi-layer adhesive prepreg GEA-67N (trade name of Hitachi Chemical Co., Ltd.) was prepared. As a laminate, LE-E-67 having a base material layer thickness of 0.1 mm is used.
(Hitachi Kasei Kogyo Co., Ltd.) was prepared, and a resin powder was adhered to the surface. The amount of resin powder increased by 10% of the area required for embedding (27.0cm3 / 1000mm x 1000mm on one side)
And Using the above, a six-layer plate shown in Table 1 was prepared. As can be seen from Table 1, in Comparative Example 1, blurring (whitening due to insufficient resin) occurred at the end of the substrate of the middle prepreg, but in Example 1, such molding failure did not occur. . In addition, in the example, it can be seen that the variation between layers is small, and the thickness accuracy between layers is significantly improved as compared with the comparative example. [Table 1] According to the present invention, the present invention eliminates the thinning of the end portion due to the resin flow by using a material in which an uncured resin is adhered to the surface of a laminate instead of a prepreg. And the thickness accuracy can be improved. Also, by adjusting the resin content of the coated cloth when making the laminate itself, a laminate having high thickness accuracy is prepared, and this is used for the substrate for a multilayer printed wiring board of the present invention. Accuracy itself can be utilized.
Claims (1)
し、これらを接着剤層と重ねあわせて一体に成形して、
多層プリント配線板を製造する方法において、接着材層
として、積層板表面に、未硬化樹脂を付着させたものを
使用することを特徴とする、多層プリント配線板用基板
の製造方法。Claims: 1. A circuit is formed with at least one copper-clad laminate, and these are laminated with an adhesive layer and integrally molded.
What is claimed is: 1. A method for manufacturing a multilayer printed wiring board, comprising: using, as an adhesive layer, an uncured resin adhered to a surface of a laminated board.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002091836A JP2003289181A (en) | 2002-03-28 | 2002-03-28 | Method of manufacturing substrate for multilayered printed wiring board |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002091836A JP2003289181A (en) | 2002-03-28 | 2002-03-28 | Method of manufacturing substrate for multilayered printed wiring board |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2003289181A true JP2003289181A (en) | 2003-10-10 |
Family
ID=29236824
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002091836A Pending JP2003289181A (en) | 2002-03-28 | 2002-03-28 | Method of manufacturing substrate for multilayered printed wiring board |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2003289181A (en) |
-
2002
- 2002-03-28 JP JP2002091836A patent/JP2003289181A/en active Pending
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