JP2003261831A - Interior coating composition and interior board using the same - Google Patents
Interior coating composition and interior board using the sameInfo
- Publication number
- JP2003261831A JP2003261831A JP2002348914A JP2002348914A JP2003261831A JP 2003261831 A JP2003261831 A JP 2003261831A JP 2002348914 A JP2002348914 A JP 2002348914A JP 2002348914 A JP2002348914 A JP 2002348914A JP 2003261831 A JP2003261831 A JP 2003261831A
- Authority
- JP
- Japan
- Prior art keywords
- component
- weight
- interior
- board
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000008199 coating composition Substances 0.000 title claims abstract description 18
- 238000010521 absorption reaction Methods 0.000 claims abstract description 88
- 239000000463 material Substances 0.000 claims abstract description 35
- 239000002245 particle Substances 0.000 claims abstract description 25
- 239000000839 emulsion Substances 0.000 claims abstract description 22
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 11
- 239000000057 synthetic resin Substances 0.000 claims abstract description 11
- 239000007787 solid Substances 0.000 claims abstract description 9
- 238000000576 coating method Methods 0.000 claims description 26
- 239000011248 coating agent Substances 0.000 claims description 24
- 125000000524 functional group Chemical group 0.000 claims description 24
- 239000010440 gypsum Substances 0.000 claims description 19
- 229910052602 gypsum Inorganic materials 0.000 claims description 19
- 229920000642 polymer Polymers 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 9
- 239000003431 cross linking reagent Substances 0.000 claims description 8
- 239000000378 calcium silicate Substances 0.000 claims description 4
- 229910052918 calcium silicate Inorganic materials 0.000 claims description 4
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims description 4
- 239000010454 slate Substances 0.000 claims description 4
- 230000003578 releasing effect Effects 0.000 abstract description 13
- 238000003795 desorption Methods 0.000 description 21
- 230000000052 comparative effect Effects 0.000 description 20
- 239000000835 fiber Substances 0.000 description 17
- 238000000034 method Methods 0.000 description 14
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 13
- -1 For example Chemical group 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 10
- 239000000178 monomer Substances 0.000 description 10
- 229920005989 resin Polymers 0.000 description 10
- 239000011347 resin Substances 0.000 description 10
- 239000005909 Kieselgur Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 7
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 6
- 235000017491 Bambusa tulda Nutrition 0.000 description 6
- 241001330002 Bambuseae Species 0.000 description 6
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 6
- 239000011425 bamboo Substances 0.000 description 6
- 239000003610 charcoal Substances 0.000 description 6
- 230000001771 impaired effect Effects 0.000 description 5
- 239000003973 paint Substances 0.000 description 5
- 229920002050 silicone resin Polymers 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 4
- 239000004925 Acrylic resin Substances 0.000 description 4
- 229920000178 Acrylic resin Polymers 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 125000003700 epoxy group Chemical group 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 125000003504 2-oxazolinyl group Chemical group O1C(=NCC1)* 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 125000004069 aziridinyl group Chemical group 0.000 description 3
- VPKDCDLSJZCGKE-UHFFFAOYSA-N carbodiimide group Chemical group N=C=N VPKDCDLSJZCGKE-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 229910001583 allophane Inorganic materials 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 239000012784 inorganic fiber Substances 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000007761 roller coating Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 239000012855 volatile organic compound Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- NVZWEEGUWXZOKI-UHFFFAOYSA-N 1-ethenyl-2-methylbenzene Chemical compound CC1=CC=CC=C1C=C NVZWEEGUWXZOKI-UHFFFAOYSA-N 0.000 description 1
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- AOBIOSPNXBMOAT-UHFFFAOYSA-N 2-[2-(oxiran-2-ylmethoxy)ethoxymethyl]oxirane Chemical compound C1OC1COCCOCC1CO1 AOBIOSPNXBMOAT-UHFFFAOYSA-N 0.000 description 1
- BQBSIHIZDSHADD-UHFFFAOYSA-N 2-ethenyl-4,5-dihydro-1,3-oxazole Chemical compound C=CC1=NCCO1 BQBSIHIZDSHADD-UHFFFAOYSA-N 0.000 description 1
- PBYIFPWEHGSUEY-UHFFFAOYSA-N 2-ethenyl-4-methyl-4,5-dihydro-1,3-oxazole Chemical compound CC1COC(C=C)=N1 PBYIFPWEHGSUEY-UHFFFAOYSA-N 0.000 description 1
- HMEVYZZCEGUONQ-UHFFFAOYSA-N 2-ethenyl-5-methyl-4,5-dihydro-1,3-oxazole Chemical compound CC1CN=C(C=C)O1 HMEVYZZCEGUONQ-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- LPIQIQPLUVLISR-UHFFFAOYSA-N 2-prop-1-en-2-yl-4,5-dihydro-1,3-oxazole Chemical compound CC(=C)C1=NCCO1 LPIQIQPLUVLISR-UHFFFAOYSA-N 0.000 description 1
- UWHCZFSSKUSDNV-UHFFFAOYSA-N 3-(aziridin-1-yl)propanoic acid;2-ethyl-2-(hydroxymethyl)propane-1,3-diol Chemical compound OC(=O)CCN1CC1.OC(=O)CCN1CC1.OC(=O)CCN1CC1.CCC(CO)(CO)CO UWHCZFSSKUSDNV-UHFFFAOYSA-N 0.000 description 1
- 241000238876 Acari Species 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 101000650817 Homo sapiens Semaphorin-4D Proteins 0.000 description 1
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 235000003570 Phyllostachys pubescens Nutrition 0.000 description 1
- 244000302661 Phyllostachys pubescens Species 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 102100027744 Semaphorin-4D Human genes 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229920002978 Vinylon Polymers 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000012615 aggregate Substances 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001350 alkyl halides Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 238000010000 carbonizing Methods 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- OAKJQQAXSVQMHS-UHFFFAOYSA-N hydrazine Substances NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- FSQQTNAZHBEJLS-UPHRSURJSA-N maleamic acid Chemical compound NC(=O)\C=C/C(O)=O FSQQTNAZHBEJLS-UPHRSURJSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000011490 mineral wool Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
- OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical compound CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 description 1
- DNTMQTKDNSEIFO-UHFFFAOYSA-N n-(hydroxymethyl)-2-methylprop-2-enamide Chemical compound CC(=C)C(=O)NCO DNTMQTKDNSEIFO-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000005332 obsidian Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- 229910001562 pearlite Inorganic materials 0.000 description 1
- 239000011301 petroleum pitch Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000011295 pitch Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920006306 polyurethane fiber Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 239000008262 pumice Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 239000011257 shell material Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000002336 sorption--desorption measurement Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Landscapes
- Finishing Walls (AREA)
- Laminated Bodies (AREA)
- Paints Or Removers (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、建築物の内装材あ
るいは天井材に使用される内装用塗料組成物及びそれを
用いた内装用ボードに関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an interior coating composition used as an interior material or ceiling material for buildings and an interior board using the same.
【0002】[0002]
【従来技術】近年、快適な居住空間に対する関心が高ま
る中、内装材については、内壁面の結露防止機能やカビ
発生防止機能、あるいは湿度の調整による不快感抑制機
能等を有する吸放湿性材料、及び、騒音等の不快感の抑
制機能を有する吸音性材料等への期待が高まっている。2. Description of the Related Art In recent years, with increasing interest in comfortable living spaces, interior materials have a moisture absorbing / releasing material having a function of preventing dew condensation on the inner wall surface, a function of preventing mold formation, or a function of suppressing discomfort by adjusting humidity. In addition, expectations for sound absorbing materials and the like having a function of suppressing discomfort such as noise are increasing.
【0003】吸放湿性、吸音性を有する材料としては、
石膏ボードが一般的に用いられる。しかし石膏ボードは
吸湿性に比べ放湿性に劣るため、近年の高気密性、高断
熱性の建築物に施工される場合、室内に発生した湿気が
ボード内に長期間蓄積され、ボード内の湿気の存在によ
り吸音性が著しく低下し、さらに、室内外での温度差に
よる結露が生じ、その結果、身体に有害なカビやダニな
どの発生の原因となり、美観性を著しく損ねてしまう。
カビ等で汚れた石膏ボード表面の美観性を回復するため
には、塗料等で改装すればよいが、この場合、塗膜で石
膏ボード表面を覆うため通気性がなくなり石膏ボードが
有する吸放湿性は失われる恐れがある。また、通気性を
失ったボード内の湿気が逃げ場を失い、かつ、石膏ボー
ドの多孔質表面が塗膜で覆われしまうため、吸音性も失
われる恐れがある。As a material having moisture absorbing / releasing property and sound absorbing property,
Gypsum board is commonly used. However, gypsum board is less hygroscopic than hygroscopic, so when it is installed in a building with high airtightness and high heat insulation in recent years, the humidity generated in the room accumulates in the board for a long time and the moisture in the board Due to the presence of the above, the sound absorbing property is remarkably reduced, and further, dew condensation occurs due to a temperature difference between indoors and outdoors, resulting in the generation of molds and mites harmful to the body, and the aesthetic appearance is significantly impaired.
In order to restore the aesthetic appearance of the surface of the gypsum board that is soiled by mold, etc., it may be refurbished with paint or the like, but in this case, since the surface of the gypsum board is covered with a coating film, the air permeability is lost and the moisture absorption and desorption properties of the gypsum board are lost. May be lost. In addition, the moisture inside the board, which has lost the air permeability, loses the escape area and the porous surface of the gypsum board is covered with the coating film, so that the sound absorbing property may be lost.
【0004】上記問題を解決する方法として、例えば、
特許文献1では、特定粒子径の合成樹脂エマルションと
珪藻土を必須成分とする塗料が開示されており、珪藻土
を高比率で含有することにより吸放湿性能を発揮させる
方法がある。また、特許文献2では、合成樹脂エマルシ
ョン、珪藻土、及び高吸水ポリマーを含有する塗料が開
示されており、珪藻土及び高吸水ポリマーを高比率で含
有することによって吸放湿性を発揮させる方法がある。As a method for solving the above problem, for example,
Patent Document 1 discloses a coating material containing a synthetic resin emulsion having a specific particle diameter and diatomaceous earth as essential components, and there is a method of exhibiting a moisture absorption / release performance by containing a high proportion of diatomaceous earth. Further, Patent Document 2 discloses a coating material containing a synthetic resin emulsion, diatomaceous earth, and a highly water-absorbing polymer, and there is a method of exhibiting moisture absorption / release properties by containing a high ratio of diatomaceous earth and a highly water-absorbing polymer.
【0005】[0005]
【特許文献1】特公昭62−15108号公報[Patent Document 1] Japanese Patent Publication No. 62-15108
【特許文献2】特開昭62−74966号公報[Patent Document 2] Japanese Patent Laid-Open No. 62-74966
【0006】しかし、上記従来技術のような珪藻土を用
いた塗料は、汎用塗料に比べると吸放湿性能はあるが、
石膏ボードを上回る様な吸放湿性能は得られなかった。
また、吸音性能についても石膏ボードを上回る様なもの
は得られなかった。[0006] However, the paint using diatomaceous earth as in the above-mentioned prior art has moisture absorbing / releasing performance as compared with general-purpose paint,
The moisture absorbing / releasing performance superior to that of gypsum board was not obtained.
Moreover, the sound absorption performance was not superior to that of gypsum board.
【0007】本発明は、このような点に鑑みなされたも
のであり、建築物の内装材あるいは天井材に適用可能
な、吸放湿性及び吸音性に優れた内装用塗料組成物及び
それを用いた内装用ボードを提供するものである。The present invention has been made in view of the above points, and is applicable to an interior material or a ceiling material of a building, which is excellent in moisture absorption / desorption and sound absorption, and a use thereof. This is to provide the interior board.
【0008】[0008]
【0009】すなわち、本発明は、以下の特徴を有する
ものである。
1.(A)合成樹脂エマルション、(B)温度20℃、
相対湿度45%における吸湿率5重量%以上の吸放湿性
高分子粒子、(C)平均粒子径が30μm以上の無機質
軽量骨材、を基本構成とし、各成分の固形分比率が
(A)成分100重量部に対し、(B)成分1〜100
重量部、(C)成分50〜300重量部であることを特
徴とする内装用塗料組成物。
2.(A)が反応性官能基含有合成樹脂エマルションで
あり、(B)が温度20℃、相対湿度45%における吸
湿率5重量%以上の反応性官能基含有吸放湿性高分子粒
子であり、さらに、(D)(A)及び(B)成分の反応
性官能基と反応可能な官能基を有する架橋剤を含有し、
(D)成分の固形分比率が(A)成分100重量部に対
し、0.05〜15重量部であることを特徴とする1.
に記載の内装用塗料組成物。
3.1.または2.に記載の内装用塗料組成物により形
成される塗膜が基材に積層されたことを特徴とする内装
用ボード。
4.基材が石膏ボード、スレート板、珪酸カルシウムボ
ードから選ばれる1種であることを特徴とする請求項
3.に記載の内装用ボード。
5.基材が、複数の貫通孔を有することを特徴とする
3.または4.に記載の内装用ボード。That is, the present invention has the following features. 1. (A) synthetic resin emulsion, (B) temperature 20 ° C.,
Moisture-absorbing and desorbing polymer particles having a moisture absorption rate of 5% by weight or more at a relative humidity of 45%, and (C) an inorganic lightweight aggregate having an average particle size of 30 μm or more are basic components, and the solid content ratio of each component is (A) component. 1 to 100 of the component (B) with respect to 100 parts by weight.
An interior coating composition, characterized in that it is 50 to 300 parts by weight of component (C). 2. (A) is a reactive functional group-containing synthetic resin emulsion, and (B) is a reactive functional group-containing hygroscopic polymer particle having a moisture absorption rate of 5% by weight or more at a temperature of 20 ° C. and a relative humidity of 45%. , (D) containing a cross-linking agent having a functional group capable of reacting with the reactive functional groups of the components (A) and (B),
The solid content ratio of the component (D) is 0.05 to 15 parts by weight with respect to 100 parts by weight of the component (A).
The interior coating composition as described in 1. 3.1. Or 2. An interior board, wherein a coating film formed from the interior coating composition according to 1. is laminated on a substrate. 4. 2. The base material is one selected from gypsum board, slate board and calcium silicate board. Interior board described in. 5. 2. The base material has a plurality of through holes. Or 4. Interior board described in.
【0010】[0010]
【発明の実施の形態】以下、本発明をその実施の形態と
ともに詳細に説明する。BEST MODE FOR CARRYING OUT THE INVENTION The present invention will be described in detail below along with its embodiments.
【0011】本発明の(A)合成樹脂エマルション(以
下、「(A)成分」という。)は、(B)吸放湿性高分
子粒子(以下、「(B)成分」という。)及び(C)無
機質軽量骨材(以下、「(C)成分」という。)を結合
させるものである。The synthetic resin emulsion (A) of the present invention (hereinafter referred to as "component (A)") comprises (B) hygroscopic polymer particles (hereinafter referred to as "component (B)") and (C). ) An inorganic lightweight aggregate (hereinafter referred to as "component (C)") is bonded.
【0012】合成樹脂エマルションとしては、例えば、
アクリル樹脂エマルション、シリコン樹脂エマルショ
ン、フッ素樹脂エマルション、アクリルシリコン樹脂エ
マルション、酢酸ビニル樹脂エマルション、塩化ビニル
樹脂エマルション、ウレタン樹脂エマルション、エポキ
シ樹脂エマルション、ポリビニルアルコール樹脂エマル
ション、エチレン樹脂エマルション等の1種または2種
以上を混合して使用することができる。Examples of synthetic resin emulsions include:
One or two kinds of acrylic resin emulsion, silicone resin emulsion, fluororesin emulsion, acrylic silicone resin emulsion, vinyl acetate resin emulsion, vinyl chloride resin emulsion, urethane resin emulsion, epoxy resin emulsion, polyvinyl alcohol resin emulsion, ethylene resin emulsion, etc. The above can be mixed and used.
【0013】また、(A)成分のガラス転移温度(T
g)は、−20〜5℃であることが好ましい。Tgがこ
のような範囲であれば、揮発性有機化合物(VOC)の
一つである造膜助剤を使用しなくても膜形成が可能であ
り、好ましい。Further, the glass transition temperature (T) of the component (A)
g) is preferably −20 to 5 ° C. When Tg is in such a range, it is possible to form a film without using a film-forming auxiliary which is one of volatile organic compounds (VOC), which is preferable.
【0014】特に(A)成分は反応性官能基含有合成樹
脂エマルションであることが好ましい。反応性官能基と
しては、後述する架橋剤(以下、「D成分」という。)
の官能基と反応可能であるものが使用できる。Particularly, the component (A) is preferably a reactive functional group-containing synthetic resin emulsion. As the reactive functional group, a crosslinking agent described below (hereinafter referred to as "D component").
Any of those capable of reacting with the functional group of can be used.
【0015】このような官能基の組み合わせとしては、
例えば、カルボキシル基と金属イオン、カルボキシル基
とカルボジイミド基、カルボキシル基とエポキシ基、カ
ルボキシル基とアジリジン基、カルボキシル基とオキサ
ゾリン基、水酸基とイソシアネート基、カルボニル基と
ヒドラジド基、エポキシ基とアミノ基、等があげられ
る。本発明では(A)成分の反応性官能基として、特
に、カルボキシル基が好適に用いられる。カルボキシル
基含有合成樹脂エマルションは、カルボキシル基を有す
る単量体(以下、「a成分」という。)を共重合するこ
とによって得られる。As a combination of such functional groups,
For example, carboxyl group and metal ion, carboxyl group and carbodiimide group, carboxyl group and epoxy group, carboxyl group and aziridine group, carboxyl group and oxazoline group, hydroxyl group and isocyanate group, carbonyl group and hydrazide group, epoxy group and amino group, etc. Can be given. In the present invention, a carboxyl group is particularly preferably used as the reactive functional group of the component (A). The carboxyl group-containing synthetic resin emulsion is obtained by copolymerizing a monomer having a carboxyl group (hereinafter referred to as “a component”).
【0016】(a)成分としては、例えば、アクリル
酸、メタクリル酸、クロトン酸、マレイン酸、イタコン
酸、フマル酸などのエチレン性不飽和カルボン酸等、及
びこれらのアンモニウム塩、有機アミン塩、アルカリ金
属塩等があげられる。これらは単独で、または2種以上
を混合して使用することができる。Examples of the component (a) include ethylenically unsaturated carboxylic acids such as acrylic acid, methacrylic acid, crotonic acid, maleic acid, itaconic acid and fumaric acid, and their ammonium salts, organic amine salts and alkalis. Examples include metal salts. These may be used alone or in admixture of two or more.
【0017】(A)成分においては、単量体総重量に対
し、通常、(a)成分を0.1〜40重量%、好ましく
は0.5〜20重量%含有する。(a)成分が40重量
%より多い場合は、皮膜の耐水性、密着性も低下する。
(a)成分が0.1重量%より少ない場合は、強靭な皮
膜を形成することができず、耐水性、耐湿性が低下す
る。The component (A) generally contains the component (a) in an amount of 0.1 to 40% by weight, preferably 0.5 to 20% by weight, based on the total weight of the monomers. If the amount of component (a) is more than 40% by weight, the water resistance and adhesiveness of the film will also deteriorate.
When the amount of the component (a) is less than 0.1% by weight, a tough film cannot be formed and the water resistance and moisture resistance deteriorate.
【0018】(A)成分において、(a)成分と共重合
可能な単量体としては、例えば、メチル(メタ)アクリ
レート、エチル(メタ)アクリレート、n−ブチル(メ
タ)アクリレート、2−エチルヘキシル(メタ)アクリ
レート、シクロヘキシル(メタ)アクリレート、フェニ
ル(メタ)アクリレート、ベンジル(メタ)アクリレー
ト等の(メタ)アクリル酸エステル;スチレン、2−メ
チルスチレン、ビニルトルエン、ジビニルベンゼン等の
芳香族ビニル類;アクリルアミド、メタクリルアミド、
マレイン酸アミド、N−メチロールアクリルアミド、N
−メチロールメタクリルアミド、ジアセトンアクリルア
ミド等のアミド類;2−ヒドロキシエチル(メタ)アク
リレート、ヒドロキシプロピル(メタ)アクリレート等
の(メタ)アクリル酸エステル類;酢酸ビニル、プロピ
オン酸ビニル等のビニルエステル類;塩化ビニリデン、
フッ化ビニリデン等のハロゲン化ビニリデン類;エチレ
ン、プロピレン、イソプレン、ブタジエン、ビニルピロ
リドン、(メタ)アクリロニトリル、塩化ビニル等があ
げられる。また、グリシジルアクリレート、グリシジメ
タクリレート、アリルグリシジルエーテル等のエポキシ
誘導体等を使用することもできる。In the component (A), examples of the monomer copolymerizable with the component (a) include methyl (meth) acrylate, ethyl (meth) acrylate, n-butyl (meth) acrylate and 2-ethylhexyl ( (Meth) acrylates such as (meth) acrylate, cyclohexyl (meth) acrylate, phenyl (meth) acrylate, benzyl (meth) acrylate; aromatic vinyls such as styrene, 2-methylstyrene, vinyltoluene, divinylbenzene; acrylamide , Methacrylamide,
Maleic acid amide, N-methylol acrylamide, N
Amides such as methylol methacrylamide, diacetone acrylamide; (meth) acrylic acid esters such as 2-hydroxyethyl (meth) acrylate and hydroxypropyl (meth) acrylate; vinyl esters such as vinyl acetate and vinyl propionate; Vinylidene chloride,
Vinylidene halides such as vinylidene fluoride; ethylene, propylene, isoprene, butadiene, vinylpyrrolidone, (meth) acrylonitrile, vinyl chloride and the like. Further, epoxy derivatives such as glycidyl acrylate, glycidyl methacrylate and allyl glycidyl ether can be used.
【0019】本発明の(D)成分は、(A)成分及び後
述する(B)成分の反応性官能基と反応可能な官能基を
有する架橋剤である。本発明組成物においては、(D)
成分が含まれることにより、塗膜の強度が向上し、さら
には優れた吸放湿性を発揮することができる。(D)成
分は、これらの官能基を一分子中に二個以上含むことが
望ましい。また、(D)成分の形態としては、エマルシ
ョンタイプ、水溶性タイプのいずれでもよい。(D)成
分の官能基としては、(A)成分及び(B)成分と反応
可能なものである限り限定されないが、本発明では特
に、カルボキシル基と反応可能な官能基であるカルボジ
イミド基、エポキシ基、アジリジン基、オキサゾリン基
等が好適に用いられる。The component (D) of the present invention is a crosslinking agent having a functional group capable of reacting with the reactive functional groups of the component (A) and the component (B) described later. In the composition of the present invention, (D)
By containing the components, the strength of the coating film is improved, and further excellent moisture absorption / release properties can be exhibited. The component (D) preferably contains two or more of these functional groups in one molecule. The form of the component (D) may be either emulsion type or water-soluble type. The functional group of the component (D) is not limited as long as it can react with the component (A) and the component (B), but in the present invention, a carbodiimide group which is a functional group capable of reacting with a carboxyl group and an epoxy group are particularly preferable. A group, an aziridine group, an oxazoline group and the like are preferably used.
【0020】(D)成分の具体例としては、例えば、カ
ルボジイミド基を含む架橋剤として、特開平10−60
272号公報、特開平10−316930号公報、特開
平11−60667号公報等に記載のもの等、エポキシ
基を含む架橋剤として、ポリエチレングリコールジグリ
シジルエーテル、ポリヒドロキシアルカンポリグリシジ
ルエーテル、ジグリセロールポリグリシジルエーテル、
ソルビトールポリグリシジルエーテル等、アジリジン基
を含む架橋剤として、2,2−ビスヒドロキシメチルブ
タノール−トリス[3−(1−アジリジニル)プロピオ
ネート]、1,6−ヘキサメチレンジエチレンウレア、
ジフェニルメタン−ビス−4,4’−N,N’−ジエチ
レンウレア等、オキサゾリン基を含む架橋剤として、2
−ビニル−2−オキサゾリン、2−ビニル−4−メチル
−2−オキサゾリン、2−ビニル−5−メチル−2−オ
キサゾリン、2−イソプロペニル−2−オキサゾリン等
の重合性オキサゾリン化合物を該化合物と共重合可能な
単量体と共重合した樹脂等、があげられる。Specific examples of the component (D) include, for example, a crosslinking agent containing a carbodiimide group, which is disclosed in JP-A-10-60.
No. 272, JP-A-10-316930, JP-A-11-60667, etc., etc. As a crosslinking agent containing an epoxy group, polyethylene glycol diglycidyl ether, polyhydroxyalkane polyglycidyl ether, diglycerol poly Glycidyl ether,
As a cross-linking agent containing an aziridine group such as sorbitol polyglycidyl ether, 2,2-bishydroxymethylbutanol-tris [3- (1-aziridinyl) propionate], 1,6-hexamethylenediethylene urea,
As a crosslinking agent containing an oxazoline group, such as diphenylmethane-bis-4,4′-N, N′-diethyleneurea, 2
-A polymerizable oxazoline compound such as vinyl-2-oxazoline, 2-vinyl-4-methyl-2-oxazoline, 2-vinyl-5-methyl-2-oxazoline, 2-isopropenyl-2-oxazoline is used together with the compound. Examples thereof include resins copolymerized with a polymerizable monomer.
【0021】(D)成分の配合量は、固形分換算で
(A)成分100重量部に対し、0.05〜15重量
部、好ましくは0.1〜5重量部である。0.05重量
部未満の場合は、塗膜強度、吸放湿性が劣る傾向とな
る。15重量部を超える場合は、コスト上昇に見合う物
性の向上が望めない。The compounding amount of the component (D) is 0.05 to 15 parts by weight, preferably 0.1 to 5 parts by weight, based on 100 parts by weight of the component (A) in terms of solid content. If the amount is less than 0.05 part by weight, the coating film strength and moisture absorption / release property tend to be poor. If it exceeds 15 parts by weight, the improvement in physical properties commensurate with the cost increase cannot be expected.
【0022】本発明の(B)成分は、温度20℃、相対
湿度45%における吸湿率5重量%以上、好ましくは1
0%以上の吸放湿性高分子粒子であり、本発明組成物に
吸放湿性能を付与する成分である。The component (B) of the present invention has a moisture absorption rate of 5% by weight or more, preferably 1 at a temperature of 20 ° C. and a relative humidity of 45%.
It is 0% or more of moisture absorbing / releasing polymer particles, and is a component that imparts moisture absorbing / releasing performance to the composition of the present invention.
【0023】なお、温度20℃、相対湿度45%におけ
る吸湿率とは、試料を50℃で72時間乾燥した後、温
度20℃、湿度45%の恒温恒湿器にて24時間吸湿さ
せたときの重量変化より求められる値である。即ち、吸
湿率(重量%)={(吸湿後の重量−乾燥後の重量)/
乾燥後の重量}×100で求められる。The moisture absorption rate at a temperature of 20 ° C. and a relative humidity of 45% means that the sample is dried at 50 ° C. for 72 hours and then absorbed in a constant temperature and humidity chamber at a temperature of 20 ° C. and a humidity of 45% for 24 hours. It is a value obtained from the change in weight. That is, moisture absorption rate (wt%) = {(weight after moisture absorption−weight after drying) /
Weight after drying} × 100.
【0024】本発明の(B)成分は、温度20℃、相対
湿度45%における吸湿率が5重量%以上であるかぎり
特に限定されないが、反応性官能基含有吸放湿性高分子
粒子であることが好ましい。反応性官能基としては、
(D)成分の官能基と反応可能であるものが使用でき、
(A)成分の反応性官能基と同様の官能基を使用するこ
とができる。本発明では、塗膜強度、吸放湿性向上の点
から、反応性官能基として、カルボキシル基を含有する
ことが望ましい。The component (B) of the present invention is not particularly limited as long as it has a moisture absorption rate of 5% by weight or more at a temperature of 20 ° C. and a relative humidity of 45%, but it is a hygroscopic polymer particle containing a reactive functional group. Is preferred. As the reactive functional group,
Those capable of reacting with the functional group of the component (D) can be used,
A functional group similar to the reactive functional group of the component (A) can be used. In the present invention, it is desirable to contain a carboxyl group as a reactive functional group from the viewpoint of improving coating film strength and moisture absorption / release.
【0025】(B)成分にカルボキシル基を導入する方
法としては、特に限定されないが、例えば、カルボキシ
ル基を有する単量体の単独重合あるいは共重合可能な他
の単量体との共重合による方法、(メタ)アクリロニト
リル等のシアノ基含有単量体と他の単量体との共重合体
に加水分解処理を施す方法、アルケン、ハロゲン化アル
キル、アルコール、アルデヒド等の酸化による方法、等
が挙げられる。(B)成分のカルボキシル基含有量は、
1mmol/g以上であることが好ましい。The method of introducing a carboxyl group into the component (B) is not particularly limited, but for example, a method of homopolymerization of a monomer having a carboxyl group or copolymerization with another copolymerizable monomer. , A method of subjecting a copolymer of a cyano group-containing monomer such as (meth) acrylonitrile and another monomer to hydrolysis treatment, a method of oxidizing an alkene, an alkyl halide, an alcohol or an aldehyde, and the like. To be The carboxyl group content of the component (B) is
It is preferably 1 mmol / g or more.
【0026】また、(B)成分は、吸放湿性向上の点か
ら、架橋構造を有することが望ましい。このような架橋
構造は、重合段階における架橋性単量体の導入、重合後
における架橋性化合物の導入等の方法により形成するこ
とができる。架橋性単量体としては、ジビニルベンゼ
ン、エチレングリコールジ(メタ)アクリレート、メチ
レンビスアクリルアミド等、また、架橋性化合物として
は、ヒドラジン系化合物等を好適に用いることができ
る。Further, the component (B) preferably has a cross-linked structure from the viewpoint of improving moisture absorption and desorption. Such a crosslinked structure can be formed by a method of introducing a crosslinkable monomer in the polymerization step, introducing a crosslinkable compound after the polymerization, or the like. As the crosslinkable monomer, divinylbenzene, ethylene glycol di (meth) acrylate, methylenebisacrylamide and the like, and as the crosslinkable compound, hydrazine compound and the like can be suitably used.
【0027】(B)成分の粒径は、特に限定されない
が、0.1〜100μm程度のものを使用することがで
きる。The particle size of the component (B) is not particularly limited, but those having a particle size of about 0.1 to 100 μm can be used.
【0028】(B)成分の配合量は、固形分比率で
(A)成分100重量部に対し、1〜100重量部、好
ましくは10〜60重量部である。1重量部未満の場合
は、吸放湿性能が不十分となり、100重量部を超える
と、耐水性に悪影響を及ぼす。The blending amount of the component (B) is 1 to 100 parts by weight, preferably 10 to 60 parts by weight, based on 100 parts by weight of the component (A) in terms of solid content. If it is less than 1 part by weight, the moisture absorption and desorption performance will be insufficient, and if it exceeds 100 parts by weight, water resistance will be adversely affected.
【0029】本発明組成物は、(C)成分を含有するこ
とにより、さらに吸放湿性能を向上させることができ
る。また、吸音率も付与することができ、本発明では特
に、高周波領域の吸音効果だけでなく、周波数が100
0Hz以下の低周波数領域でも優れた吸音効果を得るこ
とができる。The composition of the present invention can further improve the moisture absorbing / releasing performance by containing the component (C). Further, it is possible to impart a sound absorption coefficient, and in particular, in the present invention, not only the sound absorption effect in the high frequency region but also the frequency of 100
An excellent sound absorbing effect can be obtained even in a low frequency region of 0 Hz or less.
【0030】本発明の(C)成分は、平均粒子径が30
μm以上の無機質軽量骨材であれば特に限定されない
が、例えば、黒曜石、真珠石、バーミキュライト、抗火
石、シラス等の天然石の発泡物、ガラス、フライアッシ
ュ等の各種セラミックスの発泡粒状物、軽石、中空バル
ーン等の軽量粒状物等の1種または2種以上を混合して
使用することができる。このうち特に、天然石の発泡
物、発泡粒状物を好適に用いることができる。The component (C) of the present invention has an average particle size of 30.
It is not particularly limited as long as it is an inorganic lightweight aggregate of μm or more, for example, foam of natural stone such as obsidian, pearlite, vermiculite, anti-firestone, shirasu, etc., foamed granular material of various ceramics such as glass and fly ash, pumice stone, One kind or a mixture of two or more kinds of lightweight granular materials such as hollow balloons can be used. Of these, in particular, natural stone foams and foam granules can be preferably used.
【0031】本発明の(C)成分の平均粒子径は30μ
m以上のものが利用できるが、好ましくは50〜200
0μm、さらに好ましくは100〜1000μmのもの
である。平均粒子径が30μm以上であれば、吸放湿性
能及び吸音性能(特に低周波領域での吸音性能)を十分
発揮する。平均粒子径が30μm未満であれば、塗膜の
通気性が阻害されるため、吸放湿性が劣る場合がある。The average particle size of the component (C) of the present invention is 30 μm.
m or more can be used, but preferably 50 to 200
The thickness is 0 μm, more preferably 100 to 1000 μm. When the average particle size is 30 μm or more, the moisture absorbing / releasing performance and the sound absorbing performance (especially the sound absorbing performance in the low frequency region) are sufficiently exhibited. If the average particle size is less than 30 μm, the air permeability of the coating film is impaired, and the moisture absorption / release property may be poor.
【0032】本発明の(C)成分のかさ比重は特に限定
されるものではないが、好ましくは0.02〜0.6g
/cm3、さらに好ましくは0.05〜0.5g/cm
3のものを使用する。The bulk specific gravity of the component (C) of the present invention is not particularly limited, but preferably 0.02 to 0.6 g.
/ Cm 3 , more preferably 0.05 to 0.5 g / cm
Use the one of 3 .
【0033】(C)成分の配合量は、固形分比率で
(A)成分100重量部に対し、50〜300重量部、
好ましくは100〜200重量部である。50重量部未
満の場合は、吸放湿性に劣る傾向となりやすい。また、
300重量部を超えると、施工時の作業性が低下する。The amount of the component (C) blended is 50 to 300 parts by weight based on 100 parts by weight of the component (A) in terms of solid content.
It is preferably 100 to 200 parts by weight. If the amount is less than 50 parts by weight, the moisture absorption / release property tends to be poor. Also,
If it exceeds 300 parts by weight, workability during construction is reduced.
【0034】本発明組成物においては、上記成分の他
に、充填剤を含有することが好ましい。充填剤としては
例えば、炭酸カルシウム、炭酸マグネシウム、酸化亜
鉛、酸化チタン、水酸化アルミニウム、水酸化マグネシ
ウム、硫酸バリウム、シリカ、アルミナ、タルク、チタ
ン酸カリウム、等が挙げられる。特に、水酸化アルミニ
ウムを含有した場合、難燃性、及び乾燥塗膜の割れ防止
性を付与することができ、好ましい。The composition of the present invention preferably contains a filler in addition to the above components. Examples of the filler include calcium carbonate, magnesium carbonate, zinc oxide, titanium oxide, aluminum hydroxide, magnesium hydroxide, barium sulfate, silica, alumina, talc, potassium titanate, and the like. In particular, when aluminum hydroxide is contained, it is possible to impart flame retardancy and crack resistance to a dry coating film, which is preferable.
【0035】充填剤の配合量は、樹脂固形分100重量
部に対し、50〜300重量部添加することが好まし
い。The filler is preferably added in an amount of 50 to 300 parts by weight based on 100 parts by weight of the resin solid content.
【0036】本発明ではさらに、上記成分の他に、多孔
質粉体を含有することが好ましく、吸放湿性と吸音性能
をより向上させることができる。このような多孔質粉体
としては、例えば、木炭、竹炭の他、鋸屑、パルプ廃
液、やし殻、石炭、コークス、石油ピッチ等の炭化物、
アロフェン、ゼオライト、セピオライトなどの粘土鉱物
あるいは珪藻土などの多孔質粉体等があげられる。特
に、竹炭粒状物、アロフェンを好ましく使用することが
出来る。本発明では特に、竹炭を好ましく使用すること
ができる。竹炭は、モウソウチク、マダケ、ハチク、ネ
マガリダケ等の各品種の竹を、通常300〜1000℃
で炭化し、消火・冷却することにより得られるものであ
る。このような竹炭を使用することにより、一段と優れ
た吸音特性を得ることができ、吸音板の薄厚化にも極め
て有効となる。Further, in the present invention, it is preferable to contain a porous powder in addition to the above-mentioned components, so that the moisture absorbing / releasing property and the sound absorbing performance can be further improved. Examples of such a porous powder include charcoal, bamboo charcoal, sawdust, pulp waste liquid, palm shell, coal, coke, petroleum pitch, and other carbides,
Examples thereof include clay minerals such as allophane, zeolite, and sepiolite, and porous powder such as diatomaceous earth. In particular, bamboo charcoal granules and allophane can be preferably used. In the present invention, bamboo charcoal can be preferably used. Bamboo charcoal is usually from 300 to 1000 ° C. and is made from bamboo of various varieties such as Moso bamboo, Madake, Hachiku and Nemagaritake.
It is obtained by carbonizing in, extinguishing and cooling. By using such bamboo charcoal, more excellent sound absorption characteristics can be obtained, and it is extremely effective for thinning the sound absorbing plate.
【0037】本発明ではさらに、上記成分の他に、有機
系、無機系の各種繊維を含有することもできる。有機系
繊維としては、例えば、ポリアミド系繊維、ポリビニル
アルコール系繊維、ポリエステル系繊維、ポリアクリロ
ニトリル系繊維、ポリ塩化ビニル系繊維、ポリプロピレ
ン系繊維、ポリエチレン系繊維、ポリウレタン系繊維、
ポリ塩化ビニリデン系繊維、アラミド繊維、ビニロン繊
維、カーボン系繊維、パルプ繊維、等があげられる。無
機系繊維としては、例えば、ガラス繊維、スラグ繊維、
ロックウール、シリカ−アルミナ繊維、アルミニウム繊
維、ステンレス繊維等があげられる。このような繊維を
含有することにより、形成塗膜の強度をより高めること
ができる。繊維の長さは、0.1〜10mm、好ましく
は0.5〜5mmの範囲のものが使用できる。In the present invention, in addition to the above components, various organic and inorganic fibers can be contained. As the organic fiber, for example, polyamide fiber, polyvinyl alcohol fiber, polyester fiber, polyacrylonitrile fiber, polyvinyl chloride fiber, polypropylene fiber, polyethylene fiber, polyurethane fiber,
Examples thereof include polyvinylidene chloride fiber, aramid fiber, vinylon fiber, carbon fiber, pulp fiber and the like. As the inorganic fiber, for example, glass fiber, slag fiber,
Examples include rock wool, silica-alumina fiber, aluminum fiber, stainless fiber and the like. By containing such fibers, the strength of the formed coating film can be further increased. A fiber having a length of 0.1 to 10 mm, preferably 0.5 to 5 mm can be used.
【0038】また、通常塗料に配合される各種の添加
剤、例えば、顔料、骨材、増粘剤、可塑剤、分散剤、防
腐剤、防黴剤、防藻剤、凍結防止剤等を本発明の効果を
損なわない程度に配合しても良い。In addition, various additives usually added to paints such as pigments, aggregates, thickeners, plasticizers, dispersants, preservatives, antifungal agents, antialgae agents, antifreezing agents, etc. You may mix | blend as long as the effect of invention is not impaired.
【0039】この様にして得られた内装用塗料組成物
は、基材に塗装し内装用ボードとして建築物内装材、天
井材等に使用できる。The interior coating composition thus obtained can be applied to a substrate and used as an interior board for building interior materials, ceiling materials and the like.
【0040】基材としては、特に限定されないが、石膏
ボード、スレート板、珪酸カルシウムボード、押出成形
板などの乾式ボード、ベニア板などの木質ボード、アル
ミニウム板、ステンレス板などの金属ボード等を使用す
ることができる。主として建築物の内壁面、天井面等に
使用する場合は、石膏ボード、スレート板、珪酸カルシ
ウムボード等が好ましく使用できる。The base material is not particularly limited, but gypsum board, slate board, calcium silicate board, dry board such as extruded board, wood board such as veneer board, metal board such as aluminum board and stainless board is used. can do. When mainly used for the inner wall surface or ceiling surface of a building, gypsum board, slate board, calcium silicate board and the like can be preferably used.
【0041】基材の厚さは、内装用ボード全体の強度や
衝撃による破損を考慮すると1〜30mm、好ましくは
5〜15mmの範囲のものを使用することが望ましい。
特に30mm以上となるとボード自体の重量が大きくな
り、搬送が困難となり、また取り付け施工時の作業性が
低下する場合がある。The thickness of the base material is preferably in the range of 1 to 30 mm, and more preferably 5 to 15 mm, considering the strength of the entire interior board and damage due to impact.
In particular, if the thickness is 30 mm or more, the weight of the board itself becomes large, which makes it difficult to convey the board, and the workability at the time of mounting and construction may be deteriorated.
【0042】また、基材は、複数の貫通孔を有すること
が好ましい。貫通孔の孔径としては、特に限定されない
が、3〜20mm、好ましくは3〜15mmの範囲であ
ることが好ましい。また、孔の開口する面積は、基材表
面に対し、5〜70%、好ましくは10〜30%の範囲
になるように設けることが好ましい。孔径が3mm未
満、開口する面積が5%未満となると吸音性が低下し、
孔径が20mmより大きい場合、開口する面積が70%
より大きい場合になるとボードの強度が低下し好ましく
ない。The base material preferably has a plurality of through holes. The diameter of the through hole is not particularly limited, but is preferably in the range of 3 to 20 mm, preferably 3 to 15 mm. Further, it is preferable that the area where the holes are opened is provided in a range of 5 to 70%, preferably 10 to 30% with respect to the surface of the base material. If the pore size is less than 3 mm and the opening area is less than 5%, the sound absorption will decrease,
If the hole diameter is larger than 20 mm, the opening area is 70%
If it is larger than the above range, the strength of the board decreases, which is not preferable.
【0043】塗装方法としては、特に限定されないが、
基材に直接本発明内装用塗料を塗付する方法等がある。
この時、必要であれば本発明の効果を阻害しない程度
に、基材に何らかの下地処理を施すこともできる。The coating method is not particularly limited,
There is a method of directly applying the interior coating material of the present invention to a substrate.
At this time, if necessary, the base material may be subjected to some undercoating treatment to such an extent that the effect of the present invention is not impaired.
【0044】塗装方法としては、吹付け塗装、ローラー
塗装、刷毛塗り、コテ塗り等特に限定されず使用でき
る。特に、本発明では、塗料の粘度を15Pa・s〜4
5Pa・sに調整すれば、建築物の内装材あるいは天井
材に対して、よりスムースにローラー塗装できる。ま
た、ボード等の製造工場で、吹付け塗装、ロールコータ
ー、フローコーター、等の公知の方法で塗装することも
できる。塗付量は0.5〜3.0kg/m2であること
が望ましい。As a coating method, spray coating, roller coating, brush coating, iron coating or the like can be used without particular limitation. Particularly, in the present invention, the viscosity of the paint is 15 Pa · s to 4
By adjusting the pressure to 5 Pa · s, the roller coating can be applied more smoothly to the interior material or ceiling material of the building. In addition, it is also possible to coat by a known method such as spray coating, roll coater, flow coater, etc. at a manufacturing factory of boards and the like. The coating amount is preferably 0.5 to 3.0 kg / m 2 .
【0045】さらに、本発明内装用塗料を塗装した後、
本発明の効果を損なわない程度に、上塗塗料を塗付する
こともできる。上塗塗料としては、特に限定されない
が、例えば、アクリル樹脂、シリコン樹脂、フッ素樹
脂、アクリルシリコン樹脂、酢酸ビニル樹脂、塩化ビニ
ル樹脂、ウレタン樹脂、エポキシ樹脂、ポリビニルアル
コール樹脂、エチレン樹脂等が挙げられ、これらのうち
1種または2種以上を複合して用いることができる。本
発明では、上塗塗料として、シリコン樹脂を含むもので
あれば、吸放湿性、耐侯性に優れ好ましい。Further, after applying the interior coating material of the present invention,
The top coating material may be applied to the extent that the effects of the present invention are not impaired. The top coating material is not particularly limited, and examples thereof include acrylic resin, silicone resin, fluororesin, acrylic silicone resin, vinyl acetate resin, vinyl chloride resin, urethane resin, epoxy resin, polyvinyl alcohol resin, ethylene resin, and the like. Of these, one kind or a combination of two or more kinds can be used. In the present invention, the top coating material containing a silicone resin is preferable because it has excellent moisture absorption and desorption properties and weather resistance.
【0046】本発明の内装用ボードを設置する際には、
塗料塗装面が室内側となるようにコンクリート、木材等
の剛体に直接密着する方法、剛体との間に空気層を設け
て設置する方法等、種々の方法を採用することができ
る。When installing the interior board of the present invention,
Various methods can be adopted, such as a method of directly adhering to a rigid body such as concrete or wood so that the coating surface is on the indoor side, a method of providing an air layer between the rigid body and the installation, and the like.
【0047】[0047]
【実施例】以下に実施例及び比較例を示し、本発明の特
徴をより明確にする。EXAMPLES Examples and comparative examples will be shown below to further clarify the characteristics of the present invention.
【0048】表1に示す原料を用い、表2に示す配合に
て塗料を作製した。A coating material was prepared by using the raw materials shown in Table 1 and the composition shown in Table 2.
【0049】[0049]
【表1】 [Table 1]
【0050】[0050]
【表2】 [Table 2]
【0051】(試験体作製)
(実施例1〜6、比較例1〜9)150×150mmの
石膏ボード(板厚9.5mm)にSK水性ホワイトシー
ラー(アクリル樹脂系下塗材;エスケー化研株式会社
製)を温度23℃、相対湿度50%下(以下「標準状
態」という)で8時間乾燥を行った後、作製した塗料を
1.0kg/m2でローラー施工し、標準状態で14日
間乾燥養生して試験体を作製した。
(実施例7)150×150mmの複数の貫通孔を有す
る石膏ボード(孔径13.4mm、孔ピッチ24mm、
開孔面積24%、板厚9.5mm)にSK水性ホワイト
シーラー(アクリル樹脂系下塗材;エスケー化研株式会
社製)を標準状態で8時間乾燥を行った後、作製した塗
料を1.0kg/m2でローラー施工し、標準状態で1
4日間乾燥養生して試験体を作製した。(Preparation of Specimen) (Examples 1 to 6, Comparative Examples 1 to 9) A 150 × 150 mm gypsum board (board thickness: 9.5 mm) was applied to an SK aqueous white sealer (acrylic resin-based undercoat material; SK Kaken Co., Ltd.). After being dried for 8 hours at a temperature of 23 ° C. and a relative humidity of 50% (hereinafter referred to as “standard condition”), the prepared coating material is roller coated at 1.0 kg / m 2 for 14 days in standard condition. It was dried and cured to prepare a test body. (Example 7) Gypsum board having a plurality of through holes of 150 x 150 mm (hole diameter 13.4 mm, hole pitch 24 mm,
An open area of 24% and a plate thickness of 9.5 mm was dried with an SK water-based white sealer (acrylic resin-based undercoat material; manufactured by SK Kaken Co., Ltd.) for 8 hours in a standard state, and then 1.0 kg of the prepared coating material was applied. / M 2 roller installation, 1 in standard condition
A test body was prepared by drying and curing for 4 days.
【0052】(試験方法)
(1)吸放湿性試験
作製した試験体の重量WD0を測定した後、これを温度2
0℃、相対湿度90%下で24時間放置後、重量WW1を
測定し、続いて、温度20℃、相対湿度45%下で24
時間放置し、重量WD2を測定した。同様な操作をもう1
回繰り返し、湿潤状態での重量WW2と乾燥状態での重量W
D2とを測定した。得られた値を用いて下式により水蒸気
吸脱着特性値を算出した。
吸湿量W1(g)=WW1−WD0
吸湿量W2(g)=WW1−WD1
吸湿量W3(g)=WW2−WD1
吸湿量W4(g)=WW2−WD2
吸放湿特性値(g/m2)=(W1+W2+W3+W4)/
{4×(試験体面積)}。
評価は、◎:50g/m2以上、○:40〜50g/m
2、△:30〜40g/m2、×:30g/m2以下、
とし、結果を表3に示す。なお、石膏ボードのみで測定
した吸放湿特性値は19.2g/m2であった。(Test method)
(1) Moisture absorption and desorption test
Weight of the prepared test piece WD0After measuring the
Weight W after standing for 24 hours at 0 ℃ and 90% relative humidityW1To
Measured and then 24 at a temperature of 20 ° C and a relative humidity of 45%
Let stand for a time and weigh WD2Was measured. Do the same operation another 1
Repeated times, weight W in wet stateW2And dry weight W
D2And were measured. Using the obtained value, the steam is calculated by the following formula.
The adsorption / desorption characteristic value was calculated.
Moisture absorption W1(G) = WW1-WD0
Moisture absorption WTwo(G) = WW1-WD1
Moisture absorption WThree(G) = WW2-WD1
Moisture absorption WFour(G) = WW2-WD2
Moisture absorption and desorption characteristic value (g / mTwo) = (W1+ WTwo+ WThree+ WFour) /
{4 × (area of test body)}.
Evaluation is ◎: 50 g / mTwoAbove, ◯: 40 to 50 g / m
Two, Δ: 30 to 40 g / mTwo, ×: 30 g / mTwoLess than,
And the results are shown in Table 3. In addition, it measures only with gypsum board
Moisture absorption and desorption characteristic value was 19.2 g / mTwoMet.
【0053】[0053]
【表3】 [Table 3]
【0054】(2)吸音率
作製した試験体を、ASTM E1050の2マイクロ
ホン法に順じ、50〜1500Hzの周波数範囲で垂直
入射吸音率を測定した。試験装置としては、2マイクロ
ホンインピーダンス測定管4206型(ビュルエル・ケ
アー社製)を使用した。それぞれの試験体について背後
空気層を100mm設けた場合の吸音率を測定した。結
果を図1〜16に示す。なお、石膏ボードのみで測定し
た吸音率は図17、複数の貫通孔を有する石膏ボードの
みで測定した吸音率は図18に示す。(2) Sound absorption coefficient The prepared test piece was subjected to the two-microphone method of ASTM E1050, and the normal incidence sound absorption coefficient was measured in the frequency range of 50 to 1500 Hz. As the test device, a two-microphone impedance measuring tube type 4206 (manufactured by Buruel Care Co.) was used. The sound absorption coefficient was measured for each test body when a back air layer of 100 mm was provided. The results are shown in FIGS. The sound absorption coefficient measured only with the gypsum board is shown in FIG. 17, and the sound absorption coefficient measured only with the gypsum board having a plurality of through holes is shown in FIG.
【0055】(実施例1)本発明の塗料組成物であり、
優れた吸放湿性能を示した。また、図1に示すように、
低周波領域において高い吸音率を示した。Example 1 A coating composition of the present invention,
It showed excellent moisture absorption and desorption performance. Also, as shown in FIG.
The sound absorption coefficient was high in the low frequency region.
【0056】(実施例2)本発明の塗料組成物であり、
優れた吸放湿性能を示した。また、図2に示すように、
低周波領域における高い吸音率を示した。(Example 2) A coating composition of the present invention,
It showed excellent moisture absorption and desorption performance. Also, as shown in FIG.
It showed a high sound absorption coefficient in the low frequency region.
【0057】(実施例3)本発明の塗料組成物であり、
優れた吸放湿性能を示した。また、図3に示すように、
低周波領域における高い吸音率を示した。(Example 3) A coating composition of the present invention,
It showed excellent moisture absorption and desorption performance. Also, as shown in FIG.
It showed a high sound absorption coefficient in the low frequency region.
【0058】(実施例4)本発明の塗料組成物であり、
優れた吸放湿性能を示した。また、図4に示すように、
低周波領域における高い吸音率を示した。Example 4 A coating composition of the present invention,
It showed excellent moisture absorption and desorption performance. Also, as shown in FIG.
It showed a high sound absorption coefficient in the low frequency region.
【0059】(実施例5)本発明の塗料組成物であり、
優れた吸放湿性能を示した。また、図5に示すように、
低周波領域における高い吸音率を示した。Example 5 A coating composition of the present invention,
It showed excellent moisture absorption and desorption performance. Also, as shown in FIG.
It showed a high sound absorption coefficient in the low frequency region.
【0060】(実施例6)本発明の塗料組成物であり、
優れた吸放湿性能を示した。また、図6に示すように、
低周波領域における高い吸音率を示した。Example 6 A coating composition of the present invention,
It showed excellent moisture absorption and desorption performance. Also, as shown in FIG.
It showed a high sound absorption coefficient in the low frequency region.
【0061】(実施例7)本発明の塗料組成物であり、
優れた吸放湿性能を示した。また、図7に示すように、
低周波領域において高い吸音率を示した。Example 7 A coating composition of the present invention,
It showed excellent moisture absorption and desorption performance. Also, as shown in FIG.
The sound absorption coefficient was high in the low frequency region.
【0062】(比較例1)吸放湿性高分子粒子及び無機
質軽量骨材を含有していないため、吸放湿性は低い値と
なった。また、図8に示すように、低周波領域において
低い吸音率を示した。(Comparative Example 1) Since the moisture absorbing / releasing polymer particles and the inorganic lightweight aggregate were not contained, the moisture absorbing / releasing property was low. Further, as shown in FIG. 8, the sound absorption coefficient was low in the low frequency region.
【0063】(比較例2)吸放湿性高分子粒子及び無機
質軽量骨材を含有していないため、吸放湿性は低い値と
なった。また、図9に示すように、低周波領域において
低い吸音率を示した。Comparative Example 2 The moisture absorptive and desorptive property was low because it did not contain the moisture absorptive and desorptive polymer particles and the inorganic lightweight aggregate. Further, as shown in FIG. 9, the sound absorption coefficient was low in the low frequency region.
【0064】(比較例3)無機質軽量骨材を含有してい
ないため、吸放湿性に劣る結果となった。また、図10
に示すように、低周波領域において低い吸音率を示し
た。Comparative Example 3 Since the inorganic lightweight aggregate was not contained, the result was inferior in moisture absorption and desorption. In addition, FIG.
As shown in, the sound absorption coefficient was low in the low frequency region.
【0065】(比較例4)無機質軽量骨材を含有してお
らず、さらに吸湿率が本発明規定より小さいる珪藻土を
使用しているため、吸放湿性は低い値となった。また、
図11に示すように、低周波領域において低い吸音率を
示した。(Comparative Example 4) Since the diatomaceous earth which does not contain the inorganic lightweight aggregate and whose moisture absorption rate is smaller than that of the present invention is used, the moisture absorption / desorption property is low. Also,
As shown in FIG. 11, the sound absorption coefficient was low in the low frequency region.
【0066】(比較例5)吸放湿性高分子粒子を含有し
ていないため、図12に示すように、吸放湿性は低い値
となった。(Comparative Example 5) Since the moisture absorptive and desorptive polymer particles were not contained, the moisture absorptive and desorptive property was low as shown in FIG.
【0067】(比較例6)吸放湿性高分子粒子を含有し
ておらず、無機質軽量骨材の粒子径が本発明規定より小
さいため、吸放湿性は低い値となった。また、図13に
示すように、低周波領域において低い吸音率を示した。(Comparative Example 6) The moisture absorptive and desorptive property was low because the moisture absorptive and desorptive polymer particles were not contained and the particle diameter of the inorganic lightweight aggregate was smaller than that of the present invention. Further, as shown in FIG. 13, the sound absorption coefficient was low in the low frequency region.
【0068】(比較例7)無機質軽量骨材の粒子径が本
発明規定より小さいため、吸放湿性に劣る結果となっ
た。また、図14に示すように、低周波領域において低
い吸音率を示した。(Comparative Example 7) Since the particle size of the inorganic lightweight aggregate was smaller than that of the present invention, the result was inferior in moisture absorption and desorption. Further, as shown in FIG. 14, the sound absorption coefficient was low in the low frequency region.
【0069】(比較例8)吸湿率が本発明規定より小さ
いる珪藻土を使用しているため、図15に示すように、
吸放湿性は低い値となった。(Comparative Example 8) Since diatomaceous earth having a moisture absorption rate lower than that of the present invention is used, as shown in FIG.
Moisture absorption and desorption was low.
【0070】(比較例9)吸湿率が本発明規定より小さ
いる珪藻土を使用し、無機質軽量骨材の粒子径が本発明
規定より小さいため、吸放湿性は低い値となった。ま
た、図16に示すように、低周波領域において低い吸音
率を示した。(Comparative Example 9) Since diatomaceous earth having a moisture absorption rate smaller than that of the present invention was used and the particle diameter of the inorganic lightweight aggregate was smaller than that of the present invention, the moisture absorption / desorption property was low. Further, as shown in FIG. 16, the sound absorption coefficient was low in the low frequency region.
【0071】[0071]
【発明の効果】本発明によれば、水蒸気吸放湿性が高く
室内の調湿性に優れ、また低周波領域での優れた吸音性
能を示すため、結露防止、騒音の侵入の抑制といった室
内環境の改善に大きな効果を得ることができる。EFFECTS OF THE INVENTION According to the present invention, since it has a high water vapor absorption and desorption property, an excellent humidity control property in the room, and an excellent sound absorption performance in a low frequency region, it can prevent dew condensation and suppress the intrusion of noise. A great effect can be obtained for improvement.
【0072】[0072]
【図1】本発明実施例1の垂直入射吸音率の結果を示す
グラフである。FIG. 1 is a graph showing the results of normal incidence sound absorption coefficient of Example 1 of the present invention.
【図2】本発明実施例2の垂直入射吸音率の結果を示す
グラフである。FIG. 2 is a graph showing the results of normal incident sound absorption coefficient of Example 2 of the present invention.
【図3】本発明実施例3の垂直入射吸音率の結果を示す
グラフである。FIG. 3 is a graph showing the results of normal incidence sound absorption coefficient of Example 3 of the present invention.
【図4】本発明実施例4の垂直入射吸音率の結果を示す
グラフである。FIG. 4 is a graph showing the results of normal incidence sound absorption coefficient of Example 4 of the present invention.
【図5】本発明実施例5の垂直入射吸音率の結果を示す
グラフである。FIG. 5 is a graph showing the results of normal incidence sound absorption coefficient of Example 5 of the present invention.
【図6】本発明実施例6の垂直入射吸音率の結果を示す
グラフである。FIG. 6 is a graph showing the results of normal incidence sound absorption coefficient of Example 6 of the present invention.
【図7】本発明実施例7の垂直入射吸音率の結果を示す
グラフである。FIG. 7 is a graph showing the results of normal incident sound absorption coefficient of Example 7 of the present invention.
【図8】本発明比較例1の垂直入射吸音率の結果を示す
グラフである。FIG. 8 is a graph showing the results of normal incidence sound absorption coefficient of Comparative Example 1 of the present invention.
【図9】本発明比較例2の垂直入射吸音率の結果を示す
グラフである。FIG. 9 is a graph showing the results of the normal incidence sound absorption coefficient of Comparative Example 2 of the present invention.
【図10】本発明比較例3の垂直入射吸音率の結果を示
すグラフである。FIG. 10 is a graph showing the results of normal incident sound absorption coefficient of Comparative Example 3 of the present invention.
【図11】本発明比較例4の垂直入射吸音率の結果を示
すグラフである。FIG. 11 is a graph showing the results of normal incident sound absorption coefficient of Comparative Example 4 of the present invention.
【図12】本発明比較例5の垂直入射吸音率の結果を示
すグラフである。FIG. 12 is a graph showing the results of normal incidence sound absorption coefficient of Comparative Example 5 of the present invention.
【図13】本発明比較例6の垂直入射吸音率の結果を示
すグラフである。FIG. 13 is a graph showing the results of normal incident sound absorption coefficient of Comparative Example 6 of the present invention.
【図14】本発明比較例7の垂直入射吸音率の結果を示
すグラフである。FIG. 14 is a graph showing the results of normal incidence sound absorption coefficient of Comparative Example 7 of the present invention.
【図15】本発明比較例8の垂直入射吸音率の結果を示
すグラフである。FIG. 15 is a graph showing the results of normal incidence sound absorption coefficient of Comparative Example 8 of the present invention.
【図16】本発明比較例9の垂直入射吸音率の結果を示
すグラフである。16 is a graph showing the results of normal incident sound absorption coefficient of Comparative Example 9 of the present invention. FIG.
【図17】石膏ボードのみの垂直入射吸音率の結果を示
すグラフである。FIG. 17 is a graph showing the results of normal incidence sound absorption coefficient of only gypsum board.
【図18】複数の貫通孔を有する石膏ボードのみの垂直
入射吸音率の結果を示すグラフである。FIG. 18 is a graph showing the results of normal incidence sound absorption coefficient of only a gypsum board having a plurality of through holes.
───────────────────────────────────────────────────── フロントページの続き Fターム(参考) 2E110 AA14 AA33 AA65 AB03 AB04 AB23 BA02 BA12 BB04 BB05 BB09 BB18 GA33X GB03X GB06X GB16X GB17X GB19X GB62X 4F100 AA01A AA03B AE06B AK01A AL05A AT00B BA02 CA24A CC00A DC11B DE01A EH46 EH462 EJ86 EJ861 EJ98 EJ982 GB08 JC00 JD15 JD15A JD16 JD16A JH01 JL07 JM01A JM02A YY00A 4J038 CB021 CC012 CD031 CD091 CE021 CF021 CG141 CG142 CG162 CG172 DB001 DB022 DG001 DL031 EA011 GA02 GA03 GA06 GA07 HA486 HA556 HA566 JB18 JB26 JB38 KA02 KA03 KA20 MA10 NA07 PB05 PC01 PC04 ─────────────────────────────────────────────────── ─── Continued front page F-term (reference) 2E110 AA14 AA33 AA65 AB03 AB04 AB23 BA02 BA12 BB04 BB05 BB09 BB18 GA33X GB03X GB06X GB16X GB17X GB19X GB62X 4F100 AA01A AA03B AE06B AK01A AL05A AT00B BA02 CA24A CC00A DC11B DE01A EH46 EH462 EJ86 EJ861 EJ98 EJ982 GB08 JC00 JD15 JD15A JD16 JD16A JH01 JL07 JM01A JM02A YY00A 4J038 CB021 CC012 CD031 CD091 CE021 CF021 CG141 CG142 CG162 CG172 DB001 DB022 DG001 DL031 EA011 GA02 GA03 GA06 GA07 HA486 HA556 HA566 JB18 JB26 JB38 KA02 KA03 KA20 MA10 NA07 PB05 PC01 PC04
Claims (5)
20℃、相対湿度45%における吸湿率5重量%以上の
吸放湿性高分子粒子、(C)平均粒子径が30μm以上
の無機質軽量骨材、を基本構成とし、各成分の固形分比
率が(A)成分100重量部に対し、(B)成分1〜1
00重量部、(C)成分50〜300重量部であること
を特徴とする内装用塗料組成物。1. (A) Synthetic resin emulsion, (B) Moisture-absorbing and desorbing polymer particles having a moisture absorption rate of 5% by weight or more at a temperature of 20 ° C. and a relative humidity of 45%, and (C) an inorganic lightweight having an average particle size of 30 μm or more. Aggregate is the basic composition, and the solid content ratio of each component is 100 parts by weight of the component (A), and the component (B) is 1 to 1.
00 parts by weight, 50 to 300 parts by weight of component (C), an interior coating composition.
ションであり、(B)が温度20℃、相対湿度45%に
おける吸湿率5重量%以上の反応性官能基含有吸放湿性
高分子粒子であり、さらに、(D)(A)及び(B)成
分の反応性官能基と反応可能な官能基を有する架橋剤を
含有し、(D)成分の固形分比率が(A)成分100重
量部に対し、0.05〜15重量部であることを特徴と
する請求項1に記載の内装用塗料組成物。2. (A) is a reactive functional group-containing synthetic resin emulsion, and (B) is a reactive functional group-containing hygroscopic polymer having a moisture absorption rate of 5% by weight or more at a temperature of 20 ° C. and a relative humidity of 45%. The particles are cross-linking agents having a functional group capable of reacting with the reactive functional groups of the components (D), (A) and (B), and the solid content ratio of the component (D) is 100 as the component (A). The interior coating composition according to claim 1, which is 0.05 to 15 parts by weight with respect to parts by weight.
物により形成される塗膜が基材に積層されたことを特徴
とする内装用ボード。3. An interior board, wherein a coating film formed from the interior coating composition according to claim 1 or 2 is laminated on a base material.
シウムボードから選ばれる1種であることを特徴とする
請求項3に記載の内装用ボード。4. The interior board according to claim 3, wherein the base material is one selected from gypsum board, slate board and calcium silicate board.
とする請求項3または4に記載の内装用ボード。5. The interior board according to claim 3, wherein the base material has a plurality of through holes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002348914A JP4331934B2 (en) | 2001-12-13 | 2002-11-29 | Interior coating composition and interior board using the same |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001380563 | 2001-12-13 | ||
| JP2001-380563 | 2001-12-13 | ||
| JP2002348914A JP4331934B2 (en) | 2001-12-13 | 2002-11-29 | Interior coating composition and interior board using the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2003261831A true JP2003261831A (en) | 2003-09-19 |
| JP4331934B2 JP4331934B2 (en) | 2009-09-16 |
Family
ID=29217710
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002348914A Expired - Fee Related JP4331934B2 (en) | 2001-12-13 | 2002-11-29 | Interior coating composition and interior board using the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4331934B2 (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005068568A1 (en) * | 2004-01-14 | 2005-07-28 | Toshiyuki Aiba | Wall-coating material, and wall paper and wall material each coated therewith |
| JP2009197557A (en) * | 2008-02-25 | 2009-09-03 | Daiwa House Industry Co Ltd | Wall structure and wall material for building using moisture absorption/desorption material |
| JP2012111809A (en) * | 2010-11-22 | 2012-06-14 | Masanaga Sakaguchi | Dew condensation prevention agent |
| WO2016067992A1 (en) * | 2014-10-28 | 2016-05-06 | 株式会社ケープラン | Plastering material composition |
| JP2016179672A (en) * | 2015-03-23 | 2016-10-13 | エスケー化研株式会社 | Laminated body |
| JP2018071316A (en) * | 2016-11-04 | 2018-05-10 | ケイミュー株式会社 | Building materials |
| CN114351126A (en) * | 2022-01-10 | 2022-04-15 | 万华化学集团股份有限公司 | Preparation method of stainless steel fiber-loaded ZSM-5 molecular sieve, water-based damping coating and preparation method thereof |
-
2002
- 2002-11-29 JP JP2002348914A patent/JP4331934B2/en not_active Expired - Fee Related
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005068568A1 (en) * | 2004-01-14 | 2005-07-28 | Toshiyuki Aiba | Wall-coating material, and wall paper and wall material each coated therewith |
| JP2005200508A (en) * | 2004-01-14 | 2005-07-28 | Toshiyuki Aeba | Coating material for wall surface and wallpaper and wall material coated therewith |
| JP2009197557A (en) * | 2008-02-25 | 2009-09-03 | Daiwa House Industry Co Ltd | Wall structure and wall material for building using moisture absorption/desorption material |
| JP2012111809A (en) * | 2010-11-22 | 2012-06-14 | Masanaga Sakaguchi | Dew condensation prevention agent |
| WO2016067992A1 (en) * | 2014-10-28 | 2016-05-06 | 株式会社ケープラン | Plastering material composition |
| JP5966193B1 (en) * | 2014-10-28 | 2016-08-10 | 株式会社ケープラン | Painted wall material composition |
| JP2016179672A (en) * | 2015-03-23 | 2016-10-13 | エスケー化研株式会社 | Laminated body |
| JP2018071316A (en) * | 2016-11-04 | 2018-05-10 | ケイミュー株式会社 | Building materials |
| JP7112180B2 (en) | 2016-11-04 | 2022-08-03 | ケイミュー株式会社 | building material |
| CN114351126A (en) * | 2022-01-10 | 2022-04-15 | 万华化学集团股份有限公司 | Preparation method of stainless steel fiber-loaded ZSM-5 molecular sieve, water-based damping coating and preparation method thereof |
| CN114351126B (en) * | 2022-01-10 | 2023-10-17 | 万华化学集团股份有限公司 | Preparation method of ZSM-5 molecular sieve loaded with stainless steel fibers, water-based damping paint and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4331934B2 (en) | 2009-09-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4331934B2 (en) | Interior coating composition and interior board using the same | |
| JP2000281838A (en) | High damping material composition | |
| JP2004256649A (en) | Moisture-conditioning coating material | |
| JP2616770B2 (en) | Paint composition | |
| KR20050090141A (en) | The preparation of water-borne layered coating materials for noise suppression of building floors | |
| JP2005155216A (en) | Outside thermal insulating waterproof construction method for roof top | |
| JPH10245255A (en) | Highly permeable inorganic diatomaceous earth-based finishing material and construction method using it | |
| JP7531845B2 (en) | External insulation structure and construction method for external insulation structure | |
| JPH0216043A (en) | Waterproof sheet for wall | |
| JP2002080798A (en) | Moisture-absorbing and releasing coating composition and moisture-absorbing and releasing sheet | |
| JP2002317143A (en) | Coating composition for building and application method for building interior and exterior | |
| JP4118033B2 (en) | Cooling layer forming body and composition for forming body | |
| JP4484456B2 (en) | Water-based paint composition | |
| JP5564169B2 (en) | Thermal insulation structure | |
| JP7694924B2 (en) | Thermal insulation methods for buildings, thermal insulation structures for buildings, adhesives, and surface protection materials | |
| KR102566139B1 (en) | Eco-friendly waterproofing composition using coffee grounds and waterproofing method using the same | |
| JP2003155786A (en) | Moisture absorbing and discharging fire-protecting building material | |
| JP4656770B2 (en) | COOLING LAYER LAMINATE STRUCTURE AND METHOD FOR FORMING THE SAME | |
| JP4484594B2 (en) | Humidity control coating material | |
| JP2804820B2 (en) | Structure to prevent condensation forming space | |
| JP2023135584A (en) | Method for forming humidity-controlling coated film, and laminated structure of the same | |
| JP2868579B2 (en) | Insulation material and structure using this insulation material | |
| JP2576011B2 (en) | Paint for plywood | |
| JPH09174731A (en) | Dew condensation prevention material for outer wall or attic of building and dew condensation prevention method | |
| JP2000248648A (en) | Moisture-proof sheet for building outer wall, wall structure, and method of preventing dew condensation in wall |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20051020 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20080723 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20090205 |
|
| A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20090331 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20090525 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20090619 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 4331934 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120626 Year of fee payment: 3 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130626 Year of fee payment: 4 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| LAPS | Cancellation because of no payment of annual fees |